WO2008029305A1 - Temperature-stable cast-iron alloy and its use - Google Patents

Temperature-stable cast-iron alloy and its use Download PDF

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Publication number
WO2008029305A1
WO2008029305A1 PCT/IB2007/052214 IB2007052214W WO2008029305A1 WO 2008029305 A1 WO2008029305 A1 WO 2008029305A1 IB 2007052214 W IB2007052214 W IB 2007052214W WO 2008029305 A1 WO2008029305 A1 WO 2008029305A1
Authority
WO
WIPO (PCT)
Prior art keywords
iron alloy
cast
temperature
alloy according
iron
Prior art date
Application number
PCT/IB2007/052214
Other languages
French (fr)
Inventor
Asger Karlsson
Rasmus Kirkegaard Stage
Original Assignee
Flsmidth A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Flsmidth A/S filed Critical Flsmidth A/S
Priority to EP20070766720 priority Critical patent/EP2059622A1/en
Priority to US12/377,043 priority patent/US20110042051A1/en
Priority to MX2009002119A priority patent/MX2009002119A/en
Priority to CN2007800329727A priority patent/CN101512031B/en
Priority to BRPI0716636-2B1A priority patent/BRPI0716636B1/en
Publication of WO2008029305A1 publication Critical patent/WO2008029305A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C37/00—Cast-iron alloys
    • C22C37/06—Cast-iron alloys containing chromium
    • C22C37/08—Cast-iron alloys containing chromium with nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C37/00—Cast-iron alloys
    • C22C37/10—Cast-iron alloys containing aluminium or silicon

Definitions

  • the present invention relates to a temperature-stable cast-iron alloy having a high wear resistance at temperatures ranging between 500 and 900°C.
  • clinker cooler is used for cooling cement clinker which is introduced to the clinker cooler from a preceding kiln at a temperature ranging between 1300 and 1450° C.
  • the cement clinker is directed through the clinker cooler by means of appropriate means of conveyance which are typically made up of some form of elements which are reciprocated in the direction of movement of the cement clinker, and thus exposed to significant wear at temperatures ranging between 500 and 900 °C.
  • a wear-resistant cast-iron alloy having the following composition expressed in weight percentages: chromium: 12-25 %, carbon: 1.5-6 %, manganese: 2-7 %, silicon: up to 1.5%, molybdenum: up to 2 %, nickel: up to 4 %, micro alloying elements selected from the group consisting of titanium, zirconium, niobium, boron, vanadium, and tungsten: up to 2 % of each of one or more of the elements, and balance iron.
  • the alloy is subjected to heat treatment in order to give it a martensitic matrix.
  • This type of matrix is very hard and brittle, and machine elements manufactured from such material are prone to cracking if subjected to impacts or blows. Furthermore, this type of matrix lacks thermal stability due to its softening at temperatures in excess of 400° C.
  • the applicant of the present patent application also has experience with regard to a cast-iron alloy according to European standard 10295 (2002), material: G-X40 CrNiSi25-12, Material No.
  • both materials tend to form a sigma phase which is a brittle inter-metallic phase consisting of equal parts of iron and chromium, and hence be brittle, and that they are not particular wear resistant.
  • a cast-iron alloy according to the invention having the following composition expressed in weight percentages: chromium: 15.0-20.0 %, carbon: 1.0-2.0 %, manganese: 1.5-2.0 %, silicon: 0.8-1.2 %, nickel: 8.0-10.0 %, molybdenum: 0.8-1.2 % balance iron and unavoidable metallic and non-metallic contaminants, where the non-metallic contaminants comprise nitrogen, oxygen, phosphorous and sulphur.
  • the alloy according to the invention has significantly improved wear characteristics compared to the alloy according to the European standard 10295 and the modified version hereof, both defined above.
  • the test results show that the alloy according to the invention has a wear resistance which is approximately four times higher than that of the alloy according to European standard 10295 and twice as high as that of the modified version hereof.
  • the improved wear resistance is mainly ascribable to the optimization of the carbon-chromium ratio, resulting in optimum formation of chromium carbides which constitute the wear-resistant component of the alloy.
  • the cast-iron alloy according to the invention preferably comprises 16.5-19.5 weight percentage, most preferably 17.0-19.0 weight percentage chromium.
  • the cast-iron alloy according to the invention preferably comprises 1.25-1.85 weight percentage carbon, most preferably 1.5- 1.7 weight percentage carbon.
  • the cast-iron alloy according to the invention preferentially has an austenitic matrix.
  • the cast-iron alloy can be manufactured and cast into blanks using generally known techniques.
  • the described cast-iron alloy is particularly suitable for use in connection with machine parts in clinker coolers for cooling cement clinker.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Heat Treatment Of Articles (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

A description is given of a temperature-stable cast-iron alloy having high wear resistance at temperatures between 500 and 900° C. The alloy is characterized in that it has the following composition expressed in weight percentages: chromium: 15.0-20.0 %, carbon: 1.0-2.0 %, manganese: 1.5-2.0 %, silicon: 0.8-1.2 %, nickel: 8.0-10.0 %, molybdenum: 0.8-1.2 % balance iron and unavoidable metallic and non-metallic contaminants where the non-metallic contaminants comprise nitrogen, oxygen, phosphorous and sulphur. Hereby is obtained a cast-iron alloy which has a higher wear resistance and a reduced tendency to form the undesirable sigma phase when heated to temperatures between 500 and 900 °C as compared to the known allows.

Description

TEMPERATURE-STABLE CAST-IRON ALLOY AND ITS USE
The present invention relates to a temperature-stable cast-iron alloy having a high wear resistance at temperatures ranging between 500 and 900°C.
Many industries use machines containing machine parts which incur significant wear at relatively high temperatures in excess of 500 °C. For example, in the cement manufacturing industry a so-called clinker cooler is used for cooling cement clinker which is introduced to the clinker cooler from a preceding kiln at a temperature ranging between 1300 and 1450° C. The cement clinker is directed through the clinker cooler by means of appropriate means of conveyance which are typically made up of some form of elements which are reciprocated in the direction of movement of the cement clinker, and thus exposed to significant wear at temperatures ranging between 500 and 900 °C.
From WO 2004/104253 is known a wear-resistant cast-iron alloy having the following composition expressed in weight percentages: chromium: 12-25 %, carbon: 1.5-6 %, manganese: 2-7 %, silicon: up to 1.5%, molybdenum: up to 2 %, nickel: up to 4 %, micro alloying elements selected from the group consisting of titanium, zirconium, niobium, boron, vanadium, and tungsten: up to 2 % of each of one or more of the elements, and balance iron.
According to the publication, the alloy is subjected to heat treatment in order to give it a martensitic matrix. This type of matrix is very hard and brittle, and machine elements manufactured from such material are prone to cracking if subjected to impacts or blows. Furthermore, this type of matrix lacks thermal stability due to its softening at temperatures in excess of 400° C. The applicant of the present patent application also has experience with regard to a cast-iron alloy according to European standard 10295 (2002), material: G-X40 CrNiSi25-12, Material No. :1.4837, which has the following composition expressed in weight percentages: chromium: 24.0-27.0 %, carbon: 0.3-0.5 %, manganese: up to 2.0 %, silicon: 1.0-2.5 %, molybdenum: up to 0.5 %, nickel: 1 1.0-14.0 %, phosphorous: up to 0.040 % and sulphur: up to 0.030 %
and a modified version hereof having the following composition expressed in weight percentages: chromium: 24.0-26.0 %, carbon: 0.7-0.9 %, manganese: 0.6-1.0 %, silicon: 1.5-2.0 % and nickel: 2.5-3.5 %
Experience with these two materials has shown that after prolonged heating to temperatures between 500 and 900 °C both materials tend to form a sigma phase which is a brittle inter-metallic phase consisting of equal parts of iron and chromium, and hence be brittle, and that they are not particular wear resistant.
It is the objective of the present invention to provide a cast-iron alloy having a higher wear resistance and a reduced tendency to form a sigma phase at temperatures between 500 and 900 °C as compared to the cast-iron alloys currently available.
According to the invention this is achieved by a cast-iron alloy according to the invention having the following composition expressed in weight percentages: chromium: 15.0-20.0 %, carbon: 1.0-2.0 %, manganese: 1.5-2.0 %, silicon: 0.8-1.2 %, nickel: 8.0-10.0 %, molybdenum: 0.8-1.2 % balance iron and unavoidable metallic and non-metallic contaminants, where the non-metallic contaminants comprise nitrogen, oxygen, phosphorous and sulphur.
Hereby is obtained a cast-iron alloy having a higher wear resistance and a reduced tendency to form the undesired sigma phase when heated to temperatures between 500 and 900 °C as compared to the previously mentioned known alloys.
Laboratory experiments carried out by the applicant of the present patent application have indicated that the alloy according to the invention has significantly improved wear characteristics compared to the alloy according to the European standard 10295 and the modified version hereof, both defined above. The test results show that the alloy according to the invention has a wear resistance which is approximately four times higher than that of the alloy according to European standard 10295 and twice as high as that of the modified version hereof. The improved wear resistance is mainly ascribable to the optimization of the carbon-chromium ratio, resulting in optimum formation of chromium carbides which constitute the wear-resistant component of the alloy.
Furthermore, laboratory experiments during which the alloy according to the invention over a period of 8 weeks underwent heat treatment at a temperature of 500 °C with a subsequent microscopy examination, have shown that the alloy exhibits significant heat stability, given the absence of any signs of sigma phase formation. In order to avoid significant deterioration of the mechanical characteristics of the iron alloy, the non-metallic contaminants comprising nitrogen, oxygen, phosphorous and sulphur should not exceed the maximum limits specified below: maximum 0.020 N, maximumi O ppm O, maximum 0.040 P, and maximum 0.030 S.
The cast-iron alloy according to the invention preferably comprises 16.5-19.5 weight percentage, most preferably 17.0-19.0 weight percentage chromium.
Furthermore, the cast-iron alloy according to the invention preferably comprises 1.25-1.85 weight percentage carbon, most preferably 1.5- 1.7 weight percentage carbon.
The cast-iron alloy according to the invention preferentially has an austenitic matrix.
The cast-iron alloy can be manufactured and cast into blanks using generally known techniques.
The described cast-iron alloy is particularly suitable for use in connection with machine parts in clinker coolers for cooling cement clinker.

Claims

Patent claims
1. Temperature-stable cast-iron alloy having high wear resistance at temperatures between 500 - 900 °C, characterized in that it has the following composition expressed in weight percentages: chromium: 15.0-20.0 %, carbon: 1.0-2.0 %, manganese: 1.5-2.0 %, silicon: 0.8-1.2 %, nickel: 8.0-10.0 %, molybdenum: 0.8-1.2 % balance iron and unavoidable metallic and non-metallic contaminants where the non-metallic contaminants comprise nitrogen, oxygen, phosphorous and sulphur.
2. Temperature-stable cast-iron alloy according to claim 1 , characterized in that it comprises 16.5-19.5 weight percentage chromium.
3. Temperature-stable cast-iron alloy according to claim 2, characterized in that it comprises 17.0-19.0 weight percentage chromium.
4. Temperature-stable cast-iron alloy according to any of the preceding claims, characterized in that it comprises 1.25-1.85 weight percentage carbon.
5. Temperature-stable cast-iron alloy according to claim 4, characterized in that it comprises 1.5 - 1.7 weight percentage carbon.
6. Temperature-stable cast-iron alloy according to any of the preceding claims, characterized in that it has an austenitic matrix.
7. Use of cast-iron alloy according to any of the preceding claims for machine parts in clinker coolers for cooling of cement clinker.
PCT/IB2007/052214 2006-09-08 2007-06-12 Temperature-stable cast-iron alloy and its use WO2008029305A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP20070766720 EP2059622A1 (en) 2006-09-08 2007-06-12 Temperature-stable cast-iron alloy and its use
US12/377,043 US20110042051A1 (en) 2006-09-08 2007-06-12 Temperature stable cast-iron alloy and its use
MX2009002119A MX2009002119A (en) 2006-09-08 2007-06-12 Temperature-stable cast-iron alloy and its use.
CN2007800329727A CN101512031B (en) 2006-09-08 2007-06-12 Temperature-stable cast-iron alloy and its use
BRPI0716636-2B1A BRPI0716636B1 (en) 2006-09-08 2007-06-12 TEMPERATURE STABLE CAST IRON ALLOY

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA200601155 2006-09-08
DKPA200601155A DK176960B1 (en) 2006-09-08 2006-09-08 Temperature stable cast iron alloy and its use

Publications (1)

Publication Number Publication Date
WO2008029305A1 true WO2008029305A1 (en) 2008-03-13

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Family Applications (1)

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PCT/IB2007/052214 WO2008029305A1 (en) 2006-09-08 2007-06-12 Temperature-stable cast-iron alloy and its use

Country Status (9)

Country Link
US (1) US20110042051A1 (en)
EP (1) EP2059622A1 (en)
CN (1) CN101512031B (en)
BR (1) BRPI0716636B1 (en)
DK (1) DK176960B1 (en)
MX (1) MX2009002119A (en)
RU (1) RU2430182C2 (en)
UA (1) UA93557C2 (en)
WO (1) WO2008029305A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102230123B (en) * 2011-06-17 2013-10-02 湖南长高新材料股份有限公司 Chromium-based modified wear-resistant cast iron and preparation method thereof
CN103741011A (en) * 2013-12-27 2014-04-23 黄忠波 Cast iron alloy with high wear resistance and temperature stability
CN103741015A (en) * 2013-12-27 2014-04-23 黄忠波 Cast iron alloy with high wear resistance and high-temperature stability
IT201900012738A1 (en) * 2019-07-24 2021-01-24 Freni Brembo Spa CAST IRON, ESPECIALLY FOR DISC BRAKE COMPONENTS
EA037998B1 (en) * 2020-01-10 2021-06-22 Физули Расул оглы Расулов Alloyed material for obtaining wear-resistant and corrosion-resistant parts

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2818734A1 (en) * 1978-04-28 1979-10-31 Wahl Verschleiss Tech Low cost armour plating - comprises chilled cast iron layers opt. contg. hard inserts
WO2004104253A1 (en) * 2003-05-22 2004-12-02 Weir Warman Limited Wear resistant cast iron

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3543413A (en) * 1968-12-18 1970-12-01 Hanford Foundry Co Removable clinker cooler grate plates and support frame therefor
US4477283A (en) * 1981-07-21 1984-10-16 Eddie K. Wilson, Sr. Process and apparatus for producing hydraulic cements
CN1027548C (en) * 1989-05-06 1995-02-01 机械电子工业部沈阳铸造研究所 Anti-abrasive and anti-corrosive austenic cast iron and its producing technology
US5202087A (en) * 1992-07-31 1993-04-13 The Carondelet Corporation Cement cooler grate alloy
CN1028376C (en) * 1993-06-11 1995-05-10 山东省冶金研究所 Low-carbon nigh Cr cast iron wear-resisting material
US5674449A (en) * 1995-05-25 1997-10-07 Winsert, Inc. Iron base alloys for internal combustion engine valve seat inserts, and the like

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2818734A1 (en) * 1978-04-28 1979-10-31 Wahl Verschleiss Tech Low cost armour plating - comprises chilled cast iron layers opt. contg. hard inserts
WO2004104253A1 (en) * 2003-05-22 2004-12-02 Weir Warman Limited Wear resistant cast iron

Also Published As

Publication number Publication date
CN101512031B (en) 2010-12-08
US20110042051A1 (en) 2011-02-24
BRPI0716636B1 (en) 2014-10-29
CN101512031A (en) 2009-08-19
RU2009106999A (en) 2010-10-20
EP2059622A1 (en) 2009-05-20
DK176960B1 (en) 2010-07-26
MX2009002119A (en) 2009-03-09
BRPI0716636A2 (en) 2012-12-25
DK200601155A (en) 2008-03-09
UA93557C2 (en) 2011-02-25
RU2430182C2 (en) 2011-09-27

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