WO2007118747A1 - Détergent aqueux contenant du parfum - Google Patents

Détergent aqueux contenant du parfum Download PDF

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Publication number
WO2007118747A1
WO2007118747A1 PCT/EP2007/052608 EP2007052608W WO2007118747A1 WO 2007118747 A1 WO2007118747 A1 WO 2007118747A1 EP 2007052608 W EP2007052608 W EP 2007052608W WO 2007118747 A1 WO2007118747 A1 WO 2007118747A1
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WIPO (PCT)
Prior art keywords
composition according
alkyl
oil
disodium
ether
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Application number
PCT/EP2007/052608
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German (de)
English (en)
Inventor
Detlef Buisker
Heinz-Dieter Soldanski
Christian Nitsch
Original Assignee
Henkel Ag & Co. Kgaa
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Publication of WO2007118747A1 publication Critical patent/WO2007118747A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Definitions

  • the invention relates to a surfactant-containing foamable aqueous agent containing perfume oil and 5 to 35 wt .-% organic solvent, a product of this agent and a foam dispenser and the use of this agent for cleaning hard surfaces, for manual dishwashing, for the pretreatment of textiles and for carpet cleaning and hard surface cleaning methods, for manual dishwashing, textile pretreatment and carpet cleaning using this agent.
  • Surfactant-containing compositions are usually provided with a fragrance, on the one hand to mask the sometimes unpleasant odor of the ingredients and on the other hand, to give the product a pleasant "pure" fragrance.
  • the funds have only a limited absorption or dissolving power for perfume oils Increasing the amount of perfume oil leads to undesired product clouding, and accordingly dosing is often mediated with a weak fragrance impression, especially when the agent is foamed.
  • a surfactant-containing agent in the form of a foam.
  • the foam height is considered by the consumer as an essential feature of a particularly good effectiveness; The consumer usually sees the foam as the effective part of the rinse liquor.
  • a foam is classified by the consumer as particularly powerful, especially as it is often perceived on vertical surfaces as longer adherent. But also carpet cleaners or textile pretreatment in the form of a foam are appreciated by the consumer. It is therefore advantageous if such surfactant-containing agents are donated directly as foam.
  • One difficulty that arises when a surfactant-containing agent is used as a foam and should therefore be foamed with a suitable device is the often too high viscosity of the agent, which is mainly caused by the high surfactant content. This often prevents the formation of foam in commercially available pump foam dispensers, but the use of propellant-filled aerosol cans is not always possible or desirable. However, direct foaming is desirable especially for hand dishwashing detergents. In common pump foam dispensers, the incoming air in the mixing chamber is swirled with the detergent sucked in through the riser, so that a foam is formed. The turbulence and thus the foaming is deteriorated or even prevented at too high viscosities. In addition, the promotion of the agent at higher viscosities is difficult.
  • the object of the present invention was therefore to formulate a surfactant-containing agent which imparts increased perfume oil absorption capacity and thus a stronger fragrance impression and at the same time can be dosed as foam.
  • the subject of the application is therefore a surfactant-containing foamable aqueous agent containing perfume oil and 5 to 35 wt .-% water-miscible organic solvent.
  • the agent according to the invention is particularly suitable for use in a foam dispenser.
  • a further subject of this application is therefore a product comprising an agent according to the invention and a foam dispenser.
  • fatty acids or fatty alcohols or their derivatives - unless otherwise stated - representative of branched or unbranched carboxylic acids or alcohols or their derivatives having preferably 6 to 22 carbon atoms.
  • the former are particularly preferred for their vegetable base as based on renewable raw materials for environmental reasons, but without limiting the teaching of the invention to them.
  • the oxo alcohols or their derivatives which are obtainable, for example, by the RoELEN's oxo synthesis, can also be used correspondingly.
  • alkaline earth metals are mentioned as counter ions for monovalent anions, this means that the alkaline earth metal, of course, only in the half - sufficient for charge balance - amount of substance as the anion is present.
  • the indication CAS means that the following sequence of numbers is a name of the Chemical Abstracts Service.
  • composition of the invention contains surfactants in a total amount of usually 12 to 70 wt .-%, preferably 15 to 55 wt .-%, in particular 17 to 45 wt .-%.
  • composition according to the invention in particular for improving cleaning action, flow behavior and / or drying behavior, may additionally comprise one or more further anionic surfactants, amphoteric surfactants, nonionic surfactants and / or cationic surfactants.
  • alkyl ether sulfates and alkyl sulfonates and the other anionic surfactants are usually used as alkali metal, alkaline earth metal and / or mono-, di- or Trialkanolammoniumsalz and / or in the form of their with the corresponding alkali metal hydroxide, alkaline earth metal hydroxide and / or mono-, di- or trialkanolamine used in situ to be neutralized corresponding acid.
  • Particularly preferred are the sodium salts.
  • Alkyl ether sulfates are products of sulfation reactions on alkoxylated alcohols.
  • alkoxylated alcohols the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, in the context of the present invention preferably with longer-chain alcohols, ie with aliphatic straight-chain or mono- or poly-branched, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably straight-chain, acyclic, saturated, alcohols having 6 to 22, preferably 8 to 18, in particular 10 to 16 and particularly preferably 12 to 14 carbon atoms.
  • Another embodiment of the alkoxylation is the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide.
  • Very particularly preferred for the purposes of the present invention are lower ethoxylated fatty alcohols having 1 to 4 ethylene oxide units (EO), in particular 1 to 2 EO, for example 2 EO, such as Na-C 12 -i 4 -fatty alcohol + 2EO sulfate.
  • the composition according to the invention contains one or more alkyl ether sulfates in an amount of 10 to 40% by weight, preferably 12 to 35% by weight.
  • the alkyl sulfonates usually have an aliphatic straight-chain or mono- or poly-branched, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably branched, acyclic, saturated, alkyl radical having 6 to 22, preferably 9 to 20, in particular 11 to 18 and particularly preferably 13 to 17 carbon atoms.
  • suitable alkyl sulfonates are the saturated alkanesulfonates, the unsaturated olefin sulfonates and the ether sulfonates which are derived formally from the alkyl ether sulfates on which the alkoxylated alcohols are based, in which terminal ether sulfonates (n-ether sulfonates) having a sulfonate function bonded to the polyether chain and internal ether sulfonates (i-ether sulfonates) with sulfonate function linked to the alkyl radical.
  • terminal ether sulfonates n-ether sulfonates
  • i-ether sulfonates internal ether sulfonates
  • alkanesulfonates in particular alkanesulfonates having a branched, preferably secondary, alkyl radical, for example the secondary alkanesulfonate sec. Na-C 13 . 17- alkanesulfonate (INCI Sodium C14-17 alkyl lake sulfonates).
  • the agent according to the invention contains one or more sec. Alkyl sulfonates in an amount of usually 1 to 20 wt .-%, preferably 3 to 12 wt .-%, in particular 4 to 8 wt .-%.
  • Suitable betaines are the alkylbetaines, the alkylamidobetaines, the imidazolinium betaines, the sulfobetaines (INCI Sultaines) and the phosphobetaines and preferably satisfy formula I, R 1 _ [CO-X- (CH 2 ) n ] x -N + (R 2 ) (R 3 ) - (CH 2 ) m - [CH (OH) -CH 2 ] y -Y- (I)
  • R is a saturated or unsaturated C 1 6-22 -alkyl, C -i preferably 8 8 -alkyl radical, in particular a saturated Ci -i O 6 alkyl radical, for example a saturated
  • X is NH, NR 4 having the C 1-4 -alkyl radical R 4 , O or S, n is a number from 1 to 10, preferably 2 to 5, in particular 3, x 0 or 1, preferably 1,
  • R 2, R 3 independently represent a CI_ 4 alkyl optionally hydroxysubstituted, such as a
  • m is a number from 1 to 4, in particular 1, 2 or 3, y 0 or 1 and
  • Y is COO, SO 3 , OPO (OR 5 ) O or P (O) (OR 5 ) O, where R 5 is a hydrogen atom H or a C 1-6 -alkyl radical.
  • Preferred betaines are the alkylbetaines of the formula (Ia), the alkylamidobetaines of the formula (Ib), the sulfobetaines of the formula (Ic) and the amidosulfobetaines of the formula (Id),
  • R 1 is -N + (CH 3 ) 2 -CH 2 CH (OH) CH 2 SO 3 " (Ic)
  • R 1 has the same meaning as in formula I.
  • betaines are the carbo-betaines, in particular the carbo-betaines of the formula (Ia) and (Ib), most preferably the alkylamido-betaines of the formula (Ib).
  • betaines and sulfobetaines are the following compounds designated as INCI: almondamidopropyl betaines, apricotamidopropyl betaines, avocadamidopropyl betaines, babassuamidopropyl betaines, behenamidopropyl betaines, behenyl betaines, betaines, canolamidopropyl betaines, caprylic / capramidopropyl betaines, carnitines, cetyl betaines, cocamidoethyl betaines, cocamidopropyl Betaines, cocamidopropyl hydroxysultaines, coco-betaines, coco-hydroxysultaines, coco / oleamidopropyl betaines, coco-sultaines, decyl betaines, dihydroxyethyl oleyl glycinates, dihydroxyethyl soy glycinates, dihydroxyethyl
  • the agent of the invention contains one or more betaines in an amount of usually 1 to 15 wt .-%, preferably 3 to 10 wt .-%, in particular 4 to 8 wt .-%.
  • the surfactants a) alkyl ether sulfate, b) secondary alkanesulfonate and c) betaine contained in the agent according to the invention are preferably present in a ratio a): b): c) of 5: 2: 1 to 2: 1: 1.
  • the water content of the aqueous composition according to the invention is usually 15 to 83 wt .-%, preferably 20 to 80 wt .-%, in particular 30 to 75 wt .-%.
  • the agent according to the invention may advantageously additionally comprise one or more water-soluble organic solvents, usually in an amount of 5 to 35% by weight, preferably 7 to 25% by weight, in particular 8 to 20% by weight.
  • the solvent is used in the context of the teaching of the invention as needed in particular as a hydrotrope and viscosity regulator. It acts solubilizing in particular for surfactants and electrolyte as well as perfume and dye and thus contributes to their incorporation, prevents the formation of liquid-crystalline phases and has a share in the formation of clear products.
  • the viscosity of the agent according to the invention decreases with increasing amount of solvent. Finally, as the amount of solvent increases, the clouding and clearing point of the composition according to the invention decreases.
  • Suitable solvents are for example, saturated or unsaturated, preferably saturated, branched or unbranched C ⁇ o-hydrocarbons, preferably C 2 -i 5 -Kohlen- hydrogens with at least one hydroxy group and optionally one or more ether functions COC, the carbon atom chain that is interrupting oxygen atoms.
  • Preferred solvents are the - optionally unilaterally etherified with a d- 6 -alkanol - C 2 - 6 alkylene glycols and poly-C 2 - 3 -alkylene glycol ethers having an average of 1 to 9 identical or different, preferably identical, alkylene glycol groups per molecule as well as the C - ⁇ _ 6 alcohols, preferably ethanol, n-propanol or iso-propanol, especially ethanol.
  • Exemplary solvents are the following according to INCI compounds: alcohol (ethanol), buteth-3, butoxy diglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, n-butyl alcohol, t-butyl alcohol, butylene glycol, butyloctanol, diethylene glycol, dimethoxy diglycol, dimethyl Ethers, dipropylene glycol, ethoxydiglycol, ethoxyethanol, ethyl hexanediol, glycol, hexanediol, 1, 2,6-hexanetriol, hexyl alcohol, hexylene glycol, isobutoxypropanol, isopentyldiol, isopropyl alcohol (isopropanol), 3-methoxybutanol, methoxydiglycol, methoxyethanol, Methoxyisopropanol, Methoxymethylbutanol, Methoxy PEG-10, Methy
  • longer-chain polyalkylene glycols in particular polypropylene glycols, such as PPG-400 or PPG-450.
  • the solvent is selected from the group comprising methanol, ethanol, propanol, isopropanol, ethylene glycol, phenoxyethanol, propylene glycol, PPG and mixtures thereof.
  • Extremely preferred solvents are the C 2 - 3 alcohols ethanol, n-propanol and / or iso-propanol, especially ethanol, and the polyalkylene glycols, especially polypropylene glycols, in particular the PPG-400.
  • solubilizer in particular for perfume and dyes, for example, alkanolamines and alkylbenzenesulfonates having 1 to 3 carbon atoms in the alkyl radical can be used in addition to the solvents described above.
  • the flash point of the agent may be 40 ° C or below; preferred embodiments have flame points of 30 0 C to 35 ° C. Due to the high water content at the same time, however, they represent no danger if the product is used properly. perfume oil
  • the agent according to the invention also contains a perfume oil.
  • perfume oil is meant preferably self-contained perfume compositions which are commonly used for product scenting and are fragrant in particular at the human discretion. It is usually a collective (well) smelling substances. Such a collective usually consists of a plurality of individual fragrances, e.g. more than 10 or 15, preferably up to 100 or more. These fragrances cooperatively form a desired fragrant, harmonious odor image.
  • a fragrance composition which may possibly also contain perfume-like auxiliaries, is described according to the invention with the term perfume oil.
  • self-contained should clarify that the constituents of a perfume oil are usually not separated from each other, so not perceived side by side, but form a common, uniform scent collective.
  • a perfume oil used according to the invention may consist of only a single perfume, which is extremely unusual and unlikely.
  • an inventively used perfume oil ie, a perfume composition
  • at least 2, preferably at least 3, advantageously at least 4 different fragrances which together unfold a preferably fragrant odor image.
  • a perfume oil used according to the invention can therefore contain individual perfume compounds, e.g. containing the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons. Fragrance compounds of the ester type are known e.g.
  • the ethers include, for example, benzyl ethyl ether and ambroxane, to the aldehydes e.g.
  • the linear alkanals of 8 - 18 C atoms citral, citronellal, citronellyloxy-acetaldehyde, cyclamen aldehyde, lilial and bourgeonal, to the ketones e.g. the ionones, ⁇ -lsomethylionone and methylcedryl ketone, the alcohols anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and terpineol, the hydrocarbons mainly include the terpenes such as limonene and pinene.
  • mixtures of different fragrances are used, which together produce an attractive fragrance of the perfume oil formed.
  • the perfume oils can also contain natural fragrance mixtures, such as those available from plant sources, eg pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are Muskateller sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, Cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil, and orange blossom oil, neroliol, orange peel oil and sandalwood oil.
  • natural fragrance mixtures such as those available from plant sources, eg pine, citrus, jasmine, patchouly, rose or ylang-ylang oil.
  • a fragrance In order to be perceptible, a fragrance must be volatile, with molecular weight also playing an important role in addition to the nature of the functional groups and the structure of the chemical compound. For example, most odorants have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and above are more of an exception. Due to the different volatility of fragrances, the smell of a fragrance composed of several fragrances changes during evaporation, whereby the odor impressions in "top note”, “middle note or body” and “base note “(end note or dry out) divided.
  • Adhesion-resistant fragrances which are advantageously usable in the perfume oils in the context of the present invention are, for example, the essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, Bay oil, Champacablütenöl, Edeltannenöl, Edeltannenzapfen oil, Elemiöl, Eucalyptusöl, Fennelöl, Fichtennandelöl, Galbanumöl, Geranium oil, Ginger grass oil, Guaiac wood oil, Gurjun balm oil, Helichrysum oil, Ho oil, ginger oil, iris oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanga oil, cardamom oil, cassia oil, pine needle oil, copa ⁇ va balsam oil, coriander oil, spearmint oil, caraway oil, cumin oil, lemongrass oil, musk kernel oil, myrrh oil, Clove oil, Neroliol, Niaouli oil, Olibanum oil, Or
  • fragrances of natural or synthetic origin can be used in the context of the present invention advantageously as adherent fragrances or fragrance mixtures in the perfume oils.
  • These compounds include the following compounds and mixtures thereof: ambrettolide, ⁇ -amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, borneol, bornyl acetate, ⁇ -bromostyrene, n -Decylaldehyde, n-dodecyl-aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, gerany
  • the lower-boiling fragrances include natural or synthetic origin, which can be used alone or in mixtures.
  • Examples of more volatile fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.
  • fragrances can be used alone or as a mixture in the perfume oils which can be used according to the invention with the advantages already mentioned.
  • fragrances from the group of allyl alcohol esters, esters of secondary alcohols, esters of tertiary alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof may also be present in the perfume oil.
  • Allylalkohlester are in particular allyl amyl glycolate, Allylanthranilat, Al lylbenzoat, hexanbutyrat allyl butyrate, Allylcaprat, allyl caproate, allyl cinnamate, Allylcyclohexanacetat, Allylcyclo-, Allylcyclohexanpropionat, allyl heptoate, Allylnonanoat, Allylsalicylat, Amylcinnamyl- acetate, Amylcinnamylformiat, Cinnamylformiate, Cinnamylacetate, cyclogalbanate, geranyl acetate, Geranylacetoacetat , geranyl benzoate, Geranylcinnamat, Methallylbutyrat, Methallylcapro
  • Allyl alcohol esters may preferably be present in the perfume oil which can be used according to the invention.
  • esters of Secondary Alcohols are, in particular, ortho-tert-amylcyclohexyl acetate, isoamylbenzylacetate, secondary n-amylbutyrate, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, cyclohexylsalicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionate, isobornylacetate, isobornylsalicylate, isobornylvalerate , Frutene, 2-methylbutene-2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan
  • esters of tertiary alcohols are those in which three H atoms are substituted by organic radicals R 1 , R 2 , R 3 at the ⁇ -C atom which carries the OH group (general formula: R 1 R 2 R 3 C-OH)) are tertiary amyl acetate, Caryophylleneacetat, Cedrenyl acetate, Cedrylacetat, Dihydromyrcenylacetat, Dihydroterpinylacetat, dimethylbenzyl carbinyl acetate, Dimethylbenzylcarbinylisobutyrat, Dimethylheptenylacetat, Dimethylheptenyl formate, Dimethylheptenylpropionat, Dimethylheptenyl iso-butyrate, Dimethylphenylethylcarbinylacetat, Dimethylphenylethylcarbinyl iso butyrate, dimethylphenylethylcarbinylacetat, Dimethylphenylethyl
  • fragrance esters may be both esters of allylic and secondary or allylic and tertiary alcohols, such as, in particular, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, hexylvinylcarbinylacetate, 3-nonenylacetate, 4-hydroxy-2-hexenylacetate, linallylanthranilate, linallylbenzoate, linallylbutyrate, linallyliosbutyrate, linallyl carproat, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Linallylformat, Linallylheptoat, Linallyl N-methylanthranilate, Linallylmethyltiglat, Linallylpelargonat, Linallylphenylacetat, Linallylpropionat, Linallylpyruvat, Linallylsalicylat, Linallyl-n-valerate, Linallyl-iso- valerate,
  • Preferred examples are acetylfuran, allethrolone, allylionone, allylpulegone, amylcyclopentenone, benzylidenetetone, benzylideneacetophenone, alphaisomethylionone, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) 3-buten-2-one, beta damascone (1- (2,6,6-trimethylcyclohexen-1-yl) -2-buten-1-one), damascenone (1-
  • Acetals are geminal diethers of the general formula R 1 CH (OR 2 ) (OR 3 ).
  • Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-di-iso-amyl acetal, acetaldehyde di-pentanediol acetal, acetaldehyde di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal , Acetaldehyde phenylethyl-n-propyl acetal,
  • Ketals are geminal diethers of the general formula R 1 R 2 C (OR 3 ) (OR 4 ). Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals may preferably be present in the perfume oil which can be used according to the invention.
  • condensation products of amines and aldehydes are anisaldehyde methylanthranilate, aurantiol (hydroxycitronellalmethyl anthranilate), verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehyde-methyl anthranilate), vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde),
  • fragrances such as, for example, adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, anisaldehyde (4-methoxy-benzaldehydes), bacdanol (2-ethyl-4- (2, 2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexene-1-ol, (-) - ambrox (Cetalox ®, dodecahydro -3A, 6,6,9A-tetramethylnaphtho [2,1 B] -furan), cis-3-hexenylacetate, cis-3-hexenylsalicylate, citronellol, coumarin, cyclohexylsalicylate, cymal (2-methyl-3- (para
  • the perfume oil is present in amounts of from 0.1 to 6% by weight, preferably from 0.15 to 4% by weight, more preferably from 0.2 to 2% by weight, in the composition according to the invention.
  • the agent according to the invention preferably also contains one or more water-soluble salts. It may be inorganic and / or organic salts, in a preferred embodiment, the agent contains at least one inorganic salt.
  • Inorganic salts which can be used according to the invention are preferably selected from the group consisting of colorless water-soluble halides, sulfates, sulfites, carbonates, hydrogen carbonates, nitrates, nitrites, phosphates and / or oxides of the alkali metals, alkaline earth metals, aluminum and / or transition metals; Furthermore, ammonium salts can be used. Particularly preferred are halides and sulfates of the alkali metals; Preferably, therefore, the inorganic salt is selected from the group comprising sodium chloride, potassium chloride, sodium sulfate, potassium sulfate and mixtures thereof.
  • the organic salts which can be used according to the invention are, in particular, colorless water-soluble alkali metal, alkaline earth metal, ammonium, aluminum and / or transition metal salts of the carboxylic acids.
  • the salts are selected from the group comprising formate, acetate, propionate, citrate, malate, tartrate, succinate, malonate, oxalate, lactate and mixtures thereof.
  • the cleaning agent according to the invention contains in a preferred embodiment 1 to 20 wt .-%, preferably 1, 5 to 15 wt .-%, particularly preferably 2 to 10 wt .-% of at least one water-soluble inorganic and / or 1 to 20 wt .-% , preferably 1, 5 to 10 wt .-%, particularly preferably 0.5 to 7 wt .-%, in particular 0.8 to 5 wt .-% of at least one water-soluble organic salt.
  • the water-soluble salt is used to set a lower viscosity in hard surface cleaners having a high surfactant concentration, especially a high alkyl ether sulfate concentration.
  • a high surfactant concentration especially a high alkyl ether sulfate concentration.
  • one or more water-soluble salts are accordingly added to the compositions.
  • compositions according to the invention may contain further ingredients.
  • these include, for example, other surfactants, additives for improving the drainage and drying behavior, for adjusting the viscosity, for stabilization and other customary in manual dishwashing detergents and additives, such as hydrotropes, UV stabilizers, pearlescing agents, dyes, corrosion inhibitors, preservatives, organic salts, Disinfectants, enzymes, pH adjusters and skin feel-improving or nourishing additives.
  • composition of the invention may additionally comprise one or more other anionic surfactants, usually in an amount of 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, more preferably 0.5 to 1, 5 wt .-%, for example, 1 wt .-%.
  • anionic surfactants usually in an amount of 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, more preferably 0.5 to 1, 5 wt .-%, for example, 1 wt .-%.
  • Suitable further anionic surfactants are, in particular, aliphatic sulfates such as fatty alcohol sulfates, monoglyceride sulfates and ester sulfonates (sulfo fatty acid esters), lignosulfonates, alkylbenzenesulfonates, fatty acid cyanamides, anionic sulfosuccinic acid surfactants, fatty acid isethionates, acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ethecarboxylic acids and alkyl (ether) phosphates.
  • aliphatic sulfates such as fatty alcohol sulfates, monoglyceride sulfates and ester sulfonates (sulfo fatty acid esters), lignosulfonates, alkylbenzenesulfonates, fatty acid cyanamides, anionic sulf
  • Suitable further anionic surfactants are also anionic gemini surfactants having a diphenyl oxide basic structure, 2 sulfonate groups and one alkyl radical on one or both benzo rings according to the formula O 3 S (C 6 H 3 R) O (C 6 H 3 R ') SO 3 ⁇ , in which R is an alkyl radical having, for example, 6, 10, 12 or 16 carbon atoms and R 'is R or H (Dowfax ® Dry hydrotropes stands Powder with C 16 alkyl radical (s); INCI Sodium Hexyldiphenyl ether sulfonates, Disodium decyl phenyl ether disulfonates, Disodium lauryl phenyl ether disulfonates, Disodium Cetyl phenyl ether disulfonates) and fluorinated anionic surfactants, in particular perfluorinated alkylsulfonates such as ammonium Cg / io-Perfluoroalkyl
  • Particularly preferred further anionic surfactants are the anionic sulfosuccinic acid surfactants sulfosuccinates, sulfosuccinamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates.
  • the sulfosuccinates are the salts of the monoesters and diesters of sulfosuccinic acid HOOCCH (SO 3 H) CH 2 COOH, while the sulfosuccinamates are the salts of the monoamides of sulfosuccinic acid and the sulfosuccinamides are the salts of the diamides of sulfosuccinic acid.
  • a detailed description of these known anionic surfactants is provided by A. Domsch and B.
  • the salts are preferably alkali metal salts, ammonium salts and mono-, di- or trialkanolammonium salts, for example mono-, di- or triethanolammonium salts, in particular lithium, sodium, potassium or ammonium salts, particularly preferably sodium or ammonium salts , most preferably sodium salts.
  • one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified.
  • esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4.
  • the monoesters are preferred in the context of the present invention over the diesters.
  • a particularly preferred sulfosuccinate is Sulfobernsteinklarylpolyglykolester- di-sodium salt (EO lauryl sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), for example, as Tego ® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate of 30 parts by weight % is commercially available.
  • one or both carboxyl groups of the sulfosuccinic acid forms preferably with a primary or secondary amine having one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals with 4 to 22, preferably 6 to 20, in particular 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms carries, a carboxylic acid amide.
  • Particular preference is given to unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.
  • sulfosuccinates and sulfosuccinamates designated according to INCI: ammonium dinonyl sulfosuccinates, ammonium lauryl sulfosuccinates, diammonium dimethicone copolyol sulfosuccinates, diammonium lauramido-MEA sulfosuccinates, diammonium lauryl sulfosuccinates, diammonium oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Dioctyl
  • Preferred anionic sulfosuccinic are imidosuccinate, mono-Na-sulfosuccinic acid diisobutyl ester (Monawet MB ® 45), mono-Na-sulfosuccinic acid di-octyl ester (Monawet MO-84 ® R2W, Rewopol SB ® DO 75), mono- Na-sulfosuccinic acid di-tridecyl (Monawet ® MT 70) Fettalkoholpolyglykolsulfosuccinat-Na-NHU salt (sulfosuccinate S-2), di-sodium sulfosuccinic acid mono-Ci 2 / i 4 3EO ester (Texapon ® SB 3), Natruimsulfobernsteinkland (Texin ® DOS 75) and di-Na-sulfosuccinic mono-C- 12
  • the agent according to the invention contains as anionic sulfosuccinic acid surfactants one or more sulfosuccinates, sulfosuccinamates and / or sulfosuccinamides, preferably sulfosuccinates and / or sulfosuccinamates, in particular sulfosuccinates, in an amount of usually 0.001 to 5% by weight, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt .-%.
  • anionic sulfosuccinic acid surfactants one or more sulfosuccinates, sulfosuccinamates and / or sulfosuccinamides, preferably sulfosuccinates and / or
  • amphoteric surfactants are amphoteric surfactants.
  • amphoteric surfactants (amphoteric surfactants, zwitterionic surfactants) which can be used according to the invention include alkylamidoalkylamines, alkyl-substituted aminoacids, acylated
  • alkylamidoalkylamines are amphoteric surfactants of the formula (III)
  • R 9 is a saturated or unsaturated C 6-22 alkyl radical, C 8 -i 8 -alkyl radical, preferably a saturated C 10 -i 6 is preferably alkyl group, for example a saturated
  • R 10 is a hydrogen atom H or a C 1-4 -alkyl radical, preferably H, i is a number from 1 to 10, preferably 2 to 5, in particular 2 or 3,
  • R 11 is a hydrogen atom H or CH 2 COOM (to M su), j is a number from 1 to 4, preferably 1 or 2, in particular 1, k is a number from 0 to 4, preferably 0 or 1,
  • Z is CO, SO 2 , OPO (OR 12 ) or P (O) (OR 12 ), wherein R 12 is a d_ 4 alkyl radical or M (su), and M is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanol - Amine, for example protonated mono-, di- or triethanolamine, is.
  • R 11 and M have the same meaning as in formula (Ml).
  • alkylamidoalkylamines are the following named according to INCI compounds: Cocoamphodipropionic Acid, Cocobetainamido amphopropionates, DEA-Cocoamphodipropionate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Cocoamphocarboxy- ethylhydroxypropylsulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Isostearoamphodiacetate, Disodium Isostearoamphodipropionate, Disodium Laureth-5 Carboxyamphodiacetate, Disodium Lauroamphodiacetate, Disodium Lauroamphodipropionate, Disodium Oleoamphodipropionate, PPG-2-Isodeceth-7 Disodium Carboxya
  • Ricinoleoamphoacetate Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Tallamphopropionate, Sodium Tallow Amphoacetate, Sodium Undecylenoamphoacetate, Sodium Undecylenoamphopropionate, Sodium Wheat Germamphoacetate and Trisodium Lauroampho PG Acetate Chloride Phosphate.
  • Preferred alkyl-substituted amino acids are monoalkyl-substituted amino acids according to formula (IV),
  • R 13 is a saturated or unsaturated C 6-22 -alkyl radical, preferably C 8 -i 8 -alkyl radical, in particular a saturated Ci -i O 6 alkyl radical, for example a saturated C 12 -i 4 alkyl radical,
  • R 14 is a hydrogen atom H or a preferably H, u is a number from 0 to 4, preferably 0 or 1, in particular 1, and
  • M ' is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, e.g. protonated mono-, di- or triethanolamine,
  • R is a saturated or unsaturated C 15 6-22 alkyl, C -i preferably 8 8 -alkyl radical, in particular a saturated Ci -i O 6 alkyl radical, for example a saturated C 2 - 14 alkyl group, v is a number from 1 to 5, preferably 2 or 3, in particular 2, and
  • M is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine, where M" in the two
  • Carboxy groups may have the same or two different meanings, for example, hydrogen and sodium or may be twice sodium, is
  • R is a saturated or unsaturated C 16 6-22 alkyl, C 8 -i 8 -alkyl radical, preferably a saturated C 10 -i 6 is preferably alkyl group, for example a saturated
  • R 17 is a hydrogen atom or a C 1-4 -alkyl radical, optionally hydroxy- or amine-substituted, for example a methyl, ethyl, hydroxyethyl or aminopropyl radical
  • R 18 is the radical of one of the 20 natural .alpha.-amino acids H 2 NCH (R 18 ) COOH
  • M '" is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine.
  • alkyl-substituted amino acids are the aminopropionates according to formula (IVa),
  • alkyl-substituted amino acids are the following compounds designated according to INCI: aminopropyl laurylglutamines, cocaminobutyric acid, cocaminopropionic acid, DEA-lauraminopropionates, disodium cocaminopropyl iminodiacetates, disodium dicarboxyethyl coco-propylenediamines, disodium lauriminodipropionates, disodium steariminodipropionates, disodium tallowiminodipropionates, lauraminopropionic acid, Lauryl Aminopropylglycines, Lauryl Diethylenediaminoglycines, Myristaminopropionic Acid, Sodium C12-15 Alkoxypropyl Iminodipropionates, Sodium Cocaminopropionate, Sodium Lauraminopropionate, Sodium Lauriminodipropionate, Sodium Lauroyl Methylamin
  • Acylated amino acids are amino acids, in particular the 20 natural ⁇ -amino acids, which carry 19 COOH at the amino nitrogen is the acyl radical R 19 CO of a saturated or unsaturated fatty acid R, where R 19 is a saturated or unsaturated C 6-22 -alkyl radical, preferably C 8 -i 8 alkyl, in particular a saturated C 10 -i 6 alkyl, for example, a saturated C 12 . 14 alkyl.
  • the acylated amino acids can also be used as the alkali metal salt, alkaline earth metal salt or alkanolammonium salt, for example mono-, di- or triethanolammonium salt.
  • Exemplary acylated amino acids are amino acids, in particular the 20 natural ⁇ -amino acids, which carry 19 COOH at the amino nitrogen is the acyl radical R 19 CO of a saturated or unsaturated fatty acid R, where R 19 is a saturated or unsaturated C 6-22 -alkyl radical, preferably C 8 -
  • Amino acids are the acyl derivatives summarized in accordance with INCI under Amino Acids, for example sodium cocoyl glutamate, lauroyl glutamic acid, capryloyl glycine or myristoyl methylalanine.
  • a combination of two or more different amphoteric surfactants in particular a binary Amphotensidkombination is used.
  • the amphoteric surfactant combination preferably contains at least one betaine, in particular at least one alkylamidobetaine, more preferably cocoamidopropylbetaine.
  • amphoteric surfactants preferably contains at least one amphoteric surfactant is selected from the group comprising Natriumcarboxyethylkokosphosphoethylimidazolin (Phosphoteric ® TC- 6), Cs / 10 -Amidopropylbetain (INCI caprylic / Capramidopropyl Betaine, Betaine Tego ® 810), N-2-hy- droxyethyl-N- carboxymethyl-ethylamine fettklamido-Na (Rewoteric ® AMV) and N-caprylic / capric amidoethyl-N-ethyl-propionate-Na (Rewoteric AMVSF ®) and the betaine 3- (3-cocoamido-pro- pyl) -dimethylammonium- 2-hydroxypropanesulfonate (INCI sultaines; Rewoteric AM CAS ®)
  • the agent according to the invention contains one or more amphoteric surfactants in an amount of more than 8% by weight. In yet another particular embodiment, the agent according to the invention contains one or more amphoteric surfactants in an amount of less than 2% by weight.
  • the agent according to the invention may additionally contain one or more nonionic surfactants, usually in an amount of 0.001 to 10% by weight, preferably 0.01 to 8% by weight, in particular 0.1 to 4% by weight, particularly preferably 0 , 2 to 2 wt .-%.
  • Nonionic surfactants in the context of the invention are alkoxylates such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters. Also suitable are block polymers of ethylene oxide and propylene oxide as well as fatty acid alkanolamides and fatty acid polyglycol ethers. Important classes of nonionic surfactants according to the invention are furthermore the amine oxides and the sugar surfactants, in particular the alkyl polyglucosides.
  • fatty alcohol polyglycol ethers are according to the invention with ethylene oxide (EO) and / or propylene oxide (PO) alkoxylated to understand unbranched or branched, saturated or unsaturated do- 22 alcohols with a degree of alkoxylation up to 30, preferably ethoxylated do-is-fatty alcohols having a degree of ethoxylation of less than 30, preferably with a degree of ethoxylation of 1 to 20, in particular from 1 to 12, more preferably from 1 to 8, most preferably from 2 to 5, for example Ci 2 -i 4 -Fettalkoholethoxylate with 2, 3 or 4 EO or a mixture of the C 12 - 14 - fatty alcohol ethoxylates with 3 and 4 EO in a weight ratio of 1 to 1 or Isotridecylalkohol- ethoxylate with 5, 8 or 12 EO.
  • EO ethylene oxide
  • PO propylene oxide
  • amine oxides suitable in accordance with the invention include alkylamine oxides, in particular alkyldimethylamine oxides, alkylamidoamine oxides and alkoxyalkylamine oxides.
  • alkylamine oxides in particular alkyldimethylamine oxides, alkylamidoamine oxides and alkoxyalkylamine oxides.
  • Preferred amine oxides satisfy formula II,
  • R is a saturated or unsaturated C 6 6-22 alkyl, C -i preferably 8 8 -alkyl radical, in particular a saturated CIO 16 alkyl radical, for example a saturated C 2 - 14 alkyl radical, which in the alkylamidoamine oxides over a carbonylamidoalkylene -CO-NH- (CH 2 ) Z - and in the alkoxyalkylamine oxides via an oxaalkylene group -O- (CH 2 ) Z - is bonded to the nitrogen atom N, where z is in each case a number from 1 to 10, preferably 2 to 5, in particular 3, R 7 , R 8 independently of one another C
  • Suitable amine oxides are the following compounds designated as INCI: almond amidopropylamine oxides, babassuamidopropylamine oxides, behenamine oxides, cocamidopropyl amine oxides, cocamidopropylamine oxides, cocamine oxides, coco-morpholine oxides, decylamine oxides, decyltetradecylamines oxides, diaminopyrimidines oxides, dihydroxyethyl C8-10 Alkoxypropylamines oxides, dihydroxyethyl C9-11 alkoxypropylamines oxides, dihydroxyethyl C12-15 alkoxypropylamines oxides, dihydroxyethyl cocamines oxides, dihydroxyethyl lauramine oxides, dihydroxyethyl stearamines oxides, dihydroxyethyl tallowamine oxides, hydrogenated palm kernel amines oxides, hydrogenated tallowamine oxides, hydroxyethyl hydroxy
  • a preferred amine oxide is, for example, cocamidopropylamine oxides (cocoamidopropylamine oxide).
  • Sugar surfactants are known surface-active compounds, which include, for example, the sugar surfactant classes of the alkyl glucose esters, aldobionamides, gluconamides (sugar acid amides), glycerolamides, glycerol glycolipids, polyhydroxy fatty acid amide sugar surfactants (sugar amides) and alkyl polyglycosides.
  • Preferred sugar surfactants within the scope of the teaching according to the invention are the alkyl polyglycosides and the sugar amides and their derivatives, in particular their ethers and esters.
  • the ethers are the reaction products of one or more, preferably one, sugar with one or more hydroxy-containing compound, such as C- ⁇ _ 22 alcohols or glycols such as ethylene and / or propylene glycol, wherein the Zuckerhydroxyoeuvre also polyethylene glycol - And / or polypropylene glycol can carry.
  • the esters are the reaction products of one or more, preferably one, sugar with a carboxylic acid, in particular a C6 - 22 - fatty acid.
  • Particularly preferred sugar amides satisfy the formula R'C (O) N (R ") [Z], in which R 'is a linear or branched, saturated or unsaturated acyl radical, preferably a linear unsaturated acyl radical, having 5 to 21, preferably 5 to 17, in particular 7 to 15, particularly preferably 7 to 13 carbon atoms, R "is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferred 8 to 14 carbon atoms, a d- 5 alkyl, in particular a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tert-butyl or n-pentyl radical, or hydrogen and Z is a sugar residue ie a monosaccharide residue.
  • Particularly preferred sugar amides are the amides of glucose, the glucamides, for example la
  • alkyl polyglycosides are particularly preferred sugar surfactants within the scope of the teaching according to the invention and preferably satisfy the general formula R 1 O (AO) 3 [G] x , in which
  • R 1 represents a linear or branched, saturated or unsaturated alkyl radical having 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, [G] for a glycosidically linked sugar radical and x for a number from 1 to 10 and AO for an alkyleneoxy group, for example an ethyleneoxy or Propylenoxy distr, and a for the average degree of alkoxylation of 0 to 20.
  • the group (AO) 3 may also contain different alkyleneoxy, for example ethyleneoxy or propyleneoxy, where it is a to the average Automatalkoxyltechniksgrad, ie the sum of Ethoxyltechniks- and Propoxyltechniksgrad acts.
  • the alkyl radicals R 1 of the APG are linear unsaturated radicals having the stated number of carbon atoms.
  • APG are nonionic surfactants and are known substances that can be obtained by the relevant methods of preparative organic chemistry.
  • alkyl glycosides having a mean degree of oligomerization x of 1.1 to 3.0 are used. From an application point of view, those alkyl glycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.6 are preferred.
  • the glycosidic sugar used is preferably xylose, but especially glucose.
  • the alkyl or alkenyl radical R ' can be derived from primary alcohols having 8 to 18, preferably 8 to 14 carbon atoms.
  • Typical examples are caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol, and technical mixtures thereof, such as those obtained in the course of the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelene's oxosynthesis.
  • the alkyl or alkenyl radical R ' is derived from lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol.
  • lauryl alcohol myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol.
  • elaidyl alcohol petroselinyl alcohol, arachidyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and technical mixtures thereof.
  • R is as previously described for a linear or branched, saturated or unsaturated alkyl radical having 4 to 22 carbon atoms
  • [G] for a glycosidically linked sugar radical, preferably glucose residue
  • x is a number from 1 to 10, preferably 1, 1 to 3, in particular 1, 2 to 1, 6, stand.
  • preferred alkyl polyglycosides are, for example C 8 -io- and a C ⁇ 2 -u-
  • Alkylpolyglucoside having a DP degree of 1, 4 or 1, 5, in particular C 8 -alkyl-1, 5-glucoside and C 12 -i 4 -alkyl-1, 4-glucoside.
  • composition according to the invention may additionally contain one or more cationic surfactants (cation surfactants, INCI quaternary ammonium compounds), usually in an amount of 0.001 to 5% by weight, preferably 0.01 to 4% by weight, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt .-%.
  • cationic surfactants e.g., INCI quaternary ammonium compounds
  • Preferred cationic surfactants are the quaternary surface-active compounds, in particular having an ammonium, sulfonium, phosphonium, iodonium or arsonium group, as described, for example, by KH Wallrobußer in "Praxis der Sterilisation, Disinfection - Conservation: Germ Identification - Company Hygiene” (5th ed. Stuttgart, New York: Thieme, 1995) as antimicrobial agents.
  • the agent can be designed with an antimicrobial effect or its possibly existing antimicrobial effect due to other ingredients can be improved.
  • Particularly preferred cationic surfactants are the quaternary ammonium compounds (QAV, INCI Quaternary Ammonium Compounds) according to the general formula (R ') (R ") (R"') (R IV ) N + X ⁇ , in which R 1 to R ⁇ v are identical or different d- 22- alkyl radicals, C 7 .
  • radicals wherein two or in the case of an aromatic inclusion as in pyridine even three radicals together with the nitrogen atom, the heterocycle, for example a pyridinium or imidazolinium compound, form, and X " halide ions, sulfate ions, hydroxide ions or the like
  • the radicals preferably has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.
  • QACs are prepared by reacting tertiary amines with alkylating agents, e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced.
  • alkylating agents e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced.
  • alkylating agents e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced.
  • alkylating agents e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced.
  • the alkylation of tertiary amines with a long alkyl radical and two methyl groups succeeds particularly easily, and the quatern
  • Suitable QUATS are, for example, benzalkonium chloride (N-alkyl-N, N-dimethyl-benzylammonium chloride, CAS No. 8001-54-5), Benzalkon B (mp-dichlorobenzyl-dimethyl-Ci ⁇ -alkylammoniumchlorid, CAS No. 58390-78 -6), benzoxonium chloride (benzyldodecylbis (2-hydroxyethyl) ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-trimethylammonium bromide, CAS No. 57-09-0),
  • Benzetonium chloride N, N-dimethyl-N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0
  • dialkyldimethylammonium chlorides such as di-n-decyl-dimethyl-ammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyl-dimethyl-ammonium chloride, I-cetylpyridinium chloride (CAS No.
  • Preferred QUATS are the benzalkonium chlorides containing C 8 -C 8 alkyl radicals, in particular C 2 -C 4 -Aklyl-benzyl-dimethyl-ammonium chloride.
  • a particularly preferred QAC Kokospentaethoxymethylammonium- (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ®) methosulfate.
  • anionic surfactant-compatible and / or cationic surfactant is preferably used or omitted in a particular embodiment of the invention entirely on cationic surfactants.
  • the composition according to the invention may contain one or more additives from the group of surfactants, polymers and builders (builders), usually in an amount of 0.001 to 5% by weight, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt .-%.
  • one or more additives from the group of surfactants, polymers and builders (builders) usually in an amount of 0.001 to 5% by weight, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt .-%.
  • Surfactants suitable as additives are certain of the amphoteric surfactants already described above, further anionic surfactants, nonionic surfactants and cationic surfactants, which are repeated at this point.
  • the content of surface-active additives is preferably to be selected such that the total surfactant content is in the above-stated quantitative ranges.
  • suitable amphoteric surfactants are, in particular Natriumcarboxyethylkokosphospho- ethylimidazoline (Phosphoteric ® TC-6), C 8/10 -Amidopropylbetain (INCI caprylic / Capramidopropyl Betaine, Betaine Tego ® 810), N-2-hydroxyethyl-N-carboxymethyl-ethylamine fettklamido -Na (Rewoteric ® AMV) and N-caprylic / capric amidoethyl-N-ethyl-propionate-Na (Rewoteric AMVSF ®) and the betaine 3- (3-cocoamido-propyl) dimethylammonium-2-hydroxypropane (INCI sultaines; Rewoteric AM CAS ®) and the Alkylamidoalkylamin N- [N '(N "-2-hydroxyethyl-N"
  • anionic surfactants which are suitable as additives are in particular anionic gemini surfactants having a diphenyloxide basic structure, 2 sulfonate groups and one alkyl radical on one or both benzene rings according to the formula O 3 S (C 6 H 3 R) O (C 6 H 3 R ') SC> 3 ⁇ , where R is an alkyl radical having, for example, 6, 10, 12 or 16 carbon atoms and R 'is R or H (Dowfax ® Dry hydro tropic Powder with C-
  • suitable nonionic surfactants are in particular C 10 dimethyl amine oxide (Ammonyx ® DO), C 10 / i 4 fatty alcohol + 1, + 2PO 6,4EO (Dehydol ® 980), C 12 / i 4 fatty alcohol + 6 EO (Dehydol ® LS6), C 8 - fatty alcohol + 1, + 2PO 9EO (Dehydol ® O10), C 6/20 -Guerbetalkohol + 8EO, n-butyl-closed (Dehypon ® G2084), mixture of several n-butyl-sealed nonionic surfactants and C 8 / io APG-(Dehypon ® Ke 2555) C 8/10 fatty alcohol + 1 PO + 22EO- (2-hydroxydecyl) ether (Dehypon Ke ® 3447), C 12 / i 4 fatty alcohol + 5EO + 4PO ( Dehypon LS ® 54 G), 12 C / i 4 fatty fatty
  • cationic surfactants are particularly compatible with anionic surfactants, cationic surfactants such as quaternary ammonium compounds, for example Koko- spentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ®).
  • quaternary ammonium compounds for example Koko- spentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ®).
  • Polymers suitable as additives are especially maleic acid-acrylic acid copolymer, Na salt (Sokalan ® CP 5), modified polyacrylic acid Na salt (Sokalan ® CP 10), modified polycarboxylate Na salt (Sokalan ® HP 25), polyalkylene oxide, modified heptamethyltrisiloxane (Silwet ® L-77), polyalkylene oxide-modified heptamethyltrisiloxane (Silwet ® L-7608) and polyether (copolymers of polydimethylsiloxanes having ethylene oxide / propylene oxide segments (polyether)), preferably water-soluble linear polyether having terminal polyether as Tegopren ® 5840, Tegopren ® 5843, Tegopren ® 5847, Tegopren ® 5851, Tegopren ® 5863 or Tegopren ® 5878.
  • suitable builders are, in particular polyaspartic acid-Na-salt, Ethylendiamintriacetatkokosalkylacetamid (Rewopol ® CHT 12), methylglycine-Tri-Na salt (Trilon ES ® 9964) and acetophosphonic (Turpinal SL ®).
  • Blends with surfactant or polymeric additives show in the case of Monawet MO-84 ® R2W, Tegopren ® 5843 and Tegopren 5863 ® synergism.
  • Tegopren grades 5843 and 5863 is less preferred when applied to hard surfaces of glass, especially glassware, since these can apply silicone surfactants to glass.
  • the additives mentioned are dispensed with.
  • the viscosity which is favorable for the composition according to the invention is 20 ° C. and a shear rate of 30 min -1 - measured with a Brookfield LV DV II viscometer and spindle 31 - in the range from 5 to 200 mPa ⁇ s, preferably 10 to 10 10 mPa ⁇ s -S, in particular 15 to 80 mPa-s, particularly preferably 20 to 70 mPa-s.
  • the viscosity of the composition according to the invention can be increased - in particular with a low surfactant content of the composition - by thickening agents and / or - especially at a high surfactant content of the composition - be reduced by the optionally present water-soluble inorganic salts and by solvents.
  • composition according to the invention may additionally contain one or more polymeric thickeners.
  • polymeric thickeners are the polycarboxylates which have a thickening effect as polyelectrolytes, preferably homopolymers and copolymers of acrylic acid, in particular acrylic acid copolymers such as acrylic acid-methacrylic acid copolymers, and the polysaccharides, in particular heteropolysaccharides, and other customary thickening polymers.
  • Suitable polysaccharides or heteropolysaccharides are the polysaccharide gums, for example gum arabic, agar, alginates, carrageenans and their salts, guar, guar gum, tragacanth, gellan, Ramzan, dextran or xanthan and their derivatives, e.g. propoxylated guar, as well as their mixtures.
  • Other polysaccharide thickeners such as starches or cellulose derivatives, may be used alternatively, but preferably in addition to a polysaccharide gum, for example starches of various origins and starch derivatives, e.g. Hydroxyethyl starch, starch phosphate esters or starch acetates, or carboxymethyl cellulose or its sodium salt,
  • a preferred polymeric thickener is the microbial anionic heteropolysaccharide xanthan gum, which is produced by Xanthomonas campestris and some other species under aerobic conditions with a molecular weight of 2-15 * 10 6 and is commercially available for example from the company.
  • Kelco under the trade name Keltrol ®, eg as cream-colored powder Keltrol ® T (transparent) or as white granules Keltrol ® RD (Readily Dispersable).
  • Acrylic acid polymers suitable as polymeric thickeners are, for example, high molecular weight homopolymers of acrylic acid crosslinked with a polyalkenyl polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI Carbomer), which are also referred to as carboxyvinyl polymers.
  • a polyalkenyl polyether in particular an allyl ether of sucrose, pentaerythritol or propylene
  • carboxyvinyl polymers Such polyacrylic acids are obtainable inter alia from Fa. BFGoodrich under the tradename Carbopol ®, such as Carbopol ® 940 (molecular weight about 4,000,000), Carbopol ® 941 (molecular weight approximately 1,250,000) or Carbopol ® 934 (molecular weight approximately 3,000. 000).
  • Particularly suitable polymeric thickening agents include but following acrylic acid copolymers: (i) copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably with CI_ 4 -alkanols formed, esters (INCI Acrylates Copolymer), to which about copolymers of methacrylic acid, butyl acrylate and methyl methacrylate (CAS 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and which are obtainable under the trade names Aculyn ® and Acusol ® for example, by Fa.
  • acrylic acid copolymers (i) copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably with CI_ 4 -alkanols formed, esters (INCI Acrylates Copolymer), to which about copolymers of methacrylic acid, butyl acrylate and methyl methacryl
  • Rohm & Haas for example the anionic non-associative polymers Aculyn ® 33 (crosslinked), Acusol ® 810 and Acusol ® 830 (CAS 25852-37-3); (ii) crosslinked high molecular weight acrylic acid copolymers, such as those crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of C- ⁇ o- 30- alkyl acrylates with one or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably with C
  • the content of polymeric thickener is preferably between 0.01 and 4 wt .-%, more preferably between 0.1 and 2 wt .-%, in particular between 0.5 and 1, 5 wt .-%.
  • the agent is free of polymeric thickeners.
  • one or more dicarboxylic acids and / or their salts are added, particularly to a composition of Na salts of adipic, succinic and glutaric acid, such as, for example, available under the trade name Sokalan ® DSC is.
  • the use is advantageously carried out in amounts of 0.1 to 8 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1, 3 to 6 wt .-% and particularly preferably 2 to 4 wt .-%.
  • a change in the dicarboxylic acid (salt) content can - especially in amounts above 2 wt .-% - contribute to a clear solution of the ingredients. Also, within certain limits, influencing the viscosity of the mixture by this means is possible. Furthermore, this component influences the solubility of the mixture. This component is particularly preferably used at high surfactant contents, in particular at surfactant contents above 30 wt .-%.
  • the agent according to the invention is preferably free from dicarboxylic acid (salts).
  • the pH of the agent according to the invention can be adjusted by means of customary pH regulators, for example acids such as mineral acids or citric acid and / or alkalis such as sodium or potassium hydroxide, wherein - in particular with the desired hand tolerance - a range from 4 to 9, preferably 5 to 8, in particular 5.5 to 7.5, is preferred.
  • acids such as mineral acids or citric acid
  • alkalis such as sodium or potassium hydroxide
  • the agent according to the invention may contain one or more buffer substances (INCI Buffering Agents), usually in amounts of 0.001 to 5 wt .-%, preferably 0.005 to 3 wt .-%, in particular 0 , 01 to 2 wt .-%, particularly preferably 0.05 to 1 wt .-%, most preferably 0.1 to 0.5 wt .-%, for example, 0.2 wt .-%.
  • buffer substances which are at the same time complexing agents or even chelating agents (INCI chelating agents).
  • Particularly preferred buffers are citric acid or citrates, in particular the sodium and Kaliumeitrate, for example trisodium citrate 2H 2 O and tripotassium-H 2 0th
  • the agent according to the invention can be prepared by stirring the individual components together in any order.
  • the order of attachment is not critical to the preparation of the agent.
  • water surfactants and optionally further of the aforementioned ingredients are stirred together. If perfume and / or dye are used, then their addition to the resulting solution. Subsequently, the pH is adjusted as described above.
  • the composition according to the invention in the form of a foam should be applied either directly to the surface to be cleaned or on a sponge, a cloth, a brush or another, optionally moistened, cleaning aid.
  • a manually activated spray dispenser in particular selected from the group comprising aerosol spray dispenser, self-pressure spray dispenser, pump spray dispenser and trigger spray dispensers, in particular pump foam dispenser, as for example from the company Airspray, the company Taplast, the company Keltec or the Daiwa Can Company.
  • pump spray dispensers and trigger spray dispensers with a polyethylene, polypropylene or polyethylene terephthalate container are also suitable.
  • Such trigger bottles are offered for example by the company Afa-Polytec.
  • the spray head is preferably equipped with a foam nozzle.
  • the agent can also be mixed with the addition of a suitable propellant (for example n-butane, a propane / butane).
  • a further subject of the invention is accordingly a product of an aqueous cleaning agent according to the invention and a foam dispenser, in particular of an aqueous cleaning agent according to the invention and a pump foam dispenser.
  • the agent according to the invention can be used for cleaning hard surfaces.
  • a further subject of the invention is therefore the use of a composition according to the invention or a product of the agent according to the invention and a foam dispenser for cleaning hard surfaces.
  • the agent according to the invention or the product according to the invention can be used as dishwashing detergent, in particular for manual dishwashing.
  • Another subject of the invention is therefore the use of an agent according to the invention or a product of the agent according to the invention and a foam dispenser as dishwashing detergent, in particular for manual dishwashing.
  • Another use is the pretreatment of soiled textiles.
  • Yet another subject of the invention is therefore the use of a composition according to the invention or a product of the agent according to the invention and a foam dispenser for the pretreatment of soiled textiles.
  • a fourth use is the cleaning of carpets.
  • Another subject of the invention is therefore the use of a composition according to the invention or a product of the agent according to the invention and a foam dispenser as carpet cleaning agent.
  • the composition according to the invention can be used for cleaning hard surfaces and in particular for manual dishwashing.
  • a cleaning aid ie a substrate such as a cleaning sponge or a brush
  • a further subject of the invention is therefore a method for cleaning hard surfaces, in particular for manual dishwashing, consisting of the steps
  • Yet another subject of the invention is a method for cleaning hard surfaces, in particular for manual dishwashing, comprising the steps of applying a foamed by means of a foam dispenser inventive composition on the surface to be cleaned, distributed or triturated on the surface to be cleaned, rinsing with water, if necessary, drain, if necessary, wipe off and dry rub.
  • inventive means for the pretreatment of textiles can be used by the foam is applied to the stain and optionally rubbed and added immediately or after drying in a washing machine and washed in a conventional manner.
  • a further subject of the invention is therefore a process for the pretreatment of textiles, consisting of the steps of applying a foamed by means of a foam dispenser inventive composition on the soiling, optionally rubbing, if necessary, allow drying, introduction into a washing machine and performing a conventional washing program.
  • composition of the invention can also be used for carpet cleaning, wherein the foam is applied to the polluted area, optionally incorporated with a cleaning aid such as a brush or a sponge and is removed after drying with the vacuum cleaner.
  • a cleaning aid such as a brush or a sponge
  • a further subject of the invention is therefore a process for carpet cleaning, comprising the steps of applying a foamed using a foam dispenser inventive composition on the polluted site, optionally rubbing using a sponge, a brush, a cloth or other, optionally moistened, cleaning aid, drying let and remove the dried agent with the vacuum cleaner.
  • compositions E1 to E3 were prepared which, in addition to water, also contained ethanol or PPG-400 as organic solvents. Besides, a comparative solvent V1 free from organic solvents was prepared. The compositions are shown in the table below, all amounts are in wt .-% active material based on the total composition.
  • compositions V1, E1 and E2 were each applied to a sponge by means of foam trigger and additionally kneaded. They were submitted to a panel of olfactorily trained persons who assessed the scent intensity of the resulting foams. In this case, the fragrance was most intense in the inventive composition E1, followed by E2. The fragrance of the comparison agent was perceived much weaker at the same perfume oil content.
  • the absorption capacity of the produced perfume oil was tested.
  • the content of perfume oil in the formulations E1, E2 and V1 was gradually increased until it came to first product turbidity. The latter were detected by visual inspection. While in the compositions E1 and E2 according to the invention even at a perfume oil content of 5 wt .-% no product turbidity was observed, such occurred at the comparison means V1 already at 1 wt .-% perfume oil content.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Fats And Perfumes (AREA)

Abstract

L'invention concerne un produit aqueux moussant contenant un tensio-actif. Ce produit comporte de l'huile parfumée et 5 à 35 % en poids d'un solvant organique miscible à l'eau. Grâce à une capacité d'absorption améliorée de l'huile parfumée, ce produit offre une perception olfactive plus forte. Ce produit peut être utilisé dans des procédés de nettoyage correspondants pour nettoyer des surfaces dures en tant que produit vaisselle, pour prétraiter les textiles encrassés ou comme produit de nettoyage des tapis.
PCT/EP2007/052608 2006-04-11 2007-03-20 Détergent aqueux contenant du parfum WO2007118747A1 (fr)

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DE102006017311.2 2006-04-11
DE200610017311 DE102006017311A1 (de) 2006-04-11 2006-04-11 Parfümhaltiges wässriges Reinigungsmittel

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Publication number Priority date Publication date Assignee Title
ES2939503T3 (es) 2020-09-17 2023-04-24 Procter & Gamble Composición de limpieza líquida para lavado de vajilla a mano
ES2939313T3 (es) 2020-09-17 2023-04-20 Procter & Gamble Composición de limpieza líquida para lavado de vajilla a mano
PL3971275T3 (pl) * 2020-09-17 2022-12-27 The Procter & Gamble Company Płynna kompozycja czyszcząca do ręcznego zmywania naczyń

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EP0586295A1 (fr) * 1992-08-31 1994-03-09 Nln Compositions fluides, rapidement moussantes, exemptes de savons, contenant un hydrocarbure inférieur et propulsées en récipient sous pression de gaz comprimé
WO1996018717A1 (fr) * 1994-12-15 1996-06-20 Colgate-Palmolive Company Compositions liquides nettoyantes en micro-emulsion destinees a un usage peu intensif
WO1998050518A1 (fr) * 1997-05-02 1998-11-12 The Procter & Gamble Company Compositions de nettoyage, procedes et/ou articles pour surfaces dures
EP0949325A1 (fr) * 1998-04-08 1999-10-13 The Procter & Gamble Company Compositions pour le nettoyage de tapis et méthode de nettoyage
US6004920A (en) * 1999-04-09 1999-12-21 Colgate-Palmolive Co. Post foaming cleaning compositions comprising isopentane and an alkyl sulfo succinate
WO2002006435A1 (fr) * 2000-07-14 2002-01-24 Reckitt Benckiser Inc. Nettoyeurs a tapis
EP1229107A1 (fr) * 2001-02-05 2002-08-07 The Procter & Gamble Company Procédé de nettoyage des tapis avec une composition comprenant un composé fluoré
EP1270711A1 (fr) * 2001-06-28 2003-01-02 Givaudan SA Compositions de nettoyage pour tissu
JP2003183698A (ja) * 2001-12-20 2003-07-03 Lion Corp 浴室用洗浄剤組成物

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EP0586295A1 (fr) * 1992-08-31 1994-03-09 Nln Compositions fluides, rapidement moussantes, exemptes de savons, contenant un hydrocarbure inférieur et propulsées en récipient sous pression de gaz comprimé
WO1996018717A1 (fr) * 1994-12-15 1996-06-20 Colgate-Palmolive Company Compositions liquides nettoyantes en micro-emulsion destinees a un usage peu intensif
WO1998050518A1 (fr) * 1997-05-02 1998-11-12 The Procter & Gamble Company Compositions de nettoyage, procedes et/ou articles pour surfaces dures
EP0949325A1 (fr) * 1998-04-08 1999-10-13 The Procter & Gamble Company Compositions pour le nettoyage de tapis et méthode de nettoyage
US6004920A (en) * 1999-04-09 1999-12-21 Colgate-Palmolive Co. Post foaming cleaning compositions comprising isopentane and an alkyl sulfo succinate
WO2002006435A1 (fr) * 2000-07-14 2002-01-24 Reckitt Benckiser Inc. Nettoyeurs a tapis
EP1229107A1 (fr) * 2001-02-05 2002-08-07 The Procter & Gamble Company Procédé de nettoyage des tapis avec une composition comprenant un composé fluoré
EP1270711A1 (fr) * 2001-06-28 2003-01-02 Givaudan SA Compositions de nettoyage pour tissu
JP2003183698A (ja) * 2001-12-20 2003-07-03 Lion Corp 浴室用洗浄剤組成物

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