WO2006094006A3 - Gasoline production by olefin polymerization - Google Patents

Gasoline production by olefin polymerization Download PDF

Info

Publication number
WO2006094006A3
WO2006094006A3 PCT/US2006/007168 US2006007168W WO2006094006A3 WO 2006094006 A3 WO2006094006 A3 WO 2006094006A3 US 2006007168 W US2006007168 W US 2006007168W WO 2006094006 A3 WO2006094006 A3 WO 2006094006A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
converted
mww
kpag
spa
Prior art date
Application number
PCT/US2006/007168
Other languages
French (fr)
Other versions
WO2006094006A2 (en
Inventor
Stephen H Brown
George M K Mathys
Jane Chi-Ya Cheng
Jeffrey Thomas Elks
Ajit Bhaskar Dandekar
Benjamin Santiago Umansky
Michael Christopher Clark
Original Assignee
Exxonmobil Res & Eng Co
Stephen H Brown
George M K Mathys
Jane Chi-Ya Cheng
Jeffrey Thomas Elks
Ajit Bhaskar Dandekar
Benjamin Santiago Umansky
Michael Christopher Clark
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/362,257 external-priority patent/US20060194999A1/en
Application filed by Exxonmobil Res & Eng Co, Stephen H Brown, George M K Mathys, Jane Chi-Ya Cheng, Jeffrey Thomas Elks, Ajit Bhaskar Dandekar, Benjamin Santiago Umansky, Michael Christopher Clark filed Critical Exxonmobil Res & Eng Co
Priority to EP06736479A priority Critical patent/EP1856009A4/en
Priority to CA002599492A priority patent/CA2599492A1/en
Priority to JP2007558154A priority patent/JP2008531818A/en
Priority to BRPI0609156A priority patent/BRPI0609156A2/en
Publication of WO2006094006A2 publication Critical patent/WO2006094006A2/en
Publication of WO2006094006A3 publication Critical patent/WO2006094006A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1081—Alkanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C10G2300/1092—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/802—Diluents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Solid phosphoric acid (SPA) olefin oligomerization process units may be converted to operation with a more environmentally favorable solid catalyst. The SPA units in which a light olefin feed is oligomerized to form gasoline boiling range hydrocarbon product, is converted unit to operation with a molecular sieve based olefin oligomerization catalyst comprising an MWW zeolite material. Besides being more environmentally favorable in use, the MWW based zeolites offer advantages in catalyst cycle life, selectivity and product quality. After loading of the catalyst, the converted unit is operated as a fixed-bed unit by passing the C2-C4 olefinic feed to a fixed bed of the MWW zeolite condensation catalyst, typically at a temperature from 150 to 250°C, a pressure not greater than 7000 kPag, usually less than 4000 kPag and a space velocity up to 30 WHSV. The gasoline boiling range product is notable for a high level of branched chain octenes resulting in high octane quality.
PCT/US2006/007168 2005-02-28 2006-02-28 Gasoline production by olefin polymerization WO2006094006A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP06736479A EP1856009A4 (en) 2005-02-28 2006-02-28 Gasoline production by olefin polymerization
CA002599492A CA2599492A1 (en) 2005-02-28 2006-02-28 Gasoline production by olefin polymerization
JP2007558154A JP2008531818A (en) 2005-02-28 2006-02-28 Gasoline production by olefin polymerization
BRPI0609156A BRPI0609156A2 (en) 2005-02-28 2006-02-28 method for converting one unit of the olefin oligomerization process by spa, process for producing a gasoline boiling range mixing component, and method for producing a product in the gasoline boiling range

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US65695405P 2005-02-28 2005-02-28
US60/656,954 2005-02-28
US11/362,257 US20060194999A1 (en) 2005-02-28 2006-02-27 Gasoline production by olefin polymerization
US11/362,257 2006-02-27

Publications (2)

Publication Number Publication Date
WO2006094006A2 WO2006094006A2 (en) 2006-09-08
WO2006094006A3 true WO2006094006A3 (en) 2006-12-21

Family

ID=36941751

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/007168 WO2006094006A2 (en) 2005-02-28 2006-02-28 Gasoline production by olefin polymerization

Country Status (6)

Country Link
EP (1) EP1856009A4 (en)
JP (1) JP2008531818A (en)
BR (1) BRPI0609156A2 (en)
CA (1) CA2599492A1 (en)
RU (1) RU2007134098A (en)
WO (1) WO2006094006A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008013644A1 (en) 2006-07-28 2008-01-31 Exxonmobil Chemical Patents Inc. A mcm-22 family molecular sieve composition, its method of making, and use for hydrocarbon conversions
KR101044495B1 (en) 2006-07-28 2011-06-27 엑손모빌 케미칼 패턴츠 인코포레이티드 Molecular sieve compositionemm-10, its method of making, and use for hydrocarbon conversions
US7959899B2 (en) 2006-07-28 2011-06-14 Exxonmobil Chemical Patents Inc. Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions
EP2098498A1 (en) * 2008-03-04 2009-09-09 ExxonMobil Chemical Patents Inc. Selective oligomerization of isobutene

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4956514A (en) * 1988-10-06 1990-09-11 Mobil Oil Corp. Process for converting olefins to higher hydrocarbons
WO1993016020A2 (en) * 1992-01-30 1993-08-19 Exxon Chemical Patents Inc. Alkene oligomerization
US6399843B1 (en) * 2000-10-12 2002-06-04 Uop Llc Upflow oligomerization reaction process

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3960978A (en) * 1974-09-05 1976-06-01 Mobil Oil Corporation Converting low molecular weight olefins over zeolites
US4520221A (en) * 1984-04-09 1985-05-28 Mobil Oil Corporation Process of making high VI lubes
US4919896A (en) * 1987-12-28 1990-04-24 Mobil Oil Corporation Multistage catalytic reactor system for production of heavy hydrocarbons
EP0746538B1 (en) * 1994-02-22 1999-01-27 Exxon Chemical Patents Inc. Oligomerization and catalysts therefor
GB0412139D0 (en) * 2004-06-01 2004-06-30 Exxonmobil Chem Patents Inc Olefin oligomerization process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4956514A (en) * 1988-10-06 1990-09-11 Mobil Oil Corp. Process for converting olefins to higher hydrocarbons
WO1993016020A2 (en) * 1992-01-30 1993-08-19 Exxon Chemical Patents Inc. Alkene oligomerization
US6399843B1 (en) * 2000-10-12 2002-06-04 Uop Llc Upflow oligomerization reaction process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1856009A4 *

Also Published As

Publication number Publication date
EP1856009A4 (en) 2012-01-04
WO2006094006A2 (en) 2006-09-08
JP2008531818A (en) 2008-08-14
EP1856009A2 (en) 2007-11-21
RU2007134098A (en) 2009-04-10
BRPI0609156A2 (en) 2016-08-23
CA2599492A1 (en) 2006-09-08

Similar Documents

Publication Publication Date Title
WO2006094007A3 (en) Process for making high octane gasoline with reduced benzene content
KR101572714B1 (en) Production of propylene via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by metathesis
EP1948578B1 (en) Oligomerization reaction
KR101544257B1 (en) Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts
WO2010104581A3 (en) Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion
CA2599347A1 (en) Liquid phase aromatics alkylation process
KR20100058663A (en) Selective oligomerization of isobutene
KR100635314B1 (en) Process for the selective dimerisation of isobutene
JP2008531819A5 (en)
EP2736632B1 (en) Integrated nitrile poison adsorption and desorption system
MY153930A (en) Oligomerisation of olefins
WO2006094006A3 (en) Gasoline production by olefin polymerization
KR20130086342A (en) Process for co-oligomerization of olefins
CA2599351A1 (en) Gasoline production by olefin polymerization with aromatics alkylation
CA2654940A1 (en) Process for the manufacture of olefin oligomers
US9550705B2 (en) Olefin oligomerization process
US20180170825A1 (en) Process and system for low pressure olefin conversion to a distillate boiling range product
CA2599503A1 (en) Vapor phase aromatics alkylation process
US11691129B2 (en) Direct catalytic conversion of alcohols to olefins of higher carbon number with reduced ethylene production
US20150246855A1 (en) Process for the production of kerosene from butanols
US9505674B2 (en) Processes for treating olefin feedstreams and related oligomerization processes
WO2013013884A2 (en) Process for nitrile removal from hydrocarbon feeds
WO2012076991A3 (en) Process for modifying zeolite by incorporation of phosphorus into the crystalline structure and catalysts for oligomerization of olefins
FI120197B (en) Process for dimerization of olefins
RU2012123621A (en) METHOD FOR CLEANING OLEFIN RAW MATERIALS

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 2007558154

Country of ref document: JP

ENP Entry into the national phase

Ref document number: 2599492

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2006736479

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2007134098

Country of ref document: RU

ENP Entry into the national phase

Ref document number: PI0609156

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20070828