WO2008013790A3 - Conversion of carbonaceous materials to synthetic natural gas by reforming and methanation - Google Patents

Conversion of carbonaceous materials to synthetic natural gas by reforming and methanation Download PDF

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Publication number
WO2008013790A3
WO2008013790A3 PCT/US2007/016608 US2007016608W WO2008013790A3 WO 2008013790 A3 WO2008013790 A3 WO 2008013790A3 US 2007016608 W US2007016608 W US 2007016608W WO 2008013790 A3 WO2008013790 A3 WO 2008013790A3
Authority
WO
WIPO (PCT)
Prior art keywords
natural gas
synthetic natural
methanation
reforming
conversion
Prior art date
Application number
PCT/US2007/016608
Other languages
French (fr)
Other versions
WO2008013790A2 (en
Inventor
Stanley R Pearson
Original Assignee
Clean Energy L L C
Stanley R Pearson
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clean Energy L L C, Stanley R Pearson filed Critical Clean Energy L L C
Publication of WO2008013790A2 publication Critical patent/WO2008013790A2/en
Publication of WO2008013790A3 publication Critical patent/WO2008013790A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08Production of synthetic natural gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • C10J3/22Arrangements or dispositions of valves or flues
    • C10J3/24Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
    • C10J3/26Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed downwardly
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/002Removal of contaminants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/002Removal of contaminants
    • C10K1/003Removal of contaminants of acid contaminants, e.g. acid gas removal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/02Dust removal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0916Biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0916Biomass
    • C10J2300/092Wood, cellulose
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1662Conversion of synthesis gas to chemicals to methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Industrial Gases (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

A process for the production of synthetic natural gas from a carbonaceous material, preferably a biomass material, such as wood. The carbonaceous material is steam reformed to produce a syngas, which is then feed to a methanation zone to produce synthetic natural gas.
PCT/US2007/016608 2006-07-24 2007-07-24 Conversion of carbonaceous materials to synthetic natural gas by reforming and methanation WO2008013790A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US83280506P 2006-07-24 2006-07-24
US60/832,805 2006-07-24

Publications (2)

Publication Number Publication Date
WO2008013790A2 WO2008013790A2 (en) 2008-01-31
WO2008013790A3 true WO2008013790A3 (en) 2008-03-20

Family

ID=38982015

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/016608 WO2008013790A2 (en) 2006-07-24 2007-07-24 Conversion of carbonaceous materials to synthetic natural gas by reforming and methanation

Country Status (2)

Country Link
US (1) US20080016756A1 (en)
WO (1) WO2008013790A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080154144A1 (en) * 2006-08-08 2008-06-26 Kamil Unver Systems and methods for cardiac contractility analysis
US20090221725A1 (en) * 2008-02-28 2009-09-03 Enerkem, Inc. Production of ethanol from methanol
US20090293786A1 (en) * 2008-05-27 2009-12-03 Olver John W Biomass Combustion Chamber and Refractory Components
US8989837B2 (en) * 2009-12-01 2015-03-24 Kyma Medical Technologies Ltd. Methods and systems for determining fluid content of tissue
US7955403B2 (en) * 2008-07-16 2011-06-07 Kellogg Brown & Root Llc Systems and methods for producing substitute natural gas
US9012523B2 (en) 2011-12-22 2015-04-21 Kellogg Brown & Root Llc Methanation of a syngas
US20110308157A1 (en) * 2008-12-24 2011-12-22 Jian Chao Zhang Biomass gasification device and process
EP2261308B1 (en) 2009-05-07 2013-06-19 Haldor Topsøe A/S Process for the production of natural gas
CN101993748B (en) * 2010-11-05 2013-02-06 四川亚连科技有限责任公司 Method for preparing and synthesizing natural gas by utilizing straw gas
US20150052812A1 (en) * 2013-08-20 2015-02-26 Philip James Scalzo Oxygen-Deficient Thermally Produced Processed Biogas from Beneficiated Organic-Carbon-Containing Feedstock
CN106701132A (en) * 2015-08-28 2017-05-24 李宽义 Brown coal upgrading method through high-efficient and clean refined comprehensive utilization of coal-based energy

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3993457A (en) * 1973-07-30 1976-11-23 Exxon Research And Engineering Company Concurrent production of methanol and synthetic natural gas
US5079267A (en) * 1989-09-16 1992-01-07 Xytel Technologies Partnership Methanol production

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3963426A (en) * 1974-07-22 1976-06-15 Cameron Engineers, Incorporated Process for gasifying carbonaceous matter
US4124628A (en) * 1977-07-28 1978-11-07 Union Carbide Corporation Serial adiabatic methanation and steam reforming
US4292048A (en) * 1979-12-21 1981-09-29 Exxon Research & Engineering Co. Integrated catalytic coal devolatilization and steam gasification process
US20070256360A1 (en) * 2006-05-08 2007-11-08 Alchemix Corporation Method for the gasification of moisture-containing hydrocarbon feedstocks

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3993457A (en) * 1973-07-30 1976-11-23 Exxon Research And Engineering Company Concurrent production of methanol and synthetic natural gas
US5079267A (en) * 1989-09-16 1992-01-07 Xytel Technologies Partnership Methanol production

Also Published As

Publication number Publication date
US20080016756A1 (en) 2008-01-24
WO2008013790A2 (en) 2008-01-31

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