WO2005009934A3 - Two-stage hydroformylation - Google Patents

Two-stage hydroformylation Download PDF

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Publication number
WO2005009934A3
WO2005009934A3 PCT/EP2004/008209 EP2004008209W WO2005009934A3 WO 2005009934 A3 WO2005009934 A3 WO 2005009934A3 EP 2004008209 W EP2004008209 W EP 2004008209W WO 2005009934 A3 WO2005009934 A3 WO 2005009934A3
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WO
WIPO (PCT)
Prior art keywords
reaction zone
reacted
fed
hydrogen
carbon monoxide
Prior art date
Application number
PCT/EP2004/008209
Other languages
German (de)
French (fr)
Other versions
WO2005009934A2 (en
Inventor
Wolfgang Ahlers
Rocco Paciello
Edgar Zeller
Martin Volland
Miguel Angel Flores
Original Assignee
Basf Ag
Wolfgang Ahlers
Rocco Paciello
Edgar Zeller
Martin Volland
Miguel Angel Flores
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Wolfgang Ahlers, Rocco Paciello, Edgar Zeller, Martin Volland, Miguel Angel Flores filed Critical Basf Ag
Publication of WO2005009934A2 publication Critical patent/WO2005009934A2/en
Publication of WO2005009934A3 publication Critical patent/WO2005009934A3/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C07F9/5728—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems

Abstract

The invention relates to a method for production of hydroformylated olefins, whereby a) an olefin-containing feed, carbon monoxide and hydrogen are fed into a first reaction zone and reacted in the presence of a first catalyst system, b) a liquid stream essentially comprising unreacted olefins and optionally saturated hydrocarbons is separated from the discharge from the first reaction zone, c) the liquid stream obtained in step b), carbon monoxide and hydrogen are fed into a second reaction zone and reacted in the presence of a second catalyst system.
PCT/EP2004/008209 2003-07-23 2004-07-22 Two-stage hydroformylation WO2005009934A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10333519A DE10333519A1 (en) 2003-07-23 2003-07-23 Two-stage hydroformylation process
DE10333519.6 2003-07-23

Publications (2)

Publication Number Publication Date
WO2005009934A2 WO2005009934A2 (en) 2005-02-03
WO2005009934A3 true WO2005009934A3 (en) 2005-04-07

Family

ID=34071851

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/008209 WO2005009934A2 (en) 2003-07-23 2004-07-22 Two-stage hydroformylation

Country Status (2)

Country Link
DE (1) DE10333519A1 (en)
WO (1) WO2005009934A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004041850A1 (en) * 2004-08-27 2006-03-02 Basf Ag Process for the preparation of C5 aldehydes and propene from a 1-butene and 2-butene C4 stream
EP2740535A1 (en) 2012-12-04 2014-06-11 Dow Technology Investments LLC Bidentate ligands for hydroformylation of ethylene
PL3319951T3 (en) 2015-07-10 2022-02-28 Basf Se Method for the hydroformylation of 2-substituted butadienes and for the preparation of products derived from same, particularly from ambrox
US10647651B2 (en) 2015-10-12 2020-05-12 Basf Se Hydroformylation process for producing 1,6-disubstituted hexane derivatives
ES2770300T3 (en) * 2015-11-09 2020-07-01 Evonik Operations Gmbh Bisphosphites with 2,4-dimethylphenyl units and their use as ligands in hydroformylation
CN110621663A (en) 2017-06-13 2019-12-27 巴斯夫欧洲公司 Hydroformylation process for the preparation of 1, 6-hexanediol derivatives
WO2021247177A1 (en) 2020-06-05 2021-12-09 SCION Holdings LLC Alcohols production
EP4161696A1 (en) * 2020-06-05 2023-04-12 Scion Holdings LLC Branched alcohols
CN112851708B (en) * 2021-01-19 2023-05-05 成都欣华源科技有限责任公司 Method for preparing enal by catalyzing terminal alkyne or terminal conjugated eneyne and biphosphine ligand used by method
CN112898140B (en) * 2021-01-21 2022-07-22 四川大学 Method for preparing aldehyde based on internal olefin catalyzed by phosphoramidite phosphine ligand
CN115646552B (en) * 2022-11-15 2024-01-26 中国海洋石油集团有限公司 Catalyst for olefin hydroformylation and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
EP0562451A2 (en) * 1992-03-27 1993-09-29 Hoechst Aktiengesellschaft Mixtures of decyl alcohols, phthalic acid esters obtained from them and their application as plasticisers
US20020028974A1 (en) * 2000-07-14 2002-03-07 Oxeno Olefinchemie Gmbh Multistage process for the preparation of oxo aldehydes and/or alcohols
WO2003018192A2 (en) * 2001-08-24 2003-03-06 Basf Aktiengesellschaft Method for the production of 2-propylheptanol and hydroformylating catalysts and the further use thereof for carbonylation, hydrocyanation and hydrogenation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
EP0562451A2 (en) * 1992-03-27 1993-09-29 Hoechst Aktiengesellschaft Mixtures of decyl alcohols, phthalic acid esters obtained from them and their application as plasticisers
US20020028974A1 (en) * 2000-07-14 2002-03-07 Oxeno Olefinchemie Gmbh Multistage process for the preparation of oxo aldehydes and/or alcohols
WO2003018192A2 (en) * 2001-08-24 2003-03-06 Basf Aktiengesellschaft Method for the production of 2-propylheptanol and hydroformylating catalysts and the further use thereof for carbonylation, hydrocyanation and hydrogenation

Also Published As

Publication number Publication date
WO2005009934A2 (en) 2005-02-03
DE10333519A1 (en) 2005-02-17

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