WO2005049301A3 - Pultrusion systems and process - Google Patents

Pultrusion systems and process Download PDF

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Publication number
WO2005049301A3
WO2005049301A3 PCT/US2004/038118 US2004038118W WO2005049301A3 WO 2005049301 A3 WO2005049301 A3 WO 2005049301A3 US 2004038118 W US2004038118 W US 2004038118W WO 2005049301 A3 WO2005049301 A3 WO 2005049301A3
Authority
WO
WIPO (PCT)
Prior art keywords
polyisocyanate
systems
composites
pultrusion
reaction systems
Prior art date
Application number
PCT/US2004/038118
Other languages
French (fr)
Other versions
WO2005049301A2 (en
Inventor
Michael Connolly
Original Assignee
Huntsman Int Llc
Michael Connolly
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Int Llc, Michael Connolly filed Critical Huntsman Int Llc
Priority to EP04801064A priority Critical patent/EP1687128A2/en
Priority to AU2004290683A priority patent/AU2004290683B2/en
Priority to CA002544326A priority patent/CA2544326A1/en
Publication of WO2005049301A2 publication Critical patent/WO2005049301A2/en
Priority to US11/392,345 priority patent/US20060173128A1/en
Priority to NO20062257A priority patent/NO20062257L/en
Publication of WO2005049301A3 publication Critical patent/WO2005049301A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/088—Removal of water or carbon dioxide from the reaction mixture or reaction components
    • C08G18/0885—Removal of water or carbon dioxide from the reaction mixture or reaction components using additives, e.g. absorbing agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/246—Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52—Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/227—Catalysts containing metal compounds of antimony, bismuth or arsenic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2125/00—Compositions for processes using internal mould release agents

Abstract

Polyisocyanate-based reaction systems, a pultrusion process employing those systems to produce reinforced matrix composites, and to composites produced thereby. The polyisocyanate-based systems are mixing activated reaction systems that include a polyol composition, a catalyst composition which comprises a combination of at least two different metals in effective amounts, an optional chain extender or crosslinker, and a polyisocyanate. The polyisocyanate-based systems facilitate the practical use of higher line speeds in the manufacture of fiber reinforced thermoset composites via reactive pultrusion.
PCT/US2004/038118 2003-11-17 2004-11-15 Pultrusion systems and process WO2005049301A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP04801064A EP1687128A2 (en) 2003-11-17 2004-11-15 Pultrusion systems and process
AU2004290683A AU2004290683B2 (en) 2003-11-17 2004-11-15 Pultrusion systems and process
CA002544326A CA2544326A1 (en) 2003-11-17 2004-11-15 Pultrusion systems and process
US11/392,345 US20060173128A1 (en) 2004-11-15 2006-03-29 Pultrusion systems and process
NO20062257A NO20062257L (en) 2003-11-17 2006-05-19 Profile drawing systems and methods

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US52076503P 2003-11-17 2003-11-17
US60/520,765 2003-11-17
US56029504P 2004-04-07 2004-04-07
US60/560,295 2004-04-07

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/392,345 Continuation US20060173128A1 (en) 2004-11-15 2006-03-29 Pultrusion systems and process

Publications (2)

Publication Number Publication Date
WO2005049301A2 WO2005049301A2 (en) 2005-06-02
WO2005049301A3 true WO2005049301A3 (en) 2008-06-05

Family

ID=34623147

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/038118 WO2005049301A2 (en) 2003-11-17 2004-11-15 Pultrusion systems and process

Country Status (5)

Country Link
EP (1) EP1687128A2 (en)
AU (1) AU2004290683B2 (en)
CA (1) CA2544326A1 (en)
NO (1) NO20062257L (en)
WO (1) WO2005049301A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101313000A (en) * 2005-11-23 2008-11-26 米尔加德制造有限公司 Pultruded component

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8101107B2 (en) * 2005-11-23 2012-01-24 Milgard Manufacturing Incorporated Method for producing pultruded components
US8597016B2 (en) 2005-11-23 2013-12-03 Milgard Manufacturing Incorporated System for producing pultruded components
US7875675B2 (en) * 2005-11-23 2011-01-25 Milgard Manufacturing Incorporated Resin for composite structures
ITTV20090029A1 (en) * 2009-03-04 2010-09-05 Damiano Rampin COMPOSITE CARBON FIBER MATERIAL.
DE102009001806A1 (en) 2009-03-24 2010-09-30 Evonik Degussa Gmbh Prepregs and molded articles produced therefrom at low temperature
DE102009001793A1 (en) 2009-03-24 2010-10-07 Evonik Degussa Gmbh Prepregs and moldings produced therefrom
EP2507041B1 (en) 2009-12-01 2014-02-26 Basf Se Pultrusion resin system based on polyurethane
DE102010029355A1 (en) 2010-05-27 2011-12-01 Evonik Degussa Gmbh Process for the preparation of storage-stable polyurethane prepregs and moldings produced therefrom
DE102010041247A1 (en) 2010-09-23 2012-03-29 Evonik Degussa Gmbh Process for the preparation of storage-stable polyurethane prepregs and molded articles made therefrom of polyurethane composition in solution
DE102011006163A1 (en) 2011-03-25 2012-09-27 Evonik Degussa Gmbh Storage-stable polyurethane prepregs and molded articles of polyurethane composition made therefrom with liquid resin components
US11142616B2 (en) 2016-04-21 2021-10-12 Basf Se Method for producing pultruded products on the basis of polyurethane
EP3330311B1 (en) 2016-12-02 2021-05-05 Evonik Operations GmbH Storage stable 1k-polyurethane-prepregs and moulded article made from same on the basis of a polyurethane composition
EP3592793A1 (en) 2017-03-09 2020-01-15 Basf Se Polyurethane formulations for the production of composite elements
EP3747923A1 (en) * 2019-06-06 2020-12-09 Covestro Deutschland AG Method of storing an isocyanate-reactive component
WO2020212239A1 (en) * 2019-04-15 2020-10-22 Covestro Intellectual Property Gmbh & Co. Kg Method of storing an isocyanate-reactive component
WO2021021859A1 (en) * 2019-08-01 2021-02-04 Dow Global Technologies Llc Polyurethane-based composition

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5374486A (en) * 1993-08-24 1994-12-20 Miles Inc. Storage stable isocyanate-reactive compositions for use in flame-retardant systems
WO2000029459A1 (en) * 1998-11-16 2000-05-25 Huntsman International Llc Polyisocyanurate compositions and composites

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5374486A (en) * 1993-08-24 1994-12-20 Miles Inc. Storage stable isocyanate-reactive compositions for use in flame-retardant systems
WO2000029459A1 (en) * 1998-11-16 2000-05-25 Huntsman International Llc Polyisocyanurate compositions and composites

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101313000A (en) * 2005-11-23 2008-11-26 米尔加德制造有限公司 Pultruded component
CN101313000B (en) * 2005-11-23 2014-08-27 米尔加德制造有限公司 Pultruded component

Also Published As

Publication number Publication date
CA2544326A1 (en) 2005-06-02
WO2005049301A2 (en) 2005-06-02
AU2004290683A1 (en) 2005-06-02
NO20062257L (en) 2006-05-19
EP1687128A2 (en) 2006-08-09
AU2004290683B2 (en) 2009-07-09

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