WO2007105011A1 - Thermal diffusion barrier - Google Patents

Thermal diffusion barrier Download PDF

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Publication number
WO2007105011A1
WO2007105011A1 PCT/GB2007/050098 GB2007050098W WO2007105011A1 WO 2007105011 A1 WO2007105011 A1 WO 2007105011A1 GB 2007050098 W GB2007050098 W GB 2007050098W WO 2007105011 A1 WO2007105011 A1 WO 2007105011A1
Authority
WO
WIPO (PCT)
Prior art keywords
thermal barrier
thermal
coil
barrier
barrier according
Prior art date
Application number
PCT/GB2007/050098
Other languages
French (fr)
Inventor
Paul Beasley
Adrian Mark Thomas
Original Assignee
Siemens Magnet Technology Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Magnet Technology Limited filed Critical Siemens Magnet Technology Limited
Publication of WO2007105011A1 publication Critical patent/WO2007105011A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/02Shape or form of insulating materials, with or without coverings integral with the insulating materials
    • F16L59/029Shape or form of insulating materials, with or without coverings integral with the insulating materials layered
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C13/00Details of vessels or of the filling or discharging of vessels
    • F17C13/001Thermal insulation specially adapted for cryogenic vessels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/14Arrangements for modifying heat-transfer, e.g. increasing, decreasing by endowing the walls of conduits with zones of different degrees of conduction of heat
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F6/00Superconducting magnets; Superconducting coils
    • H01F6/02Quenching; Protection arrangements during quenching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F6/00Superconducting magnets; Superconducting coils
    • H01F6/04Cooling
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F6/00Superconducting magnets; Superconducting coils
    • H01F6/06Coils, e.g. winding, insulating, terminating or casing arrangements therefor

Definitions

  • the invention is concerned with barriers to thermal diffusion and has particular utility in superconducting coils.
  • Magnetic Resonance Imaging (MRI) scanners employ superconducting coils to generate the strong magnetic fields necessary for operation of the instrument.
  • the coil is maintained at a low temperature (typically about 4K) by means of a cryogenic refrigerant.
  • the invention provides a thermal diffusion barrier which achieves improved thermal isolation between, for example, a coil and an interface plane without use of excessive material thickness.
  • a thermal diffusion barrier comprises the features set out in claim 1 attached hereto.
  • a thermal diffusion barrier comprises the features set out in claim 10 attached hereto.
  • a thermal diffusion barrier comprises the features set out in claim 17 attached hereto.
  • a thermal diffusion barrier 1 is located between a superconducting coil 2 and a support structure 3. Relative movement of the barrier 1 against the support structure 3 gives rise to heat Q which, to some extent, passes through the barrier and causes a local temperature rise in the coil 2.
  • a porous layer loaded with fluid serves as the thermal diffusion barrier 1 between the coil 2 and the support structure 3.
  • the porous layer is loaded with a fluid that has a high specific heat capacity, for example helium (volume specific heat of 3.7 x 10 '3 J/cc/K), to provide a barrier having a greater capacity to absorb heat generated at the barrier/former interface, thus protecting the coil.
  • a fluid that has a high specific heat capacity for example helium (volume specific heat of 3.7 x 10 '3 J/cc/K), to provide a barrier having a greater capacity to absorb heat generated at the barrier/former interface, thus protecting the coil.
  • the porous layer could be realised as multiple layers of epoxy impregnated cloth.
  • An open weave cloth would be suitable for this purpose, that is a woven fibre material wherein the gaps between the material strands are of a similar size to, or greater than, the size of the strands themselves.
  • the thermal barrier 1 comprises a high specific heat capacity solid state composite.
  • the composite takes the form of a filled resin comprising a material with a low temperature magnetic phase change causing it to have a high specific heat capacity in the temperature range where the phase change occurs.
  • a material with a low temperature magnetic phase change causing it to have a high specific heat capacity in the temperature range where the phase change occurs.
  • Such materials are typically compounds based on the heavy transition elements, Holmium, Erbium or Gadolinium.
  • the preferred material for this application would be Gadolinium Oxysulphide (GOS) having a phase change in the 4 - 5.5K temperature range and being of reasonable cost.
  • GOS Gadolinium Oxysulphide
  • the material is used in powder form dispersed within an epoxy resin (bisphenol epoxy).
  • This filled resin may be further combined with a filamentary material such as glass or polymer fibres to create mechanical properties which match those of the coil.
  • the anisotropic barrier necessary for one embodiment of the invention could be realised as a plurality of layers of material wherein alternate layers have high (layers 4) and low (layers 5) thermal conductivity.
  • High conductivity layers would typically be metallic in nature while low conductivity layers would be polymer based.
  • thermo diffusion barrier having a plurality of layers wherein alternate layers are materials of high thermal conductivity (for example metal foil) and porous material impregnated with helium.
  • These structures bonded into the coil block can also include mechanisms for direct cooling of the coils and interface.
  • cooling tubes, carrying liquid cryogens can also be embedded, improving their efficiency.

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Magnetic Resonance Imaging Apparatus (AREA)
  • Containers, Films, And Cooling For Superconductive Devices (AREA)

Abstract

Thermal diffusion barrier is described which provides improved thermal insulation between two regions. It has particular utility in the field of superconducting magnets where small localised temperature rises can lead to quenching of the magnet. A number of embodiments are described utilizing materials having anisotropic thermal conductivity; high specific heat capacity and low temperature magnetic phase change.

Description

Thermal Diffusion Barrier
The invention is concerned with barriers to thermal diffusion and has particular utility in superconducting coils.
Medical equipment such as Magnetic Resonance Imaging (MRI) scanners employ superconducting coils to generate the strong magnetic fields necessary for operation of the instrument. In order to achieve the superconducting state, the coil is maintained at a low temperature (typically about 4K) by means of a cryogenic refrigerant.
Failure to control the coil temperature can lead to quenching, where the coil enters a normal conducting state and the magnetic field collapses. This can occur as a result of localised heating in the coil which causes a localised increase in resistance. The increased resistance gives rise to further temperature rises which in turn gives rise to further increased resistance and so on. Thus, a localised temperature rise can give rise to complete quenching of the coil in a very short time. Typically a temperature increase of O.δKelvin for more than 10 ms will be sufficient to initiate the event
Electromagnetic forces generated within superconducting coils induce small discrete wire or bulk movements, particularly circumferential expansion of the coil structure. In multi-coil systems, the coils experience whole body forces which are restrained through interaction with a mechanical structure. Movement at the interface between the coil and the restraining former is a mechanism for energy release. Since materials (particularly solids) generally have low specific heat capacity at low temperature, the energy released at this interface is capable of locally raising the temperature of the superconductor above its critical temperature and inducing a quench.
Energy release at the interface has previously been limited through a number of techniques. Bonding the coil to the support structure can be employed but is often unreliable due to weaknesses in the bond, and the effect of stress transferred into the coil structure.
More generally, a low friction interface has been created through the use of flouropolymer materials to minimise energy dissipation. In another approach, a layer of low thermal conductivity material bonded to the coil structure acts as a thermal barrier. This is normally a fibre composite. Although fibre composites offer better specific heat capacity than many homogeonous materials, their properties are still poor at low temperature and significant thicknesses must be used to achieve any benefit.
This introduces a further problem of delamination if the thermal and mechanical properties of the composite are not well matched to those of the coil.
There are examples were thermally and mechanically matched materials have also been employed with limited success (e.g. copper or aluminium rings).
The invention provides a thermal diffusion barrier which achieves improved thermal isolation between, for example, a coil and an interface plane without use of excessive material thickness.
According to a first aspect of the invention, a thermal diffusion barrier comprises the features set out in claim 1 attached hereto.
According to a second aspect of the invention, a thermal diffusion barrier comprises the features set out in claim 10 attached hereto.
According to a third aspect of the invention, a thermal diffusion barrier comprises the features set out in claim 17 attached hereto.
Referring to figure 1 , a thermal diffusion barrier 1 is located between a superconducting coil 2 and a support structure 3. Relative movement of the barrier 1 against the support structure 3 gives rise to heat Q which, to some extent, passes through the barrier and causes a local temperature rise in the coil 2.
In one embodiment, a porous layer loaded with fluid serves as the thermal diffusion barrier 1 between the coil 2 and the support structure 3.
Most solid state materials have very low specific heat capacities (for example Copper has a volume specific heat of 8.1 x 10'4 J/cc/K) which renders them unsuitable as thermal insulators for superconducting coils: only a small amount of heat is required to raise the temperature of the material and consequently that of the coil. In this embodiment the porous layer is loaded with a fluid that has a high specific heat capacity, for example helium (volume specific heat of 3.7 x 10'3 J/cc/K), to provide a barrier having a greater capacity to absorb heat generated at the barrier/former interface, thus protecting the coil.
The porous layer could be realised as multiple layers of epoxy impregnated cloth. An open weave cloth would be suitable for this purpose, that is a woven fibre material wherein the gaps between the material strands are of a similar size to, or greater than, the size of the strands themselves.
In another embodiment of the invention, the thermal barrier 1 comprises a high specific heat capacity solid state composite.
The composite takes the form of a filled resin comprising a material with a low temperature magnetic phase change causing it to have a high specific heat capacity in the temperature range where the phase change occurs. Such materials are typically compounds based on the heavy transition elements, Holmium, Erbium or Gadolinium. The preferred material for this application would be Gadolinium Oxysulphide (GOS) having a phase change in the 4 - 5.5K temperature range and being of reasonable cost.
The material is used in powder form dispersed within an epoxy resin (bisphenol epoxy). This filled resin may be further combined with a filamentary material such as glass or polymer fibres to create mechanical properties which match those of the coil.
Referring to figure 2 another thermal diffusion barrier 1 a according to the current invention comprises a barrier having anisotropic thermal conductivity, and is arranged so that the thermal conductivity Ky in a direction substantially parallel with the interface between the barrier 1 and the coil 2 is greater than the thermal conductivity Kx in a direction substantially normal to the interface.
This arrangement provides an increased tendency for heat to dissipate along the thermal diffusion barrier 1 rather than passing through to cause localized heating of the coil. Referring to figure 3, the anisotropic barrier necessary for one embodiment of the invention could be realised as a plurality of layers of material wherein alternate layers have high (layers 4) and low (layers 5) thermal conductivity.
Multiple layer composite comprising alternate layers of high and low thermal conductivity material produces bulk thermal conductivity which is higher in the in- layer directions than the perpendicular one, This has the effect of dispersing a transient energy pulse liberated at a point on one side of the layer resulting in a significantly lower energy density at the coil. High conductivity layers would typically be metallic in nature while low conductivity layers would be polymer based.
The presence of high conductivity material between the former and coil would increase the thermal conductivity and so for a steady state distributed heat input would produce a poorer condition than the low conductivity material alone. However the nature of the energy input is both transient and localised so that the ratio of the conductivity in the perpendicular directions reduces the energy density at the coil surface. It can be shown that the ratio of conductivities in the two directions is approximately equal to the ratio of the two material conductivities. Typically, conductivity ratios of 10 can be achieved between metallic and composite materials.
The embodiments described above may be combined to provide a thermal diffusion barrier having a plurality of layers wherein alternate layers are materials of high thermal conductivity (for example metal foil) and porous material impregnated with helium.
Use of a filled resin bonding agent for the porous layers has the additional advantage of providing the coil against mechanical damage during assembly and wiring of the magnet system.
These structures bonded into the coil block can also include mechanisms for direct cooling of the coils and interface. In this configuration, cooling tubes, carrying liquid cryogens, can also be embedded, improving their efficiency.

Claims

Claims
1. A thermal barrier between two regions, said barrier having anisotropic thermal conductivity and being arranged such that the thermal conductivity of the barrier in a direction substantially parallel with an interface between the barrier and one of the regions is greater than the thermal conductivity in a direction substantially normal to said interface.
2. A thermal barrier according to claim 1 , comprising at least one layer of a first material and one layer of a second material, the first material having a higher thermal conductivity than the second material.
3. The thermal barrier of claim 2, comprising a plurality of layers of the first material arranged alternately with a plurality of layers of the second material.
4. The thermal barrier of claim 3 where first material comprises a metal.
5. The thermal barrier of claim 4 where the second material comprises a polymer.
6. The thermal barrier of claim 4 wherein the second material comprises a porous material impregnated with fluid.
7. The thermal barrier of claim 6 wherein the fluid is helium.
8 A thermal barrier according to claim 7, arranged between a superconducting coil and a support structure for the coil.
9. A thermal barrier according to claim 8, incorporated in a Magnetic Resonance Imaging (MRI) scanner.
10. A thermal barrier comprising a porous material impregnated with a fluid.
1 1. A thermal barrier according to claim 10, arranged between a superconducting coil and a support structure for the coil.
12. A thermal barrier according to claim 1 1 , wherein the porous material comprises an open weave, epoxy resin impregnated cloth.
13. A thermal barrier according to claim 12 wherein the epoxy resin serves to bond the barrier to the superconducting coil and to the support structure.
14. A thermal barrier according to claim 13, where the fluid is helium.
15. A thermal barrier according to claim 14, further including at least one conduit, suitable for carrying fluid throughout the barrier.
16. A thermal barrier according to claim 15, incorporated in a Magnetic Resonance Imaging (MRI) scanner.
17. A thermal barrier comprising a solid state composite, which composite includes a material that undergoes a magnetic phase change at temperatures below 10K.
18. The thermal barrier of claim 17, wherein the material comprises a compound of holmium, erbium or gadolinium.
19. The thermal barrier of claim 18 where the material comprises gadolinium oxysulphide.
20. A thermal barrier according to claim 17, 18 or 19 arranged between a superconducting coil and a support structure for the coil.
21. A thermal barrier according to claim 20, incorporated in a Magnetic Resonance Imaging (MRI) scanner.
PCT/GB2007/050098 2006-03-10 2007-03-02 Thermal diffusion barrier WO2007105011A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0604836A GB2435918B (en) 2006-03-10 2006-03-10 Thermal diffusion barrier
GB0604836.7 2006-03-10

Publications (1)

Publication Number Publication Date
WO2007105011A1 true WO2007105011A1 (en) 2007-09-20

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Cited By (1)

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US20130255506A1 (en) * 2012-03-28 2013-10-03 Gary S. Selwyn Hollow-Cavity, Gas-Filled Cookware

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GB2454475A (en) * 2007-11-07 2009-05-13 Siemens Magnet Technology Ltd A Heat Shield for an MRI scanner
US8415952B2 (en) * 2009-12-23 2013-04-09 General Electric Company Superconducting magnet coil interface and method providing coil stability
EP2375545B1 (en) 2010-04-06 2013-02-20 Converteam Technology Ltd Electrical machines

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GB1482182A (en) * 1973-06-15 1977-08-10 Matsushita Electric Ind Co Ltd Electrical insulator comprising a synthetic polymer
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US20030164749A1 (en) * 1998-11-25 2003-09-04 Gregory L. Snitchler Superconducting conductors and their method of manufacture
US20040058188A1 (en) * 2002-06-28 2004-03-25 Groll William A. Bonded metal components having uniform thermal conductivity characteristics and method of making same
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Publication number Priority date Publication date Assignee Title
US20130255506A1 (en) * 2012-03-28 2013-10-03 Gary S. Selwyn Hollow-Cavity, Gas-Filled Cookware
US9125512B2 (en) * 2012-03-28 2015-09-08 Gary S. Selwyn Hollow-cavity, gas-filled cookware

Also Published As

Publication number Publication date
GB0604836D0 (en) 2006-04-19
GB2435918A (en) 2007-09-12
GB2435918B (en) 2008-05-14

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