WO2008002323A3 - Production de grains d'oxyde métallique contenant du cérium - Google Patents
Production de grains d'oxyde métallique contenant du cérium Download PDFInfo
- Publication number
- WO2008002323A3 WO2008002323A3 PCT/US2006/048143 US2006048143W WO2008002323A3 WO 2008002323 A3 WO2008002323 A3 WO 2008002323A3 US 2006048143 W US2006048143 W US 2006048143W WO 2008002323 A3 WO2008002323 A3 WO 2008002323A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- metal oxide
- cerium
- oxide particles
- production
- containing metal
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/224—Oxides or hydroxides of lanthanides
- C01F17/235—Cerium oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/241—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion containing two or more rare earth metals, e.g. NdPrO3 or LaNdPrO3
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/60—Compounds characterised by their crystallite size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
- C01P2004/52—Particles with a specific particle size distribution highly monodisperse size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
L'invention concerne un procédé de précipitation en milieu aqueux destiné à la préparation de particules d'oxyde métallique, ledit procédé comprenant l'introduction d'une solution de sel de nitrate de cérium 3+ et d'une base, sous agitation turbulente, dans un réacteur de précipitation, les ions cérium 3+ étant oxydés en cérium 4+ et les particules d'oxyde métallique précipitées étant obtenues directement, sans nécessiter d'étape de calcination. Selon l'invention, l'amélioration comprend l'ajout d'acide acétique à la précipitation en une quantité de 1 à 40 pourcent molaire, par rapport à la quantité molaire de cérium, et l'obtention de particules d'oxyde métallique dispersées, pratiquement pas agglomérées, de taille nanométrique.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US31810205A | 2005-12-23 | 2005-12-23 | |
US11/318,102 | 2005-12-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2008002323A2 WO2008002323A2 (fr) | 2008-01-03 |
WO2008002323A3 true WO2008002323A3 (fr) | 2008-04-17 |
Family
ID=38846140
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2006/048143 WO2008002323A2 (fr) | 2005-12-23 | 2006-12-18 | Production de grains d'oxyde métallique contenant du cérium |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2008002323A2 (fr) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8883865B2 (en) | 2006-09-05 | 2014-11-11 | Cerion Technology, Inc. | Cerium-containing nanoparticles |
EP2066767B1 (fr) | 2006-09-05 | 2015-10-21 | Cerion LLC | Additif pour carburant contenant des nanoparticules de dioxyde de cérium |
US10435639B2 (en) | 2006-09-05 | 2019-10-08 | Cerion, Llc | Fuel additive containing lattice engineered cerium dioxide nanoparticles |
US8679344B2 (en) | 2008-12-17 | 2014-03-25 | Cerion Technology, Inc. | Process for solvent shifting a nanoparticle dispersion |
WO2013158744A2 (fr) | 2012-04-17 | 2013-10-24 | Cerion Enterprises, Llc | Nanoparticules de cérium et acides aminés |
WO2013187980A1 (fr) | 2012-06-13 | 2013-12-19 | Cerion Enterprises Llc | Nanoparticules d'oxyde de cérium pour le traitement du stress oxydatif |
US9446070B2 (en) | 2012-06-13 | 2016-09-20 | Cerion, Llc | Nanoceria with citric acid additive |
US9623110B2 (en) | 2013-08-09 | 2017-04-18 | Cerion, Llc | Nanoparticles of a metal and a nucleobase |
US10143661B2 (en) | 2013-10-17 | 2018-12-04 | Cerion, Llc | Malic acid stabilized nanoceria particles |
CN109133140A (zh) * | 2018-08-27 | 2019-01-04 | 江西师范大学 | 一种制备二氧化铈纳米颗粒的方法 |
CN114653356B (zh) * | 2022-02-07 | 2023-10-24 | 江汉大学 | 镧掺杂二氧化铈催化剂材料的制备方法和去甲醛复合物 |
CN115448354B (zh) * | 2022-09-16 | 2023-10-31 | 包头稀土研究院 | 二氧化铈颗粒及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4859432A (en) * | 1986-12-19 | 1989-08-22 | Rhone-Poulenc Chimie | Novel ceric oxide particulates and process of making |
US5308548A (en) * | 1985-06-20 | 1994-05-03 | Rhone-Poulenc Specialities Chimiques | Preparing a dispersible, sol-forming cerium (IV) composition |
US6133194A (en) * | 1997-04-21 | 2000-10-17 | Rhodia Rare Earths Inc. | Cerium oxides, zirconium oxides, Ce/Zr mixed oxides and Ce/Zr solid solutions having improved thermal stability and oxygen storage capacity |
US20030215378A1 (en) * | 2002-05-15 | 2003-11-20 | Xiao-Dong Zhou | Method for preparation of nanometer cerium-based oxide particles |
-
2006
- 2006-12-18 WO PCT/US2006/048143 patent/WO2008002323A2/fr active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5308548A (en) * | 1985-06-20 | 1994-05-03 | Rhone-Poulenc Specialities Chimiques | Preparing a dispersible, sol-forming cerium (IV) composition |
US4859432A (en) * | 1986-12-19 | 1989-08-22 | Rhone-Poulenc Chimie | Novel ceric oxide particulates and process of making |
US6133194A (en) * | 1997-04-21 | 2000-10-17 | Rhodia Rare Earths Inc. | Cerium oxides, zirconium oxides, Ce/Zr mixed oxides and Ce/Zr solid solutions having improved thermal stability and oxygen storage capacity |
US20030215378A1 (en) * | 2002-05-15 | 2003-11-20 | Xiao-Dong Zhou | Method for preparation of nanometer cerium-based oxide particles |
Non-Patent Citations (1)
Title |
---|
M. INOUE ET. AL.: "Transparent colloidal solution of 2 nm ceria particles", CHEMICAL COMMUNICATION, 1999, RSC Publishing, pages 957 - 958, XP002468390 * |
Also Published As
Publication number | Publication date |
---|---|
WO2008002323A2 (fr) | 2008-01-03 |
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