WO2007128388A2 - Agent mouillant à faible teneur en cov pour préparations aqueuses de pigments - Google Patents

Agent mouillant à faible teneur en cov pour préparations aqueuses de pigments Download PDF

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Publication number
WO2007128388A2
WO2007128388A2 PCT/EP2007/003427 EP2007003427W WO2007128388A2 WO 2007128388 A2 WO2007128388 A2 WO 2007128388A2 EP 2007003427 W EP2007003427 W EP 2007003427W WO 2007128388 A2 WO2007128388 A2 WO 2007128388A2
Authority
WO
WIPO (PCT)
Prior art keywords
acid
pigment
aqueous pigment
humectant
pigment preparations
Prior art date
Application number
PCT/EP2007/003427
Other languages
German (de)
English (en)
Other versions
WO2007128388A3 (fr
Inventor
Hendrik Ahrens
Jochem Effing
Original Assignee
Clariant International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant International Ltd filed Critical Clariant International Ltd
Priority to EP07724364A priority Critical patent/EP2024445A2/fr
Publication of WO2007128388A2 publication Critical patent/WO2007128388A2/fr
Publication of WO2007128388A3 publication Critical patent/WO2007128388A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0084—Dispersions of dyes
    • C09B67/0085—Non common dispersing agents
    • C09B67/0089—Non common dispersing agents non ionic dispersing agent, e.g. EO or PO addition products
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/006—Preparation of organic pigments
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/006—Preparation of organic pigments
    • C09B67/0063—Preparation of organic pigments of organic pigments with only macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0084—Dispersions of dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44—Carbon
    • C09C1/48—Carbon black
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/32—Inkjet printing inks characterised by colouring agents
    • C09D11/322—Pigment inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium

Definitions

  • the present invention relates to aqueous pigment preparations containing humectants with low levels of volatile compounds.
  • Humectants are added to aqueous pigment preparations to prevent premature drying of the preparations on the surface.
  • pigment preparations In particular at higher temperatures, for example 60 ° C., solid cakes or a skin form on the surface of the pigment preparation.
  • the water evaporates and the pigment preparation concentrates on. Since pigment preparations usually already contain high pigment concentrations, the evaporation of the water further concentrates the pigment preparation, which leads to a further increase in the viscosity, so that a skin or a solid cake is formed.
  • Humectants bind the water and thus prevent the pigment preparation from drying out.
  • moisturizers have the task of forming uniform films when the preparations dry.
  • Such pigment preparations are used as tinting pastes in architectural paints, as pigment pastes in the dyeing of textiles, for example polyester fibers, as printing inks for printing on paper, textile and other surfaces and as ink jet inks in non-contact printing processes.
  • humectants are polyalkylene glycols and mixtures thereof.
  • DE-100 42 900 and DE-A-198 42 952 disclose humectants for pigment preparations.
  • Suitable as such are polyhydric alcohols, in particular containing 3 to 8 carbon atoms, such as glycerol, erythritol, pentaerythritol, pentitols such as arabitol, adonite and xylitol, hexitols such as sorbitol, mannitol and duleite.
  • polyalkylene glycols and polyalkylene glycol monoalkyl ethers in particular having an average molecular weight of from 100 to 1500.
  • Als Examples thereof are di-, tri- and tetraethylene glycol, diethylene glycol monomethyl, -ethyl, propyl and butyl ethers and trimethylene glycol monomethyl, ethyl, propyl and butyl ethers.
  • pyrrolidones and N-alkylpyrrolidones such as N-methylpyrrolidones.
  • the proportion of the humectant in the colorant preparations is usually 0 to 15 wt .-%.
  • thioether analogues of several glycols are also suitable as humectants.
  • a disadvantage of relatively high molecular weight polyalkylene glycols is that, with their increasing molecular weight, the viscosity of the pigment preparations also increases, which results in a difficult dosage and eligibility of the pigment
  • Pigment preparation leads. Therefore, it is preferable to use polyalkylene glycols having a low molecular weight as a humectant. However, these show an increased content of volatile organic compounds (VOC, volatile organic compounds). These pollute people and the environment through odor and toxicity and are considered to be the cause of ozone pollution in cities under sunlight. Your avoidance is therefore desirable.
  • VOC volatile organic compounds
  • the VOC content in paints and coatings is determined according to DIN EN ISO 11890-2, according to which all substances with a boiling point of less than 25O 0 C are considered VOCs and their proportions are summed.
  • Low molecular weight polyalkylene glycols have a boiling point of less than 250 ° C. or contain larger amounts of volatile organic compounds having a boiling point of less than 250 ° C.
  • Polyalkylene glycols having a higher molecular weight also contain byproducts, raw materials, auxiliaries such as catalysts and acids and in polymers low molecular weight homologues which have a boiling point of less than 250 0 C and are therefore detected as volatile organic compounds.
  • the invention relates to aqueous pigment preparations containing in addition O
  • Another object of the invention is the use of at least one polyalkylene glycol, by addition of 1 to 100 moles of C 2 - to C 4 alkylene oxide having a water content of less than 1 wt .-%, to a starting alcohol having 1 to 6 Carbon atoms and 1 to 6 hydroxyl groups, which has a water content of less than 1 wt .-%, can be obtained as a humectant with a determined according to DIN EN ISO 11890-2 VOC content of at most 5 wt .-% for preparations of inorganic or organic pigments.
  • a further subject matter is a process for preparing preparations of inorganic or organic pigments by subjecting an inorganic or organic pigment 0.1 to 20 wt .-%, based on the finished preparation of a humectant with a determined according to DIN EN ISO 11890-2 VOC Content of not more than 5% by weight, the humectant comprising at least one polyalkylene glycol obtained by addition of 1 to 100 moles of C 2 to C 4 alkylene oxide having a water content of less than 1% by weight to a Starting alcohol having 1 to 6 carbon atoms and 1 to 6 hydroxyl groups, which has a water content of less than 1 wt .-%, can be obtained added.
  • Suitable polyalkylene glycols are obtained by controlling the molecular weight and by selecting the starting alcohols, catalysts and acids and by a particular purity of the raw materials.
  • Suitable polyalkylene glycols are prepared by anionic polymerization of preferably 3 to 80, especially 4 to 50, especially 5 to 30, and especially preferably 6 to 15 mol of C 2 - to C 4 -alkylene oxides per mole of starting alcohol.
  • Preferred as the alkylene oxide is ethylene oxide or propylene oxide.
  • Suitable starting alcohols are monoethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, glycerol, pentaerythritol, polyhydric alcohols having 2 to 6 carbon atoms and 2 to 6 hydroxyl groups, methanol, ethanol, propanol, butanol and pentanol.
  • suitable humectants are polyethylene glycol having an average molecular weight of 400 g / mol, polyethylene glycol monomethyl ether having an average molecular weight of 500 g / mol, or a glycerol ethoxylate having an average molecular weight of 350 g / mol.
  • the molecular weight thereof is preferably at least 300 g / mol, in particular at least 350 g / mol and particularly preferably at least 400 g / mol.
  • the preferred upper limit of the average molecular weight is 4,000 g / mol, in particular 2,000 g / mol, especially 1,000 g / mol. References to average molecular weights refer to weight average molecular weights.
  • the polyalkylene glycols according to the invention can be prepared.
  • the water content of the alkylene oxides used, in particular of the ethylene oxide used, is preferably less than 0.1% by weight, in particular less than 500 ppm and more preferably less than 100 ppm.
  • Suitable catalysts are alkali metal and alkaline earth metal hydroxides, in particular sodium hydroxide, potassium hydroxide and calcium hydroxide.
  • the catalysts are preferably dried after the reaction with the starting alcohol in order to obtain an as anhydrous system as possible and to obtain a small proportion of low molecular weight homologs of the polyalkylene glycols, which would be mitergestasst as VOC.
  • Another measure to Preparation of polyalkylene glycols as low-VOC humectants is the control of the molecular weight and molecular weight distribution of the polyalkylene glycols. By a narrow molecular weight distribution, the proportion of low molecular weight compounds can be reduced, resulting in a lower proportion of VOCs counting constituents of the polyalkylene glycols.
  • Suitable acids for neutralizing the catalysts which is required to complete the alkoxylation, usually organic acids are used, which may have a boiling point of less than 25O 0 C in neutralized form in the gas chromatograph and thus are detectable as VOC.
  • the selection of the acids is such that the sum of all components counted to the VOC does not exceed the desired limit.
  • Acetic acid, propionic acid, lactic acid, citric acid and higher molecular weight organic carboxylic acids in particular isooctanoic acid, isononanoic acid, isodecanoic acid, lauric acid, myristic acid, hexadecanoic acid, octadecanoic acid and octadecenoic acid are used for neutralization.
  • inorganic acids are particularly suitable for the neutralization of the catalysts used, since these can not be counted among the volatile organic compounds, for example boric acid, sulfuric acid, sulfurous acid, phosphoric acid, phosphorous acid, hypophosphorous acid and hydrochloric acid, sulfuric acid and phosphoric acid being considered to be particularly suitable ,
  • the polyalkylene glycols may be further hydrotrope substances added.
  • Hydrotropes which optionally also serve as solvents, can be, for example, formamide, urea, tetramethylurea, ⁇ -caprolactam, methyl cellosolve, glycerol, N-methylpyrrolidone, 1,3-diethyl-2-imidazolidinone, thiodiglycol, sodium benzenesulfonate, sodium xylenesulfonate, Sodium toluenesulfonate, sodium cumenesulfonate, sodium dodecylsulfonate, sodium benzoate, sodium salicylate or sodium butylmonoglycol sulfate.
  • the moisturizer composed of polyalkylene glycols and other hydrotropic substances has a VOC content of at most 5% by weight determined in accordance with DIN EN ISO 11890-2.
  • the VOC content of the humectant is in particular below 1%, preferably below 0.5% and particularly preferably below 0.3%.
  • the VOC content of the aqueous pigment preparations is in particular below 3%, preferably below 1%, especially below 0.5% and particularly preferably below 0.1% (all statements by weight based on the weights of the humectants or pigment preparations).
  • the pigment preparations according to the invention are used for tinting and dyeing paints and coatings and in particular aqueous emulsion paints. Usual amounts of the pigment preparations of the invention are 0.1 to 20% by weight, based on the color. Preference is given to tinting aqueous emulsion paints with the pigment preparations according to the invention. Furthermore, aqueous silicate paints, aqueous silicone paints, solventborne and aqueous alkyd paints, epoxy paints, one- or two-component polyurethane coatings and melamine-formaldehyde stoving enamels and all aqueous or solvent-borne paints and coatings used for architectural paints are colored with the pigment preparations of the invention.
  • the pigment preparations according to the invention are also used as colorants for coloring paper, as printing pastes for textile printing, as printing inks for paper printing and as ink jet inks.
  • the pigment preparations according to the invention preferably contain the following ingredients:
  • Components B 0.1-20% by weight of one or more wetting and dispersing agents
  • Components C 0.1-20% by weight and preferably 5-15% by weight of one or more humectants
  • Components D optionally one or a combination of several
  • Preservative components E optionally resins, polymers, thickeners, dyes,
  • Pigment preparations used adjuvants component F water ad 100 wt .-%.
  • Phthalocyanine quinacridone, perylene, perinone, thioindigo, anthanthrone, anthraquinone, flavanthrone, indanthrene, isoviolanthrone, pyranthrone, dioxazine, quinophthalone, isoindolinone, isoind
  • organic pigments are carbon black pigments, such as gas or Furnaceruße; Monoazo and disazo pigments, in particular the Color Index Pigments Pigment Yellow 1, Pigment Yellow 3, Pigment Yellow 12, Pigment Yellow 13, Pigment Yellow 14, Pigment Yellow 16, Pigment Yellow 17, Pigment Yellow 73, Pigment Yellow 74, Pigment Yellow 81, Pigment Yellow® 83, Pigment Yellow® 87, Pigment Yellow® 97, Pigment Yellow® 111, Pigment Yellow® 126, Pigment Yellow® 127, Pigment Yellow® 128, Pigment Yellow® 155, Pigment Yellow® 174, Pigment Yellow® 176, Pigment Yellow® 191, Pigment Yellow® 213, Pigment Yellow 214, Pigment Red 219, Pigment Red 38, Pigment Red 144, Pigment Red 214, Pigment Red 242, Pigment Red 262, Pigment Red 266, Pigment Red 269, Pigment Red 274, Pigment Orange 13, Pigment Orange 34 or Pigment Brown 41; Naphthol and naphthol AS pigments, in particular the Color Index Pigments Pigment Yellow
  • the organic pigment is preferably combined with carbon black and / or titanium dioxide.
  • laked dyes such as Ca, Mg, Al lacquers of dyes containing sulfonic acid and / or carboxylic acid groups.
  • suitable inorganic pigments are titanium dioxides, zinc sulfides, zinc oxides, iron oxides, magnetites, manganese iron oxides, chromium oxides, ultramarine, nickel or chromium antimony titanium oxides, manganese titanium rutiles, cobalt oxides, mixed oxides of cobalt and aluminum, rutile mixed phase pigments, rare earth sulfides, spinels of cobalt with nickel and zinc, spinels based on iron and chromium with copper zinc, and manganese, bismuth vanadates and extender pigments.
  • Color Index Pigments Pigment Yellow 184, Pigment Yellow 53, Pigment Yellow 42, Pigment Yellow Brown 24, Pigment Red 101, Pigment Blue 28, Pigment Blue 36, Pigment Green 50, Pigment Green 17, Pigment Black 11, Pigment Black 33 and Pigment White 6 were used. Preference is also often given to using mixtures of inorganic pigments. Mixtures of organic and inorganic pigments are also commonly used.
  • the pigment preparation was liquid, homogeneous and foam-free after one week of storage at 6O 0 C.
  • the viscosity of the pigment preparation was 240 mPa.s.
  • the pigment preparation is prepared and tested as described in Example 1. After one week storage at 60 0 C, the pigment preparation was liquid, homogeneous and foam-free. The viscosity of the pigment preparation was 310 rnPa-s.
  • the pigment preparation is prepared and tested as described in Example 1. After one week storage at 60 0 C, the pigment preparation was liquid, homogeneous and foam-free. The viscosity of the pigment preparation was 260 mPa-s.
  • component C Molecular weight of 500 g / mol and a VOC content of 0.5%
  • component D 0.2 part of preservative
  • component E 0.5 part of defoamer
  • component F demineralized water
  • the pigment preparation is prepared and tested as described in Example 1. After one week of storage at 6O 0 C, the pigment preparation was liquid, homogeneous and foam-free. The viscosity of the pigment preparation was 600 mPa.s.
  • the pigment preparation is prepared and tested as described in Example 1. After one week storage at 60 0 C, the pigment preparation was liquid, homogeneous and foam-free. The viscosity of the pigment preparation was 200 mPa-s.
  • the pigment preparation is prepared and tested as described in Example 1. After one week storage at 60 0 C, the pigment preparation was liquid, homogeneous and foam-free. The viscosity of the pigment preparation was
  • the pigment preparation is prepared and tested as described in Example 1. After one week storage at 60 0 C was the pigment preparation liquid, homogeneous and foam-free. The viscosity of the pigment preparation was 95 mPa.s.
  • Example 8 40 parts Cl. Pigment Blue 15: 1 (component A)
  • the pigment preparation is prepared and tested as described in Example 1. After one week of storage at 6O 0 C, the pigment preparation was liquid, homogeneous and foam-free. The viscosity of the pigment preparation was 260 mPa-s.
  • the pigment preparation is prepared and tested as described in Example 1. After one week storage at 60 0 C, the pigment preparation was liquid, homogeneous and foam-free. The viscosity of the pigment preparation was 70 mPa-s.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

L'invention concerne des préparations aqueuses de pigments, contenant, outre un pigment organique ou inorganique conférant une couleur, de 0,1 à 20 % en poids d'un agent humidifiant ayant une teneur en COV, déterminée selon DIN EN ISO 11890-2, inférieure ou égale à 5 % en poids. Ledit agent humidifiant comprend au moins un polyalkylèneglycol, pouvant être obtenu par fixation de 1 à 500 mol d'oxyde d'alkylène en C<SUB>2</SUB> à C<SUB>4 </SUB>à teneur en eau inférieure à 1 % en poids, sur un alcool de départ ayant de 1 à 6 atomes de carbone et de 1 à 6 groupements hydroxyle et possédant une teneur en eau inférieure à 1 % en poids.
PCT/EP2007/003427 2006-05-06 2007-04-19 Agent mouillant à faible teneur en cov pour préparations aqueuses de pigments WO2007128388A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07724364A EP2024445A2 (fr) 2006-05-06 2007-04-19 Agent mouillant a faible teneur en cov pour preparations aqueuses de pigments

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006021178.2 2006-05-06
DE102006021178A DE102006021178A1 (de) 2006-05-06 2006-05-06 VOC-arme Feuchthaltemittel für wässrige Pigmentpräparationen

Publications (2)

Publication Number Publication Date
WO2007128388A2 true WO2007128388A2 (fr) 2007-11-15
WO2007128388A3 WO2007128388A3 (fr) 2008-01-10

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PCT/EP2007/003427 WO2007128388A2 (fr) 2006-05-06 2007-04-19 Agent mouillant à faible teneur en cov pour préparations aqueuses de pigments

Country Status (3)

Country Link
EP (1) EP2024445A2 (fr)
DE (1) DE102006021178A1 (fr)
WO (1) WO2007128388A2 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9969817B2 (en) 2015-12-15 2018-05-15 Rohm And Haas Company Phenyl glycidyl ether adduct of maltodextrin
US10604590B2 (en) 2015-12-17 2020-03-31 Dow Global Technologies Llc Di- or tristyrylphenol monogycidyl ether adduct of maltodextrin
US10654964B2 (en) 2016-07-05 2020-05-19 Dow Global Technologies Llc Compositions comprising polyether-urethane-urea additives for block resistance and open time
US10669444B2 (en) 2016-03-11 2020-06-02 Dow Global Technologies Llc Coating formulation with an open time additive

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006052139A1 (de) * 2006-11-06 2008-05-08 Clariant International Limited Universelle Stir-in Pigmente
PL3333231T3 (pl) 2016-12-07 2021-03-08 Daw Se Kompozycja wodna dla układu podbarwiania, oparty na zestawie części układ podbarwiania, podbarwiane układy powłok malarskich i tynków jak i powłoki malarskie i tynki dostępne przez nanoszenie podbarwianych układów powłok malarskich bądź tynków

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0259130A2 (fr) * 1986-09-01 1988-03-09 Ing. C. Olivetti & C., S.p.A. Encre pour imprimante à jet d'encre
DE19842952A1 (de) * 1998-09-18 2000-03-23 Basf Ag Dispergiermittel
WO2002018504A2 (fr) * 2000-08-31 2002-03-07 Basf Aktiengesellschaft Composition colorante aqueuse pour impression a jet d'encre
WO2005017047A1 (fr) * 2003-08-15 2005-02-24 Basf Aktiengesellschaft Preparations colorantes
WO2007087961A2 (fr) * 2006-01-20 2007-08-09 Clariant International Ltd Dispersant pour préparations pigmentaires aqueuses

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0259130A2 (fr) * 1986-09-01 1988-03-09 Ing. C. Olivetti & C., S.p.A. Encre pour imprimante à jet d'encre
DE19842952A1 (de) * 1998-09-18 2000-03-23 Basf Ag Dispergiermittel
WO2002018504A2 (fr) * 2000-08-31 2002-03-07 Basf Aktiengesellschaft Composition colorante aqueuse pour impression a jet d'encre
WO2005017047A1 (fr) * 2003-08-15 2005-02-24 Basf Aktiengesellschaft Preparations colorantes
WO2007087961A2 (fr) * 2006-01-20 2007-08-09 Clariant International Ltd Dispersant pour préparations pigmentaires aqueuses

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9969817B2 (en) 2015-12-15 2018-05-15 Rohm And Haas Company Phenyl glycidyl ether adduct of maltodextrin
US10604590B2 (en) 2015-12-17 2020-03-31 Dow Global Technologies Llc Di- or tristyrylphenol monogycidyl ether adduct of maltodextrin
US10669444B2 (en) 2016-03-11 2020-06-02 Dow Global Technologies Llc Coating formulation with an open time additive
US10654964B2 (en) 2016-07-05 2020-05-19 Dow Global Technologies Llc Compositions comprising polyether-urethane-urea additives for block resistance and open time

Also Published As

Publication number Publication date
EP2024445A2 (fr) 2009-02-18
DE102006021178A1 (de) 2007-11-08
WO2007128388A3 (fr) 2008-01-10

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