WO2006099672A1 - Anode support apparatus - Google Patents
Anode support apparatus Download PDFInfo
- Publication number
- WO2006099672A1 WO2006099672A1 PCT/AU2006/000383 AU2006000383W WO2006099672A1 WO 2006099672 A1 WO2006099672 A1 WO 2006099672A1 AU 2006000383 W AU2006000383 W AU 2006000383W WO 2006099672 A1 WO2006099672 A1 WO 2006099672A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- anode
- clamps
- auxiliary
- superstructure
- anodes
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/12—Anodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/16—Electric current supply devices, e.g. bus bars
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/10—External supporting frames or structures
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
Definitions
- This invention relates to an apparatus and method for supporting anodes in an electrolysis cell producing for example aluminium, and in particular an apparatus and method for adjusting the position of these anodes in a cell.
- the electrolysis of alumina to produce aluminium by the Hall-Heroult process is well known and involves an electrochemical reaction.
- This process includes an electrolytic cell comprising an electrolytic tank having a plurality of cathodes and anodes.
- the aluminium oxide is supplied to a cryolite based bath in which the aluminium oxide is dissolved.
- the electrolytic process is most effective at bath temperatures between 940 0 C and 970 0 C.
- the anodes comprise carbonaceous anode blocks and aluminium stems which provide the mechanical and electrical link to the anode beam from which the anodes are suspended.
- the anodes are partially immersed in the electrolyte to provide an anode-cathode separation distance through which an electrical current passes.
- the anode- cathode gap should be set and maintained, either at a predetermined optimum distance or within an optimum range. If the anode-cathode gap is too large, this causes a significant voltage drop between the electrodes resulting in an unwanted increased power generation in the electrolyte. If the gap is too small the electrolytic process becomes unstable and inefficient.
- the anode blocks are continuously consumed during the electrochemical reaction producing mainly CO 2 gases.
- the anode-cathode gap increases over time.
- the cell voltage is continuously monitored and the position of the anodes periodically reset to maintain the optimum anode-cathode gap. Due to the continuous consumption, the anodes have a limited lifetime of about four weeks after which they have to be replaced by new anodes. It would be appreciated by those skilled in the art that changing more than one of all the anodes in an electrolytic cell in a short period of time will lead to severe interference with the chemical and thermal processes. Therefore, it is common practice to change only one anode per day in a given cell so that each anode of that cell has a different age between zero and approximately 28 days.
- the movable anode support In a conventional electrolytic cell design, the movable anode support, called an anode beam, is supported by the superstructure.
- the anodes are clamped directly to this anode beam which provides mechanical support and supplies electrical current to the anodes.
- Conventionally a single clamp per anode is used for both, mechanical fixation and electrical contact of the anode stem with the anode beam.
- the distance between the anodes and the aluminium layer on top of the cathode is then adjusted by raising and lowering the whole anode beam.
- the downward movement of the anode beam prevails and ranges at about 15 to 20 mm per day.
- the anode beam will reach is lowest possible position on the superstructure after two to three weeks and must then be raised with the help of an auxiliary anode raising beam which is temporarily positioned on top of the cell superstructure.
- This anode raising beam is equipped with devices which hold the anodes in place while the anode clamps are manually opened by operators to allow the anode beam to move back to its upper position. When the anode beam has reached its upper position, all the anode clamps have to be closed again by the operators.
- clamping devices also exert a high lateral pressure on the anode stems to maintain electrical contact between the anode stems and anode beam while the anode beam is travelling upward sliding along the anode stems.
- the process of raising the anodes poses a significant safety risk as the pressure exerted on the anode stems can drop resulting in a loss of the electrical contact between the anode stems and anode beam. In such a situation, dangerous electrical arcs develop until the substation of the aluminium smelting plant trips due to the open electrical circuit. In such an instance, the operators executing the anode beam raising are at risk of burn injuries.
- an apparatus for supporting anodes above a cathode in an electrolysis cell including a superstructure, an anode beam to which a plurality of individual anodes are attached each anode having a respective anode stem for attachment to the anode beam by a main clamp, the anode beam being adjustably mounted to the superstructure,
- an auxiliary clamp for each anode stem and at least one electrical beam supported by the superstructure, the electrical beam having connectors providing electrical connection between the electrical beam and the anode stems.
- auxiliary clamps are fixed in position relative to the superstructure.
- the anode beam of this invention is only a mechanical fixation for the anode stems to provide vertical movements of the anodes for the control of the anode-cathode distance.
- the anode beam no longer carries out the task of conducting electricity to the anodes.
- This task is provided by the at least one electrical beam preferably fixed at the centre top of the cell superstructure and a plurality of flexibles. These flexibles preferably are made of a multitude of aluminium foils which are welded to the electrical beam and attached by way of bolted or clamped connections to the top of the anode stems. In this way, the task of mechanical fixation and adjustment of the height of the anodes can be maintained separate to the electrical connection to the anode stems. Hence, an uninterrupted electrical contact is provided to the electrical beam while a safer fixation of the anode stems is provided to the movable anode beam.
- the invention provides an apparatus for adjusting the distance between the anodes and cathode of electrolysis cells including an anode beam to which a plurality of individual anodes are attached by respective anode stems, the anode stem of each anode being maintained in position relative to the anode beam by a main clamp, an auxiliary clamp for each anode stem, and a means to control the operation of the main and auxiliary clamps to allow engagement and disengagement of the clamps.
- the apparatus may further be provided with a superstructure.
- the auxiliary clamp is preferably secured to the superstructure to support the auxiliary clamp during anode beam raising.
- the engaging and disengaging of the main and auxiliary clamps are controlled by a process control computer.
- the disconnecting and reconnecting of the electrical flexibles necessary for the operation of anode change are done by specialized tools attached to the manipulator cranes.
- the electrical flex connection will only be opened to execute the anode change at the end of the useful life of the anode block.
- the operation of raising the anode beam is no longer done with an auxiliary raising beam holding the anodes in place as described above. Instead, the two sets of clamps are used for this operation.
- the process control computer will close the auxiliary clamps to maintain the present positions of the anodes while disengaging the main clamps.
- the main clamps of all anodes of the cell are in an open position, the anode beam can be raised freely. There is no need to maintain an electrical contact between anode beam and anode stems by applying pressure on the stems since the electrical conduction remains uninterrupted through the continuous flexible-stem connection.
- a method of raising an anode beam in an electrolysis cell described above including the steps of
- Figure 1 is a sectional view of an electrolysis cell and conventional anode support of the prior art
- Figure 2 is a sectional view of an electrolysis cell and anode support according to an embodiment of the invention.
- the electrolysis cell of the prior art includes a steel outer shell 12 having a bottom refractory lining 14 and sidewall refractory lining 16.
- the bottom refractory lining supports a cathode 18 having steel collector bars 20 for conducting electricity to busbars (not shown) on the outside of the steel shell 12.
- An anode assembly comprising an anode block 24 connected to an anode stem 26 via a steel yoke 22 and stubs 28 is shown.
- the anode stem 26 is both mechanically and electrically connected to an anode beam 30 by a clamping arrangement 32 fixed to the anode beam.
- Mechanical drive trains are provided to raise and lower the anode beams in order to vary the anode-cathode gap (in reality the gap between anodes immersed in the electrolyte and the liquid aluminium layer on top of the cathode) to a desired distance.
- the design of the anode raising and lowering equipment is based on the assumption that all anodes will be consumed at a constant rate and so generally, all of the anodes in the cell can be raised or lowered concurrently to maintain the gap within the optimum range.
- a number of alumina hoppers (34) is provided to supply alumina to point feeders (not shown) which are generally positioned between the pairs of anodes.
- Such anode beam systems rely on a clamp connection providing sufficient mechanical pressure to maintain the anode stems in a fixed position relative to the anode beam with this same connection providing the electrical connection between the anode beam and the anode stems. Therefore such a system comprises both the electrical connection function and the mechanical fixation function. Furthermore, the removal and addition of the anodes is provided by a crane which is positioned above the electrolytic cell. Because of the design of the cell superstructure, the crane must necessarily be much higher in order to clear the superstructure.
- the anode support structure in accordance with the invention includes an electrical beam 50 which is preferably fixed in position and connected to anode stems 26 by electrical connectors referred to as flexibles 52. These flexibles 52 maintain the electrical connection to the anode stems while giving the stems the ability to move relative to the electrical beam 50.
- the flexibles 52 are generally formed from a plurality of aluminium sheets shaped into a laminar block of aluminium with the laminar structure extending in the direction of current flow. One end of the flexibles is welded to the electrical beam 50 while the other end is connected to the top of the anode stems by way of a bolted or clamped connection 60.
- the anode supporting structure comprises a main clamp 54 attached to the vertically movable anode beam 30 and an auxiliary clamp 56 fixed to the cell superstructure base plate 58.
- the anode beam is moved by a mechanical drive train (not shown) which is similar to that of a conventional anode support structure.
- the main clamp 54 of all anodes of a cell are continuously engaged except for during the operation of raising the anode beam.
- a control means such as pneumatic cylinders or electrical motors is provided to operate the engagement and disengagement actions of the main clamps 54 and auxiliary clamps 56.
- An alumina hopper 62 smaller than the prior art hopper, is also provided in the superstructure between the anode beams 30.
- the auxiliary clamps 56 of all anodes in a given cell are closed by the process control computer. Subsequently the main clamps 54 are opened so that the mechanical drive train can lift the anode beam 30 freely with the anodes being held in their position by the auxiliary clamps 56 and the electrical connection, provided by the flexibles 52 is uninterrupted. Once the anode beam has reached its upper position the main clamps 54 are closed followed by the opening or disengaging of the auxiliary clamps 56. The whole operation of disengaging and reengaging the clamps as well as raising the anode beam is fully automated and requires no operator intervention.
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AP2007004106A AP2007004106A0 (en) | 2005-03-24 | 2006-03-22 | Anode support apparatus |
CA002600059A CA2600059A1 (en) | 2005-03-24 | 2006-03-22 | Anode support apparatus |
BRPI0611458-0A BRPI0611458A2 (en) | 2005-03-24 | 2006-03-22 | anode holding apparatus and method |
AU2006227546A AU2006227546B2 (en) | 2005-03-24 | 2006-03-22 | Anode support apparatus |
EA200702065A EA011904B1 (en) | 2005-03-24 | 2006-03-22 | Anode support apparatus |
CN2006800092543A CN101155947B (en) | 2005-03-24 | 2006-03-22 | Anode support apparatus |
JP2008502188A JP2008533309A (en) | 2005-03-24 | 2006-03-22 | Anode support device |
EP06705043A EP1861523A4 (en) | 2005-03-24 | 2006-03-22 | Anode support apparatus |
US11/850,874 US20070295601A1 (en) | 2005-03-24 | 2007-09-06 | Anode Support Apparatus |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2005901488A AU2005901488A0 (en) | 2005-03-24 | Anode support apparatus | |
AU2005901488 | 2005-03-24 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/850,874 Continuation US20070295601A1 (en) | 2005-03-24 | 2007-09-06 | Anode Support Apparatus |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006099672A1 true WO2006099672A1 (en) | 2006-09-28 |
Family
ID=37023301
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AU2006/000383 WO2006099672A1 (en) | 2005-03-24 | 2006-03-22 | Anode support apparatus |
Country Status (15)
Country | Link |
---|---|
US (1) | US20070295601A1 (en) |
EP (1) | EP1861523A4 (en) |
JP (1) | JP2008533309A (en) |
KR (1) | KR20070112829A (en) |
CN (1) | CN101155947B (en) |
AP (1) | AP2007004106A0 (en) |
BR (1) | BRPI0611458A2 (en) |
CA (1) | CA2600059A1 (en) |
EA (1) | EA011904B1 (en) |
MY (1) | MY143811A (en) |
PE (1) | PE20061223A1 (en) |
TW (1) | TW200701540A (en) |
UA (1) | UA88064C2 (en) |
WO (1) | WO2006099672A1 (en) |
ZA (1) | ZA200706834B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2989693A1 (en) * | 2012-04-24 | 2013-10-25 | Rio Tinto Alcan Int Ltd | PREHEATING CONNECTOR |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8956524B2 (en) | 2010-12-23 | 2015-02-17 | Ge-Hitachi Nuclear Energy Americas Llc | Modular anode assemblies and methods of using the same for electrochemical reduction |
US9017527B2 (en) * | 2010-12-23 | 2015-04-28 | Ge-Hitachi Nuclear Energy Americas Llc | Electrolytic oxide reduction system |
US8771482B2 (en) | 2010-12-23 | 2014-07-08 | Ge-Hitachi Nuclear Energy Americas Llc | Anode shroud for off-gas capture and removal from electrolytic oxide reduction system |
US8636892B2 (en) | 2010-12-23 | 2014-01-28 | Ge-Hitachi Nuclear Energy Americas Llc | Anode-cathode power distribution systems and methods of using the same for electrochemical reduction |
US8900439B2 (en) | 2010-12-23 | 2014-12-02 | Ge-Hitachi Nuclear Energy Americas Llc | Modular cathode assemblies and methods of using the same for electrochemical reduction |
US8882973B2 (en) | 2011-12-22 | 2014-11-11 | Ge-Hitachi Nuclear Energy Americas Llc | Cathode power distribution system and method of using the same for power distribution |
US9150975B2 (en) | 2011-12-22 | 2015-10-06 | Ge-Hitachi Nuclear Energy Americas Llc | Electrorefiner system for recovering purified metal from impure nuclear feed material |
US8598473B2 (en) | 2011-12-22 | 2013-12-03 | Ge-Hitachi Nuclear Energy Americas Llc | Bus bar electrical feedthrough for electrorefiner system |
US8746440B2 (en) | 2011-12-22 | 2014-06-10 | Ge-Hitachi Nuclear Energy Americas Llc | Continuous recovery system for electrorefiner system |
US8945354B2 (en) | 2011-12-22 | 2015-02-03 | Ge-Hitachi Nuclear Energy Americas Llc | Cathode scraper system and method of using the same for removing uranium |
US8968547B2 (en) | 2012-04-23 | 2015-03-03 | Ge-Hitachi Nuclear Energy Americas Llc | Method for corium and used nuclear fuel stabilization processing |
AU2013296631A1 (en) * | 2012-08-01 | 2015-02-19 | Alcoa Usa Corp. | Inert electrodes with low voltage drop and methods of making the same |
DK179903B1 (en) * | 2013-08-09 | 2019-09-17 | Rio Tinto Alcan International Limited | ELECTROLYTIC DEVICE AND ANODE COLLECTION CALCULATED PRODUCTION OF ALUMINUM, ELECTROLYTICAL CELL AND DEVICE INCLUDING SUCH A DEVICE |
GB2566674A (en) * | 2017-08-01 | 2019-03-27 | Dubai Aluminium Pjsc | Electrolytic cell for aluminium production, with individual anode drives |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU524863A1 (en) * | 1975-04-23 | 1976-08-15 | Всесоюзный научно-исследовательский и проектный институт алюминиевой, магниевой и электродной промышленности "ВАМИ" | Portable device for the suspension of baked anodes of an aluminum electrolysis cell |
FR2582677A1 (en) * | 1985-05-30 | 1986-12-05 | Pechiney Aluminium | ELECTROLYSIS TANK SUPERSTRUCTURE WITH INTERMEDIATE GANTRY FOR THE PRODUCTION OF ALUMINUM |
EP0298198A1 (en) * | 1987-07-09 | 1989-01-11 | TECHMO Car S.p.A. | Equipment for the mechanized replacement of the anodes in the electrolytic cells for aluminum production |
EP0387687A1 (en) * | 1989-03-13 | 1990-09-19 | VAW Aluminium AG | Process and apparatus for regulating the interpolar distance to compensate the anode burning up in electrolysis cells |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL299426A (en) * | 1962-10-19 | |||
JPS5937352B2 (en) * | 1978-11-09 | 1984-09-08 | 日本軽金属株式会社 | Anode support beam lifting device in electrolytic furnace |
US4414070A (en) * | 1982-02-12 | 1983-11-08 | Alcan International Limited | Anode positioning system |
-
2006
- 2006-03-22 KR KR1020077022278A patent/KR20070112829A/en not_active Application Discontinuation
- 2006-03-22 AP AP2007004106A patent/AP2007004106A0/en unknown
- 2006-03-22 CA CA002600059A patent/CA2600059A1/en not_active Abandoned
- 2006-03-22 CN CN2006800092543A patent/CN101155947B/en not_active Expired - Fee Related
- 2006-03-22 BR BRPI0611458-0A patent/BRPI0611458A2/en not_active IP Right Cessation
- 2006-03-22 WO PCT/AU2006/000383 patent/WO2006099672A1/en active Application Filing
- 2006-03-22 UA UAA200711729A patent/UA88064C2/en unknown
- 2006-03-22 EP EP06705043A patent/EP1861523A4/en not_active Withdrawn
- 2006-03-22 JP JP2008502188A patent/JP2008533309A/en active Pending
- 2006-03-22 EA EA200702065A patent/EA011904B1/en not_active IP Right Cessation
- 2006-03-23 TW TW095110090A patent/TW200701540A/en unknown
- 2006-03-24 PE PE2006000339A patent/PE20061223A1/en not_active Application Discontinuation
- 2006-03-24 MY MYPI20061317A patent/MY143811A/en unknown
-
2007
- 2007-08-08 ZA ZA200706834A patent/ZA200706834B/en unknown
- 2007-09-06 US US11/850,874 patent/US20070295601A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU524863A1 (en) * | 1975-04-23 | 1976-08-15 | Всесоюзный научно-исследовательский и проектный институт алюминиевой, магниевой и электродной промышленности "ВАМИ" | Portable device for the suspension of baked anodes of an aluminum electrolysis cell |
FR2582677A1 (en) * | 1985-05-30 | 1986-12-05 | Pechiney Aluminium | ELECTROLYSIS TANK SUPERSTRUCTURE WITH INTERMEDIATE GANTRY FOR THE PRODUCTION OF ALUMINUM |
EP0298198A1 (en) * | 1987-07-09 | 1989-01-11 | TECHMO Car S.p.A. | Equipment for the mechanized replacement of the anodes in the electrolytic cells for aluminum production |
EP0387687A1 (en) * | 1989-03-13 | 1990-09-19 | VAW Aluminium AG | Process and apparatus for regulating the interpolar distance to compensate the anode burning up in electrolysis cells |
Non-Patent Citations (2)
Title |
---|
DATABASE WPI Week 197719, Derwent World Patents Index; Class M28, AN 1977-34094Y, XP008114443 * |
See also references of EP1861523A4 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2989693A1 (en) * | 2012-04-24 | 2013-10-25 | Rio Tinto Alcan Int Ltd | PREHEATING CONNECTOR |
EP2841626A4 (en) * | 2012-04-24 | 2016-01-27 | Rio Tinto Alcan Int Ltd | Preheating connector |
Also Published As
Publication number | Publication date |
---|---|
EP1861523A1 (en) | 2007-12-05 |
CN101155947A (en) | 2008-04-02 |
TW200701540A (en) | 2007-01-01 |
KR20070112829A (en) | 2007-11-27 |
ZA200706834B (en) | 2008-10-29 |
JP2008533309A (en) | 2008-08-21 |
BRPI0611458A2 (en) | 2010-09-08 |
EA200702065A1 (en) | 2008-02-28 |
AP2007004106A0 (en) | 2007-08-31 |
CN101155947B (en) | 2010-09-08 |
MY143811A (en) | 2011-07-15 |
EA011904B1 (en) | 2009-06-30 |
CA2600059A1 (en) | 2006-09-28 |
US20070295601A1 (en) | 2007-12-27 |
UA88064C2 (en) | 2009-09-10 |
EP1861523A4 (en) | 2010-11-03 |
PE20061223A1 (en) | 2007-01-13 |
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