WO2006036602A2 - Increased yield of cubic crystalline optical elements by crystal orientation - Google Patents
Increased yield of cubic crystalline optical elements by crystal orientation Download PDFInfo
- Publication number
- WO2006036602A2 WO2006036602A2 PCT/US2005/033223 US2005033223W WO2006036602A2 WO 2006036602 A2 WO2006036602 A2 WO 2006036602A2 US 2005033223 W US2005033223 W US 2005033223W WO 2006036602 A2 WO2006036602 A2 WO 2006036602A2
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- WIPO (PCT)
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- crystal plane
- alternative
- optical
- primary
- plane
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/02—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of crystals, e.g. rock-salt, semi-conductors
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/28—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 for polarising
- G02B27/283—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 for polarising used for beam splitting or combining
Definitions
- the invention relates to cubic crystalline optical elements, particularly calcium fluoride, in forms such as prisms for propagating highly collimated, linearly polarized light along predetermined crystal axes and to the manufacture and use of such cubic crystalline optical elements.
- UV light wavelengths between approximately 120 nanometers and 250 nanometers
- Most ordinary optical materials are either insufficiently transmissive or subject to breakdown by absorption.
- Calcium fluoride (CaF 2 ) is among the optical materials capable of transmitting deep UV light. Despite calcium fluoride's highly symmetric cubic crystalline structure, calcium fluoride exhibits intrinsic birefringence at the short wavelengths. Different polarization components of the ultraviolet light experience different refractive indices depending upon both the direction of polarization and the direction of propagation of the light through the crystal material. A description of the nature of the intrinsic birefringence in calcium fluoride crystals is found in a paper by John Burnett, Zachary Levine, Eric Shirley, and John Bruning entitled "Symmetry of spatial-dispersion-induced birefringence and its implications for CaF 2 ultraviolet optics", Society of Photo-Optical Instrumentation Engineers, J. Microhm., Microfab., Microsyst. p. 213-224, October 2002, which is hereby incorporated by reference.
- crystal axes which can be referenced according to Miller indicies, along which deep ultraviolet light can be propagated through calcium fluoride crystals without encountering intrinsic birefringence effects. These include propagations in both directions along the three cube axes (i.e., the family of ⁇ 1 0 0> directions) and along the four cube body diagonals (i.e., the family of ⁇ 1 1 1> directions, referred to herein as the ⁇ 1 1 1> main axis).
- the ⁇ l 1 1> main axis is a normal to the natural ⁇ 1 1 1 ⁇ cleavage plane of calcium fluoride crystals, referred to herein as the ⁇ 1 1 1 ⁇ primary plane.
- the ⁇ 1 1 1 ⁇ primary plane is the plane along which the crystal tends to break first when struck.
- Optical elements made from calcium fluoride crystals are generally oriented for propagation of light along the ⁇ 1 1 1> main axis, because the natural cleavage of calcium fluoride crystals presents planar surfaces normal to the crystal's ⁇ 1 1 1> main axis.
- Prisms for use in the deep UV are frequently cut out of calcium fluoride crystals grown in rod form with either ordered or randomly oriented crystal axes.
- One end of the rods is cleaved along the ⁇ 1 1 1 ⁇ primary plane (normal to the ⁇ 1 1 1> main axis) to provide a basis for prism orientation.
- the sides of the oriented rods are cut and polished to form slabs.
- a line of prisms are traced on the slab, and the slab is further cleaved for orienting each of the prisms to support the propagation of light along the ⁇ 1 1 1> main axis of the crystal.
- the invention contemplates the propagation of highly collimated, linearly polarized, deep UV light along cubic crystal axes that are oriented perpendicular to the ⁇ 1 1 1> main axis along which light is usually propagated.
- the alternative axes designated as ⁇ 1 1 2>, ⁇ 1 2 1> and ⁇ 2 1 1> axes, occupy even 60° intervals about the ⁇ 1 1 1> main axis.
- cubic crystal bodies can be grown as usual with either ordered or randomly oriented crystal axes, and the crystal axes can be referenced as usual by first cleaving the crystal body along the ⁇ 1 1 1 ⁇ primary plane defined as normal to the ⁇ 1 1 1> crystal axis.
- inspection determines the orientation of an alternative crystal plane ⁇ 1 1 2 ⁇ , ⁇ 1 2 1 ⁇ , or ⁇ 2 1 1 ⁇ defined as normal to one of the ⁇ 1 1 2>, ⁇ 1 2 1>, and ⁇ 2 1 1> alternative crystal axes.
- the crystal body is divided into a plurality of optical elements each having at least one surface substantially parallel to the ⁇ 1 1 1 ⁇ primary crystal plane and at least one surface substantially perpendicular to the primary crystal plane ⁇ 1 1 1 ⁇ .
- the at least one surface substantially perpendicular to the ⁇ 1 1 1 ⁇ primary crystal plane is oriented with respect to one of the ⁇ 1 1 2 ⁇ , ⁇ 1 2 1 ⁇ , or ⁇ 2 1 1 ⁇ alternative crystal planes so that an intended direction of propagation of light refracted into each of the optical elements is along the one of the ⁇ 1 1 2>, ⁇ 1 2 1>, and ⁇ 2 1 1> alternative crystal axes.
- a plurality of cuts substantially parallel to the ⁇ 1 1 1 ⁇ primary crystal plane along even increments of the crystal body length produce a plurality of commonly oriented slabs, preferably in the form of disks.
- Each of the disks has a top and bottom surface connected by a peripheral surface corresponding to a peripheral surface of the crystal body.
- the peripheral surfaces of the commonly oriented disks are finished to produce at least one optical surface in each of the disks oriented substantially perpendicular to the ⁇ 1 1 1 ⁇ primary crystal plane at a predetermined inclination to the one ⁇ 1 1 2 ⁇ , ⁇ 1 2 l ⁇ , or ⁇ 2 1 1 ⁇ alternative crystal plane.
- the at least one surface substantially perpendicular to the ⁇ 1 1 1 ⁇ primary crystal plane is preferably inclined with respect to the ⁇ 1 1 2 ⁇ , ⁇ 1 2 1 ⁇ , or ⁇ 2 1 1 ⁇ alternative crystal plane so that a highly-collimated beam of linearly-polarized light refracts into its intended direction of propagation of light through each of the optical elements along the one ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axis.
- the new orientations enable the disks to be divided into a number of parts with each part fashioned into a separate optical element.
- the periphery of the crystal body is preferably marked to identity the orientation of the ⁇ 1 1 2 ⁇ , ⁇ 1 2 1 ⁇ , or ⁇ 2 1 1 ⁇ alternative crystal plane.
- the ' markings allow the intended optical elements to be traced onto the individual disks oriented as desired to the one ⁇ 1 1 2>, ⁇ 1 2 1 >, or ⁇ 2 1 1> alternative crystal axis and for each of the disks to be cut into oriented parts for separating adjacent surfaces of the intended optical elements.
- the invention is particularly applicable to the manufacture of prisms.
- Two faces of the prisms can be formed from top and bottom surfaces of the disks cut substantially parallel to the ⁇ 1 1 1 ⁇ primary crystal plane, and side faces of the prisms can be formed in the peripheral surfaces of the disks substantially perpendicular to the ⁇ 1 1 1 ⁇ primary crystal plane .
- Each of the disks can be cut in planes substantially perpendicular to the ⁇ 1 1 1 ⁇ primary crystal plane for forming another crystal side face, particularly as an entrance face oriented for directing light along the alternative ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> crystal axis.
- FIG. 1 illustrates a seven step method, designated as steps A - G, for increasing the yield of a cubic crystal rod for forming a plurality of prisms.
- FIG. 2 is an enlargement of a disk from Step F of FIG. 1 showing the traces of two prisms and three alternative crystal axes in the disk.
- FIG. 3 is a side view of one of the prisms arranged for refracting light along one of the alternative crystal axes.
- FIG. 4 is a perspective view of the prism of FIG. 3 in wire outline form showing more of the prism surfaces.
- a sequence of processing steps laid out in FIG. 1 exemplifies a method for increasing yield of optical elements from a cubic crystal material in accordance with the invention.
- a crystal rod 10 made of calcium fluoride is grown either with randomly oriented crystal axes or with crystal axes having a preferred orientation imposed by seeding. Either way, the exact orientation of the crystal axes is not immediately apparent from the crystal rod.
- Step B the crystal rod 10 is cleaved near one end along the ⁇ 1 1 1 ⁇ plane normal to the ⁇ 1 1 1> main axis, hi such calcium fluoride crystals, this is the crystal plane along which the crystal most readily breaks and provides a convenient and accurate reference plane 14 for the crystal rod 10.
- the ⁇ 1 1 1 ⁇ reference plane 14 identifies one of the crystal axes, i.e., the ⁇ 1 1 1> main crystal axis, it is necessary to identify a second axis to fully orient the cubic crystal.
- Step C involves an inspection procedure for identifying a second crystal axis orthogonal to the ⁇ 1 1 1> main axis, hi particular, a Laue x-ray diffractometer is used to find one of the ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axes.
- Two orientation labels 16 and 18 are applied to the periphery of the crystal rod 10 to identify the location of one of the ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axes that extends perpendicular to the ⁇ 1 1 1> main axis.
- the orientation labels 16 and 18 are preferably drawn on the crystal rod 10 as two diametrically opposed lines.
- parallel cuts 20 are made along the length of the rod 10 as shown in Step D, each at a predetermined thickness "T".
- the parallel cuts 20 divide the crystal rod 10 into a plurality of slabs in the form of slightly eccentric disks 22 as shown in Step E.
- the crystal rod 10 can be mounted in a sacrificial plastic holder and loaded into a saw, such as a ID or diamond saw, and accurately cut onto the plurality of eccentric disks 22.
- the tops and bottoms of the eccentric disks 22 are then double-side lapped to create highly parallel ground surfaces 24 and 26 in much the same way as optical windows are formed.
- the top and bottom surfaces 24 and 26 of the disks 22 are ground parallel to the ⁇ 1 1 1 ⁇ reference plane 14 coincident with other of the set of parallel ⁇ 1 1 1 ⁇ planes.
- the ⁇ 1 1 1> main axis extends normal to the cut parallel surfaces 24 and 26 of the disks 22.
- the ⁇ 1 1 2>, ⁇ 1 2 1>, and ⁇ 2 1 1> alternative crystal axes are known to be oriented perpendicular to the ⁇ 1 1 1> main axis and parallel to the ⁇ 1 1 1 ⁇ planes that form the parallel surfaces 24 and 26 of the disks 22.
- FIG. 2 shows an enlargement of the Step F in which the outline of two optical elements in the form of prisms 30 and 32 are drawn on each of the disks 22 in positions that are angularly oriented as desired to the ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axes.
- orientation labels 16 and 18 only identify one of the ⁇ 1 1 2>, ⁇ 1 2 1 >, or ⁇ 2 1 1> alternative crystal axes by virtue of its direction across the surfaces 24 and 26 of the disks 22, the other two of the ⁇ 1 1 2>, ⁇ 1 2 1>, and ⁇ 2 1 1> alternative crystal axes are also know by geometric reference. Accordingly, the prisms 30 and 32 can be oriented with respect to any one of the ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axes.
- each of the prisms 30 and 32 includes two end faces 36 and 38 that correspond to the parallel surfaces 24 and 26 of the disks 22 and that lie in the ⁇ 1 1 1 ⁇ crystal planes and three side faces 40, 42, and 44 that extend perpendicular to both the parallel surfaces 24 and 26 of the disks 22 and the ⁇ 1 1 1 ⁇ crystal planes.
- the chosen direction for propagation of light through the prisms 30 and 32 along the ⁇ 1 1 2> alternative crystal axis is shown by the dashed lines 34.
- the disks 22 are cut in half in a known orientation, such as along or referenced to one of the other ⁇ 1 2 1> or ⁇ 2 1 1> alternative crystal axes - the ⁇ 1 2 1> alternative axis being shown as an appropriate cut line in FIG. 2.
- Each of the half disks 50 and 52 are finished formed into the prisms 30 and 32.
- the half disks 50 and 52 can be loaded into a micro-grinding machine, such as grinding machines available from OptoTech Optical Machinery Inc, East Greenville, Pennsylvania or LOH Optical Machinery, Inc., of Milwaukee/Germantown, Wisconsin, and ground into their desired form as the prisms 30 and 32.
- the result which is a set of the prisms 30 and 32 finished from a plurality of the disks 22, is shown as the final Step G.
- the new method shown in the Steps A - G makes more efficient use of the crystal material of the rod 10 and can be applied to extract similar efficiencies from other cubic crystal bodies and for making other optical elements oriented for propagating light along one of the ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axes.
- the crystal bodies are cut into slabs having top and bottom surfaces from which two end faces of the optical elements are finished along the ⁇ 1 1 1 ⁇ reference planes immediately adjacent to one another.
- the slabs themselves can be cut apart for finishing adjacent side faces of the optical elements.
- Slabs e.g., disks having larger areas relative to the desired size of the finished optical elements can be cut into more than two parts for forming more than two optical elements from each of the slabs.
- the parts are cut into subparts for forming even numbers of optical elements from each of the slabs, each subsequent cut being a complete cut that divides the remainder by half.
- the side faces 40, 42, and 44 of the prisms 30 are oriented during use as shown in FIGS. 3 and 4 so that the side face 40 functions as an entrance surface, the side face 42 functions as an exit surface, and the side face 44 functions as a base.
- Normals 54 and 56 of the entrance and exit surfaces 40 and 42 are inclined to both the directions 60 and 62 of light propagation to and from the prism 30 and the ⁇ 1 1 2> alternative crystal axis along which the light is intended for propagation through the prism 30.
- the inclination of the normal to the entrance surface 40 with respect to the direction 60 of light propagation to the entrance surface 40 through the angle " ⁇ i " avoids unwanted retroreflections of the light from the entrance surface 40.
- the normals 54 and 56 are preferably inclined true length within the ⁇ 1 1 1 ⁇ plane (the plane of FIG. 3) so that the entrance and exit surfaces 40 and 42 remain perpendicular to the ⁇ 1 1 1 ⁇ crystal plane.
- the angles " ⁇ i" of incidence and " ⁇ R " of refraction also remain in the ⁇ 1 1 1 ⁇ crystal plane.
- the effects of the birefringence can be avoided by limiting electric field fluctuations of light propagating along the ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axes to within the ⁇ 1 1 1 ⁇ plane.
- the propagating light is linearly polarized and the direction of polarization is within the ⁇ 1 1 1 ⁇ plane.
- the polarization direction is also preferably within the plane of incidence at which the polarized light strikes the entrance surface 40, and is therefore referenced as "P" polarized light.
- the normal to the entrance surface 40 is inclined to the one ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axis through the angle of refraction " ⁇ R " so that upon refraction through the entrance surface 40, the "P" polarized light propagates along the one ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axis.
- the light emitted by conventional lasers including lasers operating in the deep UV, is not perfectly collimated, and is, therefore, more accurately referred to as "highly" collimated light.
- emission angles of +/- 6 degrees are within the range of normal expectations for the highly collimated light, although higher or lower emission angle ranges are possible depending upon the choice of light source.
- the ⁇ 1 1 2>, ⁇ 1 2 1>, and ⁇ 2 1 1> alternative crystal axes also define directions of propagation through the cubic crystal material that accommodate such variations in ray angle with minimum of polarization conversion of the light propagating through the prisms 30 from linearly polarized light to polarized light in a different form (e.g., elliptical or rotated).
- substantially linearly polarized light incident upon the prisms 30 exits the prisms 30 as substantially the same linearly polarized light despite small variations in ray angle.
- the ⁇ 1 1 2>, ⁇ 1 2 1>, and ⁇ 2 1 1> alternative crystal axes are least sensitive to the birefringence effects of stress.
- the amount of stress-induced polarization conversion associated with propagations along the ⁇ 1 1 2>, ⁇ 1 2 1>, and ⁇ 2 1 1> alternative crystal axes is expected to be roughly comparable or even less than the amount of stress-induced polarization conversion associated with propagations along the ⁇ 1 1 1> axis over a modest range of stress magnitudes (e.g., less than 100 kPa).
- a fixed value of the stress magnitude is considered over a full range of orientations to identify the maximum polarization conversion associated with propagations along the ⁇ 1 1 1> main crystal axis and the ⁇ 1 1 2>, ⁇ 1 2 1>, and ⁇ 2 1 1> alternative crystal axes.
- the invention is particularly applicable for use in line-narrowing modules for laser systems operating at wavelengths around 157 nm or 193 nm.
- Highly polarized light propagates through a series of prisms traveling in one direction through the prisms on a first pass and traveling in nearly the opposite direction through the prisms in a second pass to provide effective feedback for the lasers.
- excimer lasers made by Lambda Physik of G ⁇ ttingen, Germany and Cymer, Inc. of San Diego, California produce linearly polarized light, regarded as "P" polarized within the plane of light ray travel.
- a series of prisms make in accordance with the invention can be used to convey the "P" polarized light within the laser cavity with a minimum of polarization conversion (e.g., "P" polarized converted into “S” polarized light) due to both intrinsic or stress-induced birefringence.
- Performance comparable to propagations along ⁇ 1 1 1> crystal axes can be achieved in the new prism designs by propagating the "P" polarized light along one of the ⁇ 1 1 2>, ⁇ 1 2 1>, or ⁇ 2 1 1> alternative crystal axes, while increasing the number of such prisms that can be harvested from a crystal body.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
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- Optical Elements Other Than Lenses (AREA)
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Abstract
Description
Claims
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007533555A JP2008513847A (en) | 2004-09-22 | 2005-09-16 | Increased yield of cubic optics by crystal orientation |
| DE112005002284T DE112005002284T5 (en) | 2004-09-22 | 2005-09-16 | Increased yield of cubic crystalline optical elements by crystal orientation |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/947,100 | 2004-09-22 | ||
| US10/947,100 US7381339B2 (en) | 2004-09-22 | 2004-09-22 | Increased yield of cubic crystalline optical elements by crystal orientation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2006036602A2 true WO2006036602A2 (en) | 2006-04-06 |
| WO2006036602A3 WO2006036602A3 (en) | 2007-09-20 |
Family
ID=36073655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2005/033223 Ceased WO2006036602A2 (en) | 2004-09-22 | 2005-09-16 | Increased yield of cubic crystalline optical elements by crystal orientation |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US7381339B2 (en) |
| JP (1) | JP2008513847A (en) |
| DE (1) | DE112005002284T5 (en) |
| WO (1) | WO2006036602A2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8224189B1 (en) | 2007-02-02 | 2012-07-17 | Sunlight Photonics Inc. | Retro-directive target for free-space optical communication and method of producing the same |
| CN106249329B (en) * | 2016-08-23 | 2018-10-19 | 苏州瑞蓝环保科技有限公司 | A kind of setting method for detaching the prism of mixed wavelengths laser |
| US10630043B1 (en) * | 2019-05-14 | 2020-04-21 | Ii-Vi Delaware, Inc. | Methods and devices for laser beam parameters sensing and control with fiber-tip integrated systems |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6690514B2 (en) * | 2001-04-27 | 2004-02-10 | Solid Optics, Inc. | Single crystal polarizing prism and method of manufacturing thereof |
-
2004
- 2004-09-22 US US10/947,100 patent/US7381339B2/en active Active
-
2005
- 2005-09-16 JP JP2007533555A patent/JP2008513847A/en not_active Abandoned
- 2005-09-16 WO PCT/US2005/033223 patent/WO2006036602A2/en not_active Ceased
- 2005-09-16 DE DE112005002284T patent/DE112005002284T5/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008513847A (en) | 2008-05-01 |
| US7381339B2 (en) | 2008-06-03 |
| WO2006036602A3 (en) | 2007-09-20 |
| DE112005002284T5 (en) | 2007-09-27 |
| US20060061864A1 (en) | 2006-03-23 |
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