WO2008016888A3 - Hydroprocessing catalyst and process of use - Google Patents

Hydroprocessing catalyst and process of use Download PDF

Info

Publication number
WO2008016888A3
WO2008016888A3 PCT/US2007/074782 US2007074782W WO2008016888A3 WO 2008016888 A3 WO2008016888 A3 WO 2008016888A3 US 2007074782 W US2007074782 W US 2007074782W WO 2008016888 A3 WO2008016888 A3 WO 2008016888A3
Authority
WO
WIPO (PCT)
Prior art keywords
components
catalyst
catalyst composition
hydroprocessing catalyst
hydroprocessing
Prior art date
Application number
PCT/US2007/074782
Other languages
French (fr)
Other versions
WO2008016888A2 (en
Inventor
Theodorus Maesen
Darren Fong
Roger Vogel
Bowmann Lee
Dennis Dykstra
Original Assignee
Chevron Usa Inc
Theodorus Maesen
Darren Fong
Roger Vogel
Bowmann Lee
Dennis Dykstra
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Usa Inc, Theodorus Maesen, Darren Fong, Roger Vogel, Bowmann Lee, Dennis Dykstra filed Critical Chevron Usa Inc
Priority to EP07813564.7A priority Critical patent/EP2046496A4/en
Priority to JP2009522998A priority patent/JP2009545441A/en
Publication of WO2008016888A2 publication Critical patent/WO2008016888A2/en
Publication of WO2008016888A3 publication Critical patent/WO2008016888A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7815—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

This invention is directed to a catalyst composition effective in hydroprocessing and a process employing this catalyst. The catalyst composition comprises three acidic components acting in synergy to provide enhanced catalytic activity, when compared to any of the components alone or in combinations of two. Two of the components are large pore zeolites, and the third component is selected from the group comprising clays and amorphous silica/alumina.
PCT/US2007/074782 2006-07-31 2007-07-31 Hydroprocessing catalyst and process of use WO2008016888A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP07813564.7A EP2046496A4 (en) 2006-07-31 2007-07-31 Hydroprocessing catalyst and process of use
JP2009522998A JP2009545441A (en) 2006-07-31 2007-07-31 Hydrotreating catalyst and usage

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US82090706P 2006-07-31 2006-07-31
US60/820,907 2006-07-31
US82898307A 2007-07-26 2007-07-26
US11/828,983 2007-07-26

Publications (2)

Publication Number Publication Date
WO2008016888A2 WO2008016888A2 (en) 2008-02-07
WO2008016888A3 true WO2008016888A3 (en) 2008-08-07

Family

ID=38997794

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/074782 WO2008016888A2 (en) 2006-07-31 2007-07-31 Hydroprocessing catalyst and process of use

Country Status (3)

Country Link
EP (1) EP2046496A4 (en)
JP (1) JP2009545441A (en)
WO (1) WO2008016888A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104588121B (en) * 2013-11-03 2017-04-12 中国石油化工股份有限公司 Hydrocracking catalyst carrier and preparation method thereof

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102451744B (en) * 2010-10-15 2014-03-05 中国石油化工股份有限公司 Preparation method of hydrocracking catalyst
US10183286B2 (en) * 2015-08-11 2019-01-22 Chevron U.S.A. Inc. Noble metal zeolite catalyst for second-stage hydrocracking to make middle distillate
US10046317B2 (en) * 2015-08-11 2018-08-14 Chevron U.S.A. Inc. Middle distillate hydrocracking catalyst containing zeolite beta with low OD acidity and large domain size
US10040058B2 (en) * 2015-08-11 2018-08-07 Chevron U.S.A. Inc. Middle distillate hydrocracking catalyst containing zeolite USY, and zeolite beta with low acidity and large domain size
CN109304226B (en) * 2017-07-28 2021-06-01 中国石油天然气股份有限公司 Hydrocracking catalyst for increasing production of heavy naphtha and aviation kerosene, and preparation method and application thereof
CN109423336B (en) * 2017-08-31 2020-09-11 中国石油化工股份有限公司 Hydrocracking method
KR102570049B1 (en) * 2018-12-13 2023-08-22 차이나 페트로리움 앤드 케미컬 코포레이션 Hydrocracking catalyst and its manufacturing method and application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5160033A (en) * 1988-03-30 1992-11-03 Uop Octane gasoline catalyst and process using same in a hydrocracking process
US5536687A (en) * 1990-05-22 1996-07-16 Uop Catalyst containing zeolite Beta

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4837396A (en) * 1987-12-11 1989-06-06 Mobil Oil Corporation Zeolite beta containing hydrocarbon conversion catalyst of stability
US5194412A (en) * 1991-01-22 1993-03-16 W. R. Grace & Co.-Conn. Catalytic compositions
US6133186A (en) * 1997-03-06 2000-10-17 Shell Oil Company Process for the preparation of a catalyst composition
KR100605276B1 (en) * 1998-08-03 2006-07-26 쉘 인터내셔날 리서치 마챠피즈 비.브이. Process for the preparation of a catalyst composition
AU4823600A (en) * 1999-05-05 2000-11-17 Exxon Chemical Patents Inc. Zeolite bound catalyst containing at least three different zeolites; use for hydrocarbon conversion
CN1108356C (en) * 2000-10-26 2003-05-14 中国石油化工股份有限公司 High-activity high-or medium-oilness hydrocracking catalyst and its preparing process
EP1794264B1 (en) * 2004-09-08 2020-05-27 Shell International Research Maatschappij B.V. Hydrocracking catalyst composition
US20080011648A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate
US20080011649A1 (en) * 2006-07-17 2008-01-17 Li Wang Hydrocracking Catalyst Containing Beta and Y Zeolites, and Process for its use to make Distillate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5160033A (en) * 1988-03-30 1992-11-03 Uop Octane gasoline catalyst and process using same in a hydrocracking process
US5536687A (en) * 1990-05-22 1996-07-16 Uop Catalyst containing zeolite Beta

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2046496A4 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104588121B (en) * 2013-11-03 2017-04-12 中国石油化工股份有限公司 Hydrocracking catalyst carrier and preparation method thereof

Also Published As

Publication number Publication date
EP2046496A2 (en) 2009-04-15
EP2046496A4 (en) 2014-08-06
WO2008016888A2 (en) 2008-02-07
JP2009545441A (en) 2009-12-24

Similar Documents

Publication Publication Date Title
WO2008016888A3 (en) Hydroprocessing catalyst and process of use
IL181780A0 (en) Hydroprocessing catalyst with zeolite and high mesoporosity
EP1963006A4 (en) Regeneration of acidic catalysts
ZA200905021B (en) Regeneration of platinum-germanium zeolite catalyst
EP1946840A4 (en) Honeycomb structure and honeycomb catalyst
SG115737A1 (en) Alkylated aromatic compositions, zeolite catalyst compositions and processes for making the same
SG10201506253UA (en) Catalyst for catalytic cracking fluidized-bed
EP1967264A4 (en) Denitrification catalyst, honeycomb structure type denitrification catalyst, and method of denitrification with the same
EP1920840A4 (en) Honeycomb structure and honeycomb catalytic structure
MY144130A (en) Zeolite catalyst and method of preparing and use of zeolite catalyst
EP1935489A4 (en) Honeycomb catalyst body and process for producing the same
EP2102315A4 (en) High activity supported distillate hydroprocessing catalysts
EP1867374A4 (en) Honeycomb structure body
EP1725329A4 (en) Selective zeolite catalyst modification
EP1997556A4 (en) Honeycomb catalyst structure
EP1893530A4 (en) Zeolite catalyst and method
ZA200705951B (en) Hydroprocessing catalyst, preparation method thereof and use of same
EP1952884A4 (en) Catalyst for exhaust-gas purification
GB0512377D0 (en) Oligomerisation of olefins with zeolite catalyst
TWI369396B (en) Hydrocracking catalyst cotaining beta and y zeolites, and process for its use to produce naphtha
ZA200707949B (en) Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
SG116601A1 (en) Method of modifying zeolite catalyst.
ZA200803447B (en) Hydrocracking catalyst containing beta and Y zeolites, and process for its use to make jet fuel or distillate
EP1963011A4 (en) Ionic liquid catalyst having enhanced activity
EP1904227A4 (en) Scr catalyst for removal of nitrogen oxides

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07813564

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 2007813564

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2009522998

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

NENP Non-entry into the national phase

Ref country code: RU