WO2007070894A3 - Non-sulfided ni-based hydrocracking catalysts - Google Patents

Non-sulfided ni-based hydrocracking catalysts Download PDF

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Publication number
WO2007070894A3
WO2007070894A3 PCT/ZA2006/000140 ZA2006000140W WO2007070894A3 WO 2007070894 A3 WO2007070894 A3 WO 2007070894A3 ZA 2006000140 W ZA2006000140 W ZA 2006000140W WO 2007070894 A3 WO2007070894 A3 WO 2007070894A3
Authority
WO
WIPO (PCT)
Prior art keywords
sulfided
hydrocracking catalysts
hydrocracking
based hydrocracking
mass
Prior art date
Application number
PCT/ZA2006/000140
Other languages
French (fr)
Other versions
WO2007070894A2 (en
Inventor
Genevieve Joorst
Christakis Panayiot Nicolaides
Haan Robert De
Original Assignee
Sasol Tech Pty Ltd
Genevieve Joorst
Christakis Panayiot Nicolaides
Haan Robert De
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Tech Pty Ltd, Genevieve Joorst, Christakis Panayiot Nicolaides, Haan Robert De filed Critical Sasol Tech Pty Ltd
Priority to CN200680052694.7A priority Critical patent/CN101370912B/en
Priority to AU2006325738A priority patent/AU2006325738A1/en
Publication of WO2007070894A2 publication Critical patent/WO2007070894A2/en
Publication of WO2007070894A3 publication Critical patent/WO2007070894A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/835Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12Inorganic carriers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products
    • C10G2300/301Boiling range
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018Spatial velocity, e.g. LHSV, WHSV

Abstract

The invention provides a method for reducing methane formation when hydrocracking hydrocarbons, and a process for the hydrocracking of hydrocarbons, said method and process utilizing a non-sulfided hydrocracking catalyst, which has Ni and Sn, wherein the Ni content is at least 1 mass% and the silica content is at least 20 mass%, present in the form of silica-alumina.
PCT/ZA2006/000140 2005-12-12 2006-12-01 Non-sulfided ni-based hydrocracking catalysts WO2007070894A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN200680052694.7A CN101370912B (en) 2005-12-12 2006-12-01 Non-sulfided Ni-based hydrocracking catalysts
AU2006325738A AU2006325738A1 (en) 2005-12-12 2006-12-01 Non-sulfided Ni-based hydrocracking catalysts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/299,836 US20070131586A1 (en) 2005-12-12 2005-12-12 Non-sulfided Ni-based hydrocracking catalysts
US11/299,836 2005-12-12

Publications (2)

Publication Number Publication Date
WO2007070894A2 WO2007070894A2 (en) 2007-06-21
WO2007070894A3 true WO2007070894A3 (en) 2007-08-02

Family

ID=37909352

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/ZA2006/000140 WO2007070894A2 (en) 2005-12-12 2006-12-01 Non-sulfided ni-based hydrocracking catalysts

Country Status (5)

Country Link
US (1) US20070131586A1 (en)
CN (1) CN101370912B (en)
AU (1) AU2006325738A1 (en)
WO (1) WO2007070894A2 (en)
ZA (1) ZA200804999B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5221659B2 (en) * 2008-07-23 2013-06-26 三井化学株式会社 Ethylene oligomerization catalyst and uses thereof

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2911356A (en) * 1957-02-18 1959-11-03 Union Oil Co Hydrocracking of hydrocarbons with reaction conditions dependent on nitrogen contentof feed
US3206391A (en) * 1962-04-13 1965-09-14 Standard Oil Co Catalytic conversion of hydrocarbons
US3232864A (en) * 1964-03-23 1966-02-01 Universal Oil Prod Co Preparation of a hydrocarbon hydrocracking catalyst for use in the conversion of hydrocarbons
GB1059692A (en) * 1964-09-01 1967-02-22 Shell Int Research Process for the preparation of a catalyst suitable for the hydrogenerative cracking of a hydrocarbon oil
US3401125A (en) * 1964-05-22 1968-09-10 Chevron Res Coprecipitation method for making multi-component catalysts
US3542696A (en) * 1968-10-14 1970-11-24 Chevron Res Hydrocracking catalyst
US3598724A (en) * 1969-09-15 1971-08-10 Chevron Res Production of propane and butanes
US4097365A (en) * 1976-03-18 1978-06-27 Union Oil Company Of California Hydrocracking process and catalyst for production of middle distillate oils
EP0587245A1 (en) * 1992-09-08 1994-03-16 Shell Internationale Researchmaatschappij B.V. Hydroconversion catalyst
WO1999010098A1 (en) * 1997-08-22 1999-03-04 Exxon Research And Engineering Company SUPPORTED Ni-Cu HYDROCONVERSION CATALYST

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3399132A (en) * 1966-07-28 1968-08-27 Chevron Res Hydrocaracking of hydrocarbons with a catalyst composite comprising nickel and tin associated with a porous acidic inorganic oxide carrier
FR2780311B1 (en) * 1998-06-25 2000-08-11 Inst Francais Du Petrole HYDROCRACKING CATALYST COMPRISING A NON-GLOBALLY DESALUMINATED Y ZEOLITE, A VB GROUP ELEMENT, AND A PROMOTING ELEMENT SELECTED IN THE GROUP FORMED BY BORON, PHOSPHORUS AND SILICON

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2911356A (en) * 1957-02-18 1959-11-03 Union Oil Co Hydrocracking of hydrocarbons with reaction conditions dependent on nitrogen contentof feed
US3206391A (en) * 1962-04-13 1965-09-14 Standard Oil Co Catalytic conversion of hydrocarbons
US3232864A (en) * 1964-03-23 1966-02-01 Universal Oil Prod Co Preparation of a hydrocarbon hydrocracking catalyst for use in the conversion of hydrocarbons
US3401125A (en) * 1964-05-22 1968-09-10 Chevron Res Coprecipitation method for making multi-component catalysts
GB1059692A (en) * 1964-09-01 1967-02-22 Shell Int Research Process for the preparation of a catalyst suitable for the hydrogenerative cracking of a hydrocarbon oil
US3542696A (en) * 1968-10-14 1970-11-24 Chevron Res Hydrocracking catalyst
US3598724A (en) * 1969-09-15 1971-08-10 Chevron Res Production of propane and butanes
US4097365A (en) * 1976-03-18 1978-06-27 Union Oil Company Of California Hydrocracking process and catalyst for production of middle distillate oils
EP0587245A1 (en) * 1992-09-08 1994-03-16 Shell Internationale Researchmaatschappij B.V. Hydroconversion catalyst
WO1999010098A1 (en) * 1997-08-22 1999-03-04 Exxon Research And Engineering Company SUPPORTED Ni-Cu HYDROCONVERSION CATALYST

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
F.G. CIAPETTA , J.B. HUNTER: "isomerization of saturated hydrocarbons in presence of hydrogenation-cracking catalysts", INDUSTRIAL ENGINEERING AND CHEMISTRY, vol. 45, 1953, pages 147 - 155, XP002430181 *

Also Published As

Publication number Publication date
CN101370912A (en) 2009-02-18
CN101370912B (en) 2012-07-18
WO2007070894A2 (en) 2007-06-21
US20070131586A1 (en) 2007-06-14
AU2006325738A1 (en) 2007-06-21
ZA200804999B (en) 2009-11-25

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