WO2008002423A3 - Reduction of fouling in heat exchangers - Google Patents

Reduction of fouling in heat exchangers Download PDF

Info

Publication number
WO2008002423A3
WO2008002423A3 PCT/US2007/014335 US2007014335W WO2008002423A3 WO 2008002423 A3 WO2008002423 A3 WO 2008002423A3 US 2007014335 W US2007014335 W US 2007014335W WO 2008002423 A3 WO2008002423 A3 WO 2008002423A3
Authority
WO
WIPO (PCT)
Prior art keywords
fouling
reduction
tubes
exchanger
liquid
Prior art date
Application number
PCT/US2007/014335
Other languages
French (fr)
Other versions
WO2008002423A2 (en
WO2008002423A8 (en
Inventor
Leroy A Clavenna
Ian A Cody
Ashley E Cooper
Steve Colgrove
Hugh L Huffman
Julio D Lobo
Limin Song
H Alan Wolf
Glen B Brons
George A Lutz
Mohsen S Yeganeh
Original Assignee
Exxonmobil Res & Eng Co
Leroy A Clavenna
Ian A Cody
Ashley E Cooper
Steve Colgrove
Hugh L Huffman
Julio D Lobo
Limin Song
H Alan Wolf
Glen B Brons
George A Lutz
Mohsen S Yeganeh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co, Leroy A Clavenna, Ian A Cody, Ashley E Cooper, Steve Colgrove, Hugh L Huffman, Julio D Lobo, Limin Song, H Alan Wolf, Glen B Brons, George A Lutz, Mohsen S Yeganeh filed Critical Exxonmobil Res & Eng Co
Priority to JP2009516552A priority Critical patent/JP2009541702A/en
Priority to EP07796271A priority patent/EP2038599A2/en
Priority to AU2007265589A priority patent/AU2007265589A1/en
Priority to CA002655295A priority patent/CA2655295A1/en
Publication of WO2008002423A2 publication Critical patent/WO2008002423A2/en
Publication of WO2008002423A3 publication Critical patent/WO2008002423A3/en
Publication of WO2008002423A8 publication Critical patent/WO2008002423A8/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28GCLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
    • F28G7/00Cleaning by vibration or pressure waves
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • F28F19/02Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/02Apparatus characterised by being constructed of material selected for its chemically-resistant properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1812Tubular reactors
    • B01J19/1825Tubular reactors in parallel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/185Stationary reactors having moving elements inside of the pulsating type
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G75/00Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094Jackets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00245Avoiding undesirable reactions or side-effects
    • B01J2219/00247Fouling of the reactor or the process equipment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02Apparatus characterised by their chemically-resistant properties
    • B01J2219/0204Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
    • B01J2219/0231Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components of diamond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02Apparatus characterised by their chemically-resistant properties
    • B01J2219/0204Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
    • B01J2219/0245Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components of synthetic organic material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/0059Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for petrochemical plants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2245/00Coatings; Surface treatments
    • F28F2245/04Coatings; Surface treatments hydrophobic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

A method for reducing the formation of deposits on the inner walls of a tubular heat exchanger through which a petroleum-based liquid is flowing comprises applying one of fluid pressure pulsations to the liquid flowing through the tubes of the exchanger and vibration to the heat exchanger to effect a reduction of the viscous boundary layer adjacent the inner walls of the tubular heat exchange surfaces. Reduction of the viscous boundary layer at the tube walls not only reduces the incidence of fouling with its consequential beneficial effect on equipment life but it also has the desirable effect of promoting heat transfer from the tube wall to the liquid in the tubes. Fouling and corrosion are further reduced by the use of a coating on the inner wall surfaces of the exchanger tubes.
PCT/US2007/014335 2006-06-23 2007-06-19 Reduction of fouling in heat exchangers WO2008002423A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2009516552A JP2009541702A (en) 2006-06-23 2007-06-19 Method for reducing dirt in heat exchangers
EP07796271A EP2038599A2 (en) 2006-06-23 2007-06-19 Reduction of fouling in heat exchangers
AU2007265589A AU2007265589A1 (en) 2006-06-23 2007-06-19 Reduction of fouling in heat exchangers
CA002655295A CA2655295A1 (en) 2006-06-23 2007-06-19 Reduction of fouling in heat exchangers

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US81584506P 2006-06-23 2006-06-23
US60/815,845 2006-06-23
US11/802,617 US20080073063A1 (en) 2006-06-23 2007-05-24 Reduction of fouling in heat exchangers
US11/802,617 2007-05-24

Publications (3)

Publication Number Publication Date
WO2008002423A2 WO2008002423A2 (en) 2008-01-03
WO2008002423A3 true WO2008002423A3 (en) 2008-03-06
WO2008002423A8 WO2008002423A8 (en) 2008-05-02

Family

ID=38805675

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/014335 WO2008002423A2 (en) 2006-06-23 2007-06-19 Reduction of fouling in heat exchangers

Country Status (7)

Country Link
US (1) US20080073063A1 (en)
EP (1) EP2038599A2 (en)
JP (1) JP2009541702A (en)
KR (1) KR20090025350A (en)
AU (1) AU2007265589A1 (en)
CA (1) CA2655295A1 (en)
WO (1) WO2008002423A2 (en)

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US8663455B2 (en) * 2008-12-11 2014-03-04 Exxonmobil Research And Engineering Company Addition of high molecular weight naphthenic tetra-acids to crude oils to reduce whole crude oil fouling
WO2010107881A1 (en) * 2009-03-17 2010-09-23 Dow Global Technologies, Inc. Tube-side sequentially pulsable-flow shell-and-tube heat exchanger apparatus, system, and method
JP5417068B2 (en) * 2009-07-14 2014-02-12 株式会社日立製作所 Oxyfuel boiler and control method for oxygen fired boiler
EP2485832B1 (en) * 2009-10-09 2016-11-23 Blue Cube IP LLC Process for producing a chlorinated and/or fluorinated propene in an isothermal multitube reactors and
US8581012B2 (en) 2009-10-09 2013-11-12 Dow Global Technologies, Llc Processes for the production of chlorinated and/or fluorinated propenes and higher alkenes
US8092618B2 (en) * 2009-10-21 2012-01-10 Nalco Company Surface passivation technique for reduction of fouling
BRPI1000208A2 (en) * 2010-01-29 2011-01-04 Sppt Pesquisas Tecnologicas Ltda low temperature conversion vibrant heat exchanger equipment for organic waste treatment and organic waste treatment process by employing low temperature conversion vibrant heat exchanger equipment
US8513367B2 (en) 2010-11-19 2013-08-20 Exxonmobil Research And Engineering Company Mitigation of elastomer reactor fouling using mechanical vibration
EP2696160B1 (en) * 2011-04-01 2019-03-27 Mitsubishi Electric Corporation Hot water supply device and flow volumen control method
US20140323783A1 (en) 2011-05-20 2014-10-30 Exxonmobil Chemical Patents Inc. Coke Gasification on Catalytically Active Surfaces
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EP1798511A1 (en) * 2005-12-14 2007-06-20 Behr GmbH & Co. KG Device for cooling a gas flow

Also Published As

Publication number Publication date
AU2007265589A1 (en) 2008-01-03
KR20090025350A (en) 2009-03-10
WO2008002423A2 (en) 2008-01-03
EP2038599A2 (en) 2009-03-25
CA2655295A1 (en) 2008-01-03
US20080073063A1 (en) 2008-03-27
WO2008002423A8 (en) 2008-05-02
JP2009541702A (en) 2009-11-26

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