WO2007127603A2

WO2007127603A2 - Apparatus and methods for pain relief using ultrasound energized polymers

Info

Publication number: WO2007127603A2
Application number: PCT/US2007/066294
Authority: WO
Inventors: Eilaz Babaev
Original assignee: Eilaz Babaev
Priority date: 2006-04-24
Filing date: 2007-04-10
Publication date: 2007-11-08
Also published as: US20180029079A1; CN101460179A; KR20090006209A; EP2010192A2; JP2009534166A; US20090155199A1; AU2007243048A1; WO2007127603A3; US20170001218A1

Abstract

Method and device to create energized polymers that can be used for pain relief, comprised of an ultrasound system that ultrasonically energize polymers that can then be used to provide an analgesic effect. Ultrasound waves are delivered to a polymer through direct contact, through a coupling medium, or without contact in order to energize the polymer. Other energies such as such as UV. microw ave, laser, electricity, RF, sun. light, magnetic/electromatinenc, etc can also be used to energize the polymer. The energized polymer can be immediately placed on a user to provide an analgesic effect, or the energized polymer can be placed storage material and removed at a later time to he placed on a user to provide an analgesic effect.

Description

Inventor Name and Address: Eiiaz P. Babaev

5929 Baker Road, Suite 470 Minnetonka, MN 55345

Citizenship: United States of America

Title: Apparatus and Methods for Pain Relief Using ultrasound Energized Polymers

APPARAIVS AM) ME THODS FOR PAIN RKUKF I SING VLTRASOIJND

ENERGIZED POLYMERS

BACKGROUN I⁾ OF 1111 ^• IN VKN DON

5 Hie present

to pain lelief. Io particular, the present indention relates to apparatus and methods foi pain ielief using polymers eπergi/ed by exposure to ultrasonic and said polymers are capable of storing the enemy imparted to them from ultrasound exposure.

Description of the Related Art- i O Treating peisistent lingei ing pain, often hut not exciusk e! y associated vv ith ai thi his, muscles soreness, headache, etc, w ith various forms of energy is well known to the art. Most often the energy chosen is a

of thermal energy,

m particular is heat or cold applied \ ia a portable pad or pack Applying thermal energy to a portable pack or pad is genet ally accomplished by means of a chemical reaction or energy transfer

placing {he pad

! 5 oi pack in hot environment, such as boiling w ater or a

or a cold em ironment such as a fridge or freezer. Transferring thermal energy to a portable pad or pack often results in the pad or pack becoming overheated oi tnercoυied When placed on the user, an ovei heated pad or pack can cause the user discomfort or burn the user's skin. Similarly, an

pad or pack when placed on the user^'s body can cause the user discomfoit or freeze burn the user^'s 0 skin.

SuppKing thermal energy to a portable pad or pack can also be accomplished by placing tv\ o or mote chemicals that are temporally separated w ithin the pack or pad these chemicals can be combined to create an endotherrøic or exothermic chemical reaction. When the user is in need of pain lelief. the user actuates the pad or pack by remox iπg the barrier separating the 5 reacthe chemicals. 1 hough effect he at pioducintj thermal energy, the use of chemicals in portable packs oi pads is ha/aitioυs in that the chemicals employed can injure the user^'s skin if the chemicals v-eie to leak out of the pad oi pack

Imparting thermal energy to a location of persistent lingering pain is also accomplished by apply ing chemicals and creams to the affected aiea and allowing them to evapoiatc Though not effective at generating heat, the evaporation of chemicals applied to the skin can generate a local cooling at the location of the user's body experiencing persistent lingering pain. The use of creams and chemicals is disadvantaged by the fact that such creams and chemicals are often messy to apply and can cause severe irritation if they come in contact with the user's eyes or mucosal membranes.

Generating and applying therapeutic energy to a location of the body experiencing persistent lingering pain is also accomplished by electrical stimulation. Transcutaneous Electrical Nerve Stimulation (TENS} is an example of this methodology. TENS, and other similar methods, treat pain by using electrodes to induce a current across the user's skin that transverses the site of persistent lingering pain. Portable versions of TENS, and similar devices, have been created and marketed. Requiring batteries or an external power source and often being bulking, TENS devices are not truly portable. Furthermore, the device is worthless if the user of the device is without batteries or an electrical outlet.

The limitations of the current energy based treatments of persistent lingering pain create a need for a portable device that is not bulky, that does not require the user to supply an external energy source or battery, that does not derive thermal energy from chemicals that irritate, injury, or burn the user's skin, and that cannot be overheated or overcooied as to avoid injuring the user.

SUMMARY OF TfIJh INVKN^'l ION

The present invention is directed towards apparatus and methods for pain relief by using polymers eneigι/ed by evposme to ultrasound, and said polymers aie capable of storing the energy imparted to them from ultrasound exposure. Apparatus and methods in accordance with the pioscnt invention may meet the

e-roentiøned needs and also piovide additional advantages and improvements that will be lεcogm/ed h\ those skilled in the art upon review of the piesem disclosure

The present invention comprises an ultrasonic generator, an ultrasonic transducer, an ultrasound horn, and an ultrasound tip Exposing a pol\ mer to ultrasonic wav es energizes the polymer and that polymer can then be used to pio\ ide pain rebel^".

Ultrasonic waves are de!i\ cred to a polymer in order to energize that polv-rner tltrasonic waves are delivered by directly contacting the polymer with the ultrasound tip, by contacting the polymer through a coupling medium, or without contacting the polymer. The energized poKmer is applied to a user to provide an analgesic effect either inimediateU after being eπeigized or the energized polymei can be stated fot use at a future time

The invention is related to apparatus and methods for pain relief that uses polymers energized by exposure to ultrasonic waves.

One aspect of this invention mav be to piw ide a method and device for quick pain relief.

Another aspect of this invention may be to provide a method and device for more effective pain relief

Another aspect of the invention may he to provide a method and de\ ice foi more efficient pain relief.

Another aspect of the invention may be to provide a method and

ice tor safer paiu relief. Another aspect of the imention may be to pro\ ide a method and device for pain relief that does not use chemicals or drugs

Another aspect of this imention may be to prov ide a method and dev ice for pain relief that is easv to use. Another aspect of the invention

ide a method and

ice for pain relief that can be used at home by an individual

Another aspect of the indention may be to pan ide a portable means for pain relief.

These and other aspects of the

ention will become more apparent from the written descriptions and figures below

BRII' F DHSC ¹RIR ION Oi* ^'1 HV SlRAW INCSS

The present Invention will be shown and described with reference to the drawings of preferred embodiments and clearly understood in details

Figure 1 is a perspective \ sew for an ultrasound appaiatus capable of eneigizing polymers according to the present im ention.

Figure 2 is a cross-sectional view of the ultrasound appaiatus

Figure 3 are of uiUasouπd tips that can be used with the ultrasound appatatus

Figure 4 is a perspective view of an ultrasound apparatus capable of energi/mg polymers through direct contact with a polymer, Figure 5 is a detailed view of an ultrasound apparatus that can energize polymers through direct contact with a polymei.

Figure 6 is a perspectn e schematic \ iew of a production line with an uhiasound apparatus capable of energs/ing polymers thiough direct contact

Figure 7 is a peispeethe schematic v iew of a production line with an uloasound apparatus capable of energizing polymers tk ough a coupling medium.

Figure 8 s a perspective schematic \ iew of an example production line w ith an ultrasound apparatus capable of energizing polymers and with a separate de\ice to seal polymers in stoi age

Figure 9 is a perspective

of a production line with an ulttasυimd apparatus capable of both energizing pαSvmers and sealing the energi/ed polymeis in storage

Figure Ϊ0 is a perspective \

of a pioduction line with a rotating ultiasound apparatus that can energi/e men ing polymeis from the tadiai side of an uiUasυimd tip

Figure 11 is a cross-sectional

of a production line with a ioiating ultrasound tip capable of energizing moving polymers from the radial side of the ultrasound tip, Figure 12 is a cross-sectional view of a production line with an ultrasound tip in a fixed position that can eneigi/e ram ing polymers Figure 13 ΪS a cioss-sectional \ ιew of a pioduction hne with h\a iotatmg ultrasound tips capable of energi/mg mo\tng poh mcis from i\κ tadial side of uilrasυimd tips

Figure 14 is a crosb-sectjoπai \iew of a production hoc wuh a ioiatmg ultrasound tip ihat is capable of ejietgtzirsg mo\ ing polymers from the tadial side of the ulnasound tip

DETAILED DESCRl PTK)N OF THE INVEN TION

The present invention is an apparatus and methods for pain relief using polymers energized by exposure to ultrasonic waves, and said polymers are capable of storing the energy imparted to them from ultrasound exposure. Preferred embodiments of the present invention in the context of an apparatus and methods are illustrated tn the figures and described in detail below.

Fig. 1 is a perspective view for an ultrasound apparatus capable of energizing polymers according to the present invention. The ultrasound apparatus comprise an ultrasound power generator !, a power supply cord 2, an ultrasonic transducer 3, an ultrasound horn 4, and an ultrasound tip 5.

Fig. 2 is a cross-sectional view of the ultrasound transducer s with accompanying ultrasound horn 4 and ultrasound tip 5 that is depicted in Fig, ϊ. The ultrasonic transducer 3 is connected to the ultrasound horn 4. The ultrasound horn 4 is mechanically connected to an ultrasound tip 5 by threading or other means 6, The preferred embodiment comprises an ultrasound tip 5 that is directly connected to the ultrasound horn 4 by a mechanical interface; alternative embodiments could have the ultrasound tip 5 directly connected to the ultrasound horn 4 to comprise a single piece without a mechanical interface.

Figs. 3a - 3g are front-views of ultrasound tips that can be used with the ultrasound apparatus depicted in Fig. 1. Fig. 3a is an ultrasound tip that has a smooth front surface 7 and a circular peripheral boundary 8. Fig, 3Ϊ> is an ultrasound tip that has a knurled front surface 9 and a rectangular peripheral boundary 10. Mg, 3e is an ultrasound tip that has a pyramidal front surface Il and a triangular peripheral boundary Ϊ2. Fig, 3d is an ultrasound tip that has a cylindrical front surface 13 and a polygonal peripheral boundary 14. Fig, 3e is an ultrasound lip that has a spiky front surface 15 and an elliptical peripheral boundary 16, Fig, 3f is an ultrasound tip that has a waved front surface 17 and a rectangular peripheral boundary IS. Fig. 3g is an ultrasound tip that has a grooved front surface 19 and a rectangular peripheral boundary 20. These are only examples of front surfaces and peripheral boundaries of ultrasound tips that can be used with the ultrasound apparatus according to the present invention. Other front surfaces and peripheral boundaries may be similarly effective. Furthermore, any front surface can be mixed and matched with any peripheral boundary Fig, 4 is a perspective view of an ultrasound apparatus capable of energizing polymers through direct contact, with a polymer. The ultrasound apparatus comprises an ultrasound power generator I, a power supply cord 2, an ultrasonic transducer 3. an ultrasound horn 4, and an ultrasound tip 5« The ultrasound tip 5 delivers ultrasonic energy to the polymer 2 ϊ that is located on base material 22. Examples of polymer 21 to use include, but are not limited to, crystalline polymers, amorphous polymers, polymer alloys, or any other polymers currently approved for use in medical devices or food contact substances by the Federal Food and Drug Administration. Other polymers not currently approved may be similarly effective. The recommended polymer to use is a crystalline polymer. Examples of base material 22 on which to place the polymer 21 during delivery of ultrasonic waves include, but are not limited to, metals, polymers, elastomers, ceramics, rubbers, fabrics, composite materials, or any other similarly effective base materials or a combination thereof. Au energized polymer 21 can be placed on a user to provide an analgesic effect.

Fig. 5 is a detailed view of the ultrasound apparatus depicted in Fig. 4 that can energize polymers through direct contact with a polymer. The ultrasound tip 5 delivers ultrasonic waves to the polymer 21 that is located on base material 22, Depending on the base material 22 used, ultrasound waves can travel through the base material 22 as shown in the sine wave that illustrates the emanated ultrasound energy. Depending upon the ultrasound parameters, reflection can occur both at me upper and lower surfaces levels of the base material 22; reflection of the ultrasonic waves can also occur at the lower surface level of the polymer 21. Finally, the amount of reflection may vary depending on the distance ill between the ultrasound tip 5 and the lower surface level of polymer 21 and may also vary depending on the distance ύ2 between the ultrasound tip 5 and the lower surface level of the base material 22. Reflection of ultrasonic waves can result in a polymer being double exposed to ultrasonic waves capable of energizing the polymer.

Fig. 6 is a perspective schematic view of a production line with an ultrasound apparatus capable of energizing polymers through direct contact. The ultrasound apparatus comprises an ultrasound power generator 1, a power supply cord 2, an ultrasound transducer 3, an ultrasound horn 4, and an ultrasound tip 5. The ultrasound tip 5 delivers ultrasonic waves to the polymer 21 that is located on base material 23, After being energized by exposure to ultrasonic waves, the polymer 2 ϊ moves down the production line and into storage material 24 that is secured by sealers 25, iesulting in a sealed packet 26 Examples of storage material 24 to use include, but arc not limited to, plastic bags, plastic sleeves, turn, υr fabnc. Other storage materials may be simiSarh effective. The energized polymer 21 can be placed on a user to pros lάe &n analgesic effect. F he use of the storage material 24 allows the polymer 2Ϊ to store energy, thus allowing the pol) ioer 2Ϊ to be removed fjoni the sealed packet 26 at a future tune to be placed on a user pro\ ide an analgesic effect.

FIg. 7 is a perspective schematic \ Jew of a ptoduction line Λ\ ith an ultrasound apparatus capable of energizing polymers through a coupling medium. The ultrasound tip 5 delivers ultrasonic energy though a coupling medium 27 to the polymer 21 that Is located on base material. 23. Kxampies of coupling medium 27 include, but aie not limited to. film, liquid, gel, or ointment. Other coupling mediums can be similarly effecm e After being energized by exposure to ultrasonic waves, the polymer 21 mo\cs down the production line and into storage material 24 that is secured by sealeis 25, resulting in a sealed packet 26. Example¹; of stoiage material 24 to use include, but are not limited to. plastic bags, plastic sleeves, film, or fabric. Other storage materials may be simiiaily effective. The energized pol\ mer 21 can be placed on a user to pro\ ide an analgesic effect The use of the storage materia! 24 allows the polymer 21 to store eueigy, thus allowing the polymer 21 to be reιno\ ed from the sealed packet 26 at a future time to be placed on a user provide an analgesic effect.

Fig, 8 is a perspective schematic view of a production line with an ultiasound appatatus capable of energizing polymers and with a separate device to seal polymets m storage. The ultrasound hora 5 delivers ultrasonic waves to the polymer 21 that is located on base material 23. After being energized by exposure to ultrasonic \va\es, the pol\ meϊ 21 tao\ es down the production line and into storage material 28 that is released from storage material spools 29. The storage material 28 may consist of one adhcshe and one non-adhcshc side, or it may also consist of two non-adhesh e sides. Examples of storage materia! 28 to use include, but are not limited to, plastic bags, plastic sleeves, film, or fabric Other storage materials may be similarly effective. The polymer 21 is then sealed in the storage material 28 by ultrasonic welding with ultrasound wax es delivered from ultrasound tip 30. Ultrasound welding is an example of a sealing method; other methods, such as heat, may be similarly effective The sealed packet 26 mo\ es down the production line by driving wheels 31 w here it is cut into an mdή idual section by blade 32 contacting cutting block 33. Other methods and devices may be similarly effective ui separating the sealed packet 26 The energized polymer 21 can be placed on a user to provide an analgesic effect. The use of the storage material 28 allow s (lie pυiyinei 21 to store energ\, thus allowing the polymer 21 to be removed from the sealed packet 26 at a futiue time to be placed on a user to provide an analgesic effect. Fig. 3 is a perspective view of a production line v\ ith an ultrasound apparatus capable of both energizing polymers and sealing the eneigued po)>meιs in storage Polymer 21 moves dow n production line into storage material 28 that is released fiom storage material spools 29 The ultiasound tip 34 then serves a dual function, ihe tip M delivers uittasonie waves io the polymer 21 that is in the storage material 28, and the tip 34 also delivers ultrasonic waves to the storage mateπai 28 in order to seal the polymei 21 in the storage mateiiai 28 I neτgϊ/iπg the polymer 21 can occur befoie, during, oτ aftei ultrasound eneϊgy is deh\eied to sea! the polymer 2! in the storage materia! 28. The sealed packet 26 moves dow n the production line by driving wheels 31 and then is cut into an indi\ idual section by blade 32 contacting cutting block S3. Other methods and devices may be similarly effective m separating the sealed packet 26. The eneigi/ed poly mer 21 can be placed on a user to pw\ ide an analgesic effect. The use of the storage material 28 allows the polymer 21 to store energy, thus allowing the polymer 2 ϊ to be reinox ed from the sealed packet 26 at a futuie time to he placed on a user to ριo\ ide an analgesic effect.

Fig, 10 is a perspective \ icvv of a production line with a rotating ultrasound apparatus that can eneigi/e mov ing polymers from the radial side of an ultrasound tip. The nitrasonnd apparatus consists of an ultrasonic transducer 35 that is connected to the ultrasound horn 36, and the ultrasound hoin 36 is connected to the ultrasound tip 37 1 he ultrasound apparatus rotates and energizes the polymer 38 from the radial side of the ultrasound tip 37 as the poi> mer 38 mov es down the production line The recommended peripheral boundary for an ultrasound tip 37 on a rotating ultrasound apparatus is circular. Other peripheral boundaries may be similarly effecm e. The recommended radial surface for the ultrasound tip 37 is smooth Other radial surfaces such as knurled, waved, or grooved (not shown) can be similarly effecm e. This production line method allows for large sections of polymer to be sonicated at once because after the moving polymer 38 has been energized it can be cut into individual sections and sealed for use at a future time

1 ! Fig, 1 1 is a cross-sectional \ iew of a pt eduction line with a rotating ultrasound tip capable of energi/ing moving polymers from the tadial side of the ultsasound tip The mo\ ing polymer 38 mo\es άo\M\ the production line to be energized b\ ultrasonic waxes delivered from the radial side of the rotating ultrasound tip 37. There is base material 39 that is located in a fixed position on the other side of the mo\ ing polymer 38 from the rotating ultrasound up 37. Once the mo\ ing polymer 38 has been energized, it can be cut into individual sections and sealed lot use at a fimuε tune

Fig. 12 is a cross-sectional Mew of a production line with an uhiasound tip in a fixed position that can energize moving polymers The moving polymer 38 mo\ cs down production line to be energi/ed by ultrasonic \\a\ es deux eied from the radial side oi distal end of the ultrasound tip 40 that is located in a fixed position fhere is base material 41 located on the other side of the moving polymer 38 from the fixed ultrasound tip 40. The base material 41 rotates as the polymer 38 mo\ es down the production line Once the mo\ ing polymer 38 has been energized, it can be cut into individual sections and scaled for use at a future time Fig, 13 is a cross-sectional \ ievv of a production Sine \\ ith two iotating ultrasound tips capable of energizing ram ing polymeis from the radial side of ultrasound tips. 1 he mo\ ing polymer 38 moves dovui production line to be eπcigized on each side by ultrasonic \xa\ es deli\ ered from the radial sides of the rotating ultrasound tips 37 1 heie no is base material in this production line. Once the mo\ ing polymer 38 has been energi/ed, it can be cut into individual sections and sealed for use at a future time

Fig, 14 is a cross-sectional \ie\\ of a production line with a rotating ultrasound tip that is capable of energi/mg moving polymers from the tadial side of the ulttasound tip The mo\ nig polymer 38 mo\es down the production line to be energized b\ ultrasonic waxes delivered from the radial side of the rotating ultrasound tip 37. There is base material 41 located on the other side of the moving poh iner 38 from the rotating ultrasound tip 37, The base material 41 also rotates as the poh met" 38 moves down the production line Once the mo\ ing polymer 38 has been energi/ed. it can be cut into indi\ iduai sections and sealed foi use at a future time

The frequency range for the ultrasonic v\a\es capable of energizing a polymer is approximately 15 kHz to approximately 40 MHz. with a preferred frequence range of appioximateSy 20 Sd Sz - approximate!) 40 kϊ iz. 1 he recommended low-frequency ultrasound value is approximately 30 LH/ and the iecommended high-frequency ultrasound \aiue is approximately 3 VIlϊ? The amplitude of the ultrasound waves can be i micion and abcne The preferred amplitude range for low -frequency ultrasound is approximately 50 microns to approximately 60 microns, and the recommended amplitude \ahιe for low -frequency ultrasound is appjoximately 50 microns Fhe prefeπed amplitude iange for high-frequency ultrasound is approxiraatelv 3 microtis to approximately 10 microns, and the recommended amplitude v alue foj high-frequency uiuasound is approximately Λ microns The time of sonieation will \ ai\ based on factors such as the ultrasound frequency, amplitude, intensity, the type of pohmer the thickness of polymer, the type of base material, the thickness of base material, etc Ultrasonic waves are delivered from an uiuasound apparatus to a poly mer to energi/e the polymer. Litrasorue wa\es can be de!i\ eied h\ either direct contact, through a coupling medium, or \\ ithoυt contact. Ultrasonic wax cs can also be delivered from either the distal end or the radial side of the ultrasound hoin/tip The shape of the ultrasound tip used may \ an The peripheral boundary' may be circular, rectangular, triangular, polygonal, elliptical, or another similar shape or combination of shapes The fiont surface of the ultrasound tip ma} be smooth, knurled, puamidal, cylindrical, spiky, waλ ed. grooved or another similar surface or combination of surfaces. The preferred shape of the ultiasound tip is a smooth front surface with a rectangular peripheral boundary, but other shapes can also be similarly effective.

The polymer may be placed on surface material while being eneigi^ed by exposure to ultrasonic \va\es. The surface materials that may be used ^■vary from metals, polymers, elastomers, ceramics, rubbers, fabrics, composite materials, or any other similarly effecth e surface materials or a combination thereof The size and thickness of the surface material can also vary. Besides acting as a base while flic polymer is being energized, the surface material can also serv e an additional purpose. Depending upon the surface material used and the parameters of the ultrasound w a\ es del K ered, ultrasound \\ a\ es cart reflect off of the surface material and back onto the polymer once again, thus resulting in the polymer being double exposed to ultrasonic waves capable of energizing the polymer. I he ultrasonic waves can also reflect off the lower surface level of the polymer itself The polymer can also be energized b> means other than ultiasound such as FV. micros a\e. laser electricity'- RF sun, light. magnetic electromagnetic, etc. The polymer may be placed in stoiage material before, after, or while being eneigized by ultrasonic waves The poly met can be cncigi/cd and then diopped into storage material, fed into storage mateπai. or any other method to store an energized polymer. Hie polymer can also be fed into storage material so that it can energized and sealed simultaneously. Final!} . the poiyraej can be sealed in its storage material and then it cati be etiemized thiough the storage material

The energized polymer can be placed on a user to pro\ ide an analgesic effect The energized polymer can be removed flora the storage material at n fuiuie to be placed on a user to prcuide an analgesic effect. The recommended use of the energized poKmer is to place the energi/ed polvmer direct!) on the users skin, and ptefeiabiv to place the energi/ed poij me? on the user's pam area

Although specific embodiments and methods of use have been illustrated and described herein, it will be appreciated by those of ordinary skill in {he an that any arrangement that is calculated to achieve the same purpose may be substituted for the specific embodiments and methods shown. It is to be understood that the abo\ c description is intended to be illustrative and not restnctiv e. Combinations of the abo\ e embodiments and other embodiments as well as combinations of the above methods of use and other methods of αsc will be apparent to those having skill in the art upon rev iew of the present disclosure The scope of the present invention should be determined with iefererice to the appended claims along with the full scope oi^" equivalents to which such claims are entitled.

Claims

CLAIMS 1 claim,

1 ) A method for creating ultrasound energized polymers, comprising the steps of" a) delivering ultrasonic waves to a polymer, and b) wherein the ultrasonic v\ a\ et> ha\ e an intensity capable of energizing a polymei

2) I he method according to claim 5. fuither comprising the steps of generating the ultiasonic waves with intensity capable of energizing a polymer

3) The method according to claim ! . wherein the ultrasound ftcqucncy is in the range of approximately 15 kHz approximately 40 MHz, 4) The method according to claim 1 , \\ herein the preferred low-frequency ultrasound range is approximately 20 kHz - approximately 40 kϊϊz

5) The method accoidmg to clasro 1 , wherein the preferred high-frequency ultrasound range s^<s approximately 1 MHz - approximately 5 MHz,

6) The method according to claim ! . wherein the recommended low-frequency ultrasound \ alue is approximately 30 kl I/.

7) Hie method according to claim 1. wherein the iecommended high-frequency ultrasound value is approximately 3 MBz,

S) The method according to clarm 1 , wherein the ultrasound amplitude is at least 1 mieton

^) I he method according to claim 1. w herein the preferred amplitude range for low-frequenc) ultrasound is approximately 50 microns - approximately b0 microns

IG) The method according to claim ! . wherein the preferred amplitude range for high-frequency ultrasound is approximately 3 microns approximately 10 microns.

11 ) f he Λ method according to claim 1, wherein the recommended amplitude \aiue for low- lϊequeney ultiasoimd is approximate!) 50 microns 12) The method accoiding to clarm 1 , wherein the recommend amplitude value for high- frequency ultrasound is approximately 3 microns. 13 } The method according to claim 1. wherein the ultrasound waves are delivered to a polymer through direct contact.

14) The method according to claim 1 , wherein the ultrasound waves are delivered io a polymer through a coupling medium. i 5} The method according to claim i , wherein the ultrasound waves are delhered to a polymer without contacting the polymer.

16 } The method according to claim 1. wherein the ultrasound \va\es are deiiveied to the polymer for at least of 0.1 seconds.

17) The method according to claim ! , wherein the recommended duration range to deliver low- frequency ultrasound waves is approximately 30 seconds to approximately 1 minute.

18} The method according to claim I .. wherein the recommended duration to deliver high- frequency ultrasound waves is approximately 3 minutes,

19} The method according to claim L wherein during delivery of the ultrasonic waves the polymer is placed on a base material such as a metal polymer, elastomer, ceramic, rubber, fabric, composite material, or any other material or any combination thereof

20} The method according to claim 1 , further comprising the step of storing the energized polymer such that the energy in said polymer does not wholly dissipate.

21) The method according to claim 20. wherein said storage means is a plastic bag. 22} The method according to claim 21, further comprising the step of sealing said plastic bag. 23} The method according to claim 20, wherein said storage means is a plastic sleeve.

24} The method according to claim 23, further comprising the step of sealing said plastic sleeve. 25) The method according to claim 20, wherein said storage means comprises: a) two pieces of film; and b) a means of tietachably adhering said films to said energized polymer; wherein one piece of said film is adhered by said means to one surface of said energized polymer and the other piece of said film is adhered by said means to the opposite surface of said energized, polymer. 2ό}Tne method according to claim 20, wherein said storage means comprises: a) two pieces of film; b) a means of detachably adhering one piece of said film to said energized polymer; and c) a means of permanently adhering one piece of said film to said energized polymer; wherein one piece of said film is permanently adhered by said means to one surface of said energized polymer and the other piece of said film is detachably adhered by said means to the opposite surface said energized polymer.

27} The method according to claim L wherein the polymer consists of a material such as crystalline polymer, amorphous polymer, polymer alloy, polymers approved for use in medical devices or food contact substances by ihe Federal Food and Drug Administration, or other polymers not currently approved,

28) The method according to claim 1 , wherein polymers move down a production line system to be directly energized by an ultrasound apparatus/system and then placed in a means of storage. 29) The method according to claim 1, wherein polymers move down a production line to be energized through a coupling medium by an ultrasound apparatus/system and then placed in a means of storage.

30) The method according to claim S . wherein polymers move down a production line to be energized by an ultrasound apparatus/system and then sealed in a means of storage by a separate apparatus/system.

31 ) The method according to claim ! , wherein polymers move down a production line to be energized and sealed in a means of storage by the same apparatus/system.

32) A method for pain relief using energized polymers, wherein the energized polymer is placed on a user to provide an analgesic effect, 33} The method according to claim 32, wherein the polymer is placed on the user's skin.

34} The method according to claim 32, wherein the polymer is placed on the user's pain area. 35} The method according to claim 32, wherein the polymer is placed on the user immediately after being energized.

36) The method according to claim 32, further comprising the step of removing said energized polymer from storage means before placing on a user. 37} The method according to claim 32, wherein the polymer is energized by ultrasound energy.

38) The method according to claim 32, wherein the polymer is energized by energy such as UV, microwave, laser, electricity, RF, son, light, magnetic electromagnetic, etc.

3^C) ) An apparatus for creating ultrasound energized polymers, comprising: a) an ultrasound apparatus'systeni for generating ultrasonic waves; b) wherein the apparatus/system delivers ultrasonic waves to a polymer; and c) wherein the ultrasonic waves have an intensity capable of energizing a polymer.

40) The apparatus according to claim 39. wherein the ultrasound apparatus-system generates the ultrasonic waves with particular ultrasound parameters indicative of an intensity capable of energizing the polymer. 41 } The apparatus according to claim 39, wherein the ultrasound frequency is in the range of approximately 15 kHz - approximately 40 MHz.

42) The apparatus according to claim 39, wherein the preferred low-frequency ultrasound range is approximately 20 kHz ^••• approximately 40 kHz.

43} The apparatus according to claim 39, wherein the preferred high- frequency ultrasound range is approximately 1 MlIz — approximately 5 MHz.

44 ) The apparatus according to claim 39, wherein the recommended low -frequency ultrasound value is approximately 30 kHz.

45) The apparatus according to claim 39, wherein the recommended high-frequency ultrasound value is approximately 3 MHz. 46) The apparatus according to claim 39, wherein the ultrasound amplitude is at least I micron.

47} The apparatus according to claim 3$, wherein the preferred amplitude range for low- frequency ultrasound is approximately 50 microns - approximately 60 microns. 48 > TKe apparatus according to claim 39, wherein the prefeired amplitude range lot high- frequency ultrasound is approximately 3 microns - approximately 10 microns

49) I he appaiatus according to claim 39. wherein the recommended amplitude value i^'oi low- frequency ultiasound is appioximaiel> 50 microtis. 50} The apparatus according to claim 5^CK wherein the recommend amplitude \ ahie for high- frequency ultrasound is approximately 3 miαυns

5 U The apparatus according to claim 39, fuithei comprising a means foi measuring the period of time during which ultrasonic waves are delivered to the polymer.

52) The apparatus according to claim 5 i, wherein said moans fot measuring time is a timer 53) The appaiatus according to claim 39. wherein ultrasonic waxes are delivered to the polymer for a duration of at least 0 I seconds.

54) I he apparatus according to claim 39, wherein the ultrasonic \va\es are delixered to a polymer through direct contact

55} The apparatus according to claim 39, wherein the υϊπasonic wax es are delixered to a polymer through a coitpl ing medium

56) The apparatus according to claim 39, wherein the ultrasonic waves are delivered to a poKiner w ithout contacting the pokmer.

57) The appaiatus accoidmg to claim 5^CK \s herein duiiπg deli\eiy of the ultrasonic xva\es the polymer is placed on a base material such as a metal, poix, raer. elastomer, ceramic, rubber. fabric, composite material, or any other materia! or any combination thereof.

58) The apparatus, according to claim 39, wherein the eneigϊzed polymei is placed m stoiage or sealed to be used at a later time.

59) I he appaiatus according to claim 39, further comprised of a means for storing the energi/ed poixmer such that the energ\ in said polymer does not xvholly dissipate. 60)Tlie apparatus according to claim 5*>, ^■wherein said stoiago means is a plastic bag

61 ) The apparatus according to claim 60, fuithei comprised of a means for sealing .said plastic batϊ 62} The. apparatus according to claim 59, wherein said stoiage means is a plastic slee\e

53 ) The apparatus according to claim 02, further comprised of a means for sealing said piastic sleeve

64) ^"I he apparatus according to claim 59. wherein said storage means comprises a) two pieces of film; and b} a means of detachabSy adhering said films to said energized polymer; wherein one piece of said film is adhered by said means to one surface of said energized polymer and the other piece of said film is adhered by said means to the opposite surface of said energized polymer, 65) The apparatus according to claim 59, wherein said storage means comprises' a) two pieces of film, b) a means of detachably adhering one piece υf said film to said energized pohπier, and c) a means of permanently adhering one piece of said film to said energized polymer: wherein one piece of said film is permanently adhered by said means to one surface of said enetgi/ed polymci and the other piece of said film is detachable adheied bv said means to the opposite surface said energized polymet

56 ) The apparatus according to claim 59, further comprising a means of sealing said storage means

67) I he appaiacυs according to claim 66, wherein the ultrasound apparatus both energizes the polymer and seals the polymer in storage.

68) The apparatus according to claim 39, w herein the transducer contains a radiation surface having a surface area dimensioned constructed for achie\ ing delh erv of the ultrasonic

\\ a\ es to a polymer with an intensity capable of energizing the pol>mer

69) The apparatus according to claim ^9, where the surface area of the distal end of the radiation surface is flat, p\. lanήdal, knurled, e\ lindricai. spiked, ruffled, grooved, or another comparable shape oi combination of shapes. 70} The apparatus according to claim 39, wherein the surface area of the radial side of die iadiation surface flat, ruffled, grooved, knmled, or another comparable shape or combination of shapes.

71 ) The apparatus according to claim 39, wherein the shape of the peripheral boundary of the radiation surface is intended to achieve delivery of the ultrasonic wa\ es to the polymer with an intensity capable energizing the polymer.

72) The apparatus according to claim 39, wherein the shape of the peripheral boundary of the radiation surface is circular, elliptical rectangular, polygonal, or another comparable shape or combination of shapes, 73} The apparatus according to claim 39, wherein the transducer is driven by a continuous or pulsed frequency.

74} The apparatus according to claim 39, wherein the transducer is dm en by a fixed or modulated frequency .

75) The apparatus according to claim 39, wherein the driving wave form of the transducer is selected from the group consisting of sinusoidal, rectangular, trapezoidal and triangular wave forms.

76) An energized polymer, comprising: a) a piece of polymer, and b) wherein the polymer has been energized through the deli\ er of energy to the polymer. 77 ) The energized polymer according to claim 76, further comprising a means of storing the energized polymer such thai the energy in said polymer does not wholly dissipate.

7S) The energized polymer according to claim 77, wherein said storage means is a plastic bag.

7^Q) The energized polymer according to claim 78, further comprising a means of sealing said plastic bag, SO) The energized polymer according to claim 77. wherein said storage means is a plastic siee\ e.

2 ! 8 U The energized polymer according to claim 80. further comprising a means of sealing said plastic sleeve,

82) The energized polymer according to claim 77, wherein said storage means comprises: a) two pieces of film; and b) a means of detaehahly adhering said films to said energized polymer. wherein one piece of said film is adhered by said means to one surface of said energized polymer and the other piece of said film is adhered by said means to the opposite surface of said energized polymer.

83 ) The energized polymer according to claim 77, wherein said storage means comprises; a) two pieces of film; b) a means of detachabiy adhering one piece of said film Io said energized polymer; and c) a means of permanently adhering one piece of said film to said energized polymer, wherein one piece of said film is permanently adhered by said means to one surface of said energized polymer and the other piece of said film is detachabiy adhered by said means to the opposite surface said energized polymer.

84} The energized polymer according to claim 77, further comprising a means of sealing said storage means.

85) The energized polymer according to claim 76, wherein the energy delivered the polymer is ultrasonic energy. 86) The energized polymer according to claim 76. wherein the energy delivered to the polymer is energy such as UV, microwave, laser, electricity, RF, sun, light, magnetic/electron-) agn eti t\ etc .

Bl) The energized polymer according to claim 85, wherein the polymer is energized by delivering ultrasound with a frequency range of approximately 15 kHz to approximately 40 MHz. 88} Hie energized polymer according to claim 85. wherem the polymer is energized b> de!i\ cring low-frequency ultrasound vv Uh a preferred ftcqucncs range of appioximately 20 kHz to approximately 40 kHz.

S^Q) I he energized polymer aceot cling to claim 85, wheiein the pohmer is energized by delivering high-frequency ultrasound with a pieferred frequency of range approximately !

MIi/ to approximately 5 Mi l/

90) The energized polymer according to claim 85, wherein the polymer is energized by deliv ering iow-frequenc> ultrasound w ifh a recommended frequency \ alue of approximately 30 kHz. 91 } The energized polymer according to claim 85. wherein the po1\ mer is energized by delivering h igh -frequency ultrasound with a recommended frequency value of approximately 3 MHz.

92) The energized polymer according to claim 85, wherein the polymer is energized by deliv ering ultrasound with an amplitude of at least 1 micron 93) The eneigi/ed polymer accoiding to claim SS, vvheidn the polymer is energi/ed by delivering low-frequency ultrasound with a preferred amplitude range of approximately 50 to appioλimately 60 microns

94) The energized polymer according to claim 85, wherein the polymer is energized by deliv ering high-frequency ultrasound with a preferred amplitude range of approximately 3 to approximately 1.0 microns

95) I he energized polymer according to claim 85, wherein the polsmer is energized by delivering low-frequency ultrasound with a recommended amplitude value of approximately 50 microns.

96) The energized polymer according to claim 85, wherein the polymer is energized by deiiv ering high-frequency ultrasound with a recommended amplitude \ alue of approximates) 3 microns

97) I lie energized polymer according to claim 85. wherein the pohmer is energized by delivering ultrasound wa\es to the polv mei while the poljmer is on a base material such as a metal, polymer, elastomer, ceramic, rubber, fabric, composite materials, or any other material or any combination thereof. The energized polymer according to claim 76, wherein the energized polymer can provide an analgesic elTect.