WO2005011384A1 - Ternary herbicidal combinations - Google Patents

Ternary herbicidal combinations Download PDF

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Publication number
WO2005011384A1
WO2005011384A1 PCT/EP2004/007833 EP2004007833W WO2005011384A1 WO 2005011384 A1 WO2005011384 A1 WO 2005011384A1 EP 2004007833 W EP2004007833 W EP 2004007833W WO 2005011384 A1 WO2005011384 A1 WO 2005011384A1
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WIPO (PCT)
Prior art keywords
plants
herbicides
salts
acid
compounds
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PCT/EP2004/007833
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German (de)
French (fr)
Inventor
Erwin Hacker
Martin Hess
Frédéric Top
Wolfgang Benz
Markus Dollinger
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Bayer Cropscience Gmbh
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Priority to EP04741027A priority Critical patent/EP1651046A1/en
Publication of WO2005011384A1 publication Critical patent/WO2005011384A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof

Definitions

  • the invention is in the technical field of crop protection agents which are used against harmful plants e.g. can be used in plant crops and contain a combination of at least three herbicides as active ingredients.
  • the effectiveness of these herbicides against harmful plants in plant crops is at a high level, but generally depends on the application rate, the particular form of preparation, the harmful plants to be controlled or the range of harmful plants, the climatic and soil conditions, etc. Another criterion is the duration of action or the rate of degradation of the herbicide. If necessary, changes in the sensitivity of harmful plants that may occur with extended use of the herbicides or geographically limited must also be taken into account. Impact on individuals
  • Harmful plants can only be compensated for to a limited extent by higher application rates of the herbicides, e.g. B. because the selectivity of the herbicides is often deteriorated or there is no improvement in effectiveness even with a higher application rate. In some cases, the selectivity in cultures can be improved by adding safeners. In general, however, there is always a need for methods to achieve the herbicidal action with a lower application rate of active compounds.
  • a lower application rate not only reduces the amount of an active ingredient required for the application, but generally also reduces the amount of formulation auxiliaries required. Both reduce the economic effort and improve the ecological compatibility of herbicide treatment.
  • One way to improve the application profile of a herbicide is to combine the active ingredient with one or more other active ingredients consist.
  • phenomena of physical and biological incompatibility often occur when several active ingredients are used in combination, e.g. B. lack of stability in a co-formulation, decomposition of an active ingredient or antagonism of the active ingredients.
  • combinations of active substances with a favorable activity profile, high stability and, as far as possible, synergistically enhanced activity are desired, which allow a reduction in the application rate compared to the individual application of the active substances to be combined.
  • the group of hydroxybenzonitriles and phenylsulfonylaminocarbonyltriazolinones interact in a particularly advantageous manner, e.g. if they are used in plant crops in which the herbicides, if appropriate with the addition of
  • Safeners can act selectively.
  • the herbicide combinations according to the invention have a herbicidally active content of components (A), (B) and (C) and can contain further components, for. B. agrochemical active substances of another type and / or additives and / or formulation auxiliaries customary in crop protection, or used together with these. Herbicide combinations are preferred which have a synergistically active content of components (A), (B) and (C).
  • the herbicide combinations according to the invention have synergistic effects.
  • the synergistic effects can be observed, for example, when the active ingredients (A), (B) and (C) are applied together, but they can often also be found when the active ingredients are applied at different times (splitting application).
  • Preferred is the simultaneous or prompt application of the active compounds of the herbicide combination according to the invention.
  • the synergistic effects allow a reduction in the application rates of the individual active ingredients, a higher potency with the same application rate, the control of previously unrecognized species (gaps), an extension of the application period and / or a reduction in the number of necessary individual applications and - as a result for the user - economically and more environmentally friendly weed control systems.
  • the formulas (I), (II) and (III) mentioned comprise all stereoisomers and their mixtures, in particular also racemic mixtures, and - if enantiomers are possible - the biologically active enantiomers in each case.
  • Compounds of formula (I) and (III) and their salts and their preparation are e.g. described in EP-A-053011 and US 5,534,486.
  • Compounds of formula (II) and their salts and esters and their preparation are e.g. described in US 3,397,054.
  • a preferred compound of the formula (I) and its salts is diflufenican (A1) (see, for example, Pesticide Manual, 10th edition 1994, pp. 335-336).
  • Preferred compounds of the formula (II) are loxynil and its salts and esters (see, for example, 4-hydroxy-3,5-diiodobenzonitrile, Pesticide Manual, 10th edition 1994, pp.
  • metal salts such as alkali metal salts and Carbonklareester such as C4- ⁇ 0 carboxylic acid esters, for example, ioxynil (B1), ioxynil octanoate, (B2), ioxynil-sodium (B3) and ioxynil-potassium (B4).
  • Preferred compounds of the formula (III) and their salts are methyl 2 - ( ⁇ [(4-methyl-5-oxo-3-propoxy-4,5-dihydro-1 H-1, 2,4-triazol-1-yl ) carbonyl] amino ⁇ sulfonyl) benzoate (propoxycarbazone, C1) and its salts such as the sodium salt (propoxycarbazone sodium, C2) (see, for example, US 5,534,486 and Z. PfIKrankh. PflSchutz, Sonderh. XVII, 545-553 (2000)).
  • the application rate of the active compounds of the formulas (I), (II) and (III) and their salts can vary within wide limits, for example between 0.001 and 2.5 kg of AS / ha. Insofar as the abbreviation AS / ha is used in this description, this means “active substance per hectare”, based on 100% active ingredient.
  • the application rates are generally lower, for. B. in the range of 0.1 to 900 g ai / ha, preferably 0.5 to 750 g ai / ha.
  • the active ingredients can e.g. as water-soluble wettable powder (WP), water-dispersible granulate (WDG), water-emulsifiable granulate (WEG), suspoemulsion (SE) or old dispersion concentrate (e.g. oil suspension concentrate) (OD).
  • WP water-soluble wettable powder
  • WDG water-dispersible granulate
  • WEG water-emulsifiable granulate
  • SE suspoemulsion
  • old dispersion concentrate e.g. oil suspension concentrate
  • the weight ratio of components (A) and (B) to one another is generally 50: 1-1: 100, preferably 25: 1-1: 25.
  • the weight ratio (A + B): C is generally 3000: 1-1 : 10, preferably 800: 1 - 1: 5.
  • Suitable safeners are e.g. known from WO-A-96/14747 and the literature cited therein.
  • the following groups of compounds are suitable, for example, as safeners for the herbicidal active ingredients (A), (B) and (C) mentioned above: a) compounds of the dichlorophenylpyrazoline-3-carboxylic acid (S1) type, preferably compounds such as 1- (2, 4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylic acid ethyl ester (S1-1, mefenpyr-diethyl, PM, S 594-595), and " related " compounds as described, for example, in WO 91/07874 and PM (pp.
  • dichlorophenylpyrazole carboxylic acid preferably compounds such as ethyl 1- (2,4-dichlorophenyl) -5-methyl-pyrazole-3-carboxylate (S1-2), 1- (2,4-dichlorophenyl) -5-isopropyl-pyrazole-3-carboxylic acid ethyl ester (S1-3), 1- (2,4-dichlorophenyl) -5- (1, 1-dimethyl-ethyl) pyrazole-3- ethyl carboxylate (S1-4), 1- (2,4-dichlorophenyl) -5-phenyl-pyrazole-3-carboxylic acid ethyl ester (S1-5) and related compounds as described in EP-A-333 131 and EP-A -269 806 are described.
  • active substances of the phenoxyacetic or propionic acid derivative or aromatic carboxylic acid type such as, for example, 2,4-dichlorophenoxyacetic acid (ester) (2,4-D), 4-chloro-2-methylphenoxy-propionester (mecoprop) , MCPA or 3,6-dichloro-2-methoxy-benzoic acid (ester) (Dicamba).
  • active substances of the pyrimidine type such as "Fenclorim" (PM, pp.
  • 450-451 2-chloro 4-trifluoromethyl-1, 3-thiazole-5-carboxylic acid benzyl ester
  • m active substances of the type of naphthalenedicarboxylic acid derivatives, which are known as seed dressings, such as, for example, “Naphthalic anhy drid "(PM, pp.
  • the herbicides (A), (B) and (C) are suitable, if appropriate in the presence of safeners, for combating harmful plants in crops, for example in economically important crops such as cereals (for example wheat, barley, rye, Oats, rice, maize, millet), sugar beet, sugar cane, rapeseed, cotton and soybeans, of particular interest being the use in monocotyledon crops such as cereals, in particular wheat, barley, rye, oats, and crosses thereof such as triticale, rice, corn and millet
  • cereals for example wheat, barley, rye, Oats, rice, maize, millet
  • sugar beet sugar beet
  • sugar cane rapeseed
  • cotton and soybeans of particular interest being the use in monocotyledon crops
  • cereals in particular wheat, barley, rye, oats, and crosses thereof such as triticale, rice, corn and millet
  • the invention also includes those herbicide combinations which, in addition to components (A), (B) and (C), also comprise one or more further agrochemical active compounds of another structure, such as herbicides, insecticides, fungicides or safeners, preferably herbicides.
  • herbicide combinations which, in addition to components (A), (B) and (C), also comprise one or more further agrochemical active compounds of another structure, such as herbicides, insecticides, fungicides or safeners, preferably herbicides.
  • herbicides from group (D) are herbicides from group (D), the herbicides from the group of the compounds consisting of (indication with the "common name” and a reference point, eg., Selectively in some monocotyledon crops against monocotyledon and / or dicotyledonous harmful plants) from "The Pesticide Manual” 12th Ed., British Crop Protection Council 2000, abbreviated “PM” ⁇ ⁇ ⁇ ⁇ or from “" Th-rPesticide Manual "10th edition 1994, British Crop Protection Council) - 30 (D1) iodosulfuron, in particular also comprising its salts and esters, for example 3- (4-methoxy-6-methyl-1, 3,5-triazin-2-yl) -1- (2-methoxycarbonyl-5-iodophenylsulfonyl) urea (iodosulfuron-methyl) and its salts like that Sodium salt (iodosulfuron-methyl-sodium
  • Imazamox in particular also comprising its esters and salts such as the sodium salt (PM, p. 528), for example (RS) -2- (4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl) -5 -methoxymethylnicotinic acid, (application rate in general: 1 - 500 g ai / ha, preferably 2 - 200 g ai / ha), (D3) florasulam, in particular also comprising its salts such as the sodium salt (PM, pp.
  • halosulfuron in particular also comprising its esters such as halosulfuron-methyl and its salts such as the sodium salt (PM, pp.
  • (D7) cinidon-ethyl, in particular also comprising its salts such as the sodium salt (PM, pp. 181-182), for example ethyl (Z) -2-chloro-3- [2-chloro-5- (1,2-cyclohex -1-enedicarboximido) phenyl] acryIate, (application rate in the old fine: " ⁇ - 500 g AS / ha, " preferably 5 - 20CTg AS / ha), ⁇ (D8) mesotrione (PM, p. 602), e.g.
  • (D11) flufenacet in particular also comprising its salts such as the sodium salt (PM, pp. 434-435), e.g. 4'-fluoro-N-isopropyl-2- (5-trifluoromethyl-1, 3,4-thiadiazol-2-yloxy) acetanilide, (application rate in general: 50-5000 g ai / ha, preferably 150-2000 g ai / Ha),
  • (D12) flumetsulam in particular also comprising its salts such as the sodium salt (PM, pp. 438-439), e.g. 2 ', 6'-difluoro-5-methyl [1, 2,4] triazolo [1,5-a] pyrimidine-2-sulfonanilide, (application rate in general: 5-1000 g ai / ha, preferably 10-600 g AS / ha)
  • (D13) flupoxam in particular also comprising its salts such as the sodium salt (PM, p. 999), e.g. 1- [4-Chloro-3- (2,2,3,3,3-pentafluoropropoxymethyl) phenyl] -5-phenyl-1 H-1, 2,4-triazole-3-carboxamide, (application rate in general: 5 - 5000 g ai / ha, preferably 20 - 3000 g ai / ha),
  • (D14) prosulfocarb in particular also comprising its salts (PM, pp. 786-787), e.g. S-benzyl dipropylthiocarbamate, (application rate in general: 50-5000 g ai / ha, preferably 200-3000 g ai / ha), (D15) flurtamone, in particular also comprising its salts such as the sodium salt (PM, p. 459), e.g.
  • 441-442 are known (application rate in general: 10-300 g ai / ha, preferably 15-200 g ai / ha), (D18) isoproturon, for example 3- (4-isopropylphenyl) -1, 1-dimethylurea pesticide manual , 10th edition 1994, pp. 611-612, (application rate in general: 50 - 5000 g ai / ha, preferably 100 - 4000 g ai / ha),
  • diclofop e.g. (r? S) -2- [4- (2,4-dichlorophenoxy) phenoxy] propionic acid including i.a. the most important form of use is the methyl ester, the diclofop-methyl, Pesticide Manual, 10th ed. 1994, pp. 315-317 (application rate in general: 100-3000 g ai / ha, preferably 200-2000 g ai / ha),
  • (D20) clodinafop e.g. (R) -2- [4- (5-chloro-3-fluoro-2-pyridyloxy) phenoxy] propionic acid, in particular also comprising the use form as clodinafop-propargyl, Pesticide Manual, 10th edition 1994, pp. 216-217, (Application rate in general: 1 - 150 g ai / ha, preferably 5 - 100 g ai / ha), (D21) chlorotoluron, e.g. 3- (3-chloro-p-tolyl) -1,1-dimethylurea, Pesticide Manual, 10th ed. 1994, pp.
  • (D23) Imazamethabenz e.g. reaction product, comprising ( ⁇ ) -6- (4-isopropyl-4-methyl-4-oxo-2-imidazolin-2-yl) -t? 7-toluic acid and ( ⁇ ) -6- ( 4-Isopropyl-4-methyl-4-oxo-2-imidazoli ⁇ -2-yl) -toluic acid7 - whereby the esters, for example the methyl esters known under the name Imazamethabenz-methyl, can also be used, Pesticide Manual, 10th ed. 1994, pp.
  • Flamprop also comprising Flamprop-M, for example ⁇ / -Benzoyl- ⁇ / - (3-chloro-4- 0 fluorophenyl) -DL-alanine and ⁇ / -Benzoyl- / V- (3-chloro-4- fluorophenyI) -D-alanine, including, inter alia, Flamprop-methyl, Flamprop-M-methyl, Flamprop-M-isopropyl, Pesticide Manual, 10th ed.
  • MCPA for example (4-chloro-2-methylphenoxy) acetic acid
  • D29 MCPA-butotyl, MCPA-dimethylammonium, MCPA-isoctyl, MCPA-potassium , MCPA sodium, Pesticide Manual, 10th ed. 5 1994, pp.
  • dichloroprop comprising also dichloroprop-P, for example (RS) -2- (2,4-dichlorophenoxy) propionic acid and (r?) - 2- (2,4- - " ⁇ - - ⁇ OichlOrophenoxy) propionic acid, dichloroprop-0 are also commonly used butotyl, dichloroprop-ethyl ammonium, dichloroprop-iso-octyl, dichloroprop-potassium, Pesticide Manual, 10th ed. 1994, pp. 309-311 and 311-312, (ed in general: 10 - 5000 g ai / ha, preferably 20 - 3000 g AS / ha),
  • dicamba e.g. 3,6-dichloro-anisic acid, used inter alia as dicamba-dimethylammonium, dicamba-potassium, dicamba-sodium, dicamba-trolamine, Pesticide Manual, 10th edition 1994, pp. 298-300, (application rate in general: 20-500 g ai / ha, preferably 30-400 g AS / ha)
  • fluroxypyr e.g. 4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid, further use: fluoroxypyr-meptyl and particularly preferably: fluroxypyr-butoxypropyl ester, Pesticide Manual, 10th ed. 1994, pp. 505-507, (application rate in general: 20 - 500 g ai / ha, preferably 30 - 400 g ai / ha),
  • bromoxynil e.g. 3,5-dibromo-4-hydroxy-benzonitrile, frequently used as bromoxynil octanoate, bromoxynil potassium, Pesticide Manual, 10th ed. 1994, pp. 121-123, (application rate in general: 10 - 3000 g ai / ha , preferably 50 - 1500 g ai / ha),
  • (D37) fluoroglycofen for example 0- [5- (2-chloro- ⁇ , ⁇ , ⁇ -trifluoro-p-tolyloxy) -2-nitrobenzoylglycolic acid, further use: fluoroglycofen-ethyl, Pesticide Manual, 10th edition 1994, p 492-494, (application rate in general: 1 - 200 g ai / ha, preferably 2 - 150 g ai / ha) - " (D38) lactofen, for example ethyl 0- [5- (2-chloro- ⁇ , ⁇ , ⁇ -trifluoro-p-tolyloxy) -2-nitrobenzoyl] - DL-lactate, Pesticide Manual, 10th edition 1994, p.
  • (D42) amidosulfuron e.g. 1- (4,6-dimethoxypyrimidin-2-yl) -3-mesyl (methyl) sulfamoyl urea, Pesticide Manual, 10th edition 1994, pp. 34-35, (application rate in general: 0, 5-200 g ai / ha, preferably 1-100 g ai / ha),
  • (D43) metsulfuron for example 2- (4-methoxy-6-methyl-1, 3,5-triazin-2-ylcarbamoylsulfamoyl) benzoic acid, usually used as Metsulfuron-methyl, Pesticide Manual, 10th ed. 1994, pp.
  • D48 Flupyrsulfuron (DPX-KE459), e.g. methyl 2- (4,6-dimethoxypyrimidin-2-ylcarbamoylsulfamoyl) -6-trifluoromethylnicotinate, e.g. flupyrsulfuron-methyl-sodium (PM, pp. 447 - 448), (application rate in general : 1 - 120 g ai / ha, preferably 2 - 100 g ai / ha), (D49) fluazolates (MON 48500), e.g.
  • glufosinate including also glufosinate-P, for example 4- [hydroxy (methyl) phosphinoyl] -DL-homoalanine, 4- [Hydroxy (methyl) phosphinoyl] -L-homoalanine, each preferred as salts, for example ammonium or alkali metal salts such as glufosinate-ammonium, glufosinate-P-ammonium, glufos inate sodium or glufosinate P sodium can be used, Pesticide Manual, 10th ed.
  • Glyphosate for example ⁇ / - (phosphonomethyl) glycine, which is preferably used as glyphosate-isopropylammonium, glyphosate-sesquinatrium, glyphosate-trimesium, Pesticide Manual, 10th ed. 1994, pp.
  • 2- (4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl) nicotinic acid (application rate in general: 1 - 500 g ⁇ """ AS / ha, preferably 2 - 300 g AS / ha), 0 (D61) Imazapic, in particular also comprising its esters and salts such as the sodium salt (PM, p. 529), for example (RS) -2- (4-isopropyl-4-methyl-5-oxo-2 imidazolin-2-yl) -5-methylnicot Acid, (application rate in general: 1 - 500 g ai / ha, preferably 2 - 300 g ai / ha).
  • herbicides D1, D2, D4, D8, D9, D11 - D16, D18, D21, D22, D23, D24, D27, D40, D43, D47 - D53, D58 - D61, D63 are suitable - D65 in particular for controlling monocotyledon and dicotyledonous harmful plants
  • the herbicides D17, D19, D20, D25, D26, D54-D56 are particularly suitable for controlling monocotyledonous harmful plants
  • the herbicides D3, D5, D6, D7, D10, D28 - D39, D41 , D42, D44, D45, D46, D57, D62 are particularly suitable for controlling dicotyledonous harmful plants.
  • Herbicide combinations containing the following compounds (A) + (B) + (C) and (A) + (B) + (C) + (D) are of particular interest:
  • each of the herbicide combinations mentioned above can also contain a 10 or more safener, in particular a safener such as mefenpyr-diethyl (S1-1), isoxadifen-ethyl (S1-9) and cloquintocet-mexyl (S2-1).
  • a safener such as mefenpyr-diethyl (S1-1), isoxadifen-ethyl (S1-9) and cloquintocet-mexyl (S2-1).
  • S1-1 mefenpyr-diethyl
  • S1-9 isoxadifen-ethyl
  • S2-1 cloquintocet-mexyl
  • herbicides (A) with one or more herbicides (B) and / or more herbicides (C), for example one Herbicide (A) with one herbicide (B) and one herbicide (C).
  • herbicide combinations according to the invention can be used together with other agrochemical active ingredients, for example from the group of safeners, fungicides, herbicides, in particular from the group of herbicides (D), insecticides and plant growth regulators or additives customary in crop protection, such as fertilizers and dyes and formulation auxiliaries, the above ranges of application rates and
  • the application rate ratio (A + B + C): D is generally 2500: 1-1: 500, preferably 1000: 1-1: 300.
  • Herbicide combinations with several herbicides D e.g. those containing the following herbicide combinations as component D): D35 + D29, D1 + D42, D1 + D65, D44 + D45, D43 + D45, D46 + D32, D33 + D35 or D48 + D57, preferably as components ( A), (B) and (C) the compounds (A1) + (B1) + (C1), (A1) + (B1) + (C2), (A1) + (B2) + (C1), (A1 ) + (B2) + (C2), (A1) + (B3) + (C1), (A1) + (B3) + (C2), (A1) + (B4) + (C1) or (A1) + (B4) + (C2), in particular (A1) + (B2) + (C2), are contained, and additionally a safener
  • the combinations according to the invention have excellent herbicidal activity against a broad spectrum of economically important mono- and dicotyledonous harmful plants.
  • Perennial weeds that are difficult to control and that sprout from rhizomes, rhizomes or other permanent organs are also well captured by the active ingredients. It does not matter whether the substances are applied by pre-sowing, pre-emergence or post-emergence. Use in the post-emergence process or in the early post-sowing pre-emergence process is preferred.
  • Some representatives of the monocotyledonous and dicotyledon weed flocks are examples.
  • the cfiS should be able to control the compounds according to the invention without the name being intended to restrict them to certain species.
  • On the side of the monocotyledon weed species for example, Apera spica venti, Avena spp., Alopecurus spp., Brachiaria spp., Digitaria spp., Lolium spp., Echinochloa spp., Panicum spp., Phalaris spp., Poa spp., Setaria spp , and Bromus spp.
  • the spectrum of activity extends to species such as Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp., Ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp., Polygonum spp., Sida spp., Sinapis spp ., Solanum spp., Stellaria spp., Veronica spp. and Viola spp., Xanthium spp., Paphaver rhoeas spp., Centaurea spp. on the annual side as well as Convolvulus, Cirsium, Rumex and Artemisia spp. in the perennial weeds.
  • the herbicide combinations according to the invention are applied to the surface of the earth before germination, either the weed seedlings emerge completely or the weeds grow to the cotyledon stage, but then stop growing and finally die completely after three to four weeks ,
  • the herbicidal compositions according to the invention are notable for a rapid onset and long-lasting herbicidal action.
  • the rain resistance of the active ingredients in the combinations according to the invention is generally favorable.
  • a particular advantage is that the effective dosages of compounds (A), (B) and (C) used in the combinations can be set so low that their soil effect is optimally low. This makes their use not only possible in sensitive crops, but groundwater contamination is practically avoided.
  • the combination of active substances according to the invention enables a considerable reduction in the amount of active substances required.
  • the combinations according to the invention have excellent herbicidal activity against monocotyledonous and dicotyledonous harmful plants, the crop plants are damaged only insignificantly or not at all.
  • some of the agents according to the invention have excellent growth-regulatory properties in the crop plants. They intervene regulating the plant's own metabolism and can thus be used to influence plant constituents in a targeted manner and to facilitate harvesting, for example by triggering desiccation and stunted growth.
  • they are also suitable for general control and inhibition of undesirable vegetative growth without killing the plants. Inhibiting vegetative growth plays a major role in many monocotyledonous and dicotyledonous crops, as this can reduce or completely prevent crop losses during storage.
  • the agents according to the invention for controlling harmful plants can be used in genetically modified crops or crop plants obtained by mutation selection.
  • crop plants are generally distinguished by special advantageous properties, such as resistance to herbicidal compositions or resistance to plant diseases or pathogens causing plant diseases such as certain insects or microorganisms such as fungi, bacteria or viruses.
  • special properties concern e.g. B. the crop in terms of quantity, quality, shelf life, composition and special ingredients. For example, transgenic plants with an increased starch content or altered starch quality or those with a different fatty acid composition of the crop are known.
  • transgenic crop plants which are resistant to other herbicides, for example sulfonylureas (US-A-5013659), transgenic crop plants with the ability to produce Bacillus thuringiensis toxins (Bt toxins) which make the plants resistant to certain pests (EP- A-0142924, EP-A-0193259).
  • transgenic crop plants with modified fatty acid composition WO 91/13972).
  • nucleic acid molecules can be introduced into plasmids which allow mutagenesis or a sequence change by recombining DNA sequences.
  • plasmids which allow mutagenesis or a sequence change by recombining DNA sequences.
  • base exchanges partial sequences removed or natural or synthetic sequences added.
  • adapters or linkers can be attached to the fragments.
  • the production of plant cells with a reduced activity of a gene product can be achieved, for example by expressing at least one corresponding antisense RNA, a sense RNA for achieving a CosuppreBsiöns bines ödertlie "expression of at least cleaves one suitably constructed ribozyme which specifically cleaves transcripts of the abovementioned gene product.
  • DNA molecules can be used that comprise the entire coding sequence of a gene product, including any flanking sequences that may be present, as well as DNA molecules that only comprise parts of the coding sequence, these parts having to be long enough to be in the cells to cause an antisense effect. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product, but which are not completely identical.
  • the synthesized protein When nucleic acid molecules are expressed in plants, the synthesized protein can be located in any compartment of the plant cell. However, in order to achieve localization in a particular compartment, z. B. the coding region can be linked to DNA sequences that ensure localization in a particular compartment. Such sequences are known to the person skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1: 95-106 (1991).
  • the transgenic plant cells can be regenerated into whole plants using known techniques.
  • the transgenic plants can in principle be plants of any plant species, i.e. both monocot and dicot plants.
  • the present invention furthermore also relates to a process for controlling unwanted vegetation (for example harmful plants such as weeds or undesired crop plants), preferably in crops such as - fet ' reideT (for example wheat rye, rye, oats; hybrids thereof such as ritical rice, maize, Millet), sugar beet, sugar cane, rapeseed, cotton and soy, particularly preferably in monocot crops such as cereals, for example wheat, barley, rye, oats, crosses thereof such as triticale, rice, corn and millet, one or several herbicides of type (A) with one or more herbicides of type (B) and one or more herbicides of type (C) together or separately, for example pre-emergence, post-emergence or pre-post-emergence, on the plants, for example harmful plants, Plant parts, plant seeds or the area on which the plants 5 grow, for example the cultivated area applied.
  • unwanted vegetation for example harmful plants such as weeds or undesi
  • Undesirable plants are understood to mean all plants that grow in places where they are undesirable. This can e.g. Harmful plants (e.g. weeds or unwanted crops), e.g. also those that are resistant to certain 10 herbicidal active ingredients such as glyphosate, atrazine, glufosinate or imidazolinones.
  • Harmful plants e.g. weeds or unwanted crops
  • herbicidal active ingredients such as glyphosate, atrazine, glufosinate or imidazolinones.
  • the plant cultures can also be genetically modified or obtained by mutation selection and are preferably tolerant of 15 acetolactate synthase (ALS) inhibitors.
  • ALS acetolactate synthase
  • the invention also relates to the use of the herbicide combinations according to the invention of compounds (A) + (B) + (C) for controlling harmful plants, preferably in plant crops.
  • herbicidal compositions according to the invention can also be used non-selectively for controlling unwanted vegetation, e.g. in plantation crops, on roadsides, squares, industrial plants or railway systems.
  • the active substance combinations according to the invention can be used both as mixed formulations of components (A), (B) and (C), if appropriate with further agrochemical active substances, additives and / or customary * ---- . -_ -p ⁇ rr ⁇ iferu ⁇ gshJifsmJ teln are present, which are then diluted with water in the usual way ⁇ 30 to use, or prepared as so-called tank mixes by jointly diluting the separately formulated or partially separately formulated components with water.
  • the components (A), (B) and (C) can also be formulated separately and applied separately, so that the active compound combination according to the invention forms at the application site.
  • the compounds (A), (B) and (C) or their combinations can be formulated in 5 different ways, depending on which biological and / or chemical-physical parameters are specified.
  • Examples of general formulation possibilities are: wettable powder (WP), water-soluble concentrates, emulsifiable concentrates (EC), aqueous solutions (SL), emulsions (EW) such as oil-in-water and water-in-oil emulsions, 0 sprayable Solutions or emulsions, suspension concentrates (SC), dispersions based on oil or water, suspoemulsions, dusts (DP), mordants, granules for soil or litter application or water-dispersible granules (WG), ULV formulations, microcapsules or waxes.
  • Combinations can also be made on the basis of these formulations with other agrochemical active ingredients, such as other herbicides, fungicides, insecticides, as well as safeners, fertilizers and / or growth regulators, for example in the form of a finished formulation or as a tank mix.
  • Spray powders are preparations which are uniformly dispersible in water and which, in addition to the active substance, contain not only a diluent or inert substance, but also ionic or nonionic surfactants (wetting agents, dispersing agents), e.g. polyoxethylated alkylphenols, polyethoxylated fatty alcohols or fatty amines, alkanesulfonates or alkylbenzenesulfonates, ligninsulfonic acid sodium, 2,2'-dinaphthylmethane-6,6'-disulfonic acid sodium, dibutylnaphthalene sulfonic acid sodium or also oleoylmethyl tauric acid sodium.
  • ionic or nonionic surfactants e.g. polyoxethylated alkylphenols, polyethoxylated fatty alcohols or fatty amines, alkanesulfonates or alkylbenzenesulfonates
  • Emulsifiable concentrates are made by dissolving the active ingredient in an organic solvent, e.g. Butanol, cyclohexanone, dimethylformamide, xylene or higher-boiling aromatics or hydrocarbons with the addition of one or more ionic or nonionic surfactants (emulsifiers).
  • organic solvent e.g. Butanol, cyclohexanone, dimethylformamide, xylene or higher-boiling aromatics or hydrocarbons.
  • ionic or nonionic surfactants emulsifiers
  • alkylarylsulfonic acid calcium salts such as calcium dodecylbenzenesulfonate
  • nonionic emulsifiers such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide / ethylene oxide condensation products, alkyl polyethers, sorbitan fatty acid ester sorbate polyethylenefatty acid sorboxate, polyoxyethylene ethoxylate sorbate, polyoxyethylene ethoxylate sorbet, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbet
  • Dusts are obtained by grinding the active ingredient with finely divided solid substances, e.g. Talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
  • finely divided solid substances e.g. Talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
  • SC Suspension concentrates
  • SC can be water or oil based. They can be prepared, for example, by wet grinding using commercially available bead mills and, where appropriate, “ further, if they ” are already listed above for the other “ types of formulation ” .
  • Emulsions for example oil-in-water emulsions (EW), can be used, for example, using stirrers, colloid mills and / or static mixers aqueous organic solvents and optionally other surfactants, such as those already listed above for the other types of formulation.
  • EW oil-in-water emulsions
  • Granules can either be produced by spraying the active ingredient onto adsorbable, granulated inert material or by applying active ingredient concentrates by means of adhesives, e.g. Polyvinyl alcohol, sodium polyacrylic acid or mineral oils, on the surface of carriers such as sand, kaolinite or granulated inert material. Suitable active ingredients can also be granulated in the manner customary for the production of fertilizer granules, if desired in a mixture with fertilizers. Water-dispersible granules are generally produced using the customary methods, such as spray drying, fluidized bed granulation, plate granulation, mixing with high-speed mixers and extrusion without solid inert material. For the production of plate, fluidized bed, extruder and spray granules, see e.g.
  • the agrochemical formulations generally contain 0.1 to 99 percent by weight, in particular 2 to 95% by weight, of active ingredients of types A and / or B and / or C, the following concentrations being customary depending on the type of formulation: the active ingredient concentration in wettable powders is for example about 10 to 95 wt .-%, the rest of 100 wt .-% consists of conventional formulation components. Beie ⁇ nu1gie7l are ⁇ Ki- ⁇ iz ⁇ the Wirkstoffk ⁇ nzentratiori eg 5 to be "80% by weight. 7 Dust-like formulations contain at most 5 to 20 wt .-%
  • Active ingredient sprayable solutions about 0.2 to 25 wt .-% active ingredient.
  • the active ingredient content depends in part on whether the active compound is liquid or solid and which granulating agents and fillers are used. As a rule, the content of the water-dispersible granules is between 10 and 90% by weight.
  • the active ingredient formulations mentioned may contain the customary adhesives, wetting agents, dispersants, emulsifiers, preservatives, antifreezes and solvents, fillers, dyes and carriers, defoamers, evaporation inhibitors and agents which adjust the pH or Influence viscosity.
  • the herbicidal activity of the herbicide combinations according to the invention can be improved, for example, by surface-active substances, preferably by wetting agents from the range of fatty alcohol polyglycol ethers.
  • the fatty alcohol polyglycol ethers preferably contain 10 to 18 carbon atoms in the fatty alcohol residue and 2 to 20 ethylene oxide units in the polyglycol ether part.
  • the fatty alcohol polyglycol ethers can be nonionic or ionic, for example in the form of fatty alcohol polyglycol ether sulfates, which are used, for example, as alkali metal salts (for example sodium and potassium salts) or ammonium salts, or also as alkaline earth metal salts such as magnesium salts, such as C-
  • Nonionic fatty alcohol polyglycol ethers are, for example, 2 to 20, preferably 3 to 15, ethylene oxide units (C 10 -C 8 ), preferably (C 1 -C 0 ) fatty alcohol polyglycol ethers (for example isotridecyl alcohol polyglycol ether), for example from Genapol ® X series such as Genapol ® X-030, Genapol ® X-060, Genapol ® X-080 or Genapol ® X-150 (all from Clariant GmbH).
  • Genapol ® X series such as Genapol ® X-030, Genapol ® X-060, Genapol ® X-080 or Genapol ® X-150 (all from Clariant GmbH).
  • the present invention further comprises the combination of herbicides (A), (B) and (C) with the above-mentioned wetting agents from the series of fatty alcohol polyglycol ethers, which preferably contain 10 to 18 carbon atoms in the fatty alcohol residue and 2 to 20 ethylene oxide units in the polyglycol ether part contain and can be non-ionic or ionic (for example as fatty alcohol polyglycol ether sulfates).
  • Ci2 / C 14 fatty alcohol diglycol ether sulfate sodium are preferred, and Isotridecyl alcohol polyglycol ether, with 3 - 15 ethylene oxide units, e.g.
  • Genapol ® X series such as Genapol ® X-030, Genapol ® X-060, Genapol ® X-080 and Genapol ® X-150 (all from Clariant GmbH).
  • fatty alcohol polyglycol ethers such as nonionic or ionic fatty alcohol polyglycol ethers (e.g. fatty alcohol polyglycol ether sulfates) are also suitable as penetration aids and activity enhancers for a number of other herbicides, including herbicides from the imidazolinone series (see, for example, EP-A - 0502014).
  • fatty alcohol polyglycol ethers such as nonionic or ionic fatty alcohol polyglycol ethers (e.g. fatty alcohol polyglycol ether sulfates) are also suitable as penetration aids and activity enhancers for a number of other herbicides, including herbicides from the imidazolinone series (see, for example, EP-A -0,502,014).
  • the herbicidal activity of the herbicide combinations according to the invention can also be enhanced by using vegetable oils.
  • vegetable oils is understood to mean oils from oil-producing plant species such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, safflower oil or castor oil, in particular rapeseed oil, and their transesterification products, e.g. Alkyl esters such as rapeseed oil methyl ester or rapeseed oil ethyl ester.
  • the vegetable oils are preferably esters of C ⁇ o-C 22 -, preferably C-i2-C 20 - fatty acids.
  • the C 10 -C 22 fatty acid esters are, for example, esters of unsaturated or saturated C 0 -C 22 fatty acids, in particular with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular C 8 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
  • Cfo-C 22 fatty acids-EsTersihd ⁇ Ester7 ' which are obtained by r- reaction of glycerol or glycol with the C ⁇ o-C 22 fatty acids, such as those contained in oils from oil-producing plant species, or C ⁇ -C 2 o-Alkyl -C 0 C 22 fatty acid esters, such as those obtained, for example, by transesterification of the above-mentioned glycerol or glycol-C ⁇ o-C22- Fatty acid esters with C 2 -C 20 alcohols (for example methanol, ethanol, propanol or butanol) can be obtained.
  • the transesterification can be carried out according to known methods, as described, for example, in the Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
  • Preferred C 1 -C 20 -alkyl-C 22 -C 22 fatty acid esters are methyl esters, ethyl esters, propyl esters, butyl esters, 2-ethyl hexyl esters and dodecyl esters.
  • Preferred as glycol and glycerol -CC 22 fatty acid esters are the uniform or mixed glycol esters and glycerol esters of -CC 22 fatty acids, in particular those fatty acids with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular C- i ⁇ fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
  • the vegetable oils can be present in the inventive herbicidal compositions, for example in the form of commercially available oil-containing formulation additives, in particular those (hereinafter referred Victorian Chemical Company, Australia, Hasten, main constituent: rapeseed oil ethyl ester) based on rapeseed oil such as Hasten ®, Actirob ® B (Novance, France, hereinafter Called ActirobB, main component: rapeseed oil methyl ester), Rako-Binol ® (Bayer AG, Germany, hereinafter called Rako-Binol, main component: rapeseed oil), Renol ® (Stefes, Germany, hereinafter referred to as Renol, vegetable oil component: rapeseed oil methyl ester) or Stefes Mero ® (Stefes , Germany, hereinafter called Mero, main ingredient: rapeseed oil methyl ester).
  • Oil-containing formulation additives in particular those (hereinafter
  • Combinations of herbicides (A), (B) and (C) with the vegetable oils mentioned above such as rapeseed oil preferably in the form of commercially available oil-containing formulation additives, in particular those based on rapeseed oil such as Hasten ® (Victofiän Che ⁇ ica eornp ⁇ a ⁇ y Ausfrä.ie ⁇ r hereinafter referred to as, - Main ingredient: rapeseed oil ethyl ester), Actirob ® B (Novance, France, hereinafter called ActirobB, main ingredient: rapeseed oil methyl ester), Rako-Binol ® (Bayer AG, Germany, hereinafter called Rako-Binol, main ingredient: rapeseed oil), Renol ® (Stefes, Germany, hereinafter called Renol, vegetable oil component: rapeseed oil methyl ester) or Stefes Mero ® (Stefes, Germany, hereinafter called Mero
  • the formulations present in the commercial form are optionally diluted in the customary manner, e.g. for wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules using water.
  • Preparations in the form of dust, ground granules or granules for spreading, and sprayable solutions are usually no longer diluted with other inert substances before use.
  • the active compounds can be applied to the plants, parts of plants, plant seeds or the area under cultivation (arable soil), preferably to the green plants and parts of plants and, if appropriate, additionally to the arable soil.
  • arable soil preferably to the green plants and parts of plants and, if appropriate, additionally to the arable soil.
  • One possible application is the joint application of the active ingredients in the form of tank mixes, the optimally formulated concentrated formulations of the individual active ingredients being mixed together with water in the tank and the spray liquor obtained being applied.
  • a common herbicidal formulation of the combination according to the invention of active ingredients (A), (B) and (C) generally has the advantage of being easier to use.
  • a dusting agent is obtained by mixing 10 parts by weight of an active substance / active substance mixture and 90 parts by weight of talc as an inert substance and comminuting them in a hammer mill.
  • a readily water-dispersible wettable powder is obtained by mixing 25 wt ⁇ ⁇ parts-% fr ⁇ es "" drug / Wifkstoffgemischs, 64 wt. -Teile- kaolin-containing quartz as inert substance, 10 parts by wt. of potassium lignosulfonate and 1 wt - Mixes sodium oleoylmethyl tauric acid as a wetting and dispersing agent and grinds it in a pin mill.
  • a readily water-dispersible dispersion concentrate is obtained by mixing 20 parts by weight of an active compound / active compound mixture with 6 parts by weight of alkylphenol polyglycol ether (Triton ® X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 wt. Parts of paraffinic mineral oil (boiling range approx. 255 to 277 ° C) and ground in a friction ball mill to a fineness of less than 5 microns.
  • alkylphenol polyglycol ether Triton ® X 207
  • isotridecanol polyglycol ether 8 EO
  • Parts of paraffinic mineral oil (boiling range approx. 255 to 277 ° C) and ground in a friction ball mill to a fineness of less than 5 microns.
  • An emulsifiable concentrate is obtained from 15 parts by weight of an active ingredient / active ingredient mixture, 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of oxyethylated nonylphenol as emulsifier.
  • a water-dispersible granulate is obtained by mixing 75 parts by weight of an active ingredient / active ingredient mixture, 10 parts by weight of calcium lignosulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol and 7 parts by weight of kaolin , grinds on a pin mill and granulates the powder in a fluidized bed by spraying water as the granulating liquid.
  • a water-dispersible granulate is also obtained by adding 25 parts by weight of an active ingredient / active ingredient mixture, 5 parts by weight of 2,2'-dinaphthylmethane-6,6'-disulfonic acid sodium, 2 parts by weight of oleoylmethyl tauric acid sodium , 1 part by weight of polyvinyl alcohol, 17 parts by weight of calcium carbonate and 50 parts by weight of water and vofzeTkleinert, then ground in a bead mill and the suspension thus obtained is atomized and dried in a spray tower using a single-component nozzle.
  • B. Biological examples are also obtained by adding 25 parts by weight of an active ingredient / active ingredient mixture, 5 parts by weight of 2,2'-dinaphthylmethane-6,6'-disulfonic acid sodium, 2 parts by weight of oleoylmethyl tauric acid sodium , 1 part by weight of polyvinyl alcohol, 17 parts by weight of calcium carbonate and 50 parts by weight of water and vo
  • the seeds or rhizome pieces of the harmful plants and useful plants were laid out or were present in the soil and grown under natural outdoor conditions.
  • the treatment with the active ingredients or combinations of active ingredients was carried out after, before and / or after emergence of the plants, as a rule in the 2 to 4 leaf stage in various dosages with a water application rate of the equivalent of 100 to 400 l / ha.

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Abstract

The invention relates to herbicidal combinations with an active content of components (A), (B) and (C), said combinations exhibiting improved characteristics as agricultural pesticides. According to the invention: (A) represents one or more herbicides from the group of compounds of formula (I) and the salts of said compounds; (B) represents one or more herbicides from the group of compounds of formula (II) and the salts and esters of said compounds; (C) represents one or more herbicides from the group of compounds of formula (III) and the salts of said compounds.

Description

TERNARE HERBIZID-KOMBINATIONEN TERNARE HERBICIDE COMBINATIONS
Die Erfindung liegt auf dem technischen Gebiet der Pflanzenschutzmittel, die gegen Schadpflanzen z.B. in Pflanzenkulturen eingesetzt werden können und als Wirkstoffe eine Kombination von mindestens drei Herbiziden enthalten.The invention is in the technical field of crop protection agents which are used against harmful plants e.g. can be used in plant crops and contain a combination of at least three herbicides as active ingredients.
Aus den Druckschriften EP-A-053011, US 3,397,054 und US 5,534,486 sind bestimmte Herbizide und deren Salze sowie deren Verwendung als Herbizide und/oder Pflanzenwachstumsregulatoren bekannt.From the publications EP-A-053011, US 3,397,054 and US 5,534,486 certain herbicides and their salts and their use as herbicides and / or plant growth regulators are known.
Die Wirksamkeit dieser Herbizide gegen Schadpflanzen in den Pflanzenkulturen liegt auf einem hohen Niveau, hängt jedoch im allgemeinen von der Aufwandmenge, der jeweiligen Zubereitungsform, den jeweils zu bekämpfenden Schadpflanzen oder dem Schadpflanzenspektrum, den Klima- und Bodenverhältnissen, etc. ab. Ein weiteres Kriterium ist die Dauer der Wirkung bzw. die Abbaugeschwindigkeit des Herbizids. Zu berücksichtigen sind gegebenenfalls auch Veränderungen in der Empfindlichkeit von Schadpflanzen, die bei längerer Anwendung der Herbzide oder geographisch begrenzt auftreten können. Wirkungsverluste bei einzelnenThe effectiveness of these herbicides against harmful plants in plant crops is at a high level, but generally depends on the application rate, the particular form of preparation, the harmful plants to be controlled or the range of harmful plants, the climatic and soil conditions, etc. Another criterion is the duration of action or the rate of degradation of the herbicide. If necessary, changes in the sensitivity of harmful plants that may occur with extended use of the herbicides or geographically limited must also be taken into account. Impact on individuals
Schadpflanzen lassen sich nur bedingt durch höhere Aufwandmengen der Herbizide ausgleichen, z. B. weil damit häufig die Selektivität der Herbizide verschlechtert wird oder eine Wirkungsverbesserung auch bei höherer Aufwandmenge nicht eintritt. Teilweise kann die Selektivität in Kulturen durch Zusatz von Safenern verbessert werden. Generell besteht jedoch immer Bedarf für Methoden, die Herbizidwirkung mit geringerer Aufwandmenge an Wirkstoffen zu erreichen. Eine geringere Aufwandmenge reduziert nicht nur die für die Applikation erforderliche Menge eines Wirkstoffs, sondern reduziert in der Regel auch die Menge an nötigen Formulierü τgshiifsmitteln. Beides verringert den wirtschaftlichen Aufwand und verbessert die ökologische Verträglichkeit der Herbizidbehandlung.Harmful plants can only be compensated for to a limited extent by higher application rates of the herbicides, e.g. B. because the selectivity of the herbicides is often deteriorated or there is no improvement in effectiveness even with a higher application rate. In some cases, the selectivity in cultures can be improved by adding safeners. In general, however, there is always a need for methods to achieve the herbicidal action with a lower application rate of active compounds. A lower application rate not only reduces the amount of an active ingredient required for the application, but generally also reduces the amount of formulation auxiliaries required. Both reduce the economic effort and improve the ecological compatibility of herbicide treatment.
Eine Möglichkeit zur Verbesserung des Anwendungsprofils eines Herbizids kann in der Kombination des Wirkstoffs mit einem oder mehreren anderen Wirkstoffen bestehen. Allerdings treten bei der kombinierten Anwendung mehrerer Wirkstoffe nicht selten Phänomene der physikalischen und biologischen Unverträglichkeit auf, z. B. mangelnde Stabilität in einer Coformulierung, Zersetzung eines Wirkstoffes bzw. Antagonismus der Wirkstoffe. Erwünscht dagegen sind Kombinationen von Wirkstoffen mit günstigem Wirkungsprofil, hoher Stabilität und möglichst synergistisch verstärkter Wirkung, welche eine Reduzierung der Aufwandmenge im Vergleich zur Einzelapplikation der zu kombinierenden Wirkstoffe erlaubt.One way to improve the application profile of a herbicide is to combine the active ingredient with one or more other active ingredients consist. However, phenomena of physical and biological incompatibility often occur when several active ingredients are used in combination, e.g. B. lack of stability in a co-formulation, decomposition of an active ingredient or antagonism of the active ingredients. On the other hand, combinations of active substances with a favorable activity profile, high stability and, as far as possible, synergistically enhanced activity are desired, which allow a reduction in the application rate compared to the individual application of the active substances to be combined.
Überraschenderweise wurde nun gefunden, daß bestimmte herbizide Wirkstoffe aus der Gruppe der Nicotinamide in Kombination mit bestimmten Wirkstoffen aus derSurprisingly, it has now been found that certain herbicidal active ingredients from the group of nicotinamides in combination with certain active ingredients from the
Gruppe der Hydroxybenzonitrile und Phenylsulfonylaminocarbonyltriazolinone in besonders günstiger Weise zusammenwirken, z.B. wenn sie in Pflanzenkulturen eingesetzt werden, in denen die Herbizide, gegebenenfalls unter Zusatz vonThe group of hydroxybenzonitriles and phenylsulfonylaminocarbonyltriazolinones interact in a particularly advantageous manner, e.g. if they are used in plant crops in which the herbicides, if appropriate with the addition of
Safenern, selektiv wirken können.Safeners, can act selectively.
Gegenstand der Erfindung sind somit Herbizid-Kombinationen mit einem wirksamenThe invention thus relates to herbicide combinations with an effective
Gehalt an Komponenten (A), (B) und (C) wobeiContent of components (A), (B) and (C) where
(A) ein oder mehrere Herbizide aus der Gruppe der Verbindungen der Formel (I) und deren Salze bedeutet,(A) one or more herbicides from the group of the compounds of the formula (I) and their salts,
Figure imgf000004_0001
Figure imgf000004_0001
(B) ein oder mehrere Herbizide aus der Gruppe der Verbindungen der Formel (II) und deren Salze und Ester bedeutet,
Figure imgf000005_0001
(B) one or more herbicides from the group of the compounds of the formula (II) and their salts and esters,
Figure imgf000005_0001
(C) ein oder mehrere Herbizide aus der Gruppe der Verbindungen der Formel (III) und deren Salze bedeutet,(C) one or more herbicides from the group of the compounds of the formula (III) and their salts,
Figure imgf000005_0002
Figure imgf000005_0002
Die erfindungsgemäßen Herbizid-Kombinationen weisen einen herbizid wirksamen Gehalt an Komponenten (A), (B) und (C) auf und können weitere Komponenten enthalten, z. B. agrochemische Wirkstoffe anderer Art und/oder im Pflanzenschutz übliche Zusatzstoffe und/oder Formulierungshilfsmittel, oder zusammen mit diesen eingesetzt werden. Es sind Herbizid-Kombinationen bevorzugt, die einen synergistisch wirksamen Gehalt an Komponenten (A), (B) und (C) aufweisen.The herbicide combinations according to the invention have a herbicidally active content of components (A), (B) and (C) and can contain further components, for. B. agrochemical active substances of another type and / or additives and / or formulation auxiliaries customary in crop protection, or used together with these. Herbicide combinations are preferred which have a synergistically active content of components (A), (B) and (C).
Die erfindungsgemäßen Herbizid-Kombinationen weisen in bevorzugter Ausführungsform synergistische Wirkungen auf. Die synergistischen Wirkungen können z.B. bei gemeinsamer Ausbringung der Wirkstoffe (A), (B) und (C) beobachtet werden, sie können jedoch häufig auch bei zeitlich versetzter Anwendung der Wirkstoffe (Splitting-Applikation) festgestellt werden. Möglich ist auch die Anwendung der einzelnen Herbizide oder der Herbizid-Kombinationen in mehreren Portionen (Sequenzanwendung), z. B. Anwendungen im Vorauflauf, gefolgt von Nachauflauf-Applikationen oder frühe Nachauflaufanwendungen, gefolgt von Applikationen im mittleren oder späten Nachauflauf. Bevorzugt ist dabei die gemeinsame oder die zeitnahe Anwendung der Wirkstoffe der erfindungsgemäßen Herbizid-Kombination. Die synergistischen Effekte erlauben eine Reduktion der Aufwandmengen der Einzelwirkstoffe, eine höhere Wirkungsstärke bei gleicher Aufwandmenge, die Kontrolle bislang nicht erfasster Arten (Lücken), eine Ausdehnung des Anwendungszeitraums und/oder eine Reduzierung der Anzahl notwendiger Einzelanwendungen und - als Resultat für den Anwender - ökonomisch und ökologisch vorteilhaftere Unkrautbekämpfungssysteme.In a preferred embodiment, the herbicide combinations according to the invention have synergistic effects. The synergistic effects can be observed, for example, when the active ingredients (A), (B) and (C) are applied together, but they can often also be found when the active ingredients are applied at different times (splitting application). It is also possible to use the individual herbicides or the herbicide combinations in several portions (sequence application), e.g. B. Pre-emergence applications, followed by post-emergence applications or early post-emergence applications, followed by mid or late post-emergence applications. Preferred is the simultaneous or prompt application of the active compounds of the herbicide combination according to the invention. The synergistic effects allow a reduction in the application rates of the individual active ingredients, a higher potency with the same application rate, the control of previously unrecognized species (gaps), an extension of the application period and / or a reduction in the number of necessary individual applications and - as a result for the user - economically and more environmentally friendly weed control systems.
Die genannten Formeln (I), (II) und (III) umfassen alle Stereoisomeren und deren Gemische, insbesondere auch racemische Gemische, und - soweit Enantiomere möglich sind - die jeweils biologisch wirksamen Enantiomere. Verbindungen der Formel (I) und (III) und ihre Salze sowie ihre Herstellung sind z.B. beschrieben in EP-A-053011 und US 5,534,486. Verbindungen der Formel (II) und deren Salze und Ester sowie deren Herstellung sind z.B. beschrieben in US 3,397,054.The formulas (I), (II) and (III) mentioned comprise all stereoisomers and their mixtures, in particular also racemic mixtures, and - if enantiomers are possible - the biologically active enantiomers in each case. Compounds of formula (I) and (III) and their salts and their preparation are e.g. described in EP-A-053011 and US 5,534,486. Compounds of formula (II) and their salts and esters and their preparation are e.g. described in US 3,397,054.
Eine bevorzugte Verbindung der Formel (I) und deren Salze ist Diflufenican (A1) (siehe z.B. Pesticide Manual, 10. Aufl. 1994, S. 335-336). Bevorzugte Verbindungen der Formel (II) sind loxynil und dessen Salze und Ester (siehe z.B. 4-Hydroxy-3,5-di- iodobenzonitril, Pesticide Manual, 10. Aufl. 1994, S. 598-600), insbesondere Metallsalze wie Alkalisalze und Carbonsäureester wie C4-C-ι0-Carbonsäureester, z.B., loxynil (B1), loxynil-octanoat (B2), loxynil-Natrium (B3) und loxynil-Kalium (B4). Bevorzugte Verbindungen der Formel (III) und deren Salze sind Methyl 2-({[(4- methyl-5-oxo-3-propoxy-4,5-dihydro-1 H-1 ,2,4-triazol-1- yl)carbonyl]amino}sulfonyl)benzoat (Propoxycarbazone, C1) und dessen Salze wie das Natriumsalz (Propoxycarbazone-Natrium, C2) (siehe z.B. US 5,534,486 und Z. PfIKrankh. PflSchutz, Sonderh. XVII, 545-553 (2000)).A preferred compound of the formula (I) and its salts is diflufenican (A1) (see, for example, Pesticide Manual, 10th edition 1994, pp. 335-336). Preferred compounds of the formula (II) are loxynil and its salts and esters (see, for example, 4-hydroxy-3,5-diiodobenzonitrile, Pesticide Manual, 10th edition 1994, pp. 598-600), in particular metal salts such as alkali metal salts and Carbonsäureester such as C4-ι 0 carboxylic acid esters, for example, ioxynil (B1), ioxynil octanoate, (B2), ioxynil-sodium (B3) and ioxynil-potassium (B4). Preferred compounds of the formula (III) and their salts are methyl 2 - ({[(4-methyl-5-oxo-3-propoxy-4,5-dihydro-1 H-1, 2,4-triazol-1-yl ) carbonyl] amino} sulfonyl) benzoate (propoxycarbazone, C1) and its salts such as the sodium salt (propoxycarbazone sodium, C2) (see, for example, US 5,534,486 and Z. PfIKrankh. PflSchutz, Sonderh. XVII, 545-553 (2000)).
Die Aufwandmenge der Wirkstoffe der Formel (I), (II) und (III) und deren Salzen kann in weiten Bereichen variieren, beispielsweise zwischen 0,001 und 2,5 kg AS/ha. Soweit in dieser Beschreibung die Abkürzung AS/ha verwendet wird, bedeutet dies „Aktivsubstanz pro Hektar", bezogen auf 100%igen Wirkstoff. Bei Anwendungen mit Aufwandmengen von 0,01 bis 1 ,5 kg AS/ha der Wirkstoffe A, B und C, vorzugsweise der Wirkstoffe (A1) + (B1) + (C2) und (A1) + (B2) + (C2), wird im Vor- und Nachauflaufverfahren ein relativ breites Spektrum an annuellen und perennierenden Unkräutern, Ungräsern sowie Cyperaceen bekämpft. Bei den erfindungsgemäßen Kombinationen liegen die Aufwandmengen in der Regel niedriger, z. B. im Bereich von 0,1 bis 900 g AS/ha, vorzugsweise 0,5 bis 750 g AS/ha.The application rate of the active compounds of the formulas (I), (II) and (III) and their salts can vary within wide limits, for example between 0.001 and 2.5 kg of AS / ha. Insofar as the abbreviation AS / ha is used in this description, this means “active substance per hectare”, based on 100% active ingredient. For applications with application rates of 0.01 to 1.5 kg AS / ha of active ingredients A, B and C, preferably the active ingredients (A1) + (B1) + (C2) and (A1) + (B2) + (C2), a relatively broad spectrum of annual and perennial weeds, grass weeds and cyperaceae is combated in the pre- and post-emergence process , In the combinations according to the invention, the application rates are generally lower, for. B. in the range of 0.1 to 900 g ai / ha, preferably 0.5 to 750 g ai / ha.
Die Wirkstoffe können z.B. als wasserlösliches Spritzpulver (WP), wasserdispergierbares Granulat (WDG), wasseremulgierbares Granulat (WEG), Suspoemulsion (SE) oder Oldispersionskonzentrat (z.B. Olsuspensionskonzentrat) (OD) formuliert werden.The active ingredients can e.g. as water-soluble wettable powder (WP), water-dispersible granulate (WDG), water-emulsifiable granulate (WEG), suspoemulsion (SE) or old dispersion concentrate (e.g. oil suspension concentrate) (OD).
Das Gewichtsverhältnis der Komponenten (A) und (B) zueinander beträgt dabei im allgemeinen 50 : 1 - 1 : 100, vorzugsweise 25 : 1 - 1 : 25. Das Gewichtsverhältnis (A + B) : C beträgt im allgemeinen 3000 : 1 - 1 : 10, vorzugsweise 800 : 1 - 1 : 5.The weight ratio of components (A) and (B) to one another is generally 50: 1-1: 100, preferably 25: 1-1: 25. The weight ratio (A + B): C is generally 3000: 1-1 : 10, preferably 800: 1 - 1: 5.
Zur Anwendung der Wirkstoffe (A), (B) und (C) in Pflanzenkulturen kann es je nach Pflanzenkultur zweckmäßig sein, ab bestimmter Aufwandmengen einen Safener zu applizieren, um eventuelle Schäden an der Kulturpflanze zu reduzieren oder zu vermeiden. Geeignete Safener sind z.B. aus WO-A-96/14747 und der dort zitierten Literatur bekannt.For the use of active ingredients (A), (B) and (C) in plant crops, depending on the crop, it may be appropriate to apply a safener above certain application rates in order to reduce or avoid possible damage to the crop. Suitable safeners are e.g. known from WO-A-96/14747 and the literature cited therein.
Folgende Gruppen von Verbindungen sind beispielsweise als Safener für die oben erwähnten herbiziden Wirkstoffe (A), (B) und (C) geeignet: a) Verbindungen vom Typ der Dichlorphenylpyrazolin-3-carbonsäure (S1), vorzugsweise Verbindungen wie 1-(2,4-Dichlorphenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazolin-3- carbonsäureethylester (S1-1 , Mefenpyr-diethyl, PM, S 594-595), und " verwandte"Verbindungen wie sie z.B. in der WO 91/07874 und PM (S.594- 595) beschrieben sind, b) Derivate der Dichlorphenylpyrazolcarbonsäure, vorzugsweise Verbindungen wie 1-(2,4-Dichlorphenyl)-5-methyI-pyrazol-3-carbonsäureethylester (S1-2), 1-(2,4-DichlorphenyI)-5-isopropyl-pyrazol-3-carbonsäureethylester (S1-3), 1-(2,4-Dichlorphenyl)-5-(1 ,1-dimethyl-ethyl)pyrazol-3-carbonsäureethyl-ester (S1-4), 1-(2,4-Dichlorphenyl)-5-phenyl-pyrazol-3-carbonsäureethylester (S1-5) und verwandte Verbindungen, wie sie in EP-A-333 131 und EP-A-269 806 beschrieben sind. c) Verbindungen vom Typ der Triazolcarbonsäuren (S1), vorzugsweise Verbindungen wie Fenchlorazol, d.h. 1-(2,4-Dichlorphenyl)-5-trichlormethyl-(1 H)-1 ,2,4-triazol-3- carbonsäureethylester (S1-6), und verwandte Verbindungen (siehe EP-A-174 562 und EP-A-346 620); d) Verbindungen vom Typ der 5-Benzyl- oder 5-Phenyl-2-isoxazolin-3- carbonsäure, oder der 5,5-Diphenyl-2-isoxazolin-3-carbonsäure vorzugsweise Verbindungen wie 5-(2,4-Dichlorbenzyl)-2-isoxazolin-3-carbonsäureethylester (S1-7) oder 5-Phenyl-2-isoxazolin-3-carbonsäureethylester (S1-8) und verwandte Verbindungen, wie sie z.B. in WO 91/08202 beschrieben sind, bzw. der 5,5-Diphenyl-2-isoxazolin-3-carbonsäure und deren Ethylester (S1- 9, Isoxadifen-ethyl) oder -n-Propylester (S1-10) oder der 5-(4-Fluorphenyl)-5- phenyl-2-isoxazolin-3-carbonsäureethylester (S1-11), wie sie in der Patentanmeldung (WO-A-95/07897) beschrieben sind. e) Verbindungen vom Typ der 8-Chinolinoxyessigsäure (S2), vorzugsweise (5-ChIor-8-chinolinoxy)-essigsäure-(1 -methyl-hex-1 -yl)-ester (S2-1 , Cloquintocet-mexyl, z.B. PM, S. 195-196), (5-Chlor-8-chinolinoxy)-essigsäure- (1 ,3-dimethyl-but-1-yl)-ester (S2-2), (5-Chlor-8-chinolinoxy)-essigsäure-4-allyl-oxy-butylester (S2-3), (5-Chlor-8-chinolinoxy)-essigsäure-1 -allyloxy-prop-2-ylester (S2-4), (5-Chlor-8-chinolinoxy)-essigsäureethylester (S2-5), (5-Chlor-8-chinolinoxy)-essigsäuremethylester.(S2-6), (5-Chlor-8-chinolinoxy)-essigsäureallylester (S2-7), (5-Chlor-8-crrinolinoxy)-essigsäύre-2-(2-propyliden-'πτiirιoxy)-1- - ethylester (S2-8), (5-ChIor-8-chinolinoxy)-essigsäure-2-oxo-prop-1 -ylester (S2-9) und verwandte Verbindungen, wie sie in EP-A-86 750, EP-A-94 349 und EP-A-191 736 oder EP-A-0 492 366 beschrieben sind. f) Verbindungen vom Typ der (5-Chlor-8-chinolinoxy)-malonsäure, vorzugsweise Verbindungen wie (5-Chlor-8-chinolinoxy)-maIonsäure- diethylester, (5-Chlor-8-chinolinoxy)-malonsäurediallylester, (5-Chlor-8-chinolinoxy)-malonsäure-methyl-ethylester und verwandte Verbindungen, wie sie in EP-A-0 582 198 beschrieben sind. g) Wirkstoffe vom Typ der Phenoxyessig- bzw. -propionsäurederivate bzw. der aromatischen Carbonsäuren, wie z.B. 2,4-Dichlorphenoxyessigsäure(ester) (2,4-D), 4-Chlor-2-methyl-phenoxy-propionester (Mecoprop), MCPA oder 3,6-Dichlor-2-methoxy-benzoesäure(ester) (Dicamba). h) Wirkstoffe vom Typ der Pyrimidine, wie „Fenclorim" (PM, S. 386-387) (= 4,6- Dichlor-2-phenylpyrimidin), i) Wirkstoffe vom Typ der Dichloracetamide, die häufig als Vorauflaufsafener (bodenwirksame Safener) angewendet werden, wie z.B. „Dichlormid" (PM, S. 270-271 ) (= N,N-Dia!lyl-2,2-dichloracetamid), AR-29148" (= 3-Dichloracetyl-2,2,5-trimethyl-1 ,3-oxazolidon von der Firma Stauffer), „Benoxacor" (PM, S. 74-75) (= 4-Dichloracetyl-3,4-dihydro-3-methyl-2H-1 ,4- benzoxazin). APPG-1292" (= N-Allyl-N[(1 ,3-dioxolan-2-yl)-methyl]dichloracetamid von der Firma PPG Industries), ADK-24" (= N-Allyl-N-[(allylaminocarbonyl)-methyl]-dichloracetamid von der Firma Sagro-Chem), AAD-67" oder AMON 4660" (= 3-DichIoracetyl-1-oxa-3-aza-spiro[4,5]decan von der Firma Nitrokemia bzw. Monsanto), „Dicionon" oder ABAS 145138" oder ALAB145138" (= (= 3-Dichloracetyl-2,5,5- trimethyl-1 ,3-diazabiclyco[4.3.0]nonan von der Firma BASF) und „Furilazol" oder AMON 13900" (siehe PM, S. 482-483) (= (RS)-3- Dichloracetyl-5-(2-fuιyl)-2,2-dirπethyloxazolidon) - . - - j) Wirkstoffe vom Typ der Dichloracetonderivate, wie z.B. AMG 191" (CAS-Reg. Nr. 96420-72-3) (= 2-Dichlormethyl-2-methyl-1 ,3- dioxolan von der Firma Nitrokemia), k) Wirkstoffe vom Typ der Oxyimino-Verbindungen, die als Saatbeizmittel bekannt sind, wie z.B. „Oxabetrinil" (PM, S. 689) (= (Z)-1 ,3-DioxoIan-2- ylmethoxyimino(phenyl)acetonitril), das als Saatbeiz-Safener gegen Schäden von Metolachlor bekannt ist, „Fluxofenim" (PM, S. 467-468) (= 1-(4-Chlorphenyl)-2,2,2-trifluor-1-ethanon- 0-(1 ,3-dioxolan-2-ylmethyl)-oxim, das als Saatbeiz-Safener gegen Schäden von Metolachlor bekannt ist, und „Cyometrinil" oder A-CGA-43089" (PM, S. 983) (= (Z)-Cyanomethoxyimino (phenyl)acetonitril), das als Saatbeiz-Safener gegen Schäden von Metolachlor bekannt ist, I) Wirkstoffe vom Typ der Thiazolcarbonsäureester, die als Saatbeizmittel bekannt sind, wie z.B. „Flurazol" (PM, S. 450-451) (= 2-Chlor-4-trifluormethyl-1 ,3-thiazol-5- carbonsäurebenzylester), das als Saatbeiz-Safener gegen Schäden von Alachlor und Metolachlor bekannt ist, m) Wirkstoffe vom Typ der Napthalindicarbonsäurederivate, die als Saatbeizmittel bekannt sind, wie z.B. „Naphthalic anhydrid" (PM, S. 1009-1010) (= 1 ,8- Naphthalindicarbonsäureanhydrid), das als Saatbeiz-Safener für Mais gegen Schäden von Thiocarbamatherbiziden bekannt ist, n) Wirkstoffe vom Typ Chromanessigsäurederivate, wie z.B. ACL 304415" (CAS-Reg. Nr. 31541-57-8) (= 2-84-Carboxy-chroman-4-yl)- essigsäure von der Firma American Cyanamid), o) Wirkstoffe, die neben einer herbiziden Wirkung gegen Schadpflanzen auch Safenerwirkung an Kulturpflanzen aufweisen, wie z.B. „Dimepiperate" oder AMY-93" (PM, S. 302-303) (= Piperidin-1- thiocarbonsäure-S-1 -methyl-1 -phenylethylester), „Daimurörϊ"iOderASK -?3"-(PM, S. 247) (= 1-(1 -Methyl-1 -phenylethyl)-3-p-tolyl- harnstoff), „Cumyluron" = AJC-940" (= 3-(2-Chlorphenylmethyl)-1-(1 -methyl-1 -phenyl- ethyl)-harnstoff, siehe JP-A-60087254), „Methoxyphenon" oder ANK 049" (= 3,3'-Dimethyl-4-methoxy- benzophenon), „CSB" (= 1-Brom-4-(chlormethylsulfonyl)-benzol) (CAS-Reg. Nr. 54091-06-4 von Kumiäi). 5 Die Herbizide (A), (B) und (C) sind, gegebenenfalls in Gegenwart von Safenern zur Bekämpfung von Schadpflanzen in Pflanzenkulturen geeignet, beispielsweise in wirtschaftlich bedeutenden Kulturen wie Getreide (z.B. Weizen, Gerste, Roggen, Hafer, Reis, Mais, Hirse), Zuckerrübe, Zuckerrohr, Raps, Baumwolle und Soja. Von 10 besonderem Interesse ist dabei die Anwendung in monokotylen Kulturen wie Getreide, insbesondere Weizen, Gerste, Roggen, Hafer, Kreuzungen davon wie Triticale, Reis, Mais und Hirse. Für die Kombinationen (A)+(B)+(C) sind diese Kulturen ebenfalls bevorzugt.The following groups of compounds are suitable, for example, as safeners for the herbicidal active ingredients (A), (B) and (C) mentioned above: a) compounds of the dichlorophenylpyrazoline-3-carboxylic acid (S1) type, preferably compounds such as 1- (2, 4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylic acid ethyl ester (S1-1, mefenpyr-diethyl, PM, S 594-595), and " related " compounds as described, for example, in WO 91/07874 and PM (pp. 594-595) are described, b) derivatives of dichlorophenylpyrazole carboxylic acid, preferably compounds such as ethyl 1- (2,4-dichlorophenyl) -5-methyl-pyrazole-3-carboxylate (S1-2), 1- (2,4-dichlorophenyl) -5-isopropyl-pyrazole-3-carboxylic acid ethyl ester (S1-3), 1- (2,4-dichlorophenyl) -5- (1, 1-dimethyl-ethyl) pyrazole-3- ethyl carboxylate (S1-4), 1- (2,4-dichlorophenyl) -5-phenyl-pyrazole-3-carboxylic acid ethyl ester (S1-5) and related compounds as described in EP-A-333 131 and EP-A -269 806 are described. c) Compounds of the triazole carboxylic acid (S1) type, preferably compounds such as fenchlorazole, ie 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1 H) -1, 2,4-triazole-3-carboxylic acid ethyl ester (S1- 6), and related compounds (see EP-A-174 562 and EP-A-346 620); d) Compounds of the 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid type, or the 5,5-diphenyl-2-isoxazoline-3-carboxylic acid, preferably compounds such as 5- (2,4-dichlorobenzyl) -2-isoxazoline-3-carboxylic acid ethyl ester (S1-7) or 5-phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1-8) and related compounds, as described for example in WO 91/08202, or the 5, 5-Diphenyl-2-isoxazoline-3-carboxylic acid and its ethyl ester (S1- 9, isoxadifen-ethyl) or -n-propyl ester (S1-10) or the 5- (4-fluorophenyl) -5-phenyl-2-isoxazoline -3-carboxylic acid ethyl ester (S1-11), as described in the patent application (WO-A-95/07897). e) Compounds of the 8-quinolinoxyacetic acid (S2) type, preferably (5-chloro-8-quinolinoxy) acetic acid (1-methyl-hex-1-yl) ester (S2-1, cloquintocet-mexyl, for example PM , Pp. 195-196), (5-chloro-8-quinolinoxy) acetic acid (1,3-dimethyl-but-1-yl) ester (S2-2), (5-chloro-8-quinolinoxy) 4-allyl-oxy-butyl acetate (S2-3), (5-chloro-8-quinolinoxy) -1-allyloxy-prop-2-yl ester (S2-4), (5-chloro-8- quinolinoxy) -acetic acid ethyl ester (S2-5), (5-chloro-8-quinolinoxy) -acetic acid methyl ester. (S2-6), (5-chloro-8-quinolinoxy) -acetic acid allyl ester (S2-7), (5-chloro 8-crrinolinoxy) -acetic acid-2- (2-propylidene- ' πτiirιoxy) -1- - ethyl ester (S2-8), (5-chloro-8-quinolinoxy) -acetic acid-2-oxo-prop-1-ethyl ester ( S2-9) and related compounds as described in EP-A-86 750, EP-A-94 349 and EP-A-191 736 or EP-A-0 492 366. f) Compounds of the (5-chloro-8-quinolinoxy) malonic acid type, preferably compounds such as (5-chloro-8-quinolinoxy) malonic acid diethyl ester, (5-chloro-8-quinolinoxy) malonic acid diallyl ester, (5- Chloro-8-quinolinoxy) -malonic acid methyl ethyl ester and related compounds as described in EP-A-0 582 198. g) active substances of the phenoxyacetic or propionic acid derivative or aromatic carboxylic acid type, such as, for example, 2,4-dichlorophenoxyacetic acid (ester) (2,4-D), 4-chloro-2-methylphenoxy-propionester (mecoprop) , MCPA or 3,6-dichloro-2-methoxy-benzoic acid (ester) (Dicamba). h) Active substances of the pyrimidine type, such as "Fenclorim" (PM, pp. 386-387) (= 4,6-dichloro-2-phenylpyrimidine), i) Active substances of the dichloroacetamide type, which are often used as pre-emergence safeners (soil-acting safeners) can be used, such as "dichlormid" (PM, p. 270-271) (= N, N-dialyl-2,2-dichloroacetamide), AR-29148 "(= 3-dichloroacetyl-2,2,5- trimethyl-1,3-oxazolidone from Stauffer), "Benoxacor" (PM, p. 74-75) (= 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine). APPG-1292 "(= N-allyl-N [(1,3-dioxolan-2-yl) methyl] dichloroacetamide from PPG Industries), ADK-24" (= N-allyl-N - [(allylaminocarbonyl) -methyl] -dichloroacetamide from Sagro-Chem), AAD-67 "or AMON 4660" (= 3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane from Nitrokemia or Monsanto) , "Dicionon" or ABAS 145138 "or ALAB145138" (= (= 3-dichloroacetyl-2,5,5-trimethyl-1, 3-diazabiclyco [4.3.0] nonane from BASF) and "Furilazole" or AMON 13900 "(see PM, pp. 482-483) (= (RS) -3-dichloroacetyl-5- (2-fuιyl) -2,2-dirπethyloxazolidon) -. - - j) Active substances of the dichloroacetone derivative type, such as AMG 191 "(CAS Reg. No. 96420-72-3) (= 2-dichloromethyl-2-methyl-1,3-dioxolane from Nitrokemia), k) Active compounds of the oxyimino compound type which are known as seed dressings, such as, for example, “oxabetrinil” (PM, p. 689) (= (Z) -1, 3-dioxolan-2-ylmethoxyimino (phenyl) acetonitrile), that known as a seed dressing safener against damage to metolachlor, “fluxofenim” (PM, pp. 467-468) (= 1- (4-chlorophenyl) -2,2,2-trifluoro-1-ethanone-0- (1, 3-dioxolan-2-ylmethyl) -oxime, which is known as a seed dressing safener against damage to metolachlor, and "Cyometrinil" or A-CGA-43089 "(PM, p. 983) (= (Z) -cyanomethoxyimino (phenyl ) acetonitrile), which is known as a seed dressing safener against damage to metolachlor, I) active substances of the thiazolecarboxylic acid ester type which are known as seed dressings, such as, for example, “flurazole” (PM, pp. 450-451) (= 2-chloro 4-trifluoromethyl-1, 3-thiazole-5-carboxylic acid benzyl ester), which is known as a seed dressing safener against damage to alachlor and metolachlor, m) active substances of the type of naphthalenedicarboxylic acid derivatives, which are known as seed dressings, such as, for example, “Naphthalic anhy drid "(PM, pp. 1009-1010) (= 1, 8-naphthalenedicarboxylic acid anhydride), which is known as a seed dressing safener for maize against damage to thiocarbamate herbicides, n) active compounds of the chromanacetic acid derivative type, such as, for example, ACL 304415" (CAS-Reg , No. 31541-57-8) (= 2-84-carboxy-chroman-4-yl) - acetic acid from American Cyanamid), o) active substances which, in addition to a herbicidal action against harmful plants, also have a safener effect on crop plants, such as, for example "Dimepiperate" or AMY-93 "(PM, pp. 302-303) (= piperidine-1-thiocarboxylic acid S-1-methyl-1-phenylethyl ester)," Daimurörϊ " i OderASK -? 3" - (PM, S . 247) (= 1- (1-methyl-1-phenylethyl) -3-p-tolylurea), "cumyluron" = AJC-940 "(= 3- (2-chlorophenylmethyl) -1- (1-methyl -1-phenyl-ethyl) -urea, see JP-A-60087254), "Methoxyphenon" or ANK 049 "(= 3,3'-dimethyl-4-methoxybenzophenone)," COD "(= 1-bromo-4- (chloromethylsulfonyl) benzene) (CAS Reg. No. 54091-06 -4 by Kumiäi) 5 The herbicides (A), (B) and (C) are suitable, if appropriate in the presence of safeners, for combating harmful plants in crops, for example in economically important crops such as cereals (for example wheat, barley, rye, Oats, rice, maize, millet), sugar beet, sugar cane, rapeseed, cotton and soybeans, of particular interest being the use in monocotyledon crops such as cereals, in particular wheat, barley, rye, oats, and crosses thereof such as triticale, rice, corn and millet These combinations are also preferred for the combinations (A) + (B) + (C).
15 Erfindungsgemäß umfasst sind auch solche Herbizid- Kombinationen, die neben den Komponenten (A), (B) und (C) noch ein oder mehrere weitere agrochemische Wirkstoffe anderer Struktur enthalten, wie Herbizide, Insektizide, Fungizide oder Safener, bevorzugt Herbizide. Für solche Kombinationen gelten die insbesondere für erfindungsgemäße Kombinationen (A) + (B) + (C) erläuterten bevorzugtenThe invention also includes those herbicide combinations which, in addition to components (A), (B) and (C), also comprise one or more further agrochemical active compounds of another structure, such as herbicides, insecticides, fungicides or safeners, preferably herbicides. The preferred ones explained in particular for combinations according to the invention (A) + (B) + (C) apply to such combinations
20 Bedingungen in erster Linie ebenfalls, sofern darin die erfindungsgemäßen Kombinationen (A) + (B) + (C) enthalten sind und bezüglich der betreffenden Kombination (A) + (B) + (C).20 First and foremost also conditions, provided that the combinations (A) + (B) + (C) according to the invention are included and with regard to the combination (A) + (B) + (C).
Beispiele für bevorzugte weitere Herbizide sind Herbizide der Gruppe (D), der 25 selektiv in einigen monokotylen Kulturen gegen monokotyle und/oder dikotyle Schadpflanzen wirksamen Herbizide aus der Gruppe der Verbindungen, bestehend aus (Angabe mit dem "common name" und einer Referenzstelle, z.B. aus "The Pesticide Manual" 12th Ed., British Crop Protection Council 2000, abgekürzt "PM" ~^^~ oder aus" "Th-rPesticide Manual" 10. Auflage 1994, British Crop Protection Council) - 30 (D1) lodosulfuron, insbesondere auch umfassend dessen Salze und Ester, z.B. 3-(4-Methoxy-6-methyI-1 ,3,5-triazin-2-yl)-1-(2-methoxycarbonyl-5-iod-phenyl- sulfonyl)-harnstoff (lodosulfuron-methyl) und dessen Salze wie das Natriumsalz (lodosulfuron-methyl-Natrium) (siehe z.B. WO 92/13845 und PM, S. 547-548), (Aufwandmenge im allgemeinen: 0,5 - 200 gAS/ha, vorzugsweise 1 - 100 gAS/ha) (D2) Imazamox, insbesondere auch umfassend dessen Ester und Salze wie das Natriumsalz (PM, S. 528), z.B. (RS)-2-(4-isopropyl-4-methyl-5-oxo-2- imidazolin-2-yl)-5-methoxymethylnicotinsäure, (Aufwandmenge im allgemeinen: 1 - 500 g AS/ha, vorzugsweise 2 - 200 g AS/ha), (D3) Florasulam, insbesondere auch umfassend dessen Salze wie das Natriumsalz (PM, S. 420 - 421), z.B. 2',6',8,-Trifluoro-5- methoxy[1 ,2,4]triazolo[1 ,5-c]pyrimidin-2-sulfonaniIid, (Aufwandmenge im allgemeinen: 1 - 500 g AS/ha, vorzugsweise 1 - 50 g AS/ha), (D4) Halosulfuron, insbesondere auch umfassend dessen Ester wie Halosulfuron- methyl und dessen Salze wie das Natriumsalz (PM, S. 497-499), z.B. Methyl 3-chloro-5-(4,6-dimethoxypyrimidin-2-ylcarbamoylsulfamoyl)-1- methylpyrazol-4-carboxylat, (Aufwandmenge im allgemeinen: 1 - 500 g AS/ha, vorzugsweise 5 - 200 g AS/ha), (D5) Tritosulfuron, insbesondere auch umfassend dessen Ester und Salze wie das Natriumsalz (AG Chem, New Compound Review (publ. Agranova), Vol. 17, 1999, S. 24), z.B. N-[[[4'-Methoxy-6-(trifluoromethyl)-1 ,3,5-triazin-2- yl]amino]carbonyl]-2-trifluoromethyIbenzolsulfonamid), (Aufwandmenge im allgemeinen: 1 - 500 g AS/ha, vorzugsweise 5 - 200 g AS/ha), (D6) Picolinafen, insbesondere auch umfassend dessen Salze wie das Natriumsalz (PM, S. 742 - 743), z.B. 4'-Fluoro-6-[(α,α,α-trifluoro-m- tolyl)oxy]picolinanilid; (Aufwandmenge im allgemeinen: 1 - 500 g AS/ha, vorzugsweise 5 - 200 g AS/ha),Examples of preferred further herbicides are herbicides from group (D), the herbicides from the group of the compounds consisting of (indication with the "common name" and a reference point, eg., Selectively in some monocotyledon crops against monocotyledon and / or dicotyledonous harmful plants) from "The Pesticide Manual" 12th Ed., British Crop Protection Council 2000, abbreviated "PM" ~ ^ ^ ~ or from "" Th-rPesticide Manual "10th edition 1994, British Crop Protection Council) - 30 (D1) iodosulfuron, in particular also comprising its salts and esters, for example 3- (4-methoxy-6-methyl-1, 3,5-triazin-2-yl) -1- (2-methoxycarbonyl-5-iodophenylsulfonyl) urea (iodosulfuron-methyl) and its salts like that Sodium salt (iodosulfuron-methyl-sodium) (see, for example, WO 92/13845 and PM, pp. 547-548), (application rate in general: 0.5-200 gAS / ha, preferably 1-100 gAS / ha) (D2) Imazamox, in particular also comprising its esters and salts such as the sodium salt (PM, p. 528), for example (RS) -2- (4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl) -5 -methoxymethylnicotinic acid, (application rate in general: 1 - 500 g ai / ha, preferably 2 - 200 g ai / ha), (D3) florasulam, in particular also comprising its salts such as the sodium salt (PM, pp. 420 - 421), for example 2 ', 6', 8 , -trifluoro-5-methoxy [1, 2,4] triazolo [1, 5-c] pyrimidine-2-sulfonanide, (application rate in general: 1 - 500 g ai / ha, preferably 1 - 50 g ai / ha), (D4) halosulfuron, in particular also comprising its esters such as halosulfuron-methyl and its salts such as the sodium salt (PM, pp. 497-499), for example methyl 3-chloro-5- (4,6 -dimethoxypyrimidin-2-ylcarbamoylsulfamoyl) -1- methylpyrazole-4-carboxylate, (application rate in general: 1 - 500 g ai / ha, preferably 5 - 200 g ai / ha), (D5) tritosulfuron, especially including its esters and salts such as the sodium salt (AG Chem, New Compound Review (publ. Agranova), Vol. 17, 1999, p. 24), for example N - [[[4'-methoxy-6- (trifluoromethyl) -1, 3,5-triazin-2-yl] amino] carbonyl] -2- trifluoromethyIbenzenesulfonamid), (application rate in general: 1 - 500 g ai / ha, preferably 5 - 200 g ai / ha), (D6) picolinafen, in particular also comprising its salts such as the sodium salt (PM, p. 742 - 743), for example 4'-fluoro-6 - [(α, α, α-trifluoro-m-tolyl) oxy] picolin anilide; (Application rate in general: 1 - 500 g ai / ha, preferably 5 - 200 g ai / ha),
(D7) Cinidon-ethyl, insbesondere auch umfassend dessen Salze wie das Natriumsalz (PM, S. 181-182), z.B. Ethyl (Z)-2-chloro-3-[2-chloro-5-(1 ,2- cyclohex-1-enedicarboximido)phenyl]acryIat, (Aufwandmenge im altgefneinen: " ~- 500 g ÄS/ha, "vorzugsweise 5 - 20CTg AS/ha), ~ (D8) Mesotrione (PM, S. 602), z.B. 2-(4-(Mesyl-2-nitrobenzoyl)cyclohexan-1 ,3- dion, (Aufwandmenge im allgemeinen: 5 - 1000 g AS/ha, vorzugsweise 20 - 600 g AS/ha), (D9) Metosulam, insbesondere auch umfassend dessen Salze wie das Natriumsalz (PM, S. 640-641), z.B. 2',6'-Dichloro-5,7-dimethoxy-3'- methyl[1 ,2,4]triazolo[1 ,5-a]pyrimidin-2-sulfonanilid, (Aufwandmenge im allgemeinen: 1 - 500 g AS/ha, vorzugsweise 10 - 300 g AS/ha), (D10) Clopyralid, insbesondere auch umfassend dessen Ester und Salze wie das Natriumsalz (PM, S. 193-194), z.B. 3,6-Dichloropyridin-2-carbonsäure, (Aufwandmenge im allgemeinen: 10 - 1000 g AS/ha, vorzugsweise 20 - 800 g AS/ha),(D7) cinidon-ethyl, in particular also comprising its salts such as the sodium salt (PM, pp. 181-182), for example ethyl (Z) -2-chloro-3- [2-chloro-5- (1,2-cyclohex -1-enedicarboximido) phenyl] acryIate, (application rate in the old fine: " ~ - 500 g AS / ha, " preferably 5 - 20CTg AS / ha), ~ (D8) mesotrione (PM, p. 602), e.g. 2- ( 4- (mesyl-2-nitrobenzoyl) cyclohexane-1,3-dione, (application rate in general: 5-1000 g ai / ha, preferably 20-600 g ai / ha), (D9) Metosulam, in particular also comprising its salts such as the sodium salt (PM, pp. 640-641), for example 2 ', 6'-dichloro-5,7-dimethoxy-3'-methyl [1, 2,4] triazolo [1, 5-a] pyrimidine-2-sulfonanilide, (application rate in general: 1 - 500 g ai / ha, preferably 10 - 300 g ai / ha), (D10) clopyralid, in particular also comprising its esters and salts such as that Sodium salt (PM, pp. 193-194), e.g. 3,6-dichloropyridine-2-carboxylic acid, (application rate in general: 10 - 1000 g ai / ha, preferably 20 - 800 g ai / ha),
(D11) Flufenacet, insbesondere auch umfassend dessen Salze wie das Natriumsalz (PM, S. 434-435), z.B. 4'-Fluoro-N-isopropyl-2-(5- trifluoromethyl-1 ,3,4-thiadiazol-2-yloxy)acetanilid, (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 150 - 2000 g AS/ha),(D11) flufenacet, in particular also comprising its salts such as the sodium salt (PM, pp. 434-435), e.g. 4'-fluoro-N-isopropyl-2- (5-trifluoromethyl-1, 3,4-thiadiazol-2-yloxy) acetanilide, (application rate in general: 50-5000 g ai / ha, preferably 150-2000 g ai / Ha),
(D12) Flumetsulam, insbesondere auch umfassend dessen Salze wie das Natriumsalz (PM, S. 438-439), z.B. 2',6'-Difluoro-5-methyl[1 ,2,4]triazolo[1 ,5- a]pyrimidin-2-sulfonanilid, (Aufwandmenge im allgemeinen: 5 - 1000 g AS/ha, vorzugsweise 10 - 600 g AS/ha),(D12) flumetsulam, in particular also comprising its salts such as the sodium salt (PM, pp. 438-439), e.g. 2 ', 6'-difluoro-5-methyl [1, 2,4] triazolo [1,5-a] pyrimidine-2-sulfonanilide, (application rate in general: 5-1000 g ai / ha, preferably 10-600 g AS / ha)
(D13) Flupoxam, insbesondere auch umfassend dessen Salze wie das Natriumsalz (PM, S. 999), z.B. 1-[4-Chloro-3-(2,2,3,3,3- pentafluoropropoxymethyl)phenyl]-5-phenyl-1 H-1 ,2,4-triazol-3-carboxamid, (Aufwandmenge im allgemeinen: 5 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha),(D13) flupoxam, in particular also comprising its salts such as the sodium salt (PM, p. 999), e.g. 1- [4-Chloro-3- (2,2,3,3,3-pentafluoropropoxymethyl) phenyl] -5-phenyl-1 H-1, 2,4-triazole-3-carboxamide, (application rate in general: 5 - 5000 g ai / ha, preferably 20 - 3000 g ai / ha),
(D14) Prosulfocarb, insbesondere auch umfassend dessen Salze (PM, S. 786- 787), z.B. S-Benzyl dipropylthiocarbamat, (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 200 - 3000 g AS/ha), (D15) Flurtamone, insbesondere auch umfassend dessen Salze wie das Natriumsalz (PM, S. 459), z.B. (RS)-5-Methylamino-2-phenyl-4-(α,α,α- trifluoro-m-tolyl)furan-3(2H)-on, (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 200 - 3000 g AS/ha),(D14) prosulfocarb, in particular also comprising its salts (PM, pp. 786-787), e.g. S-benzyl dipropylthiocarbamate, (application rate in general: 50-5000 g ai / ha, preferably 200-3000 g ai / ha), (D15) flurtamone, in particular also comprising its salts such as the sodium salt (PM, p. 459), e.g. (RS) -5-methylamino-2-phenyl-4- (α, α, α-trifluoro-m-tolyl) furan-3 (2H) -one, (application rate in general: 50-5000 g ai / ha, preferably 200 - 3000 g AS / ha),
(DI 6) Aclonifen, insbesondere aucffύmfassend~dessen Salze wie das Natriumsalz' (PM, S. 14-15), z.B. 2-Chloro-6-nitro-3-phenoxyanilin, (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 200 - 3000 g AS/ha),(DI 6) Aclonifen, in particular comprehensive ~ its salts such as the sodium salt '(PM, pp. 14-15), for example 2-chloro-6-nitro-3-phenoxyaniline, (application rate in general: 50 - 5000 g ai / ha , preferably 200 - 3000 g AS / ha),
(D17) Fenoxaprop, umfassend auch Fenoxaprop-P, z.B. (±) -2-[4-(6-Chlor-1 ,3- benzoxazol-2-yloxy)phenoxy]propionsäure, umfassend u.a. die Aufwendungsform als Fenoxaprop-ethyl (R)-2-[4-(6-Chlor-1 ,3-benzoxazol-2- yloxy)phenoxy]propionsäure, umfassend u.a. die häufigste Aufwendungsform Fenoxaprop-P-ethyl, wobei die vorgenannten Verbindungen C17) z.B. aus Pesticide Manual, 10. Aufl. 1994, S. 439-441 u. 441-442 bekannt sind, (Aufwandmenge im allgemeinen: 10 - 300 g AS/ha, vorzugsweise 15 - 200 g AS/ha), (D18) Isoproturon, z.B. 3-(4-lsopropylphenyl)-1 ,1-dimethylharnstoff Pesticide Manual, 10. Aufl. 1994, S. 611-612, (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 100 - 4000 g AS/ha),(D17) fenoxaprop, also including fenoxaprop-P, for example (±) -2- [4- (6-chloro-1, 3- benzoxazol-2-yloxy) phenoxy] propionic acid, including the formulation as fenoxaprop-ethyl (R) -2- [4- (6-chloro-1, 3-benzoxazol-2-yloxy) phenoxy] propionic acid, including the most common Application form Fenoxaprop-P-ethyl, the aforementioned compounds C17), for example from Pesticide Manual, 10th edition 1994, pp. 439-441 and. 441-442 are known (application rate in general: 10-300 g ai / ha, preferably 15-200 g ai / ha), (D18) isoproturon, for example 3- (4-isopropylphenyl) -1, 1-dimethylurea pesticide manual , 10th edition 1994, pp. 611-612, (application rate in general: 50 - 5000 g ai / ha, preferably 100 - 4000 g ai / ha),
(D19) Diclofop, z.B. (r?S)-2-[4-(2,4-Dichlorophenoxy)phenoxy]propionsäure umfassend u.a. als wichtigste Anwendungsform den Methylester, das Diclofop-methyl, Pesticide Manual, 10. Aufl. 1994, S. 315-317, (Aufwandmenge im allgemeinen: 100 - 3000 g AS/ha, vorzugsweise 200 - 2000 g AS/ha),(D19) diclofop, e.g. (r? S) -2- [4- (2,4-dichlorophenoxy) phenoxy] propionic acid including i.a. the most important form of use is the methyl ester, the diclofop-methyl, Pesticide Manual, 10th ed. 1994, pp. 315-317 (application rate in general: 100-3000 g ai / ha, preferably 200-2000 g ai / ha),
(D20) Clodinafop, z.B. (R)-2-[4-(5-Chlor-3-fluor-2-pyridyloxy)phenoxy]propionsäure umfassend insbesondere auch die Anwendungsform als Clodinafop- propargyl, Pesticide Manual, 10. Aufl. 1994, S. 216-217, (Aufwandmenge im allgemeinen: 1 - 150 g AS/ha, vorzugsweise 5 - 100 g AS/ha), (D21) Chlortoluron, z.B. 3-(3-Chlor-p-tolyl)-1,1-dimethylharnstoff, Pesticide Manual, 10. Aufl. 1994, S. 194-196, (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha), (D22) Methabenzthiazuron, z.B. 1-(1 ,3-Benzothiazol-2-yl)-1 ,3-dimethylharnstoff, Pesticide Manual, 10. Aufl. 1994, S. 670-671 , (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha),(D20) clodinafop, e.g. (R) -2- [4- (5-chloro-3-fluoro-2-pyridyloxy) phenoxy] propionic acid, in particular also comprising the use form as clodinafop-propargyl, Pesticide Manual, 10th edition 1994, pp. 216-217, (Application rate in general: 1 - 150 g ai / ha, preferably 5 - 100 g ai / ha), (D21) chlorotoluron, e.g. 3- (3-chloro-p-tolyl) -1,1-dimethylurea, Pesticide Manual, 10th ed. 1994, pp. 194-196, (application rate in general: 10 - 5000 g ai / ha, preferably 20 - 3000 g AS / ha), (D22) methabenzthiazuron, e.g. 1- (1, 3-Benzothiazol-2-yl) -1, 3-dimethylurea, Pesticide Manual, 10th ed. 1994, pp. 670-671, (application rate in general: 10 - 5000 g ai / ha, preferably 20 - 3000 g AS / ha),
(D23) Imazamethabenz, z.B. Reaktionsprodukt, aufweisend (±)-6-(4-lsopropyl-4-methyl-4-oxo-2- imidazolin-2-yl)-t?7-toluylsäure und (±)-6-(4-lsopropyl-4-methyl-4-oxo-2- imidazoliή-2-yl)-toluylsäure7 — wobei jeweils auch die Ester, z.B. die unter der Bezeichnung Imazamethabenz-methyl bekannten Methylester eingesetzt werden können, Pesticide Manual, 10. Aufl. 1994, S. 582-584, (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha), (D24) Tralkoxydim, z.B. 2-[1-(Ethoxyimino)propyl]-3-hydroxy-5-mesitylcyclohex-2- enon, Pesticide Manual, 10. Aufl. 1994, S. 995-996, (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha), 5 (D25) Difenzoquat, z.B. 1 ,2-Dimethyl-3,5-diphenyIpyrazolium z.B. auch als Difenzoquat-metilsulfat, Pesticide Manual, 10. Aufl. 1994, S. 330-331 , (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha), (D26) Flamprop, umfassend auch Flamprop-M , z.B. Λ/-Benzoyl-Λ/-(3-chlor-4- 0 fluorophenyl)-DL-alanin und Λ/-Benzoyl-/V-(3-chlor-4-fluorophenyI)-D-alanin, umfassend u.a. auch, Flamprop-methyl, Flamprop-M-methyl, Flamprop-M- isopropyl, Pesticide Manual, 10. Aufl. 1994, S. 464-465 und 466-468, (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha), 5 (D27) Pendimethalin, z.B. Λ/-(1-Ethylpropyl)-2,6-dinitro-3,4-xylidin, Pesticide Manual, 10. Aufl. 1994, S. 779-780, (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 100 - 3000 g AS/ha), (D28) Mecoprop, umfassend auch Mecoprop-P, z.B. (RS)-2-(4-Chlor-o- tolyloxy)propionsäure und (R)-2-(4-Chlor-o-tolyloxy)propionsäure, Pesticide 0 Manual, 10. Aufl. 1994, S. 646-647 und 647-648, (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha), (D29) MCPA, z.B. (4-Chloro-2-methylphenoxy)essigsäure , z.B. vorwiegend eingesetzte Formen sind u.a., MCPA-butotyl, MCPA-dimethylammonium, MCPA-isoctyl, MCPA-Kalium, MCPA-Natrium, Pesticide Manual, 10. Aufl. 5 1994, S. 638-640, (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha), (D30) Dichlorprop, umfassend auch Dichlorprop-P, z.B. (RS)-2-(2,4- Dichlorophenoxy)propionsäure und (r?)-2-(2,4- -"■- - ~OichlOrophenoxy)propionsäure, gebräuchlich sind u.a. auch Dichlorprop- 0 butotyl, Dichlorprop-ethylammonium, Dichlorprop-iso-octyl, Dichlorprop- Kalium, Pesticide Manual, 10. Aufl. 1994, S. 309-311 und 311-312, (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha),(D23) Imazamethabenz, e.g. reaction product, comprising (±) -6- (4-isopropyl-4-methyl-4-oxo-2-imidazolin-2-yl) -t? 7-toluic acid and (±) -6- ( 4-Isopropyl-4-methyl-4-oxo-2-imidazoliή-2-yl) -toluic acid7 - whereby the esters, for example the methyl esters known under the name Imazamethabenz-methyl, can also be used, Pesticide Manual, 10th ed. 1994, pp. 582-584, (application rate in general: 10 - 5000 g ai / ha, preferably 20 - 3000 g ai / ha), (D24) tralkoxydim, for example 2- [1- (ethoxyimino) propyl] -3-hydroxy-5-mesitylcyclohex-2-enone, pesticide Manual, 10th ed. 1994, pp. 995-996, (application rate in general: 10 - 5000 g ai / ha, preferably 20 - 3000 g ai / ha), 5 (D25) difenzoquat, e.g. 1, 2-dimethyl 3,5-diphenyipyrazolium, for example also as difenzoquat-metal sulfate, Pesticide Manual, 10th edition 1994, pp. 330-331, (application rate in general: 10 - 5000 g ai / ha, preferably 20 - 3000 g ai / ha), (D26) Flamprop, also comprising Flamprop-M, for example Λ / -Benzoyl-Λ / - (3-chloro-4- 0 fluorophenyl) -DL-alanine and Λ / -Benzoyl- / V- (3-chloro-4- fluorophenyI) -D-alanine, including, inter alia, Flamprop-methyl, Flamprop-M-methyl, Flamprop-M-isopropyl, Pesticide Manual, 10th ed. 1994, pp. 464-465 and 466-468, (application rate in general : 10 - 5000 g ai / ha, preferably 20 - 3000 g ai / ha), 5 (D27) pendimethalin, e.g. Λ / - (1-ethylpropyl) -2,6-dinitro-3,4-xylidine, Pesticide Manual, 10th ed. 1994, pp. 779-780, (ed Amount in general: 50-5000 g ai / ha, preferably 100-3000 g ai / ha), (D28) mecoprop, including also mecoprop-P, for example (RS) -2- (4-chloro-o-tolyloxy) propionic acid and (R) -2- (4-chloro-o-tolyloxy) propionic acid, Pesticide 0 Manual, 10th ed. 1994, pp. 646-647 and 647-648, (application rate in general: 10 - 5000 g ai / ha , preferably 20 - 3000 g ai / ha), (D29) MCPA, for example (4-chloro-2-methylphenoxy) acetic acid, for example predominantly used forms include MCPA-butotyl, MCPA-dimethylammonium, MCPA-isoctyl, MCPA-potassium , MCPA sodium, Pesticide Manual, 10th ed. 5 1994, pp. 638-640, (application rate in general: 10 - 5000 g ai / ha, preferably 20 - 3000 g ai / ha), (D30) dichloroprop, comprising also dichloroprop-P, for example (RS) -2- (2,4-dichlorophenoxy) propionic acid and (r?) - 2- (2,4- - "■ - - ~ OichlOrophenoxy) propionic acid, dichloroprop-0 are also commonly used butotyl, dichloroprop-ethyl ammonium, dichloroprop-iso-octyl, dichloroprop-potassium, Pesticide Manual, 10th ed. 1994, pp. 309-311 and 311-312, (ed in general: 10 - 5000 g ai / ha, preferably 20 - 3000 g AS / ha),
(D31) 2,4-D, z.B. (2,4-Dichlorophenoxy)essigsäure häufig eingesetzte Formen: 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-dimethylammonium, 2,4-D-diolamin, 2,4-D- iso-octyl, 2,4-D-isopropyl, 2,4-D-trolamin, Pesticide Manual, 10. Aufl. 1994, S. 271-273, (Aufwandmenge im allgemeinen: 10 - 5000 g AS/ha, vorzugsweise 20 - 3000 g AS/ha),(D31) 2,4-D, e.g. (2,4-dichlorophenoxy) acetic acid frequently used forms: 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-dimethylammonium, 2,4-D-diolamine, 2,4-D- iso-octyl, 2,4-D-isopropyl, 2,4-D-trolamine, Pesticide Manual, 10th ed. 1994, pp. 271-273, (application rate in general: 10 - 5000 g ai / ha, preferably 20 - 3000 g AS / ha),
(D32) Dicamba, z.B. 3,6-Dichlor-o-anissäure, angewendet u.a. als Dicamba- dimethylammonium, Dicamba-Kalium, Dicamba-Natrium, Dicamba-trolamin, Pesticide Manual, 10. Aufl. 1994, S. 298-300, (Aufwandmenge im allgemeinen: 20 - 500 g AS/ha, vorzugsweise 30 - 400 g AS/ha),(D32) dicamba, e.g. 3,6-dichloro-anisic acid, used inter alia as dicamba-dimethylammonium, dicamba-potassium, dicamba-sodium, dicamba-trolamine, Pesticide Manual, 10th edition 1994, pp. 298-300, (application rate in general: 20-500 g ai / ha, preferably 30-400 g AS / ha)
(D33) Fluroxypyr, z.B. 4-Amino-3,5-dichlor-6-fluor-2-pyridyloxyessigsäure, weitere Anwendungsform: Fluoroxypyr-meptyl sowie besonders bevorzugt: Fluroxypyr-butoxypropylester, Pesticide Manual, 10. Aufl. 1994, S. 505-507, (Aufwandmenge im allgemeinen: 20 - 500 g AS/ha, vorzugsweise 30 - 400 g AS/ha),(D33) fluroxypyr, e.g. 4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid, further use: fluoroxypyr-meptyl and particularly preferably: fluroxypyr-butoxypropyl ester, Pesticide Manual, 10th ed. 1994, pp. 505-507, (application rate in general: 20 - 500 g ai / ha, preferably 30 - 400 g ai / ha),
(D34) Flufenacet, z.B. 4'-Fluor-N-isopropyl-2-(5-trifluormethyl-1 ,3,4-thiadiazol-2- yloxy)acetanilid (PM, S. 434 - 435), (Aufwandmenge im allgemeinen: 10 - 1000 g AS/ha, vorzugsweise 20 - 800 g AS/ha),(D34) Flufenacet, e.g. 4'-fluoro-N-isopropyl-2- (5-trifluoromethyl-1, 3,4-thiadiazol-2-yloxy) acetanilide (PM, pp. 434 - 435), (application rate in general: 10 - 1000 g ai / ha, preferably 20 - 800 g ai / ha),
(D35) Bromoxynil, z.B. 3,5-Dibromo-4-hydroxy-benzonitril, häufig angewendet als Bromoxynil-octanoat, Bromoxynil-Kalium, Pesticide Manual, 10. Aufl. 1994, S. 121-123, (Aufwandmenge im allgemeinen: 10 - 3000 g AS/ha, vorzugsweise 50 - 1500 g AS/ha),(D35) bromoxynil, e.g. 3,5-dibromo-4-hydroxy-benzonitrile, frequently used as bromoxynil octanoate, bromoxynil potassium, Pesticide Manual, 10th ed. 1994, pp. 121-123, (application rate in general: 10 - 3000 g ai / ha , preferably 50 - 1500 g ai / ha),
(D36) Bifenox, z.B. Methyl 5-(2,4-Dichlorophenoxy)-2-nitrobenzoat, Pesticide Manual, 10. Aufl. 1994, S. 94-96, (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 100 - 4000 g AS/ha),(D36) bifenox, e.g. Methyl 5- (2,4-dichlorophenoxy) -2-nitrobenzoate, Pesticide Manual, 10th ed. 1994, pp. 94-96, (application rate in general: 50 - 5000 g ai / ha, preferably 100 - 4000 g ai / Ha),
(D37) Fluoroglycofen, z.B. 0-[5-(2-Chlor-α,α,α-trifluor-p-tolyloxy)-2- nitrobenzoyljglycolsäure, weitere Einsatzform: Fluoroglycofen-ethyl, Pesticide Manual, 10. Aufl. 1994, S. 492-494, (Aufwandmenge im allgemeinen: 1 - 200 g AS/ha, vorzugsweise 2 - 150 g AS/ha)- " (D38) Lactofen, z.B. Ethyl 0-[5-(2-Chlor-α,α,α-trifluor-p-tolyloxy)-2-nitrobenzoyl]- DL-Iactat, Pesticide Manual, 10. Aufl. 1994, S. 623, (Aufwandmenge im allgemeinen: 5 - 1000 g AS/ha, vorzugsweise 10 - 500 g AS/ha), (D39) Pyraflufen, umfassend auch Pyraflufen-ethyl (ET 751) , z.B. Ethyl 2-Chlor-5- (4-chlor-5-difluoromethoxy-1-methylpyrazol-3-yl)-4-fluorophenoxyacetat, (PM S. 792 - 793), (Aufwandmenge im allgemeinen: 1 - 50 g AS/ha, vorzugsweise 2 - 40 g AS/ha), (D40) Amicarbazone, z.B. 4-Amino-N-tert. butyl-4,5-dihydro-3-isopropyl-5-oxo-1 H- 1 ,2,4-triazol-1-carboxamid (PM, S. 28 - 29), (Aufwandmenge im allgemeinen: 10 - 1000 g AS/ha, vorzugsweise 20 - 800 g AS/ha), (D41) Bentazon, z.B. 3-lsopropyl-1H-2,1 ,3-benzothiadiazin-4(3H)-on 2,2-dioxid, Pesticide Manual, 10. Aufl. 1994, S. 90-91 , (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 100 - 3000 g AS/ha),(D37) fluoroglycofen, for example 0- [5- (2-chloro-α, α, α-trifluoro-p-tolyloxy) -2-nitrobenzoylglycolic acid, further use: fluoroglycofen-ethyl, Pesticide Manual, 10th edition 1994, p 492-494, (application rate in general: 1 - 200 g ai / ha, preferably 2 - 150 g ai / ha) - " (D38) lactofen, for example ethyl 0- [5- (2-chloro-α, α, α-trifluoro-p-tolyloxy) -2-nitrobenzoyl] - DL-lactate, Pesticide Manual, 10th edition 1994, p. 623, (application rate in general: 5-1000 g ai / ha, preferably 10-500 g ai /Ha), (D39) Pyraflufen, also including pyraflufen-ethyl (ET 751), for example ethyl 2-chloro-5- (4-chloro-5-difluoromethoxy-1-methylpyrazol-3-yl) -4-fluorophenoxyacetate, (PM p. 792 - 793), (application rate in general: 1-50 g ai / ha, preferably 2-40 g ai / ha), (D40) amicarbazones, for example 4-amino-N-tert. butyl-4,5-dihydro-3-isopropyl-5-oxo-1 H-1, 2,4-triazole-1-carboxamide (PM, pp. 28-29), (application rate in general: 10-1000 g ai / ha, preferably 20-800 g ai / ha), (D41) bentazone, for example 3-isopropyl-1H-2,1, 3-benzothiadiazin-4 (3H) -one 2,2-dioxide, Pesticide Manual, 10. Ed. 1994, pp. 90-91, (application rate in general: 50 - 5000 g ai / ha, preferably 100 - 3000 g ai / ha),
(D42) Amidosulfuron, z.B. 1-(4,6-Dimethoxypyrimidin-2-yl)-3- mesyl(methyl)sulfamoylharnstoff, Pesticide Manual, 10. Aufl. 1994, S. 34-35, (Aufwandmenge im allgemeinen: 0,5 - 200 g AS/ha, vorzugsweise 1 - 100 g AS/ha), (D43) Metsulfuron, z.B. 2-(4-Methoxy-6-methyl-1 ,3,5-triazin-2- ylcarbamoylsulfamoyl)benzoesäure, üblicherweise eingesetzt als Metsulfuron-methyl, Pesticide Manual, 10. Aufl. 1994, S. 701-702, (Aufwandmenge im allgemeinen: 0,5 - 120 g AS/ha, vorzugsweise 1 - 100 g AS/ha), (D44) Tribenuron, z.B. 2-[4-Methoxy-6-methyl-1 ,3,5-triazin-2- yl(methyl)carbamoylsulfamoyl] benzoesäure, üblicherweise eingesetzt als Tribenuron-methyl, Pesticide Manual, 10. Aufl. 1994, S. 1010-1011 , (Aufwandmenge im allgemeinen: 0,5 - 120 g AS/ha, vorzugsweise 1 - 100 g AS/ha), (D45) Thifensulfuron, z.B. 3-(4-Methoxy-6-methyl-1 ,3,5-triazin-2- ylcarbamoylsulfamoyl)thiophen-2-carbonsäure, meist verwendet als Thifensulfuron-methyl, Pesticide Manual, 10. Aufl. 1994, S. 976-978, (Aufwandmenge im allgemeinen: 0,5 - 120 g AS/ha, vorzugsweise 1 - 100 g AS/ha), ■ • "^ r - - - • - (D46) Triasulfuron, z.B. 1-[2-(2-Chloroethoxy)phenylsulfonyl]-3-(4-methoxy-6- methyl-1 ,3,5-triazin-2-yl)harnstoff, Pesticide Manual, 10. Aufl. 1994, S. 1005-1006, (Aufwandmenge im allgemeinen: 0,5 - 120 g AS/ha, vorzugsweise 1 - 100 g AS/ha), (D47) Chlorsulfuron, z.B. 1-(2-Chlorophenylsulfonyl)-3-(4-methoxy-6-methyl-1 ,3,5- triazin-2-yl)harnstoff, Pesticide Manual, 10. Aufl. 1994, S. 203-205, (Aufwandmenge im allgemeinen: 1 - 150 g AS/ha, vorzugsweise 2 - 120 g AS/ha),(D42) amidosulfuron, e.g. 1- (4,6-dimethoxypyrimidin-2-yl) -3-mesyl (methyl) sulfamoyl urea, Pesticide Manual, 10th edition 1994, pp. 34-35, (application rate in general: 0, 5-200 g ai / ha, preferably 1-100 g ai / ha), (D43) metsulfuron, for example 2- (4-methoxy-6-methyl-1, 3,5-triazin-2-ylcarbamoylsulfamoyl) benzoic acid, usually used as Metsulfuron-methyl, Pesticide Manual, 10th ed. 1994, pp. 701-702, (application rate in general: 0.5-120 g ai / ha, preferably 1-100 g ai / ha), (D44) tribenuron , for example 2- [4-methoxy-6-methyl-1, 3,5-triazin-2-yl (methyl) carbamoylsulfamoyl] benzoic acid, usually used as tribenuron-methyl, Pesticide Manual, 10th ed. 1994, p. 1010 -1011, (application rate in general: 0.5-120 g ai / ha, preferably 1-100 g ai / ha), (D45) thifensulfuron, for example 3- (4-methoxy-6-methyl-1, 3.5 -triazin-2-ylcarbamoylsulfamoyl) thiophene-2-carboxylic acid, mostly used as thifensulfuron-methyl, Pesticide Manual, 10th ed. 1994, pp. 976-978, (application rate in general : 0,5 - 120 g AS / ha, preferably 1 - 100 g AS / ha), ■ • "^ r - - - • - (D46) triasulfuron, for example 1- [2- (2-chloroethoxy) phenylsulfonyl] - 3- (4-methoxy-6-methyl-1, 3,5-triazin-2-yl) urea, Pesticide Manual, 10th ed. 1994, pp. 1005-1006, (application rate in general: 0.5-120 g AS / ha, preferably 1-100 g ai / ha), (D47) chlorosulfuron, for example 1- (2-chlorophenylsulfonyl) -3- (4-methoxy-6-methyl-1, 3,5-triazin-2-yl) urea, pesticides Manual, 10th edition 1994, pp. 203-205, (application rate in general: 1 - 150 g ai / ha, preferably 2 - 120 g ai / ha),
(D48) Flupyrsulfuron (DPX-KE459) , z.B. Methyl 2-(4,6-dimethoxypyrimidin-2- ylcarbamoylsulfamoyl)-6-trifluoromethylnicotinat, z.B. Flupyrsulfuron-methyl- Natrium (PM, S. 447 - 448), (Aufwandmenge im allgemeinen: 1 - 120 g AS/ha, vorzugsweise 2 - 100 g AS/ha), (D49) Fluazolate (MON 48500), z.B. Isopropyl 5-(4-bromo-1-methyl-5- trifluormethylpyrazol-3-yl)-2-chlor-4-fluorbenzoat, bevorzugt als Natriumsalz, (PM, S. 425 - 426), (Aufwandmenge im allgemeinen: 1 - 120 g AS/ha, vorzugsweise 2 - 100 g AS/ha), (D50) Sulfosulfuron (MON37500), z.B. 1-(4,6-dimethoxypyrimidin-2-yI)-3-(2- ethyIsulfonylimidazo[1 ,2-a]pyridin-3-yl)sulfonylhamstoff, (PM, S. 853 - 854), (Aufwandmenge im allgemeinen: 1 - 120 g AS/ha, vorzugsweise 2 - 100 g AS/ha), (D51) Glufosinate, umfassend auch Glufosinate-P, z.B. 4- [Hydroxy(methyl)phosphinoyl]-DL-homoalanin, 4-[Hydroxy(methyl) phosphinoyl]-L-homoalanin, die jeweils bevorzugt als Salze, z.B. Ammonium- oder Alkalimetallsalze wie Glufosinate-Ammonium, Glufosinate- P-Ammonium, Glufosinate-Natrium oder Glufosinate-P-Natrium verwendet werden, Pesticide Manual, 10. Aufl. 1994, S. 541-542, (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 100 - 2000 g AS/ha), (D52) Glyphosate, z.B. Λ/-(Phosphonomethyl)glycin, das bevorzugt als Glyphosate- isopropylammonium, Glyphosate-sesquinatrium, Glyphosate-trimesium eingesetzt wird, Pesticide Manual, 10. Aufl. 1994, S. 542-544, (Aufwandmenge im allgemeinen: 50 - 5000 g AS/ha, vorzugsweise 100 - 2000"g7ΛS/ha), - (D53) Sulcotrione (ICIA0051), z.B. 2-[2-Chlor-4-(methylsulfonyl)benzoyl]-1 ,3- cyclohexandion, Pesticide Manual, 10. Aufl. 1994, S.577-578, (Aufwandmenge im allgemeinen: 50 - 1500 g AS/ha, vorzugsweise 100 - 1000 g AS/ha), (D54) Cycloxydim, z.B. (±)-2-[1-(ethoxyimino)butyl]-3-hydroxy-5-thian-3-ylcyclohex- 2-enon, (PM, S. 218 - 219), (Aufwandmenge im allgemeinen: 5 - 2000 g 5 AS/ha, vorzugsweise 8 - 1000 g AS/ha), (D55) Sethoxydim, z.B. (±)-(EZ)-2-(1-ethoxyiminobutyl)-5-[2-(ethylthio)propyl]-3- hydroxycyclohex-2-enon,(PM, S. 832 - 833), (Aufwandmenge im allgemeinen: 5 - 2000 g AS/ha, vorzugsweise 8 - 1000 g AS/ha), (D56) Clethodim, z.B. (±)-2-[(E)-1-[(E)-3-chloroalkyloxyimino]propyl]-5-[2- 0 (ethylthio)propyl]-3-hydroxycyclohex-2-enon, (PM, S. 185 - 186), (Aufwandmenge im allgemeinen: 5 - 2000 g AS/ha, vorzugsweise 8 - 1000 g AS/ha), (D57) Carfentrazon, z.B. ethyl (RS)-2-chloro-3-[2-chloro-5-(4-difluoromethyl-4,5- dihydro-3-methyl-5-oxo-1 H-1 ,2,4-triazol-1-yl)-4-fluorophenyl]propionat, 5 angewendet u.a. als Carfentrazone-ethyl (wie dargestellt) oder auch als Säure, (PM, S. 141 - 142), (Aufwandmenge im allgemeinen: 1 - 80 g AS/ha, vorzugsweise 2 - 60 g AS/ha), (D58) Imazethapyr, insbesondere auch umfassend dessen Ester und Salze wie das Natriumsalz (PM, S. 533-534), z.B. (RS)-5-ethyl-2-(4-isopropyl-4-methyl- 0 5-oxo-2-imidazolin-2-yl)nicotinsäure, (Aufwandmenge im allgemeinen: 1 - 500 g AS/ha, vorzugsweise 2 - 300 g AS/ha), (D59) Imazaquin, insbesondere auch umfassend dessen Ester und Salze wie das Natriumsalz (PM, S. 531-533), z.B. (RS)-2-(4-isopropyl-4-methyl-5-oxo-2- imidazolin-2-yl)chinolin-3-carbonsäure, (Aufwandmenge im allgemeinen: 1 - 5 500 g AS/ha, vorzugsweise 2 - 300 g AS/ha), (D60) Imazapyr, insbesondere auch umfassend dessen Ester und Salze wie das Natriumsalz (PM, S. 530-531), z.B. 2-(4-isopropyl-4-methyl-5-oxo-2- imidazolin-2-yl)nicotinsäure, (Aufwandmenge im allgemeinen: 1 - 500 g ~ " " " AS/ha, vorzugsweise 2 - 300 g AS/ha), 0 (D61) Imazapic, insbesondere auch umfassend dessen Ester und Salze wie das Natriumsalz (PM, S. 529), z.B. (RS)-2-(4-isopropyl-4-methyl-5-oxo-2- imidazolin-2-yl)-5-methylnicotinsäure, (Aufwandmenge im allgemeinen: 1 - 500 g AS/ha, vorzugsweise 2 - 300 g AS/ha). (D62) Beflubutamid, z.B. N-Benzyl-2-(α,α,α-4-tetrafluor-m-tolyloxy)butyramid (PM, S. 63), (Aufwandmenge im allgemeinen: 10 - 1000 gAS/ha, vorzugsweise 20 - 800 gAS/ha), (D63) Fentrazamid, z.B. 4-(2-Chlorphenyl)-N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo- 1 H-tetrazol-1-carboxamid (PM, S. 406 - 407), (Aufwandmenge im allgemeinen: 10 - 1000 gAS/ha, vorzugsweise 20 - 800 gAS/ha), (D64) Flucarbazone, insbesondere auch umfassend dessen Salze wie das Natriumsalz (PM, S. 427-428), z.B. 4,5-dihydro-3-methoxy-4-methyl-5-oxo- N-(2-trif luoromethoxyphenylsulfonyl)-1 H-1 ,2,4-triazole-1 -carboxamid Natrium Salz, (Aufwandmenge im allgemeinen: 1 - 500 g AS/ha, vorzugsweise 5 - 200 g AS/ha), und (D65) Mesosulfuron, insbesondere auch umfassend dessen Salze und Ester, z.B. Methyl-2-[3-(4,6-dimethoxypyrimidin-2-yl)ureidosulfonyl]-4-methansulfon- aminomethyl-benzoat (Mesosulfuron-methyl) und dessen Salze wie das Natriumsalz (Mesosulfuron-methyl-Natrium) (siehe z.B. WO 95/10507 und Agrow Nr. 347, 3.3.2000, Seite 22 (PJB Publications Ltd. 2000)), (Aufwandmenge im allgemeinen: 0,5 - 200 gAS/ha, vorzugsweise 1 - 100 gAS/ha).(D48) Flupyrsulfuron (DPX-KE459), e.g. methyl 2- (4,6-dimethoxypyrimidin-2-ylcarbamoylsulfamoyl) -6-trifluoromethylnicotinate, e.g. flupyrsulfuron-methyl-sodium (PM, pp. 447 - 448), (application rate in general : 1 - 120 g ai / ha, preferably 2 - 100 g ai / ha), (D49) fluazolates (MON 48500), e.g. isopropyl 5- (4-bromo-1-methyl-5-trifluoromethylpyrazol-3-yl) - 2-chloro-4-fluorobenzoate, preferably as sodium salt, (PM, pp. 425 - 426), (application rate in general: 1 - 120 g ai / ha, preferably 2 - 100 g ai / ha), (D50) sulfosulfuron ( MON37500), e.g. 1- (4,6-dimethoxypyrimidin-2-yI) -3- (2-ethylsulfonylimidazo [1, 2-a] pyridin-3-yl) sulfonylurea, (PM, pp. 853-854), ( Application rate in general: 1 - 120 g ai / ha, preferably 2 - 100 g ai / ha), (D51) glufosinate, including also glufosinate-P, for example 4- [hydroxy (methyl) phosphinoyl] -DL-homoalanine, 4- [Hydroxy (methyl) phosphinoyl] -L-homoalanine, each preferred as salts, for example ammonium or alkali metal salts such as glufosinate-ammonium, glufosinate-P-ammonium, glufos inate sodium or glufosinate P sodium can be used, Pesticide Manual, 10th ed. 1994, pp. 541-542, (application rate in general: 50-5000 g ai / ha, preferably 100-2000 g ai / ha), (D52) Glyphosate, for example Λ / - (phosphonomethyl) glycine, which is preferably used as glyphosate-isopropylammonium, glyphosate-sesquinatrium, glyphosate-trimesium, Pesticide Manual, 10th ed. 1994, pp. 542-544, (application rate in general : 50 - 5000 g ai / ha, preferably 100 - 2000 " g7ΛS / ha), - (D53) sulcotrione (ICIA0051), for example 2- [2-chloro-4- (methylsulfonyl) benzoyl] -1, 3-cyclohexanedione, Pesticide Manual, 10th ed. 1994, p.577-578, (Application rate in general: 50-1500 g ai / ha, preferably 100-1000 g ai / ha), (D54) cycloxydim, for example (±) -2- [1- (ethoxyimino) butyl] -3-hydroxy-5- thian-3-ylcyclohex-2-enone, (PM, pp. 218-219), (application rate in general: 5-2000 g 5 AS / ha, preferably 8-1000 g AS / ha), (D55) sethoxydim, e.g. (±) - (EZ) -2- (1-ethoxyiminobutyl) -5- [2- (ethylthio) propyl] -3-hydroxycyclohex-2-enone, (PM, pp. 832 - 833), (application rate in general: 5-2000 g ai / ha, preferably 8-1000 g ai / ha), (D56) clethodim, for example (±) -2 - [(E) -1 - [(E) -3-chloroalkyloxyimino] propyl] -5 - [2- 0 (ethylthio) propyl] -3-hydroxycyclohex-2-enone, (PM, pp. 185-186), (application rate in general: 5-2000 g ai / ha, preferably 8-1000 g ai / ha ), (D57) carfentrazone, for example ethyl (RS) -2-chloro-3- [2-chloro-5- (4-difluoromethyl-4,5-dihydro-3-methyl-5-oxo-1 H-1, 2,4-triazol-1-yl) -4-fluorophenyl] propionate, 5 used inter alia as Carfentrazone-ethyl (as shown) or as an acid, (PM, pp. 141 - 142), (application rate in general: 1 - 80 g ai / ha , preferably 2-60 g ai / ha), (D58) imazethapyr, in particular also comprising its esters and salts such as the sodium salt (PM, pp. 533-534), for example (RS) -5-ethyl-2- (4- isopropyl-4-methyl-0 5-oxo-2-imidazolin-2-yl) nicotinic acid, (application rate in general: 1 - 500 g ai / ha, preferably 2 - 300 g ai / ha), (D59) imazaquin, in particular also comprising its esters and salts such as the sodium salt (PM, pp. 531-533), for example (RS) -2- (4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl) quinolin-3 carboxylic acid, (application rate in general: 1 - 5 500 g ai / ha, preferably 2 - 300 g ai / ha), (D60) imazapyr, in particular also comprising its esters and salts such as the sodium salt (PM, pp. 530-531 ), for example 2- (4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl) nicotinic acid, (application rate in general: 1 - 500 g ~ """ AS / ha, preferably 2 - 300 g AS / ha), 0 (D61) Imazapic, in particular also comprising its esters and salts such as the sodium salt (PM, p. 529), for example (RS) -2- (4-isopropyl-4-methyl-5-oxo-2 imidazolin-2-yl) -5-methylnicot Acid, (application rate in general: 1 - 500 g ai / ha, preferably 2 - 300 g ai / ha). (D62) Beflubutamide, e.g. N-benzyl-2- (α, α, α-4-tetrafluoro-m-tolyloxy) butyramide (PM, p. 63), (application rate in general: 10 - 1000 gAS / ha, preferably 20 - 800 gAS / ha), (D63) fentrazamide, e.g. 4- (2-chlorophenyl) -N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1 H-tetrazole-1-carboxamide (PM, Pp. 406-407), (application rate in general: 10-1000 gAS / ha, preferably 20-800 gAS / ha), (D64) flucarbazones, in particular also comprising its salts such as the sodium salt (PM, pp. 427-428) , e.g. 4,5-dihydro-3-methoxy-4-methyl-5-oxo-N- (2-trifluoromethoxyphenylsulfonyl) -1 H-1, 2,4-triazole-1-carboxamide sodium salt, (application rate in general : 1 - 500 g ai / ha, preferably 5 - 200 g ai / ha), and (D65) mesosulfuron, in particular also comprising its salts and esters, for example methyl-2- [3- (4,6-dimethoxypyrimidine-2- yl) ureidosulfonyl] -4-methanesulfonaminomethyl-benzoate (mesosulfuron-methyl) and its salts such as the sodium salt (mesosulfuron-methyl-sodium) (see, for example, WO 95/10507 and Agrow No. 347, 3.3.2000, page 22 (PJB Publications Ltd. 2000)), (application rate in general: 0.5 - 200 gAS / ha, preferably 1 - 100 gAS / ha).
Wenn im Rahmen dieser Beschreibung die Kurzform des „common name" eines Wirkstoffs verwendet wird, so sind damit jeweils alle gängigen Derivate, wie die Ester und Salze, und Isomere, insbesondere optische Isomere umfasst, insbesondere die handelsübliche Form bzw. Formen. Wird mit dem „common name" ein Ester oder Salz bezeichnet, so sind damit auch jeweils alle anderen gängigen Derivate wie andere Ester und Salze, die freien Säuren und Neutralverbindungen, und Isomere, insbesondere optische Isomere umfasst, insbesondere die handelsübliche Form bzw. Formen. Die angegebenen chemischen Verbindungsnamen bezeichnen zumindest eine der von dem „common name" umfaßten Verbindungen, häufig eine bevorzugte Verbindung. Bei Sulfonamiden wie Sulfonylharnstoffen sind mit Salzen auch die umfaßt, die durch Austausch eines Wasserstoffatoms an der Sulfonamidgruppe durch ein Kation entstehen. Bei Anwendung der erfindungsgemäßen Herbizid-Kombinationen eignen sich die Herbizide D1 , D2, D4, D8, D9, D11 - D16, D18, D21 , D22, D23, D24, D27, D40, D43, D47 - D53, D58 - D61 , D63 - D65 insbesondere zur Bekämpfung monokotyler und dikotyler Schadpflanzen, die Herbizide D17, D19, D20, D25, D26, D54-D56 eignen sich insbesondere zur Bekämpfung monokotyler Schadpflanzen und die Herbizide D3, D5, D6, D7, D10, D28 - D39, D41 , D42, D44, D45, D46, D57, D62 eignen sich insbesondere zur Bekämpfung dikotyler Schadpflanzen.If the short form of the "common name" of an active ingredient is used in the context of this description, all common derivatives, such as the esters and salts, and isomers, in particular optical isomers, are included, in particular the commercially available form or forms “Common name” denotes an ester or salt, so that each also includes all other common derivatives such as other esters and salts, which include free acids and neutral compounds, and isomers, in particular optical isomers, in particular the commercially available form or forms. The chemical compound names given designate at least one of the compounds included in the "common name", often a preferred compound. In the case of sulfonamides such as sulfonylureas, salts are also included, which are formed by the exchange of a hydrogen atom on the sulfonamide group by a cation. When using the herbicide combinations according to the invention, herbicides D1, D2, D4, D8, D9, D11 - D16, D18, D21, D22, D23, D24, D27, D40, D43, D47 - D53, D58 - D61, D63 are suitable - D65 in particular for controlling monocotyledon and dicotyledonous harmful plants, the herbicides D17, D19, D20, D25, D26, D54-D56 are particularly suitable for controlling monocotyledonous harmful plants and the herbicides D3, D5, D6, D7, D10, D28 - D39, D41 , D42, D44, D45, D46, D57, D62 are particularly suitable for controlling dicotyledonous harmful plants.
Von besonderem Interesse sind Herbizid-Kombinationen mit einem Gehalt an folgenden Verbindungen (A) + (B) + (C) sowie (A) + (B) + (C) + (D):Herbicide combinations containing the following compounds (A) + (B) + (C) and (A) + (B) + (C) + (D) are of particular interest:
(A1) + (B1) + (C1), (A1) + (B1) + (C2), (A1) + (B2) + (C1), (A1) + (B2) + (C2), (A1) + (B3) + C1), (A1) + (B3) + (C2), (A1) + (B4) + (C1), (A1) + (B4) + (C2), (A1) + (B1) + (C1) + (D1), (A1) + (B1) + (C1) + (D2), (A1) + (B1) + (C1) + (D3), (A1) + (B1) + (C1) + (D4), (A1) + (B1) + (C1) + (D5), (A1) + (B1) + (C1) + (D6), (A1) + (B1) + (C1) + (D7), (A1) + (B1) + (C1) + (D8), (A1) + (B1) + (C1) + (D9), (A1) + (B1) + (C1) + (D10), (A1) + (B1) + (C1) + (D11), (A1) + (B1) + (C1) + (D12), (A1) + (B1) +(A1) + (B1) + (C1), (A1) + (B1) + (C2), (A1) + (B2) + (C1), (A1) + (B2) + (C2), (A1 ) + (B3) + C1), (A1) + (B3) + (C2), (A1) + (B4) + (C1), (A1) + (B4) + (C2), (A1) + ( B1) + (C1) + (D1), (A1) + (B1) + (C1) + (D2), (A1) + (B1) + (C1) + (D3), (A1) + (B1) + (C1) + (D4), (A1) + (B1) + (C1) + (D5), (A1) + (B1) + (C1) + (D6), (A1) + (B1) + ( C1) + (D7), (A1) + (B1) + (C1) + (D8), (A1) + (B1) + (C1) + (D9), (A1) + (B1) + (C1) + (D10), (A1) + (B1) + (C1) + (D11), (A1) + (B1) + (C1) + (D12), (A1) + (B1) +
(cι; ) + (D13) ) + (B1 ) + (C1 + (D14), (A1) + (B1) + (C1) + (D15) (A1) + (B1) +(cι;) + (D13)) + (B1) + (C1 + (D14), (A1) + (B1) + (C1) + (D15) (A1) + (B1) +
(ci; | + (D16) ) + (B1 ) + (C1 + (D17), (A1) + (B1) + (C1) + (D18) (A1) + (B1) +(ci; | + (D16)) + (B1) + (C1 + (D17), (A1) + (B1) + (C1) + (D18) (A1) + (B1) +
(cι; > + (D19) ) + (B1 ) + (C1 + (D20) , (A1) + (B1) + (C1) + (D21), (A1) + (B1) +(cι;> + (D19)) + (B1) + (C1 + (D20), (A1) + (B1) + (C1) + (D21), (A1) + (B1) +
(ci; ) + (D22) ) + (B1 ) + (C1 )■ (A1) + (B' l) + (C1) (A1) + (B1)(ci;) + (D22)) + (B1) + (C1) ■ (A1) + (B 'l) + (C1) (A1) + (B1)
(ci; ) + (D25) ) + (B1 ) + (C1 ), (A1) + (B' l) + (C1) (A1) + (B1)(ci;) + (D25)) + (B1) + (C1), (A1) + (B 'l) + (C1) (A1) + (B1)
(ci; ) + (D28) ) + (B1 ) + (C1 ), (A1) + (B' 1) + (C1) (A1) + (B1)(ci;) + (D28)) + (B1) + (C1), (A1) + (B '1) + (C1) (A1) + (B1)
(ci; l + (D31) ) + (B1 ) + (C1 ). (A1) + (B' l) + (C1) (A1) + (B1)(ci; l + (D31)) + (B1) + (C1). (A1) + (B 'l) + (C1) (A1) + (B1)
(ci; ) + (D34) ) + (B1 ) + (C1 ), (A1) + (B' l) + (C1) (A1) + (B1)(ci;) + (D34)) + (B1) + (C1), (A1) + (B 'l) + (C1) (A1) + (B1)
(ci; ) + (D37) ) + (B1 ) + (C1 ), (A1) + (B' 1) + (C1) (A1) + (B1)(ci;) + (D37)) + (B1) + (C1), (A1) + (B '1) + (C1) (A1) + (B1)
(ci; ) + (D40) ) + (B1 ) + (C1 ), (A1) + (B' l) + (C1) (A1) + (B1)(ci;) + (D40)) + (B1) + (C1), (A1) + (B 'l) + (C1) (A1) + (B1)
(ci; ) + (D43) ) + (B1 ) + (C1 ). (A1) + (B' l) + (C1) (A1) + (B1)(ci;) + (D43)) + (B1) + (C1). (A1) + (B 'l) + (C1) (A1) + (B1)
(ci; ) + (D46) ) + (B1 ) + (C1 ), (A1) +-(B- 1)-+ (C1) (A1) + (B1)(ci;) + (D46)) + (B1) + (C1), (A1) + - (B- 1) - + (C1) (A1) + (B1)
(ci; ) + (D49) ) + (B1 ) + (C1 ), (A1) + (B' 1) + (C1) (A1) + (B1)(ci;) + (D49)) + (B1) + (C1), (A1) + (B '1) + (C1) (A1) + (B1)
(ci; I + (D52) ) + (B1 ) + (C1 ), (A1) + (B' l) + (C1) (A1) + (B1)(ci; I + (D52)) + (B1) + (C1), (A1) + (B 'l) + (C1) (A1) + (B1)
(ci; ) + (D55) ) + (B1 ) + (C1 ). (A1) + (B' l) + (C1) (A1) + (B1) (C1) + D58), (A1) + (B1) + (C1) + (D59), (A1) + (B1) + (C1) + (D60), (A1) + (B1) + (C1) + D61), (A1) + (B1) + (C1) + (D62), (A1) + (B1) + (C1) + (D63), (A1) + (B1) + (C1) + D64), (A1) + (B1) + (C1) + (D65);(ci;) + (D55)) + (B1) + (C1). (A1) + (B 'l) + (C1) (A1) + (B1) (C1) + D58), (A1) + (B1) + (C1) + (D59), (A1) + (B1) + (C1) + (D60), (A1) + (B1) + (C1) + D61), (A1) + (B1) + (C1) + (D62), (A1) + (B1) + (C1) + (D63), (A1) + (B1) + (C1) + D64) , (A1) + (B1) + (C1) + (D65);
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Figure imgf000023_0003
+ (C1) + (D63)
Figure imgf000023_0002
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Figure imgf000023_0003
+ (C1) + (D63)
Figure imgf000023_0002
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Figure imgf000023_0001
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Figure imgf000023_0001
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(C1) + (D49), (A1) + (B3) + (C1) + (D50), (A1) + (B3) + (C1) + (D51), (A1) + (B3) +(C1) + (D49), (A1) + (B3) + (C1) + (D50), (A1) + (B3) + (C1) + (D51), (A1) + (B3) +
(C1) + (D52), (A1) + (B3) + (C1) + (D53), (A1) + (B3) + (C1) + (D54), (A1) + (B3) +(C1) + (D52), (A1) + (B3) + (C1) + (D53), (A1) + (B3) + (C1) + (D54), (A1) + (B3) +
(C1) + (D55), (AT)"- + (B3) + (C 1 ) + (D56) , (A1 ) + (B3 "(G1 ) + (D57-) , (A1 ) + (B3) "+(C1) + (D55), (AT) " - + (B3) + (C 1) + (D56), (A1) + (B3 " (G1) + (D57-), (A1) + (B3) " +
(C1) + (D58), (A1) + (B3) + (C1) + (D59), (A1) + (B3) + (C1) + (D60), (A1) + (B3) +(C1) + (D58), (A1) + (B3) + (C1) + (D59), (A1) + (B3) + (C1) + (D60), (A1) + (B3) +
(C1) + (D61), (A1) + (B3) + (C1) + (D62), (A1) + (B3) + (C1) + (D63), (A1) + (B3) +(C1) + (D61), (A1) + (B3) + (C1) + (D62), (A1) + (B3) + (C1) + (D63), (A1) + (B3) +
(C1) + (D64), (A1) + (B3) + (C1) + (D65); (A1) + B3) + (C2), (A1) + (B3) + (C2), (A1) + (B2) + (C2), (A1) + (B2) + (C2), (A1) + B3) + (C2) + (D1), (A1) + (B3) + (C2) + (D2), (A1) + (B3) + (C2) + (D3), (A1) + (B3) (C2) + (D4), (A1) + (B3) + (C2) + (D5), (A1) + (B3) + (C2) + (D6), (A1) + (B3) + C2) + (D7), (A1) + (B3) + (C2) + (D8), (A1) + (B3) + (C2) + (D9), (A1) + (B3) + (C2) i- (D10), (A1) + (B3) + (C2) + (D11), (A1) + (B3) + (C2) + (D12), (A1) + (B3) + (C2) + D13) + (B3) + C2) + (D14), (A1) + (B3) + (C2) + (D15), (A1) + (C2) + D16) + (B3) + C2) + (D17), (A1) + (B3) + (C2) + (D18), (A1) + (C2) + D19) + (B3) + C2) + (D20) , (A1) + (B3) + (C2) + (D21), (A1) + (C2) + D22) + (B3) + C2) + (D23), (A1) + (B3) + (C2) + (D24), (A1) + (C2) + D25) + (B3) + C2) + (D26), (A1) + (B3) + (C2) + (D27), (A1) + (C2) + D28) + (B3) + C2) + (D29), (A1) + (B3) + (C2) + (D30), (A1) + (C2) + D31) + (B3) + C2) + (D32), (A1) + (B3) + (C2) + (D33), (A1) + (C2) + D34) + (B3) + C2) + (D35), (A1) + (B3) + (C2) + (D36), (A1) + (C2) + D37) + (B3) + C2) + (D38), (A1) + (B3) + (C2) + (D39), (A1) + (C2) + D40) + (B3) + C2) + (D41), (A1) + (B3) + (C2) + (D42), (A1) + (C2) + D43) + (B3) + C2) + (D44), (A1) + (B3) + (C2) + (D45), (A1) + (C2) + D46) + (B3) + C2) + (D47), (A1) + (B3) + (C2) + (D48), (A1) + (C2) + D49) + (B3) + C2) + (D50), (A1) + (B3) + (C2) + (D51), (A1) + (C2) + D52) + (B3) + C2) + (D53), (A1) + (B3) + (C2) + (D54), (A1) + (C2) + D55) + (B3) + C2) + (D56), (A1) + (B3) + (C2) + (D57), (A1) + (C2) + D58) + (B3) + C2) + (D59), (A1) + (B3) + (C2) + (D60), (A1) + (C2) + D61) + (B3) + C2) + (D62), (A1) + (B3) + (C2) + (D63), (A1) + (C2) + D64) + (B3) + C2) + (D65);(C1) + (D64), (A1) + (B3) + (C1) + (D65); (A1) + B3) + (C2), (A1) + (B3) + (C2), (A1) + (B2) + (C2), (A1) + (B2) + (C2), (A1) + B3) + (C2) + (D1), (A1) + (B3) + (C2) + (D2), (A1) + (B3) + (C2) + (D3), (A1) + (B3 ) (C2) + (D4), (A1) + (B3) + (C2) + (D5), (A1) + (B3) + (C2) + (D6), (A1) + (B3) + C2 ) + (D7), (A1) + (B3) + (C2) + (D8), (A1) + (B3) + (C2) + (D9), (A1) + (B3) + (C2) i - (D10), (A1) + (B3) + (C2) + (D11), (A1) + (B3) + (C2) + (D12), (A1) + (B3) + (C2) + D13 ) + (B3) + C2) + (D14), (A1) + (B3) + (C2) + (D15), (A1) + (C2) + D16) + (B3) + C2) + (D17) , (A1) + (B3) + (C2) + (D18), (A1) + (C2) + D19) + (B3) + C2) + (D20), (A1) + (B3) + (C2) + (D21), (A1) + (C2) + D22) + (B3) + C2) + (D23), (A1) + (B3) + (C2) + (D24), (A1) + (C2) + D25) + (B3) + C2) + (D26), (A1) + (B3) + (C2) + (D27), (A1) + (C2) + D28) + (B3) + C2) + ( D29), (A1) + (B3) + (C2) + (D30), (A1) + (C2) + D31) + (B3) + C2) + (D32), (A1) + (B3) + ( C2) + (D33), (A1) + (C2) + D34) + (B3) + C2) + (D35), (A1) + (B3) + (C2) + (D36), (A1) + ( C2) + D37) + (B3) + C2) + (D3 8), (A1) + (B3) + (C2) + (D39), (A1) + (C2) + D40) + (B3) + C2) + (D41), (A1) + (B3) + ( C2) + (D42), (A1) + (C2) + D43) + (B3) + C2) + (D44), (A1) + (B3) + (C2) + (D45), (A1) + ( C2) + D46) + (B3) + C2) + (D47), (A1) + (B3) + (C2) + (D48), (A1) + (C2) + D49) + (B3) + C2) + (D50), (A1) + (B3) + (C2) + (D51), (A1) + (C2) + D52) + (B3) + C2) + (D53), (A1) + (B3) + (C2) + (D54), (A1) + (C2) + D55) + (B3) + C2) + (D56), (A1) + (B3) + (C2) + (D57), (A1) + (C2) + D58) + (B3) + C2) + (D59), (A1) + (B3) + (C2) + (D60), (A1) + (C2) + D61) + (B3) + C2) + (D62), (A1) + (B3) + (C2) + (D63), (A1) + (C2) + D64) + (B3) + C2) + (D65);
(A1) + B4) + (C1) + (D1), (A1) + (B4) + (C1) + (D2), (A1) + (B4) + (C1) + (D3), (A1) + (B4) (C1) + (D4), (A1) + (B4) + (C1) + (D5), (A1) + (B4) + (C1) + (D6), (A1) + (B4) + C1) + (D7), (A1) + (B4) + (C1) + (D8), (A1) + (B4) + (C1) + (D9), (A1) + (B4) ■ + (C1) H (D10)," (A ) + (B4) + (CTr U TA2!) + (B4) + (C ) + (D12), (A1) + (B4) + (C1) + D13), (A1) + (B4) + (C1) + (D14), (A1) + (B4) + (C1) + (D15), (A1) + (B4) + (C1) + D16), (A1) + (B4) + (C1) + (D17), (A1) + (B4) + (C1) + (D18), (A1) + (B4) + (C1) + D19), (A1) + (B4) + (C1) + (D20) , (A1) + (B4) + (C1) + (D21), (A1) + (B4) + (C1) + D22 + (B4) + (C + (B4) + (C + (D24) (Ai; + (B4) + (C1) + D25 + (B4) + (C + (B4) + (C + (D27) (AI; I + (B4) + (C1) + D28 + (B4) + (C + (B4) + (C + (D30) (AI; I + (B4) + (C1) + D31 + (B4) + (C + (B4) + (C + (D33) (AI; > + (B4) + (C1) + D34 + (B4) + (C + (B4) + (C + (D36) (AI; ) + (B4) + (C1) + D37 + (B4) + (C + (B4) + (C + (D39) (AI; ) + (B4) + (C1) + D40 + (B4) + (C + (B4) + (C + (D42) (AI; I + (B4) + (C1) + D43 + (B4) + ( + (B4) + (C + (D45) (AI; ) + (B4) + (C1) + D46 + (B4) + (C + (B4) + (C + (D48) (AI; ) + (B4) + (C1) + D49 + (B4) + (C + (B4) + (C + (D51) (AI; ) + (B4) + (C1) + D52 + (B4) + ( + (B4) + (C + (D54) (A1 ) + (B4) + (C1) + D55 + (B4) + ( + (B4) + (C + (D57) (A1 ) + (B4) + (C1) + D58 + (B4) + ( + (B4) + (C + (D60) (Ai; ) + (B4) + (C1) + D61 + (B4) + ( + (B4) + (C + (D63) (A1 ) + (B4) + (C1) + D64 + (B4) + (
Figure imgf000026_0001
(A1) + B4) + (C1) + (D1), (A1) + (B4) + (C1) + (D2), (A1) + (B4) + (C1) + (D3), (A1) + (B4) (C1) + (D4), (A1) + (B4) + (C1) + (D5), (A1) + (B4) + (C1) + (D6), (A1) + (B4 ) + C1) + (D7), (A1) + (B4) + (C1) + (D8), (A1) + (B4) + (C1) + (D9), (A1) + (B4) ■ + (C1) H (D10), " (A) + (B4) + (CTr U TA 2 !) + (B4) + (C) + (D12), (A1) + (B4) + (C1) + D13 ), (A1) + (B4) + (C1) + (D14), (A1) + (B4) + (C1) + (D15), (A1) + (B4) + (C1) + D16), ( A1) + (B4) + (C1) + (D17), (A1) + (B4) + (C1) + (D18), (A1) + (B4) + (C1) + D19), (A1) + (B4) + (C1) + (D20), (A1) + (B4) + (C1) + (D21), (A1) + (B4) + (C1) + D22 + (B4) + (C + (B4) + (C + (D24) (Ai; + (B4) + (C1) + D25 + (B4) + (C + (B4) + (C + (D27) (AI; I + (B4) + (C1) + D28 + (B4) + (C + (B4) + (C + (D30) (AI; I + (B4) + (C1) + D31 + (B4) + (C + (B4) + (C + (D33) (AI;> + (B4) + (C1) + D34 + (B4) + (C + (B4) + (C + (D36) (AI;) + (B4) + (C1) + D37 + (B4) + (C + (B4) + (C + (D39) (AI;) + (B4) + (C1) + D40 + (B4) + (C + (B4) + (C + (D42) (AI; I + (B4) + (C1) + D43 + (B4) + (+ (B4) + (C + (D45) (AI;) + (B4) + (C1) + D46 + (B4) + (C + (B4) + (C + (D48) (AI;) + (B4) + (C1) + D49 + (B4) + (C + ( B4) + (C + (D51) (AI;) + (B4) + (C1) + D52 + (B4) + (+ (B4) + (C + (D54) (A1) + (B4) + (C1 ) + D55 + (B4) + (+ (B4) + (C + (D57) (A1) + (B4) + (C1) + D58 + (B4) + (+ (B4) + (C + (D60) (Ai;) + (B4) + (C1) + D61 + (B4) + (+ (B4) + (C + (D63) (A1) + (B4) + (C1) + D64 + (B4) + (
Figure imgf000026_0001
(A1) + B4) + (C2), (A1) + (B4) + (C2), (A1) + (B2) + (C2), (A1) + (B2) + (C2), (A1) + B4) + (C2) + (D1), (A1) + (B4) + (C2) + (D2), (A1) + (B4) + (C2) + (D3), (A1) + (B4) H (C2) + (D4), (A1) + (B4) + (C2) + (D5), (A1) + (B4) + (C2) + (D6), (A1) + (B4) + C2) + (D7), (A1) + (B4) + (C2) + (D8), (A1) + (B4) + (C2) + (D9), (A1) + (B4) + (C2) - (D10), (A1) + (B4) + (C2) + (D11), (A1) + (B4) + (C2) + (D12), (A1) + (B4) + (C2) + D13), (A1) + (B4) + (C2) + (D14), (A1) + (B4) + (C2) + (D15), (A1) + (B4) + (C2) + D16) (A1) + (B4) + (C2) + (D17) (A1) + (B4) + (C2) + (D18), (A1) + (B4) + (C2) + D19) (A1) + (B4) + (C2) + (D20) , (A1) + (B4) + (C2) + (D21), (A1) + (B4) + (C2) + D22) (A1) + (B4) + (C2) + (D23) (A1) + (B4) + (C2) + (D24), (A1) + (B4) + (C2) + D25) (A1) + (B4) + (C2) + (D26) (A1) + (B4) + (C2) + (D27), (A1) + (B4) + (C2) + D28) (A1) + (B4) + (C2) + (D29) (A1) + (B4) + (C2) + (D30), (A1) + (B4) + (C2) + D31) (A1) + (B4) + (C2) + (D32) (A1) + (B4) + (C2) + (D33), (A1) + (B4) + (C2) + D34) ϊ(AT)-+(B4?f+ (C2)+(D35) (AI)* (B4pι- (C2)- +-(D36), (A1) + (B4) -f (C2) + D37) (A1) + (B4) + (C2) + (D38) (A1) + (B4) + (C2) + (D39), (A1) + (B4) + (C2) + D40) (A1) + (B4) + (C2) + (D41) (A1) + (B4) + (C2) + (D42), (A1) + (B4) + (C2) + D43) (A1) + (B4) + (C2) + (D44) (A1) + (B4) + (C2) + (D45), (A1) + (B4) + (C2) + (D46), (A1) + (B4) + (C2) + (D47), (A1) + (B4) + (C2) + (D48), (A1) + (B4) + (C2) + (D49), (A1) + (B4) + (C2) + (D50), (A1) + (B4) + (C2) + (D51), (A1) + (B4) + (C2) + (D52), (A1) + (B4) + (C2) + (D53), (A1) + (B4) + (C2) + (D54), (A1) + (B4) + (C2) + (D55), (A1) + (B4) + (C2) + (D56), (A1) + (B4) + (C2) + (D57), (A1) + (B4) + 5 (C2) + (D58), (A1) + (B4) + (C2) + (D59), (A1) + (B4) + (C2) + (D60), (A1) + (B4) + (C2) + (D61), (A1) + (B4) + (C2) + (D62), (A1) + (B4) + (C2) + (D63), (A1) + (B4) + (C2) + (D64), (A1) + (B4) + (C2) + (D65).(A1) + B4) + (C2), (A1) + (B4) + (C2), (A1) + (B2) + (C2), (A1) + (B2) + (C2), (A1) + B4) + (C2) + (D1), (A1) + (B4) + (C2) + (D2), (A1) + (B4) + (C2) + (D3), (A1) + (B4 ) H (C2) + (D4), (A1) + (B4) + (C2) + (D5), (A1) + (B4) + (C2) + (D6), (A1) + (B4) + C2) + (D7), (A1) + (B4) + (C2) + (D8), (A1) + (B4) + (C2) + (D9), (A1) + (B4) + (C2) - (D10), (A1) + (B4) + (C2) + (D11), (A1) + (B4) + (C2) + (D12), (A1) + (B4) + (C2) + D13 ), (A1) + (B4) + (C2) + (D14), (A1) + (B4) + (C2) + (D15), (A1) + (B4) + (C2) + D16) (A1 ) + (B4) + (C2) + (D17) (A1) + (B4) + (C2) + (D18), (A1) + (B4) + (C2) + D19) (A1) + (B4) + (C2) + (D20), (A1) + (B4) + (C2) + (D21), (A1) + (B4) + (C2) + D22) (A1) + (B4) + (C2) + (D23) (A1) + (B4) + (C2) + (D24), (A1) + (B4) + (C2) + D25) (A1) + (B4) + (C2) + (D26) ( A1) + (B4) + (C2) + (D27), (A1) + (B4) + (C2) + D28) (A1) + (B4) + (C2) + (D29) (A1) + (B4 ) + (C2) + (D30), (A1) + (B4) + (C2) + D31) (A1) + (B4) + (C2) + (D32) (A1) + (B4) + (C2) + (D33), (A1) + (B4) + (C2) + D34) ϊ (AT) - + (B4? f + (C2) + (D35) (AI) * (B4pι- (C2) - + - (D36), (A1) + (B4) -f (C2) + D37) ( A1) + (B4) + (C2) + (D38) (A1) + (B4) + (C2) + (D39), (A1) + (B4) + (C2) + D40) (A1) + (B4 ) + (C2) + (D41) (A1) + (B4) + (C2) + (D42), (A1) + (B4) + (C2) + D43) (A1) + (B4) + (C2) + (D44) (A1) + (B4) + (C2) + (D45), (A1) + (B4) + (C2) + (D46), (A1) + (B4) + (C2) + (D47), (A1) + (B4) + (C2) + (D48), (A1) + (B4) + (C2 ) + (D49), (A1) + (B4) + (C2) + (D50), (A1) + (B4) + (C2) + (D51), (A1) + (B4) + (C2) + (D52), (A1) + (B4) + (C2) + (D53), (A1) + (B4) + (C2) + (D54), (A1) + (B4) + (C2) + (D55 ), (A1) + (B4) + (C2) + (D56), (A1) + (B4) + (C2) + (D57), (A1) + (B4) + 5 (C2) + (D58) , (A1) + (B4) + (C2) + (D59), (A1) + (B4) + (C2) + (D60), (A1) + (B4) + (C2) + (D61), ( A1) + (B4) + (C2) + (D62), (A1) + (B4) + (C2) + (D63), (A1) + (B4) + (C2) + (D64), (A1) + (B4) + (C2) + (D65).
Darüber hinaus kann jede der oben genannten Herbizid-Kombinationen noch einen 10 oder mehrere Safener enthalten, insbesondere einen Safener wie Mefenpyr-diethyl (S1-1), Isoxadifen-ethyl (S1-9) und Cloquintocet-mexyl (S2-1). Dabei sind die oben genannten Aufwandmengenbereiche und Aufwandmengenverhältnisse jeweils bevorzugt. Beispiele hierfür sind die nachfolgend genannten Herbizid- Kombinationen. 15 (A1) + (B1) + (C1) + (D1) + (S1-1), (A1) + (B1) + (C1) + (D2) + (S1-1), (A1) + (B1) + (C1) + (D3) + (S1-1), (A1) + (B1) + (C1) + (D4) + (S1-1), (A1) + (B1) + (C1) + (D5) + (S1-1), (A1) + (B1) + (C1) + (D6) + (S1-1), (A1) + (B1) + (C1) + (D7) + (S1-1), (A1) + (B1) + (C1) + (D8) + (S1-1), (A1) + (B1) + (C1) + (D9) + (S1-1), (A1) + (B1) + (C1) + 20 (D10) + (S1-1), (A1) + (B1) + (C1) + (D11) + (S1-1), (A1) + (B1) + (C1) + (D12) + (S1-1), (A1) + (B1) + (C1) + (D13) + (S1-1), (A1) + (B1) + (C1) + (D14) + (S1-1), (A1) + (B1) + (C1) + (D15) + (S1-1), (A1) + (B1) + (C1) + (D16) + (S1-1), (A1) + (B1) + (C1) + (D17) + (S1-1), (A1) + (B1) + (C1) + (D18) + (S1-1), (A1) + (B1) + (C1) + (D19) + (S1-1), (A1) + (B1) + (C1) + (D20) + (S1-1) , (A1) + (B1) + (C1) + (D21) + 25 (S1-1), (A1) + (B1) + (C1) + (D22) + (S1-1), (A1) + (B1) + (C1) + (D23) + (S1-1), (A1) + (B1) + (C1) + (D24) + (S1-1), (A1) + (B1) + (C1) + (D25) + (S1-1), (A1) + (B1) + (C1) + (D26) + (S1-1), (A1) + (B1) + (C1) + (D27) + (S1-1), (A1) + (B1) + (C1) + (D28) + (S1-1), (A1) + (B1) + (C1) + (D29) + (S1-1), (A1) + (B1) + (C1) + (D30) + - ~- - (St ), fAT) + (BT + (01)'+ "(D31) + (Sf-Ϊ), (A1) + (B1) + (C1) + (D32) + (S1-1) (A1)" 30 + (B1) + (C1) + (D33) + (S1-1), (A1) + (B1) + (C1) + (D34) + (S1-1), (A1) + (B1) + (C1) + (D35) + (S1-1), (A1) + (B1) + (C1) + (D36) + (S1-1), (A1) + (B1) + (C1) + (D37) + (S1-1), (A1) + (B1) + (C1) + (D38) + (S1-1), (A1) + (B1) + (C1) + (D39) + (S1-1), (A1) + (B1) + (C1) + (D40) + (S1-1), (A1) + (B1) + (C1) + (D41) + (S1-1), (A1) + (B1) + (C1) + (D42) + (S1-1), (A1) + (B1) + (C1) + (D43) + (S1-1), (A1) + (B1) + (C1) + (D44) + (S1-1), (A1) + (B1) + (C1) + (D45) + (S1-1), (A1) + (B1) + (C1) + (D46) + (S1-1), (A1) + (B1) + (C1) + (D47) + (S1-1), (A1) + (B1) + (C1) + (D48) + (S1-1), (A1) + (B1) + (C1) + (D49) + (S1-1), (A1) + (B1) + (C1) + (D50) + (S1-1), (A1) + (B1) + (C1) + (D51) + (S1-1), (A1) + (B1) + (C1) + (D52) + (S1-1), (A1) + (B1) + (C1) + (D53) + (S1-1), (A1) + (B1) + (C1) + (D54) + (S1-1), (A1) + (B1) + (C1) + (D55) + (S1-1), (A1) + (B1) + (C1) + (D56) + (S1-1), (A1) + (B1) + (C1) + (D57) + (S1-1), (A1) + (B1) + (C1) + (D58) + (S1-1), (A1) + (B1) + (C1) + (D59) + (S1-1), (A1) + (B1) + (C1) + (D60) + (S1-1), (A1) + (B1) + (C1) + (D61) + (S1-1), (A1) + (B1) + (C1) + (D62), (A1) + (B1) + (C1) + (D63), (A1) + (B1) + (C1) + (D64), (A1) + (B1) + (C1) + (D65);In addition, each of the herbicide combinations mentioned above can also contain a 10 or more safener, in particular a safener such as mefenpyr-diethyl (S1-1), isoxadifen-ethyl (S1-9) and cloquintocet-mexyl (S2-1). The above-mentioned application rate ranges and application rate ratios are preferred in each case. Examples of this are the herbicide combinations mentioned below. 15 (A1) + (B1) + (C1) + (D1) + (S1-1), (A1) + (B1) + (C1) + (D2) + (S1-1), (A1) + ( B1) + (C1) + (D3) + (S1-1), (A1) + (B1) + (C1) + (D4) + (S1-1), (A1) + (B1) + (C1) + (D5) + (S1-1), (A1) + (B1) + (C1) + (D6) + (S1-1), (A1) + (B1) + (C1) + (D7) + ( S1-1), (A1) + (B1) + (C1) + (D8) + (S1-1), (A1) + (B1) + (C1) + (D9) + (S1-1), ( A1) + (B1) + (C1) + 20 (D10) + (S1-1), (A1) + (B1) + (C1) + (D11) + (S1-1), (A1) + (B1 ) + (C1) + (D12) + (S1-1), (A1) + (B1) + (C1) + (D13) + (S1-1), (A1) + (B1) + (C1) + (D14) + (S1-1), (A1) + (B1) + (C1) + (D15) + (S1-1), (A1) + (B1) + (C1) + (D16) + (S1 -1), (A1) + (B1) + (C1) + (D17) + (S1-1), (A1) + (B1) + (C1) + (D18) + (S1-1), (A1 ) + (B1) + (C1) + (D19) + (S1-1), (A1) + (B1) + (C1) + (D20) + (S1-1), (A1) + (B1) + (C1) + (D21) + 25 (S1-1), (A1) + (B1) + (C1) + (D22) + (S1-1), (A1) + (B1) + (C1) + ( D23) + (S1-1), (A1) + (B1) + (C1) + (D24) + (S1-1), (A1) + (B1) + (C1) + (D25) + (S1- 1), (A1) + (B1) + (C1) + (D26) + (S1-1), (A1) + (B1) + (C1) + (D27) + (S1-1), (A1) + (B1) + (C1) + (D28) + (S1-1), (A1) + (B1) + (C1) + (D29) + (S1-1), (A1) + (B1 ) + (C1) + (D30) + - ~ - - (St), fAT) + (BT + (01) '+ " (D31) + (Sf-Ϊ), (A1) + (B1) + (C1 ) + (D32) + (S1-1) (A1) " 30 + (B1) + (C1) + (D33) + (S1-1), (A1) + (B1) + (C1) + (D34) + (S1-1), (A1) + (B1) + (C1) + (D35) + (S1-1), (A1) + (B1) + (C1) + (D36) + (S1-1) , (A1) + (B1) + (C1) + (D37) + (S1-1), (A1) + (B1) + (C1) + (D38) + (S1-1), (A1) + ( B1) + (C1) + (D39) + (S1-1), (A1) + (B1) + (C1) + (D40) + (S1-1), (A1) + (B1) + (C1) + (D41) + (S1-1), (A1) + (B1) + (C1) + (D42) + (S1-1), (A1) + (B1) + (C1) + (D43) + (S1-1), (A1) + (B1 ) + (C1) + (D44) + (S1-1), (A1) + (B1) + (C1) + (D45) + (S1-1), (A1) + (B1) + (C1) + (D46) + (S1-1), (A1) + (B1) + (C1) + (D47) + (S1-1), (A1) + (B1) + (C1) + (D48) + (S1 -1), (A1) + (B1) + (C1) + (D49) + (S1-1), (A1) + (B1) + (C1) + (D50) + (S1-1), (A1 ) + (B1) + (C1) + (D51) + (S1-1), (A1) + (B1) + (C1) + (D52) + (S1-1), (A1) + (B1) + (C1) + (D53) + (S1-1), (A1) + (B1) + (C1) + (D54) + (S1-1), (A1) + (B1) + (C1) + (D55 ) + (S1-1), (A1) + (B1) + (C1) + (D56) + (S1-1), (A1) + (B1) + (C1) + (D57) + (S1-1 ), (A1) + (B1) + (C1) + (D58) + (S1-1), (A1) + (B1) + (C1) + (D59) + (S1-1), (A1) + (B1) + (C1) + (D60) + (S1-1), (A1) + (B1) + (C1) + (D61) + (S1-1), (A1) + (B1) + (C1 ) + (D62), (A1) + (B1) + (C1) + (D63), (A1) + (B1) + (C1) + (D64), (A1) + (B1) + (C1) + (D65);
(A1) + (B1) + (C2) + (D1) + (S1-1), (A1) + (B1) + (C2) + (D2) + (S1-1), (A1) + (B1) + (C2) + (D3) + (S1-1), (A1) + (B1) + (C2) + (D4) + (S1-1), (A1) + (B1) + (C2) + (D5) + (S1-1), (A1) + (B1) + (C2) + (D6) + (S1-1), (A1) + (B1) + (C2) + (D7) + (S1-1), (A1) + (B1) + (C2) + (D8) + (S1-1), (A1) + (B1) + (C2) + (D9) + (S1-1), (A1) + (B1) + (C2) + (D10) + (S1-1), (A1) + (B1) + (C2) + (D11) + (S1-1), (A1) + (B1) + (C2) + (D12) + (S1-1), (A1) + (B1) + (C2) + (D13) + (S1-1), (A1) + (B1) + (C2) + (D14) + (S1-1), (A1) + (B1) + (C2) + (D15) + (S1-1), (A1) + (B1) + (C2) + (D16) + (S1-1), (A1) + (B1) + (C2) + (D17) + (S1-1), (A1) + (B1) + (C2) + (D18) + (S1-1), (A1) + (B1) + (C2) + (D19) + (S1-1), (A1) + (B1) + (C2) + (D20) + (S1-1) , (A1) + (B1) + (C2) + (D21) + (S1-1), (A1) + (B1) + (C2) + (D22) + (S1-1), (A1) + (B1) + (C2) + (D23) + (S1-1), (A1) + (B1) + (C2) + (D24) + (S1-1), (A1) + (B1) + (C2) + (D25) + (S1-1), (A1) + (B1) + (C2) + (D26) + (S1-1), (A1) + (B1) + (C2) + (D27) + (S1-1), (A1) + (B1) + (C2) + (D28) + (S1-1), (A1) + (B1) + (C2) + (D29) + (S1-1), (A1) + (B1) + (C2) + (D30) + (S1-1), (A1) + (B1) + (C2) + (D31) + (S1-1), (A1) + (B1) + (C2) + (D32) + (S1-1), (A1) + (B1) + (C2) + (D33) + (S1-1), (A1) + (B1) + (C2) + (D34) + (S1-1), (A1) + (B1) + (C2) +- (D3~5) + (S -I), (A1 ) + (B1 ) + (C2) + (D36) + {ST-1 ), (A1 ) *-(B1 ) + (C2) +-=" (D37) + (S1-1), (A1) + (B1) + (C2) + (D38) + (S1-1), (A1) + (B1) + (C2) + (D39) +(A1) + (B1) + (C2) + (D1) + (S1-1), (A1) + (B1) + (C2) + (D2) + (S1-1), (A1) + (B1 ) + (C2) + (D3) + (S1-1), (A1) + (B1) + (C2) + (D4) + (S1-1), (A1) + (B1) + (C2) + (D5) + (S1-1), (A1) + (B1) + (C2) + (D6) + (S1-1), (A1) + (B1) + (C2) + (D7) + (S1 -1), (A1) + (B1) + (C2) + (D8) + (S1-1), (A1) + (B1) + (C2) + (D9) + (S1-1), (A1 ) + (B1) + (C2) + (D10) + (S1-1), (A1) + (B1) + (C2) + (D11) + (S1-1), (A1) + (B1) + (C2) + (D12) + (S1-1), (A1) + (B1) + (C2) + (D13) + (S1-1), (A1) + (B1) + (C2) + (D14 ) + (S1-1), (A1) + (B1) + (C2) + (D15) + (S1-1), (A1) + (B1) + (C2) + (D16) + (S1-1 ), (A1) + (B1) + (C2) + (D17) + (S1-1), (A1) + (B1) + (C2) + (D18) + (S1-1), (A1) + (B1) + (C2) + (D19) + (S1-1), (A1) + (B1) + (C2) + (D20) + (S1-1), (A1) + (B1) + (C2 ) + (D21) + (S1-1), (A1) + (B1) + (C2) + (D22) + (S1-1), (A1) + (B1) + (C2) + (D23) + (S1-1), (A1) + (B1) + (C2) + (D24) + (S1-1), (A1) + (B1) + (C2) + (D25) + (S1-1), (A1) + (B1) + (C2) + (D26) + (S1-1), (A1) + (B1) + (C2) + (D27) + (S1-1), (A1) + (B 1) + (C2) + (D28) + (S1-1), (A1) + (B1) + (C2) + (D29) + (S1-1), (A1) + (B1) + (C2) + (D30) + (S1-1), (A1) + (B1) + (C2) + (D31) + (S1-1), (A1) + (B1) + (C2) + (D32) + ( S1-1), (A1) + (B1) + (C2) + (D33) + (S1-1), (A1) + (B1) + (C2) + (D34) + (S1-1), ( A1) + (B1) + (C2) + - (D3 ~ 5) + (S -I), (A1) + (B1) + (C2) + (D36) + {ST-1), (A1) * - (B1) + (C2) + - = " (D37) + (S1-1), (A1) + (B1) + (C2) + (D38) + (S1-1), (A1) + (B1 ) + (C2) + (D39) +
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(A1) + (B2) + (C1) + (D1) + (S1-1), (A1) + (B2) + (C1) + (D2) + (S1-1), (A1) + (B2) + (C1) + (D3) + (S1-1), (A1) + (B2) + (C1) + (D4) + (S1-1), (A1) + (B2) + (C1) + (D5) + (S1-1), (A1) + (B2) + (C1) + (D6) + (S1-1), (A1) + (B2) + (C1) + (D7) + (S1-1), (A1) + (B2) + (C1) + (D8) + (S1-1), (A1) + (B2) + (C1) + (D9) + (S1-1), (A1) + (B2) + (C1) + (D10) + (S1-1), (A1) + (B2) + (C1) + (D11) + (S1-1), (A1) + (B2) + (C1) + (D12) + (S1-1), (A1) + (B2) + (C1) + (D13) + (S1-1), (A1) + (B2) + (C1) + (D14) + (S1-1), (A1) + (B2) + (C1) + (D15) + (S1-1), (A1) + (B2) + (C1) + (D16) + (S1-1), (A1) + (B2) + (C1) + (D17) + (S1-1), (A1) + (B2) + (C1) + (D18) + (S1-1), (A1) + (B2) + (C1) + (D19) + (S1-1), (A1) + (B2) + (C1) + (D20) + (S1-1), (A1) + (B2) + (C1) + (D21) +(A1) + (B2) + (C1) + (D1) + (S1-1), (A1) + (B2) + (C1) + (D2) + (S1-1), (A1) + (B2 ) + (C1) + (D3) + (S1-1), (A1) + (B2) + (C1) + (D4) + (S1-1), (A1) + (B2) + (C1) + (D5) + (S1-1), (A1) + (B2) + (C1) + (D6) + (S1-1), (A1) + (B2) + (C1) + (D7) + (S1 -1), (A1) + (B2) + (C1) + (D8) + (S1-1), (A1) + (B2) + (C1) + (D9) + (S1-1), (A1 ) + (B2) + (C1) + (D10) + (S1-1), (A1) + (B2) + (C1) + (D11) + (S1-1), (A1) + (B2) + (C1) + (D12) + (S1-1), (A1) + (B2) + (C1) + (D13) + (S1-1), (A1) + (B2) + (C1) + (D14 ) + (S1-1), (A1) + (B2) + (C1) + (D15) + (S1-1), (A1) + (B2) + (C1) + (D16) + (S1-1 ), (A1) + (B2) + (C1) + (D17) + (S1-1), (A1) + (B2) + (C1) + (D18) + (S1-1), (A1) + (B2) + (C1) + (D19) + (S1-1), (A1) + (B2) + (C1) + (D20) + (S1-1), (A1) + (B2) + (C1 ) + (D21) +
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- -- " (S- 1),-(A ) + (E3f+
Figure imgf000031_0001
(D49) +*(S1-1), (A1) + (B3) + (C1) + (D50) +~(S1-1),-(A1)- - " (S- 1), - (A) + (E3f +
Figure imgf000031_0001
(D49) + * (S1-1), (A1) + (B3) + (C1) + (D50) + ~ (S1-1), - (A1)
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Figure imgf000041_0001
(027) + (S1-9); (A1) + (B4)"+ (C2) +' (D28) + (S1-9), (A1) + (B4) + (C2) + (D29) + (S1-9), (A1) + (B4) + (C2) + (D30) +(A1) + (B4) + (C2) + (D1) + (S1-9), (A1) + (B4) + (C2) + (D2) + (S1-9), (A1) + (B4 ) + (C2) + (D3) + (S1-9), (A1) + (B4) + (C2) + (D4) + (S1-9), (A1) + (B4) + (C2) + (D5) + (S1-9), (A1) + (B4) + (C2) + (D6) + (S1-9), (A1) + (B4) + (C2) + (D7) + (S1 -9), (A1) + (B4) + (C2) + (D8) + (S1-9), (A1) + (B4) + (C2) + (D9) + (S1-9), (A1 ) + (B4) + (C2) + (D10) + (S1-9), (A1) + (B4) + (C2) + (D11) + (S1-9), (A1) + (B4) + (C2) + (D12) + (S1-9), (A1) + (B4) + (C2) + (D13) + (S1-9), (A1) + (B4) + (C2) + (D14 ) + (S1-9), (A1) + (B4) + (C2) + (D15) + (S1-9), (A1) + (B4) + (C2) + (D16) + (S1-9 ), (A1) + (B4) + (C2) + (D17) + (S1-9), (A1) + (B4) + (C2) + (D18) + (S1-9), (A1) + (B4) + (C2) + (D19) + (S1-9), (A1) + (B4) + (C2) + (D20) + (S1-9), (A1) + (B4) + (C2 ) + (D21) + (S1-9), (A1) + (B4) + (C2) + (D22) + (S1-9), (A1) + (B4) + (C2) + (D23) + (S1-9), (A1) + (B4) + (C2) + (D24) + (S1-9), (A1) + (B4) + (C2) + (D25) + (S1-9), (A1) + (B4) + (02) + (D2B) + " (S? -9) " , (M + i J B4) +
Figure imgf000041_0001
(027) + (S1-9); (A1) + (B4) " + (C2) + ' (D28) + (S1-9), (A1) + (B4) + (C2) + (D29) + (S1-9), (A1) + (B4) + (C2) + (D30) +
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15 (S2-1), (A1) + (B2) + (C2) + (D13) + (S2-1), (A1) + (B2) + (C2) + (D14) + (S2-1), (A1) + (B2) + (C2) + (D15) + (S2-1), (A1) + (B2) + (C2) + (D16) + (S2-1), (A1) + (B2) + (C2) + (D17) + (S2-1), (A1) + (B2) + (C2) + (D18) + (S2-1), (A1) + (B2) + (C2) + (D19) + (S2-1), (A1) + (B2) + (C2) + (D20) + (S2-1), (A1) + (B2) + (C2) + (D21) + (S2-1), (A1) + (B2) + (C2) + (D22) + (S2-1), (A1) + (B2) + (C2) + (D23) + (S2-1), (A1)15 (S2-1), (A1) + (B2) + (C2) + (D13) + (S2-1), (A1) + (B2) + (C2) + (D14) + (S2-1) , (A1) + (B2) + (C2) + (D15) + (S2-1), (A1) + (B2) + (C2) + (D16) + (S2-1), (A1) + ( B2) + (C2) + (D17) + (S2-1), (A1) + (B2) + (C2) + (D18) + (S2-1), (A1) + (B2) + (C2) + (D19) + (S2-1), (A1) + (B2) + (C2) + (D20) + (S2-1), (A1) + (B2) + (C2) + (D21) + ( S2-1), (A1) + (B2) + (C2) + (D22) + (S2-1), (A1) + (B2) + (C2) + (D23) + (S2-1), ( A1)
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25 (C2) + (D35) + (S2-1), (A1) + (B2) + (C2) + (D36) + (S2-1), (A1) + (B2) + (C2) + (D37) + (S2-1), (A1) + (B2) + (C2) + (D38) + (S2-1), (A1) + (B2) + (C2) + (D39) + (S2-1), (A1) + (B2) + (C2) + (D40) + (S2-1), (A1) + (B2) + (C2) + (D41) + (S2-1), (A1) + (B2) + (C2) + (D42) + (S2-1), (A1) + (B2) + (C2) + (D43) + (S2-1), (A1) + (B2) +25 (C2) + (D35) + (S2-1), (A1) + (B2) + (C2) + (D36) + (S2-1), (A1) + (B2) + (C2) + ( D37) + (S2-1), (A1) + (B2) + (C2) + (D38) + (S2-1), (A1) + (B2) + (C2) + (D39) + (S2- 1), (A1) + (B2) + (C2) + (D40) + (S2-1), (A1) + (B2) + (C2) + (D41) + (S2-1), (A1) + (B2) + (C2) + (D42) + (S2-1), (A1) + (B2) + (C2) + (D43) + (S2-1), (A1) + (B2) +
' " -~ ■ (C2) + (D447 + (S2-1), (AI ) ^(&2)'+=(C2^ + (D45) +- (S2-1 ), (Mf+'{B2) + (C2) + '" - ~ ■ (C2) + (D447 + (S2-1), (AI) ^ (& 2) ' + = (C2 ^ + (D45) + - (S2-1), (Mf + ' {B2) + (C2) +
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(S2-1), (A1) + (B3) + (C1) + (D31) + (S2-1), (A1) + (B3) + (C1) + (D32) + (S2-1), (A1) + (B3) + (C1) + (D33) + (S2-1), (A1) + (B3) + (C1) + (D34) + (S2-1), (A1) + (B3) + (C1) + (D35) + (S2-1), (A1) + (B3) + (C1) + (D36) + (S2-1), (A1) + (B3) + (C1) + (D37) + (S2-1), (A1) + (B3) + (C1) + (D38) + (S2-1), (A1) + (B3) + (C1) + (D39) + (S2-1), (A1) + (B3) + (C1) + (D40) + (S2-1), (A1) + (B3) + (C1) + (D41) + (S2-1), (A1) + (B3) + (C1) + (D42) + (S2-1), (A1) + (B3) + (C1) + (D43) + (S2-1), (A1) + (B3) + (C1) + (D44) + (S2-1), (A1) + (B3) + (C1) + (D45) + (S2-1), (A1) + (B3) + (C1) + (D46) + (S2-1), (A1) + (B3) + (C1) + (D47) + (S2-1), (A1) + (B3) + (C1) + (D48) +
Figure imgf000046_0001
(O1 + (D49) + (S2-*T), (A1) + (B3J + (C1) + (D50) + (S2-1), (A1) + (B3) + (C1) + (D51) + (S2-1), (A1) + (B3) + (C1) + (D52) + (S2-1), (A1) + (B3) + (C1) + (D53) + (S2-1), (A1) + (B3) + (C1) + (D54) + (S2-1), (A1) + (B3) + (C1) + (D55) + (S2-1), (A1) + (B3) + (C1) + (D56) + (S2-1), (A1) + (B3) + (C1) + (D57) + (S2-1), (A1) + (B3) + (C1) + (D58) + (S2-1), (A1) + (B3) + (C1) + (D59) + (S2-1), (A1) + (B3) + (C1) + (D60) + (S2-1), (A1) + (B3) + (C1) + (D61) + (S2-1), (A1) + (B3) + (C1) + (D62) + (S2-1), (A1) + (B3) + (C1) + (D63) + (S2-1), (A1) + (B3) + (C1) + (D64) + (S2-1), (A1) + (B3) + (C1) + (D65) + (S2-1);(S2-1), (A1) + (B3) + (C1) + (D31) + (S2-1), (A1) + (B3) + (C1) + (D32) + (S2-1), (A1) + (B3) + (C1) + (D33) + (S2-1), (A1) + (B3) + (C1) + (D34) + (S2-1), (A1) + (B3 ) + (C1) + (D35) + (S2-1), (A1) + (B3) + (C1) + (D36) + (S2-1), (A1) + (B3) + (C1) + (D37) + (S2-1), (A1) + (B3) + (C1) + (D38) + (S2-1), (A1) + (B3) + (C1) + (D39) + (S2 -1), (A1) + (B3) + (C1) + (D40) + (S2-1), (A1) + (B3) + (C1) + (D41) + (S2-1), (A1 ) + (B3) + (C1) + (D42) + (S2-1), (A1) + (B3) + (C1) + (D43) + (S2-1), (A1) + (B3) + (C1) + (D44) + (S2-1), (A1) + (B3) + (C1) + (D45) + (S2-1), (A1) + (B3) + (C1) + (D46 ) + (S2-1), (A1) + (B3) + (C1) + (D47) + (S2-1), (A1) + (B3) + (C1) + (D48) +
Figure imgf000046_0001
(O1 + (D49) + (S2- * T), (A1) + (B3J + (C1) + (D50) + (S2-1), (A1) + (B3) + (C1) + (D51) + (S2-1), (A1) + (B3) + (C1) + (D52) + (S2-1), (A1) + (B3) + (C1) + (D53) + (S2-1) , (A1) + (B3) + (C1) + (D54) + (S2-1), (A1) + (B3) + (C1) + (D55) + (S2-1), (A1) + ( B3) + (C1) + (D56) + (S2-1), (A1) + (B3) + (C1) + (D57) + (S2-1), (A1) + (B3) + (C1) + (D58) + (S2-1), (A1) + (B3) + (C1) + (D59) + (S2-1), (A1) + (B3) + (C1) + (D60) + (S2-1), (A1) + (B3) + (C1) + (D61) + (S2-1), (A1) + (B3 ) + (C1) + (D62) + (S2-1), (A1) + (B3) + (C1) + (D63) + (S2-1), (A1) + (B3) + (C1) + (D64) + (S2-1), (A1) + (B3) + (C1) + (D65) + (S2-1);
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+ (B4) + (C2) + (D33) + (S2-1 , (A1) + (B4) + (C2) + (D34) + (S2-1), (A1) + (B4) + (C2) + (D35) + (S2-1), (A1) + B4) + (C2) + (D36) + (S2-1), (A1) + (B4) + (C2) + (D37) + (S2-1), (A1) + (B4) + C2) + (D38) + (S2-1), (A1) + (B4) + (C2) + (D39) ++ (B4) + (C2) + (D33) + (S2-1, (A1) + (B4) + (C2) + (D34) + (S2-1), (A1) + (B4) + (C2 ) + (D35) + (S2-1), (A1) + B4) + (C2) + (D36) + (S2-1), (A1) + (B4) + (C2) + (D37) + ( S2-1), (A1) + (B4) + C2) + (D38) + (S2-1), (A1) + (B4) + (C2) + (D39) +
(S2-1), (A1) + (B4) + (C2) + (D40) + (S2-1), (A1) + (B4) + (C2) + (D41) + (S2-1), (A1)(S2-1), (A1) + (B4) + (C2) + (D40) + (S2-1), (A1) + (B4) + (C2) + (D41) + (S2-1), (A1)
+ (B4) + (C2) + (D42) + (S2-1 , (A1) + (B4) + (C2) + (D43) + (S2-1), (A1) + (B4) + (C2) + (D44) + (S2-1), (A1) + B4) + (C2) + (D45) + (S2-1), (A1) + (B4) + (C2) + (D46) + (S2-1), (A1) + (B4) + C2) + (D47) + (S2-1), (A1) + (B4) + (C2) + (D48) ++ (B4) + (C2) + (D42) + (S2-1, (A1) + (B4) + (C2) + (D43) + (S2-1), (A1) + (B4) + (C2 ) + (D44) + (S2-1), (A1) + B4) + (C2) + (D45) + (S2-1), (A1) + (B4) + (C2) + (D46) + ( S2-1), (A1) + (B4) + C2) + (D47) + (S2-1), (A1) + (B4) + (C2) + (D48) +
(S2-1), (A1) + (B4) + (C2) + (D49) + (S2-1), (A1) + (B4) + (C2) + (D50) + (S2-1), (A1)(S2-1), (A1) + (B4) + (C2) + (D49) + (S2-1), (A1) + (B4) + (C2) + (D50) + (S2-1), (A1)
+ (B4) + (C2) + (D51) + (S2-1 , (A1) + (B4) + (C2) + (D52) + (S2-1), (A1) + (B4) + (C2) + (D53) + (S2-1), (A1) + B4) + (C2) + (D54) + (S2-1), (A1) + (B4) + (C2) + (D55) + (S2-1), (A1) + (B4) + C2) + (D56) + (S2-1), (A1) + (B4) + (C2) + (D57) ++ (B4) + (C2) + (D51) + (S2-1, (A1) + (B4) + (C2) + (D52) + (S2-1), (A1) + (B4) + (C2 ) + (D53) + (S2-1), (A1) + B4) + (C2) + (D54) + (S2-1), (A1) + (B4) + (C2) + (D55) + ( S2-1), (A1) + (B4) + C2) + (D56) + (S2-1), (A1) + (B4) + (C2) + (D57) +
(S2-1), (A1) + (B4) + (C2) + (D58) + (S2-1), (A1) + (B4) + (C2) + (D59) + (S2-1), (A1)(S2-1), (A1) + (B4) + (C2) + (D58) + (S2-1), (A1) + (B4) + (C2) + (D59) + (S2-1), (A1)
+ (B4) + (C2) + (D60) + (S2-1 , (A1) + (B4) + (C2) + (D61) + (S2-1), (A1) + (B4) + (C2) + (D62) + (S2-1), (A1) + B4) + (C2) + (D63) + (S2-1), (A1) + (B4) + (C2) + (D"64)s +:(SΪf), (A1 ) + (B4> '++ (B4) + (C2) + (D60) + (S2-1, (A1) + (B4) + (C2) + (D61) + (S2-1), (A1) + (B4) + (C2 ) + (D62) + (S2-1), (A1) + B4) + (C2) + (D63) + (S2-1), (A1) + (B4) + (C2) + (D " 64) s + : (SΪf), (A1) + (B4>'+
Es kann sinnvoll sein, ein oder mehrere Herbizide (A) mit einem oder mehreren Herbiziden (B) und einem/oder mehreren Herbiziden (C) zu kombinieren, z.B. ein Herbizid (A) mit einem Herbizid (B) und einem Herbizid (C). Weiterhin können die erfindungsgemäßen Herbizid-Kombinationen zusammen mit anderen agrochemischen Wirkstoffen beispielsweise aus der Gruppe der Safener, Fungizide, Herbizide, insbesondere aus der Gruppe der Herbizide (D), Insektizide und Pflanzenwachstumsregulatoren oder im Pflanzenschutz üblichen Zusatzstoffen wie Düngemitteln und Farbstoffen und Formulierungshilfsmittel eingesetzt werden, wobei die oben genannten Aufwandmengenbereiche undIt may be useful to combine one or more herbicides (A) with one or more herbicides (B) and / or more herbicides (C), for example one Herbicide (A) with one herbicide (B) and one herbicide (C). Furthermore, the herbicide combinations according to the invention can be used together with other agrochemical active ingredients, for example from the group of safeners, fungicides, herbicides, in particular from the group of herbicides (D), insecticides and plant growth regulators or additives customary in crop protection, such as fertilizers and dyes and formulation auxiliaries, the above ranges of application rates and
Aufwandmengenverhältnisse jeweils bevorzugt sind. Das Aufwandmengenverhältnis (A + B + C) : D beträgt im allgemeinen 2500 : 1 - 1 : 500, vorzugsweise 1000 : 1 - 1 : 300. Erfindungsgemäß sind auch Herbizid-Kombinationen mit mehreren Herbiziden D), z.B. solche, die als Komponente D) folgende Herbizid-Kombinationen enthalten: D35 + D29, D1 + D42, D1 + D65, D44 + D45, D43 + D45, D46 + D32, D33 + D35 oder D48 + D57, wobei bevorzugt als Komponenten (A), (B) und (C) die Verbindungen (A1) + (B1) + (C1), (A1) + (B1) + (C2), (A1) + (B2) + (C1), (A1) + (B2) + (C2), (A1) + (B3) + (C1), (A1) + (B3) + (C2), (A1) + (B4) + (C1) oder (A1) + (B4) + (C2), insbesondere (A1) + (B2) + (C2), enthalten sind, und zusätzlich ein Safener wie (S1-1), (S1-9) oder (S2-1) enthalten sein kann, insbesondere (S1-1).Application ratios are preferred in each case. The application rate ratio (A + B + C): D is generally 2500: 1-1: 500, preferably 1000: 1-1: 300. Herbicide combinations with several herbicides D), e.g. those containing the following herbicide combinations as component D): D35 + D29, D1 + D42, D1 + D65, D44 + D45, D43 + D45, D46 + D32, D33 + D35 or D48 + D57, preferably as components ( A), (B) and (C) the compounds (A1) + (B1) + (C1), (A1) + (B1) + (C2), (A1) + (B2) + (C1), (A1 ) + (B2) + (C2), (A1) + (B3) + (C1), (A1) + (B3) + (C2), (A1) + (B4) + (C1) or (A1) + (B4) + (C2), in particular (A1) + (B2) + (C2), are contained, and additionally a safener such as (S1-1), (S1-9) or (S2-1) can be contained, in particular (S1-1).
Die erfindungsgemäßen Kombinationen (= herbiziden Mittel) weisen eine ausgezeichnete herbizide Wirksamkeit gegen ein breites Spektrum wirtschaftlich wichtiger mono- und dikotyler Schadpflanzen auf. Auch schwer bekämpfbare perennierende Unkräuter, die aus Rhizomen, Wurzelstöcken oder anderen Dauerorganen austreiben, werden durch die Wirkstoffe gut erfaßt. Dabei ist es gleichgültig, ob die Substanzen im Vorsaat-, Vorauflauf- oder Nachauflaufverfahren ausgebracht werden. Bevorzugt ist die Anwendung im Nachauflaufverfahren oder im frühen Nachsaat-Vorauflaufverfahren.The combinations according to the invention (= herbicidal compositions) have excellent herbicidal activity against a broad spectrum of economically important mono- and dicotyledonous harmful plants. Perennial weeds that are difficult to control and that sprout from rhizomes, rhizomes or other permanent organs are also well captured by the active ingredients. It does not matter whether the substances are applied by pre-sowing, pre-emergence or post-emergence. Use in the post-emergence process or in the early post-sowing pre-emergence process is preferred.
Im einzelnen seien beispielhaft einige Vertreter der mono- und dikotylen UnkrautflO gerTäfϊnt.'cfiS dür rTdie erfihdungsgemäßen Verbindungen kontrolliert werden können, ohne daß durch die Nennung eine Beschränkung auf bestimmte Arten erfolgen soll. Auf der Seite der monokotylen Unkrautarten werden z.B. Apera spica venti, Avena spp., Alopecurus spp., Brachiaria spp., Digitaria spp., Lolium spp., Echinochloa spp., Panicum spp., Phalaris spp., Poa spp., Setaria spp. sowie Bromus spp. wie Bromus catharticus, Bromus secalinus, Bromus erectus, Bromus tectorum und Bromus japonicus und Cyperusarten aus der annuellen Gruppe und auf Seiten der perennierenden Spezies Agropyron, Cynodon, Imperata sowie Sorghum und auch ausdauernde Cyperusarten gut erfaßt.Some representatives of the monocotyledonous and dicotyledon weed flocks are examples. The cfiS should be able to control the compounds according to the invention without the name being intended to restrict them to certain species. On the side of the monocotyledon weed species, for example, Apera spica venti, Avena spp., Alopecurus spp., Brachiaria spp., Digitaria spp., Lolium spp., Echinochloa spp., Panicum spp., Phalaris spp., Poa spp., Setaria spp , and Bromus spp. such as Bromus catharticus, Bromus secalinus, Bromus erectus, Bromus tectorum and Bromus japonicus and Cyperus species from the annual group and on the part of the perennial species Agropyron, Cynodon, Imperata as well as sorghum and also persistent Cyperus species.
Bei dikotylen Unkrautarten erstreckt sich das Wirkungsspektrum auf Arten wie z.B. Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp., Ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp., Polygonum spp.,Sida spp., Sinapis spp., Solanum spp., Stellaria spp., Veronica spp. und Viola spp., Xanthium spp., Paphaver rhoeas spp., Centaurea spp. auf der annuellen Seite sowie Convolvulus, Cirsium, Rumex und Artemisia spp. bei den perennierenden Unkräutern.With dicotyledon weed species, the spectrum of activity extends to species such as Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp., Ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp., Polygonum spp., Sida spp., Sinapis spp ., Solanum spp., Stellaria spp., Veronica spp. and Viola spp., Xanthium spp., Paphaver rhoeas spp., Centaurea spp. on the annual side as well as Convolvulus, Cirsium, Rumex and Artemisia spp. in the perennial weeds.
Werden die erfindungsgemäßen Herbizid-Kombinationen vor dem Keimen auf die Erdoberfläche appliziert, so wird entweder das Auflaufen der Unkrautkeimlinge vollständig verhindert oder die Unkräuter wachsen bis zum Keimblattstadium heran, stellen jedoch dann ihr Wachstum ein und sterben schließlich nach Ablauf von drei bis vier Wochen vollkommen ab.If the herbicide combinations according to the invention are applied to the surface of the earth before germination, either the weed seedlings emerge completely or the weeds grow to the cotyledon stage, but then stop growing and finally die completely after three to four weeks ,
Bei Applikation der Wirkstoffe auf die grünen Pflanzenteile im Nachauflaufverfahren tritt ebenfalls sehr rasch nach der Behandlung ein drastischer Wachstumsstop ein und die Unkrautpflanzen bleiben in dem zum Applikationszeitpunkt vorhandenen Wachstumsstadium stehen oder sterben nach einer gewissen Zeit ganz ab, so daß auf diese Weise eine für die Kulturpflanzen schädliche Unkrautkonkurrenz sehr früh und nachhaltig beseitigt wird.When the active ingredients are applied to the green parts of the plant in the post-emergence process, there is also a drastic growth stop very quickly after the treatment and the weed plants remain in the growth stage at the time of application or die completely after a certain time, so that one for the crop plants harmful weed competition is eliminated very early and sustainably.
Die erfindungsgemäßen herbiziden Mittel zeichnen sich durch eine schnell einsetzende und lang andauernde herbizide Wirkung aus. Die Regenfestigkeit der Wirkstoffe in den erfindungsgemäßen Kombinationen ist in der Regel günstig. Als besonderer Vorteil fällt ins Gewicht, daß die in den Kombinationen verwendeten und wirksamen Dosierungen von Verbindungen (A), (B) und (C) so gering eingestellt werden können, daß ihre Bodenwirkung optimal niedrig ist. Somit wird deren Einsatz nicht nur in empfindlichen Kulturen erst möglich, sondern Grundwasser- Kontaminationen werden praktisch vermieden. Durch die erfindungsgemäßen Kombination von Wirkstoffen wird eine erhebliche Reduzierung der nötigen Aufwandmenge der Wirkstoffe ermöglicht.The herbicidal compositions according to the invention are notable for a rapid onset and long-lasting herbicidal action. The rain resistance of the active ingredients in the combinations according to the invention is generally favorable. As A particular advantage is that the effective dosages of compounds (A), (B) and (C) used in the combinations can be set so low that their soil effect is optimally low. This makes their use not only possible in sensitive crops, but groundwater contamination is practically avoided. The combination of active substances according to the invention enables a considerable reduction in the amount of active substances required.
Bei der gemeinsamen Anwendung von Herbiziden des Typs (A)+(B)+(C) treten in bevorzugter Ausführungsform überadditive (= synergistische) Effekte auf. Dabei ist die Wirkung in den Kombinationen stärker als die zu erwartende Summe der Wirkungen der eingesetzten Einzelherbizide. Die synergistischen Effekte erlauben eine Reduzierung der Aufwandmenge, die Bekämpfung eines breiteren Spektrums von Unkräutern und Ungräsern, einen schnelleren Einsatz der herbiziden Wirkung, eine längere Dauerwirkung, eine bessere Kontrolle der Schadpflanzen mit nur einer bzw. wenigen Applikationen sowie eine Ausweitung des möglichen Anwendungszeitraumes. Teilweise wird durch den Einsatz der Mittel auch die Menge an schädlichen Inhaltsstoffen, wie Stickstoff oder Ölsäure, und deren Eintrag in den Boden reduziert.When herbicides of the type (A) + (B) + (C) are used together, in a preferred embodiment, superadditive (= synergistic) effects occur. The effect in the combinations is stronger than the expected total of the effects of the individual herbicides used. The synergistic effects allow a reduction in the application rate, the control of a broader spectrum of weeds and weeds, a faster use of the herbicidal action, a longer lasting effect, better control of the harmful plants with only one or a few applications and an expansion of the possible application period. In part, the use of the agents also reduces the amount of harmful ingredients, such as nitrogen or oleic acid, and their entry into the soil.
Die genannten Eigenschaften und Vorteile sind in der praktischen Unkrautbekämpfung von Nutzen, um landwirtschaftliche Kulturen von unerwünschten Konkurrenzpflanzen freizuhalten und damit die Erträge qualitativ und quantitativ zu sichern und/oder zu erhöhen. Der technische Standard wird durch diese neuen Kombinationen hinsichtlich der beschriebenen Eigenschaften deutlich übertroffen.The properties and advantages mentioned are useful in practical weed control in order to keep agricultural crops free of undesired competing plants and thus to ensure and / or increase the yields qualitatively and quantitatively. These new combinations significantly exceed the technical standard in terms of the properties described.
Obgleich die erfindungsgemäßen Kombinationen eine ausgezeichnete herbizide Aktivität gegenüber mono- und dikotylen Schadpflanzen aufweisen, werden die Kulturpflanzen nur unwesentlich oder gar nicht geschädigt. Darüberhinaus weisen die erfindungsgemäßen Mittel teilweise hervorragende wachstuimsregulatorische Eigenschaften bei den Kulturpflanzen auf. Sie greifen regulierend in den pflanzeneigenen Stoffwechsel ein und können damit zur gezielten Beeinflussung von Pflanzeninhaltsstoffen und zur Ernteerleichterung wie z.B. durch Auslösen von Desikkation und Wuchsstauchung eingesetzt werden. Desweiteren eignen sie sich auch zur generellen Steuerung und Hemmung von unerwünschtem vegetativen Wachstum, ohne dabei die Pflanzen abzutöten. Eine Hemmung des vegetativen Wachstums spielt bei vielen mono- und dikotylen Kulturen eine große Rolle, da Ernteverluste beim Lagern hierdurch verringert oder völlig verhindert werden können.Although the combinations according to the invention have excellent herbicidal activity against monocotyledonous and dicotyledonous harmful plants, the crop plants are damaged only insignificantly or not at all. In addition, some of the agents according to the invention have excellent growth-regulatory properties in the crop plants. They intervene regulating the plant's own metabolism and can thus be used to influence plant constituents in a targeted manner and to facilitate harvesting, for example by triggering desiccation and stunted growth. Furthermore, they are also suitable for general control and inhibition of undesirable vegetative growth without killing the plants. Inhibiting vegetative growth plays a major role in many monocotyledonous and dicotyledonous crops, as this can reduce or completely prevent crop losses during storage.
Aufgrund ihrer herbiziden und pflanzenwachstumsregulatorischen Eigenschaften können die erfindungsgemäßen Mittel zur Bekämpfung von Schadpflanzen in gentechnisch veränderten oder durch Mutationsselektion erhaltenen Kulturpflanzen eingesetzt werden. Diese Kulturpflanzen zeichnen sich in der Regel durch besondere vorteilhafte Eigenschaften aus, wie Resistenzen gegenüber herbiziden Mitteln oder Resistenzen gegenüber Pflanzenkrankheiten oder Erregern von Pflanzenkrankheiten wie bestimmten Insekten oder Mikroorganismen wie Pilzen, Bakterien oder Viren. Andere besondere Eigenschaften betreffen z. B. das Erntegut hinsichtlich Menge, Qualität, Lagerfähigkeit, Zusammensetzung und spezieller Inhaltsstoffe. So sind z.B. transgene Pflanzen mit erhöhtem Stärkegehalt oder veränderter Qualität der Stärke oder solche mit anderer Fettsäurezusammensetzung des Ernteguts bekannt. Herkömmliche Wege zur Herstellung neuer Pflanzen, die im Vergleich zu bisher vorkommenden Pflanzen modifizierte Eigenschaften aufweisen, bestehen beispielsweise in klassischen Züchtungsverfahren und der Erzeugung von Mutanten (siehe z.B. US 5,162,602; US 4,761,373; US 4,443,971). Alternativ können neue Pflanzen mit veränderten Eigenschaften mit Hilfe gentechnischer Verfahren erzeugt -werden (siehe z. B. EP-A-0221O44, EP-A-Q1"31624y. Beschrieben wurden beispielsweise in mehreren Fällen gentechnische Veränderungen von Kulturpflanzen zwecks Modifikation der in den Pflanzen synthetisierten Stärke (z. B. WO 92/11376, WO 92/14827, transgene Kulturpflanzen, welche Resistenzen gegen andere Herbizide aufweisen, beispielsweise gegen Sulfonylharnstoffe (US-A-5013659), transgene Kulturpflanzen, mit der Fähigkeit Bacillus thuringiensis-Toxine (Bt-Toxine) zu produzieren, welche die Pflanzen gegen bestimmte Schädlinge resistent machen (EP-A-0142924, EP-A-0193259). transgene Kulturpflanzen mit modifizierter Fettsäurezusammensetzung (WO 91/13972).Because of their herbicidal and plant growth regulatory properties, the agents according to the invention for controlling harmful plants can be used in genetically modified crops or crop plants obtained by mutation selection. These crop plants are generally distinguished by special advantageous properties, such as resistance to herbicidal compositions or resistance to plant diseases or pathogens causing plant diseases such as certain insects or microorganisms such as fungi, bacteria or viruses. Other special properties concern e.g. B. the crop in terms of quantity, quality, shelf life, composition and special ingredients. For example, transgenic plants with an increased starch content or altered starch quality or those with a different fatty acid composition of the crop are known. Conventional ways of producing new plants which have modified properties in comparison to previously occurring plants are, for example, classic breeding methods and the generation of mutants (see, for example, US Pat. No. 5,162,602; US Pat. No. 4,761,373; US Pat. No. 4,443,971). Alternatively, new plants with modified properties can be produced with the aid of genetic engineering processes (see, for example, EP-A-0221O44, EP-A-Q1 " 31624y). In several cases, for example, genetic engineering changes in crop plants have been described in order to modify those in the plants synthesized starch (e.g. WO 92/11376, WO 92/14827, transgenic crop plants which are resistant to other herbicides, for example sulfonylureas (US-A-5013659), transgenic crop plants with the ability to produce Bacillus thuringiensis toxins (Bt toxins) which make the plants resistant to certain pests (EP- A-0142924, EP-A-0193259). transgenic crop plants with modified fatty acid composition (WO 91/13972).
Zahlreiche molekularbiologische Techniken, mit denen neue transgene Pflanzen mit veränderten Eigenschaften hergestellt werden können, sind im Prinzip bekannt; siehe z.B. Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2. Aufl. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; oder Winnacker "Gene und Klone", VCH Weinheim 2. Auflage 1996 oder Christou, "Trends in Plant Science" 1 (1996) 423-431).In principle, numerous molecular biological techniques with which new transgenic plants with modified properties can be produced are known; see e.g. Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd ed. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker "Gene and Clones", VCH Weinheim 2nd edition 1996 or Christou, "Trends in Plant Science" 1 (1996) 423-431).
Für derartige gentechnische Manipulationen können Nucleinsäuremoleküle in Plasmide eingebracht werden, die eine Mutagenese oder eine Sequenzveränderung durch Rekombination von DNA-Sequenzen erlauben. Mit Hilfe der obengenannten Standardverfahren können z. B. Basenaustausche vorgenommen, Teilsequenzen entfernt oder natürliche oder synthetische Sequenzen hinzugefügt werden. Für die Verbindung der DNA-Fragmente untereinander können an die Fragmente Adaptoren oder Linker angesetzt werden.For such genetic engineering manipulations, nucleic acid molecules can be introduced into plasmids which allow mutagenesis or a sequence change by recombining DNA sequences. With the help of the standard procedures mentioned above, e.g. B. base exchanges, partial sequences removed or natural or synthetic sequences added. To connect the DNA fragments to one another, adapters or linkers can be attached to the fragments.
Die Herstellung von Pflanzenzellen mit einer verringerten Aktivität eines Genprodukts kann beispielsweise erzielt werden durch die Expression mindestens einer entsprechenden antisense-RNA, einer sense-RNA zur Erzielung eines CosuppreBsiönseffektes ödertlie" Expression mindestens eines entsprechend konstruierten Ribozyms, das spezifisch Transkripte des obengenannten Genprodukts spaltet. Hierzu können zum einen DNA-Moleküle verwendet werden, die die gesamte codierende Sequenz eines Genprodukts einschließlich eventuell vorhandener flankierender Sequenzen umfassen, als auch DNA-Moleküle, die nur Teile der codierenden Sequenz umfassen, wobei diese Teile lang genug sein müssen, um in den Zellen einen antisense-Effekt zu bewirken. Möglich ist auch die Verwendung von DNA-Sequenzen, die einen hohen Grad an Homologie zu den codiereden Sequenzen eines Genprodukts aufweisen, aber nicht vollkommen identisch sind.The production of plant cells with a reduced activity of a gene product can be achieved, for example by expressing at least one corresponding antisense RNA, a sense RNA for achieving a CosuppreBsiönseffektes ödertlie "expression of at least cleaves one suitably constructed ribozyme which specifically cleaves transcripts of the abovementioned gene product. For this purpose, DNA molecules can be used that comprise the entire coding sequence of a gene product, including any flanking sequences that may be present, as well as DNA molecules that only comprise parts of the coding sequence, these parts having to be long enough to be in the cells to cause an antisense effect. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product, but which are not completely identical.
Bei der Expression von Nucleinsäuremolekülen in Pflanzen kann das synthetisierte Protein in jedem beliebigen Kompartiment der pflanzlichen Zelle lokalisiert sein. Um aber die Lokalisation in einem bestimmten Kompartiment zu erreichen, kann z. B. die codierende Region mit DNA-Sequenzen verknüpft werden, die die Lokalisierung in einem bestimmten Kompartiment gewährleisten. Derartige Sequenzen sind dem Fachmann bekannt (siehe beispielsweise Braun et al., EMBO J. 11 (1992), 3219- 3227; Wolter et al., Proc. Natl. Acad. Sei. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1991), 95-106).When nucleic acid molecules are expressed in plants, the synthesized protein can be located in any compartment of the plant cell. However, in order to achieve localization in a particular compartment, z. B. the coding region can be linked to DNA sequences that ensure localization in a particular compartment. Such sequences are known to the person skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1: 95-106 (1991).
Die transgenen Pflanzenzellen können nach bekannten Techniken zu ganzen Pflanzen regeneriert werden. Bei den transgenen Pflanzen kann es sich prinzipiell um Pflanzen jeder beliebigen Pflanzenspezies handeln, d.h. sowohl monokotyle als auch dikotyle Pflanzen. So sind transgene Pflanzen erhältlich, die veränderte Eigenschaften durch Überexpression, Suppression oder Inhibierung homologer (= natürlicher) Gene oder Gensequenzen oder Expression heterologer (= fremder) Gene oder Gensequenzen aufweisen.The transgenic plant cells can be regenerated into whole plants using known techniques. The transgenic plants can in principle be plants of any plant species, i.e. both monocot and dicot plants. Thus, transgenic plants are available which have changed properties due to overexpression, suppression or inhibition of homologous (= natural) genes or gene sequences or expression of heterologous (= foreign) genes or gene sequences.
Gegenstand der vorliegenden Erfindung ist weiterhin auch ein Verfahren zur Bekämpfung von unerwünschtem Pflanzenwuchs (z.B. Schadpflanzen wie Unkräuter oder unerwünschte Kulturpflanzen), vorzugsweise in Pflanzenkulturen wie--fet'reideT(z.BTWeizerτ Gersfeτ Roggen, Hafer; Kreuzungen davon wie riticaler Reis, Mais, Hirse), Zuckerrübe, Zuckerrohr, Raps, Baumwolle und Soja, besonders bevorzugt in monokotylen Kulturen wie Getreide, z.B. Weizen, Gerste, Roggen, Hafer, Kreuzungen davon wie Triticale, Reis, Mais und Hirse, wobei man ein oder mehrere Herbizide des Typs (A) mit einem oder mehreren Herbiziden des Typs (B) und einem oder mehreren Herbiziden des Typs (C) gemeinsam oder getrennt, z.B. im Vorauflauf, Nachauflauf oder im Vor- und Nachauflauf, auf die Pflanzen, z.B. Schadpflanzen, Pflanzenteile, Pflanzensamen oder die Fläche auf der die Pflanzen 5 wachsen, z.B. die Anbaufläche appliziert.The present invention furthermore also relates to a process for controlling unwanted vegetation (for example harmful plants such as weeds or undesired crop plants), preferably in crops such as - fet ' reideT (for example wheat rye, rye, oats; hybrids thereof such as ritical rice, maize, Millet), sugar beet, sugar cane, rapeseed, cotton and soy, particularly preferably in monocot crops such as cereals, for example wheat, barley, rye, oats, crosses thereof such as triticale, rice, corn and millet, one or several herbicides of type (A) with one or more herbicides of type (B) and one or more herbicides of type (C) together or separately, for example pre-emergence, post-emergence or pre-post-emergence, on the plants, for example harmful plants, Plant parts, plant seeds or the area on which the plants 5 grow, for example the cultivated area applied.
Unter unerwünschten Pflanzen sind dabei alle Pflanzen zu verstehen, die an Orten wachsen, wo sie unerwünscht sind. Dies können z.B. Schadpflanzen (z.B. Unkräuter oder unerwünschte Kulturpflanzen) sein, z.B. auch solche, die gegen bestimmte 10 herbizide Wirkstoffe wie Glyphosate, Atrazin, Glufosinate oder Imidazolinone resistent sind.Undesirable plants are understood to mean all plants that grow in places where they are undesirable. This can e.g. Harmful plants (e.g. weeds or unwanted crops), e.g. also those that are resistant to certain 10 herbicidal active ingredients such as glyphosate, atrazine, glufosinate or imidazolinones.
Die Pflanzenkulturen können auch gentechnisch verändert oder durch Mutationsselektion erhalten sein und sind bevorzugt tolerant gegenüber 15 Acetolactatsynthase (ALS)-Inhibitoren.The plant cultures can also be genetically modified or obtained by mutation selection and are preferably tolerant of 15 acetolactate synthase (ALS) inhibitors.
Gegenstand der Erfindung ist auch die Verwendung der erfindungsgemäßen Herbizid-Kombinationen aus Verbindungen (A)+(B)+(C) zur Bekämpfung von Schadpflanzen, vorzugsweise in Pflanzenkulturen.The invention also relates to the use of the herbicide combinations according to the invention of compounds (A) + (B) + (C) for controlling harmful plants, preferably in plant crops.
20 Die erfindungsgemäßen herbiziden Mittel können auch nicht-selektiv zur Bekämpfung unerwünschten Pflanzenwuchses eingesetzt werden, z.B. in Plantagenkulturen, an Wegrändern, Plätzen, Industrieanlagen oder Eisenbahnanlagen.20 The herbicidal compositions according to the invention can also be used non-selectively for controlling unwanted vegetation, e.g. in plantation crops, on roadsides, squares, industrial plants or railway systems.
25 Die erfindungsgemäßen Wirkstoffkombinationen können sowohl als Mischformulierungen der Komponenten (A), (B) und (C) gegebenenfalls mit weiteren agrochemischen Wirkstoffen, Zusatzstoffen und/oder üblichen *----.-_ -pσrrπ iferuπgshJifsmJ teln vorliegen, die dann in üblicher Weise mit Wasser verdünnt^ 30 zur Anwendung gebracht werden, oder als sogenannte Tankmischungen durch gemeinsame Verdünnung der getrennt formulierten oder partiell getrennt formulierten Komponenten mit Wasser hergestellt werden. Die Komponenten (A), (B) und (C) können auch getrennt formuliert und getrennt ausgebracht werden, so dass sich die erfindungsgemäße Wirkstoffkombination am Applikationsort bildet.The active substance combinations according to the invention can be used both as mixed formulations of components (A), (B) and (C), if appropriate with further agrochemical active substances, additives and / or customary * ---- . -_ -pσrrπ iferuπgshJifsmJ teln are present, which are then diluted with water in the usual way ^ 30 to use, or prepared as so-called tank mixes by jointly diluting the separately formulated or partially separately formulated components with water. The components (A), (B) and (C) can also be formulated separately and applied separately, so that the active compound combination according to the invention forms at the application site.
Die Verbindungen (A), (B) und (C) oder deren Kombinationen können auf 5 verschiedene Art formuliert werden, je nachdem welche biologischen und/oder chemisch-physikalischen Parameter vorgegeben sind. Als allgemeine Formulierungsmöglichkeiten kommen beispielsweise in Frage: Spritzpulver (WP), wasserlösliche Konzentrate, emulgierbare Konzentrate (EC), wäßrige Lösungen (SL), Emulsionen (EW) wie Öl-in-Wasser- und Wasser-in-ÖI-Emulsionen,0 versprühbare Lösungen oder Emulsionen, Suspensionskonzentrate (SC), Dispersionen auf Öl- oder Wasserbasis, Suspoemulsionen, Stäubemittel (DP), Beizmittel, Granulate zur Boden- oder Streuapplikation oder wasserdispergierbare Granulate (WG), ULV-Formulierungen, Mikrokapseln oder Wachse. 5 Die einzelnen Formulierungstypen sind im Prinzip bekannt und werden beispielsweise beschrieben in: Winnacker-Küchler, "Chemische Technologie", Band 7, C. Hauser Verlag München, 4. Aufl. 1986; van Valkenburg, "Pesticide Formulations", Marcel Dekker N.Y., 1973; K. Martens, "Spray Drying Handbook", 3rd Ed. 1979, G. Goodwin Ltd. London.0 Die notwendigen Formulierungshilfsmittel wie Inertmaterialien, Tenside, Lösungsmittel und weitere Zusatzstoffe sind ebenfalls bekannt und werden beispielsweise beschrieben in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell N.J.; H.v. Olphen, "Introduction to Clay5 Colloid Chemistry"; 2nd Ed., J. Wiley & Sons, N.Y. Marsden, "Solvents Guide", 2nd Ed., Interscience, N.Y. 1950; McCutcheon's, "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridegewood N.J.; Sisley and Wood, "Encyclopedia of Surface Active Agents", Chem. Publ. Co. Inc., N.Y. 1964; Schönfeldt, "Grenzflächenaktive r - - Äthylenöxidaddükfe", Wissr feτlags^eseltsehaft, Stuttgart 976 Winnacker-Küchler 0 "Chemische Technologie", Band 7, C. Hauser Verlag München, 4. Aufl. 1986. Auf der Basis dieser Formulierungen lassen sich auch Kombinationen mit anderen agrochemischen Wirkstoffen, wie anderen Herbiziden, Fungiziden, Insektiziden, sowie Safenern, Düngemitteln und/oder Wachstumsregulatoren herstellen, z.B. in Form einer Fertigformulierung oder als Tankmix.The compounds (A), (B) and (C) or their combinations can be formulated in 5 different ways, depending on which biological and / or chemical-physical parameters are specified. Examples of general formulation possibilities are: wettable powder (WP), water-soluble concentrates, emulsifiable concentrates (EC), aqueous solutions (SL), emulsions (EW) such as oil-in-water and water-in-oil emulsions, 0 sprayable Solutions or emulsions, suspension concentrates (SC), dispersions based on oil or water, suspoemulsions, dusts (DP), mordants, granules for soil or litter application or water-dispersible granules (WG), ULV formulations, microcapsules or waxes. 5 The individual types of formulation are known in principle and are described, for example, in: Winnacker-Küchler, "Chemical Technology", Volume 7, C. Hauser Verlag Munich, 4th ed. 1986; van Valkenburg, "Pesticide Formulations", Marcel Dekker NY, 1973; K. Martens, "Spray Drying Handbook", 3rd Ed. 1979, G. Goodwin Ltd. London.0 The necessary formulation aids such as inert materials, surfactants, solvents and other additives are also known and are described, for example, in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell NJ; Hv Olphen, "Introduction to Clay5 Colloid Chemistry"; 2nd Ed., J. Wiley & Sons, NY Marsden, "Solvents Guide", 2nd Ed., Interscience, NY 1950; McCutcheon's, Detergents and Emulsifiers Annual, MC Publ. Corp., Ridegewood NJ; Sisley and Wood, "Encyclopedia of Surface Active Agents", Chem. Publ. Co. Inc., NY 1964; Schönfeldt, "Grenzflächenaktiv r - - Äthylenöxidaddükfe", Wissr feτlags ^ eseltsehaft, Stuttgart 976 Winnacker-Küchler 0 "Chemische Technologie", Volume 7, C. Hauser Verlag Munich, 4th ed. 1986. Combinations can also be made on the basis of these formulations with other agrochemical active ingredients, such as other herbicides, fungicides, insecticides, as well as safeners, fertilizers and / or growth regulators, for example in the form of a finished formulation or as a tank mix.
Spritzpulver (benetzbare Pulver) sind in Wasser gleichmäßig dispergierbare Präparate, die neben dem Wirkstoff außer einem Verdünnungs- oder Inertstoff noch Tenside ionischer oder nichtionischer Art (Netzmittel, Dispergiermittel), z.B. polyoxethylierte Alkylphenole, polyethoxylierte Fettalkohole oder -Fettamine, Alkansulfonate oder Alkylbenzolsulfonate, ligninsulfonsaures Natrium, 2,2'- dinaphthylmethan-6,6'-disulfonsaures Natrium, dibutylnaphthalin-sulfonsaures Natrium oder auch oleoylmethyltaurinsaures Natrium enthalten.Spray powders (wettable powders) are preparations which are uniformly dispersible in water and which, in addition to the active substance, contain not only a diluent or inert substance, but also ionic or nonionic surfactants (wetting agents, dispersing agents), e.g. polyoxethylated alkylphenols, polyethoxylated fatty alcohols or fatty amines, alkanesulfonates or alkylbenzenesulfonates, ligninsulfonic acid sodium, 2,2'-dinaphthylmethane-6,6'-disulfonic acid sodium, dibutylnaphthalene sulfonic acid sodium or also oleoylmethyl tauric acid sodium.
Emulgierbare Konzentrate werden durch Auflösen des Wirkstoffs in einem organischen Lösungsmittel, z.B. Butanol, Cyclohexanon, Dimethylformamid, Xylol oder auch höhersiedenden Aromaten oder Kohlenwasserstoffe unter Zusatz von einem oder mehreren ionischen oder nichtionischen Tensiden (Emulgatoren) hergestellt. Als Emulgatoren können beispielsweise verwendet werden: Alkylarylsulfonsaure Calcium-Salze wie Ca-Dodecylbenzolsulfonat oder nichtionische Emulgatoren wie Fettsäurepolyglykolester, Alkylarylpolyglykolether, Fettalkoholpolyglykolether, Propylenoxid-Ethylenoxid-Kondensationsprodukte, Alkylpolyether, Sorbitanfettsäureester, Polyoxyethylensorbitanfettsäureester oder Polyoxethylensorbitester.Emulsifiable concentrates are made by dissolving the active ingredient in an organic solvent, e.g. Butanol, cyclohexanone, dimethylformamide, xylene or higher-boiling aromatics or hydrocarbons with the addition of one or more ionic or nonionic surfactants (emulsifiers). Examples of emulsifiers which can be used are: alkylarylsulfonic acid calcium salts, such as calcium dodecylbenzenesulfonate, or nonionic emulsifiers, such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide / ethylene oxide condensation products, alkyl polyethers, sorbitan fatty acid ester sorbate polyethylenefatty acid sorboxate, polyoxyethylene ethoxylate sorbate, polyoxyethylene ethoxylate sorbet, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbitan acid ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbetyl ester, polyoxyethylene fatty acid sorbitan acid ester, polyoxyethylene fatty acid sorboxyl ester, polyoxyethylene fatty acid sorboxate, polyoxyethylene fatty acid sorboxate, polyoxyethylene ethoxylate,
Stäubemittel erhält man durch Vermählen des Wirkstoffs mit fein verteilten festen Stoffen, z.B. Talkum, natürlichen Tonen, wie Kaolin, Bentonit und Pyrophyllit, oder Diatomeenerde.Dusts are obtained by grinding the active ingredient with finely divided solid substances, e.g. Talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
Suspensionskonzentrate (SC) können auf Wasser- oder Ölbasis sein. Sie können beispielsweise durch Naß-Vermahlung mittels handelsüblicher Perlmühlen und gegeber ^alls^Os r-z-voή"weitererrT§r fden-, wre"sie z.B oben bei den anderen " Formulierungstypen bereits aufgeführt sind, hergestellt werden.Suspension concentrates (SC) can be water or oil based. They can be prepared, for example, by wet grinding using commercially available bead mills and, where appropriate, “ further, if they ” are already listed above for the other “ types of formulation ” .
Emulsionen, z.B. ÖI-in-Wasser-Emulsionen (EW), lassen sich beispielsweise mittels Rührern, Kolloidmühlen und/oder statischen Mischern unter Verwendung von wäßrigen organischen Lösungsmitteln und gegebenenfalls von weiteren Tensiden, wie sie z.B. oben bei den anderen Formulierungstypen bereits aufgeführt sind, herstellen.Emulsions, for example oil-in-water emulsions (EW), can be used, for example, using stirrers, colloid mills and / or static mixers aqueous organic solvents and optionally other surfactants, such as those already listed above for the other types of formulation.
Granulate können entweder durch Verdüsen des Wirkstoffs auf adsorptionsfähiges, granuliertes Inertmaterial hergestellt werden oder durch Aufbringen von Wirkstoffkonzentraten mittels Klebemitteln, z.B. Polyvinylalkohol, polyacrylsaurem Natrium oder auch Mineralölen, auf die Oberfläche von Trägerstoffen wie Sand, Kaolinite oder von granuliertem Inertmaterial. Auch können geeignete Wirkstoffe in der für die Herstellung von Düngemittelgranulaten üblichen Weise - gewünschtenfalls in Mischung mit Düngemitteln - granuliert werden. Wasserdispergierbare Granulate werden in der Regel nach den üblichen Verfahren wie Sprühtrocknung, Wirbelbett-Granulierung, Teller-Granulierung, Mischung mit Hochgeschwindigkeitsmischern und Extrusion ohne festes Inertmaterial hergestellt. Zur Herstellung von Teller-, Fließbett-, Extruder- und Sprühgranulate siehe z.B.Granules can either be produced by spraying the active ingredient onto adsorbable, granulated inert material or by applying active ingredient concentrates by means of adhesives, e.g. Polyvinyl alcohol, sodium polyacrylic acid or mineral oils, on the surface of carriers such as sand, kaolinite or granulated inert material. Suitable active ingredients can also be granulated in the manner customary for the production of fertilizer granules, if desired in a mixture with fertilizers. Water-dispersible granules are generally produced using the customary methods, such as spray drying, fluidized bed granulation, plate granulation, mixing with high-speed mixers and extrusion without solid inert material. For the production of plate, fluidized bed, extruder and spray granules, see e.g.
Verfahren in "Spray-Drying Handbook" 3rd ed. 1979, G. Goodwin Ltd., London; J.E. Browning, "Agglomeration", Chemical and Engineering 1967, Seiten 147 ff; "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York 1973, S. 8-57. Für weitere Einzelheiten zur Formulierung von Pflanzenschutzmitteln siehe z.B. G.C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York,Procedure in "Spray-Drying Handbook" 3rd ed. 1979, G. Goodwin Ltd., London; J.E. Browning, "Agglomeration", Chemical and Engineering 1967, pages 147 ff; "Perry's Chemical Engineer's Handbook," 5th Ed., McGraw-Hill, New York 1973, pp. 8-57. For more details on the formulation of crop protection products see e.g. G.C. Klingman, "Weed Control as a Science," John Wiley and Sons, Inc., New York,
1961 , Seiten 81-96 und J.D. Freyer, S.A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, Seiten 101-103.1961, pages 81-96 and J.D. Freyer, S.A. Evans, "Weed Control Handbook," 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pages 101-103.
Die agrochemischen Formulierungen enthalten in der Regel 0,1 bis 99 Gewichtsprozent, insbesondere 2 bis 95 Gew.-%, Wirkstoffe der Typen A und/oder B und/oder C, wobei je nach Formulierungsart folgende Konzentrationen üblich sind: In Spritzpulvern beträgt die Wirkstoffkonzentration z.B. etwa 10 bis 95 Gew.-%, der Rest zu 100 Gew.-% besteht aus üblichen Formulierungsbestandteilen. Beieτnu1gie7l areιτKi-τiz^ die Wirkstoffkσnzentratiori z.B. 5 bis" 80 Gew %7 betragen. Staubförmige Formulierungen enthalten meistens 5 bis 20 Gew.-% anThe agrochemical formulations generally contain 0.1 to 99 percent by weight, in particular 2 to 95% by weight, of active ingredients of types A and / or B and / or C, the following concentrations being customary depending on the type of formulation: the active ingredient concentration in wettable powders is for example about 10 to 95 wt .-%, the rest of 100 wt .-% consists of conventional formulation components. Beieτnu1gie7l areιτKi-τiz ^ the Wirkstoffkσnzentratiori eg 5 to be "80% by weight. 7 Dust-like formulations contain at most 5 to 20 wt .-%
Wirkstoff, versprühbare Lösungen etwa 0,2 bis 25 Gew.-% Wirkstoff. Bei Granulaten wie dispergierbaren Granulaten hängt der Wirkstoffgehalt zum Teil davon ab, ob die wirksame Verbindung flüssig oder fest vorliegt und welche Granulierhilsmittel und Füllstoffe verwendet werden. In der Regel liegt der Gehalt bei den in Wasser dispergierbaren Granulaten zwischen 10 und 90 Gew.-%. Daneben enthalten die genannten Wirkstofformulierungen gegebenenfalls die jeweils üblichen Haft-, Netz-, Dispergier-, Emulgier-, Konservierungs-, Frostschutz- und Lösungsmittel, Füll-, Färb- und Trägerstoffe, Entschäumer, Verdunstungshemmer und Mittel, die den pH-Wert oder die Viskosität beeinflussen.Active ingredient, sprayable solutions about 0.2 to 25 wt .-% active ingredient. In the case of granules such as dispersible granules, the active ingredient content depends in part on whether the active compound is liquid or solid and which granulating agents and fillers are used. As a rule, the content of the water-dispersible granules is between 10 and 90% by weight. In addition, the active ingredient formulations mentioned may contain the customary adhesives, wetting agents, dispersants, emulsifiers, preservatives, antifreezes and solvents, fillers, dyes and carriers, defoamers, evaporation inhibitors and agents which adjust the pH or Influence viscosity.
Die herbizide Wirkung der erfindungsgemäßen Herbizid-Kombinationen kann z.B. durch oberflächenaktive Substanzen verbessert werden, vorzugsweise durch Netzmittel aus der Reihe der Fettalkohol-Polyglykolether. Die Fettalkohol- Polyglykolether enthalten vorzugsweise 10 - 18 C-Atome im Fettalkoholrest und 2 - 20 Ethylenoxideinheiten im Polyglykoletherteil. Die Fettalkohol-Polyglykolether können nichtionisch vorliegen, oder ionisch, z.B. in Form von Fettalkohol- Polyglykolethersulfaten, vorliegen, die z.B. als Alkalisalze (z.B. Natrium- und Kaliumsalze) oder Ammoniumsalze, oder auch als Erdalkalisalze wie Magnesiumsalze verwendet werden, wie C-|2/Cι -Fettalkohol-diglykolethersulfat- Natrium (Genapol® LRO, Clariant GmbH); siehe z.B. EP-A-0476555, EP-A-0048436, EP-A-0336151 oder US-A-4,400,196 sowie Proc. EWRS Symp. "Factors Affecting Herbicidal Activity and Selectivity", 227 - 232 (1988). Nichtionische Fettalkohol- Polyglykolether sind beispielsweise 2 - 20, vorzugsweise 3 - 15, Ethylenoxideinheiten enthaltende (C10- C-ι8)-, vorzugsweise (C-ι0-Cι )-Fettalkohol- Polyglykolether (z.B. Isotridecylalkohol-Polyglykolether) z.B. aus der Genapol® X- Reihe wie Genapol® X-030, Genapol® X-060, Genapol® X-080 oder Genapol® X-150 (alle von Clariant GmbH).The herbicidal activity of the herbicide combinations according to the invention can be improved, for example, by surface-active substances, preferably by wetting agents from the range of fatty alcohol polyglycol ethers. The fatty alcohol polyglycol ethers preferably contain 10 to 18 carbon atoms in the fatty alcohol residue and 2 to 20 ethylene oxide units in the polyglycol ether part. The fatty alcohol polyglycol ethers can be nonionic or ionic, for example in the form of fatty alcohol polyglycol ether sulfates, which are used, for example, as alkali metal salts (for example sodium and potassium salts) or ammonium salts, or also as alkaline earth metal salts such as magnesium salts, such as C- | 2 / -C-fatty alcohol diglycol ether sulfate sodium (Genapol ® LRO, Clariant GmbH); see for example EP-A-0476555, EP-A-0048436, EP-A-0336151 or US-A-4,400,196 and Proc. EWRS Symp. "Factors Affecting Herbicidal Activity and Selectivity", 227-232 (1988). Nonionic fatty alcohol polyglycol ethers are, for example, 2 to 20, preferably 3 to 15, ethylene oxide units (C 10 -C 8 ), preferably (C 1 -C 0 ) fatty alcohol polyglycol ethers (for example isotridecyl alcohol polyglycol ether), for example from Genapol ® X series such as Genapol ® X-030, Genapol ® X-060, Genapol ® X-080 or Genapol ® X-150 (all from Clariant GmbH).
Die vorliegende Erfindung umfaßt ferner die Kombination von Herbiziden (A), (B) und (C) mit den vorgängig genannten Netzmitteln aus der Reihe der Fettalkohol-Polyglykolether, die vorzugsweise 10 - 18 C-Atofrie im Fettalkoholrest und 2 - 20 Ethylenoxideinheiten im Polyglykoletherteil enthalten und nichtionisch oder ionisch (z.B. als Fettalkohol-polyglykolethersulfate) vorliegen können. Bevorzugt sind Ci2/C14-Fettalkohol-diglykolethersulfat-Natrium (Genapol® LRO, Clariant GmbH) und Isotridecylalkohol-Polyglykolether, mit 3 - 15 Ethylenoxideneinheiten, z.B. aus der Genapol® X-Reihe wie Genapol® X-030, Genapol® X-060, Genapol® X-080 und Genapol® X-150 (alle von Clariant GmbH). Weiterhin ist bekannt, daß Fettalkohol- Polyglykolether wie nichtionische oder ionische Fettalkohol-polyglykolether (z.B. Fettalkohol-Polyglykolethersulfate) auch als Penetrationshilfsmittel und Wirkungsverstärker für eine Reihe anderer Herbizide, unter anderem auch für Herbizide aus der Reihe der Imidazolinone geeignet sind (siehe z.B. EP-A- 0502014). Weiterhin ist bekannt, daß Fettalkohol-Polyglykolether wie nichtionische oder ionische Fettalkohol-Polyglykolether (z.B. Fettalkohol-Polyglykolethersulfate) auch als Penetrationshilfsmittel und Wirkungsverstärker für eine Reihe anderer Herbizide, unter anderem auch für Herbizide aus der Reihe der Imidazolinone geeignet sind (siehe z.B. EP-A-0502014).The present invention further comprises the combination of herbicides (A), (B) and (C) with the above-mentioned wetting agents from the series of fatty alcohol polyglycol ethers, which preferably contain 10 to 18 carbon atoms in the fatty alcohol residue and 2 to 20 ethylene oxide units in the polyglycol ether part contain and can be non-ionic or ionic (for example as fatty alcohol polyglycol ether sulfates). Ci2 / C 14 fatty alcohol diglycol ether sulfate sodium (Genapol ® LRO, Clariant GmbH) are preferred, and Isotridecyl alcohol polyglycol ether, with 3 - 15 ethylene oxide units, e.g. from the Genapol ® X series such as Genapol ® X-030, Genapol ® X-060, Genapol ® X-080 and Genapol ® X-150 (all from Clariant GmbH). It is also known that fatty alcohol polyglycol ethers such as nonionic or ionic fatty alcohol polyglycol ethers (e.g. fatty alcohol polyglycol ether sulfates) are also suitable as penetration aids and activity enhancers for a number of other herbicides, including herbicides from the imidazolinone series (see, for example, EP-A - 0502014). It is also known that fatty alcohol polyglycol ethers such as nonionic or ionic fatty alcohol polyglycol ethers (e.g. fatty alcohol polyglycol ether sulfates) are also suitable as penetration aids and activity enhancers for a number of other herbicides, including herbicides from the imidazolinone series (see, for example, EP-A -0,502,014).
Die herbizide Wirkung der erfindungsgemäßen Herbizid-Kombinationen kann auch durch die Verwendung von Pflanzenölen verstärkt werden. Unter dem Begriff Pflanzenöle werden Öle aus ölliefernden Pflanzenarten wie Sojaöl, Rapsöl, Maiskeimöl, Sonnenblumenöl, Baumwollsaatöl, Leinöl, Kokosöl, Palmöl, Distelöl oder Rhizinusöl, insbesondere Rapsöl verstanden, sowie deren Umesterungsprodukte, z.B. Alkylester wie Rapsölmethylester oder Rapsölethylester.The herbicidal activity of the herbicide combinations according to the invention can also be enhanced by using vegetable oils. The term vegetable oils is understood to mean oils from oil-producing plant species such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, safflower oil or castor oil, in particular rapeseed oil, and their transesterification products, e.g. Alkyl esters such as rapeseed oil methyl ester or rapeseed oil ethyl ester.
Die Pflanzenöle sind bevorzugt Ester von Cιo-C22-, vorzugsweise C-i2-C20- Fettsäuren. Die C10-C22-Fettsäureester sind beispielsweise Ester ungesättigter oder gesättigter Cι0-C22-Fettsäuren, insbesondere mit gerader Kohlenstoffatomzahl, z.B. Erucasäure, Laurinsäure, Palmitinsäure und insbesondere Cι8-Fettsäuren wie Stearinsäure, Ölsäure, Linolsäure oder Linolensäure.The vegetable oils are preferably esters of Cιo-C 22 -, preferably C-i2-C 20 - fatty acids. The C 10 -C 22 fatty acid esters are, for example, esters of unsaturated or saturated C 0 -C 22 fatty acids, in particular with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular C 8 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
- Beispiete ür Cfo-C22-Fettsäüte-EsTersihdÄEster7'die durchrUmsetzung-von Glycerin oder Glykol mit den Cιo-C22-Fettsäuren erhalten werden, wie sie z.B. in Ölen aus ölliefernden Pflanzenarten enthalten sind, oder Cι-C2o-Alkyl-Cι0C22-Fettsäure-Ester, wie sie z.B. durch Umesterung der vorgenannten Glycerin- oder Giykol-Cιo-C22- Fettsäure-Ester mit Cι-C2o-Alkoholen (z.B. Methanol, Ethanol, Propanol oder Butanol) erhalten werden können. Die Umesterung kann nach bekannten Methoden erfolgen, wie sie z.B. beschrieben sind im Römpp Chemie Lexikon, 9. Auflage, Band 2, Seite 1343, Thieme Verlag Stuttgart.- Examples for Cfo-C 22 fatty acids-EsTersihd Ä Ester7 ' which are obtained by r- reaction of glycerol or glycol with the Cιo-C 22 fatty acids, such as those contained in oils from oil-producing plant species, or Cι-C 2 o-Alkyl -C 0 C 22 fatty acid esters, such as those obtained, for example, by transesterification of the above-mentioned glycerol or glycol-Cιo-C22- Fatty acid esters with C 2 -C 20 alcohols (for example methanol, ethanol, propanol or butanol) can be obtained. The transesterification can be carried out according to known methods, as described, for example, in the Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
Als Cι-C2o-Alkyl-Cιo-C22-Fettsäure-Ester bevorzugt sind Methylester, Ethylester, Propylester, Butylester, 2-ethyl-hexylester und Dodecylester. Als Glykol- und Glycerin-Cιo-C22-Fettsäure-Ester bevorzugt sind die einheitlichen oder gemischten Glykolester und Glycerinester von Cιo-C22-Fettsäuren, insbesondere solcher Fettsäuren mit gerader Anzahl an Kohlenstoffatomen, z.B. Erucasäure, Laurinsäure, Palmitinsäure und insbesondere C-iβ-Fettsäuren wie Stearinsäure, Ölsäure, Linolsäure oder Linolensäure.Preferred C 1 -C 20 -alkyl-C 22 -C 22 fatty acid esters are methyl esters, ethyl esters, propyl esters, butyl esters, 2-ethyl hexyl esters and dodecyl esters. Preferred as glycol and glycerol -CC 22 fatty acid esters are the uniform or mixed glycol esters and glycerol esters of -CC 22 fatty acids, in particular those fatty acids with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular C- iβ fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
Die Pflanzenöle können in den erfindungsgemäßen herbiziden Mitteln z.B. in Form kommerziell erhältlicher ölhaltiger Formulierungszusatzstoffe, insbesondere solcher auf Basis von Rapsöl wie Hasten® (Victorian Chemical Company, Australien, nachfolgend Hasten genannt, Hauptbestandteil: Rapsölethylester), Actirob®B (Novance, Frankreich, nachfolgend ActirobB genannt, Hauptbestandteil: Rapsölmethylester), Rako-Binol® (Bayer AG, Deutschland, nachfolgend Rako-Binol genannt, Hauptbestandteil: Rapsöl), Renol® (Stefes, Deutschland, nachfolgend Renol genannt, Pflanzenölbestandteil: Rapsölmethylester) oder Stefes Mero® (Stefes, Deutschland, nachfolgend Mero genannt, Hauptbestandteil: Rapsölmethylester) enthalten sein.The vegetable oils can be present in the inventive herbicidal compositions, for example in the form of commercially available oil-containing formulation additives, in particular those (hereinafter referred Victorian Chemical Company, Australia, Hasten, main constituent: rapeseed oil ethyl ester) based on rapeseed oil such as Hasten ®, Actirob ® B (Novance, France, hereinafter Called ActirobB, main component: rapeseed oil methyl ester), Rako-Binol ® (Bayer AG, Germany, hereinafter called Rako-Binol, main component: rapeseed oil), Renol ® (Stefes, Germany, hereinafter referred to as Renol, vegetable oil component: rapeseed oil methyl ester) or Stefes Mero ® (Stefes , Germany, hereinafter called Mero, main ingredient: rapeseed oil methyl ester).
Die vorliegende Erfindung umfasst in einer weiteren AusführungsformThe present invention comprises in a further embodiment
Kombinationen von Herbiziden (A), (B) und (C) mit den vorgängig genannten Pflanzenölen wie Rapsöl, bevorzugt in Form kommerziell erhältlicher ölhaltiger Formulierungszusatzstoffe, insbesondere solcher auf Basis von Rapsöl wie Hasten® (Victofiän Cheτπica eornpιaπy Ausfrä.ieτr nachfolgendΗasten genannt, - Hauptbestandteil: Rapsölethylester), Actirob®B (Novance, Frankreich, nachfolgend ActirobB genannt, Hauptbestandteil: Rapsölmethylester), Rako-Binol® (Bayer AG, Deutschland, nachfolgend Rako-Binol genannt, Hauptbestandteil: Rapsöl), Renol® (Stefes, Deutschland, nachfolgend Renol genannt, Pflanzenölbestandteil: Rapsölmethylester) oder Stefes Mero® (Stefes, Deutschland, nachfolgend Mero genannt, Hauptbestandteil: Rapsölmethylester).Combinations of herbicides (A), (B) and (C) with the vegetable oils mentioned above such as rapeseed oil, preferably in the form of commercially available oil-containing formulation additives, in particular those based on rapeseed oil such as Hasten ® (Victofiän Cheτπica eornpιaπy Ausfrä.ieτr hereinafter referred to as, - Main ingredient: rapeseed oil ethyl ester), Actirob ® B (Novance, France, hereinafter called ActirobB, main ingredient: rapeseed oil methyl ester), Rako-Binol ® (Bayer AG, Germany, hereinafter called Rako-Binol, main ingredient: rapeseed oil), Renol ® (Stefes, Germany, hereinafter called Renol, vegetable oil component: rapeseed oil methyl ester) or Stefes Mero ® (Stefes, Germany, hereinafter called Mero, main component: rapeseed oil methyl ester).
Zur Anwendung werden die in handelsüblicher Form vorliegenden Formulierungen gegebenenfalls in üblicher Weise verdünnt, z.B. bei Spritzpulvern, emulgierbaren Konzentraten, Dispersionen und wasserdispergierbaren Granulaten mittels Wasser. Staubförmige Zubereitungen, Boden- bzw. Streugranulate, sowie versprühbare Lösungen werden vor der Anwendung üblicherweise nicht mehr mit weiteren inerten Stoffen verdünnt.For use, the formulations present in the commercial form are optionally diluted in the customary manner, e.g. for wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules using water. Preparations in the form of dust, ground granules or granules for spreading, and sprayable solutions are usually no longer diluted with other inert substances before use.
Die Wirkstoffe können auf die Pflanzen, Pflanzenteile, Pflanzensamen oder die Anbaufläche (Ackerboden) ausgebracht werden, vorzugsweise auf die grünen Pflanzen und Pflanzenteile und gegebenenfalls zusätzlich auf den Ackerboden. Eine Möglichkeit der Anwendung ist die gemeinsame Ausbringung der Wirkstoffe in Form von Tankmischungen, wobei die optimal formulierten konzentrierten Formulierungen der Einzelwirkstoffe gemeinsam im Tank mit Wasser gemischt und die erhaltene Spritzbrühe ausgebracht wird. Eine gemeinsame herbizide Formulierung der erfindungsgemäßen Kombination an Wirkstoffen (A), (B) und (C) hat im allgemeinen den Vorteil der leichteren Anwendbarkeit.The active compounds can be applied to the plants, parts of plants, plant seeds or the area under cultivation (arable soil), preferably to the green plants and parts of plants and, if appropriate, additionally to the arable soil. One possible application is the joint application of the active ingredients in the form of tank mixes, the optimally formulated concentrated formulations of the individual active ingredients being mixed together with water in the tank and the spray liquor obtained being applied. A common herbicidal formulation of the combination according to the invention of active ingredients (A), (B) and (C) generally has the advantage of being easier to use.
A. Formulierungsbeispiele allgemeiner ArtA. General wording examples
a) Ein Stäubemittel wird erhalten, indem man 10 Gew. -Teile eines Wirkstoffs/Wirkstoffgemischs und 90 Gew. -Teile Talkum als Inertstoff mischt und in einer Schlagmühle zerkleinert.a) A dusting agent is obtained by mixing 10 parts by weight of an active substance / active substance mixture and 90 parts by weight of talc as an inert substance and comminuting them in a hammer mill.
b) Ein in Wasser leicht dispergierbares, benetzbares Pulver wird erhalten, indem man 25^Gew^Teile-%frιes""Wirkstoffs/Wifkstoffgemischs, 64 Gew. -Teile— kaolinhaltigen Quarz als Inertstoff, 10 Gew. -Teile ligninsulfonsaures Kalium und 1 Gew. -Teil oleoylmethyltaurinsaures Natrium als Netz- und Dispergiermittel mischt und in einer Stiftmühle mahlt. c) Ein in Wasser leicht dispergierbares Dispersionskonzentrat wird erhalten, indem man 20 Gew.-Teile eines Wirkstoffs/Wirkstoffgemischs mit 6 Gew.- Teilen Alkylphenolpolyglykolether (Triton® X 207), 3 Gew.-Teilen Isotridecanolpolyglykolether (8 EO) und 71 Gew.-Teilen paraffinischem Mineralöl (Siedebereich z.B. ca. 255 bis 277°C) mischt und in einer Reibkugelmühle auf eine Feinheit von unter 5 Mikron vermahlt.b) A readily water-dispersible wettable powder is obtained by mixing 25 wt ^ ^ parts-% frιes "" drug / Wifkstoffgemischs, 64 wt. -Teile- kaolin-containing quartz as inert substance, 10 parts by wt. of potassium lignosulfonate and 1 wt - Mixes sodium oleoylmethyl tauric acid as a wetting and dispersing agent and grinds it in a pin mill. c) A readily water-dispersible dispersion concentrate is obtained by mixing 20 parts by weight of an active compound / active compound mixture with 6 parts by weight of alkylphenol polyglycol ether (Triton ® X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 wt. Parts of paraffinic mineral oil (boiling range approx. 255 to 277 ° C) and ground in a friction ball mill to a fineness of less than 5 microns.
d) Ein emulgierbares Konzentrat wird erhalten aus 15 Gew.-Teilen eines Wirkstoffs/Wirkstoffgemischs, 75 Gew.-Teilen Cyclohexanon als Lösemittel und 10 Gew.-Teilen oxethyliertem Nonylphenol als Emulgator.d) An emulsifiable concentrate is obtained from 15 parts by weight of an active ingredient / active ingredient mixture, 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of oxyethylated nonylphenol as emulsifier.
e) Ein in Wasser dispergierbares Granulat wird erhalten indem man 75 Gew.-Teile eines Wirkstoffs/Wirkstoffgemischs, 10 Gew.-Teile ligninsulfonsaures Calcium, 5 Gew.-Teile Natriumlaurylsulfat, 3 Gew.-Teile Polyvinylalkohol und 7 Gew.-Teile Kaolin mischt, auf einer Stiftmühle mahlt und das Pulver in einem Wirbelbett durch Aufsprühen von Wasser als Granulierflüssigkeit granuliert.e) A water-dispersible granulate is obtained by mixing 75 parts by weight of an active ingredient / active ingredient mixture, 10 parts by weight of calcium lignosulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol and 7 parts by weight of kaolin , grinds on a pin mill and granulates the powder in a fluidized bed by spraying water as the granulating liquid.
f) Ein in Wasser dispergierbares Granulat wird auch erhalten, indem man 25 Gew.-Teile eines Wirkstoffs/Wirkstoffgemischs, 5 Gew.-Teile 2,2'-dinaphthylmethan-6,6'-disulfonsaures Natrium, 2 Gew.-Teile oleoylmethyltaurinsaures Natrium, 1 Gew.-Teil Polyvinylalkohol, 17 Gew.-Teile Calciumcarbonat und 50 Gew.-Teile Wasser
Figure imgf000064_0001
und vofzeTkleinert, anschließend au - einer Perlmühle mahlt und die so erhaltene Suspension in einem Sprühturm mittels einer Einstoffdüse zerstäubt und trocknet. B. Biologische Beispielef) A water-dispersible granulate is also obtained by adding 25 parts by weight of an active ingredient / active ingredient mixture, 5 parts by weight of 2,2'-dinaphthylmethane-6,6'-disulfonic acid sodium, 2 parts by weight of oleoylmethyl tauric acid sodium , 1 part by weight of polyvinyl alcohol, 17 parts by weight of calcium carbonate and 50 parts by weight of water
Figure imgf000064_0001
and vofzeTkleinert, then ground in a bead mill and the suspension thus obtained is atomized and dried in a spray tower using a single-component nozzle. B. Biological examples
Herbizide Wirkung (Feldversuche)Herbicidal activity (field trials)
Die Samen oder Rhizomstücke der Schadpflanzen und Nutzpflanzen wurden ausgelegt oder waren im Boden vorhanden und unter natürlichen Freilandbedingungen herangezogen. Die Behandlung mit den Wirkstoffen bzw. Wirkstoff-Kombinationen erfolgte nach, vor und/oder nach dem Auflaufen der Pflanzen in der Regel im 2 bis 4-Blattstadium in verschiedenen Dosierungen mit einer Wasseraufwandmenge von umgerechnet 100 bis 400 l/ha.The seeds or rhizome pieces of the harmful plants and useful plants were laid out or were present in the soil and grown under natural outdoor conditions. The treatment with the active ingredients or combinations of active ingredients was carried out after, before and / or after emergence of the plants, as a rule in the 2 to 4 leaf stage in various dosages with a water application rate of the equivalent of 100 to 400 l / ha.
Nach der Anwendung (ca. 4 Wochen nach Applikation) wurde die Wirksamkeit der Wirkstoffe bzw. Wirkstoff-Kombinationen anhand der behandelten Parzellen im Vergleich zu unbehandelten Kontroll-Parzellen visuell bonitiert. Dabei wurde Schädigung und Entwicklung aller oberirdischen Pflanzenteile erfaßt. Die Bonitierung erfolgte nach einer Prozentskala (100% Wirkung = alle Pflanzen abgestorben; 50 % Wirkung = 50% der Pflanzen und grünen Pflanzenteile abgestorben; 0 % Wirkung = keine erkennbare Wirkung = wie Kontrollparzelle). Die Boniturwerte von jeweils 2-4 Parzellen wurden gemittelt. Es wurde z.B. bei Anwendung der Wirkstoff-Kombination (A1) + (B2) + (C2) eine erhöhte herbizide Wirkung bei hoher Selektivität festgestellt. After application (approx. 4 weeks after application), the effectiveness of the active substances or combinations of active substances was assessed visually on the basis of the treated plots in comparison to untreated control plots. Damage and development of all parts of the plant above ground were recorded. The ratings were given on a percentage scale (100% effect = all plants died; 50% effect = 50% of the plants and green parts of the plants died; 0% effect = no recognizable effect = like control parcel). The ratings of 2-4 plots were averaged. For example, when using the active ingredient combination (A1) + (B2) + (C2) an increased herbicidal activity with high selectivity was found.

Claims

Patentansprüche claims
1. Herbizid-Kombination mit einem wirksamen Gehalt an Komponenten (A), (B) und (C), wobei1. Herbicide combination with an effective content of components (A), (B) and (C), wherein
(A) ein oder mehrere Herbizide aus der Gruppe der Verbindungen der Formel (I) und deren Salzen bedeutet,(A) one or more herbicides from the group of the compounds of the formula (I) and their salts,
Figure imgf000066_0001
Figure imgf000066_0001
(B) ein oder mehrere Herbizide aus der Gruppe der Verbindungen der Formel (II) und deren Salzen und Ester bedeutet,(B) one or more herbicides from the group of the compounds of the formula (II) and their salts and esters,
Figure imgf000066_0002
Figure imgf000066_0002
(C) ein oder mehrere Herbizide aus der Gruppe der Verbindungen der Formel (II) und deren Salzen bedeutet.(C) one or more herbicides from the group of the compounds of the formula (II) and their salts.
Figure imgf000066_0003
Figure imgf000066_0003
2. Herbizid-Kombination nach Anspruch 1 , worin als Komponente (A) Diflufenican, als Komponente (B) loxynil, loxynil-octanoat, loxynil-Natrium und/oder loxynil-Kalium, und als Komponente (C) Propoxycarbazone und/oder Propoxycarbazone-Natrium enthalten ist. 2. Herbicide combination according to claim 1, wherein as component (A) diflufenican, as component (B) loxynil, loxynil octanoate, loxynil sodium and / or loxynil potassium, and as component (C) propoxycarbazone and / or propoxycarbazone Sodium is included.
3. Herbizid-Kombination nach Anspruch 1 oder 2, zusätzlich enthaltend eine oder mehrere weitere Komponenten aus der Gruppe enthaltend agrochemische Wirkstoffe anderer Art, im Pflanzenschutz übliche Zusatzstoffe und3. Herbicide combination according to claim 1 or 2, additionally containing one or more further components from the group containing agrochemical active substances of another type, additives customary in crop protection and
5 Formulierungshilfsmittel.5 formulation aids.
4. Herbizid-Kombination nach einem oder mehreren der Ansprüche 1 bis 3, zusätzlich enthaltend einen oder mehrere Safener. 04. Herbicide combination according to one or more of claims 1 to 3, additionally containing one or more safeners. 0
5. Herbizid-Kombination nach einem oder mehreren der Ansprüche 1 bis 4, zusätzlich enthaltend einen oder mehrere Fettalkohol-Polyglykolether und/oder eines oder mehrere Pflanzenöle.5. Herbicide combination according to one or more of claims 1 to 4, additionally containing one or more fatty alcohol polyglycol ethers and / or one or more vegetable oils.
6. Verfahren zur Bekämpfung von unerwünschtem Pflanzenwuchs, worin die5 Herbizide (A), (B) und (C), definiert gemäß Anspruch 1 oder 2, gemeinsam oder getrennt auf die Pflanzen, Pflanzenteile, Pflanzensamen oder die Fläche, auf der die Pflanzen wachsen, appliziert werden.A method of controlling undesirable plant growth, wherein the herbicides (A), (B) and (C), defined according to claim 1 or 2, together or separately on the plants, parts of plants, plant seeds or the area on which the plants grow , can be applied.
7. Verfahren nach Anspruch 6 zur selektiven Bekämpfung von Schadpflanzen in0 Pflanzenkulturen.7. The method according to claim 6 for the selective control of harmful plants in0 plant crops.
8. Verfahren nach Anspruch 7 zur Bekämpfung von Schadpflanzen in monokotylen Pflanzenkulturen. 58. The method according to claim 7 for controlling harmful plants in monocot plant crops. 5
9. Verfahren nach Anspruch 7 oder 8, worin die Pflanzenkulturen gentechnisch verändert oder durch Mutationsselektion erhalten sind.9. The method according to claim 7 or 8, wherein the plant cultures are genetically modified or obtained by mutation selection.
10. Verwendung der nach einem der Ansprüche 1 bis 5 definierten Herbizid- "-^ 'Kombination iuTi.- -.kampfuf.g von uπerwüri§clTfe Pflanzeriwuchs, z.B:0 Schadpflanzen. 10. Use of the herbicide- " - ^ 'combination iuTi.- -.kampfuf.g defined by one of claims 1 to 5 of uπerwüri§clTfe plant growth, for example: 0 harmful plants.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0210818A1 (en) * 1985-07-23 1987-02-04 May & Baker Limited Herbicidal method comprising the use of diflufenican
WO2003028467A1 (en) * 2001-09-27 2003-04-10 Syngenta Participations Ag Herbicidal composition

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US3397054A (en) * 1962-08-30 1968-08-13 Schering Corp Process for controlling plant growth
US4943544A (en) * 1989-10-10 1990-07-24 Corhart Refractories Corporation High strength, abrasion resistant refractory castable
US5534486A (en) * 1991-04-04 1996-07-09 Bayer Aktiengesellschaft Herbicidal sulphonylaminocarbonyl triazolinones having substituents bonded via oxygen
US5549859A (en) * 1992-08-11 1996-08-27 E. Khashoggi Industries Methods for the extrusion of novel, highly plastic and moldable hydraulically settable compositions
US5527387A (en) * 1992-08-11 1996-06-18 E. Khashoggi Industries Computer implemented processes for microstructurally engineering cementious mixtures
US7137448B2 (en) * 2003-12-22 2006-11-21 Bj Services Company Method of cementing a well using composition containing zeolite

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0210818A1 (en) * 1985-07-23 1987-02-04 May & Baker Limited Herbicidal method comprising the use of diflufenican
WO2003028467A1 (en) * 2001-09-27 2003-04-10 Syngenta Participations Ag Herbicidal composition

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