WO2007138363A1 - ProcÉdÉ et dispositif pour la purification et l'enrichissement en matÉriau hydrocarbonÉ - Google Patents
ProcÉdÉ et dispositif pour la purification et l'enrichissement en matÉriau hydrocarbonÉ Download PDFInfo
- Publication number
- WO2007138363A1 WO2007138363A1 PCT/GE2007/000001 GE2007000001W WO2007138363A1 WO 2007138363 A1 WO2007138363 A1 WO 2007138363A1 GE 2007000001 W GE2007000001 W GE 2007000001W WO 2007138363 A1 WO2007138363 A1 WO 2007138363A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hydrocarbon material
- electrolyte
- purifying
- electrodes
- hydrocarbon
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
- C10G32/02—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms by electric or magnetic means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M27/00—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
- F02M27/04—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by electric means, ionisation, polarisation or magnetism
Definitions
- the invention refers to method and device for purifying hydrocarbon material from hetero-organic impurities, metals and mechanical particles.
- the invention may be used for internal combustion engines and other devices using hydrocarbon fuel. It may be used at gas and oil fields, where the hydrocarbon raw will be purified from corrosion causing impurities directly prior to transportation over a pipeline or in railway tank-wagons that will significantly reduce the costs for their maintenance and operation, will reduce the ecological load on the environment, flora and fauna.
- One of the methods for reducing toxic injections in combustion materials is catalytic process based on passing the fuel through the thermocatalytic chamber [1] SU No 1799429 or purification of exhaust gases by free radicals [2] SU No 111522.
- the main disadvantages for the catalytic process of purification are as follows: high cost price of catalytic materials and their alloys (platinum, palladium, etc.); complexity of the design; heating of some components up to high temperature; reduce of engine power; fuel over-expenditure; non-occurrence of neutralization of the whole set of toxic injection.
- electrochemical method for purification of hydrocarbons from organic impurities [3], WO 9325636 1993, [4] WO No 9749785 1997.
- One of their disadvantages is the need for neutralization of products of purification.
- the prior art of the proposed method is the process for purification of hydrocarbons by electrochemical method, which comprises counterflow of hydrocarbon and electrolyte in electrolytic cell (due to the difference in specific gravities the hydrocarbon is moving over the electrolyte).
- the purification is effected only on the contact surface of hydrocarbon and electrolyte under significant power expenses [5] GE U 1999452 Georgia.
- the filters by means of which the purification of hydrocarbon fuel from mechanical impurities is carried out [6] the USSR No 1586747 23.08.90. But said filters do not purity the fuel from toxic organic impurities and metals.
- Another prior art of the proposed device is also the gravitation filter. Said filter provides purification of the fuel only from mechanical impurities [7] the USSR No 1454994 1989.
- the technical result of the invention is purification of hydrocarbon material from detrimental and toxic impurities, reduce of fuel consumption, increase in recourse for engine operation, simplification and cheapening of the whole cycle of the turnaround of oil-refining plants, chemical and other enterprises consuming hydrocarbon material, radical solution of the ecological problems concerned.
- the technical result is achieved in that the hydrocarbon material is purified from the detrimental impurities through its contact with the short-lived radicals of hydrogen (H*) and oxygen (O**) arising during the electrolysis.
- H* and O** the contact of H* and O** is effected in the whole volume of the electrolyte, through which in order to increase the contact surface the hydrocarbon is moving upwards via the sparger, alternately interacting with positive and negative mesh electrodes, i.e. with H* and O**.
- Fig.l shows the device, its vertical cross-section.
- the device comprises a hermetic body with a sediment box, a power supply connected to the packet of conical or spherical electrodes, the amount and the area of which depends on the amount and the quantity of the cleanable material, a sparger disposed under the lower electrode, a cylinder with the electrodes included therein.
- the body comprises the electrolyte level controller.
- the device operates as follows: the body 1 is filled with the electrolyte 2 from the plug fitting 3 to the level between the plates (A and B) 4.
- the cleanable material 5 from the capacity 6 by means of the pump 7 is fed to the sprayer 8. From there, broken into small fractions material due to the difference in specific gravities is moving upwards through the electrolyte 2 and the assembly of mesh electrodes 9 and 10 placed therein, alternately interacting with free radicals H* and O** formed in the result of electrolysis. They are very active. Their lifetime is some microseconds only.
- the process proceeds under the normal temperature and pressure, without the use of expensive catalysts and at the minimal cost of electric power.
- the purified material is saturate with hydrogen and oxygen remaining after the reaction that promotes to more efficient combustion of the fuel and after pass through the control filter 12 by means of the pump 7 arrives to the consumer, in particular to the internal combustion engine 13 and a suppressor 14.
- the level controller - a magnetically operated sealed switch 15 is switched and from capacity 16 the body 1 is filled with electrolyte to the blades level (A and B).
- the heater 17 serves for keeping the optimal temperature in body 1.
- the reverse valve 18 serves for preventing ingress of electrolyte 2 into capacity 6 with hydrocarbon material.
- the power supply 19 with the voltage regulator 20 provides feeding of voltage to electrodes 9 and 10. For internal combustion engines the voltage may be fed from generator-dynamo. Cylinder 21 provides the bottom-up movement of cleanable material only through the assembly of mesh conical or spherical electrodes 9 and 10.
Abstract
L'invention concerne un procédé et un dispositif permettant de purifier un matériau hydrocarboné d'impuretés organiques hétérogènes, de métaux et de particules mécaniques. Le procédé consiste à faire passer le matériau hydrocarboné à travers une cellule électrolytique et est caractérisé en ce que la purification se produit en faisant passer le matériau à travers un ensemble d'électrodes coniques ou sphériques à l'envers dans le volume entier d'un corps. Le dispositif comprend un corps fermé équipé de tuyaux pour l'entrée et la sortie du matériau hydrocarboné et d'un électrolyte, un ensemble d'électrodes de forme sphérique ou conique avec une alimentation en énergie, un régulateur et un atomiseur.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GEAP2006009425 | 2006-06-01 | ||
GEAP20069425A GEP20094631B (en) | 2006-06-01 | 2006-06-01 | Method and the device of clearing and enrichment of hydrocarbonic materials |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007138363A1 true WO2007138363A1 (fr) | 2007-12-06 |
Family
ID=38515707
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GE2007/000001 WO2007138363A1 (fr) | 2006-06-01 | 2007-05-29 | ProcÉdÉ et dispositif pour la purification et l'enrichissement en matÉriau hydrocarbonÉ |
Country Status (2)
Country | Link |
---|---|
GE (1) | GEP20094631B (fr) |
WO (1) | WO2007138363A1 (fr) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009149327A2 (fr) * | 2008-06-05 | 2009-12-10 | Global Opportunities Investment Group, Llc | Procédé et système de combustion de carburant |
US7836543B2 (en) | 2006-02-10 | 2010-11-23 | Tennant Company | Method and apparatus for producing humanly-perceptable indicator of electrochemical properties of an output cleaning liquid |
US7891046B2 (en) | 2006-02-10 | 2011-02-22 | Tennant Company | Apparatus for generating sparged, electrochemically activated liquid |
US8007654B2 (en) | 2006-02-10 | 2011-08-30 | Tennant Company | Electrochemically activated anolyte and catholyte liquid |
US8012339B2 (en) | 2006-02-10 | 2011-09-06 | Tennant Company | Hand-held spray bottle having an electrolyzer and method therefor |
US8012340B2 (en) | 2006-02-10 | 2011-09-06 | Tennant Company | Method for generating electrochemically activated cleaning liquid |
US8016996B2 (en) | 2006-02-10 | 2011-09-13 | Tennant Company | Method of producing a sparged cleaning liquid onboard a mobile surface cleaner |
US8025787B2 (en) | 2006-02-10 | 2011-09-27 | Tennant Company | Method and apparatus for generating, applying and neutralizing an electrochemically activated liquid |
US8025786B2 (en) | 2006-02-10 | 2011-09-27 | Tennant Company | Method of generating sparged, electrochemically activated liquid |
US8046867B2 (en) | 2006-02-10 | 2011-11-01 | Tennant Company | Mobile surface cleaner having a sparging device |
US8236147B2 (en) | 2008-06-19 | 2012-08-07 | Tennant Company | Tubular electrolysis cell and corresponding method |
US8319654B2 (en) | 2008-06-19 | 2012-11-27 | Tennant Company | Apparatus having electrolysis cell and indicator light illuminating through liquid |
US8337690B2 (en) | 2007-10-04 | 2012-12-25 | Tennant Company | Method and apparatus for neutralizing electrochemically activated liquids |
US8371315B2 (en) | 2008-12-17 | 2013-02-12 | Tennant Company | Washing systems incorporating charged activated liquids |
WO2013054176A3 (fr) * | 2011-10-12 | 2013-06-13 | Indian Oil Corporation Ltd. | Ensemble réacteur destiné à améliorer une réaction entre deux phases non miscibles en vue de réduire la teneur en métaux dans les hydrocarbures |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1838927A (en) * | 1927-06-23 | 1931-12-29 | Petroleum Rectifying Co | Stepped cone-type treater |
GB490767A (en) * | 1936-02-29 | 1938-08-22 | Bataafsche Petroleum | Improved process and apparatus for treating oil |
US2274636A (en) * | 1938-09-21 | 1942-03-03 | Standard Oil Dev Co | Electrodes for voltolization |
US2855357A (en) * | 1952-04-10 | 1958-10-07 | Petrolite Corp | Chemical refining of oils |
US4623442A (en) * | 1985-09-26 | 1986-11-18 | Alberta Oil Sands Technology And Research Authority | Apparatus for continuously separating particulate solids from liquid suspensions |
US5855764A (en) * | 1997-07-15 | 1999-01-05 | Exxon Research And Engineering Company | Method for demetallating petroleum streams |
-
2006
- 2006-06-01 GE GEAP20069425A patent/GEP20094631B/en unknown
-
2007
- 2007-05-29 WO PCT/GE2007/000001 patent/WO2007138363A1/fr active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1838927A (en) * | 1927-06-23 | 1931-12-29 | Petroleum Rectifying Co | Stepped cone-type treater |
GB490767A (en) * | 1936-02-29 | 1938-08-22 | Bataafsche Petroleum | Improved process and apparatus for treating oil |
US2274636A (en) * | 1938-09-21 | 1942-03-03 | Standard Oil Dev Co | Electrodes for voltolization |
US2855357A (en) * | 1952-04-10 | 1958-10-07 | Petrolite Corp | Chemical refining of oils |
US4623442A (en) * | 1985-09-26 | 1986-11-18 | Alberta Oil Sands Technology And Research Authority | Apparatus for continuously separating particulate solids from liquid suspensions |
US5855764A (en) * | 1997-07-15 | 1999-01-05 | Exxon Research And Engineering Company | Method for demetallating petroleum streams |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8046867B2 (en) | 2006-02-10 | 2011-11-01 | Tennant Company | Mobile surface cleaner having a sparging device |
US7836543B2 (en) | 2006-02-10 | 2010-11-23 | Tennant Company | Method and apparatus for producing humanly-perceptable indicator of electrochemical properties of an output cleaning liquid |
US7891046B2 (en) | 2006-02-10 | 2011-02-22 | Tennant Company | Apparatus for generating sparged, electrochemically activated liquid |
US8007654B2 (en) | 2006-02-10 | 2011-08-30 | Tennant Company | Electrochemically activated anolyte and catholyte liquid |
US8012339B2 (en) | 2006-02-10 | 2011-09-06 | Tennant Company | Hand-held spray bottle having an electrolyzer and method therefor |
US8012340B2 (en) | 2006-02-10 | 2011-09-06 | Tennant Company | Method for generating electrochemically activated cleaning liquid |
US8025787B2 (en) | 2006-02-10 | 2011-09-27 | Tennant Company | Method and apparatus for generating, applying and neutralizing an electrochemically activated liquid |
US8719999B2 (en) | 2006-02-10 | 2014-05-13 | Tennant Company | Method and apparatus for cleaning surfaces with high pressure electrolyzed fluid |
US8603320B2 (en) | 2006-02-10 | 2013-12-10 | Tennant Company | Mobile surface cleaner and method for generating and applying an electrochemically activated sanitizing liquid having O3 molecules |
US8016996B2 (en) | 2006-02-10 | 2011-09-13 | Tennant Company | Method of producing a sparged cleaning liquid onboard a mobile surface cleaner |
US8156608B2 (en) | 2006-02-10 | 2012-04-17 | Tennant Company | Cleaning apparatus having a functional generator for producing electrochemically activated cleaning liquid |
US8025786B2 (en) | 2006-02-10 | 2011-09-27 | Tennant Company | Method of generating sparged, electrochemically activated liquid |
US8337690B2 (en) | 2007-10-04 | 2012-12-25 | Tennant Company | Method and apparatus for neutralizing electrochemically activated liquids |
US8485140B2 (en) | 2008-06-05 | 2013-07-16 | Global Patent Investment Group, LLC | Fuel combustion method and system |
WO2009149327A3 (fr) * | 2008-06-05 | 2010-03-18 | Global Opportunities Investment Group, Llc | Procédé et système de combustion de carburant |
WO2009149327A2 (fr) * | 2008-06-05 | 2009-12-10 | Global Opportunities Investment Group, Llc | Procédé et système de combustion de carburant |
US8319654B2 (en) | 2008-06-19 | 2012-11-27 | Tennant Company | Apparatus having electrolysis cell and indicator light illuminating through liquid |
US8236147B2 (en) | 2008-06-19 | 2012-08-07 | Tennant Company | Tubular electrolysis cell and corresponding method |
US8371315B2 (en) | 2008-12-17 | 2013-02-12 | Tennant Company | Washing systems incorporating charged activated liquids |
WO2013054176A3 (fr) * | 2011-10-12 | 2013-06-13 | Indian Oil Corporation Ltd. | Ensemble réacteur destiné à améliorer une réaction entre deux phases non miscibles en vue de réduire la teneur en métaux dans les hydrocarbures |
Also Published As
Publication number | Publication date |
---|---|
GEP20094631B (en) | 2009-03-10 |
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