WO2006136158A1 - A control valve - Google Patents

A control valve Download PDF

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Publication number
WO2006136158A1
WO2006136158A1 PCT/DK2006/000338 DK2006000338W WO2006136158A1 WO 2006136158 A1 WO2006136158 A1 WO 2006136158A1 DK 2006000338 W DK2006000338 W DK 2006000338W WO 2006136158 A1 WO2006136158 A1 WO 2006136158A1
Authority
WO
WIPO (PCT)
Prior art keywords
valve
control valve
pressure
inner ring
flow
Prior art date
Application number
PCT/DK2006/000338
Other languages
French (fr)
Inventor
Ole JØRGENSEN
Original Assignee
Frese A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=36888895&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2006136158(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Frese A/S filed Critical Frese A/S
Priority to MX2007015116A priority Critical patent/MX2007015116A/en
Priority to CN2006800222195A priority patent/CN101203705B/en
Priority to AT06742464T priority patent/ATE458947T1/en
Priority to EP20060742464 priority patent/EP1896755B1/en
Priority to US11/916,034 priority patent/US7967023B2/en
Priority to BRPI0612484-4A priority patent/BRPI0612484A2/en
Priority to DE200660012484 priority patent/DE602006012484D1/en
Priority to EA200702501A priority patent/EA012361B1/en
Priority to CA 2610601 priority patent/CA2610601C/en
Publication of WO2006136158A1 publication Critical patent/WO2006136158A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D19/00Details
    • F24D19/10Arrangement or mounting of control or safety devices
    • F24D19/1006Arrangement or mounting of control or safety devices for water heating systems
    • F24D19/1009Arrangement or mounting of control or safety devices for water heating systems for central heating
    • F24D19/1015Arrangement or mounting of control or safety devices for water heating systems for central heating using a valve or valves
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D16/00Control of fluid pressure
    • G05D16/028Controlling a pressure difference
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D16/00Control of fluid pressure
    • G05D16/04Control of fluid pressure without auxiliary power
    • G05D16/06Control of fluid pressure without auxiliary power the sensing element being a flexible membrane, yielding to pressure, e.g. diaphragm, bellows, capsule
    • G05D16/063Control of fluid pressure without auxiliary power the sensing element being a flexible membrane, yielding to pressure, e.g. diaphragm, bellows, capsule the sensing element being a membrane
    • G05D16/0644Control of fluid pressure without auxiliary power the sensing element being a flexible membrane, yielding to pressure, e.g. diaphragm, bellows, capsule the sensing element being a membrane the membrane acting directly on the obturator
    • G05D16/0655Control of fluid pressure without auxiliary power the sensing element being a flexible membrane, yielding to pressure, e.g. diaphragm, bellows, capsule the sensing element being a membrane the membrane acting directly on the obturator using one spring-loaded membrane
    • G05D16/0658Control of fluid pressure without auxiliary power the sensing element being a flexible membrane, yielding to pressure, e.g. diaphragm, bellows, capsule the sensing element being a membrane the membrane acting directly on the obturator using one spring-loaded membrane characterised by the form of the obturator
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/2931Diverse fluid containing pressure systems
    • Y10T137/3003Fluid separating traps or vents
    • Y10T137/3084Discriminating outlet for gas
    • Y10T137/309Fluid sensing valve
    • Y10T137/3093With vaporized liquid stop
    • Y10T137/3096With separate return for condensate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/8593Systems
    • Y10T137/86919Sequentially closing and opening alternately seating flow controllers

Definitions

  • the invention relates to a control valve for use in liquid-carrying systems of the type which is adapted to serve as a differential pressure governor, as it maintains a constant differential pressure over an inlet side and an outlet side irrespective of the amount flowing therethrough.
  • Valves of this type are used particularly in connection with systems for heating or cooling, e.g. in district or local heating systems, but in general everywhere where there is a need for the above-mentioned functions in liquid-carrying systems.
  • Differential pressure governors are known for maintaining a constant differential pressure over an inlet side and an outlet side irrespective of the amount of liquid flowing therethrough, where a throttle member sets itself in a balance under the influence of the inlet pressure on the one side and the outlet pressure and a spring pressure on the other side, so that the pres- sure difference will always be the same, irrespective of the other circumstances, such as the flow amount through the governor.
  • the valve according to the invention is of this type.
  • the object of the invention is to be able to preset the flow through the valve, and this is achieved according to the invention when, additionally, the valve is provided with an arrangement for setting and adjusting the amount of liquid flowing therethrough, it being arranged as defined in the characterizing portion of claim
  • this arrangement comprises an adjustable flow valve having two valve members consisting of two concentric rings with annular recesses which extend over approximately 180 degrees. The external one of these two rings is stationary, while the internal one is rotatably connected with a handle, so that the overlap of the recesses may be adjusted manually. It is thus possible to preset the maximum flow through the control valve.
  • the internal ring, and optionally also the carrier is displaceable in the axial direction, whereby the axial overlap between the recesses may be changed. This makes it possible to adjust the flow through the valve by means of an actuator within the limits of the preset value, and, if so desired, to block the flow completely in the one outer position of the displacement.
  • the arrangement according to the invention provides a control valve where the maximum flow may be adjusted by simple rotation of a handle, and which may be adjusted to any value between zero and this maximum value by an axial displacement, optionally by an actuator.
  • the device according to claim 2 ensures that the inner ring may be made displaceable in the circumferential direction as well as in the axial direction in a simple manner by means of the carrier for the handle, which allows axial displacement, as its carrier faces are axial.
  • fig. 1 shows a sectional view through the control valve which illustrates the differential pressure governor in particular
  • fig. 2 shows the arrangement for setting the maximum flow and for adjusting the flow, in disassembled form.
  • FIG. 1 shows a control valve having an inlet and an outlet.
  • the control mechanism consists of a housing 23, a rolling diaphragm 24, a piston 25, which also supports the rolling diaphragm 24.
  • a cover 22 with a guide for the piston 25 is secured to the housing 23.
  • the housing 23 has a plurality of openings or slots in the periphery which are closed more or less by the piston 25 according to the axial position of the piston.
  • the pressure at the inlet is transferred to the outer side of the rolling diaphragm through a bore or a capillary pipe 21.
  • a spring 26 urges the piston to its top position, while the piston, at its inner side, is affected by the pressure before the adjusting slots.
  • Figure 2 shows the arrangement in the housing 3 of the control valve for adjusting and optionally blocking the flow amount.
  • a manually operated ro- tary button 10 is connected with a carrier 5, so that the rotary button can bring along the carrier in the direction of rotation, while the carrier 5 is axi- ally displaceable relative to the rotary button 10.
  • an outer cylindrical valve member 4 which is provided with an annular slot extending over approximately 180 degrees.
  • an inner valve member 6 which has a corresponding annular slot. These two slots are present in the normal position opposite each other.
  • the last-mentioned inner valve mem- ber is connected with the carrier 5, so that its angular position relative to the outer valve member may be adjusted by means of the rotary button 10. Thereby, the overlap in the circumferential position between the two slots and thus the maximum flow amount through the governor may be adjusted manually.
  • the inner valve member 6 and the carrier are axially displaceable relative to the housing and the rotary button 10 against the effect of a pressure spring 16.
  • a pressure spring 16 By such an axial displacement, the axial overlap between the slots in the outer valve member and the inner valve member may be changed, whereby the flow amount through the governor may be set or adjusted within the limits of the preset maximum value. Blocking of the flow may be established in an outer position in that the two slots are brought entirely out of mutual connection.
  • control valve which is relative simple in its mechanical structure and nevertheless offers many setting and adjustment options.

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Fluid Mechanics (AREA)
  • General Physics & Mathematics (AREA)
  • Automation & Control Theory (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Safety Valves (AREA)
  • Control Of Fluid Pressure (AREA)
  • Valve Device For Special Equipments (AREA)
  • Sliding Valves (AREA)
  • Lift Valve (AREA)
  • Mechanically-Actuated Valves (AREA)
  • Temperature-Responsive Valves (AREA)

Abstract

A control valve for use in a liquid-carrying system, such as a heating or cooling system, containing a differential pressure governor which, keeps the differential pressure between the inlet and the outlet constant. The control valve also includes an arrangement for setting and adjusting the maximum flow of liquid through the valve. This arrangement comprises a flow valve having two cooperating valve members (4 and 6) , which are arranged in the flow path and are constructed as two concentric rings, each of which has a recess extending about 180 degrees in the circumferential direction. The outer ring (4) is stationary relative to the valve housing, while the inner ring (6) may be displaced in the circumferential direction by means of a ro- tatable handle, whereby a greater or smaller overlap between the recesses may be provided. The maximum flow amount may hereby be set manually. The inner ring (6) may also be displaced in the axial direction, whereby a greater or smaller overlap between the recesses in the axial direction may be provided. The flow amount may hereby be adjusted within the limits of the presetting e.g. by means of an actuator. The flow may be blocked completely in an outer position.

Description

A CONTROL VALVE
The prior art
The invention relates to a control valve for use in liquid-carrying systems of the type which is adapted to serve as a differential pressure governor, as it maintains a constant differential pressure over an inlet side and an outlet side irrespective of the amount flowing therethrough.
Valves of this type are used particularly in connection with systems for heating or cooling, e.g. in district or local heating systems, but in general everywhere where there is a need for the above-mentioned functions in liquid-carrying systems.
Differential pressure governors are known for maintaining a constant differential pressure over an inlet side and an outlet side irrespective of the amount of liquid flowing therethrough, where a throttle member sets itself in a balance under the influence of the inlet pressure on the one side and the outlet pressure and a spring pressure on the other side, so that the pres- sure difference will always be the same, irrespective of the other circumstances, such as the flow amount through the governor.
The object of the invention
The valve according to the invention is of this type. The object of the invention is to be able to preset the flow through the valve, and this is achieved according to the invention when, additionally, the valve is provided with an arrangement for setting and adjusting the amount of liquid flowing therethrough, it being arranged as defined in the characterizing portion of claim Thus, this arrangement comprises an adjustable flow valve having two valve members consisting of two concentric rings with annular recesses which extend over approximately 180 degrees. The external one of these two rings is stationary, while the internal one is rotatably connected with a handle, so that the overlap of the recesses may be adjusted manually. It is thus possible to preset the maximum flow through the control valve.
However, the internal ring, and optionally also the carrier, is displaceable in the axial direction, whereby the axial overlap between the recesses may be changed. This makes it possible to adjust the flow through the valve by means of an actuator within the limits of the preset value, and, if so desired, to block the flow completely in the one outer position of the displacement.
In every position of this flow control, a constant pressure difference is maintained over the inlet side and the outlet side by virtue of the differential pressure governor mentioned initially.
The arrangement according to the invention provides a control valve where the maximum flow may be adjusted by simple rotation of a handle, and which may be adjusted to any value between zero and this maximum value by an axial displacement, optionally by an actuator.
The device according to claim 2 ensures that the inner ring may be made displaceable in the circumferential direction as well as in the axial direction in a simple manner by means of the carrier for the handle, which allows axial displacement, as its carrier faces are axial.
When the device is constructed as stated in claim 3, a particularly simple structure is achieved, as the axially displaceable carrier may be used as a connection between the actuator and the internal ring. The drawing
An embodiment of the invention will be explained more fully with reference to the drawing, in which
fig. 1 shows a sectional view through the control valve which illustrates the differential pressure governor in particular, and
fig. 2 shows the arrangement for setting the maximum flow and for adjusting the flow, in disassembled form.
Description of the exemplary embodiment
Figure 1 shows a control valve having an inlet and an outlet. The control mechanism consists of a housing 23, a rolling diaphragm 24, a piston 25, which also supports the rolling diaphragm 24. A cover 22 with a guide for the piston 25 is secured to the housing 23. The housing 23 has a plurality of openings or slots in the periphery which are closed more or less by the piston 25 according to the axial position of the piston. The pressure at the inlet is transferred to the outer side of the rolling diaphragm through a bore or a capillary pipe 21. A spring 26 urges the piston to its top position, while the piston, at its inner side, is affected by the pressure before the adjusting slots.
In use, a balance is provided between the inlet pressure and the outlet pressure plus the spring force, so that the differential pressure corresponds to the spring force. This differential pressure will therefore be constant with a given spring force.
Figure 2 shows the arrangement in the housing 3 of the control valve for adjusting and optionally blocking the flow amount. A manually operated ro- tary button 10 is connected with a carrier 5, so that the rotary button can bring along the carrier in the direction of rotation, while the carrier 5 is axi- ally displaceable relative to the rotary button 10.
Stationary relative to the housing is an outer cylindrical valve member 4 which is provided with an annular slot extending over approximately 180 degrees. Within this and concentrically with it is an inner valve member 6 which has a corresponding annular slot. These two slots are present in the normal position opposite each other. The last-mentioned inner valve mem- ber is connected with the carrier 5, so that its angular position relative to the outer valve member may be adjusted by means of the rotary button 10. Thereby, the overlap in the circumferential position between the two slots and thus the maximum flow amount through the governor may be adjusted manually.
The inner valve member 6 and the carrier are axially displaceable relative to the housing and the rotary button 10 against the effect of a pressure spring 16. By such an axial displacement, the axial overlap between the slots in the outer valve member and the inner valve member may be changed, whereby the flow amount through the governor may be set or adjusted within the limits of the preset maximum value. Blocking of the flow may be established in an outer position in that the two slots are brought entirely out of mutual connection.
Thus, a control valve is provided which is relative simple in its mechanical structure and nevertheless offers many setting and adjustment options.

Claims

PATENT CLAIMS
1. A control valve for use in liquid-carrying systems, and particularly for use in heating or cooling systems, having a valve housing (3) with an inlet side and an outlet side, and including an arrangement for maintaining a constant differential pressure between the inlet side and the outlet side independently of the liquid amount flowing therethrough, wherein a throttle elements sets itself in a balance under the influence of the inlet pressure on the one side and the outlet pressure and a spring pressure on the other side, c h a r a c t e r i z e d in that it additionally comprises an arrangement for adjusting the liquid amount flowing therethrough with two cooperating valve members (4, 6) arranged in the flow path, said valve members being constructed as two concentric rings which each have a recess extending approximately 180 degrees in the circumferential direction, wherein the outer one of the two concentric rings (4) is fixed relative to the valve housing (3), while the inner ring (6) is displaceable in the circumferential direction under the influence of a rotatable handle (10), whereby a greater or smaller overlap may be established manually in the circumferential direction between the recesses, and is also displaceable in the axial direction, so that a greater or smaller overlap may be provided between the recesses in the axial direction, as it is connected with an actuator for controlled or automatic adjustment of the axial overlap.
2. A control valve according to claim ^ c h a r a c t e r i z e d in that the rotatable handle (10) is firmly connected with the inner ring (6), but is axially displaceable relative to it, as the connection is formed by a carrier having axially extending engagement faces.
3. A control valve according to claim ^ c h a r a c t e r i z e d in that the carrier (5) is firmly connected with the inner ring (6) and may be displaced, together with said ring, in the axial direction against the action of a pressure spring (16).
PCT/DK2006/000338 2005-06-23 2006-06-14 A control valve WO2006136158A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
MX2007015116A MX2007015116A (en) 2005-06-23 2006-06-14 A control valve.
CN2006800222195A CN101203705B (en) 2005-06-23 2006-06-14 A control valve
AT06742464T ATE458947T1 (en) 2005-06-23 2006-06-14 CONTROL VALVE
EP20060742464 EP1896755B1 (en) 2005-06-23 2006-06-14 A control valve
US11/916,034 US7967023B2 (en) 2005-06-23 2006-06-14 Control valve
BRPI0612484-4A BRPI0612484A2 (en) 2005-06-23 2006-06-14 control valve
DE200660012484 DE602006012484D1 (en) 2005-06-23 2006-06-14 CONTROL VALVE
EA200702501A EA012361B1 (en) 2005-06-23 2006-06-14 A control valve
CA 2610601 CA2610601C (en) 2005-06-23 2006-06-14 A control valve

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA200500920 2005-06-23
DK200500920A DK176350B2 (en) 2005-06-23 2005-06-23 Control valve

Publications (1)

Publication Number Publication Date
WO2006136158A1 true WO2006136158A1 (en) 2006-12-28

Family

ID=36888895

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DK2006/000338 WO2006136158A1 (en) 2005-06-23 2006-06-14 A control valve

Country Status (13)

Country Link
US (1) US7967023B2 (en)
EP (1) EP1896755B1 (en)
CN (1) CN101203705B (en)
AT (1) ATE458947T1 (en)
BR (1) BRPI0612484A2 (en)
CA (1) CA2610601C (en)
DE (1) DE602006012484D1 (en)
DK (1) DK176350B2 (en)
EA (1) EA012361B1 (en)
ES (1) ES2340609T3 (en)
MX (1) MX2007015116A (en)
PT (1) PT1896755E (en)
WO (1) WO2006136158A1 (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009006893A1 (en) * 2007-07-06 2009-01-15 Frese A/S A control valve
WO2009135490A2 (en) * 2008-05-05 2009-11-12 Frese A/S A control valve
WO2014044282A2 (en) * 2012-09-20 2014-03-27 Frese A/S A differential pressure control valve
EP2729719B1 (en) 2011-07-08 2015-06-03 Flowcon International ApS A valve
ITMI20132133A1 (en) * 2013-12-19 2015-06-20 Vir Valvoindustria Ing Rizzio S P A DYNAMIC BALANCING VALVE FOR PRESSURE INDEPENDENT FLOW CONTROL
CN105359048A (en) * 2013-06-13 2016-02-24 菲姆斯股份公司 Control valve
EP3059651A1 (en) 2015-02-20 2016-08-24 Vir Valvoindustria Ing. Rizzio - S.P.A. Pressure independent hydraulic valve for flow control and regulation
US9823666B2 (en) 2008-06-26 2017-11-21 Belparts Flow control system
EP3483691A1 (en) * 2017-11-10 2019-05-15 Danfoss A/S Pressure controlled valve
EP3502823A1 (en) * 2017-12-20 2019-06-26 Siemens Schweiz AG Control valve
WO2020002337A1 (en) * 2018-06-29 2020-01-02 Siemens Schweiz Ag Control valve
WO2020083453A1 (en) 2018-10-23 2020-04-30 Frese A/S The present invention relates to a district heating system and methods for flow control and retrofitting of a flow regulation system in a district heating system
EP3708884A1 (en) 2019-03-12 2020-09-16 Frese A/S A valve with an amount control arrangement with manual pre-setting
WO2021134743A1 (en) * 2020-01-02 2021-07-08 西门子瑞士有限公司 Control valve
EP3418847B1 (en) 2016-03-24 2022-01-26 Honeywell Technologies Sarl Flow regulation valve

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US8061195B2 (en) 2009-05-08 2011-11-22 Jones Iii Tommy Jefferson Flow control assembly
ITMI20090324U1 (en) * 2009-10-13 2011-04-14 Flii Pettinaroli Spa AUTOMATIC BALANCING VALVE
CN101929574B (en) * 2010-09-19 2012-01-04 卓旦春 Dynamic balance motor-driven pressure-difference valve
SE535490C2 (en) * 2010-12-01 2012-08-28 Tour & Andersson Ab Control valve
DK178181B1 (en) * 2014-01-10 2015-07-27 Flowcon Internat Aps A control valve
DK178182B1 (en) * 2014-01-10 2015-07-27 Flowcon Internat Aps A control valve
DE102014203548A1 (en) * 2014-02-27 2015-08-27 Hans-Alfred Balg Radiator valve device with slot
US9910447B2 (en) * 2015-03-10 2018-03-06 Fratelli Pettinaroli S.P.A. Automatic balancing valve
DE102016101722A1 (en) * 2016-02-01 2017-08-03 Geva Automation Gmbh Control valve, in particular for use in cooling sections
EP3309643B1 (en) * 2016-10-14 2020-10-14 Honeywell Technologies Sarl Pressure independent control valve
CN106523749B (en) * 2016-12-09 2018-09-14 广东汉特科技有限公司 A kind of adjustable key spool
DE102021134501B3 (en) 2021-12-23 2023-03-16 Meibes System-Technik Gmbh Valve for controlling fluid flow and use thereof, and valve insert for a valve housing for controlling fluid flow

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US4702279A (en) * 1984-12-10 1987-10-27 Mepaco, Inc. Valve to control the rate and shape of a fluid stream
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DE10256035B3 (en) * 2002-11-30 2004-09-09 Danfoss A/S Control valve for heat exchanger or heater has valve body screwed onto seat by spindle and has pressure regulating valve with opening spring and diaphragm

Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009006893A1 (en) * 2007-07-06 2009-01-15 Frese A/S A control valve
KR101597798B1 (en) 2008-05-05 2016-02-25 프레세 에이/에스 A control valve
EA019954B1 (en) * 2008-05-05 2014-07-30 Фрезе А/С A control valve
WO2009135490A3 (en) * 2008-05-05 2010-12-16 Frese A/S A control valve
CN102089725A (en) * 2008-05-05 2011-06-08 弗雷泽公共有限责任公司 A control valve
US8469052B2 (en) 2008-05-05 2013-06-25 Frese A/S Control valve
KR20110013403A (en) * 2008-05-05 2011-02-09 프레세 에이/에스 A control valve
AU2009243857B2 (en) * 2008-05-05 2014-07-03 Frese A/S A control valve
WO2009135490A2 (en) * 2008-05-05 2009-11-12 Frese A/S A control valve
US10394257B2 (en) 2008-06-26 2019-08-27 Belparts Flow control system
US9823666B2 (en) 2008-06-26 2017-11-21 Belparts Flow control system
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EP1896755A1 (en) 2008-03-12
BRPI0612484A2 (en) 2012-10-02
PT1896755E (en) 2010-05-11
EA200702501A1 (en) 2008-08-29
DK200500920A (en) 2006-12-24
ES2340609T3 (en) 2010-06-07
US20080245428A1 (en) 2008-10-09
ATE458947T1 (en) 2010-03-15
CN101203705B (en) 2013-07-24
MX2007015116A (en) 2008-03-18
CN101203705A (en) 2008-06-18
DK176350B2 (en) 2008-10-13
DE602006012484D1 (en) 2010-04-08
EP1896755B1 (en) 2010-02-24
DK176350B1 (en) 2007-09-03
CA2610601C (en) 2012-09-25
US7967023B2 (en) 2011-06-28
EA012361B1 (en) 2009-10-30
CA2610601A1 (en) 2006-12-28

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