WO2005102052A1 - Fungizide mischungen - Google Patents
Fungizide mischungen Download PDFInfo
- Publication number
- WO2005102052A1 WO2005102052A1 PCT/EP2005/004002 EP2005004002W WO2005102052A1 WO 2005102052 A1 WO2005102052 A1 WO 2005102052A1 EP 2005004002 W EP2005004002 W EP 2005004002W WO 2005102052 A1 WO2005102052 A1 WO 2005102052A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- compound
- mixtures
- compounds
- formula
- water
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Definitions
- the present invention relates to fungicidal mixtures containing as active components
- the invention relates to a method for controlling harmful fungi with mixtures of the compound I with the compound II and the use of the compound I with the compound II for the preparation of such mixtures and compositions containing these mixtures.
- the mixtures of the compound I and the compound II or the simultaneous joint or separate use of the compound I and the compound II are distinguished by an outstanding activity against a broad spectrum of plant pathogenic fungi, in particular from the class of the Ascomycetes, Deuteromyces ten, Oomycetes and Basidiomycetes. They can be used in crop protection as foliar, pickling and soil fungicides.
- fungi Blumeria graminis (powdery mildew) on cereals, Erysiphe cichoracearum and Sphaerotheca fuliginea on cucurbits, Podosphaera leucotricha on apples, Unin cinula necator on vines, Puccinia species on cereals, Rhizoctonia species Cotton, Rice and Turf, Ustilago A anen on cereals and sugarcane, Venturia inaequalis on apples, Bipolaris and Drechslera species on cereals, rice and turf, Septoria nodourum on wheat, Botrytis cinerea on strawberries, vegetables, ornamental plants and Vines, mycosphaerella plants on bananas, peanuts and cereals, Pseudocercosporella her- potrichoides on wheat and barley, Pyricularia oryzae on rice, Phakopsora species on soya, Phytophthora infest
- the compound I and the compound II can be applied simultaneously together or separately or in succession, the sequence in the case of separate application generally having no effect on the control result.
- the pure active ingredients I and II which can be added as needed further active against harmful fungi or other pests such as insects, spider animals or nematodes, or herbicidal or growth-regulating agents or fertilizers.
- fungicides selected from the following group are suitable as further active ingredients in the above sense:
- Acylalanines such as benalaxyl, metalaxyl, ofurace, oxadixyl, amine derivatives such as aldimorph, dodine, dodemorph, fenpropimorph, fenpropidin, guazatine, iminoctadine, tridemorph,
- Anilinopyrimidines such as pyrimethanil, mepanipyrim or cyprdinil,
- antibiotics such as cycloheximide, griseofulvin, kasugamycin, natamycin, polyoxin or streptomycin
- azoles such as bitertanol, bromoconazole, cyproconazole, difenoconazole, dinitroconazole, enilconazole, epoxiconazole, fenbuconazole, fluquiconazole, flusilazole, flutriafol, hexaconazole, imazalil, ipconazole, metconazole, Myclobutanil, penconazole, propiconazole, prochlorazole, prothioconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimol, triflumizole, triticonazole, dicarboximides such as iprodione, myclozolin, procymidone, vinclozol
- Dithiocarbamates such as Ferbam, Nabam, Maneb, Mancozeb, Metam, Metiram, Propineb, Polycarbamate, Tiram, Ziram, Zineb,
- Heterocyclic compounds such as anilazine, benomyl, boscalid, carbendazim, carboxine, oxycarboxine, cyazofamide, dazomet, dithianone, famoxadone, fenamidone, fenarimol, fuberidazole, flutolanil, furametpyr, isoprothiolane, mepronil, nuarimol, penthiopyrad, picobenzamide, probenazole, proquinazide, Pyrifenox, pyroquilon, quinoxyfen, silthiofam, thiabendazole, thifluzamide, thiophanate-methyl, tiadinil, tricycla lazole, triforine,
- Copper fungicides such as Bordeaux broth, copper oxychloride, copper hydroxide, copper oxide, (basic) copper sulfate, copper oxychloride sulfate,
- Nitrophenyl derivatives such as binapacryl, dinocap, dinobutone, nitrophthalic-isopropyl
- Phenylpyrroles such as fenpiclonil or fludioxonil
- fungicides such as acibenzolar-S-methyl, benthiavalicarb, carpropamide, chlorothalonil, cyflufenamid, cymoxanil, diclomethine, diclocymet, diethofencarb, edi fenphos, ethaboxam, fenhexamide, fentin acetate, fenoxanil, ferimzone, fluaziamine, fosetyl, fosetyl-aluminum, iprovalicarb, hexachlorobenzene, mandipropamide, metrafenone, pencycuron, propamocarb, phosphorous acid, phthalide, toloclofos- methyl, quintozene, zoxamide,
- Strobilurins such as azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, cresoxime-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin or trifloxystrobin,
- Sulfenic acid derivatives such as captafol, captan, dichlofluanid, folpet, tolylfluanid,
- Cinnamic acid amides and analogues such as dimethomorph, flumetover or flumorph.
- another fungicide III or two fungicides III and IV are added to the compounds I and II.
- Mixtures of compounds I and II with a component III are preferred. Particular preference is given to mixtures of the compounds I and II.
- the compound I and the compound II are usually used in a weight ratio of 100: 1 to 1: 100, preferably 20: 1 to 1:20, especially 10: 1 to 1:10 applied.
- components III and, if appropriate, IV are admixed to compound I in a ratio of from 20: 1 to 1:20.
- the application rates of the mixtures according to the invention are from 5 g / ha to 1000 g / ha, preferably from 50 to 900 g / ha, in particular from 50 to 750 g / ha.
- the application rates for the compound I are accordingly generally 1 to 1000 g / ha, preferably 10 to 900 g / ha, in particular 20 to 750 g / ha.
- the application rates for compound II are accordingly generally 1 to 1000 g / ha, preferably 10 to 900 g / ha, in particular 40 to 750 g / ha.
- application rates of mixture of 1 to 1000 g / 100 kg of seed preferably 1 to 750 g / 100 kg, in particular 5 to 500 g / 100 kg, are generally used.
- the method for controlling harmful fungi is carried out by the separate or combined application of the compound I and the compound II or the mixtures of the compound I and the compound II by spraying or dusting the Sa the plants or soils before or after sowing the plants or before or after plant emergence.
- the mixtures according to the invention, or the compounds I and II, can be converted into the customary formulations, e.g. Solutions, emulsions, suspensions, dusts, powders, pastes and granules.
- the application form depends on the respective purpose; It should in any case ensure a fine and uniform distribution of the compound according to the invention.
- the formulations are prepared in a known manner, e.g. by stretching the active ingredient with solvents and / or carriers, if desired using emulsifiers and dispersants.
- Suitable solvents / auxiliaries are essentially: water, aromatic solvents (eg Solvesso products, xylene), paraffins (eg petroleum fractions), alcohols (eg methanol, butanol, pentanol, benzyl alcohol), ketones (eg cyclohexanone, gamma-butyrololactone) , Pyrrolidones (NMP, NOP), acetates (glycol diacetate), glycols, dimethyl fatty acid amides, fatty acids and fatty acid esters.
- aromatic solvents eg Solvesso products, xylene
- paraffins eg petroleum fractions
- alcohols eg methanol, butanol, pentanol, benzyl alcohol
- ketones eg
- solvent mixtures may also be used, carriers such as ground natural minerals (e.g., kaolins, clays, talc, chalk) and ground synthetic minerals (e.g., fumed silica, silicates); Emulsifiers such as nonionic and anionic emulsifiers (e.g., polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignin liquors and methyl cellulose.
- ground natural minerals e.g., kaolins, clays, talc, chalk
- ground synthetic minerals e.g., fumed silica, silicates
- Emulsifiers such as nonionic and anionic emulsifiers (e.g., polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignin liquors and methyl cellulose.
- dispersants such as
- the surface-active substances used are alkali metal, alkaline earth metal, ammonium salts of lignin sulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid, alkylarylsulfonates, alkyl sulfates, alkyl sulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, and condensation products of sulfonated naphthalene and naphthalene derivatives with formaldehyde , Condensation products of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ethers, tributylphenyl
- mineral oil fractions of medium to high boiling point such as kerosine or diesel oil, coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, eg toluene, xy lol, paraffin, tetrahydronaphthalene, alkylated naphthalenes or derivatives thereof, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strongly polar solvents, for example dimethyl sulfoxide, N-methylpyrrolidone or water into consideration.
- mineral oil fractions of medium to high boiling point such as kerosine or diesel oil, coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, eg toluene, xy lol, paraffin, tetrahydronaphthalene, alkylated naphthalenes or derivatives thereof, methanol,
- Powders, dispersants and dusts may be prepared by mixing or co-grinding the active substances with a solid carrier.
- Granules e.g. Coated, impregnated and homogeneous granules can be prepared by binding the active compounds to solid carriers.
- Solid carriers are e.g. Mineral earths, such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulphate, magnesium oxide, ground plastics, fertilizers, e.g. Ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products such as cereal flour, tree bark, wood and nutshell meal, cellulose powder and other solid carriers.
- Mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulphate, magnesium oxide, ground plastics
- the formulations generally contain between 0.01 and 95 wt .-%, preferably between 0.1 and 90 wt .-% of the active ingredients.
- the active ingredients are used in a purity of 90% to 100%, preferably 95% to 100% (according to NMR spectrum).
- formulations are: 1. Products for dilution in water
- DC Dispersible Concentrates
- Emulsifiable Concentrates 15 parts by weight of the active compounds are dissolved in xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5%). Dilution in water results in an emulsion.
- Emulsions EW, EO 40 parts by weight of the active compounds are dissolved in xylene with addition of calcium dodecylbenzene sulfonate and castor oil ethoxylate (5% each). This mixture is introduced by means of an emulsifier (Ultraturax) in water and brought to a homogeneous emulsion. Dilution in water results in an emulsion.
- EW Emulsions
- the active ingredients 50 parts by weight of the active ingredients are finely ground with the addition of dispersing and wetting agents and prepared by means of technical equipment (for example extrusion, spray tower, fluidized bed) as water-dispersible or water-soluble granules. Dilution in water results in a stable dispersion or solution of the active ingredient.
- 75 parts by weight of the active ingredients are ground in a rotor-stator mill with the addition of dispersing and wetting agents and silica gel. Dilution in water results in a stable dispersion or solution of the active ingredient.
- the active compounds can be used as such, in the form of their formulations or the use forms prepared therefrom, for example in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dusts, scattering agents, granules by spraying, atomizing, dusting, scattering or Pouring be applied.
- the forms of application depend entirely on the intended use; In any case, they should ensure the finest possible distribution of the active compounds according to the invention.
- Aqueous application forms can be prepared from emulsion concentrates, pastes or wettable powders (wettable powders, oil dispersions) by adding water.
- the substances as such or dissolved in an oil or solvent, can be homogenized in water by means of wetter, tackifier, dispersant or emulsifier. But it can also be made of effective substance wetting, adhesion, dispersing or emulsifying and possibly solvent or oil concentrates, which are suitable for dilution with water.
- the Wirkstoffkonzenträtionen in the ready-to-use preparations can be varied in larger areas. In general, they are between 0.0001 and 10%, preferably between 0.01 and 1%.
- the active ingredients can also be used with great success in the ultra-low-volume (ULV) process, it being possible to apply formulations containing more than 95% by weight of active ingredient or even the active ingredient without additives.
- UUV ultra-low-volume
- wetting agents To the active ingredients oils of various types, wetting agents, adjuvants, herbicides, fungicides, other pesticides, bactericides, optionally also just before use (tank mix), are added. These agents are usually added to the inventive compositions in a weight ratio of 1:10 to 10: 1.
- the compounds I and II, or the mixtures or the corresponding formulations are applied by mixing the harmful fungi, the plants, seeds, soils, areas, materials or spaces to be kept free of them with a fungicidally effective amount of the mixture or of the compounds I and II in the case of separate application.
- the application can be made before or after the attack by the harmful fungi.
- the active compounds were prepared separately or together as a stock solution with 0.25% by weight of active ingredient in acetone or DMSO. This solution was 1 wt .-% emulsifier Uniperol® EL (wetting agent with emulsifying and dispersing based on ethoxylated Alkylphenols) and diluted with water according to the desired concentration.
- Uniperol® EL wetting agent with emulsifying and dispersing based on ethoxylated Alkylphenols
- the efficiency (W) is calculated according to the formula of Abbot as follows:
- ⁇ corresponds to the fungal infestation of the treated plants in% and ⁇ corresponds to the fungal infestation of the untreated (control) plants in%
- the infestation of the treated plants corresponds to that of the untreated control plants; at an efficiency of 100, the treated plants have no infestation.
- E x + y - xy / 100 E expected efficiency, expressed as% of untreated control, using the mixture of active substances A and B at concentrations a and bx the efficiency expressed as% of untreated control, when using active substance A at the concentration ay the efficiency, expressed as% of untreated control, when using active substance B in concentration b
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Cultivation Of Plants (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Description
Claims
Priority Applications (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2005235415A AU2005235415A1 (en) | 2004-04-21 | 2005-04-15 | Fungicidal mixtures |
BRPI0509547-6A BRPI0509547A (pt) | 2004-04-21 | 2005-04-15 | misturas fungicidas para combater fungos nocivos fitopatogênicos, agente, processo para combater fungos nocivos, semente, e, uso dos compostos |
UAA200611843A UA81089C2 (en) | 2004-04-21 | 2005-04-15 | Fungicidal mixture, agent, method for controlling parasitic fungi, seed and use of compounds |
EP05733632A EP1740049B1 (de) | 2004-04-21 | 2005-04-15 | Fungizide mischungen |
DE502005001581T DE502005001581D1 (de) | 2004-04-21 | 2005-04-15 | Fungizide mischungen |
JP2007508797A JP2007533678A (ja) | 2004-04-21 | 2005-04-15 | 殺菌混合物 |
EA200601838A EA200601838A1 (ru) | 2004-04-21 | 2005-04-15 | Фунгицидные смеси |
DK05733632T DK1740049T3 (da) | 2004-04-21 | 2005-04-15 | Fungicide blandinger |
MXPA06010608A MXPA06010608A (es) | 2004-04-21 | 2005-04-15 | Mezclas fungicidas. |
US11/587,131 US20070259784A1 (en) | 2004-04-21 | 2005-04-15 | Fungicidal Mixtures |
CA002559435A CA2559435A1 (en) | 2004-04-21 | 2005-04-15 | Fungicidal mixtures |
PL05733632T PL1740049T3 (pl) | 2004-04-21 | 2005-04-15 | Mieszaniny grzybobójcze |
NZ550721A NZ550721A (en) | 2004-04-21 | 2005-04-15 | Fungicidal mixtures |
IL178014A IL178014A0 (en) | 2004-04-21 | 2006-09-11 | Fungicidal mixtures |
NO20065041A NO20065041L (no) | 2004-04-21 | 2006-11-02 | Fungicidblandinger |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004019935.3 | 2004-04-21 | ||
DE102004019935 | 2004-04-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005102052A1 true WO2005102052A1 (de) | 2005-11-03 |
Family
ID=34965076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/004002 WO2005102052A1 (de) | 2004-04-21 | 2005-04-15 | Fungizide mischungen |
Country Status (27)
Country | Link |
---|---|
US (1) | US20070259784A1 (de) |
EP (1) | EP1740049B1 (de) |
JP (1) | JP2007533678A (de) |
KR (1) | KR20070004104A (de) |
CN (1) | CN1942098A (de) |
AR (1) | AR048621A1 (de) |
AT (1) | ATE373956T1 (de) |
AU (1) | AU2005235415A1 (de) |
BR (1) | BRPI0509547A (de) |
CA (1) | CA2559435A1 (de) |
CR (1) | CR8633A (de) |
DE (1) | DE502005001581D1 (de) |
DK (1) | DK1740049T3 (de) |
EA (1) | EA200601838A1 (de) |
EC (1) | ECSP066946A (de) |
ES (1) | ES2292129T3 (de) |
IL (1) | IL178014A0 (de) |
MX (1) | MXPA06010608A (de) |
NO (1) | NO20065041L (de) |
NZ (1) | NZ550721A (de) |
PL (1) | PL1740049T3 (de) |
PT (1) | PT1740049E (de) |
SI (1) | SI1740049T1 (de) |
TW (1) | TW200603733A (de) |
UA (1) | UA81089C2 (de) |
WO (1) | WO2005102052A1 (de) |
ZA (1) | ZA200609629B (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2844069A1 (de) * | 2012-05-01 | 2015-03-11 | DSM IP Assets B.V. | Antimykotische zusammensetzungen |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998046607A1 (en) * | 1997-04-14 | 1998-10-22 | American Cyanamid Company | Fungicidal trifluorophenyl-triazolopyrimidines |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3735555A1 (de) * | 1987-03-07 | 1988-09-15 | Bayer Ag | Aminomethylheterocyclen |
US6268371B1 (en) * | 1998-09-10 | 2001-07-31 | American Cyanamid Co. | Fungicidal mixtures |
-
2005
- 2005-04-15 JP JP2007508797A patent/JP2007533678A/ja not_active Withdrawn
- 2005-04-15 MX MXPA06010608A patent/MXPA06010608A/es unknown
- 2005-04-15 AT AT05733632T patent/ATE373956T1/de not_active IP Right Cessation
- 2005-04-15 PT PT05733632T patent/PT1740049E/pt unknown
- 2005-04-15 PL PL05733632T patent/PL1740049T3/pl unknown
- 2005-04-15 NZ NZ550721A patent/NZ550721A/en unknown
- 2005-04-15 AU AU2005235415A patent/AU2005235415A1/en not_active Abandoned
- 2005-04-15 CN CNA200580011669XA patent/CN1942098A/zh active Pending
- 2005-04-15 SI SI200530104T patent/SI1740049T1/sl unknown
- 2005-04-15 ES ES05733632T patent/ES2292129T3/es active Active
- 2005-04-15 BR BRPI0509547-6A patent/BRPI0509547A/pt not_active IP Right Cessation
- 2005-04-15 CA CA002559435A patent/CA2559435A1/en not_active Abandoned
- 2005-04-15 WO PCT/EP2005/004002 patent/WO2005102052A1/de active IP Right Grant
- 2005-04-15 EA EA200601838A patent/EA200601838A1/ru unknown
- 2005-04-15 UA UAA200611843A patent/UA81089C2/uk unknown
- 2005-04-15 US US11/587,131 patent/US20070259784A1/en not_active Abandoned
- 2005-04-15 KR KR1020067024230A patent/KR20070004104A/ko not_active Application Discontinuation
- 2005-04-15 DE DE502005001581T patent/DE502005001581D1/de not_active Expired - Fee Related
- 2005-04-15 DK DK05733632T patent/DK1740049T3/da active
- 2005-04-15 EP EP05733632A patent/EP1740049B1/de active Active
- 2005-04-20 AR ARP050101573A patent/AR048621A1/es unknown
- 2005-04-21 TW TW094112709A patent/TW200603733A/zh unknown
-
2006
- 2006-09-11 IL IL178014A patent/IL178014A0/en unknown
- 2006-09-14 CR CR8633A patent/CR8633A/es not_active Application Discontinuation
- 2006-10-23 EC EC2006006946A patent/ECSP066946A/es unknown
- 2006-11-02 NO NO20065041A patent/NO20065041L/no not_active Application Discontinuation
- 2006-11-20 ZA ZA200609629A patent/ZA200609629B/xx unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998046607A1 (en) * | 1997-04-14 | 1998-10-22 | American Cyanamid Company | Fungicidal trifluorophenyl-triazolopyrimidines |
Also Published As
Publication number | Publication date |
---|---|
ES2292129T3 (es) | 2008-03-01 |
AR048621A1 (es) | 2006-05-10 |
IL178014A0 (en) | 2006-12-31 |
PL1740049T3 (pl) | 2008-02-29 |
JP2007533678A (ja) | 2007-11-22 |
ECSP066946A (es) | 2007-02-28 |
SI1740049T1 (sl) | 2008-02-29 |
KR20070004104A (ko) | 2007-01-05 |
NZ550721A (en) | 2009-05-31 |
CA2559435A1 (en) | 2005-11-03 |
PT1740049E (pt) | 2007-10-29 |
TW200603733A (en) | 2006-02-01 |
UA81089C2 (en) | 2007-11-26 |
NO20065041L (no) | 2006-11-16 |
AU2005235415A1 (en) | 2005-11-03 |
EP1740049A1 (de) | 2007-01-10 |
US20070259784A1 (en) | 2007-11-08 |
CN1942098A (zh) | 2007-04-04 |
CR8633A (es) | 2007-06-08 |
MXPA06010608A (es) | 2006-12-15 |
DE502005001581D1 (de) | 2007-11-08 |
EA200601838A1 (ru) | 2007-04-27 |
EP1740049B1 (de) | 2007-09-26 |
ATE373956T1 (de) | 2007-10-15 |
ZA200609629B (en) | 2008-08-27 |
DK1740049T3 (da) | 2007-12-27 |
BRPI0509547A (pt) | 2007-09-18 |
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