WO2005121220A3 - Preparation of polyphosphonates via transesterification without a catalyst - Google Patents

Preparation of polyphosphonates via transesterification without a catalyst Download PDF

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Publication number
WO2005121220A3
WO2005121220A3 PCT/US2005/019431 US2005019431W WO2005121220A3 WO 2005121220 A3 WO2005121220 A3 WO 2005121220A3 US 2005019431 W US2005019431 W US 2005019431W WO 2005121220 A3 WO2005121220 A3 WO 2005121220A3
Authority
WO
WIPO (PCT)
Prior art keywords
polyphosphonates
catalyst
disclosed
preparation
polymer compositions
Prior art date
Application number
PCT/US2005/019431
Other languages
French (fr)
Other versions
WO2005121220A2 (en
Inventor
Dieter Freitag
Original Assignee
Triton Systems Inc
Dieter Freitag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Triton Systems Inc, Dieter Freitag filed Critical Triton Systems Inc
Publication of WO2005121220A2 publication Critical patent/WO2005121220A2/en
Publication of WO2005121220A3 publication Critical patent/WO2005121220A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/04—Phosphorus linked to oxygen or to oxygen and carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4025—Esters of poly(thio)phosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4084—Esters with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
    • C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Disclosed are embodiments of polyphosphonates produced via a transesterification process that does not required the use of a catalyst, and methods related thereto. Due to the elimination of the catalyst, these polyphosphonates exhibit a unique and advantageous combination of properties, such as fire resistance, improved heat stability, toughness and processing characteristics. Also disclosed are polymer compositions that comprise these polyphosphonates and at least one other polymer, wherein the resulting polymer compositions exhibit flame retardant properties. Further disclosed are articles of manufacture produced from these polymers, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.
PCT/US2005/019431 2004-06-04 2005-06-02 Preparation of polyphosphonates via transesterification without a catalyst WO2005121220A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US57709904P 2004-06-04 2004-06-04
US60/577,099 2004-06-04

Publications (2)

Publication Number Publication Date
WO2005121220A2 WO2005121220A2 (en) 2005-12-22
WO2005121220A3 true WO2005121220A3 (en) 2006-10-26

Family

ID=35503719

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/019431 WO2005121220A2 (en) 2004-06-04 2005-06-02 Preparation of polyphosphonates via transesterification without a catalyst

Country Status (2)

Country Link
US (1) US20060020104A1 (en)
WO (1) WO2005121220A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6861499B2 (en) * 2003-02-24 2005-03-01 Triton Systems, Inc. Branched polyphosphonates that exhibit an advantageous combination of properties, and methods related thereto
US20040167283A1 (en) * 2003-02-24 2004-08-26 Michael Vinciguerra Linear polyphosphonates that exhibit an advantageous combination of properties, and methods related thereto
US7560525B2 (en) * 2004-04-02 2009-07-14 Frx Polymers, Llc Crystalline polyphosphonates and methods related thereto
US7569717B2 (en) * 2005-07-19 2009-08-04 Frx Polymers, Llc Diaryl alkylphosphonates and method for preparing same
US7645850B2 (en) * 2005-08-11 2010-01-12 Frx Polymers, Inc. Poly(block-phosphonato-ester) and poly(block-phosphonato-carbonate) and methods of making same
US7666932B2 (en) * 2005-10-17 2010-02-23 Frx Polymers, Inc. Compositions comprising polyphosphonates and additives that exhibit an advantageous combination of properties, and methods related thereto
EP1940855B1 (en) * 2005-10-18 2015-07-01 FRX Polymers, Inc. Diaryl alkylphosphonates and methods for preparing same
US7838604B2 (en) * 2005-12-01 2010-11-23 Frx Polymers, Inc. Method for the production of block copolycarbonate/phosphonates and compositions therefrom
EP2181141B1 (en) * 2007-07-30 2015-09-02 Frx Polymers, Inc. Insoluble and branched polyphosphonates and methods related thereto
US7928259B2 (en) * 2008-02-12 2011-04-19 Frx Polymers, Inc. Diaryl alkylphosphonates and methods for preparing same
TW201439222A (en) 2013-01-22 2014-10-16 Frx Polymers Inc Phosphorus containing epoxy compounds and compositions therefrom

Citations (2)

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Publication number Priority date Publication date Assignee Title
US4331614A (en) * 1979-06-22 1982-05-25 Bayer Aktiengesellschaft Aromatic polyphosphonates and a process for their production
US6861499B2 (en) * 2003-02-24 2005-03-01 Triton Systems, Inc. Branched polyphosphonates that exhibit an advantageous combination of properties, and methods related thereto

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US2682522A (en) * 1952-09-10 1954-06-29 Eastman Kodak Co Process for preparing polymeric organo-phosphonates
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US4020124A (en) * 1974-02-15 1977-04-26 General Electric Company Blends of a polyphenylene ether resin, alkenyl aromatic resins modified with EPDM rubber and graft polymerized high rubber content polymers
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Also Published As

Publication number Publication date
US20060020104A1 (en) 2006-01-26
WO2005121220A2 (en) 2005-12-22

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