WO2007092084A3 - Integrated gasification combined cycle synthesis gas membrane process - Google Patents

Integrated gasification combined cycle synthesis gas membrane process Download PDF

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Publication number
WO2007092084A3
WO2007092084A3 PCT/US2006/048358 US2006048358W WO2007092084A3 WO 2007092084 A3 WO2007092084 A3 WO 2007092084A3 US 2006048358 W US2006048358 W US 2006048358W WO 2007092084 A3 WO2007092084 A3 WO 2007092084A3
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WO
WIPO (PCT)
Prior art keywords
gas
combined cycle
integrated gasification
synthesis gas
gasification combined
Prior art date
Application number
PCT/US2006/048358
Other languages
French (fr)
Other versions
WO2007092084A2 (en
Inventor
Richard A Callahan
Original Assignee
Richard A Callahan
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Publication date
Application filed by Richard A Callahan filed Critical Richard A Callahan
Publication of WO2007092084A2 publication Critical patent/WO2007092084A2/en
Publication of WO2007092084A3 publication Critical patent/WO2007092084A3/en

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/52Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415Purification by absorption in liquids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0475Composition of the impurity the impurity being carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0485Composition of the impurity the impurity being a sulfur compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86Carbon dioxide sequestration
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643Conversion of synthesis gas to energy
    • C10J2300/165Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C10J2300/1675Integration of gasification processes with another plant or parts within the plant with the production of electricity making use of a steam turbine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1678Integration of gasification processes with another plant or parts within the plant with air separation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1687Integration of gasification processes with another plant or parts within the plant with steam generation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

A Membrane Separation Unit (MSU) and an integrated gasification combined cycle (IGCC) process and apparatus are described in which a produced synthesis gas is separated in the MSU into a hydrogen rich permeate gas and a carbon monoxide rich retentate gas, and, combusting the hydrogen rich permeate gas with air in a gas turbine-combined cycle to produce electricity and a carbon dioxide lean exhaust gas suitable for atmospheric emission, and, combusting the carbon monoxide rich retentate gas with oxygen and re-circulated exhaust gas in a gas turbine-combined cycle to produce electricity and a carbon dioxide rich exhaust gas suitable for capture.
PCT/US2006/048358 2005-12-21 2006-12-20 Integrated gasification combined cycle synthesis gas membrane process WO2007092084A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US75199805P 2005-12-21 2005-12-21
US60/751,998 2005-12-21

Publications (2)

Publication Number Publication Date
WO2007092084A2 WO2007092084A2 (en) 2007-08-16
WO2007092084A3 true WO2007092084A3 (en) 2007-12-21

Family

ID=38345601

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/048358 WO2007092084A2 (en) 2005-12-21 2006-12-20 Integrated gasification combined cycle synthesis gas membrane process

Country Status (1)

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WO (1) WO2007092084A2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008048062B3 (en) 2008-09-19 2010-04-08 Forschungszentrum Jülich GmbH IGCC power plant with flue gas recirculation and purge gas
US8495882B2 (en) 2009-08-10 2013-07-30 General Electric Company Syngas cleanup section with carbon capture and hydrogen-selective membrane
DE102009043499A1 (en) * 2009-09-30 2011-03-31 Uhde Gmbh Method of operating an IGCC power plant process with integrated CO2 separation
DE102010049792B4 (en) * 2009-11-02 2016-05-25 Mahnken & Partner GmbH Small power plant and method and apparatus for obtaining high purity hydrogen
US8506676B2 (en) * 2011-02-11 2013-08-13 General Electric Company Waste heat recovery system and method of using waste heat
DE102011110213A1 (en) * 2011-08-16 2013-02-21 Thyssenkrupp Uhde Gmbh Method and device for recirculating exhaust gas from a gas turbine with subsequent waste heat boiler
CN106914117B (en) * 2017-04-18 2022-08-12 长沙紫宸科技开发有限公司 Device suitable for continuously capturing carbon dioxide in cement kiln flue gas and generating electricity
US11149634B2 (en) * 2019-03-01 2021-10-19 Richard Alan Callahan Turbine powered electricity generation
US11149636B2 (en) * 2019-03-01 2021-10-19 Richard Alan Callahan Turbine powered electricity generation
US11994063B2 (en) 2019-10-16 2024-05-28 Richard Alan Callahan Turbine powered electricity generation
US11808206B2 (en) * 2022-02-24 2023-11-07 Richard Alan Callahan Tail gas recycle combined cycle power plant
EP4400564A1 (en) 2023-01-13 2024-07-17 Mash Makes A/S Hydrogen production from a biomass-based synthesis gas

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030223931A1 (en) * 2002-05-30 2003-12-04 Narayan Raghu S. Synthesis gas production
US20040123601A1 (en) * 2002-09-17 2004-07-01 Foster Wheeler Energia Oy Advanced hybrid coal gasification cycle utilizing a recycled working fluid

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030223931A1 (en) * 2002-05-30 2003-12-04 Narayan Raghu S. Synthesis gas production
US20040123601A1 (en) * 2002-09-17 2004-07-01 Foster Wheeler Energia Oy Advanced hybrid coal gasification cycle utilizing a recycled working fluid

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BAKER ET AL.: "The design of membranes vapor/gas separation systems", JOURNAL OF MEMBRANE SCIENCE, vol. 151, no. 9, December 1998 (1998-12-01), pages 55 - 62 *

Also Published As

Publication number Publication date
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