JPH01132875A - Method for imparting change to surface of cloth - Google Patents
Method for imparting change to surface of clothInfo
- Publication number
- JPH01132875A JPH01132875A JP29147787A JP29147787A JPH01132875A JP H01132875 A JPH01132875 A JP H01132875A JP 29147787 A JP29147787 A JP 29147787A JP 29147787 A JP29147787 A JP 29147787A JP H01132875 A JPH01132875 A JP H01132875A
- Authority
- JP
- Japan
- Prior art keywords
- fabric
- change
- gel
- hydrous
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims description 14
- 125000003010 ionic group Chemical group 0.000 claims abstract description 4
- 230000005611 electricity Effects 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 abstract description 5
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 abstract 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 abstract 1
- 229920002401 polyacrylamide Polymers 0.000 abstract 1
- 239000000017 hydrogel Substances 0.000 description 9
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- -1 softeners Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical group 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Decoration Of Textiles (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、イｉ帛の新規な表面変化骨【プ方法に関する
ものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a novel surface-altered bone removal method.
（従来の技術）
本発明にあける表面変化とは、しわ、しぼ等の表面の凹
凸をいう。従来、布帛に一種独特の風合と感触を与える
等のため、イ５帛に表面変化を付けることは、古くから
よく知られている。(Prior Art) The term "surface change" as used in the present invention refers to surface irregularities such as wrinkles and wrinkles. It has been well known for a long time to add surface changes to fabrics in order to give them a unique texture and feel.
その方法として、例えば、古川富三著「化繊糸イ■の基
礎知識」江南書院、１９５５年３月１９日発行１３５ペ
ージに記載されているような方法などがある。Examples of this method include the method described in Tomizo Furukawa, ``Basic Knowledge of Chemical Fiber Threads'', Konan Shoin, published March 19, 1955, page 135.
これら従来の表面変化骨は方法で得られた布帛はそれな
りに利用者を満足させてきた。The fabrics obtained by these conventional surface-change bone methods have satisfied users to a certain extent.
しかし、近年、利用者の好みが極めて多様化するに従い
、これら従来の方法による表面変化には飽きたらず、ざ
らに−風変わった表面変化とか、自然風の表面変化など
が求められる志向が強くなってぎた。However, in recent years, as the preferences of users have become extremely diverse, they are not tired of surface changes made using these conventional methods, and there is a strong desire for rough and unusual surface changes, natural-style surface changes, etc. It was getting worse.
（発明が解決しようとする問題点）
本発明者らは自然風の表面変化が求められる志向に鑑み
、布帛の従来にない自然風の変わった表面変化、例えば
極めてなだらかな曲線からなり、その曲率が曲線の部分
によって異なるような表面変化などを得る方法について
鋭意検討した結果、本発明に到達した。(Problems to be Solved by the Invention) In view of the desire to have a natural wind surface change, the present inventors have created a fabric with a natural wind surface change that has never been seen before, such as an extremely gentle curve, and its curvature. As a result of extensive research into methods for obtaining surface changes that vary depending on the portion of the curve, the present invention was arrived at.
（問題点を解決するための手段）
本発明は次の構成を有する。すなわち、布帛を、イオン
基を有する含水ゲルで処理した後、通電することを特徴
とする布帛の表面変化骨は方法である。(Means for solving the problems) The present invention has the following configuration. That is, the method for changing the surface of a fabric is characterized in that the fabric is treated with a hydrous gel having ionic groups and then electricity is applied.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
本発明におけるイオン基を有する含水ゲルとして公知の
ものが使用されてよい。例えば、２−アクリルアミド−
２−メチルプロパンスルホンｌ（ＡＭＰＳ）の重合体の
含水ゲル、アクリルアミド（ＡＡＭ＞の重合体の部分加
水分解物の含水ゲル、ＡＭＰＳとＡＡＭの共重合体の含
水グル、ポリメタクリル酸の含水グル等の負の電荷を有
するもの、部分四級化ポリビニルピリジン等の正の電荷
を有するもの、寒天等の天然高分子が挙げられるが、電
荷を有する含水高分子ゲルであればいずれのものでも使
用できる。Known hydrogels having ionic groups may be used in the present invention. For example, 2-acrylamide-
Hydrogel of polymer of 2-methylpropanesulfone (AMPS), hydrogel of partial hydrolyzate of polymer of acrylamide (AAM>), hydrogel of copolymer of AMPS and AAM, hydrogel of polymethacrylic acid, etc. Examples include those with a negative charge, those with a positive charge such as partially quaternized polyvinylpyridine, and natural polymers such as agar, but any hydrous polymer gel with a charge can be used. .
本発明における布帛としては、公知の布帛が使用される
。例えば、公知の繊維からなる編物、織物、不織布等が
使用される。布帛の目付は一般には小さい方が際立った
鋭い表面変化が付けやすい。As the fabric in the present invention, a known fabric is used. For example, knitted fabrics, woven fabrics, nonwoven fabrics, etc. made of known fibers may be used. In general, the smaller the fabric weight, the easier it is to create noticeable sharp surface changes.
布帛を含水ゲルで処理する方法としては、浸漬法、コー
ティング法、スプレ法、接着法等公知の手段が使用でき
る。As a method for treating the fabric with a hydrogel, known methods such as dipping, coating, spraying, adhesion, etc. can be used.
含水ゲルで処理した布帛に対する通電方法は公知の方法
で構わない。電源として乾電池、蓄電池、スタビライナ
ーを介した直流電源等が使用される。A known method may be used to apply electricity to the fabric treated with the hydrogel. As a power source, a dry battery, a storage battery, a DC power source via a stabilizer liner, etc. are used.
電圧は含水グルのサイズや望む収縮速度によって異なり
一概に言えない。The voltage varies depending on the size of the water-containing glue and the desired contraction speed, and cannot be determined with certainty.
通電による収縮以前から、収縮と同時に、収縮中以後に
含水ゲルの水分を公知の手段を使って乾燥除去する。乾
燥した含水ゲルの樹脂成分はそのままであっても、また
、後で除いても構わない。The water content of the hydrogel is removed by drying using a known method before, during, and after shrinkage due to energization. The resin component of the dried hydrogel may be left as is or may be removed later.
この通電による収縮を利用した表面変化付【）はプレス
による機械的な型付は等と異なり厳密に均一な表面変化
が得にくい。これが逆にイ「帛に自然風の表面変化を発
現させるものと考えられる。さらに、通電時に極の形や
配列を様々に変え得るので布帛に変わった表面変化を付
は得る。Unlike mechanical molding using a press, it is difficult to obtain a strictly uniform surface change with this method of surface modification using shrinkage caused by energization. This, in turn, is thought to cause the fabric to exhibit natural surface changes.Furthermore, the shape and arrangement of the poles can be changed in various ways when energized, resulting in unique surface changes to the fabric.
含水グルおよび布帛は染料や顔料等で着色されていても
、柔軟剤、防黴剤、帯電防止剤等の添加剤等で処理され
ていても何等差支えない。The water-containing glue and fabric may be colored with dyes or pigments, or may be treated with additives such as softeners, antifungal agents, and antistatic agents.
（実施例） 以下の実施例により本発明をさらに詳細に説明する。(Example) The invention will be explained in further detail by the following examples.
実施例 １
反応容器に分子１１２０００のポリオキシエチレングリ
コール４０部、トリメチロールプロパン５゜４部、イソ
ボロンジイソシアネート３５．５部を採り、９０℃で２
００時間反応せた俊タウリンの微粉末２．５部を添加し
８５〜９０’Ｃでさらに２４時間反応を続けた。得られ
たイソシアネート基末端のプレポリマの１００ｇと分散
剤としての゛エマルジット２５”（第−工業製桑社〉の
７ｇを容器に採り、ホモジナイザで充分に攪拌しつつ水
７３０ｇを添加し分散液を１ｑだ。分散液を手早く濾過
した後２分間静置した。次にジエヂレントリアミン２ｇ
、水１００９からなる溶液を加え（ポリウレタン液をつ
くった）だ後、手早く攪拌し、直ちに１０ｃｍｘ １０
ｃｍの織物（東し、シルツクＩＶ、品番Ｆ８７７０Ｇ＞
を浸漬した後引上げガーゼで余分の液を拭い去った。Example 1 40 parts of polyoxyethylene glycol with a molecular weight of 112,000, 5.4 parts of trimethylolpropane, and 35.5 parts of isoborone diisocyanate were placed in a reaction vessel, and the mixture was heated at 90°C for 2 hours.
2.5 parts of shuntaurine fine powder reacted for 00 hours was added, and the reaction was continued at 85 to 90'C for an additional 24 hours. 100 g of the obtained isocyanate group-terminated prepolymer and 7 g of "Emulgit 25" (Dai-Kogyo Seisakusha Co., Ltd.) as a dispersant were placed in a container, and while thoroughly stirring with a homogenizer, 730 g of water was added to make 1 q of the dispersion liquid. The dispersion was quickly filtered and left to stand for 2 minutes.Next, 2g of dielenetriamine was added.
After adding a solution consisting of water 1009 (to create a polyurethane solution), stir quickly and immediately make a 10 cm x 10
cm fabric (east, silk IV, product number F8770G>
After soaking, excess liquid was wiped off with pulled gauze.
このポリウレタン処理した織物を５ｍｍおきに陽陰に配
列した白金棒の上へフリーの状態にして置き、陽陰極間
に５０Ｖの電圧をかけた。１０分１変に通電を止め、電
子レンジと熱風乾燥器で水分を飛ばした。この織物は若
干堅くなるものの、その表面は極めてなだらかな曲線か
らなり、しかもその曲率が曲線の部分によって異なり、
人工的に付けたとは見えないでしわ調や、しぼ調とは思
えないうな表面に変化していた。また、変わったざらつ
いた感触をしていた。This polyurethane-treated fabric was placed in a free state on platinum rods arranged in positive and negative directions at intervals of 5 mm, and a voltage of 50 V was applied between the positive and negative electrodes. After 10 minutes, the power was turned off and the water was removed using a microwave oven and hot air dryer. Although this fabric is somewhat stiff, its surface is made up of extremely gentle curves, and the curvature varies depending on the curved part.
It didn't look like it was artificially applied, but the surface had changed to a wrinkled look, or a texture that didn't seem to be grainy. It also had a strange rough feel to it.
（発明の効果）
本発明の方法により、従来にない変わった表面変化、例
えば、表面は極めてなだらかな曲線からなり、しかもそ
の曲率が曲線の部分によって異なって、しわ調や、しぼ
調とは思えないうな変化を有する布帛が得られる。電極
の形ヤ）配列を適当に選択することにより、ざらにより
変化に冨む形を右する表面の布帛が１ｑられる。(Effects of the Invention) By the method of the present invention, unusual surface changes not seen before, for example, the surface consists of an extremely gentle curve, and the curvature differs depending on the curved portion, making it difficult to imagine that it is wrinkled or wrinkled. A fabric having such changes is obtained. By appropriately selecting the shape and arrangement of the electrodes, a surface fabric with a shape that can vary widely depending on the roughness can be obtained.
Claims (1)
、通電することを特徴とする布帛の表面変化付け方法。(1) A method for changing the surface of a fabric, which comprises treating the fabric with a hydrous gel having ionic groups and then applying electricity.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29147787A JPH01132875A (en) | 1987-11-18 | 1987-11-18 | Method for imparting change to surface of cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29147787A JPH01132875A (en) | 1987-11-18 | 1987-11-18 | Method for imparting change to surface of cloth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01132875A true JPH01132875A (en) | 1989-05-25 |
Family
ID=17769381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29147787A Pending JPH01132875A (en) | 1987-11-18 | 1987-11-18 | Method for imparting change to surface of cloth |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01132875A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007127603A3 (en) * | 2006-04-24 | 2008-10-30 | Eilaz Babaev | Apparatus and methods for pain relief using ultrasound energized polymers |
-
1987
- 1987-11-18 JP JP29147787A patent/JPH01132875A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007127603A3 (en) * | 2006-04-24 | 2008-10-30 | Eilaz Babaev | Apparatus and methods for pain relief using ultrasound energized polymers |
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