WO2008020044A3 - Method and apparatus for liquefying a hydrocarbon-containing feed stream - Google Patents

Method and apparatus for liquefying a hydrocarbon-containing feed stream Download PDF

Info

Publication number
WO2008020044A3
WO2008020044A3 PCT/EP2007/058461 EP2007058461W WO2008020044A3 WO 2008020044 A3 WO2008020044 A3 WO 2008020044A3 EP 2007058461 W EP2007058461 W EP 2007058461W WO 2008020044 A3 WO2008020044 A3 WO 2008020044A3
Authority
WO
WIPO (PCT)
Prior art keywords
cooling
stream
refrigerant
feed stream
liquefying
Prior art date
Application number
PCT/EP2007/058461
Other languages
French (fr)
Other versions
WO2008020044A2 (en
Inventor
Marco Dick Jager
Suyog Kalyanji Kotecha
Irina Tanaeva
Original Assignee
Shell Int Research
Marco Dick Jager
Suyog Kalyanji Kotecha
Irina Tanaeva
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research, Marco Dick Jager, Suyog Kalyanji Kotecha, Irina Tanaeva filed Critical Shell Int Research
Priority to AU2007285734A priority Critical patent/AU2007285734B2/en
Priority to EP07788440.1A priority patent/EP2052197B1/en
Priority to US12/377,655 priority patent/US20110185767A1/en
Publication of WO2008020044A2 publication Critical patent/WO2008020044A2/en
Publication of WO2008020044A3 publication Critical patent/WO2008020044A3/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0292Refrigerant compression by cold or cryogenic suction of the refrigerant gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022Hydrocarbons, e.g. natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
    • F25J1/0055Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/007Primary atmospheric gases, mixtures thereof
    • F25J1/0072Nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/008Hydrocarbons
    • F25J1/0087Propane; Propylene
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/008Hydrocarbons
    • F25J1/0092Mixtures of hydrocarbons comprising possibly also minor amounts of nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0211Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
    • F25J1/0217Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as at least a three level refrigeration cascade with at least one MCR cycle
    • F25J1/0218Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as at least a three level refrigeration cascade with at least one MCR cycle with one or more SCR cycles, e.g. with a C3 pre-cooling cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0262Details of the cold heat exchange system
    • F25J1/0264Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams
    • F25J1/0265Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams comprising cores associated exclusively with the cooling of a refrigerant stream, e.g. for auto-refrigeration or economizer
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0262Details of the cold heat exchange system
    • F25J1/0264Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams
    • F25J1/0265Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams comprising cores associated exclusively with the cooling of a refrigerant stream, e.g. for auto-refrigeration or economizer
    • F25J1/0268Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams comprising cores associated exclusively with the cooling of a refrigerant stream, e.g. for auto-refrigeration or economizer using a dedicated refrigeration means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/64Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general

Abstract

Method and apparatus for liquefying a hydrocarbon stream such as natural gas from a feed stream. The method comprises at least the steps of: first cooling the feed stream (10) against a first cooling refrigerant being cycled in a first cooling refrigerant circuit (100), wherein the first cooling refrigerant comprises > 90 mol% propane, second cooling the cooled gas stream (20) to obtain a liquefied stream (60) against a first mixed refrigerant being cycled in a first mixed refrigerant circuit (200), wherein said second cooling is in two or more heat exchangers (42, 44), at least two of which are operating at different pressures and sub-cooling the liquefied stream (60) against a second mixed refrigerant or against a nitrogen refrigerant being cycled in a sub-cooling refrigerant circuit (300), thereby obtaining a sub-cooled hydrocarbon stream (70).
PCT/EP2007/058461 2006-08-17 2007-08-15 Method and apparatus for liquefying a hydrocarbon-containing feed stream WO2008020044A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU2007285734A AU2007285734B2 (en) 2006-08-17 2007-08-15 Method and apparatus for liquefying a hydrocarbon-containing feed stream
EP07788440.1A EP2052197B1 (en) 2006-08-17 2007-08-15 Method and apparatus for liquefying a hydrocarbon-containing feed stream
US12/377,655 US20110185767A1 (en) 2006-08-17 2007-08-15 Method and apparatus for liquefying a hydrocarbon-containing feed stream

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06119050.0 2006-08-17
EP06119050 2006-08-17

Publications (2)

Publication Number Publication Date
WO2008020044A2 WO2008020044A2 (en) 2008-02-21
WO2008020044A3 true WO2008020044A3 (en) 2008-11-27

Family

ID=37762283

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/058461 WO2008020044A2 (en) 2006-08-17 2007-08-15 Method and apparatus for liquefying a hydrocarbon-containing feed stream

Country Status (5)

Country Link
US (1) US20110185767A1 (en)
EP (1) EP2052197B1 (en)
AU (1) AU2007285734B2 (en)
RU (1) RU2447382C2 (en)
WO (1) WO2008020044A2 (en)

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Publication number Priority date Publication date Assignee Title
US20080141711A1 (en) 2006-12-18 2008-06-19 Mark Julian Roberts Hybrid cycle liquefaction of natural gas with propane pre-cooling
US9441877B2 (en) 2010-03-17 2016-09-13 Chart Inc. Integrated pre-cooled mixed refrigerant system and method
WO2012027063A1 (en) * 2010-08-23 2012-03-01 Dresser-Rand Company Process for throttling a compressed gas for evaporative cooling
EP2426451A1 (en) 2010-09-06 2012-03-07 Shell Internationale Research Maatschappij B.V. Method and apparatus for cooling a gaseous hydrocarbon stream
EP2426452A1 (en) 2010-09-06 2012-03-07 Shell Internationale Research Maatschappij B.V. Method and apparatus for cooling a gaseous hydrocarbon stream
EP2597406A1 (en) 2011-11-25 2013-05-29 Shell Internationale Research Maatschappij B.V. Method and apparatus for removing nitrogen from a cryogenic hydrocarbon composition
RU2607198C2 (en) 2011-12-12 2017-01-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Method and apparatus for removing nitrogen from cryogenic hydrocarbon composition
CN103998882B (en) 2011-12-12 2016-04-13 国际壳牌研究有限公司 For removing the method and apparatus of nitrogen from low temperature hydrocarbon composition
WO2013087571A2 (en) 2011-12-12 2013-06-20 Shell Internationale Research Maatschappij B.V. Method and apparatus for removing nitrogen from a cryogenic hydrocarbon composition
EP2604960A1 (en) 2011-12-15 2013-06-19 Shell Internationale Research Maatschappij B.V. Method of operating a compressor and system and method for producing a liquefied hydrocarbon stream
EP2891243A2 (en) 2012-08-31 2015-07-08 Shell Internationale Research Maatschappij B.V. Variable speed drive system, method for operating a variable speed drive system and method for refrigerating a hydrcarbon stream
US11408673B2 (en) 2013-03-15 2022-08-09 Chart Energy & Chemicals, Inc. Mixed refrigerant system and method
CA3140415A1 (en) 2013-03-15 2014-09-18 Chart Energy & Chemicals, Inc. Mixed refrigerant system and method
US11428463B2 (en) 2013-03-15 2022-08-30 Chart Energy & Chemicals, Inc. Mixed refrigerant system and method
BR112015026176B1 (en) 2013-04-22 2022-05-10 Shell Internationale Research Maatschappij B.V Method and apparatus for producing a liquefied hydrocarbon stream
EP2857782A1 (en) 2013-10-04 2015-04-08 Shell International Research Maatschappij B.V. Coil wound heat exchanger and method of cooling a process stream
EP2869415A1 (en) 2013-11-04 2015-05-06 Shell International Research Maatschappij B.V. Modular hydrocarbon fluid processing assembly, and methods of deploying and relocating such assembly
EP2977430A1 (en) 2014-07-24 2016-01-27 Shell Internationale Research Maatschappij B.V. A hydrocarbon condensate stabilizer and a method for producing a stabilized hydrocarbon condenstate stream
EP2977431A1 (en) 2014-07-24 2016-01-27 Shell Internationale Research Maatschappij B.V. A hydrocarbon condensate stabilizer and a method for producing a stabilized hydrocarbon condenstate stream
EP3032204A1 (en) 2014-12-11 2016-06-15 Shell Internationale Research Maatschappij B.V. Method and system for producing a cooled hydrocarbons stream
CA2988905A1 (en) * 2015-04-07 2016-10-13 Conocophillips Company Quench system for a refrigeration cycle of a liquefied natural gas facility and method of quenching
AR105277A1 (en) 2015-07-08 2017-09-20 Chart Energy & Chemicals Inc MIXED REFRIGERATION SYSTEM AND METHOD
WO2018212830A1 (en) * 2017-05-16 2018-11-22 Exxonmobil Upstream Research Company Method and system for efficient nonsynchronous lng production using large scale multi-shaft gas tusbines

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US6105389A (en) * 1998-04-29 2000-08-22 Institut Francais Du Petrole Method and device for liquefying a natural gas without phase separation of the coolant mixtures
US6347532B1 (en) * 1999-10-12 2002-02-19 Air Products And Chemicals, Inc. Gas liquefaction process with partial condensation of mixed refrigerant at intermediate temperatures
EP1340951A2 (en) * 1999-10-12 2003-09-03 Air Products And Chemicals, Inc. Hybrid cycle for production of liquefied natural gas
US20050056051A1 (en) * 2003-09-17 2005-03-17 Roberts Mark Julian Hybrid gas liquefaction cycle with multiple expanders
WO2006072365A1 (en) * 2005-01-03 2006-07-13 Linde Aktiengesellschaft Method for liquefying a hydrocarbon-enriched flow
EP1790926A1 (en) * 2005-11-24 2007-05-30 Shell Internationale Researchmaatschappij B.V. Method and apparatus for cooling a stream, in particular a hydrocarbon stream such as natural gas

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DE3521060A1 (en) * 1984-06-12 1985-12-12 Snamprogetti S.P.A., Mailand/Milano Method for cooling and liquefying gases
US6105389A (en) * 1998-04-29 2000-08-22 Institut Francais Du Petrole Method and device for liquefying a natural gas without phase separation of the coolant mixtures
US6347532B1 (en) * 1999-10-12 2002-02-19 Air Products And Chemicals, Inc. Gas liquefaction process with partial condensation of mixed refrigerant at intermediate temperatures
EP1340951A2 (en) * 1999-10-12 2003-09-03 Air Products And Chemicals, Inc. Hybrid cycle for production of liquefied natural gas
US20050056051A1 (en) * 2003-09-17 2005-03-17 Roberts Mark Julian Hybrid gas liquefaction cycle with multiple expanders
WO2006072365A1 (en) * 2005-01-03 2006-07-13 Linde Aktiengesellschaft Method for liquefying a hydrocarbon-enriched flow
EP1790926A1 (en) * 2005-11-24 2007-05-30 Shell Internationale Researchmaatschappij B.V. Method and apparatus for cooling a stream, in particular a hydrocarbon stream such as natural gas

Also Published As

Publication number Publication date
WO2008020044A2 (en) 2008-02-21
EP2052197A2 (en) 2009-04-29
US20110185767A1 (en) 2011-08-04
EP2052197B1 (en) 2018-05-16
AU2007285734B2 (en) 2010-07-08
RU2009109420A (en) 2010-09-27
RU2447382C2 (en) 2012-04-10
AU2007285734A1 (en) 2008-02-21

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