WO2007114052A1 - Core for transmission belt, and transmission belt - Google Patents

Core for transmission belt, and transmission belt Download PDF

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Publication number
WO2007114052A1
WO2007114052A1 PCT/JP2007/055748 JP2007055748W WO2007114052A1 WO 2007114052 A1 WO2007114052 A1 WO 2007114052A1 JP 2007055748 W JP2007055748 W JP 2007055748W WO 2007114052 A1 WO2007114052 A1 WO 2007114052A1
Authority
WO
WIPO (PCT)
Prior art keywords
transmission belt
belt
core wire
polyketone
pulley
Prior art date
Application number
PCT/JP2007/055748
Other languages
French (fr)
Japanese (ja)
Inventor
Kimichika Ohno
Original Assignee
Bando Chemical Industries, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bando Chemical Industries, Ltd. filed Critical Bando Chemical Industries, Ltd.
Priority to EP07739191A priority Critical patent/EP2009323A4/en
Priority to JP2008508506A priority patent/JPWO2007114052A1/en
Priority to US12/296,198 priority patent/US20100105510A1/en
Priority to CN2007800206233A priority patent/CN101460764B/en
Publication of WO2007114052A1 publication Critical patent/WO2007114052A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16GBELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G5/00V-belts, i.e. belts of tapered cross-section
    • F16G5/20V-belts, i.e. belts of tapered cross-section with a contact surface of special shape, e.g. toothed

Definitions

  • the present invention relates to a transmission belt core wire and a transmission belt.
  • a transmission belt is used to transmit power from a drive source to an auxiliary machine.
  • noise may be generated due to the transmission belt.
  • a serpentine drive system is often employed in which an auto tensioner is used and the torque on each auxiliary equipment is driven by a single V-ribbed belt.
  • the drive-side torque and the accessory-side torque will resonate and the swing of the auto tensioner will become very large, and the belt on the tension pulley of the auto tensioner will Noises such as tapping may occur.
  • Patent Document 1 discloses using aramid fiber, polyvinyl alcohol fiber, or polyethylene naphthalate fiber instead of the polyethylene terephthalate fiber that has been generally used as a material for the core wire. .
  • the conventional transmission belt maintains sufficient performance for use and has sufficient noise. There is a drawback that it cannot be suppressed.
  • Patent Document 1 Japanese Patent Laid-Open No. 2001-248692
  • the present invention has been made in view of the above-mentioned conventional drawbacks.
  • the present invention provides the transmission belt with sufficient performance (for example, durability), and
  • a core wire such as a V-ribbed belt
  • the swing amount is substantially reduced, sufficient performance (for example, durability) is provided, and noise generation is substantially reduced.
  • the present invention exhibits sufficient performance (for example, durability, etc.) for use, and when used as, for example, a V-ribbed belt, the swing amount is substantially reduced, which is sufficient for use.
  • Other problems of the present invention are apparent from the description of the present specification.
  • the present invention has been made in view of the above problems, and relates to a core wire for a transmission belt characterized by containing polyketone fibers.
  • the present invention also relates to a transmission belt, wherein the transmission belt core wire is embedded.
  • the transmission belt core wire of the present invention when used in a transmission belt, the transmission belt is provided with sufficient performance (for example, durability, etc.) for use, and for example, a V-ribbed belt.
  • the swing amount is substantially reduced, sufficient performance (for example, durability) is provided, and noise generation is substantially suppressed, etc. It has an excellent effect of achieving at least one of the following.
  • the performance sufficient for use for example, durability, etc.
  • the swing amount is substantially reduced. Providing sufficient performance for use (for example, durability) and substantially suppressing noise generation It has an excellent effect that at least one of the above can be achieved.
  • FIG. 1 is a cross-sectional view of a V-ribbed belt as an example of a transmission belt, and shows a view perpendicular to the longitudinal direction of the belt.
  • FIG. 2 is a schematic view of a multi-axis transmission device.
  • FIG. 3 is a schematic view of a multi-axis transmission device.
  • FIG. 4 is a schematic diagram showing a core wire and a monofilament.
  • the broken line A shows the center line
  • the solid line B shows the center line of the minimum twist unit.
  • the thick vertical line indicates the core.
  • the present invention relates to a core wire for a transmission belt containing polyketone fibers.
  • the core wire for the transmission belt of the present invention contains polyketone fiber, which is one major feature. There are signs. Therefore, when the core wire for a transmission belt according to the present invention is used as a core wire for a transmission belt, for example, a V-ribbed belt, it is possible to substantially suppress the generation of noise due to resonance caused by the transmission belt.
  • the core wire for a transmission belt of the present invention when used as a core wire for a transmission belt, for example, a V-ribbed belt, it exhibits excellent adhesion to a rubber composition. Even when repeated bending is repeated, pop-out of the transmission belt core wire can be substantially suppressed. Further, according to the core wire for a transmission belt of the present invention, since the polyketone fiber is contained, an excellent effect that the influence on wet heat at the time of vulcanization can be substantially suppressed is exhibited.
  • the inclination angle of the polyketone fiber monofilament is preferably 8 ° or more with respect to the longitudinal axis of the polyketone fiber from the viewpoint of bending fatigue. From the standpoint of elongation during belt travel, which is more preferred above 24. It is preferable that the angle is 20 ° or less. According to the core wire for the power transmission belt, when used in the manufacture of the power transmission belt, the power transmission belt can exhibit excellent durability, and the generation of abnormal noise due to the power transmission belt can be substantially suppressed. You can.
  • the inclination angle ( ⁇ ) means the center line of the core in the belt circumferential direction (broken line in FIG. 4) and the center line of the minimum twist unit (solid line of B in FIG. 4). Observation direction of the core line intersecting with
  • T is the number of times of twisting (times / 10cm)
  • D is the total fineness of the twisted yarn (denier)
  • E indicates specific gravity
  • T 1 is the number of times of lower twist (times / 10 cm)
  • D 1 is the total fineness of the lower twist yarn (dtex)
  • is the angle with respect to the upper twist diameter direction line of the lower twist yarn
  • T 2 is the number of times of lower twist (times / 10 cm)
  • D 2 is the total fineness (denier) of the lower twist
  • s is the specific gravity
  • T 2 is the number of times of twisting (times / 10 cm)
  • D 2 is the total fineness of the twisted yarn (dtex)
  • the polyketone compound used in the polyketone fiber is not particularly limited.
  • 90% by weight or more of the repeating units are represented by the following formula (I):
  • the transmission belt for example, the ability to suppress abnormal noise when embedded as a core wire of the transmission belt, the adhesion to the rubber composition, and the ability to suppress moisture and heat deterioration are fully expressed in the transmission belt.
  • the polyketone composed of the 1-oxotrimethylene unit force is preferable.
  • the “polyketone composed of 1-oxotrimethylene units in which 90% by weight or more of the repeating units are represented by the above formula (I)” is, in other words, 1-oxotrimethylene monomer power to be polymerized. It can be regarded as a product obtained by carrying out a polymerization reaction so as to be 90% by weight or more.
  • the core wire for the transmission belt of the present invention preferably has a filament strength of the polyketone fiber.
  • the monofilament composed of the polyketone compound is not particularly limited, and can be produced, for example, by a wet spinning method, a dry spinning method, or the like.
  • the wet spinning method is a method in which a polyketone compound-containing solution is discharged from a spinneret into a coagulation bath, and the resulting product is dried and hot drawn.
  • the dry spinning method is a method in which the polyketone compound-containing solution is dried. In this method, the liquid component contained in the product discharged from the spinneret and discharged in a high-temperature atmosphere is volatilized and hot stretched.
  • the polyketone compound-containing solution contains the polyketone compound, for example, a halogenated suboxide. It is a solution obtained by dissolving in a lead compound-containing aqueous solution, hexafluoroisopropanol, m-cresol, resorcin, zinc aqueous solution or the like.
  • the fiber length of the monofilament is preferably 10 mm or more from the viewpoint of taking advantage of the strength of the fiber.
  • the diameter of the monofilament is from the viewpoint of easy spinning,
  • a monofilament composed of the polyketone compound is, for example,
  • the total fineness of the polyketone fiber should be in a range according to the purpose of use.
  • the total fineness is preferably not less than 200 Odtex, more preferably not less than 3000 dtex, and more preferably not more than 12,000 dtex, and more preferably not more than 7000 dtex from the viewpoint of suppressing bending fatigue. .
  • the monofilament made of a polyketone composed of the 1-year-old xisotrimethylene unit is obtained by polymerizing ethylene and carbon monoxide in a dilute solvent in the presence of a radical initiator.
  • a polyketone in which 90% by weight or more of the repeating units are units of 1-oxotrimethylene is obtained by polymerizing ethylene and carbon monoxide in a dilute solvent in the presence of a radical initiator.
  • a polyketone in which 90% by weight or more of the repeating units are units of 1-oxotrimethylene
  • dissolve the polyketone in an aqueous solution containing a halogenated zinc compound or the like to obtain a polyketone-containing solution.
  • the product is discharged into a coagulation bath, and the resulting product is dried and hot drawn (wet spinning method); the polyketone-containing solution is discharged from a spinneret and contained in the product discharged in a high-temperature atmosphere. It can be obtained by volatilizing the liquid component and hot drawing (dry spinning method). Subsequently, polyketone fibers are obtained by twisting the monofilament so as to have an inclination angle force of 8 ° to 24 ° with respect to the longitudinal axis.
  • step (C) a step of immersing the polyketone fiber obtained in the step (B) in a solution (first treatment liquid) containing an isocyanate H-hybrid compound or an epoxy compound.
  • step (F) a step of drying the product obtained in the step (E) through an oven adjusted to 180 ° C to 280 ° C for 30 seconds to 2 minutes,
  • the isocyanate compound is not particularly limited, and examples thereof include 4,4'-diphenylmethane diisocyanate, p_phenyldiisocyanate, polymethylene polyphenyl polyisocyanate, and the like.
  • the epoxy compound include polyhydric alcohols (eg, ethylene glycol, glycerin, pentaerythritol, sorbitol, etc.), polyalkylene glycols (eg, polyethylene glycol, etc.), and halogen-containing epoxy compounds (eg, epichlore).
  • reaction products with hydrins, etc . reaction products of polyhydric phenol compounds (eg bis (4-hydroxyphenyl) dimethylethane, phenol formaldehyde resins, resorcin formaldehyde resins, etc.) with halogen-containing epoxy compounds Etc.
  • the solution containing the isocyanate compound or epoxy compound can be obtained by dissolving the isocyanate compound or epoxy compound in, for example, toluene.
  • the amount of adhesive may be stabilized by repeating the step (E) 2 to 3 times.
  • the product obtained in the step (E) is a solution containing an epoxy compound (epoxy resin), a phenol compound (phenol resin) or the like, or an adhesive rubber composition It may be further immersed in a solution dissolved in a solvent and dried.
  • the present invention relates to a transmission belt characterized in that the transmission belt core wire is embedded. Since the power transmission belt of the present invention is mounted on the power transmission belt of the present invention, the power transmission belt of the present invention exhibits sufficient performance (for example, durability) and is used as, for example, a V-ribbed belt. If this occurs, the amount of rocking will be substantially reduced and noise will be reduced. Can be substantially suppressed.
  • the transmission belt of the present invention can be used, for example, as a V-ribbed belt in the case of using an auto tensioner.
  • Examples of the transmission belt of the present invention include belts (V-ribbed belts, etc.), flat belts, toothed belts, and the like.
  • V-ribbed belt shown in Fig. 1 will be described as an example of the transmission belt of the present invention.
  • the transmission belt of the present invention is not limited to a powerful example.
  • the V-ribbed belt shown in FIG. 1 includes an adhesive rubber layer 3 having a rubber composition as a constituent member, an upper canvas layer 1 disposed on the upper surface side of the adhesive rubber layer 3, and the adhesive rubber layer 3
  • the upper surface canvas layer 1, the adhesive rubber layer 3, and the rib rubber layer 4 are integrally formed.
  • a plurality of core wires 2 that extend in a substantially belt length direction and are spirally provided at a predetermined pitch in the belt width direction are arranged at regular intervals. It has been installed.
  • the adhesive rubber layer 3 is a layer made of a rubber composition.
  • the rubber composition contains, for example, black-prene rubber, ethylene propylene rubber, hydrogenated nitrile rubber, alkyl chlorosulfonated polyethylene, etc. alone or as a mixture of two or more. As long as the rubber composition does not interfere with the object of the present invention, reinforcing agents such as short fibers and inorganic fillers described later, co-crosslinking agents, plasticizers, stabilizers, processing aids, and coloring agents. Etc. may be contained appropriately.
  • the adhesive rubber layer 3 serves as a rubber layer that forms a belt main body and holds a plurality of core wires 4.
  • the upper surface canvas layer 1 is bonded to the upper surface of the belt by applying an adhesive treatment to a woven fabric such as nylon, cotton, etc., by dissolving the rubber in a solvent, and sticking to the upper surface of the belt. When it is urged to abut, it bears one end of power transmission.
  • the rib rubber layer 4 is made of a rubber composition containing chloroprene rubber, ethylene propylene rubber, hydrogenated nitrile rubber, alkylsulfonated polyethylene or the like.
  • the elastic rib rubber layer 4 has improved elastic modulus in the belt width direction. Short fibers such as nylon fiber, aramid fiber, cotton, and vinylon may be mixed so as to be oriented in the belt width direction. When the V-ribbed belt is strung against the pulley, the strong rib rubber layer 4 comes into contact with the pulley and becomes the main component of power transmission.
  • the adhesive rubber layer 3 and the upper canvas layer 1 can be replaced with a layer having the same composition as the rib rubber layer 4 and a corresponding thickness.
  • the V-ribbed belt shown in FIG. 1 can be manufactured as follows, for example.
  • a cylindrical mold is covered with a canvas that has been subjected to adhesion treatment with rubber glue or the like, and a rubber sheet having a rubber composition force is wound on the canvas.
  • the core wire for the transmission belt of the present invention is wound around the rubber sheet.
  • a rubber sheet made of a rubber composition is rubbed onto the transmission belt core wire. Thereby, a laminated body is obtained.
  • the cylindrical mold holding the obtained cylindrical laminate is introduced into the vulcanizing can. Thereafter, pressurization is performed from outside with high-pressure steam, and the laminated body inside the vulcanizing can is heated to vulcanize and integrate to obtain a rubber cylinder.
  • the outer peripheral surface of the obtained rubber cylindrical body is ground with a grindstone, thereby providing a plurality of protrusions extending in the circumferential direction and formed at a predetermined pitch in the cylindrical axis direction.
  • a transmission belt V-ribbed belt is obtained by cutting the rubber cylinder into a predetermined width with a width corresponding to the three protrusions.
  • the obtained core wire was immersed in a 20% by volume toluene solution of isocyanate (Sumidure 44V20, manufactured by Sumika Bayer Urethane Co., Ltd.) and then pre-treated by heating and drying at 240 ° C for 40 seconds.
  • the cord is resorcinol formalin latex (RFL) solution Soaked in Zorcine (Sumitomo Chemical Co., Ltd.), formalin (Guangei Chemical Industry Co., Ltd.), Latex (CR Latex) (Showa Denko Co., Ltd.)] gave.
  • the filament angle [inclination angle (h)] is an angle (°) determined by the equation (1).
  • a cylindrical mold having a circumferential length of 1000 mm was subjected to an adhesive treatment using an RFL solution, and a cotton / polyester blended canvas subjected to a pasting treatment was covered in a biased shape.
  • an ethylene / propylene / gen rubber composition manufactured by Sumitomo Chemical Co., Ltd., trade name: Esprene 30
  • the core wire obtained in Example 1 was beaten on the strong first adhesive rubber sheet.
  • a second adhesive rubber sheet made of an ethylene-propylene-gen rubber composition was wound on the core wire.
  • the thus obtained cylindrical mold obtained placed in a vulcanizer, the inner pressure 588kPa (6kgf / cm 2), the external pressure 883kPa (9kgf / cm 2), 165.
  • C. Sulfurized under conditions of 35 minutes to obtain a rubber cylinder.
  • the outer peripheral surface of the obtained rubber cylindrical body was ground with a grindstone, thereby providing a plurality of protrusions (shape: PK shape) extending in the circumferential direction and formed at a predetermined pitch in the cylinder axis direction.
  • a transmission belt V-ribbed belt
  • the resulting belt had a total belt thickness of 4.3 mm and a rib height of 2. Omm.
  • Example 3 In the same manner as in Example 1, a polyethylene terephthalate core (lOOdtexZ 2 X 3) was produced. A transmission belt (V-ribbed belt) was obtained in the same manner as in Example 2 using the obtained core wire.
  • Example 2 In the same manner as in Example 1, a polyethylene naphthalate core wire (1100 dtex Z2 X 3) was produced. Using the obtained core wire, a transmission belt (V Ribbed belt) was obtained.
  • the multi-axis transmission device was operated at room temperature (25 ° C).
  • the amount of swing of the auto tensioner 12 was measured.
  • the pulley diameter of alternator pulley 11 in Fig. 2 is 55 mm, this load is 1103 W, pulley diameter of air conditioner pulley 8 is 95 mm, this load is 809 W, power steering pulley 9 pulley diameter is 115 mm, and this load is 588 W.
  • the water pump pulley 10 has a pulley diameter of 115 mm and a load of 37 W.
  • the idler pulley 7 has a pulley diameter of 90 mm
  • the tension pulley 13 has a pulley diameter of 70 mm
  • its arm length is 75 mm
  • the tension applied to the belt is 147 N
  • the drive pulley 6 has a pulley diameter of 120 mm and its rotational speed.
  • 1000 rpm and the drive shaft rotation fluctuation rate was ⁇ 10%.
  • Table 1 The results are shown in Table 1.
  • a polyketone fiber with a core of 1650dtex / l X 3 and a filament angle of 8 ° (Asahi Kasei Fibers Co., Ltd., trade name: Cyvalon TM, strength: 18cN / dte X , elongation: 6%, tensile elasticity: 33 5cN / dt ex ], a cord was obtained by the same operation as in Example 1, and then a V-ribbed belt was obtained by the same operation as in Example 2.
  • a polyketone fiber with a core of 1650dtex / l X 3 and a filament angle of 5 ° (Asahi Kasei Fibers Co., Ltd., trade name: Cyvalon TM, strength: 18cN / dte X , elongation: 6%, tensile elasticity: 33 5cN / dtex], a core wire was obtained by the same operation as in Example 1, and then a V-ribbed belt was obtained by the same operation as in Example 2.
  • a polyketone fiber with a core wire of 1650 dtex / l X 3 and a filament angle of 26 ° [Asahi Kasei Fibers Corporation, trade name: Cyvalon TM, strength: 18 cN / dte X , elongation: 6%, tensile elasticity: 335 cN / A cord was obtained by the same operation as in Example 1 except that dtex], and then a V-ribbed belt was obtained by the same operation as in Example 2.
  • the core wire was the same as in Example 2 except that the core wire was made of polyethylene naphthalate (trade name: Type Q904M, manufactured by Teijin Techno Products Co., Ltd.) with 1100dtex / 2 X 3 and filament angle of 5 °. A V-ribbed belt was obtained.
  • polyethylene naphthalate trade name: Type Q904M, manufactured by Teijin Techno Products Co., Ltd.
  • the core is the same as in Example 2 except that the core is made of aromatic polyamide (trade name: Technora, manufactured by Teijin Techno Products Co., Ltd.) with 1650 dtex / l X 3 and filament angle of 5 °. By operation, a V-ribbed belt was obtained.
  • aromatic polyamide trade name: Technora, manufactured by Teijin Techno Products Co., Ltd.
  • the core wire is a core wire made of polybulal alcohol (trade name: manufactured by Kuraray Co., Ltd., trade name: Claron) with 1100 dtex / 2 X 3 and a filament angle of 5 °, the same operation as in Example 2 was performed. A V-ribbed belt was obtained.
  • polybulal alcohol trade name: manufactured by Kuraray Co., Ltd., trade name: Claron
  • Each of the V-ribbed belts of Experiment Nos. 1 to 7 is connected to the drive pulley 6 (direct It was attached to a belt drive system with a force of 120 mm (diameter), driven pulley 14 (diameter 120 mm), idler pulley 7 (diameter 70 mm) and tension pulley 13 (diameter 55 mm) arranged between these pulleys.
  • the idler pulley 7 was engaged with the back of the belt.
  • the load of the driven pulley 14 is set to 11.9 kw (16 horsepower), the initial tension of the tension pulley 13 is set to 833 N (85 kgf), and the drive pulley 6 is driven at a rotational speed of 4900 rpm.
  • the belt was run.
  • the tensile strength of the belt before and after running was measured, and the strength maintenance rate (strength after running Z before running) was determined. The results are shown in Table 2.
  • the filament angle is 8 ° to 24 °.
  • the V-ribbed belt core wires are embedded consisting of polyketone fibers is, filament angle 5 ° or compared to 26 ° of the polyketone fiber strength becomes cord, this and the force s Wachikararu also excellent in durability.
  • the transmission belt core wire and the transmission belt of the present invention it is possible to provide means capable of suppressing noise and maintaining, for example, a state suitable for use of a drive source, an auxiliary machine, and the like. .

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A core for a transmission belt capable of substantially suppressing the occurrence of noise by adding a sufficient performance to the drive belt when it is used in the drive belt. A drive belt which can effect a sufficient performance when it is used, and in which the occurrence of noise can be substantially suppressed.

Description

明 細 書  Specification
伝動ベルト用心線及び伝動ベルト 技術分野  Transmission belt core wire and transmission belt technology
[0001] 本発明は、伝動ベルト用心線及び伝動ベルトに関する。  The present invention relates to a transmission belt core wire and a transmission belt.
背景技術  Background art
[0002] 現在、駆動源から補機への動力の伝達には、伝動ベルトが用いられている。しかし ながら、駆動源から補機への動力の伝達に際して、伝動ベルトに起因して、騒音を生 じる場合がある。  [0002] Currently, a transmission belt is used to transmit power from a drive source to an auxiliary machine. However, when power is transmitted from the drive source to the auxiliary equipment, noise may be generated due to the transmission belt.
[0003] 例えば、自動車の補機駆動においては、オートテンショナ一を用い、各補機側のト ルクを 1本の Vリブドベルトによって駆動させるサーペンタインドライブ方式が多く採用 されている。し力 ながら、前記サーペンタインドライブ方式において、駆動側のトノレ クと補機側のトノレクとが共振して、オートテンショナ一の揺動が非常に大きくなり、ォー トテンショナ一のテンションプーリ上でベルトの叩き音等の騒音が発生する場合があ る。  [0003] For example, in the driving of auxiliary equipment for automobiles, a serpentine drive system is often employed in which an auto tensioner is used and the torque on each auxiliary equipment is driven by a single V-ribbed belt. However, in the serpentine drive system, the drive-side torque and the accessory-side torque will resonate and the swing of the auto tensioner will become very large, and the belt on the tension pulley of the auto tensioner will Noises such as tapping may occur.
[0004] これに対し、 Vリブドべノレ卜にぉレヽて、見カ ナの攀十生率を 1リブあたり 19600〜1000 00Nにすることにより、オートテンショナ一の揺動量を小さくする試みが提案されてい る(特許文献 1を参照のこと)。前記特許文献 1には、心線の材料として、従来から一 般的に用いられてきたポリエチレンテレフタレート繊維に代えて、ァラミド繊維、ポリビ ニルアルコール繊維又はポリエチレンナフタレート繊維を用いることが開示されてい る。  [0004] On the other hand, an attempt was made to reduce the amount of oscillation of the auto tensioner by setting the life span of the canopy to 19600 to 100000N per rib, following the V-ribbed borer. (See Patent Document 1). Patent Document 1 discloses using aramid fiber, polyvinyl alcohol fiber, or polyethylene naphthalate fiber instead of the polyethylene terephthalate fiber that has been generally used as a material for the core wire. .
[0005] しかし、ポリビュルアルコール繊維を用いた場合、加硫時、蒸気に触れることにより 湿熱劣化することから、完全に蒸気をシャットアウトできる製法を検討する必要があり 、現状では、安定的に量産することが困難であることがわかってきている。また、ポリ エチレンナフタレート繊維及び芳香族ポリアミド繊維は、ポリエチレンテレフタレート繊 維に比べて、難接着性であり、極端な屈曲を繰り返し受けた場合に心線がポップァゥ トする場合があるという欠点がある。  [0005] However, when polybulu alcohol fiber is used, wet heat degradation occurs when it is exposed to steam during vulcanization. Therefore, it is necessary to study a production method that can completely shut out steam. It has proven difficult to mass produce. In addition, polyethylene naphthalate fiber and aromatic polyamide fiber are less adhesive than polyethylene terephthalate fiber, and there is a drawback that the core wire may pop up when repeatedly subjected to extreme bending. .
[0006] このように、従来の伝動ベルトでは、使用に十分な性能を維持し、かつ十分に騒音 を抑制することができないという欠点がある。 [0006] Thus, the conventional transmission belt maintains sufficient performance for use and has sufficient noise. There is a drawback that it cannot be suppressed.
特許文献 1 :日本国特開 2001— 248692号公報  Patent Document 1: Japanese Patent Laid-Open No. 2001-248692
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems to be solved by the invention
[0007] 本発明は、上記従来の欠点に鑑みてなされたものであり、伝動ベルトに用いられた 場合、当該伝動ベルトに、使用に十分な性能 (例えば、耐久性等)を付与し、かつ例 えば、 Vリブドベルト等の心線として用いられた場合、揺動量を実質的に低下せしめ ること、使用に十分な性能 (例えば、耐久性等)を付与し、かつ騒音の発生を実質的 に抑制せしめること等の少なくとも 1つを達成する、伝動ベルト用心線を提供すること を課題とする。また、本発明は、使用に十分な性能 (例えば、耐久性等)を発揮し、か つ、例えば、 Vリブドベルト等として用いられた場合、揺動量を実質的に低下させるこ と、使用に十分な性能 (例えば、耐久性等)を発揮し、かつ騒音の発生を実質的に抑 制すること等の少なくとも 1つを達成する、伝動ベルトを提供することを課題とする。本 発明の他の課題は、本明細書の記載から明らかである。 [0007] The present invention has been made in view of the above-mentioned conventional drawbacks. When used in a transmission belt, the present invention provides the transmission belt with sufficient performance (for example, durability), and For example, when used as a core wire such as a V-ribbed belt, the swing amount is substantially reduced, sufficient performance (for example, durability) is provided, and noise generation is substantially reduced. It is an object to provide a transmission belt core wire that achieves at least one of restraining and the like. In addition, the present invention exhibits sufficient performance (for example, durability, etc.) for use, and when used as, for example, a V-ribbed belt, the swing amount is substantially reduced, which is sufficient for use. It is an object of the present invention to provide a transmission belt that achieves at least one of exhibiting excellent performance (for example, durability, etc.) and substantially suppressing noise generation. Other problems of the present invention are apparent from the description of the present specification.
課題を解決するための手段  Means for solving the problem
[0008] 本発明は、前記課題に鑑みてなされたものであり、ポリケトン繊維を含有しているこ とを特徴とする、伝動ベルト用心線に関する。また、本発明は、前記伝動ベルト用心 線が埋設されたものであることを特徴とする、伝動ベルトに関する。 [0008] The present invention has been made in view of the above problems, and relates to a core wire for a transmission belt characterized by containing polyketone fibers. The present invention also relates to a transmission belt, wherein the transmission belt core wire is embedded.
発明の効果  The invention's effect
[0009] 本発明の伝動ベルト用心線によれば、伝動ベルトに用いられた場合、当該伝動べ ノレトに、使用に十分な性能(例えば、耐久性等)を付与し、かつ例えば、 Vリブドベル ト等の心線として用レ、られた場合、揺動量を実質的に低下せしめること、使用に十分 な性能 (例えば、耐久性等)を付与し、かつ騒音の発生を実質的に抑制せしめること 等の少なくとも 1つを達成することができるという優れた効果を奏する。また、本発明 の伝動ベルトによれば、使用に十分な性能(例えば、耐久性等)を発揮し、かつ、例 えば、 Vリブドベルト等として用いられた場合、揺動量を実質的に低下させること、使 用に十分な性能 (例えば、耐久性等)を発揮し、かつ騒音の発生を実質的に抑制す ること等の少なくとも 1つを達成することができるという優れた効果を奏する。 [0009] According to the transmission belt core wire of the present invention, when used in a transmission belt, the transmission belt is provided with sufficient performance (for example, durability, etc.) for use, and for example, a V-ribbed belt. When used as a core wire, etc., the swing amount is substantially reduced, sufficient performance (for example, durability) is provided, and noise generation is substantially suppressed, etc. It has an excellent effect of achieving at least one of the following. Further, according to the transmission belt of the present invention, the performance sufficient for use (for example, durability, etc.) is exhibited and, for example, when used as a V-ribbed belt, the swing amount is substantially reduced. , Providing sufficient performance for use (for example, durability) and substantially suppressing noise generation It has an excellent effect that at least one of the above can be achieved.
図面の簡単な説明  Brief Description of Drawings
[0010] [図 1]図 1は、伝動ベルトの一例である Vリブドベルトの横断面図であり、ベルト長手方 向に直角な面の図を示す。  [0010] FIG. 1 is a cross-sectional view of a V-ribbed belt as an example of a transmission belt, and shows a view perpendicular to the longitudinal direction of the belt.
[図 2]図 2は、多軸伝動装置の概略図を示す。  FIG. 2 is a schematic view of a multi-axis transmission device.
[図 3]図 3は、多軸伝動装置の概略図を示す。  FIG. 3 is a schematic view of a multi-axis transmission device.
[図 4]図 4は、心線とモノフィラメントとを示す模式図である。図中、 Aの破線は、中心 線を示し、 Bの実線は、最小撚り単位の中心線を示す。また、図中、縦方向の太線は 、心線を示す。  FIG. 4 is a schematic diagram showing a core wire and a monofilament. In the figure, the broken line A shows the center line, and the solid line B shows the center line of the minimum twist unit. In the figure, the thick vertical line indicates the core.
符号の説明  Explanation of symbols
1 上面帆布層  1 Top canvas layer
2 心線  2 core wire
3 接着ゴム層  3 Adhesive rubber layer
4 リブゴム層  4 Rib rubber layer
5 リブ  5 ribs
6 駆動プーリ  6 Drive pulley
7 アイドラプーリ  7 idler pulley
8 エアコンプーリ  8 Air conditioner pulley
9 パワステプーリ  9 Power steering pulley
10 ウォータポンププーリ  10 Water pump pulley
11 オルタネータプーリ  11 Alternator pulley
12 オートテンショナ  12 Auto tensioner
13 テンションプーリ  13 Tension pulley
14 従動プーリ  14 Driven pulley
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0012] 本発明は、 1つの側面では、ポリケトン繊維を含有する、伝動ベルト用心線に関する  [0012] In one aspect, the present invention relates to a core wire for a transmission belt containing polyketone fibers.
[0013] 本発明の伝動ベルト用心線は、ポリケトン繊維を含有していることに 1つの大きな特 徴がある。したがって、本発明の伝動ベルト用心線は、伝動ベルト、例えば、 Vリブド ベルト等の心線として用いられた場合、該伝動ベルトに起因する共振による異音の発 生を実質的に抑制させうる。 [0013] The core wire for the transmission belt of the present invention contains polyketone fiber, which is one major feature. There are signs. Therefore, when the core wire for a transmission belt according to the present invention is used as a core wire for a transmission belt, for example, a V-ribbed belt, it is possible to substantially suppress the generation of noise due to resonance caused by the transmission belt.
[0014] また、本発明の伝動ベルト用心線は、伝動ベルト、例えば、 Vリブドベルト等の心線 として用いられた場合、ゴム組成物に対する優れた接着性を発現するため、当該伝 動ベルトが極端な屈曲を繰り返し受けた場合であっても、伝動ベルト用心線のポップ アウトを実質的に抑制することができる。さらに、本発明の伝動ベルト用心線によれば 、ポリケトン繊維を含有しているため、加硫時の湿熱に対する影響を実質的に抑制す ることができるという優れた効果を発揮する。  [0014] Further, when the core wire for a transmission belt of the present invention is used as a core wire for a transmission belt, for example, a V-ribbed belt, it exhibits excellent adhesion to a rubber composition. Even when repeated bending is repeated, pop-out of the transmission belt core wire can be substantially suppressed. Further, according to the core wire for a transmission belt of the present invention, since the polyketone fiber is contained, an excellent effect that the influence on wet heat at the time of vulcanization can be substantially suppressed is exhibited.
[0015] 本発明の伝動ベルト用心線において、ポリケトン繊維のモノフィラメントの傾斜角が 、ポリケトン繊維の長さ方向軸に対して、屈曲疲労性の観点から、 8° 以上であること が好ましぐ 12° 以上であることがより好ましぐベルト走行時の伸びの観点から、 24 。 以下であることが好ましぐ 20° 以下であることがより好ましい。力かる伝動ベルト 用心線によれば、伝動ベルトの製造に用いた場合、該伝動ベルトに優れた耐久性を 発現させることができ、かつ該伝動ベルトによる異音の発生を実質的に抑制させるこ とができる。  [0015] In the core wire for a transmission belt of the present invention, the inclination angle of the polyketone fiber monofilament is preferably 8 ° or more with respect to the longitudinal axis of the polyketone fiber from the viewpoint of bending fatigue. From the standpoint of elongation during belt travel, which is more preferred above 24. It is preferable that the angle is 20 ° or less. According to the core wire for the power transmission belt, when used in the manufacture of the power transmission belt, the power transmission belt can exhibit excellent durability, and the generation of abnormal noise due to the power transmission belt can be substantially suppressed. You can.
[0016] なお、本明細書において、前記傾斜角( α )は、心線のベルト周方向中心線(図 4 中の Αの破線)と最小撚り単位の中心線(図 4の Bの実線)とが交差している心線の観 察方向 [0016] In the present specification, the inclination angle ( α ) means the center line of the core in the belt circumferential direction (broken line in FIG. 4) and the center line of the minimum twist unit (solid line of B in FIG. 4). Observation direction of the core line intersecting with
表面のモノフィラメントのなす角度 (° ) (図 4参照)であり、式(1):  The angle (°) between the monofilaments on the surface (see Fig. 4), equation (1):
[0017] [数 1] [0017] [Equation 1]
« = |90 - + 90 - 0 I I ( 1 )  «= | 90-+ 90-0 I I (1)
[0018] 〔式(1)中、 βは、モノフィラメントの下撚り糸の直径方向の線の角度であり、式(2): [0019] [数 2]
Figure imgf000005_0001
[In the formula (1), β is the angle of the line in the diameter direction of the monofilament twist yarn, and the formula (2): [0019] [Equation 2]
Figure imgf000005_0001
[0020] 〔式(2)中、 Tは、下撚り回数(回/ 10cm)、 Dは、下撚り糸のトータル繊度(デニー ル)、 sは、比重を示す〕 [0020] [In the formula (2), T is the number of times of twisting (times / 10cm), D is the total fineness of the twisted yarn (denier) E), s indicates specific gravity]
により求められる角度、すなわち、換算すると、式 (2') : Angle obtained by, i.e., in terms of the formula (2 '):
[0021] [数 3] (2,)[0021] [Equation 3] (2,)
Figure imgf000006_0001
Figure imgf000006_0001
[0022] 〔式(2')中、 T 1は、下撚り回数(回/ 10cm)、 D 1は、下撚り糸のトータル繊度(dtex)[In the formula (2 ′), T 1 is the number of times of lower twist (times / 10 cm), D 1 is the total fineness of the lower twist yarn (dtex)
、 Sは、比重を示す〕 , S indicates specific gravity)
により求められる角度であり、 Θは、下撚り糸の上撚り糸直径方向線に対する角度で あり、式(3) :  Θ is the angle with respect to the upper twist diameter direction line of the lower twist yarn, and the equation (3):
[0023] [数 4] [0023] [Equation 4]
^θ-^μ= (3) ^ θ- ^ μ = (3)
[0024] 〔式(3)中、 T 2は、下撚り回数(回/ 10cm)、 D 2は、下撚り糸のトータル繊度(デニー ル)、 sは、比重を示す〕 [In Formula (3), T 2 is the number of times of lower twist (times / 10 cm), D 2 is the total fineness (denier) of the lower twist, and s is the specific gravity]
により算出される角度、すなわち、換算すると、式(3'):  The angle calculated by the equation (ie, the equation (3 ′) when converted):
[0025] [数 5] iane (3,)[0025] [ Equation 5] i ane (3,)
Figure imgf000006_0002
Figure imgf000006_0002
[0026] 〔式(3')中、 T 2は、下撚り回数(回/ 10cm)、 D 2は、下撚り糸のトータル繊度(dtex)[In formula (3 ′), T 2 is the number of times of twisting (times / 10 cm), D 2 is the total fineness of the twisted yarn (dtex)
、 sは、比重を示す〕 , S indicates specific gravity)
により算出される角度である〕  It is an angle calculated by
で算出される角度である。  Is an angle calculated by.
[0027] なお、ラング撚り等のように、下撚りと上撚りの撚り方向が同じ方向である場合、前記 式(1)においては、式(2)により算出された j3の値に対して、負の符号をつけた値を βとして用いる。また、片撚り等のように、 1回の撚りのみで心線が形成されている場 合には、 /3 =0とし、 ひは、式(4):  [0027] When the twist direction of the lower twist and the upper twist is the same direction, such as Lang twist, in the formula (1), with respect to the value of j3 calculated by the formula (2), The value with a negative sign is used as β. Also, when the core wire is formed by only one twist, such as single twist, / 3 = 0, and the formula (4):
[0028] [数 6] α = 90-θ (4) [0029] 〔式(4)中、 Θは、前記と同様である〕 [0028] [Equation 6] α = 90-θ (4) [In formula (4), Θ is the same as above]
により算出される。  Is calculated by
[0030] 前記ポリケトン繊維に用いられるポリケトンィ匕合物としては、特に限定されないが、 例えば、繰り返し単位の 90重量%以上が下記式 (I):  [0030] The polyketone compound used in the polyketone fiber is not particularly limited. For example, 90% by weight or more of the repeating units are represented by the following formula (I):
[0031] [化 1] [0031] [Chemical 1]
-^ C H2 C H2C O ^- ( I) -^ CH 2 CH 2 CO ^-(I)
[0032] で表される 1—ォキソトリメチレン単位から構成されるポリケトン等が挙げられる。本発 明においては、伝動ベルト、例えば、伝動ベルトの心線として埋設させた場合におけ る異音の抑制能、ゴム組成物との接着性及び耐湿熱劣化抑制能を伝動ベルトに十 分発現させる観点から、好ましくは、前記 1—ォキソトリメチレン単位力 構成されるポ リケトンである。なお、「繰り返し単位の 90重量%以上が前記式 (I)で表される 1—ォ キソトリメチレン単位から構成されるポリケトン」は、いいかえれば、重合させる 1—ォキ ソトリメチレンモノマー力 原材料中、 90重量%以上となるように重合反応を行なって 得られたものとしてもとらえられる。 [0032] Polyketones composed of 1-oxotrimethylene units represented by In the present invention, the transmission belt, for example, the ability to suppress abnormal noise when embedded as a core wire of the transmission belt, the adhesion to the rubber composition, and the ability to suppress moisture and heat deterioration are fully expressed in the transmission belt. From the viewpoint of making it preferable, the polyketone composed of the 1-oxotrimethylene unit force is preferable. The “polyketone composed of 1-oxotrimethylene units in which 90% by weight or more of the repeating units are represented by the above formula (I)” is, in other words, 1-oxotrimethylene monomer power to be polymerized. It can be regarded as a product obtained by carrying out a polymerization reaction so as to be 90% by weight or more.
[0033] 本発明の伝動ベルト用心線としては、好ましくは、前記ポリケトン繊維のフィラメント 力 なるものであることが望ましレ、。  [0033] The core wire for the transmission belt of the present invention preferably has a filament strength of the polyketone fiber.
[0034] 前記ポリケトン繊維の製造方法としては、具体的には、  [0034] As a method for producing the polyketone fiber, specifically,
(A) ポリケトンィ匕合物からなるフィラメントを製造する工程、及び  (A) producing a filament made of a polyketone compound, and
(B) 前記工程 (B)で得られたフィラメントを撚る工程  (B) A step of twisting the filament obtained in the step (B)
を含む方法等が挙げられる。  And the like.
[0035] 前記工程 (A)におレ、て、ポリケトン化合物からなるモノフィラメントは、特に限定され ないが、例えば、湿式紡糸法、乾式紡糸法等により製造されうる。前記湿式紡糸法は 、ポリケトン化合物含有溶液を、紡糸口金より凝固浴に吐出させ、得られた産物を乾 燥させ、熱延伸させる方法であり、前記乾式紡糸法は、前記ポリケトン化合物含有溶 液を、紡糸口金より吐出させ、高温雰囲気下に吐出された産物中に含まれる液体成 分を揮発させ、熱延伸させる方法である。  [0035] In the step (A), the monofilament composed of the polyketone compound is not particularly limited, and can be produced, for example, by a wet spinning method, a dry spinning method, or the like. The wet spinning method is a method in which a polyketone compound-containing solution is discharged from a spinneret into a coagulation bath, and the resulting product is dried and hot drawn. The dry spinning method is a method in which the polyketone compound-containing solution is dried. In this method, the liquid component contained in the product discharged from the spinneret and discharged in a high-temperature atmosphere is volatilized and hot stretched.
[0036] 前記ポリケトン化合物含有溶液は、前記ポリケトン化合物を、例えば、ハロゲン化亜 鉛化合物含有水溶液、へキサフルォロイソプロパノール、 m—クレゾール、レゾルシ ン、亜鉛水溶液等に溶解させることにより得られた溶液である。 [0036] The polyketone compound-containing solution contains the polyketone compound, for example, a halogenated suboxide. It is a solution obtained by dissolving in a lead compound-containing aqueous solution, hexafluoroisopropanol, m-cresol, resorcin, zinc aqueous solution or the like.
[0037] 前記モノフィラメントの繊維長は、繊維がもつ強度を生かす観点から、 10mm以上 であることが望ましい。また、前記モノフィラメントの径は、紡糸の容易性の観点から、[0037] The fiber length of the monofilament is preferably 10 mm or more from the viewpoint of taking advantage of the strength of the fiber. In addition, the diameter of the monofilament is from the viewpoint of easy spinning,
3 μ m〜40 μ mであることが望ましレ、。 Desired to be between 3 μm and 40 μm.
[0038] 前記工程 (B)においては、前記ポリケトンィ匕合物からなるモノフィラメントを、例えば[0038] In the step (B), a monofilament composed of the polyketone compound is, for example,
、下撚りと上撚りとを組み合わせて撚糸することにより、前記範囲の傾斜角となるよう する。 In addition, by twisting a combination of the lower twist and the upper twist, the inclination angle in the above range is obtained.
[0039] なお、本発明においては、ポリケトン繊維の総繊度は、使用目的に応じた範囲であ ればよレ、。前記総繊度は、ベルト走行中の張力に対する切断防止の観点から、 200 Odtex以上が好ましぐ 3000dtex以上がより好ましぐ屈曲疲労抑制の観点から、 1 2000dtex以下力 S好ましく、 7000dtex以下がより好ましい。  [0039] In the present invention, the total fineness of the polyketone fiber should be in a range according to the purpose of use. The total fineness is preferably not less than 200 Odtex, more preferably not less than 3000 dtex, and more preferably not more than 12,000 dtex, and more preferably not more than 7000 dtex from the viewpoint of suppressing bending fatigue. .
[0040] 具体的には、例えば、前記 1一才キソトリメチレン単位から構成されるポリケトンから なるモノフィラメントは、エチレンと一酸化炭素とをラジカル開始剤の存在下に希釈溶 媒中で重合することにより、繰り返し単位の 90重量%以上が 1—ォキソトリメチレン単 位であるポリケトンを得、ついで、該ポリケトンをハロゲンィ匕亜鉛化合物含有水溶液等 に溶解して得られたポリケトン含有溶液を、紡糸口金より凝固浴に吐出させ、得られ た産物を乾燥させ、熱延伸させること (湿式紡糸法);前記ポリケトン含有溶液を、紡 糸口金より吐出させ、高温雰囲気下に吐出された産物中に含まれる液体成分を揮発 させ、熱延伸させること(乾式紡糸法)等で得られうる。ついで、前記モノフィラメントを 、長さ方向軸に対して、傾斜角力 8° 〜24° となるように撚ることにより、ポリケトン 繊維が得られる。  [0040] Specifically, for example, the monofilament made of a polyketone composed of the 1-year-old xisotrimethylene unit is obtained by polymerizing ethylene and carbon monoxide in a dilute solvent in the presence of a radical initiator. To obtain a polyketone in which 90% by weight or more of the repeating units are units of 1-oxotrimethylene, and then dissolve the polyketone in an aqueous solution containing a halogenated zinc compound or the like to obtain a polyketone-containing solution. The product is discharged into a coagulation bath, and the resulting product is dried and hot drawn (wet spinning method); the polyketone-containing solution is discharged from a spinneret and contained in the product discharged in a high-temperature atmosphere. It can be obtained by volatilizing the liquid component and hot drawing (dry spinning method). Subsequently, polyketone fibers are obtained by twisting the monofilament so as to have an inclination angle force of 8 ° to 24 ° with respect to the longitudinal axis.
[0041] 前記製造方法においては、 (C) 前記工程 (B)で得られたポリケトン繊維を、イソシ ァネー Hヒ合物又はエポキシ化合物を含有した溶液(第 1処理液)に浸漬させる工程 、 (D) 前記工程 (C)で得られた産物を、 180°C〜280°Cに調整されたオーブンに 3 0秒〜 2分間通して乾燥させる工程、  [0041] In the production method, (C) a step of immersing the polyketone fiber obtained in the step (B) in a solution (first treatment liquid) containing an isocyanate H-hybrid compound or an epoxy compound. D) drying the product obtained in the step (C) by passing it through an oven adjusted to 180 ° C to 280 ° C for 30 seconds to 2 minutes;
(E) 前記工程 (D)で得られた繊維を、 RFL〔レゾノレシンとホルマリンとの初期縮合体 と、ラテックス(例えば、スチレン 'ブタジエン'ビュルピリジン共重合体、クロ口プレン等 )〕溶液(第 2処理液)に浸漬させる工程、及び (E) The fiber obtained in the step (D) is mixed with RFL [initial condensate of resorenosin and formalin and latex (for example, styrene 'butadiene' bullpyridine copolymer, black mouth plane, etc. )] Step of immersing in solution (second treatment liquid), and
(F) 前記工程(E)で得られた産物を、 180°C〜280°Cに調整されたオーブンに 30 秒〜 2分間通して乾燥させる工程、  (F) a step of drying the product obtained in the step (E) through an oven adjusted to 180 ° C to 280 ° C for 30 seconds to 2 minutes,
をさらに行なってもよレ、。これらの工程を行なうことにより、得られた繊維力 伝動ベル トに用いられるゴム成分等に対して、優れた接着性を発現する。  You can do more. By performing these steps, excellent adhesion to the rubber component used in the obtained fiber force transmission belt is exhibited.
[0042] 前記イソシァネートイ匕合物としては、特に限定されないが、例えば、 4, 4'—ジフエ ニルメタンジイソシァネート、 p_フエニルジイソシァネート、ポリメチレンポリフエニル ポリイソシァネート等が挙げられる。前記エポキシ化合物としては、例えば、多価アル コール(例えば、エチレングリコール、グリセリン、ペンタエリスリトール、ソルビトール等 )、ポリアルキレングリコール(例えば、ポリエチレングリコール等)等と、ハロゲン含有 エポキシ化合物(例えば、ェピクロルヒドリン等)との反応生成物;多価フエノール化合 物〔例えば、ビス(4—ヒドロキシフエニル)ジメチルェタン、フエノール'ホルムアルデヒ ド樹脂、レゾルシンホルムアルデヒド樹脂等〕とハロゲン含有エポキシィヒ合物との反応 生成物等が挙げられる。前記イソシァネートイ匕合物又はエポキシ化合物を含有した 溶液は、前記イソシァネー H匕合物又はエポキシ化合物を、例えば、トルエン等に溶 解させることにより得られうる。 [0042] The isocyanate compound is not particularly limited, and examples thereof include 4,4'-diphenylmethane diisocyanate, p_phenyldiisocyanate, polymethylene polyphenyl polyisocyanate, and the like. Can be mentioned. Examples of the epoxy compound include polyhydric alcohols (eg, ethylene glycol, glycerin, pentaerythritol, sorbitol, etc.), polyalkylene glycols (eg, polyethylene glycol, etc.), and halogen-containing epoxy compounds (eg, epichlore). Reaction products with hydrins, etc .; reaction products of polyhydric phenol compounds (eg bis (4-hydroxyphenyl) dimethylethane, phenol formaldehyde resins, resorcin formaldehyde resins, etc.) with halogen-containing epoxy compounds Etc. The solution containing the isocyanate compound or epoxy compound can be obtained by dissolving the isocyanate compound or epoxy compound in, for example, toluene.
[0043] なお、前記製造方法においては、前記工程 (E)を 2〜3回繰り返すことにより、接着 剤の付着量を安定させてもょレ、。  [0043] In the above production method, the amount of adhesive may be stabilized by repeating the step (E) 2 to 3 times.
[0044] また、前記製造方法においては、伝動ベルトに用いられるゴム成分等に対する心 線の接着性を十分に発揮させる観点、ベルト製造時におけるゴムとのタック性をあげ る観点力 、(F) 前記工程 (E)で得られた産物を、エポキシ化合物(エポキシ樹脂) 、フエノール化合物 (フエノール樹脂)等を含む溶液又は接着ゴム組成物若しくは該 接着ゴム組成物に近レ、組成のものを適切な溶剤に溶解させた溶液に浸漬させ、乾 燥させる工程をさらに行なってもよレ、。  [0044] Further, in the manufacturing method, the viewpoint of sufficiently exerting the adhesiveness of the core wire to the rubber component or the like used in the transmission belt, the viewpoint power to improve the tackiness with the rubber at the time of manufacturing the belt, (F) When the product obtained in the step (E) is a solution containing an epoxy compound (epoxy resin), a phenol compound (phenol resin) or the like, or an adhesive rubber composition It may be further immersed in a solution dissolved in a solvent and dried.
[0045] 本発明は、他の側面では、前記伝動ベルト用心線が埋設されていることを特徴とす る、伝動ベルトに関する。本発明の伝動ベルトは、本発明の伝動ベルト用心線が坦 設されているものであるため、使用に十分な性能 (例えば、耐久性等)を発揮し、かつ 、例えば、 Vリブドベルト等として用いられた場合、揺動量を実質的に低下させ、騒音 の発生を実質的に抑制することができる。 In another aspect, the present invention relates to a transmission belt characterized in that the transmission belt core wire is embedded. Since the power transmission belt of the present invention is mounted on the power transmission belt of the present invention, the power transmission belt of the present invention exhibits sufficient performance (for example, durability) and is used as, for example, a V-ribbed belt. If this occurs, the amount of rocking will be substantially reduced and noise will be reduced. Can be substantially suppressed.
[0046] 本発明の伝動ベルトは、例えば、オートテンショナ一を用いる場合における Vリブド ベルト等として用いられうる。  [0046] The transmission belt of the present invention can be used, for example, as a V-ribbed belt in the case of using an auto tensioner.
[0047] 本発明の伝動ベルトとしては、 ベルト(Vリブドベルト等)、平ベルト、歯付ベルト等 が挙げられる。 [0047] Examples of the transmission belt of the present invention include belts (V-ribbed belts, etc.), flat belts, toothed belts, and the like.
[0048] 以下、本発明の伝動ベルトとして、図 1に示される Vリブドベルトを一例として挙げ、 説明する。なお、本発明の伝動ベルトは、力かる例にのみ限定されるものではない。  [0048] Hereinafter, the V-ribbed belt shown in Fig. 1 will be described as an example of the transmission belt of the present invention. Note that the transmission belt of the present invention is not limited to a powerful example.
[0049] 図 1に示される Vリブドベルトは、ゴム組成物を構成部材とする接着ゴム層 3と、該接 着ゴム層 3の上面側に配された上面帆布層 1と、該接着ゴム層 3の下面側に配された リブゴム層 4とを有し、該上面帆布層 1と該接着ゴム層 3と該リブゴム層 4とは、一体と して形成されている。前記リブゴム層 4の底面側には、それぞれベルト長さ方向に延 在させるように設けられた 3つのリブ 5部がベルト幅方向に所定のピッチで形成されて いる。また、前記接着ゴム層 3のベルト厚さ方向中心領域には、略ベルト長さ方向に 伸びかつベルト幅方向に所定ピッチをおいて螺旋状に設けられた複数本の心線 2が 一定の間隔を設けて坦設されている。  [0049] The V-ribbed belt shown in FIG. 1 includes an adhesive rubber layer 3 having a rubber composition as a constituent member, an upper canvas layer 1 disposed on the upper surface side of the adhesive rubber layer 3, and the adhesive rubber layer 3 The upper surface canvas layer 1, the adhesive rubber layer 3, and the rib rubber layer 4 are integrally formed. On the bottom surface side of the rib rubber layer 4, three ribs 5 provided so as to extend in the belt length direction are formed at a predetermined pitch in the belt width direction. Further, in the central region of the adhesive rubber layer 3 in the belt thickness direction, a plurality of core wires 2 that extend in a substantially belt length direction and are spirally provided at a predetermined pitch in the belt width direction are arranged at regular intervals. It has been installed.
[0050] 接着ゴム層 3は、ゴム組成物からなる層である。前記ゴム組成物は、例えば、クロ口 プレンゴム、エチレンプロピレンジェンゴム、水素化二トリルゴム、アルキルクロロスル ホン化ポリエチレン等を単独で、又は 2種以上の混合物として含有したものである。か 力るゴム組成物は、本発明の目的を妨げないものであれば、後述の短繊維、無機充 填剤等の補強剤、共架橋剤、可塑剤、安定剤、加工助剤、着色剤等を適宜含有して いてもよい。かかる接着ゴム層 3は、ベルト本体部を形成し、かつ複数本の心線 4を保 持するゴム層としての役割をになう。  [0050] The adhesive rubber layer 3 is a layer made of a rubber composition. The rubber composition contains, for example, black-prene rubber, ethylene propylene rubber, hydrogenated nitrile rubber, alkyl chlorosulfonated polyethylene, etc. alone or as a mixture of two or more. As long as the rubber composition does not interfere with the object of the present invention, reinforcing agents such as short fibers and inorganic fillers described later, co-crosslinking agents, plasticizers, stabilizers, processing aids, and coloring agents. Etc. may be contained appropriately. The adhesive rubber layer 3 serves as a rubber layer that forms a belt main body and holds a plurality of core wires 4.
[0051] 上面帆布層 1は、ナイロン、綿等の織布にゴムを溶剤に溶力、したゴムのりによる接着 処理が施されて、ベルト上面に貼付されており、ベルト上面がフラットなプーリに当接 するように卷きかけられた場合には、動力伝達の一端を担う。  [0051] The upper surface canvas layer 1 is bonded to the upper surface of the belt by applying an adhesive treatment to a woven fabric such as nylon, cotton, etc., by dissolving the rubber in a solvent, and sticking to the upper surface of the belt. When it is urged to abut, it bears one end of power transmission.
[0052] リブゴム層 4は、前記接着ゴム層 3と同様に、クロロプレンゴム、エチレンプロピレン ジェンゴム、水素化二トリルゴム、アルキルスルホン化ポリエチレン等を含有したゴム 組成物からなるものである。力かるリブゴム層 4には、ベルト幅方向の弾性率を向上さ せるベぐベルト幅方向に配向するように、ナイロン繊維、ァラミド繊維、綿、ビニロン 等の短繊維が混入されていてもよい。 Vリブドベルトが、プーリに卷きかけられた際、 力かるリブゴム層 4がプーリに当接し、動力伝達の主体となる。 [0052] Like the adhesive rubber layer 3, the rib rubber layer 4 is made of a rubber composition containing chloroprene rubber, ethylene propylene rubber, hydrogenated nitrile rubber, alkylsulfonated polyethylene or the like. The elastic rib rubber layer 4 has improved elastic modulus in the belt width direction. Short fibers such as nylon fiber, aramid fiber, cotton, and vinylon may be mixed so as to be oriented in the belt width direction. When the V-ribbed belt is strung against the pulley, the strong rib rubber layer 4 comes into contact with the pulley and becomes the main component of power transmission.
[0053] なお、接着ゴム層 3及び上面帆布層 1については、前記リブゴム層 4と同様の組成 で、相当する厚さを有する層で代替することもできる。  [0053] The adhesive rubber layer 3 and the upper canvas layer 1 can be replaced with a layer having the same composition as the rib rubber layer 4 and a corresponding thickness.
[0054] 図 1に示される Vリブドベルトは、例えば、以下のように製造されうる。すなわち、円 筒金型に、ゴム糊等で接着処理を施した帆布を被せ、前記帆布の上に、ゴム組成物 力、らなるゴムシートを巻き付ける。力、かるゴムシート上に、本発明の伝動ベルト用心線 を巻き付ける。前記伝動ベルト用心線の上に、ゴム組成物からなるゴムシートを卷き 付ける。これにより、積層体が得られる。ついで、得られた円筒状の積層体を保持し た円筒金型を、加硫缶に導入する。その後、外部から高圧水蒸気により加圧して、前 記加硫缶内部の積層体を加熱することで、加硫し、一体化させ、ゴム円筒体を得る。 得られたゴム円筒体の外周面を砥石で研削し、それにより、周方向に延び且つ円筒 軸方向に所定ピッチで形成された複数の突条を設ける。ついで、前記突条 3つ分の 幅で、ゴム円筒体を所定の幅で輪切りすることにより、伝動ベルト (Vリブドベルト)が 得られる。  [0054] The V-ribbed belt shown in FIG. 1 can be manufactured as follows, for example. In other words, a cylindrical mold is covered with a canvas that has been subjected to adhesion treatment with rubber glue or the like, and a rubber sheet having a rubber composition force is wound on the canvas. The core wire for the transmission belt of the present invention is wound around the rubber sheet. A rubber sheet made of a rubber composition is rubbed onto the transmission belt core wire. Thereby, a laminated body is obtained. Next, the cylindrical mold holding the obtained cylindrical laminate is introduced into the vulcanizing can. Thereafter, pressurization is performed from outside with high-pressure steam, and the laminated body inside the vulcanizing can is heated to vulcanize and integrate to obtain a rubber cylinder. The outer peripheral surface of the obtained rubber cylindrical body is ground with a grindstone, thereby providing a plurality of protrusions extending in the circumferential direction and formed at a predetermined pitch in the cylindrical axis direction. Next, a transmission belt (V-ribbed belt) is obtained by cutting the rubber cylinder into a predetermined width with a width corresponding to the three protrusions.
[0055] 以下、本発明を実施例等により詳細に説明するが、本発明は、かかる実施例に限 定されるものではない。  Hereinafter, the present invention will be described in detail with reference to examples and the like, but the present invention is not limited to such examples.
実施例  Example
[0056] (実施例 1) [Example 1]
(伝動ベルト用心線の製造)  (Manufacture of core wire for transmission belt)
l lOOdtexに束ねられたポリケトン繊維〔旭化成せんい株式会社製、商品名:サイ バロン™、強度: 18cN/dtex、伸度: 6%、引張弾性度: 335cNZdtex〕のマルチフ イラメントを 2本引きそろえ、下撚りを所定回数かけ、それを 3本束ねて上撚りをかけ、 フィラメント角度〔傾斜角(ひ)〕 5° 、合計 6600dtexの心線(1100dtex/2 X 3)を 得た。得られた心線を、イソシァネート(住化バイエルウレタン株式会社製、スミジユー ル 44V20)の 20容積% トルエン溶液に浸漬させた後、 240°Cで 40秒間、加熱乾燥 させて前処理した。前記心線を、レゾルシン ホルマリン ラテックス (RFL)溶液〔レ ゾルシン (住友化学株式会社製)、ホルマリン (広栄化学工業株式会社製)、ラテック ス(CRラテックス)(昭和電工株式会社製)〕に浸漬させて、接着処理を施し、ついで、 熱延伸固定処理を施した。 l Two multifilaments of polyketone fiber (made by Asahi Kasei Fibers Co., Ltd., trade name: Cyvalon ™, strength: 18cN / dtex, elongation: 6%, tensile elasticity: 335cNZdtex) bundled in lOOdtex Twisting was applied a predetermined number of times, and three of them were bundled and subjected to top twisting to obtain a core angle (1100 dtex / 2 X 3) with a filament angle (inclination angle (h)) of 5 ° and a total of 6600 dtex. The obtained core wire was immersed in a 20% by volume toluene solution of isocyanate (Sumidure 44V20, manufactured by Sumika Bayer Urethane Co., Ltd.) and then pre-treated by heating and drying at 240 ° C for 40 seconds. The cord is resorcinol formalin latex (RFL) solution Soaked in Zorcine (Sumitomo Chemical Co., Ltd.), formalin (Guangei Chemical Industry Co., Ltd.), Latex (CR Latex) (Showa Denko Co., Ltd.)] gave.
[0057] なお、前記フィラメント角度〔傾斜角(ひ)〕は、前記式(1)で求められた角度 (° )で ある。 [0057] The filament angle [inclination angle (h)] is an angle (°) determined by the equation (1).
[0058] (実施例 2)  [Example 2]
(伝動ベルトの製造)  (Manufacture of transmission belt)
周長 1000mmの円筒金型に、 RFL溶液を用いて接着処理を施し、糊引き処理を 行なった綿'ポリエステル混紡帆布をバイヤス状に被せた。前記帆布の上に、ェチレ ン一プロピレン一ジェンゴム組成物(住友化学株式会社製、商品名:エスプレン 30) 力 なる第 1接着ゴム用シートを巻き付けた。力かる第 1接着ゴム用シート上に、前記 実施例 1で得られた心線を卷きつけた。  A cylindrical mold having a circumferential length of 1000 mm was subjected to an adhesive treatment using an RFL solution, and a cotton / polyester blended canvas subjected to a pasting treatment was covered in a biased shape. On the canvas, an ethylene / propylene / gen rubber composition (manufactured by Sumitomo Chemical Co., Ltd., trade name: Esprene 30) was wound. The core wire obtained in Example 1 was beaten on the strong first adhesive rubber sheet.
[0059] さらに、前記心線の上に、エチレン プロピレン ジェンゴム組成物からなる第 2接 着ゴム用シートを巻き付けた。このようにして得られた円筒金型を、加硫缶に入れ、内 圧 588kPa (6kgf/cm2)、外圧 883kPa (9kgf/cm2)、 165。C、 35分間の条件でカロ 硫して、ゴム円筒体を得た。 [0059] Further, a second adhesive rubber sheet made of an ethylene-propylene-gen rubber composition was wound on the core wire. The thus obtained cylindrical mold obtained, placed in a vulcanizer, the inner pressure 588kPa (6kgf / cm 2), the external pressure 883kPa (9kgf / cm 2), 165. C. Sulfurized under conditions of 35 minutes to obtain a rubber cylinder.
[0060] 得られたゴム円筒体の外周面を砥石で研削し、それにより、周方向に延び且つ円 筒軸方向に所定ピッチで形成された複数の突条 (形状: PK形)を設けた。ついで、前 記突条 3つ分の幅で、ゴム円筒体を輪切りにすることにより、伝動ベルト (Vリブドベル ト)を得た。得られたベルトは、ベルト総厚さが 4. 3mm、リブ高さが 2. Ommであった  [0060] The outer peripheral surface of the obtained rubber cylindrical body was ground with a grindstone, thereby providing a plurality of protrusions (shape: PK shape) extending in the circumferential direction and formed at a predetermined pitch in the cylinder axis direction. . Next, a transmission belt (V-ribbed belt) was obtained by cutting the rubber cylinder into a ring with a width corresponding to the three protrusions. The resulting belt had a total belt thickness of 4.3 mm and a rib height of 2. Omm.
[0061] (比較例 1) [0061] (Comparative Example 1)
前記実施例 1と同様の手法により、ポリエチレンテレフタレートの心線(l lOOdtexZ 2 X 3)を作製した。得られた心線を用レ、、前記実施例 2と同様の手法で伝動ベルト( Vリブドベルト)を得た。  In the same manner as in Example 1, a polyethylene terephthalate core (lOOdtexZ 2 X 3) was produced. A transmission belt (V-ribbed belt) was obtained in the same manner as in Example 2 using the obtained core wire.
[0062] (比較例 2) [0062] (Comparative Example 2)
前記実施例 1と同様の手法により、ポリエチレンナフタレートの心線(1100dtexZ2 X 3)を作製した。得られた心線を用レ、、前記実施例 2と同様の手法で伝動ベルト (V リブドベルト)を得た。 In the same manner as in Example 1, a polyethylene naphthalate core wire (1100 dtex Z2 X 3) was produced. Using the obtained core wire, a transmission belt (V Ribbed belt) was obtained.
[0063] (試験例 1)  [0063] (Test Example 1)
前記実施例 1、比較例 1及び比較例 2の Vリブドベルトそれぞれを、図 2に示される 多軸伝動装置の伝動ベルトとして用い、室温条件下(25°C)、多軸伝動装置を作動 させてオートテンショナ 12の揺動量を測定した。図 2のオルタネータプーリ 11のプー リ径を 55mm、この負荷を 1103Wとし、エアコンプーリ 8のプーリ径を 95mm、この負 荷を 809Wとし、またパワステプーリ 9のプーリ径を 115mm、この負荷を 588Wとし、 さらにウォータポンププーリ 10のプーリ径を 115mm、この負荷を 37Wとした。また、 アイドラプーリ 7のプーリ径を 90mmとし、またテンションプーリ 13のプーリ径を 70mm 、そのアーム長さを 75mm、ベルトに加える張力を 147Nとし、さらに駆動プーリ 6の プーリ径を 120mm、その回転数を 1000rpm、駆動軸回転変動率を ± 10%とした。 結果を、表 1に示す。  Using each of the V-ribbed belts of Example 1, Comparative Example 1 and Comparative Example 2 as the transmission belts of the multi-axis transmission device shown in FIG. 2, the multi-axis transmission device was operated at room temperature (25 ° C). The amount of swing of the auto tensioner 12 was measured. The pulley diameter of alternator pulley 11 in Fig. 2 is 55 mm, this load is 1103 W, pulley diameter of air conditioner pulley 8 is 95 mm, this load is 809 W, power steering pulley 9 pulley diameter is 115 mm, and this load is 588 W. In addition, the water pump pulley 10 has a pulley diameter of 115 mm and a load of 37 W. The idler pulley 7 has a pulley diameter of 90 mm, the tension pulley 13 has a pulley diameter of 70 mm, its arm length is 75 mm, the tension applied to the belt is 147 N, and the drive pulley 6 has a pulley diameter of 120 mm and its rotational speed. Was 1000 rpm, and the drive shaft rotation fluctuation rate was ± 10%. The results are shown in Table 1.
[0064] [表 1] [0064] [Table 1]
Figure imgf000013_0001
Figure imgf000013_0001
[0065] その結果、表 1に示されるように、ポリケトン繊維からなる心線が埋設された実施例 1 の Vリブドベルトによれば、ポリエチレンテレフタレートからなる心線又はポリエチレン ナフタレートからなる心線が埋設された比較例 1及び 2の各 Vリブドベルトに比べ、ォ ートテンショナ一の揺動量が驚くべく低くなつていることがわかる。  As a result, as shown in Table 1, according to the V-ribbed belt of Example 1 in which the core wire made of polyketone fiber was embedded, the core wire made of polyethylene terephthalate or the core wire made of polyethylene naphthalate was embedded. Compared with the V-ribbed belts of Comparative Examples 1 and 2, it can be seen that the swing amount of the auto tensioner is surprisingly low.
[0066] (試験例 2)  [0066] (Test Example 2)
(1)実験番号 1  (1) Experiment number 1
心線を、 1650dtex/l X 3、フィラメント角度 8° のポリケトン繊維〔旭化成せんい株 式会社製、商品名:サイバロン™、強度: 18cN/dteX、伸度: 6%、引張弾性度: 33 5cN/dtex〕としたことを除き、実施例 1と同様の操作により心線を得、ついで、実施 例 2と同様の操作により、 Vリブドベルトを得た。 A polyketone fiber with a core of 1650dtex / l X 3 and a filament angle of 8 ° (Asahi Kasei Fibers Co., Ltd., trade name: Cyvalon ™, strength: 18cN / dte X , elongation: 6%, tensile elasticity: 33 5cN / dt ex ], a cord was obtained by the same operation as in Example 1, and then a V-ribbed belt was obtained by the same operation as in Example 2.
[0067] (2)実験番号 2 心線を、 1650dtex/l X 3、フィラメント角度 24° のポリケトン繊維〔旭化成せんい 株式会社製、商品名:サイバロン™、強度:18cN/dtex、伸度 : 6%、引張弾性度:3 35cN/dtex〕としたことを除き、実施例 1と同様の操作により心線を得、ついで、実 施例 2と同様の操作により、 Vリブドベルトを得た。 [0067] (2) Experiment number 2 A polyketone fiber with a core wire of 1650 dtex / l X 3 and a filament angle of 24 ° [made by Asahi Kasei Fibers Co., Ltd., trade name: Cyvalon ™, strength: 18 cN / dt ex , elongation: 6%, tensile elasticity: 335 cN / A cord was obtained by the same operation as in Example 1 except that dtex], and then a V-ribbed belt was obtained by the same operation as in Example 2.
[0068] (3)実験番号 3 [0068] (3) Experiment number 3
心線を、 1650dtex/l X 3、フィラメント角度 5° のポリケトン繊維〔旭化成せんい株 式会社製、商品名:サイバロン™、強度: 18cN/dteX、伸度: 6%、引張弾性度:33 5cN/dtex〕としたことを除き、実施例 1と同様の操作により心線を得、ついで、実施 例 2と同様の操作により、 Vリブドベルトを得た。 A polyketone fiber with a core of 1650dtex / l X 3 and a filament angle of 5 ° (Asahi Kasei Fibers Co., Ltd., trade name: Cyvalon ™, strength: 18cN / dte X , elongation: 6%, tensile elasticity: 33 5cN / dtex], a core wire was obtained by the same operation as in Example 1, and then a V-ribbed belt was obtained by the same operation as in Example 2.
[0069] (4)実験番号 4 [0069] (4) Experiment number 4
心線を、 1650dtex/l X 3、フィラメント角度 26° のポリケトン繊維〔旭化成せんい 株式会社製、商品名:サイバロン™、強度: 18cN/dteX、伸度: 6%、引張弾性度:3 35cN/dtex〕としたことを除き、実施例 1と同様の操作により心線を得、ついで、実 施例 2と同様の操作により、 Vリブドベルトを得た。 A polyketone fiber with a core wire of 1650 dtex / l X 3 and a filament angle of 26 ° [Asahi Kasei Fibers Corporation, trade name: Cyvalon ™, strength: 18 cN / dte X , elongation: 6%, tensile elasticity: 335 cN / A cord was obtained by the same operation as in Example 1 except that dtex], and then a V-ribbed belt was obtained by the same operation as in Example 2.
[0070] (5)実験番号 5 [0070] (5) Experiment number 5
心線を、 1100dtex/2 X 3、フィラメント角度 5° のポリエチレンナフタレート(商品 名:タイプ Q904M、帝人テクノプロダクツ株式会社製)からなる心線としたことを除き 、実施例 2と同様の操作により、 Vリブドベルトを得た。  The core wire was the same as in Example 2 except that the core wire was made of polyethylene naphthalate (trade name: Type Q904M, manufactured by Teijin Techno Products Co., Ltd.) with 1100dtex / 2 X 3 and filament angle of 5 °. A V-ribbed belt was obtained.
[0071] (6)実験番号 6 [0071] (6) Experiment number 6
心線を、 1650dtex/l X 3、フィラメント角度 5° の芳香族ポリアミド(商品名:テクノ ーラ、帝人テクノプロダクツ株式会社製)からなる心線としたことを除き、実施例 2と同 様の操作により、 Vリブドベルトを得た。  The core is the same as in Example 2 except that the core is made of aromatic polyamide (trade name: Technora, manufactured by Teijin Techno Products Co., Ltd.) with 1650 dtex / l X 3 and filament angle of 5 °. By operation, a V-ribbed belt was obtained.
[0072] (7)実験番号 7 [0072] (7) Experiment number 7
心線を、 1100dtex/2 X 3、フィラメント角度 5° のポリビュルアルコール(商品名: 株式会社クラレ製、商品名クラロン)からなる心線としたことを除き、実施例 2と同様の 操作により、 Vリブドベルトを得た。  Except that the core wire is a core wire made of polybulal alcohol (trade name: manufactured by Kuraray Co., Ltd., trade name: Claron) with 1100 dtex / 2 X 3 and a filament angle of 5 °, the same operation as in Example 2 was performed. A V-ribbed belt was obtained.
[0073] (8) Vリブドベルトの評価 [0073] (8) Evaluation of V-ribbed belt
前記実験番号 1〜7の Vリブドベルトそれぞれを、図 3に示すように駆動プーリ 6 (直 径 120mm)と従動プーリ 14 (直径 120mm)とこれらのプーリの間に配置したアイドラ 一プーリ 7 (直径 70mm)とテンションプーリ 13 (直径 55mm)と力 なるベルト駆動シ ステムに取り付けた。アイドラープーリ 7にはベルト背面を係合させた。温度 110°Cの 雰囲気温度の下で、従動プーリ 14の負荷を 11. 9kw (16馬力)とし、テンションプー リ 13の初張力を 833N (85kgf)とし、駆動プーリ 6を回転数 4900rpmで駆動して、ベ ルトを走行させた。また、走行前後のベルトの引っ張り強さの測定を行レ、、強力維持 率〔走行後の強力 Z走行前の強力〕を求めた。結果を表 2に示す。 Each of the V-ribbed belts of Experiment Nos. 1 to 7 is connected to the drive pulley 6 (direct It was attached to a belt drive system with a force of 120 mm (diameter), driven pulley 14 (diameter 120 mm), idler pulley 7 (diameter 70 mm) and tension pulley 13 (diameter 55 mm) arranged between these pulleys. The idler pulley 7 was engaged with the back of the belt. Under an ambient temperature of 110 ° C, the load of the driven pulley 14 is set to 11.9 kw (16 horsepower), the initial tension of the tension pulley 13 is set to 833 N (85 kgf), and the drive pulley 6 is driven at a rotational speed of 4900 rpm. The belt was run. In addition, the tensile strength of the belt before and after running was measured, and the strength maintenance rate (strength after running Z before running) was determined. The results are shown in Table 2.
[¾2]  [¾2]
Figure imgf000015_0001
Figure imgf000015_0001
[0075] その結果、ポリケトン繊維からなる心線が埋設された Vリブドベルトの場合、騒音が 抑制され、さらに、特に、実験番号 1及び 2の Vリブドベルトのように、フィラメント角度 、 8° 〜24° であるポリケトン繊維からなる心線が埋設された Vリブドベルトは、フィ ラメント角度 5° 又は 26° のポリケトン繊維力 なる心線に比べ、耐久性にも優れるこ と力 sわ力る。 As a result, in the case of a V-ribbed belt in which a core made of polyketone fiber is embedded, noise is suppressed, and in particular, as in the V-ribbed belts of Experiment Nos. 1 and 2, the filament angle is 8 ° to 24 °. the V-ribbed belt core wires are embedded consisting of polyketone fibers is, filament angle 5 ° or compared to 26 ° of the polyketone fiber strength becomes cord, this and the force s Wachikararu also excellent in durability.
産業上の利用可能性  Industrial applicability
[0076] 本発明の伝動ベルト用心線及び伝動ベルトによれば、騒音が抑制され、かつ例え ば、駆動源、補機等の使用に適した状態の維持が可能な手段の提供が可能になる。 [0076] According to the transmission belt core wire and the transmission belt of the present invention, it is possible to provide means capable of suppressing noise and maintaining, for example, a state suitable for use of a drive source, an auxiliary machine, and the like. .

Claims

請求の範囲 The scope of the claims
ポリケトン繊維を含有してなることを特徴とする、伝動ベルト用心線。  A core wire for a transmission belt, comprising polyketone fiber.
該ポリケトン繊維のモノフィラメントの傾斜角力 心線の長さ方向軸に対して、 8〜24 Inclination angular force of the monofilament of the polyketone fiber 8-24 with respect to the longitudinal axis of the core wire
° である、請求項 1記載の伝動ベルト用心線。 The core wire for a transmission belt according to claim 1, wherein:
請求項 1または 2記載の伝動ベルト用心線が埋設されてなることを特徴とする、伝動 ベノレ卜。  A power transmission belt, wherein the power cable core wire according to claim 1 or 2 is embedded.
Vリブドベルトである、請求項 3記載の伝動ベルト。  The power transmission belt according to claim 3, which is a V-ribbed belt.
PCT/JP2007/055748 2006-04-05 2007-03-20 Core for transmission belt, and transmission belt WO2007114052A1 (en)

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US12/296,198 US20100105510A1 (en) 2006-04-05 2007-03-20 Core wire for transmission belt and transmission belt
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JP6740494B1 (en) * 2019-03-19 2020-08-12 三ツ星ベルト株式会社 Processing agent for core wire for power transmission belt, core wire and manufacturing method thereof
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