WO2006038011A3 - Active filler particles in inks - Google Patents

Active filler particles in inks Download PDF

Info

Publication number
WO2006038011A3
WO2006038011A3 PCT/GB2005/003842 GB2005003842W WO2006038011A3 WO 2006038011 A3 WO2006038011 A3 WO 2006038011A3 GB 2005003842 W GB2005003842 W GB 2005003842W WO 2006038011 A3 WO2006038011 A3 WO 2006038011A3
Authority
WO
WIPO (PCT)
Prior art keywords
substrate
usually
autocatalytic
inks
plating
Prior art date
Application number
PCT/GB2005/003842
Other languages
French (fr)
Other versions
WO2006038011A2 (en
Inventor
Daniel Robert Johnson
Richard Lance Willis
William Norman Damerell
Original Assignee
Qinetiq Ltd
Daniel Robert Johnson
Richard Lance Willis
William Norman Damerell
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinetiq Ltd, Daniel Robert Johnson, Richard Lance Willis, William Norman Damerell filed Critical Qinetiq Ltd
Priority to US11/663,819 priority Critical patent/US20070261595A1/en
Priority to EP05797479A priority patent/EP1799880B1/en
Priority to AT05797479T priority patent/ATE451431T1/en
Priority to JP2007535236A priority patent/JP2008516039A/en
Priority to DE602005018241T priority patent/DE602005018241D1/en
Publication of WO2006038011A2 publication Critical patent/WO2006038011A2/en
Publication of WO2006038011A3 publication Critical patent/WO2006038011A3/en

Links

Classifications

    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
    • H05K3/18—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material
    • H05K3/181—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material by electroless plating
    • H05K3/182—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material by electroless plating characterised by the patterning method
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1603—Process or apparatus coating on selected surface areas
    • C23C18/1607—Process or apparatus coating on selected surface areas by direct patterning
    • C23C18/1608—Process or apparatus coating on selected surface areas by direct patterning from pretreatment step, i.e. selective pre-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/1803—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
    • C23C18/1824—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
    • C23C18/1827—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment only one step pretreatment
    • C23C18/1831—Use of metal, e.g. activation, sensitisation with noble metals
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/28—Sensitising or activating
    • C23C18/30—Activating or accelerating or sensitising with palladium or other noble metal
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1646—Characteristics of the product obtained
    • C23C18/165—Multilayered product
    • C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
    • H05K2201/0203—Fillers and particles
    • H05K2201/0206—Materials
    • H05K2201/0209—Inorganic, non-metallic particles
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
    • H05K2201/0203—Fillers and particles
    • H05K2201/0206—Materials
    • H05K2201/0212—Resin particles
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/07—Treatments involving liquids, e.g. plating, rinsing
    • H05K2203/0703—Plating
    • H05K2203/0709—Catalytic ink or adhesive for electroless plating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemically Coating (AREA)
  • Powder Metallurgy (AREA)
  • Manufacturing Of Printed Wiring (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Autocatalytic plating is a form of electrode-less plating in which a metal, for example, cobalt, nickel, gold, silver or copper, is deposited onto a substrate via a chemical reduction process. Coatings derived from this process are usually more uniform and adherent than from other processes and can be applied to unusually shaped surfaces. Non-metallic surfaces can only usually be coated via this process following suitable sensitisation of the substrate. This invention therefore provides a method of preparing a substrate material for subsequent autocatalytic deposition of a metal coating reducing the need for surface preparation by using a reducible silver salt with a suitable filler in a printable ink formulation. Autocatalytic deposition may be used to coat whole surfaces or pre-determined patterns may be deposited by known printing methods.
PCT/GB2005/003842 2004-10-08 2005-10-06 Active filler particles in inks WO2006038011A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US11/663,819 US20070261595A1 (en) 2004-10-08 2005-10-06 Active Filler particles in Inks
EP05797479A EP1799880B1 (en) 2004-10-08 2005-10-06 Active filler particles in inks
AT05797479T ATE451431T1 (en) 2004-10-08 2005-10-06 ACTIVE FILLER PARTICLES IN PRINTING INKS
JP2007535236A JP2008516039A (en) 2004-10-08 2005-10-06 Active filler particles in ink
DE602005018241T DE602005018241D1 (en) 2004-10-08 2005-10-06 ACTIVE FILLER PARTS IN PRINTING COLORS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0422386.3 2004-10-08
GBGB0422386.3A GB0422386D0 (en) 2004-10-08 2004-10-08 Active filler particles in inks

Publications (2)

Publication Number Publication Date
WO2006038011A2 WO2006038011A2 (en) 2006-04-13
WO2006038011A3 true WO2006038011A3 (en) 2007-08-02

Family

ID=33443601

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2005/003842 WO2006038011A2 (en) 2004-10-08 2005-10-06 Active filler particles in inks

Country Status (7)

Country Link
US (1) US20070261595A1 (en)
EP (1) EP1799880B1 (en)
JP (1) JP2008516039A (en)
AT (1) ATE451431T1 (en)
DE (1) DE602005018241D1 (en)
GB (1) GB0422386D0 (en)
WO (1) WO2006038011A2 (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE602006020031D1 (en) 2005-04-12 2011-03-24 Asahi Glass Co Ltd COLOR COMPOSITION AND METAL MATERIAL
US8231811B2 (en) 2006-07-22 2012-07-31 Conductive Inkjet Technology Limited Formation of conductive metal regions on substrates
EP2384246A1 (en) * 2009-01-30 2011-11-09 E. I. du Pont de Nemours and Company Inkjet inks with increased optical density
CN103183979B (en) * 2011-12-27 2014-11-05 比亚迪股份有限公司 Ink composition and application for same, as well as product with selectively-metallized surface and preparation method for same
US9663667B2 (en) * 2013-01-22 2017-05-30 Andre Reiss Electroless silvering ink
EP3209808A4 (en) * 2014-10-21 2017-10-11 Oreltech Ltd. A method and system for forming a patterned metal film on a substrate
US9592493B2 (en) 2014-12-16 2017-03-14 Eastman Kodak Company Forming silver catalytic sites from silver phosphite carboxylates
US9375704B1 (en) 2014-12-16 2016-06-28 Eastman Kodak Company Metal catalytic composition with silver carboxylate-trialkyl(triaryl)phosphite complex
US9377688B1 (en) 2014-12-16 2016-06-28 Eastman Kodak Company Metal catalytic composition with silver N-heterocycle complex
US9586200B2 (en) 2014-12-16 2017-03-07 Eastman Kodak Company Forming catalytic sites from reducible silver complexes
US9587315B2 (en) 2014-12-16 2017-03-07 Eastman Kodak Company Forming silver catalytic sites from reducible silver-oximes
US9624582B2 (en) 2014-12-16 2017-04-18 Eastman Kodak Company Non-aqueous metal catalytic composition with oxyazinium photoreducing agent
US9586201B2 (en) 2014-12-16 2017-03-07 Eastman Kodak Company Forming catalytic sites from reducible silver-heterocyclic complexes
US9387460B2 (en) 2014-12-16 2016-07-12 Eastman Kodak Company Metal catalytic composition with silver-oxime complex
US9982349B2 (en) 2015-05-11 2018-05-29 Eastman Kodak Company Method for making electrically-conductive articles
US9566569B2 (en) 2015-05-11 2017-02-14 Eastman Kodak Company Metal catalytic compositions and articles therefrom
CN105142353A (en) * 2015-06-12 2015-12-09 信丰福昌发电子有限公司 Selective electroless gold plating process for printed circuit boards
CN105176193A (en) * 2015-09-02 2015-12-23 王景泉 In-mold decoration made electric appliance panel mirror surface printing ink and preparation method thereof
US10174425B2 (en) 2015-09-22 2019-01-08 Eastman Kodak Company Non-aqueous compositions and articles using stannous alkoxides
US9617642B1 (en) 2015-09-22 2017-04-11 Eastman Kodak Company Silver formation using stannous alkoxide complexes
KR102112435B1 (en) * 2016-03-23 2020-05-18 후지필름 가부시키가이샤 Method of manufacturing a conductive laminate, a three-dimensional structure having a precursor layer to be plated, a three-dimensional structure having a pattern-shaped plated layer, a conductive laminate, a touch sensor, a heating member, and a three-dimensional structure
US10814659B2 (en) 2018-06-28 2020-10-27 Xerox Corporation Methods for printing conductive objects
JP7175850B2 (en) * 2019-06-21 2022-11-21 トッパン・フォームズ株式会社 silver ink composition
CN115427514B (en) * 2020-03-30 2024-01-02 东丽株式会社 Resin composition, light-shielding film, and substrate with partition wall
CN114958081B (en) * 2022-05-20 2023-03-28 江苏广信感光新材料股份有限公司 PCB (printed circuit board) one-stage type liquid flame-retardant hole plugging ink and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4368281A (en) * 1980-09-15 1983-01-11 Amp Incorporated Printed circuits
US5378268A (en) * 1990-11-16 1995-01-03 Bayer Aktiengesellschaft Primer for the metallization of substrate surfaces
WO2002099163A2 (en) * 2001-06-04 2002-12-12 Qinetiq Limited Autocatalytic coating method

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Publication number Priority date Publication date Assignee Title
US3560257A (en) * 1967-01-03 1971-02-02 Kollmorgen Photocircuits Metallization of insulating substrates
DE2442762C2 (en) * 1974-09-06 1983-02-24 Basf Ag, 6700 Ludwigshafen Layered magnetogram carrier with polyurethane elastomer binders in the magnetic layer
JPS537225A (en) * 1976-07-07 1978-01-23 Fuji Photo Film Co Ltd Photographic material and image formation using the same
US4965094A (en) * 1988-12-27 1990-10-23 At&T Bell Laboratories Electroless silver coating for dielectric filter
DE4107644A1 (en) * 1991-03-09 1992-09-10 Bayer Ag HYDROPRIMER FOR METALLIZING SUBSTRATE SURFACES
JP3731639B2 (en) * 1999-11-15 2006-01-05 信越化学工業株式会社 Fluorine-containing polysiloxane, method for producing the same, and fiber treating agent composition
US20030177639A1 (en) * 2002-03-19 2003-09-25 Berg N. Edward Process and apparatus for manufacturing printed circuit boards

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4368281A (en) * 1980-09-15 1983-01-11 Amp Incorporated Printed circuits
US5378268A (en) * 1990-11-16 1995-01-03 Bayer Aktiengesellschaft Primer for the metallization of substrate surfaces
WO2002099163A2 (en) * 2001-06-04 2002-12-12 Qinetiq Limited Autocatalytic coating method

Also Published As

Publication number Publication date
ATE451431T1 (en) 2009-12-15
US20070261595A1 (en) 2007-11-15
WO2006038011A2 (en) 2006-04-13
DE602005018241D1 (en) 2010-01-21
EP1799880A2 (en) 2007-06-27
GB0422386D0 (en) 2004-11-10
JP2008516039A (en) 2008-05-15
EP1799880B1 (en) 2009-12-09

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