WO2005108336A1 - System and process for synthesis of methanol - Google Patents
System and process for synthesis of methanol Download PDFInfo
- Publication number
- WO2005108336A1 WO2005108336A1 PCT/EP2005/052043 EP2005052043W WO2005108336A1 WO 2005108336 A1 WO2005108336 A1 WO 2005108336A1 EP 2005052043 W EP2005052043 W EP 2005052043W WO 2005108336 A1 WO2005108336 A1 WO 2005108336A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- methanol
- reactor
- syngas
- offgas
- reaction product
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
Definitions
- the methanol forming reaction can be performed at a pressure of between 30 and 150 bar, for example 75 bar and a temperature of between 200 and 320 °C, for example 230 °C.
- the hydrogen recovery in the PSA can be performed at for example 60 bar.
- Fig. 3 shows a schematic process flow chart. A corresponding Table II is also presented, that shows calculated compositions and flow rates of through the lines that are identified in Fig. 3 by letters a to i . The calculation is made for a low quality and low cost natural gas as the source gas, having a particularly high concentration of N 2 . Comparing columns d and e, it can be seen that SN is enhanced from 1.1 to 2.01 by injection of the hydrogen recycle stream i.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2005240368A AU2005240368B2 (en) | 2004-05-07 | 2005-05-04 | System and process for synthesis of methanol |
JP2007512195A JP2007536347A (en) | 2004-05-07 | 2005-05-04 | Methanol synthesis system and method |
EP05743070A EP1742901A1 (en) | 2004-05-07 | 2005-05-04 | System and process for synthesis of methanol |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04101995.1 | 2004-05-07 | ||
EP04101995 | 2004-05-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005108336A1 true WO2005108336A1 (en) | 2005-11-17 |
Family
ID=34929076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/052043 WO2005108336A1 (en) | 2004-05-07 | 2005-05-04 | System and process for synthesis of methanol |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1742901A1 (en) |
JP (1) | JP2007536347A (en) |
CN (1) | CN1950316A (en) |
AU (1) | AU2005240368B2 (en) |
RU (1) | RU2386611C2 (en) |
WO (1) | WO2005108336A1 (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008006787A2 (en) * | 2006-07-11 | 2008-01-17 | Shell Internationale Research Maatschappij B.V. | Process to prepare a synthesis gas |
EP1914219A1 (en) * | 2006-10-20 | 2008-04-23 | BP Chemicals Limited | Process for the conversion of hydrocarbons to alcohols |
WO2009127657A1 (en) * | 2008-04-16 | 2009-10-22 | Methanol Casale S.A. | Process for producing methanol from steam reforming |
CN101993339A (en) * | 2010-11-04 | 2011-03-30 | 四川天一科技股份有限公司 | Cold blowing cooling method for converter gas in production of methyl alcohol by using coke-oven gas and converter gas |
US9556092B2 (en) | 2012-12-22 | 2017-01-31 | Gas Technologies Llc | Method and apparatus for providing oxygenated hydrocarbons |
WO2017178771A1 (en) * | 2016-04-15 | 2017-10-19 | Engie | Device and method for cogeneration of methanol and synthetic methane |
WO2020154284A1 (en) * | 2019-01-21 | 2020-07-30 | Sabic Global Technologies, B.V. | Methanol production process |
EP3725760A1 (en) | 2019-04-18 | 2020-10-21 | thyssenkrupp Industrial Solutions AG | Method and system for synthesising methanol |
EP3744416A1 (en) * | 2019-05-28 | 2020-12-02 | thyssenkrupp Industrial Solutions AG | Method and system for synthesising methanol |
RU2753269C2 (en) * | 2017-02-23 | 2021-08-12 | Касале Са | Method for producing methanol |
RU2782754C1 (en) * | 2019-05-28 | 2022-11-02 | Гэсконтек Гмбх | Method and installation for methanol synthesis |
US12006280B2 (en) | 2019-01-21 | 2024-06-11 | Eni S.P.A. | Methanol production process with higher carbon utilization by CO2 recycle |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7642293B2 (en) * | 2004-07-29 | 2010-01-05 | Gas Technologies Llc | Method and apparatus for producing methanol with hydrocarbon recycling |
CN104128186B (en) * | 2014-08-04 | 2016-06-29 | 太原理工大学 | For being prepared the Catalysts and its preparation method of low-carbon alcohols by synthesis gas |
CN105460891B (en) * | 2014-09-03 | 2017-11-07 | 中国石油天然气股份有限公司 | Recycling method and system of methanol purge gas |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0111376A2 (en) * | 1982-12-14 | 1984-06-20 | Stamicarbon B.V. | Process for the preparation of methanol |
EP0123534A2 (en) * | 1983-04-22 | 1984-10-31 | Foster Wheeler Energy Limited | Process for the production of oxygenated organic compounds such as methanol |
US5310506A (en) * | 1991-09-14 | 1994-05-10 | Metallgesellschaft Aktiengesellschaft | Process of producing a synthesis gas for methanol synthesis |
US5496859A (en) * | 1995-01-28 | 1996-03-05 | Texaco Inc. | Gasification process combined with steam methane reforming to produce syngas suitable for methanol production |
-
2005
- 2005-05-04 EP EP05743070A patent/EP1742901A1/en not_active Withdrawn
- 2005-05-04 RU RU2006143195/04A patent/RU2386611C2/en not_active IP Right Cessation
- 2005-05-04 CN CN 200580014655 patent/CN1950316A/en active Pending
- 2005-05-04 JP JP2007512195A patent/JP2007536347A/en active Pending
- 2005-05-04 AU AU2005240368A patent/AU2005240368B2/en not_active Ceased
- 2005-05-04 WO PCT/EP2005/052043 patent/WO2005108336A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0111376A2 (en) * | 1982-12-14 | 1984-06-20 | Stamicarbon B.V. | Process for the preparation of methanol |
EP0123534A2 (en) * | 1983-04-22 | 1984-10-31 | Foster Wheeler Energy Limited | Process for the production of oxygenated organic compounds such as methanol |
US5310506A (en) * | 1991-09-14 | 1994-05-10 | Metallgesellschaft Aktiengesellschaft | Process of producing a synthesis gas for methanol synthesis |
US5496859A (en) * | 1995-01-28 | 1996-03-05 | Texaco Inc. | Gasification process combined with steam methane reforming to produce syngas suitable for methanol production |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008006787A2 (en) * | 2006-07-11 | 2008-01-17 | Shell Internationale Research Maatschappij B.V. | Process to prepare a synthesis gas |
WO2008006787A3 (en) * | 2006-07-11 | 2008-03-27 | Shell Int Research | Process to prepare a synthesis gas |
US7553405B2 (en) | 2006-07-11 | 2009-06-30 | Shell Oil Company | Process to prepare a synthesis gas |
AU2007274366B2 (en) * | 2006-07-11 | 2010-09-09 | Shell Internationale Research Maatschappij B.V. | Process to prepare a synthesis gas |
EP1914219A1 (en) * | 2006-10-20 | 2008-04-23 | BP Chemicals Limited | Process for the conversion of hydrocarbons to alcohols |
WO2008047125A1 (en) * | 2006-10-20 | 2008-04-24 | Bp Chemicals Limited | Process for the conversion of hydrocarbons to oxygenates |
US8329960B2 (en) | 2006-10-20 | 2012-12-11 | Bp Chemicals Limited | Process for the conversion of hydrocarbons to oxygenates |
WO2009127657A1 (en) * | 2008-04-16 | 2009-10-22 | Methanol Casale S.A. | Process for producing methanol from steam reforming |
EP2116295A1 (en) * | 2008-04-16 | 2009-11-11 | Methanol Casale S.A. | Process for producing methanol from steam reforming |
RU2497583C2 (en) * | 2008-04-16 | 2013-11-10 | Метанол Касале С.А. | Method of methanol production by vapour conversion |
CN101993339A (en) * | 2010-11-04 | 2011-03-30 | 四川天一科技股份有限公司 | Cold blowing cooling method for converter gas in production of methyl alcohol by using coke-oven gas and converter gas |
US9556092B2 (en) | 2012-12-22 | 2017-01-31 | Gas Technologies Llc | Method and apparatus for providing oxygenated hydrocarbons |
WO2017178771A1 (en) * | 2016-04-15 | 2017-10-19 | Engie | Device and method for cogeneration of methanol and synthetic methane |
FR3050123A1 (en) * | 2016-04-15 | 2017-10-20 | Engie | DEVICE AND METHOD FOR CO2 HYDROGENATION TO PRODUCE METHANOL AND DEVICE AND METHOD FOR COGENERATION OF METHANOL AND SYNTHETIC METHANE |
US11746076B2 (en) | 2017-02-23 | 2023-09-05 | Casale Sa | Process for methanol production |
RU2753269C2 (en) * | 2017-02-23 | 2021-08-12 | Касале Са | Method for producing methanol |
CN113574040A (en) * | 2019-01-21 | 2021-10-29 | 埃尼股份公司 | Methanol production method |
WO2020154284A1 (en) * | 2019-01-21 | 2020-07-30 | Sabic Global Technologies, B.V. | Methanol production process |
US12006280B2 (en) | 2019-01-21 | 2024-06-11 | Eni S.P.A. | Methanol production process with higher carbon utilization by CO2 recycle |
CN113574040B (en) * | 2019-01-21 | 2023-12-01 | 埃尼股份公司 | Methanol production method |
WO2020212222A1 (en) | 2019-04-18 | 2020-10-22 | Gascontec Gmbh | Method and system for the synthesis of methanol |
CN114008009A (en) * | 2019-04-18 | 2022-02-01 | 盖斯康泰克技术有限公司 | Method and system for synthesizing methanol |
RU2800952C2 (en) * | 2019-04-18 | 2023-08-01 | Гэсконтек Гмбх | Method and unit for methanol synthesis |
EP3725760A1 (en) | 2019-04-18 | 2020-10-21 | thyssenkrupp Industrial Solutions AG | Method and system for synthesising methanol |
RU2782754C1 (en) * | 2019-05-28 | 2022-11-02 | Гэсконтек Гмбх | Method and installation for methanol synthesis |
WO2020239754A1 (en) * | 2019-05-28 | 2020-12-03 | Gascontec Gmbh | Method and system for the synthesis of methanol |
EP3744416A1 (en) * | 2019-05-28 | 2020-12-02 | thyssenkrupp Industrial Solutions AG | Method and system for synthesising methanol |
Also Published As
Publication number | Publication date |
---|---|
EP1742901A1 (en) | 2007-01-17 |
AU2005240368B2 (en) | 2009-04-02 |
CN1950316A (en) | 2007-04-18 |
RU2386611C2 (en) | 2010-04-20 |
AU2005240368A1 (en) | 2005-11-17 |
JP2007536347A (en) | 2007-12-13 |
RU2006143195A (en) | 2008-06-20 |
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