WO2007005921A3 - Bronsted acidic aluminoxane compositions and their use in olefin polymerization catalyst compositions - Google Patents

Bronsted acidic aluminoxane compositions and their use in olefin polymerization catalyst compositions Download PDF

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Publication number
WO2007005921A3
WO2007005921A3 PCT/US2006/026113 US2006026113W WO2007005921A3 WO 2007005921 A3 WO2007005921 A3 WO 2007005921A3 US 2006026113 W US2006026113 W US 2006026113W WO 2007005921 A3 WO2007005921 A3 WO 2007005921A3
Authority
WO
WIPO (PCT)
Prior art keywords
compositions
olefin polymerization
polymerization catalyst
aluminoxane
bronsted acidic
Prior art date
Application number
PCT/US2006/026113
Other languages
French (fr)
Other versions
WO2007005921A2 (en
Inventor
Lubin Luo
Steven P Diefenbach
Rajeev S Mathur
Uwe F Winkler
Xiao Wu
Original Assignee
Albemarle Corp
Lubin Luo
Steven P Diefenbach
Rajeev S Mathur
Uwe F Winkler
Xiao Wu
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Corp, Lubin Luo, Steven P Diefenbach, Rajeev S Mathur, Uwe F Winkler, Xiao Wu filed Critical Albemarle Corp
Publication of WO2007005921A2 publication Critical patent/WO2007005921A2/en
Publication of WO2007005921A3 publication Critical patent/WO2007005921A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

This invention provides activator compositions comprising Brønsted acidic aluminoxanes that are stabilized with inert functional groups, Lewis bases, or both. Methods to make and use such activator compositions to form metallocene-based olefin polymerization catalysts are also provided.
PCT/US2006/026113 2005-07-01 2006-07-01 Bronsted acidic aluminoxane compositions and their use in olefin polymerization catalyst compositions WO2007005921A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US69640605P 2005-07-01 2005-07-01
US60/696,406 2005-07-01

Publications (2)

Publication Number Publication Date
WO2007005921A2 WO2007005921A2 (en) 2007-01-11
WO2007005921A3 true WO2007005921A3 (en) 2007-05-24

Family

ID=36123150

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/026113 WO2007005921A2 (en) 2005-07-01 2006-07-01 Bronsted acidic aluminoxane compositions and their use in olefin polymerization catalyst compositions

Country Status (1)

Country Link
WO (1) WO2007005921A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2562434T3 (en) 2006-09-20 2016-03-04 Albemarle Corporation Catalyst activators, processes for making them, and use thereof in catalysts and polymerization of olefins
KR20090074752A (en) * 2006-09-20 2009-07-07 알베마를 코포레이션 Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
HUE044002T2 (en) 2006-12-14 2019-09-30 Grace W R & Co Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
WO2017199870A1 (en) * 2016-05-16 2017-11-23 東ソー・ファインケム株式会社 Aluminum-oxide-forming composition and method of producing same, and polyolefin-based polymer nanocomposite containing zinc oxide particles or aluminum oxide particles and method of producing same
US11447861B2 (en) * 2016-12-15 2022-09-20 Asm Ip Holding B.V. Sequential infiltration synthesis apparatus and a method of forming a patterned structure

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6160145A (en) * 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
WO2002020156A2 (en) * 2000-09-05 2002-03-14 Albemarle Corporation Stable catalysts and co-catalyst compositions formed from hydroxyaluminoxane and their use
WO2004007570A2 (en) * 2002-07-15 2004-01-22 Basell Polyolefine Gmbh Preparation of supported catalyst systems

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6160145A (en) * 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
WO2002020156A2 (en) * 2000-09-05 2002-03-14 Albemarle Corporation Stable catalysts and co-catalyst compositions formed from hydroxyaluminoxane and their use
WO2004007570A2 (en) * 2002-07-15 2004-01-22 Basell Polyolefine Gmbh Preparation of supported catalyst systems

Also Published As

Publication number Publication date
WO2007005921A2 (en) 2007-01-11

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