WO2008014447A2 - Vascular access device antimicrobial materials and solutions - Google Patents
Vascular access device antimicrobial materials and solutions Download PDFInfo
- Publication number
- WO2008014447A2 WO2008014447A2 PCT/US2007/074576 US2007074576W WO2008014447A2 WO 2008014447 A2 WO2008014447 A2 WO 2008014447A2 US 2007074576 W US2007074576 W US 2007074576W WO 2008014447 A2 WO2008014447 A2 WO 2008014447A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- septum
- low coefficient
- slit
- coating
- Prior art date
Links
- 230000002792 vascular Effects 0.000 title claims abstract description 51
- 239000000463 material Substances 0.000 title claims description 24
- 230000000845 anti-microbial effect Effects 0.000 title abstract description 34
- 238000000576 coating method Methods 0.000 claims abstract description 81
- 239000011248 coating agent Substances 0.000 claims abstract description 51
- 239000004599 antimicrobial Substances 0.000 claims abstract description 50
- 238000000034 method Methods 0.000 claims abstract description 25
- 244000052769 pathogen Species 0.000 claims description 31
- 230000001717 pathogenic effect Effects 0.000 claims description 26
- 239000010687 lubricating oil Substances 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 19
- 229920001296 polysiloxane Polymers 0.000 claims description 18
- 230000002285 radioactive effect Effects 0.000 claims description 6
- 230000000754 repressing effect Effects 0.000 claims description 6
- 238000000151 deposition Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 98
- 239000000243 solution Substances 0.000 description 15
- 239000004447 silicone coating Substances 0.000 description 10
- 239000012530 fluid Substances 0.000 description 9
- 238000001802 infusion Methods 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000003814 drug Substances 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 7
- 238000002560 therapeutic procedure Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229940079593 drug Drugs 0.000 description 5
- 238000001990 intravenous administration Methods 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 4
- 230000036961 partial effect Effects 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 229940126062 Compound A Drugs 0.000 description 3
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 208000015181 infectious disease Diseases 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 208000012503 Bathing suit ichthyosis Diseases 0.000 description 2
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 2
- WJLVQTJZDCGNJN-UHFFFAOYSA-N Chlorhexidine hydrochloride Chemical compound Cl.Cl.C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 WJLVQTJZDCGNJN-UHFFFAOYSA-N 0.000 description 2
- 206010040047 Sepsis Diseases 0.000 description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 210000004204 blood vessel Anatomy 0.000 description 2
- 208000037815 bloodstream infection Diseases 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 229960003500 triclosan Drugs 0.000 description 2
- 206010002091 Anaesthesia Diseases 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 230000036592 analgesia Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000010836 blood and blood product Substances 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- 229940125691 blood product Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229940117927 ethylene oxide Drugs 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 210000005166 vasculature Anatomy 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M39/00—Tubes, tube connectors, tube couplings, valves, access sites or the like, specially adapted for medical use
- A61M39/02—Access sites
- A61M39/04—Access sites having pierceable self-sealing members
- A61M39/045—Access sites having pierceable self-sealing members pre-slit to be pierced by blunt instrument
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B1/00—Instruments for performing medical examinations of the interior of cavities or tubes of the body by visual or photographical inspection, e.g. endoscopes; Illuminating arrangements therefor
- A61B1/00163—Optical arrangements
- A61B1/00188—Optical arrangements with focusing or zooming features
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M39/00—Tubes, tube connectors, tube couplings, valves, access sites or the like, specially adapted for medical use
- A61M39/10—Tube connectors; Tube couplings
- A61M39/16—Tube connectors; Tube couplings having provision for disinfection or sterilisation
- A61M39/162—Tube connectors; Tube couplings having provision for disinfection or sterilisation with antiseptic agent incorporated within the connector
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M39/00—Tubes, tube connectors, tube couplings, valves, access sites or the like, specially adapted for medical use
- A61M39/22—Valves or arrangement of valves
- A61M39/26—Valves closing automatically on disconnecting the line and opening on reconnection thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M39/00—Tubes, tube connectors, tube couplings, valves, access sites or the like, specially adapted for medical use
- A61M2039/0036—Tubes, tube connectors, tube couplings, valves, access sites or the like, specially adapted for medical use characterised by a septum having particular features, e.g. having venting channels or being made from antimicrobial or self-lubricating elastomer
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M39/00—Tubes, tube connectors, tube couplings, valves, access sites or the like, specially adapted for medical use
- A61M39/10—Tube connectors; Tube couplings
- A61M2039/1072—Tube connectors; Tube couplings with a septum present in the connector
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2205/00—General characteristics of the apparatus
- A61M2205/02—General characteristics of the apparatus characterised by a particular materials
- A61M2205/0222—Materials for reducing friction
Definitions
- the present invention has been developed in response to problems and needs in the art that have not yet been fully resolved by currently available vascular access systems, devices, and methods. Thus, these systems, devices, and methods are developed to reduce the risk and occurrence of CRBSIs.
- the high temperature resistant tube may include metal, a polymer, polytetrafluorocthylene, and/or a material with a low coefficient of friction.
- the solution may be a solvent that is cured on the two opposing interior surfaces at about 150° C for about 15 minutes.
Landscapes
- Health & Medical Sciences (AREA)
- Heart & Thoracic Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Anesthesiology (AREA)
- Hematology (AREA)
- Pulmonology (AREA)
- Surgery (AREA)
- Physics & Mathematics (AREA)
- Biophysics (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Optics & Photonics (AREA)
- Pathology (AREA)
- Radiology & Medical Imaging (AREA)
- Epidemiology (AREA)
- Medical Informatics (AREA)
- Molecular Biology (AREA)
- Materials For Medical Uses (AREA)
- Infusion, Injection, And Reservoir Apparatuses (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK07813460.8T DK2046422T3 (en) | 2006-07-28 | 2007-07-27 | Vascular access apparatus for antimicrobial materials and solutions |
EP20070813460 EP2046422B1 (en) | 2006-07-28 | 2007-07-27 | Vascular access device antimicrobial materials and solutions |
JP2009522970A JP2009544454A (en) | 2006-07-28 | 2007-07-27 | Antibacterial materials and fluids for tube access devices |
BRPI0714940A BRPI0714940B8 (en) | 2006-07-28 | 2007-07-27 | vascular access device and method of repressing pathogens in a vascular access device |
CN2007800283352A CN101495166B (en) | 2006-07-28 | 2007-07-27 | Vascular access device antimicrobial materials and solutions |
ES07813460.8T ES2542859T3 (en) | 2006-07-28 | 2007-07-27 | Materials and antimicrobial solutions for vascular access device |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82070606P | 2006-07-28 | 2006-07-28 | |
US60/820,706 | 2006-07-28 | ||
US11/829,010 | 2007-07-26 | ||
US11/829,010 US8512294B2 (en) | 2006-07-28 | 2007-07-26 | Vascular access device antimicrobial materials and solutions |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2008014447A2 true WO2008014447A2 (en) | 2008-01-31 |
WO2008014447A3 WO2008014447A3 (en) | 2008-09-18 |
Family
ID=38982379
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2007/074576 WO2008014447A2 (en) | 2006-07-28 | 2007-07-27 | Vascular access device antimicrobial materials and solutions |
Country Status (8)
Country | Link |
---|---|
US (1) | US8512294B2 (en) |
EP (1) | EP2046422B1 (en) |
JP (2) | JP2009544454A (en) |
CN (1) | CN101495166B (en) |
BR (1) | BRPI0714940B8 (en) |
DK (1) | DK2046422T3 (en) |
ES (1) | ES2542859T3 (en) |
WO (1) | WO2008014447A2 (en) |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010065422A1 (en) * | 2008-12-01 | 2010-06-10 | Becton, Dickinson And Company | Antimicrobial lubricant compositions |
WO2014031774A1 (en) * | 2012-08-22 | 2014-02-27 | Becton, Dickinson And Company | Blood control iv catheter with antimicrobial properties |
WO2014126866A1 (en) * | 2013-02-13 | 2014-08-21 | Becton, Dickinson And Company | Blood control iv catheter with stationary septum activator |
US8821455B2 (en) | 2009-07-09 | 2014-09-02 | Becton, Dickinson And Company | Antimicrobial coating for dermally invasive devices |
WO2014143600A1 (en) * | 2013-03-11 | 2014-09-18 | Becton, Dickinson And Company | Blood control catheter with antimicrobial needle lube |
US9352119B2 (en) | 2012-05-15 | 2016-05-31 | Becton, Dickinson And Company | Blood control IV catheter with antimicrobial properties |
US9675793B2 (en) | 2014-04-23 | 2017-06-13 | Becton, Dickinson And Company | Catheter tubing with extraluminal antimicrobial coating |
US9695323B2 (en) | 2013-02-13 | 2017-07-04 | Becton, Dickinson And Company | UV curable solventless antimicrobial compositions |
US9750927B2 (en) | 2013-03-11 | 2017-09-05 | Becton, Dickinson And Company | Blood control catheter with antimicrobial needle lube |
WO2017157416A1 (en) * | 2016-03-14 | 2017-09-21 | Observe Medical Aps | Biofilm prevention in catheter systems |
US9789279B2 (en) | 2014-04-23 | 2017-10-17 | Becton, Dickinson And Company | Antimicrobial obturator for use with vascular access devices |
US10232088B2 (en) | 2014-07-08 | 2019-03-19 | Becton, Dickinson And Company | Antimicrobial coating forming kink resistant feature on a vascular access device |
US10376686B2 (en) | 2014-04-23 | 2019-08-13 | Becton, Dickinson And Company | Antimicrobial caps for medical connectors |
US10493244B2 (en) | 2015-10-28 | 2019-12-03 | Becton, Dickinson And Company | Extension tubing strain relief |
US10806918B2 (en) | 2011-09-30 | 2020-10-20 | Becton, Dickinson And Company | Syringe with disinfecting tip feature |
US10898412B2 (en) | 2013-05-16 | 2021-01-26 | Becton Dickinson and Company, Ltd. | Mechanical friction enhancement for threaded connection incorporating micro-threads |
WO2021158824A1 (en) * | 2020-02-07 | 2021-08-12 | Carefusion 303, Inc. | Needleless access connector with antimicrobial resistant valve |
WO2021158822A1 (en) * | 2020-02-07 | 2021-08-12 | Carefusion 303, Inc. | Antimicrobial coating extending performance of needleless connector |
US12029835B2 (en) | 2020-02-07 | 2024-07-09 | Carefusion 303, Inc. | Needleless access connector with antimicrobial resistant valve |
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US11229746B2 (en) | 2006-06-22 | 2022-01-25 | Excelsior Medical Corporation | Antiseptic cap |
US9259535B2 (en) | 2006-06-22 | 2016-02-16 | Excelsior Medical Corporation | Antiseptic cap equipped syringe |
JP5493595B2 (en) * | 2008-09-01 | 2014-05-14 | 株式会社ジェイ・エム・エス | Medical port |
US9078992B2 (en) | 2008-10-27 | 2015-07-14 | Pursuit Vascular, Inc. | Medical device for applying antimicrobial to proximal end of catheter |
WO2013009998A2 (en) | 2011-07-12 | 2013-01-17 | Pursuit Vascular, Inc. | Device for delivery of antimicrobial agent into trans-dermal catheter |
US10792398B2 (en) | 2014-02-20 | 2020-10-06 | Becton, Dickinson And Company | Antimicrobial inserts for medical devices |
US10792399B2 (en) | 2014-02-20 | 2020-10-06 | Becton, Dickinson And Company | Antimicrobial inserts for medical devices |
US10668266B2 (en) * | 2014-04-23 | 2020-06-02 | Becton, Dickinson And Company | Ported catheter or female luer fitting with antimicrobial septum |
US10149971B2 (en) | 2014-04-23 | 2018-12-11 | Becton, Dickinson And Company | Antimicrobial stopcock medical connector |
CA2945406C (en) | 2014-05-02 | 2022-10-18 | Excelsior Medical Corporation | Strip package for antiseptic cap |
US20150337975A1 (en) * | 2014-05-23 | 2015-11-26 | Charles Allen | Inflation valve cap apparatus and method |
US20160008569A1 (en) * | 2014-07-08 | 2016-01-14 | Becton, Dickinson And Company | Antimicrobial actuator for opening the side port of a ported catheter |
US10436336B2 (en) * | 2014-11-13 | 2019-10-08 | Charles Allen | Cap with valve for inflation |
US10004890B2 (en) | 2015-01-27 | 2018-06-26 | Becton, Dickinson And Company | Antimicrobial inserts for stopcock medical connectors |
WO2016122894A1 (en) | 2015-01-27 | 2016-08-04 | Becton, Dickinson And Company | Antimicrobial inserts for medical devices |
CA2982456A1 (en) | 2015-05-08 | 2016-11-17 | Icu Medical, Inc. | Medical connectors configured to receive emitters of therapeutic agents |
WO2017156240A1 (en) * | 2016-03-10 | 2017-09-14 | Np Medical Inc. | Unitary medical connector with a rigid and a resilient portion |
US10157598B2 (en) | 2016-05-19 | 2018-12-18 | Leto R&D Corporation | Mouthpiece cap for a musical instrument |
ES2929769T3 (en) | 2016-10-14 | 2022-12-01 | Icu Medical Inc | Disinfectant caps for medical connectors |
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WO2018204206A2 (en) | 2017-05-01 | 2018-11-08 | Icu Medical, Inc. | Medical fluid connectors and methods for providing additives in medical fluid lines |
US10543354B2 (en) | 2017-09-27 | 2020-01-28 | Becton, Dickinson And Company | Peripheral intravenous catheters having flow diverting features |
US11517732B2 (en) | 2018-11-07 | 2022-12-06 | Icu Medical, Inc. | Syringe with antimicrobial properties |
US11541221B2 (en) | 2018-11-07 | 2023-01-03 | Icu Medical, Inc. | Tubing set with antimicrobial properties |
US11541220B2 (en) | 2018-11-07 | 2023-01-03 | Icu Medical, Inc. | Needleless connector with antimicrobial properties |
US11534595B2 (en) | 2018-11-07 | 2022-12-27 | Icu Medical, Inc. | Device for delivering an antimicrobial composition into an infusion device |
US11400195B2 (en) | 2018-11-07 | 2022-08-02 | Icu Medical, Inc. | Peritoneal dialysis transfer set with antimicrobial properties |
CA3118905A1 (en) | 2018-11-21 | 2020-05-28 | Icu Medical, Inc. | Antimicrobial device comprising a cap with ring and insert |
JP7363054B2 (en) * | 2019-02-28 | 2023-10-18 | 日本ゼオン株式会社 | Covered stents and stent delivery systems |
CA3158095A1 (en) * | 2019-11-11 | 2021-05-20 | John Grant | Single use caps and covers for vascular access devices, and kits and methods for using the same |
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Also Published As
Publication number | Publication date |
---|---|
US20080161763A1 (en) | 2008-07-03 |
DK2046422T3 (en) | 2015-07-27 |
CN101495166A (en) | 2009-07-29 |
EP2046422B1 (en) | 2015-04-22 |
BRPI0714940A2 (en) | 2013-05-21 |
JP2009544454A (en) | 2009-12-17 |
ES2542859T3 (en) | 2015-08-12 |
BRPI0714940B1 (en) | 2020-08-18 |
JP2012254319A (en) | 2012-12-27 |
EP2046422A4 (en) | 2012-10-03 |
EP2046422A2 (en) | 2009-04-15 |
BRPI0714940B8 (en) | 2021-06-22 |
US8512294B2 (en) | 2013-08-20 |
JP5575853B2 (en) | 2014-08-20 |
WO2008014447A3 (en) | 2008-09-18 |
CN101495166B (en) | 2012-03-21 |
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