WO2006119357A3 - Processes for catalytic conversion of lignin to liquid bio-fuels - Google Patents

Processes for catalytic conversion of lignin to liquid bio-fuels Download PDF

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Publication number
WO2006119357A3
WO2006119357A3 PCT/US2006/016969 US2006016969W WO2006119357A3 WO 2006119357 A3 WO2006119357 A3 WO 2006119357A3 US 2006016969 W US2006016969 W US 2006016969W WO 2006119357 A3 WO2006119357 A3 WO 2006119357A3
Authority
WO
WIPO (PCT)
Prior art keywords
lignin
fuels
bio
partially
reaction
Prior art date
Application number
PCT/US2006/016969
Other languages
French (fr)
Other versions
WO2006119357A2 (en
Inventor
Wlodzimierz W Zmierczak
Jan D Miller
Original Assignee
Univ Utah Res Found
Wlodzimierz W Zmierczak
Jan D Miller
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Utah Res Found, Wlodzimierz W Zmierczak, Jan D Miller filed Critical Univ Utah Res Found
Priority to CN2006800150036A priority Critical patent/CN101171324B/en
Priority to CA002605672A priority patent/CA2605672A1/en
Priority to MX2007013672A priority patent/MX2007013672A/en
Priority to BRPI0611343-5A priority patent/BRPI0611343A2/en
Priority to EP06758980A priority patent/EP1888713A4/en
Publication of WO2006119357A2 publication Critical patent/WO2006119357A2/en
Publication of WO2006119357A3 publication Critical patent/WO2006119357A3/en
Priority to US11/932,408 priority patent/US7964761B2/en
Priority to US13/102,799 priority patent/US8299310B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Processes for conversion of lignin to liquid products such as bio-fiiels and fuel additives are disclosed and described (Figure 1). A process for conversion of a lignin material to bio- fuels can include subjecting the lignin material to a base catalyzed depolymerization reaction (Stage I) to produce a partially depolymerized lignin. The partially depolymerized lignin can then be subjected to a stabilization/partial hydrodeoxygenation reaction (Stage II) to form a partially hydrodeoxygenated product. Following partial hydrodeoxygenation, the partially hydrodeoxygenated product can be reacted in a refining step (Stage TS) to form a bio-fuel. Each of these reaction steps can be performed in single or multiple steps, depending on the design of the process. The production of an intermediate partially hydrodeoxygenation product and subsequent reaction thereof can significantly reduce or eliminate reactor plugging and catalyst coking. A variety of useful bio- fuels such as fuels, fuel additives, and the like can be readily produced from renewable lignin materials in an improved conversion process.
PCT/US2006/016969 2005-05-02 2006-05-02 Processes for catalytic conversion of lignin to liquid bio-fuels WO2006119357A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CN2006800150036A CN101171324B (en) 2005-05-02 2006-05-02 Processes for catalytic conversion of lignin to liquid bio-fuels
CA002605672A CA2605672A1 (en) 2005-05-02 2006-05-02 Processes for catalytic conversion of lignin to liquid bio-fuels
MX2007013672A MX2007013672A (en) 2005-05-02 2006-05-02 Processes for catalytic conversion of lignin to liquid bio-fuels.
BRPI0611343-5A BRPI0611343A2 (en) 2005-05-02 2006-05-02 processes for catalytic conversion of lignin to liquid biofuels
EP06758980A EP1888713A4 (en) 2005-05-02 2006-05-02 Processes for catalytic conversion of lignin to liquid bio-fuels
US11/932,408 US7964761B2 (en) 2005-05-02 2007-10-31 Processes for catalytic conversion of lignin to liquid bio-fuels and novel bio-fuels
US13/102,799 US8299310B2 (en) 2005-05-02 2011-05-06 Processes for catalytic conversion of lignin to liquid bio-fuels and novel bio-fuels

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US67766205P 2005-05-02 2005-05-02
US60/677,662 2005-05-02

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/932,408 Continuation-In-Part US7964761B2 (en) 2005-05-02 2007-10-31 Processes for catalytic conversion of lignin to liquid bio-fuels and novel bio-fuels

Publications (2)

Publication Number Publication Date
WO2006119357A2 WO2006119357A2 (en) 2006-11-09
WO2006119357A3 true WO2006119357A3 (en) 2007-01-25

Family

ID=37308674

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/016969 WO2006119357A2 (en) 2005-05-02 2006-05-02 Processes for catalytic conversion of lignin to liquid bio-fuels

Country Status (6)

Country Link
EP (1) EP1888713A4 (en)
CN (1) CN101171324B (en)
BR (1) BRPI0611343A2 (en)
CA (1) CA2605672A1 (en)
MX (1) MX2007013672A (en)
WO (1) WO2006119357A2 (en)

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US8466330B2 (en) 2008-09-05 2013-06-18 Shell Oil Company Liquid fuel compositions
US9303226B2 (en) 2009-12-31 2016-04-05 Shell Oil Company Direct aqueous phase reforming of bio-based feedstocks
US9388344B2 (en) 2010-05-12 2016-07-12 Shell Oil Company Biofuels via hydrogenolysis and dehydrogenation-condensation
US9410216B2 (en) 2010-06-26 2016-08-09 Virdia, Inc. Sugar mixtures and methods for production and use thereof
US9428704B2 (en) 2010-05-12 2016-08-30 Shell Oil Company Direct aqueous phase reforming and aldol condensation to form bio-based fuels
US9447347B2 (en) 2009-12-31 2016-09-20 Shell Oil Company Biofuels via hydrogenolysis-condensation
US9476106B2 (en) 2010-06-28 2016-10-25 Virdia, Inc. Methods and systems for processing a sucrose crop and sugar mixtures
US9512495B2 (en) 2011-04-07 2016-12-06 Virdia, Inc. Lignocellulose conversion processes and products

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US7964761B2 (en) 2005-05-02 2011-06-21 University Of Utah Research Foundation Processes for catalytic conversion of lignin to liquid bio-fuels and novel bio-fuels
CA2671730A1 (en) 2006-12-20 2008-11-20 Virent Energy Systems, Inc. Reactor system for producing gaseous products
ES2817876T3 (en) 2007-03-08 2021-04-08 Virent Inc Synthesis of liquid fuels from oxygenated hydrocarbons
US8084655B2 (en) 2007-06-15 2011-12-27 E. I. Du Pont De Nemours And Company Catalytic process for converting renewable resources into paraffins for use as diesel blending stocks
WO2009037281A2 (en) * 2007-09-18 2009-03-26 Basf Se Method for hydrogenating separation of lignin using transition metal carbides
EP2334625A1 (en) 2008-09-08 2011-06-22 Basf Se Method for the integrated production of cellulose and low-molecular-weight reusable materials
WO2010094697A1 (en) 2009-02-17 2010-08-26 Bergen Teknologioverføring As Liquefaction of lignin with gaseous components
US8871989B2 (en) * 2009-02-27 2014-10-28 Uop Llc Combination of hydrogenation and base catalyzed depolymerization for lignin conversion
EP2440515B1 (en) 2009-06-13 2018-08-15 Archer-Daniels-Midland Company Production of adipic acid and derivatives from carbohydrate-containing materials
NZ596974A (en) 2009-06-13 2014-03-28 Rennovia Inc Production of glutaric acid and derivatives from carbohydrate-containing materials
US8669397B2 (en) 2009-06-13 2014-03-11 Rennovia, Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
WO2011027220A1 (en) 2009-09-01 2011-03-10 Paul O'connor Improved process for dissolving cellulose-containing biomass material in an ionic liquid medium
EP2473534A1 (en) * 2009-09-01 2012-07-11 O'Connor, Paul Temperature-optimized conversion of lignocellulosic biomass
EP2473553A1 (en) 2009-09-01 2012-07-11 O'Connor, Paul Pretreatment of solid biomass material comprising cellulose with ionic liquid medium
US8404908B2 (en) * 2009-10-13 2013-03-26 Uop Llc Process for lignin conversion to chemicals or fuels with H2 generated from lignin depolymerization products
US8669393B2 (en) 2010-03-05 2014-03-11 Rennovia, Inc. Adipic acid compositions
NZ603395A (en) * 2010-05-07 2014-10-31 Solray Holdings Ltd Biomasses for the production of alternative petrochemical feedstock
US9770705B2 (en) 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
AU2011325472B2 (en) * 2010-11-04 2017-03-16 Albemarle Europe Sprl Hydrodeoxygenation of pyrolysis oil in presence of admixed alcohol
BR112013015553A2 (en) * 2010-12-20 2016-09-20 Shell Int Research biomass conversion system, and, method
US9187390B2 (en) * 2011-06-17 2015-11-17 Biochemtex S.P.A. Lignin conversion process
US8754275B2 (en) 2011-07-26 2014-06-17 Uop Llc Methods and apparatuses for producing aromatic hydrocarbon-rich effluent from lignocellulosic material
US8772557B2 (en) 2011-07-26 2014-07-08 Uop Llc Aromatic hydrocarbons from depolymerization and deoxygenation of lignin
US8772558B2 (en) 2011-07-26 2014-07-08 Uop Llc Methods and apparatuses for producing aromatic hydrocarbon-containing effluent
US9080109B2 (en) * 2011-12-14 2015-07-14 Uop Llc Methods for deoxygenating biomass-derived pyrolysis oil
US20130232853A1 (en) * 2012-03-09 2013-09-12 Thesis Chemistry, Llc Method for selective production of biobased chemicals and biofuels from plant lignin
US20130232852A1 (en) * 2012-03-09 2013-09-12 Thesis Chemistry, Llc Method for tiered production of biobased chemicals and biofuels from lignin
CN102604668B (en) * 2012-03-16 2014-09-03 山西盛驰科技有限公司 Application of transition metal carbide to biomass oil hydrodeoxygenation
AU2013280245B2 (en) * 2012-06-28 2016-02-04 Shell Internationale Research Maatschappij B.V. Biomass conversion systems providing integrated stabilization of a hydrolysate using a slurry catalyst following biomass pretreatment and methods for use thereof
EP3004455A4 (en) * 2013-05-29 2017-01-18 SunCarbon AB A method for the treatment of spent pulping liquor for the removal and production of a lignin containing product
US20160168473A1 (en) * 2013-07-24 2016-06-16 East China University Of Science And Technology Methods for producing alkanes from biomass
US9435002B2 (en) * 2014-06-07 2016-09-06 Api Intellectual Property Holdings, Llc Continuous processes for hydrolyzing hemicelluloses from ligocellulosic materials with cleaning system
CN104073278A (en) * 2014-07-15 2014-10-01 厦门大学 Method for converting lignin into liquid fuel through adopting two-step method
WO2016081082A1 (en) * 2014-11-20 2016-05-26 Exxonmobil Chemical Patents Inc. Conversion of lignin to fuels and aromatics
FR3030560B1 (en) * 2014-12-18 2017-01-27 Ifp Energies Now PROCESS FOR THE TRANSFORMATION OF LIGNOCELLULOSIC BIOMASS TO HYDROCARBONS AND OXYGENIC MOLECULES
WO2017048164A1 (en) * 2015-09-16 2017-03-23 Sca Forest Products Ab A batch process for producing bio-oil from spent black liquor
CA2998571C (en) * 2015-09-16 2022-07-26 Sca Forest Products Ab A continuous process for producing bio-oil from spent black liquor
ES2773659T3 (en) * 2015-11-04 2020-07-14 Sca Forest Prod Ab A process to produce a hydrocarbon product from lignin oil
US10240099B2 (en) 2016-10-27 2019-03-26 Uop Llc Processes for producing a fuel from a renewable feedstock
CN107417498B (en) * 2017-05-24 2020-01-31 中国科学技术大学 method for catalytic depolymerization of lignin
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CN112892539A (en) * 2019-12-03 2021-06-04 中国科学院广州能源研究所 Method for coupling hydrogenolysis of lignin by heterogeneous catalyst and homogeneous catalyst
CN113117688A (en) * 2021-04-22 2021-07-16 福州大学 MOF precursor molybdenum-nickel catalyst, preparation method thereof and application thereof in lignin degradation
CN113527065B (en) * 2021-07-14 2023-10-13 中国科学院广州能源研究所 Method for preparing aviation oil precursor by catalyzing depolymerization of alkali lignin in ethanol-water solvent by Pd/C catalyst and alkali catalyst
CN115106111B (en) * 2022-03-21 2023-08-15 安徽理工大学 Molybdenum carbide particle size dependent nitrogen-doped carbon material catalyst and preparation method and application thereof

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8466330B2 (en) 2008-09-05 2013-06-18 Shell Oil Company Liquid fuel compositions
US9206366B2 (en) 2008-09-05 2015-12-08 Shell Oil Company Liquid fuel compositions
US9303226B2 (en) 2009-12-31 2016-04-05 Shell Oil Company Direct aqueous phase reforming of bio-based feedstocks
US9447349B2 (en) 2009-12-31 2016-09-20 Shell Oil Company Direct aqueous phase reforming of bio-based feedstocks
US9447347B2 (en) 2009-12-31 2016-09-20 Shell Oil Company Biofuels via hydrogenolysis-condensation
US9493719B2 (en) 2009-12-31 2016-11-15 Shell Oil Company Biofuels via hydrogenolysis-condensation
US9388344B2 (en) 2010-05-12 2016-07-12 Shell Oil Company Biofuels via hydrogenolysis and dehydrogenation-condensation
US9428704B2 (en) 2010-05-12 2016-08-30 Shell Oil Company Direct aqueous phase reforming and aldol condensation to form bio-based fuels
US9410216B2 (en) 2010-06-26 2016-08-09 Virdia, Inc. Sugar mixtures and methods for production and use thereof
US9476106B2 (en) 2010-06-28 2016-10-25 Virdia, Inc. Methods and systems for processing a sucrose crop and sugar mixtures
US9512495B2 (en) 2011-04-07 2016-12-06 Virdia, Inc. Lignocellulose conversion processes and products

Also Published As

Publication number Publication date
CN101171324B (en) 2012-12-12
MX2007013672A (en) 2008-01-28
EP1888713A2 (en) 2008-02-20
CN101171324A (en) 2008-04-30
WO2006119357A2 (en) 2006-11-09
CA2605672A1 (en) 2006-11-09
BRPI0611343A2 (en) 2010-08-31
EP1888713A4 (en) 2011-04-13

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