WO2007145732A2

WO2007145732A2 - Injection molding process for molding mechanical interlocks between molded components

Info

Publication number: WO2007145732A2
Application number: PCT/US2007/010833
Authority: WO
Inventors: Jean-Pierre Giraud; Michel Zbirka
Original assignee: Csp Technologies, Inc.
Priority date: 2006-05-04
Filing date: 2007-05-04
Publication date: 2007-12-21
Also published as: EP2089206A4; EP2089206B1; US8420197B2; WO2007145732A3; CA2636373C; CN101479090A; CA2636373A1; CN101479090B; JP2009535247A; EP2089206A2; US20090081407A1; US20120009410A1

Abstract

A two-shot or multi-shot multi-material injection molding process is provided. The process allows dissimilar materials to be injection molded to form a single, injection molded part by creating a structural interlock between the materials to prevent the materials from separating. The structural interlock is formed by forming at least one interlock cavity adjacent to a interfacial surface of a first portion of a molded part molded from a first material, and injecting a second, different material into the mold so that the second material flows into the interlock cavity and fills it. Solidification of the second material in the interlock cavity formed by the first material creates the structural interlock between the two materials.

Description

INJECTION MOLDING PROCESS FOR MOLDING MECHANICAL INTERLOCKS BETWEEN MOLDED COMPONENTS

RELATED APPLICATIONS

[0001] This patent application makes reference to, claims priority to and claims benefit from United States Provisional Patent Application Serial No. 60/746,438 filed on May 4, 2006.

FIELD OF THE INVENTION

[0002] The present technology relates to a method of molding different materials to form an individual injection molded part. More particularly, the present technology relates to an injection molding method that creates a structural interlock between two different materials that allows the two different materials to be used to form a single, injection molded part.

BACKGROUND OF THE INVENTION

[0003] Consumer are demanding smaller bulk packages that incorporate greater functionality (i.e., one-by-one product presentation and resealability). These bulk packages, especially bulk packages that must also have other functional requirements, such as moisture-resistance and resealability, is particularly challenging to produce because the functional requirements often necessitate the use of multiple parts and materials. However, the use of fasteners to join components together adds to the component count and, most importantly, takes up valuable space.

[0004] Two-shot or multi-shot injection molding allows different materials having different functional properties to be molded into a single part without the need to use fasteners to join the materials together. The two materials are typically joined to each other by means of a weld defined by the interface solidification of melted portions of the two materials. In order to form such a weld, however, the different materials must be chemically similar or compatible. This limits the selection of materials that can be used to fabricate the molded part.

[0005] There is still a need for an injection molding method that enables mechanical interlocking to occur between dissimilar materials, thereby maximizing the functionality of the component part without regard to chemical similarity or compatibility of the materials, and without the need to employ separate fasteners or utilize adhesives.

SUMMARY OF THE INVENTION

[0006] One aspect of the present technology is directed to a method of molding that creates a structural interlock between two different materials.

[0007] Another aspect of the present technology is directed to an injection molding process that employs design characteristics that enable mechanical interlocking to occur between dissimilar materials without the use of fasteners or adhesives.

[0008] A further aspect of the present technology is a two-shot or multi- shot injection molding process wherein a first material is injected into a mold cavity to form a first portion of a molded part. The first portion includes an interfacial surface and at least one interlock cavity formed adjacent to the interfacial surface. A second material is injected into the mold cavity so that the second material contacts the interfacial surface and flows into the at least one interlock cavity. Solidification of the second material in the at least one interlock cavity formed in the first portion of the molded part creates a mechanical interlock between the first and second materials which prevents the two materials from being separated, and results in an injection molded part formed from dissimilar materials without the need for fasteners or adhesives.

[0009] In one embodiment of the molding process described herein a passive interlock is created wherein the at least one interlock cavity has an opening at the interfacial surface to allow the second material to flow into the interlock cavity.

[0010] In another embodiment of the molding process described herein, an active interlock is created wherein the at least one interlock cavity is blocked by a thin wall formed from the first material, and fill pressure from the second material breaches the wall, thereby allowing the second material to flow into the at least one interlock cavity.

[0011] Formation of the mechanical interlock advantageously allows dissimilar materials to be used in forming an injection molded part thereby allowing the selection of materials based upon the functional properties or characteristics needed without regard to chemical similarity. However, the mechanical interlock may be used to join similar materials where material adhesion does not provide enough strength. For example, similar materials may include polypropylene as the first material and a polypropylene impregnated with an electrically conductive compound (e.g., carbon black) as the second material.

[0012] Other advantages and features of the present invention will become apparent from the following detailed description of the invention, from the claims, and from the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

[0013] Figure A1 is a perspective view of a two-shot injection molded part made by one embodiment of the process of the present technology.

[0014] Figure A3 is a detailed view of the mechanical interlock between the two materials forming the injection molded part shown in Figure A1.

[0015] Figure A4 is a cutaway view of the first material forming a portion of the injection molded part and the interlock cavities for receiving the second material; the molding cavity is shown in section.

[0016] Figure A5 is a cutaway view of the second material filling a second mold and flowing into the interlock cavities formed by the first material. [0017] Figure A6 is a detailed view of a partially filled interlock cavity shown in Figure A5.

[0018] Figure A7 is a cutaway sectional view of the mold cavity for molding the first material.

[0019] Figure B1 is a perspective view of a second embodiment of a two- shot injection molded part made in accordance with the present technology.

[0020] Figure B2 is a cross-sectional view of the injection mold for the embodiment shown in Figure B1 , but showing the portion of the injection molded part and the interlock cavities formed by the first material.

[0021] Figure B3 is a cross-sectional view of the injection mold, illustrating the second material flowing into the interlock cavities formed by the first material.

[0022] Figure B4 is a detailed view of a partially filled interlock cavity shown in Figure B3.

[0023] Figure B5 is a cross-sectional view of the injection molded part shown Figure B1, illustrating the interlock cavities completely filled by the second material.

[0024] Figure B6 is a detailed view of a filled interlock cavity shown in

Figure B5.

[0025] Figure C1 is a perspective view of another embodiment of a two- shot injection molded part made in accordance with the present technology.

[0026] Figure C3 is a cross-sectional view taken along lines C5 in Figure

C1, illustrating the second material flowing into the interlock cavities formed by the first material.

[0027] Figure C4 is a detailed view of a partially filled interlock cavity show in Figure C3.

[0028] Figure C5 is a cross-sectional view taken along lines C5 in Figure

C1, illustrating the interlock cavities completely filled by the second material. [0029] Figure C6 is a detailed view of a filled interlock cavity shown in

Figure C5.

[0030] Figure D1 is a perspective view of a two-shot injection molded part made by an alternative embodiment of the process of the present technology.

[0031] Figure D3 is a detailed view of the mechanical interlock between the two materials forming the injection molded part shown in Figure D1.

[0032] Figure D4 is a cutaway view of the first material forming a portion of the injection molded part shown in Figure D1 and the interlock cavities for receiving the second material, with the interlock cavities closed by walls formed from the first material; the mold cavity is shown in section.

[0033] Figure D5 is a cutaway view of the second material breaking the walls formed by the first material and flowing into the interlock cavities formed by the first material.

[0034] Figure D6 is a detailed view of a partially filled interlock cavity shown in Figure D5.

[0035] Figure E1 is a top plan view of another embodiment of an injection molded part made by the process of the present technology.

[0036] Figure E2 is a side view of the injection molded part of Figure E1.

DETAILED DESCRIPTION OF THE INVENTION

[0037] The present technology describes methods for molding a molded part formed from at least two materials that exhibit different chemical and/or physical properties. One of the materials is molded to form a first portion of the molded part which includes an interfacial surface and at least one interlock cavity adjacent to the interfacial surface. The other material is molded to form the remainder of the molded part and flows into the interlock cavity created in the first portion of the molded part. When the second material solidifies within the interlock cavity, it creates a mechanical interlock at the interfacial surface that prevents the two materials from being separated. The mechanical interlock is not dependent on adhesion between the materials.

[0038] In one embodiment of the present technology, a passive interlock is created at the interfacial surface by forming the interlock cavity so as to have an opening at the interfacial surface that allows the second material to flow into the interlock cavity. In another embodiment of the present technology, an active interlock is created at the interfacial surface by forming the interlock cavity so that a thin wall of first material separates the interlock cavity from the mold section receiving the second material. Fill pressure from the second material shot is used to breach the thin wall, thereby allowing the second material to flow into the interlock cavity. Each type of interlock can be created in different ways to form both butt joints and lap joints between dissimilar materials.

[0039] The formation of the interlock cavities in the first portion of the molded part followed by the molding and solidification of the second material within the interlock cavities has several advantages. No molding undercut is formed in forming the interlock cavities. In molding processes, the molding of undercuts often is considered undesirable because undercuts make the molded part more difficult to extract from the mold. Typically, the part must be molded from a flexible material in order to facilitate extraction of the part from the mold, which limits the choice of materials for the part, or the mold is complicated to design and manufacture, thereby increasing the cost of production of the part. In the present process, however, the interlock cavities are formed by pins that can easily be removed from the mold cavity, thereby simplifying the mold design.

[0040] Although the molding method described herein is particularly suitable for two-shot or multi-shot injection molding processes, the method can also be used in overmold processes. Using an overmolding process, a previously molded part is inserted into a mold and a second material is overmolded about the molded part. The use of mechanical interlocks, especially with materials that do not adhere together, are useful in joining the overmolded component to the previously molded part. [0041] The materials that can be used to form the injection molded part can be virtually any polymeric material that is capable of being injection molded. If the injection molded part is to be used in a package or container the polymer materials must also be compatible with the product to be stored in the container. Suitable polymeric materials include polyethylene (PE - high density, low density, LLD, VLLD), polypropylene (PP), polyvinyl chloride (PVC), high impact polystyrene (HIPS), cyclic olefin co-polymer (CoC) polyethylene vinyl acetate (EVA), polystyrene (PS), polycarbonate (PC), polyester terephthalate (PET), , polyamide (nylon), acetal copolymer or homopolymer resin, and liquid crystal polymer.

[0042] As used herein, "dissimilar" means materials with different physical and/or chemical properties. Dissimilar materials may be of a different grade of a thermoplastic resin where each grade has specific physical or chemical properties. For example, a co-polymer (e.g., ethylene vinyl acetate co-polymer) may have different properties based on the ratio (and arrangement) of the copolymer components.

[0043] In one embodiment, one of the selected materials for forming a portion of the injection molded part can be an active polymer composition that absorbs or releases a gas. For example, the active polymer composition may incorporate a desiccant. Suitable desiccants include, but are not limited to, silica gel, molecular sieve, calcium carbonate and naturally occurring clay compounds, including, but not limited to montmorillonite clay.

[0044] Alternatively, the desiccant composition includes one or more of the following desiccant plastic compositions comprising formulations that are used to mold shaped articles comprising 2-phase and 3-phase compositions. A 2-phase composition is one that comprises a desiccant and a polymer. A 3-phase composition is one that comprises a desiccant and at least 2 immiscible polymers. [0045] The polymer is preferably selected from a group of thermoplastics that include polyolefins (for example: polyethylene (LDPE₁ LLDPE, HDPE and polypropylene) may be used. Suitable 3-phase desiccant entrained plastic compositions include, but are not limited to, the desiccant plastics disclosed in one or more of the following U.S. Patent Nos.: 5,911,937, 6,214,255, 6,130,263, 6,080,350 and 6,174,952, 6,124,006, and 6,221,446. These references are incorporated herein by reference.

[0046] Particular combinations of dissimilar polymers that are envisaged for use in the present two-shot injection molding process include, but are not limited to, a nylon and a liquid crystal polymer material, a polystyrene and an acetal copolymer or homopolymer resin, and a desiccant entrained plastic and an acetal resin. For example, a part that needs to have anti-static properties in one area and high temperature resistance in another area could be molded from a nylon material for its anti-static properties and a liquid crystal polymer for its heat resistance properties. As another example, a part that needs to have moisture resistance in one area and provide a bearing surface in another area could be molded from a desiccant entrained plastic for the portion that must have moisture resistance and from an acetal resin to form the bearing surface. In a further example the exposed portion of the part can be composed of polycarbonate and the interior portion of the part could be composed of desiccant plastic. The polycarbonate protects the desiccant plastic portion of the part from abrasion and/or dusting. Other material combinations will occur to one of skill in the art.

[0047] Various embodiments of the molding method of the present invention will now be discussed with reference to the drawings. It is to be understood that the invention is not intended to be limited to the embodiments described herein, and the scope of the invention will be pointed out in the appended claims.

[0048] A two-shot injection molded part 10 made according to one embodiment of the method of the present invention is illustrated in Figures A1- A7. The injection molded part 10 is formed by injecting a first material, which can be, for example, a nylon, into a mold cavity 12 to form a first portion 20 of the injection molded part. The mold cavity 12 includes a plurality of pins 16 placed adjacent to one wall of the mold cavity 12, and intersecting what will become the interface between the first and second materials. When the first material is injected into the mold cavity 12, it flows partially around the pins, resulting in a plurality of interlock cavities 24 in the first portion that each have an opening 26 at the interfacial surface 28 of the molded first portion. Although a plurality of interlock cavities are illustrated in the first portion 20, it will be appreciated that the number of interlock cavities could be one, two, or more cavities depending upon the size of the part, the size of the cavity, and the materials selected to form the part.

[0049] It is important that the opening 26 to each interlock cavity has a size that is less than the diameter of the interlock cavity, alternatively less than half the diameter of the interlock cavity so that the opening is restricted or narrow. This restricted opening is wide enough to allow the second material to flow into the interlock cavity, but narrow enough to act as a mechanical anchor that prevents the second material from being pulled apart from the first material after solidification, as explained further below.

[0050] After molding the first material to form the first portion of the injection molded part, the mold is opened and rotated to a second mold cavity 14, the mold is closed, and a second material, which can be, for example, a liquid crystal polymer material, is injected into the mofd cavity 14. The second material contacts the interfacial surface 28 of the molded first portion and flows into the interlock cavities 24 formed in the first portion 20, as shown in Figures A5 and A6, forming a second portion 22 of the molded part. A mechanical interlock 29 is then created between the first and second materials by the cooling and solidification of the second material in the interlock cavities formed in the first material, as shown in Figures A1 and A3.

[0051] A two-shot injection molded part made according to another embodiment of the injection molding process of the present invention is illustrated in Figures B1-B6. The B1-B6 embodiment would be suitable for a part that needs to have moisture resistance in one area and provide a bearing surface in another area. The injection molded part 30 has a first portion 32, that is molded from a first material and that overlaps a second portion 34. The second portion 34 is molded from a second material that differs from the first material in at least one property. The injection molded part 30 is formed by injection molding the first material in a mold cavity to form the first portion 32 of the injection molded part. The mold cavity is provided with a plurality of generally frustaconically-shaped pins that project downwardly from the top of the mold cavity (as oriented in Figure B2). The frustaconically-shaped pins have their base end at the top of the mold cavity, while the smaller diameter end intersects what will become the interface between the first and second materials.

[0052] When the first material is injected into the mold cavity, it flows around the pins, resulting, upon solidification, in a plurality of interlock cavities 36 that extend completely through the molded first portion. Because of the shape of the pins, the resulting interlock cavities 36 have an opening 38 at the interfacial surface 35 of the molded first portion that is smaller than the opening 39 at the opposite end of the interlock cavity, as shown in Figure B2.

[0053] After molding the first material to form the first portion of the injection molded part, the pins are removed. The mold is opened and rotated to a second mold cavity 40, the mold is closed, and the second material is injected into the second mold cavity. The second material fills the second mold cavity, contacts the interfacial surface 35 and flows into the interlock cavities 36 formed in the first portion, as shown in Figures B3 and B4. Solidification of the second material in the interlock cavities formed in the first material creates a mechanical interlock 48 between the first and second materials, as illustrated in Figures B5 and B6, by forming a neck portion of solidified second material that is more narrow than the diameter of the filled interlock cavity.

[0054] Another embodiment of a two-shot injection molded part made in accordance with the present process is illustrated in Figures C1-C6. The two- shot injection molded part 50 has a first portion 52, molded from a first material, and a second portion 54 molded from a second material that differs from the first material in at least one property. The embodiment illustrated in Figures C1-C6 is suitable for a molded part wherein the second portion is comprised of a desiccant entrained plastic and the first portion is comprised of a polycarbonate to provide protection for the desiccant plastic portion and protect it from abrasion and/or dusting. The first portion 52 is bowl-shaped and has an inner sidewall 56 that forms an interfacial surface and an outer sidewall 58.

[0055] The injection molded part 50 is formed by injection molding the first material in a mold cavity 60 to form the first portion of the injection molded part. The moid cavity is provided with a plurality of pins that project inward from the wall of the mold cavity. Each pin has a larger diameter end that is adjacent to the mold cavity wall and a smaller diameter end that intersects what will become the interface between the first and second materials.

[0056] Similar to the embodiment shown in Figures B1-B6, when the first material is injected into the mold cavity, it flows around the pins, resulting, upon solidification, in a plurality of interlock cavities 62 that extend completely through the first portion, from the inner sidewall 56, forming the interfacial surface, to the outer sidewall 58. Each interlock cavity 62 has an opening 64 at the interfacial surface that has a diameter that is smaller than the diameter of the opening at the outer sidewall 58.

[0057] After forming the first portion 52, the mold is opened and rotated to a second mold cavity. The mold is then closed and the second material is injected into the second mold cavity to form the second portion 54 of the molded part. The second material fills the second mold cavity, contacts the interfacial surface, and flows into the interlock cavities 62 formed in the first portion 52, as shown in Figures C3 and C4. Solidification of the second material in the interlock cavities formed in the first portion creates a mechanical interlock 68 between the first and second materials, as illustrated in Figures C5 and C6. [0058] A further embodiment of the injection molding process of the present invention, illustrating the use of an active interlock, is described with reference to Figures D1-D6. The injection molded part 70 has a first portion 72, formed from a first material, and a second portion 74 formed from a second material that differs from the first material in at least one property. The molding of the first and second materials is similar to the process described in connection with Figures A1-A7, except that the pins are positioned in the mold cavity so that they are adjacent to but do not intersect what will become the interface between the first and second materials. When the first material is injected into the mold cavity 80, it flows completely around the pins, resulting, upon solidification, in a plurality of interlock cavities 76 in the first portion 72 that are closed off from the second mold cavity by a thin wall 78 formed from the first material as shown in Figure D4. The wall has a thickness ranging from about 0.005 to about 0.010 inches (0.125 mm to 0.250 mm).

[0059] When the second material is injected into the second mold cavity, fill pressure from the injection breaks the wall 78, allowing the second material to flow into the interlock cavities 76 formed in the first portion 72, as shown in Figures D5 and D6. Solidification of the second material in the interlock cavities 76 creates a mechanical interlock 82 between the first and second materials. Further, when the thin-walled section of the interlock cavity is broken, the second material flows around the broken portions of the walls to create additional mechanical anchors 84, as shown in Figures D1 and D3, that further prevent the two materials from being pulled apart.

[0060] Another embodiment of an injection molded part made in accordance with the method of the present technology is shown in Figures E1 and E2. The molding process described in connection with Figures A1-A7 is used to mold the part 90. A first portion 92 is molded from a first material, such as a polycarbonate, that can flex, as shown in Figure E2, and has a memory that enables the first portion of the part to be. used as a type of spring. A second portion 94 is molded from a second material, such as a desiccant entrained plastic.

[0061] The invention has now been described in such full, clear, concise and exact terms as to enable any person skilled in the art to which it pertains to practice the same. It is to be understood that the foregoing describes preferred embodiments and examples of the invention, and that modifications may be made therein without departing from the spirit or scope of the invention as set forth in the claims.

Claims

1. A method of molding a molded part formed from at least two materials comprising the steps of:

(a) injecting a first molten material into a mold so that the first material forms a first portion of the molded part, the first portion of the molded part having an interfacial surface and at least one interlock cavity formed adjacent to the interfacial surface;

(b) injecting a second molten material into the mold such that the second material contacts the interfacial surface and flows into the interlock cavity adjacent to the interfacial surface, and

(c) allowing the second material to cool and solidify, whereby solidification of the second material in the interlock cavity forms a mechanical interlock between the first material and the second material that prevents the first and second materials from being separated.

2. The method of claim 1, wherein the interlock cavity has an opening at the interfacial surface that is less than the diameter of the interlock cavity.

3. The method of claim 1 or 2, wherein the interlock cavity has an opening at the interfacial surface that is less than one-half the diameter of the interlock cavity.

4. The method of claim 1, wherein the interlock cavity is closed by a wall formed from the first material, the wall having a thickness in the range of about 0.005 to about 0.010 inches, and wherein fill pressure from the injection of the second material into the mold breaches the wall to permit the second material to flow into the interlock cavity.

5. The method of any preceding claim, wherein the first portion of the molded part has a plurality of interlock cavities formed adjacent to the interfacial surface.

6. The method of any preceding claim, wherein at least one of the first or second materials comprises a thermoplastic polymer.

7. The method of any preceding claim, wherein the first and second materials are dissimilar.

8. The method of claims 1 to 6, wherein the first and second materials are similar.

9. The method of claims 1 to 7, wherein the first material comprises a polycarbonate resin and the second material comprises a desiccant entrained polymer.

10. The method of any preceding claim, wherein at least one of the first or the second materials comprises a desiccant entrained polymer.

11. The method of claim 10, wherein the desiccant entrained polymer comprises at least one polymer and a desiccant.

12. The method of claims 10 or 11 , wherein the desiccant entrained polymer comprises at least two immiscible polymers and a desiccant.

13. The method of claim 1 , wherein the at least one interlock cavity is formed by a pin inserted into the mold.

14. The method of claim 1, wherein the first and second materials are injection molded in a two-shot injection mold.

15. The method of claim 1, wherein the first and second materials are injection molded in an overmolding process.

16. An injection molded part formed from at least two materials comprising:

(a) a first material that forms a first portion of the molded part having an interfacial surface and at least one interlock cavity formed adjacent to the interfacial surface;

(b) a second material that forms a second portion of the molded part such that the second material contacts the interfacial surface and fills the interlock cavity adjacent to the interfacial surface, thereby forming a mechanical interlock between the first material and the second material that prevents the first and second materials from being separated.

17. The injection molded part of claim 16, wherein the mechanical interlock has a neck that is narrower than the diameter of the interlock cavity.

18. The injection molded part of claims 16 or 17, wherein the first portion of the molded part has a plurality of cavities formed adjacent to the interfacial surface.

19. The injection molded part of claims 16 to 18, wherein at least one of the first or second materials comprises a thermoplastic polymer.

20. The injection molded part of claims 16 to 19, wherein the first and second materials are dissimilar.

21. The injection molded part of claims 16 to 19, wherein the first and second materials are similar.

22. The injection molded part of claims 16 to 20, wherein the first material comprises a polycarbonate resin and the second, material comprises a desiccant entrained polymer.

23. The injection molded part of claims 16-22, wherein at least one of the first or the second materials comprises a desiccant entrained polymer.

24. The injection molded part of claim 23, wherein the desiccant entrained polymer comprises at least one polymer and a desiccant.

25. The injection molded part of claims 23 or 24, wherein the desiccant entrained polymer comprises at least two immiscible polymers and a desiccant.