WO2005087657A8 - Reactor and method of chlorine dioxide production - Google Patents

Reactor and method of chlorine dioxide production

Info

Publication number
WO2005087657A8
WO2005087657A8 PCT/US2003/014161 US0314161W WO2005087657A8 WO 2005087657 A8 WO2005087657 A8 WO 2005087657A8 US 0314161 W US0314161 W US 0314161W WO 2005087657 A8 WO2005087657 A8 WO 2005087657A8
Authority
WO
WIPO (PCT)
Prior art keywords
reactor
chlorine dioxide
disclosed
bleaching
disinfection
Prior art date
Application number
PCT/US2003/014161
Other languages
French (fr)
Other versions
WO2005087657A9 (en
WO2005087657A1 (en
Inventor
Wilfried J Schmitz
David Francis
Original Assignee
Wilfried J Schmitz
David Francis
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wilfried J Schmitz, David Francis filed Critical Wilfried J Schmitz
Priority to PCT/US2003/014161 priority Critical patent/WO2005087657A1/en
Priority to CA002539984A priority patent/CA2539984A1/en
Priority to MXPA05012626A priority patent/MXPA05012626A/en
Priority to EP03738905.3A priority patent/EP2234918A4/en
Priority to AU2003245268A priority patent/AU2003245268A1/en
Publication of WO2005087657A1 publication Critical patent/WO2005087657A1/en
Publication of WO2005087657A9 publication Critical patent/WO2005087657A9/en
Publication of WO2005087657A8 publication Critical patent/WO2005087657A8/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/20Gaseous substances, e.g. vapours
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B11/00Oxides or oxyacids of halogens; Salts thereof
    • C01B11/02Oxides of chlorine
    • C01B11/022Chlorine dioxide (ClO2)
    • C01B11/023Preparation from chlorites or chlorates
    • C01B11/024Preparation from chlorites or chlorates from chlorites
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/76Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • C02F1/763Devices for the addition of such compounds in gaseous form
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/001Upstream control, i.e. monitoring for predictive control
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/20Total organic carbon [TOC]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/29Chlorine compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

Abstract

A novel chlorine dioxide production apparatus, or reactor, is disclosed. The reactor receives reactants from two or more feed pipes under pressure, and the reactants react in a reaction chamber that operates under elevated pressure and within a specified temperature range. A gaseous product, such as chlorine dioxide, is generated and is released directly into a liquid stream for bleaching, disinfection, and other purposes. Also disclosed is a novel system for production of quantities of chlorine compounds from commercial grades of starting materials, and methods of using the reactor in situ for bleaching, and for disinfection, decontamination, and sterilization of flows of water or other liquids. An automated system for multiple points of addition of chlorine dioxide to a flow to be treated is also disclosed.
PCT/US2003/014161 2003-05-23 2003-05-23 Reactor and method of chlorine dioxide production WO2005087657A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
PCT/US2003/014161 WO2005087657A1 (en) 2003-05-23 2003-05-23 Reactor and method of chlorine dioxide production
CA002539984A CA2539984A1 (en) 2003-05-23 2003-05-23 Reactor and method of chlorine dioxide production
MXPA05012626A MXPA05012626A (en) 2003-05-23 2003-05-23 Reactor and method of chlorine dioxide production.
EP03738905.3A EP2234918A4 (en) 2003-05-23 2003-05-23 Reactor and method of chlorine dioxide production
AU2003245268A AU2003245268A1 (en) 2003-05-23 2003-05-23 Reactor and method of chlorine dioxide production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2003/014161 WO2005087657A1 (en) 2003-05-23 2003-05-23 Reactor and method of chlorine dioxide production

Publications (3)

Publication Number Publication Date
WO2005087657A1 WO2005087657A1 (en) 2005-09-22
WO2005087657A9 WO2005087657A9 (en) 2005-10-27
WO2005087657A8 true WO2005087657A8 (en) 2005-12-15

Family

ID=34975477

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/014161 WO2005087657A1 (en) 2003-05-23 2003-05-23 Reactor and method of chlorine dioxide production

Country Status (5)

Country Link
EP (1) EP2234918A4 (en)
AU (1) AU2003245268A1 (en)
CA (1) CA2539984A1 (en)
MX (1) MXPA05012626A (en)
WO (1) WO2005087657A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8802139B2 (en) 2003-06-26 2014-08-12 Intellipharmaceutics Corp. Proton pump-inhibitor-containing capsules which comprise subunits differently structured for a delayed release of the active ingredient
US20080292727A1 (en) * 2005-08-09 2008-11-27 Westerman Wilferd J Technique for treatment and prevention of fungal diseases in field-grown grains and legumes by application of acid-activated sodium chlorite solution
WO2009077213A1 (en) * 2007-12-19 2009-06-25 Infracor Gmbh Method for the treatment of water with chorine dioxide
DE102008055016A1 (en) 2008-12-19 2010-07-01 Infracor Gmbh Process for treating water and aqueous systems in pipelines with chlorine dioxide
WO2011086579A1 (en) * 2010-01-18 2011-07-21 Prophylaxis Process for producing stable and pure liquid form of chlorine dioxide
DE102010055982A1 (en) 2010-12-23 2012-06-28 a.p.f.Aqua System AG Process for the preparation of an aqueous chlorine dioxide solution
MX2019010144A (en) 2017-02-27 2019-10-02 Ecolab Usa Inc Method for onsite production of chlorine dioxide.
PL3601157T3 (en) 2017-03-24 2021-11-02 Ecolab USA, Inc. Low risk chlorine dioxide onsite generation system
MX2020001822A (en) 2017-08-17 2020-03-20 Ecolab Usa Inc Low risk chlorine dioxide onsite generation system.

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3816077A (en) * 1971-05-21 1974-06-11 Hooker Chemical Corp Chlorine dioxide generating system
US4251503A (en) * 1978-09-19 1981-02-17 Erco Industries Limited Efficiency control system for chlorine dioxide plants
US4234446A (en) * 1979-10-09 1980-11-18 Kenneth T. Place Method and apparatus for producing chlorine dioxide
FI840236A (en) * 1983-01-26 1984-07-27 Calgon Corp KLORDIOXIDGENERATOR OCH FOERFARANDE.
US4659459A (en) * 1985-07-18 1987-04-21 Betz Laboratories, Inc. Automated systems for introducing chemicals into water or other liquid treatment systems
US5110580A (en) * 1989-09-14 1992-05-05 Iolab Corporation Method and apparatus for chlorine dioxide manufacture
US5091107A (en) * 1989-10-20 1992-02-25 The Drackett Company Chlorine dioxide generating device
US5324497A (en) * 1992-02-26 1994-06-28 Westerlund G Oscar Integrated procedure for high yield production of chlorine dioxide and apparatus used therefor
US5487881A (en) * 1993-02-26 1996-01-30 Eka Nobel Inc. Process of producing chlorine dioxide
US5458858A (en) * 1994-02-08 1995-10-17 Vulcan Chemicals Integrated procedure for high yield production of chlorine dioxide
US5855861A (en) * 1996-02-23 1999-01-05 Water Technologies Limited Method and apparatus for making aqueous chlorine dioxide
US6235240B1 (en) * 1996-12-12 2001-05-22 Johnson & Johnson Gas recovery system
WO2002044089A2 (en) * 2000-11-28 2002-06-06 Ecochlor, Inc. Methods, apparatus, and compositions for controlling organisms in ballast water

Also Published As

Publication number Publication date
EP2234918A1 (en) 2010-10-06
EP2234918A4 (en) 2015-02-25
WO2005087657A9 (en) 2005-10-27
AU2003245268A1 (en) 2005-09-29
CA2539984A1 (en) 2005-09-22
MXPA05012626A (en) 2006-08-23
WO2005087657A1 (en) 2005-09-22

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