WO2005023937A1 - Electrically conducting polymer and production method and use thereof - Google Patents
Electrically conducting polymer and production method and use thereof Download PDFInfo
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- WO2005023937A1 WO2005023937A1 PCT/JP2004/013011 JP2004013011W WO2005023937A1 WO 2005023937 A1 WO2005023937 A1 WO 2005023937A1 JP 2004013011 W JP2004013011 W JP 2004013011W WO 2005023937 A1 WO2005023937 A1 WO 2005023937A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/201—Pre-melted polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/12—Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/016—Additives defined by their aspect ratio
Definitions
- the present invention relates to a production method of an electrically conductive polymer using vapor grown carbon fiber as a conductive filler, more specifically to a production method of an electrically conductive polymer having vapor grown carbon fiber compounded therein in a smaller amount but exhibiting an electric conductivity which is as high as or higher than conventional electrically conductive polymers. Also, the present invention relates to an electrically conductive polymer produced by the method excellent in mechanical strength and conductivity, and to use of the polymer.
- thermoplastic resin which per se is electrically insulative
- a conductive filler is a long-known technique for imparting characteristics such as conductivity and antistatic property to the resin, and therefore, a variety of conductive fillers are employed for this purpose.
- a conductive substance is incorporated into resin or rubber which is generally an insulator, for the purpose of imparting conductivity, a phenomenon is observed that the conductivity, which only gradually increases as the filling amount of the conductive substance increases, drastically increases at the point when the filling amount reaches a critical amount and then again gradually increases, so-called "percolation", a characteristic transition from an insulator to a conductor.
- threshold value The critical amount is called “percolation threshold value” (hereinafter referred to simply as “threshold value”).
- the threshold value is known to virtually depend on the type of the resin serving as a matrix and the type of the conductor.
- conductive fillers include carbonaceous materials having graphite structure such as carbon black, graphite, vapor grown carbon fiber (hereinafter abbreviated as "CF"), and carbon fiber; metallic materials such as metallic fiber, metallic powder, and metal foil; metal oxides; and metal-coated inorganic fillers.
- a conductive resin composition a polymer alloy predominantly containing polycarbonate resin (blend of polycarbonate resin with ABS resin) or a polymer alloy predominantly containing polyphenylene ether resin (blend of polyphenylene ether resin with polystyrene resin) , into which a conductive filler such as carbon black is incorporated.
- a conductive filler such as carbon black
- electrostatic coating is applied where a coating having an opposite charge added thereto is sprayed to a conductivity-imparted resin molded product while electrifying the molded product,
- adhesion of the coating onto the surface of molded products is enhanced on the basis of attractive force between the charge on the surface and the opposite charge in the coating.
- Many exterior panels and parts of automobiles are formed of a polycarbonate resin-polyester resin blend or a polyphenylene ether-polyamide resin blend. When a conductive filler is incorporated into these molding resin materials for imparting conductivity, mechanical strength and fluidity thereof problematically decrease.
- An object of the present invention is to provide a production method for a conductive polymer which attains conductivity equal to or higher than that of a conventional conductive polymer, through employment of vapor grown carbon fiber as a conductive filler and incorporation of the conductive filler in an amount smaller than a conventionally employed amount so that mechanical strength may be maintained and the viscosity at the time of kneading may be prevented from increasing, a conductive polymer obtained by the method and uses of the polymer.
- the present inventors have found out that, in order to obtain electric conductivity which is as high as or higher than that of conventional polymer with a compounding amount of vapor grown carbon fiber smaller than in conventional methods, it is important to blend a polymer with carbon fiber by using a low blending energy under a condition that the polymer exhibits a melt viscosity under a given value, and have completed the present invention based on this finding. Accordingly, the present invention provides a conductive polymer, and a method for producing the polymer.
- a method for producing a conductive polymer comprising a step of blending a polymer in a state of a melt viscosity of 600 Pa-s or less at a shear rate of 100 s _1 with a vapor grown carbon fiber in an amount of 1 to 15 mass%, at a mixing energy of 1,000 mJ/m 3 or less.
- thermosetting polymer is selected from the group consisting of polyether, polyester, polyimide, polysulfone, epoxy resin, unsaturated polyester resin, phenol resin, urethane resin, ureic resin and melamine resin.
- thermoplastic polymer is selected from the group consisting of polyamide, polyester, liquid crystal polymer, polyethylene, polypropylene, phenylene sulfide and polystyrene.
- a method for producing a conductive polymer comprising a step of blending a polymer in a state of a melt viscosity of
- the vapor grown carbon fiber employed in the present invention may be produced through thermal decomposition of an organic compound in the presence of an organic transition metal compound.
- organic compound which can be employed as a raw material for producing vapor grown carbon fiber include, in the gas form, toluene, benzene, naphthalene, ethylene, acetylene, ethane, natural gas, carbon monoxide, and mixtures thereof. Of these, aromatic hydrocarbons such as toluene and benzene are preferred.
- the organic transition metal compound employed in the present invention contains a transition metal which serves as a catalyst during thermal decomposition of an organic compound.
- the transition metal contained in the organic transition metal compound examples include metal elements of Groups 4 to 10 in the periodic table. Particularly preferred are compounds such as ferrocene or nickelocene.
- the vapor grown carbon fiber is produced by mixing the aforementioned organic compound and the aforementioned organic transition metal compound with a reducing gas such as hydrogen and feeding the mixture into a reactor furnace which is heated at 800 to 1,300°C, thereby causing thermal decomposition.
- the thus-produced vapor grown carbon fiber may be hollow along the fiber axis, or the fiber may be branched.
- the vapor grown carbon fiber is preferably baked through heat treatment in an inert atmosphere at 900 to 1,300°C, thereby removing an organic substance such as tar which has adhered onto the fiber during a production step.
- the vapor grown carbon fiber is preferably further heat-treated in an inert atmosphere at 2,000 to 3,500°C, thereby growing graphite crystals contained in the vapor grown carbon fiber.
- the fiber may be pressed and molded into a solid compact (e.g., a columnar compact).
- the furnace for heat treatment of the compact No particular limitation is imposed on the furnace for heat treatment of the compact, and any furnace such as a typical Acheson-type furnace, a resistance furnace, or a high- frequency furnace may be employed, so long as the furnace can maintain a target temperature of 2,000°C or higher, preferably 2,300°C or higher.
- the compact may be heated through direct passage of electricity. After completion of heating, the compact is lightly crushed or pulverized, to thereby provide finely divided carbon fiber products (outer fiber diameter: 80 to 500 nm, aspect ratio: 40 to 1,000: and BET specific surface area: 4 to 30 m 2 /g) .
- the atmosphere where the aforementioned heat treatment is performed at 2,000°C or higher is a non-oxidizing atmosphere, preferably a rare gas atmosphere containing one or more species selected from among argon, helium, neon, etc.
- the time for heat treatment is preferably as short as possible, from the viewpoint of productivity.
- the carbon fibers are heated for a long period of time, the fiber is sintered to be solidified, thereby lowering production yield.
- the compact may be maintained at the temperature for one hour or shorter in order to fully attain the object. It is preferable that the thus-produced carbon fiber be subjected to surface treatment to thereby reduce the surface energy.
- the surface energy of the vapor grown carbon fiber is preferably 115 mJ/m 2 or less.
- Use of vapor grown carbon fiber with the surface energy exceeding 115 mJ/m 2 can neither allow reduction in the addition amount of the vapor grown carbon fiber nor achieve improvement of fluidity.
- the surface energy of the vapor grown carbon fiber is preferably 20 to 115 mJ/m 2 , more preferably 30 to 110 mJ/m 2 , still more preferably 40 to 100 mJ/m 2 .
- Measurement of the surface energy is conducted using reverse phase chromatography.
- the measurement method is specifically described in Nippon Gomu Kyokaishi Vol.67, No.11, pages 752-759 (1994) published by THE SOCIETY OF RUBBER INDUSTRY, JAPAN.
- treatment methods for reducing the surface energy of the vapor grown carbon fiber may be classified into dry method (e.g., discharge treatment or actinic ray treatment) or wet method (e.g., chemical treatment, polymer-coating, or grafting in the presence of a catalyst) .
- dry method is preferred, from the viewpoint of simplicity, post treatment, productivity, environmental problems, etc.
- Specific examples of the surface treatment method for reducing the surface energy include direct fluorination, fluorination through chemical vapor deposition (CVD) (plasma, photo-, or laser) , boron addition treatment, and silylation.
- CVD chemical vapor deposition
- Fluorine is an atom characterized by its remarkably strong electro-negativity and its size which is the second smallest to hydrogen and its remarkably high reactivity.
- carbon fiber can be directly fluorinated by use of fluorine gas.
- fluorine gas is generally diluted with an inert gas such as nitrogen or helium to a concentration of about 0.1 to 5%. Appropriate temperature control is also critical, and reaction is generally performed at room temperature or lower.
- CVD plasma, photo, or laser
- CVD chemical vapor deposition
- a substance present in a gas phase is reacted to deposit as a solid substance.
- fluorination through a widely used plasma CVD technique will be described.
- the plasma apparatus which can be employed include DC plasma, low-frequency plasma, high-frequency plasma, pulse wave plasma, tri-electrode plasma, microwave plasma, downstream plasma, and columnar plasma apparatuses.
- an atmospheric plasma apparatus which has been recently developed and attracting attention for its easiness of operation, is a useful apparatus.
- Surface treatment by fluorination by means of a plasma apparatus can be attained by exposing VGCF to a plasma inert gas atmosphere and treating the surface with any of the following treatment gases.
- the treatment gas employable for fluorination in the CVD technique include hexafluoroacetone, C 2 F 6 , C 2 F 4 , SF 6 , CF 4 , CF 2 C1 2 , CF 3 H, NF 3 , and fluorine-containing monomers having an F/C ratio of 1.5 or higher.
- an excimer beam or laser treatment may also be employed.
- Boron addition treatment accelerates crystallization of carbon fiber to reduce the surface energy of the carbon fiber, and to elevate conductivity of the carbon fiber.
- the treatment may be performed by a method where boric compound such as boron carbide (B 4 C) , boron oxide (B 2 0 3 ) , boron in elemental state, boric acid (H 3 B0 3 ) or boric acid salt is mixed in the carbon fiber at the time of heat treatment of 2,000°C to 3,500°C under an inert atmosphere of preferably one or more rare gases of argon, helium and neon.
- the boron content added into the carbon fiber which depends on chemical properties and physical properties of the boric compound, is not limited.
- the content is within a range of 0.05 to 10 mass%, preferably 0.1 to 5 mass% in the amount of the carbon fiber after pulverization.
- the heat treatment is performed in the presence of a boron compound, the crystallinity of carbon in the carbon fiber increases, thereby elevating conductivity.
- the boron content in the crystals of carbon fiber or on the crystal surface is preferably 0.01 to 5 mass%.
- the boron content is more preferably 0.1 mass% or more.
- the amount of boron which substitutes carbon atoms forming a graphene sheet (carbon hexagonal network plane) is approximately 3 mass%.
- the excess boron remains in the form of boron carbide or boron oxide, which may lower conductivity and is not preferred.
- vapor grown carbon fiber may be oxidized, thereby introducing a phenolic hydroxyl group, a carboxyl group, a quinone group or a lactone group on the surface of the carbon fiber.
- the vapor grown carbon fiber may be surface-treated with, for example, a coupling agent (titanate- base, aluminum-base, or phosphate ester-base) .
- the vapor grown carbon fiber employed in the present invention has an outer fiber diameter of 80 to 500 nm, preferably 90 to 250 nm, more preferably 100 to 200 nm.
- the vapor grown carbon fiber has an aspect ratio of 40 to 1,000, preferably 50 to 800, more preferably 60 to 500, and particularly preferably 60 to 200.
- aspect ratio i.e., fiber length
- fiber filaments are entangled together, and the thus-formed mass is difficult to be disentangled, resulting in insufficient dispersion
- aspect ratio is less than 40
- a large amount of filler must be incorporated into a resin so as to form a conductive network structure, leading to remarkable decrease in fluidity and tensile strength of the resin, and both cases are not preferred.
- the vapor grown carbon fiber has a BET specific surface area of 4 to 30 m 2 /g, preferably 8 to 25 m 2 /g, more preferably 10 to 20 m 2 /g.
- the interplanar spacing doo 2? as obtained through an X-ray diffraction method is 0.345 nm or less, preferably 0.343 nm or less, more preferably 0.340 nm or less.
- the ratio (Id/Ig) is 0.1 to 2, preferably 0.15 to 1.5, more preferably 0.2 to 1, wherein Id represents a peak height of a band ranging from 1,341 to 1,349 cm -1 and Ig represents a peak height of a band ranging from 1,570 to 1,578 cm -1 , as observed in a Raman scattering spectrum.
- crystallinity of vapor grown carbon fiber is preferably high for both the fiber radius direction and the axial direction.
- thermosetting resins used in the present invention include polyether, polyester, polyimide, polysulfone, epoxy resin, unsaturated polyester resin, phenol resin, urethane resin, ureic resin and melamine resin.
- thermoplastic resins used in the present invention include include aliphatic and alicyclic polyolefins such as polyethylene, polypropylene, polybutene, and polymethylpentene; aromatic polycarbonates; polybutylene terephthalate; polyethylene terephthalate; polyphenylene sulfide; polyamides; polyether-imides; polysulfones; polyether-sulfones; polyether- ether-ketones; acrylic resins; styrene resins; modified polyphenylene ethers; and non-olefinic polyethylene resins such as liquid crystal polyesters.
- aliphatic and alicyclic polyolefins such as polyethylene, polypropylene, polybutene, and polymethylpentene
- aromatic polycarbonates polybutylene terephthalate; polyethylene terephthalate
- polyphenylene sulfide polyamides; polyether-imides; polysulfones; polyether-sulfones
- thermosetting resin is preferred, from the viewpoint of kneadability at low viscosity.
- thermoplastic resins resins having a low melt viscosity, such as polyamides, polyesters, liquid crystal polymers, polyethylene, polypropylene, and polystyrene, are preferred.
- vapor grown carbon fiber is remarkably stable to temperature upon kneading and may be kneaded at high temperature.
- the resin mixture can be kneaded at an elevated temperature so as to reduce viscosity of the resin, so long as the resin does not undergo deterioration, decomposition, or any adverse change in quality.
- Conductive polymers may be produced through a method including kneading components by means of a customary apparatus such as an extruder or a kneader.
- a customary apparatus such as an extruder or a kneader.
- the method for molding thermoplastic resin include press molding, extrusion, vacuum molding, blow molding, and injection molding.
- the method for molding thermosetting resin include transfer molding.
- the energy applied to mixing (kneading) of the polymer and the vapor grown carbon fiber is 1,000 mJ/m 3 or less, so as to prevent cutting and localized dispersion of the vapor grown carbon fiber, preferably 50 to 1,000 mJ/m 3 , more preferably 50 to 800 mJ/m 3 , still more preferably 50 to 500 mJ/m 3 .
- the mixing energy is determined predominantly from the following three factors: viscosity of a composition containing a polymer and vapor grown carbon fiber at a given kneading temperature; a rotation rate of a kneader; and a kneading time.
- kneading is preferably performed at low viscosity and low rotation rate for a short period of time.
- mixing is performed at 50 mJ/m 3 or less, variation (lack of uniformity) in concentration of vapor grown carbon fiber contained in the matrix cannot be eliminated, thereby deteriorating reliability in product characteristics, which is nor preferred.
- the mixing energy is 1,000 mJ/m 3 or higher, diffusion, cutting, and localized dispersion of the vapor grown carbon fiber occur, resulting in failure to attain desired characteristics .
- the matrix polymer is a thermosetting polymer, particularly where the polymer in a state of a melt viscosity of 200 Pa-s or less at a shear rate of 100 s _1 is mixed, it is preferable that the mixing energy be 400 mJ/m 3 or less. In a case where the matrix polymer is a thermoplastic polymer, particularly where the polymer in a state of a melt viscosity of 200 to 600 Pa-s at a shear rate of 100 s "1 is mixed, it is preferable that the mixing energy be 200 to 1,000 mJ/m 3 .
- vapor grown carbon fiber is incorporated in an amount of 1 to 15 mass%, preferably 5 to 10 mass%, so as to attain a volume resistivity of 10 to 10 s ⁇ -cm, preferably IO 2 to 10 5 ⁇ -cm.
- the conductivity of the resultant plastic composition is insufficient, whereas when the content is in excess of 15 mass%, conductivity may be satisfactory, but problems such as inevitable increase in cost, decrease in plastic characteristics, and inhibition of flow of resin during extrusion or injection molding arise.
- Outer fiber diameter (outer diameter) of the vapor grown carbon fiber was derived by observing the fiber under a scanning electron microscope (x20,000) as 30 visible images, measuring the outer fiber diameters of 300 fiber filaments by means of an image analyzer (LUZEX-AP, product of Nireco) , and averaging the values.
- ii) Aspect ratio The aspect ratio was calculated by mean fiber length /mean fiber diameter of the vapor grown carbon fiber. The mean fiber length was derived by observing the fiber under a scanning electron microscope (x2,000) as 30 visible images and measuring the fiber diameters of 300 fiber filaments by means of an image analyzer.
- BET specific surface area BET specific surface area was determined through a nitrogen gas ad-sorption method (by means of NOVA 1000, product of Yuasa Ionics Inc.).
- d 002 Value determined through X-ray diffraction method doo 2 Values were determined through powder X-ray diffraction (by means of Rigaku Geigerflex) while Si was used as an internal standard.
- Ratio (Id/Ig) determined from a Raman scattering spectrum The ratio (Id/Ig) , wherein Id represents a peak height of a band ranging from 1,341 to 1,349 cm -1 and Ig represents a peak height of a band ranging from 1,570 to 1,578 cm -1 as determined from a Raman scattering spectrum was determined by means of a Raman spectrometer (LabRam HR, product of Jobin Yvon) .
- a raw material liquid was prepared by mixing benzene, ferrocene, and sulfur in proportions (by mass) of 91 : 7 : 2.
- the raw material liquid was fed with hydrogen serving as a carrier gas to a reaction furnace (inner diameter: 100 mm, height: 2,500 mm) heated at 1,200°C and sprayed.
- the feed rates of the raw material and the hydrogen flow were adjusted to 10 g/min and 60 L/min, respectively.
- the reaction product (150 g) obtained through the above method was charged into a graphite crucible (inner diameter: 100 mm, height: 10 mm), baked at 1,000°C for one hour under argon, and subsequently, graphitized at 2,800°C for one hour under argon, to thereby produce vapor grown carbon fiber A.
- the vapor grown carbon fiber A was found to have a mean fiber diameter of 150 nm, a mean fiber length of 9.0 ⁇ m, an aspect ratio of 60, a BET specific surface area of 13 m 2 /g, a d 0 02 of 0.339 nm, and an Id/Ig of 0.2.
- the method for producing vapor grown carbon fiber B employed in the Examples and characteristics of carbon fiber B will be described below.
- a raw material liquid was prepared by mixing benzene, ferrocene, and sulfur in proportions (by mass) of 97 : 2 : 1.
- the raw material liquid was fed with hydrogen serving as a carrier gas to a reaction furnace (inner diameter: 100 mm, height: 2,500 mm) heated at 1,200°C and sprayed.
- the feed rates of the raw material and the hydrogen flow were adjusted to 5 g/min and 90 L/min, respectively.
- the reaction product (150 g) obtained through the above method was charged into a graphite crucible (inner diameter:
- the vapor grown carbon fiber B was found to have a mean fiber diameter of 80 nm, a mean fiber length of 12.0 ⁇ m, an aspect ratio of 150, a BET specific surface area of 25 m 2 /g, a d 00 2 of 0.340 nm, and an Id/Ig of 0.14.
- the method for producing vapor grown carbon fiber C employed in the Examples and characteristics of carbon fiber C will be described below.
- a raw material liquid was prepared by mixing benzene, ferrocene, and sulfur in proportions (by mass) of 92 : 6 : 2.
- the raw material liquid was heated and vaporized by using a 300°C-evaporator .
- Thus prepared raw material gas was fed with hydrogen serving as a carrier gas to a reaction furnace (inner diameter: 100 mm, height: 2,500 mm) heated at 1,200°C.
- the feed rates of the raw material and the hydrogen flow were adjusted to 8 g/min and 60 L/min, respectively.
- the reaction product (150 g) obtained through the above method was charged into a graphite crucible (inner diameter: 100 mm, height: 150 mm), baked at 1,000°C for one hour under argon, and subsequently, graphitized at 2,800°C for one hour under argon, to thereby produce vapor grown carbon fiber C (hereinafter, sometimes referred to as "VGCF-S") .
- the vapor grown carbon fiber C(VGCF-S) was found to have a mean fiber diameter of 100 nm, a mean fiber length of 13.0 ⁇ m, an aspect ratio of 130, a BET specific surface area of 20 m 2 /g, a d 002 of 0.340 nm, and an Id/Ig of 0.14.
- the thus-collected vapor grown carbon fiber was observed under a scanning electron microscope, and an average fiber length was derived through image analysis, whereby the degree of fiber cutting due to kneading was evaluated.
- the viscosity (fluidity) of the matrix polymer and composition was measured by using a Capirograph (a capillary type rheometer) .
- Example 1 Polypropylene resin (Sun-Allomer PWB02N (MFI: 70), product of SunAllomer Ltd.) (90 mass%) and vapor grown carbon fiber A (10 mass%) were melt-kneaded by means of Laboplast mill R100 (product of Toyo Seiki Seisakusho, Ltd.) at 200°C and 40 rpm for 5 minutes (kneading energy: 200 mJ/m 3 ) .
- the kneaded product was molded by means of a 50-ton thermal molding apparatus (product of Nippo Engineering) at 200°C and 200 kgf/cm 2 for 30 seconds, to thereby produce 10 mm x 10 mm x 2 mm t plate samples.
- the matrix resin had a melt viscosity of 100 Pa-s at a shear rate of 100s "1 at a temperature of 200°C.
- Example 2 Polyamide 6 resin (Novamid 1010, product of Mitsubishi Chemical Industries, Ltd.) (90 mass%) and vapor grown carbon fiber A (10 mass%) were melt-kneaded by means of Laboplast mill R100 (product of Toyo Seiki Seisakusho, Ltd.) at 260°C and 40 rpm for 10 minutes (kneading energy: 500 mJ/m 3 ) .
- the kneaded product was molded by means of a 50-ton thermal molding apparatus (product of Nippo Engineering) at 200°C and 200 kgf/cm 2 for 30 seconds, to thereby produce 10 mm x 10 mm x 2 mm t plate samples.
- the matrix resin had a melt viscosity of 80 Pa-s at a shear rate of lOOs -1 at a temperature of 260°C.
- Example 3 Polypropylene resin (Sun-Allomer PWB02N (MFI: 70), product of SunAllomer Ltd.) (54 mass%) , polyethylene resin (J-Rex HD KMA90K (MFI: 30), product of Japan Polyolefins Co., Ltd.) (46 mass%) , and vapor grown carbon fiber A (10 mass%) were melt- kneaded by means of Laboplast mill R100 (product of Toyo Seiki Seisakusho, Ltd.) at 180°C and 40 rpm for 5 minutes (kneading energy: 180 mJ/m 3 ) .
- the kneaded product was molded by means of a 50-ton thermal molding apparatus (product of Nippo Engineering) at 200°C and 200 kgf/cm 2 for 30 seconds, to thereby produce 10 mm x 10 mm x 2 mm t plate samples.
- the matrix resin had a melt viscosity of 150 Pa-s at a shear rate of 100s "1 at a temperature of 180°C.
- Example 4 Polypropylene resin (Sun-Allomer PWB02N (MFI: 70), product of SunAllomer Ltd.) (95 mass%) and vapor grown carbon fiber B (5 mass%) were melt-kneaded by means of Laboplast mill R100 (product of Toyo Seiki) at 200°C and 40 rpm for 5 minutes (kneading energy: 150 mJ/m 3 ) .
- the kneaded product was molded by means of a 50-ton thermal molding apparatus (product of Nippo Engineering) at 200°C and 200 kgf/cm 2 for 30 seconds, to thereby produce 10 mm x 10 mm x 2 mm t plate samples.
- the matrix resin had a melt viscosity of 100 Pa-s at a shear rate of 100s -1 at a temperature of 200°C.
- Example 5 Epoxy resin (EPICLON HP-7200, product of Dainippon Ink and Chemicals, Inc.) (90 mass%) and vapor grown carbon fiber A (10 mass%) were melt-kneaded by means of Laboplast mill RlOO (product of Toyo Seiki Seisakusho, Ltd.) at 80°C and 40 rpm for
- the kneaded product was molded by means of a 50-ton thermal molding apparatus (product of Nippo Engineering) at 175°C and 100 kgf/cm 2 for 5 hours, to thereby produce 10 mm x 10 mm x 2 nm t plate samples.
- the matrix resin had a melt viscosity of 30 Pa-s at a shear rate of 100s -1 at a temperature of 80°C.
- the kneaded product was molded by means of a 50-ton thermal molding apparatus (product of Nippo Engineering) at 200°C and 200 kgf/cm 2 for 30 seconds, to thereby produce 10 mm x 10 mm x 2 mm t plate samples.
- the matrix resin had a melt viscosity of 150 Pa-s at a shear rate of 100s -1 at a temperature of 180°C.
- VGCF-S As vapor grown carbon fiber, VGCF-S (average fiber diameter: 100 nm, average fiber length: 13 ⁇ m, aspect ratio: 130,
- Fluorination treatment A plasma powder treatment device (product of Samco International Kenkyusho) was employed. In a sample flask where plasma was to be generated, vapor grown carbon fiber was placed together with argon serving as a carrier gas and CF 4 serving as a reactive gas, and the gas pressure was adjusted to 1 Torr. The vapor carbon grown fiber was surface-treated in the flask by means of a high-frequency power source of a frequency of 13.54 MHz at a discharge power of 200 W for 60 seconds.
- argon serving as a carrier gas
- CF 4 serving as a reactive gas
- B 4 C powder (mean particle size: 15 ⁇ m) (120 g) was added to vapor grown carbon fiber (2.88 kg), and the mixture was sufficiently mixed by means of a Henschel mixer. The mixture was charged into a cylindrical graphite crucible (volume: 50 L) and pressed, thereby adjusting the bulk density to 0.07 g/cm 3 .
- the crucible was closed with a lid while the compact was pressurized with a graphite pressure sheet and transferred to an Acheson-type furnace for heat treatment.
- the heat treatment temperature was 2,900°C, and the treatment was continued at the temperature for 60 minutes.
- the treated vapor grown carbon fiber was removed from the crucible and pulverized by means of a
- Laboplast mill (volume: 100 ml) (product of Toyo Seiki) was employed as a kneader.
- Laboplast mill is employed for assessing processing characteristics of a polymer such as thermoplastic resin, thermosetting resin, or elastomer on the basis of a mixing test.
- a sample kneading portion of the heated mixer two kneading blades, which are rotatable in directions different from each other at different rotating ratios, and a resin temperature detector are provided.
- the resin fed to the mixer is kneaded by accepting shear, and melting of the resin and dispersion of the filler occur as kneading proceeds depending on the characteristics of the resin and filler.
- the feature of melting and dispersing can be detected as a torque applied to the blades.
- a resin having a high melt viscosity is used, a considerably high torque; i.e., high shear stress, is applied to the mixture, thereby uniformly dispersing the filler.
- thermoplastic resin Each thermoplastic resin was molded into plate pieces (100 x 100 x 2 mm) by means of an injection molding machine (Sicap, clamping force 75 tons, product of Sumitomo Heavy Industries, Ltd.) at a cylinder temperature shown in Table 2. PP, PA6, and PPS were molded at a mold temperature of 20°C, 40°C, and 120°C, respectively, ii) Thermosetting resin Each thermosetting resin was molded into plate pieces (100 x 100 x 2 mm) by means of a molding machine (M-70C-TS, product of Meiki Co., Ltd.). Allyl ester was molded at a cylinder temperature of 80°C and a mold temperature of 160°C for a retention time of 10 minutes.
- Measurement of physical properties Volume resistivity was determined in accordance with a four-probe method (JIS K7194) . Bending characteristics of the samples were evaluated in terms of three-point bending strength (test piece: 100 x 10 x 2 mm, span interval: 64 mm, and bending speed: 2 mm/min) .
- Measurement of viscosity (Capirograph) A Capirograph is a capillary type rheometer and is employed for measurement as stipulated in JIS K7119. Through employment of this rheometer, fluidity of each matrix polymer and each composition were determined. Table 3 shows the measurement results with respect to matrix polymers, and Tables 4 and 5 show the results with respect to resin compositions.
- Table 6 shows threshold values of various vapor grown carbon fibers at different molding temperature.
- a composite material containing polypropylene (PM 900A) and VGCF was molded at 220°C, the threshold value was found to be 7%. In other words, high conductivity was obtained (conductive network was formed) when the amount of VGCF added reached 7%.
- a modified VGCF boron-added, fluorinated, or silylated whose surface energy had been lowered was used, the threshold value was reduced to 3%, exhibiting the effect of the invention.
- the threshold value was reduced to 8%, exhibiting the effect of reduced surface energy.
- the threshold value was found to be 10%.
- the threshold value was reduced to 7%.
- the threshold value was found to be 8%.
- silylated VGCF was used, the threshold value was reduced to 3%, exhibiting the effect of reduced surface energy on VGCF.
- the threshold value was found to be 3%. However, when a fluorinated VGCF-S having a reduced surface energy was used, the threshold value was reduced to 1.5%, which showed that use of such a fluorinated
- VGCF-S was effective.
- Table 6 Type of vapor grown carbon fiber, molding temperature, and threshold values of resins
- the conductive polymer of the present invention uses as a conductivity imparting agent, a vapor grown carbon fiber which is excellent in economical efficiency and a mass supply of which is available.
- cutting of vapor grown carbon fiber can be reduced through the control of kneading energy at the time of kneading matrix polymer and the vapor grown carbon fiber and thus a conductive network structure is formed and maintained, as a result, the polymer obtained by incorporating a small amount of vapor grown carbon fiber can exhibit excellent conductivity. Therefore, the polymer maintains its intrinsic fluidity and provides excellent molded products.
- the conductive polymer of the present invention which is excellent in electric properties such as conductivity and antistatic property, and further in surface smoothness, dimension precision, glossiness, mechanical strength, coatability, heat stability and impact resistance, is useful in many industrial fields, such as the field of material for shipping or wrapping electronic components, the field of components of office automation (OA) apparatus and electronic apparatus and the field of antistatic coating material for automobile.
- OA office automation
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
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Abstract
Description
Claims
Priority Applications (2)
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US10/570,140 US7569161B2 (en) | 2003-09-02 | 2004-09-01 | Electrically conducting polymer and production method and use thereof |
EP04772883A EP1660589A4 (en) | 2003-09-02 | 2004-09-01 | Electrically conducting polymer and production method and use thereof |
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JP2003309929 | 2003-09-02 | ||
JP2003-309929 | 2003-09-02 | ||
US50023703P | 2003-09-05 | 2003-09-05 | |
US60/500,237 | 2003-09-05 | ||
JP2004-037676 | 2004-02-16 | ||
JP2004037676 | 2004-02-16 | ||
US54697304P | 2004-02-24 | 2004-02-24 | |
US60/546,973 | 2004-02-24 |
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PCT/JP2004/013011 WO2005023937A1 (en) | 2003-09-02 | 2004-09-01 | Electrically conducting polymer and production method and use thereof |
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US (1) | US7569161B2 (en) |
EP (1) | EP1660589A4 (en) |
KR (1) | KR100795876B1 (en) |
WO (1) | WO2005023937A1 (en) |
Cited By (5)
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WO2005095687A1 (en) | 2004-03-31 | 2005-10-13 | Bussan Nanotech Research Institute Inc. | Microscopic carbon fiber with a variety of structures |
EP1710014A1 (en) * | 2004-01-27 | 2006-10-11 | Showa Denko Kabushiki Kaisha | Catalyst support and fuel cell using same |
US20100173108A1 (en) * | 2007-02-28 | 2010-07-08 | Showa Denko K. K. | Semiconductive resin composition |
US7919427B2 (en) | 2004-01-27 | 2011-04-05 | Showa Denko K.K. | Catalyst carrier and fuel cell using the same |
GB2497558A (en) * | 2011-12-14 | 2013-06-19 | Bostik Ltd | Tile adhesive |
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Also Published As
Publication number | Publication date |
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US7569161B2 (en) | 2009-08-04 |
EP1660589A1 (en) | 2006-05-31 |
KR100795876B1 (en) | 2008-01-21 |
US20070021546A1 (en) | 2007-01-25 |
KR20060083972A (en) | 2006-07-21 |
EP1660589A4 (en) | 2007-07-04 |
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