WO2005003047A1 - Pane which can be heated by means of invisible light - Google Patents

Pane which can be heated by means of invisible light Download PDF

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Publication number
WO2005003047A1
WO2005003047A1 PCT/IB2004/050994 IB2004050994W WO2005003047A1 WO 2005003047 A1 WO2005003047 A1 WO 2005003047A1 IB 2004050994 W IB2004050994 W IB 2004050994W WO 2005003047 A1 WO2005003047 A1 WO 2005003047A1
Authority
WO
WIPO (PCT)
Prior art keywords
pane
light
glass
invisible light
windscreen
Prior art date
Application number
PCT/IB2004/050994
Other languages
French (fr)
Inventor
Dietrich Bertram
Augustinus Gregorius Henricus Meijers
Walter Schlager
Lukas KÜPPER
Original Assignee
Philips Intellectual Property & Standards Gmbh
Koninklijke Philips Electronics N. V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Philips Intellectual Property & Standards Gmbh, Koninklijke Philips Electronics N. V. filed Critical Philips Intellectual Property & Standards Gmbh
Publication of WO2005003047A1 publication Critical patent/WO2005003047A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10339Specific parts of the laminated safety glass or glazing being colored or tinted
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60SSERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
    • B60S1/00Cleaning of vehicles
    • B60S1/02Cleaning windscreens, windows or optical devices
    • B60S1/023Cleaning windscreens, windows or optical devices including defroster or demisting means
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/0033Heating devices using lamps
    • H05B3/0038Heating devices using lamps for industrial applications
    • H05B3/0042Heating devices using lamps for industrial applications used in motor vehicles
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/84Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
    • H05B3/86Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields the heating conductors being embedded in the transparent or reflecting material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60SSERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
    • B60S1/00Cleaning of vehicles
    • B60S1/02Cleaning windscreens, windows or optical devices
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/48Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/013Heaters using resistive films or coatings
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2214/00Aspects relating to resistive heating, induction heating and heating using microwaves, covered by groups H05B3/00, H05B6/00
    • H05B2214/02Heaters specially designed for de-icing or protection against icing

Definitions

  • the invention relates to a pane which can be heated by means of invisible light
  • the windscreen can be heated by means of a lamp radiating infrared light.
  • the lamp is positioned under the windscreen.
  • the lamp has to burn for an extended period of time in order to warm the windscreen because the heating capacity is low-efficiency.
  • red light is radiated forwards from the windscreen. This compromises safety because red light characterizes the rear end of a car.
  • the car windscreen must be transparent and clear of any materials that may interrupt vision. Condensation and ice form on the windscreen in cold weather conditions, drastically reducing visibility and, therefore, preventing safe driving.
  • the pane possesses a material which is permeable to visible light and which absorbs invisible light. The material absorbs the light and converts the light energy into heat. This heat is transmitted to the pane which is then warmed up, and any ice and condensation on the pane are also warmed up and cleared.
  • the material which is permeable to visible light and which absorbs invisible light is simply applied to the pane as a film coating.
  • the pane is advantageously designed as a laminated pane with a film which possesses a material which is permeable to visible light and which absorbs invisible light.
  • One such multilayer pane is used as a windscreen in vehicles.
  • a plastic film which is integrated into one such windscreen is impregnated with a dye which possesses the absorbent material.
  • the material advantageously absorbs invisible light in the infrared range, hereinafter also referred to as the IR range, with a wavelength greater than 750 nm.
  • the material advantageously absorbs invisible light in the ultraviolet range, hereinafter also referred to as the UV range, with a wavelength of less than 400 nm.
  • UV light is rich in energy and can, therefore, achieve a high thermal output.
  • the material advantageously absorbs invisible light in the IR and UV range. A higher thermal output can be achieved by using radiation from both ranges simultaneously.
  • the light is advantageously coupled into the pane. Consequently, a light source is positioned in such a way that the light is conducted directly into a pane.
  • the light source is positioned on or in the pane, the light is coupled directly into the pane.
  • the light is advantageously coupled in via a fibre glass element or another optical fibre.
  • the light can be coupled to several ends of the windscreen from a centrally positioned light source via several optical fibres. Distribution of the absorbent material advantageously possesses a gradient.
  • the absorption gradient is low at a point of entry of the light so as to absorb strong radiation a little and higher at points which are further away from the point of entry of the light so as to absorb weak radiation more. Consequently, areas which are far apart can also be warmed well with radiation which has already been weakened, or places which are in particular need of being heated up can be warmed up more.
  • the light advantageously strikes the surfaces of an absorber, which possesses the absorbent material, at a specified angle of incidence.
  • This type of absorber is designed as a film, layer, coating or partial coating.
  • the light, or light beam or light radiation to be more precise, is guided within a pane at a specified angle, which is known as wave guiding.
  • the pane is advantageously used as a windscreen, with at least one glass element, in a vehicle.
  • One such pane can be used in a vehicle as a front or rear windscreen made from glass or plastic.
  • Such windscreens, with at least one glass element are designed as panes of multilayer glass with an outer pane of glass, an inner pane of glass and a plastic film in-between, which is impregnated with a dye.
  • Light is used to heat the window pane, so as to clear any condensation or ice. This is achieved by either using infrared-absorbent material and a light source which radiates infrared light and which is integrated into the pane, hereinafter referred to as the pane of glass or glass, or alternatively by means of a material, which absorbs near UV light, and a near UV light source. Irrespective of the method, the absorber must be transparent for the visible range so as to preserve the transparency of the window, and the light source must radiate within the invisible portion of the spectrum so as to avoid any reduction in contrast. Light is used which is invisible to the human eye so as to increase the temperature of the glass by means of an absorbent material which is integrated into the pane of glass.
  • the light which can be used is radiated under 380 nm, in the near UV range, from indium, gallium and nitrogen-based light-emitting diodes, or InGaN or GaN-LEDs for short.
  • This light can be absorbed by many different materials which do not absorb light in the visible range, which means that they are completely transparent to the eye.
  • the material is either distributed in the glass as an intermediate layer or is applied to the glass as a coating. To come back to the near UV light, this light is distributed within the glass by means of total internal reflection, and the absorbing material converts the light energy into heat.
  • near IR light e.g. with a wavelength above 750 nm
  • a near IR-absorbent material e.g. with a wavelength above 750 nm
  • the LEDs or other light sources are positioned in such a way that the light is effectively conducted into the windscreen and distributed by means of total reflection.
  • the absorbent material can also be distributed within the window with a density gradient in order to create different thermal outputs across the windscreen. Even though this type of pane is primarily used as a windscreen in a vehicle, this principle can also be transferred to other applications. It works on the principle that the light is distributed within the glass by means of internal total reflection.
  • the absorbent material must have a concentration gradient, where possible, so that the thermal output is distributed homogeneously within the pane of glass. It may also be applied with precise distribution in cases where some areas require higher temperatures than other areas. Light may also be conducted between the light source and the window glass by means of glass fibres or other optical fibres.
  • Fig. 1 shows a heatable pane of multilayer glass with lamps radiating infrared light
  • Fig. 2 shows a heatable pane
  • Fig. 3 shows an absorption spectrum for an IR light-absorbent dye
  • Fig. 4 shows a further absorption spectrum for another IR light-absorbent dye.
  • Fig. 1 shows a pane of multilayer glass 1 with an outer pane of glass 2, an inner pane of glass 3 and a plastic film 4 in-between, which is impregnated with a dye.
  • the dye possesses UV light and IR light-absorbent material.
  • the plastic film 4 acts as an absorption layer.
  • Lamps 5, 6, 7 and 8 radiating infrared light are distributed evenly along the side face 9 of the pane of multilayer glass 1 and radiate infrared light with a wavelength of 909 - 910 nm.
  • Fig. 2 shows a heatable pane 21 with a strip of glass 22 and an absorption layer 23.
  • the strip of glass 22 is spray-coated with an IR light-absorbent dye.
  • IR radiation with a wavelength of 950 nm is admitted into the pane of glass. Precisely because of the abso ⁇ tion of the layer 23, the light creates energy in the layer 23 which increases the temperature of the abso ⁇ tion layer 23 and, thus, the temperature of the pane of glass 22.
  • Fig. 3 shows an abso ⁇ tion spectrum in which abso ⁇ tion is applied across the wavelength.
  • One such abso ⁇ tion spectrum is achieved with a coating of Epolight 2063, dye no. IV-62B, recommended for laser diodes and coatings with maximum abso ⁇ tion at 910 nm, with dark green powder, abso ⁇ tion coefficient 74.
  • the melting point is 147°C to 150°C.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to a pane (1) which can be heated by means of invisible light (5,6,7,8). The pane possesses a material (4) which is permeable to visible light and which absorbs invisible light. The material (4) absorbs the light and converts the light energy into heat. This heat is transmitted to the pane which is then warmed up, and any ice and condensation on the pane is also warmed up and cleared.

Description

Pane which can be heated by means of invisible light
The invention relates to a pane which can be heated by means of invisible light
One such pane, which is used as a windscreen in a vehicle, is known from DE 41 22 462. The windscreen can be heated by means of a lamp radiating infrared light. The lamp is positioned under the windscreen. The lamp has to burn for an extended period of time in order to warm the windscreen because the heating capacity is low-efficiency. Furthermore, red light is radiated forwards from the windscreen. This compromises safety because red light characterizes the rear end of a car. To enable the car to be driven safely, the car windscreen must be transparent and clear of any materials that may interrupt vision. Condensation and ice form on the windscreen in cold weather conditions, drastically reducing visibility and, therefore, preventing safe driving. However, it is tiresome and annoying to have to scrape the ice or wipe the condensation off the windscreen, especially in cold temperatures. Consequently, it could be useful to have this type of heating element integrated into the front or rear windscreen of the car, enabling the driver to clear the ice and condensation quickly and easily by raising the temperature of the pane. However, the heating element must also be invisible or be adequately transparent so as not to hinder the driver's view. Existing technical solutions to this problem are thin metal wires which run within the pane and which are heated by an electrical current. However, these wires are not invisible and, if they are placed in the windscreen in particular, can confuse the driver with dangerous consequences, causing him or her to pay more attention to the structures in the windscreen than to the road and the traffic. Another possible solution may be to use transparent metallic coatings or transparent conductive coatings with a terminating ohmic resistor and the same principle as that for electric heating. The biggest disadvantage with this solution is the level of costs associated with these types of coatings, especially for large-area applications. Consequently, it is an object of the present invention to indicate a simple pane which can be heated by means of invisible light. This object is solved in accordance with the features of claim 1. In accordance with the invention, the pane possesses a material which is permeable to visible light and which absorbs invisible light. The material absorbs the light and converts the light energy into heat. This heat is transmitted to the pane which is then warmed up, and any ice and condensation on the pane are also warmed up and cleared. The material which is permeable to visible light and which absorbs invisible light is simply applied to the pane as a film coating. The pane is advantageously designed as a laminated pane with a film which possesses a material which is permeable to visible light and which absorbs invisible light. One such multilayer pane is used as a windscreen in vehicles. A plastic film which is integrated into one such windscreen is impregnated with a dye which possesses the absorbent material. The material advantageously absorbs invisible light in the infrared range, hereinafter also referred to as the IR range, with a wavelength greater than 750 nm. The material advantageously absorbs invisible light in the ultraviolet range, hereinafter also referred to as the UV range, with a wavelength of less than 400 nm. UV light is rich in energy and can, therefore, achieve a high thermal output. The material advantageously absorbs invisible light in the IR and UV range. A higher thermal output can be achieved by using radiation from both ranges simultaneously. The light is advantageously coupled into the pane. Consequently, a light source is positioned in such a way that the light is conducted directly into a pane. The light source is positioned on or in the pane, the light is coupled directly into the pane. The light is advantageously coupled in via a fibre glass element or another optical fibre. The light can be coupled to several ends of the windscreen from a centrally positioned light source via several optical fibres. Distribution of the absorbent material advantageously possesses a gradient. The absorption gradient is low at a point of entry of the light so as to absorb strong radiation a little and higher at points which are further away from the point of entry of the light so as to absorb weak radiation more. Consequently, areas which are far apart can also be warmed well with radiation which has already been weakened, or places which are in particular need of being heated up can be warmed up more. The light advantageously strikes the surfaces of an absorber, which possesses the absorbent material, at a specified angle of incidence. This type of absorber is designed as a film, layer, coating or partial coating. The light, or light beam or light radiation to be more precise, is guided within a pane at a specified angle, which is known as wave guiding. This type of guiding is possible within the actual absorber or in a pane adjacent to the absorber. Total reflection occurs above a limit angle. The light is not radiated outwards, nor is it radiated forwards from a windscreen as red light; instead, all light is used for the purpose of absorption and, thus, for warming. The pane is advantageously used as a windscreen, with at least one glass element, in a vehicle. One such pane can be used in a vehicle as a front or rear windscreen made from glass or plastic. Such windscreens, with at least one glass element, are designed as panes of multilayer glass with an outer pane of glass, an inner pane of glass and a plastic film in-between, which is impregnated with a dye. Light is used to heat the window pane, so as to clear any condensation or ice. This is achieved by either using infrared-absorbent material and a light source which radiates infrared light and which is integrated into the pane, hereinafter referred to as the pane of glass or glass, or alternatively by means of a material, which absorbs near UV light, and a near UV light source. Irrespective of the method, the absorber must be transparent for the visible range so as to preserve the transparency of the window, and the light source must radiate within the invisible portion of the spectrum so as to avoid any reduction in contrast. Light is used which is invisible to the human eye so as to increase the temperature of the glass by means of an absorbent material which is integrated into the pane of glass. Consequently, the pane remains transparent, and this system functions harmlessly and is not confusing to the driver. Furthermore, this system is very inexpensive and easy to control. The light which can be used is radiated under 380 nm, in the near UV range, from indium, gallium and nitrogen-based light-emitting diodes, or InGaN or GaN-LEDs for short. This light can be absorbed by many different materials which do not absorb light in the visible range, which means that they are completely transparent to the eye. The material is either distributed in the glass as an intermediate layer or is applied to the glass as a coating. To come back to the near UV light, this light is distributed within the glass by means of total internal reflection, and the absorbing material converts the light energy into heat. This heat is transmitted to the glass which is then warmed up, and any ice and condensation on the glass is also warmed up and cleared. Alternatively, near IR light, e.g. with a wavelength above 750 nm, can be used in combination with a near IR-absorbent material. The LEDs or other light sources are positioned in such a way that the light is effectively conducted into the windscreen and distributed by means of total reflection. The absorbent material can also be distributed within the window with a density gradient in order to create different thermal outputs across the windscreen. Even though this type of pane is primarily used as a windscreen in a vehicle, this principle can also be transferred to other applications. It works on the principle that the light is distributed within the glass by means of internal total reflection. This means that, depending on how the light is introduced, the absorbent material must have a concentration gradient, where possible, so that the thermal output is distributed homogeneously within the pane of glass. It may also be applied with precise distribution in cases where some areas require higher temperatures than other areas. Light may also be conducted between the light source and the window glass by means of glass fibres or other optical fibres. In order to gain a better understanding, these and other aspects of the invention are apparent from and will be elucidated with reference to the embodiments described hereinafter.
In the drawings: Fig. 1 shows a heatable pane of multilayer glass with lamps radiating infrared light; Fig. 2 shows a heatable pane; Fig. 3 shows an absorption spectrum for an IR light-absorbent dye; and Fig. 4 shows a further absorption spectrum for another IR light-absorbent dye.
Fig. 1 shows a pane of multilayer glass 1 with an outer pane of glass 2, an inner pane of glass 3 and a plastic film 4 in-between, which is impregnated with a dye. The dye possesses UV light and IR light-absorbent material. The plastic film 4 acts as an absorption layer. Lamps 5, 6, 7 and 8 radiating infrared light are distributed evenly along the side face 9 of the pane of multilayer glass 1 and radiate infrared light with a wavelength of 909 - 910 nm. Fig. 2 shows a heatable pane 21 with a strip of glass 22 and an absorption layer 23. The strip of glass 22 is spray-coated with an IR light-absorbent dye. Once the solvent has dried, IR radiation with a wavelength of 950 nm is admitted into the pane of glass. Precisely because of the absoφtion of the layer 23, the light creates energy in the layer 23 which increases the temperature of the absoφtion layer 23 and, thus, the temperature of the pane of glass 22. Fig. 3 shows an absoφtion spectrum in which absoφtion is applied across the wavelength. One such absoφtion spectrum is achieved with a coating of Epolight 2063, dye no. IV-62B, recommended for laser diodes and coatings with maximum absoφtion at 910 nm, with dark green powder, absoφtion coefficient 74. The melting point is 147°C to 150°C. Fig. 4 shows an absoφtion spectrum in which absoφtion is applied across the wavelength. One such absoφtion spectrum is achieved with a coating of Epolight 2067, dye no. IV-67, recommended for laser diodes and coatings with maximum absoφtion at 909 nm, with green powder, absoφtion coefficient 94. The melting point is 148°C to 154°C. These spray-coatings are distributed by EPOLIN, INC., 358-364 Adams Street, Newark, NJ 07105. Also refer to the website at www.epolin.com.
REFERENCE LIST:
1 Pane of multilayer glass
2 Outer pane of glass
3 Inner pane of glass
4 Plastic film
5 Lamp
6 Lamp
7 Lamp
8 Lamp
9 Side face
10
11
12
13
14
15
16
17
18
19
20
21 Heatable pane
22 Glass strip
23 Absoφtion layer
24
25

Claims

CLAIMS:
1. A pane (1, 21), which can be heated by means of invisible light, characterized in that the pane (1, 21) possesses a material which is permeable to visible light and which absorbs invisible light.
2. A pane as claimed in claim 1 , characterized in that the material which is permeable to visible light and which absorbs invisible light is applied to the pane (21) as a film coating (23).
3. A pane as claimed in claim 1, characterized in that the pane (1) is designed as a laminated pane (1) with a film (4) which possesses material which is permeable to visible light and which absorbs invisible light.
4. A pane as claimed in any one of the preceding claims 1 - 3, characterized in that the material absorbs invisible light in the infrared range.
5. A pane as claimed in any one of the preceding claims 1 - 3, characterized in that the material absorbs invisible light in the ultraviolet range.
6. A pane as claimed in any one of the preceding claims 1 - 3, characterized in that the material absorbs invisible light in the infrared and ultraviolet range.
7. A pane as claimed in any one of the preceding claims 1 - 6, characterized in that the light is coupled into the pane.
8. A pane as claimed in any one of the preceding claims 1 - 7, characterized in that the light is coupled via an optical fibre.
9. A pane as claimed in any one of the preceding claims 1 - 3, characterized in that a distribution of the absorbent material possesses a gradient.
10. A pane as claimed in any one or more of the preceding claims, characterized in that the light strikes surfaces of an absorber (4, 23), which comprises the absorbent material, at a specified angle of incidence.
11. A pane as claimed in any one or more of the preceding claims 1 - 10, used as a windscreen, with at least one glass element (2, 3), in a vehicle.
PCT/IB2004/050994 2003-07-03 2004-06-24 Pane which can be heated by means of invisible light WO2005003047A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03101990.4 2003-07-03
EP03101990 2003-07-03

Publications (1)

Publication Number Publication Date
WO2005003047A1 true WO2005003047A1 (en) 2005-01-13

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Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010063434A1 (en) * 2008-12-03 2010-06-10 Gm Global Technology Operations, Inc. Device for heating windows, heatable window
FR2967117A1 (en) * 2010-11-09 2012-05-11 Peugeot Citroen Automobiles Sa Windscreen defogging and defrosting device for car, has absorbing unit absorbing infrared radiation, and infrared radiation sources arranged on base of joint on which lower edge of windscreen rests
WO2012142075A1 (en) 2011-04-13 2012-10-18 Merck Sharp & Dohme Corp. 2'-azido substituted nucleoside derivatives and methods of use thereof for the treatment of viral diseases
WO2012142085A1 (en) 2011-04-13 2012-10-18 Merck Sharp & Dohme Corp. 2'-substituted nucleoside derivatives and methods of use thereof for the treatment of viral diseases
WO2014059901A1 (en) 2012-10-17 2014-04-24 Merck Sharp & Dohme Corp. 2'-cyano substituted nucleoside derivatives and methods of use thereof for treatment of viral diseases
WO2014062596A1 (en) 2012-10-17 2014-04-24 Merck Sharp & Dohme Corp. 2'-methyl substituted nucleoside derivatives and methods of use thereof for the treatment of viral diseases
WO2014078463A1 (en) 2012-11-19 2014-05-22 Merck Sharp & Dohme Corp. 2 -alkynyl substituted nucleoside derivatives for treating viral diseases
WO2014206529A1 (en) * 2013-06-25 2014-12-31 Daimler Ag Defroster
WO2015121372A1 (en) * 2014-02-12 2015-08-20 Jaguar Land Rover Limited Windowpane system and vehicle incorporating same
WO2015148746A1 (en) 2014-03-28 2015-10-01 Merck Sharp & Dohme Corp. 4'-substituted nucleoside-derivatives as hiv reverse transcriptase inhibitors
DE102014006532A1 (en) * 2014-05-05 2015-11-05 Robert Csaky Device for defrosting a transparent pane
WO2016084008A1 (en) * 2014-11-25 2016-06-02 Sabic Global Technologies B.V. Method and device for heating a surface
GB2536237A (en) * 2015-03-09 2016-09-14 Jaguar Land Rover Ltd Windshield monitoring system
WO2017137111A1 (en) * 2016-02-11 2017-08-17 Jaguar Land Rover Limited A system comprising a transparent or translucent member
WO2017223012A1 (en) 2016-06-20 2017-12-28 Merck Sharp & Dohme Corp. Cyclic phosphate substituted nucleoside compounds and methods of use thereof for the treatment of viral diseases
WO2018091542A1 (en) 2016-11-21 2018-05-24 Idenix Pharmaceuticals Llc Cyclic phosphate substituted nucleoside derivatives for the treatment of liver diseases
US10107948B2 (en) 2014-11-25 2018-10-23 Sabic Global Technologies B.V. Method and article for emitting radiation from a surface
WO2019169077A1 (en) * 2018-02-28 2019-09-06 Sabic Global Technologies B.V. Method and device for emitting radiation or heat from a surface
JP2019192645A (en) * 2019-06-14 2019-10-31 大日本印刷株式会社 Sheet with conductor used for heating plate
CN113597032A (en) * 2021-08-10 2021-11-02 北京航空航天大学 Compatible stealth anti-icing material and preparation method and application thereof
WO2022013408A2 (en) 2020-07-16 2022-01-20 Merck Sharp & Dohme Corp. Cyclic cyanoenone derivatives as modulators of keap1
DE102021113571A1 (en) 2021-05-26 2022-12-01 Bayerische Motoren Werke Aktiengesellschaft Reflective display system for motor vehicle with defrost function

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Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010063434A1 (en) * 2008-12-03 2010-06-10 Gm Global Technology Operations, Inc. Device for heating windows, heatable window
FR2967117A1 (en) * 2010-11-09 2012-05-11 Peugeot Citroen Automobiles Sa Windscreen defogging and defrosting device for car, has absorbing unit absorbing infrared radiation, and infrared radiation sources arranged on base of joint on which lower edge of windscreen rests
WO2012142075A1 (en) 2011-04-13 2012-10-18 Merck Sharp & Dohme Corp. 2'-azido substituted nucleoside derivatives and methods of use thereof for the treatment of viral diseases
WO2012142085A1 (en) 2011-04-13 2012-10-18 Merck Sharp & Dohme Corp. 2'-substituted nucleoside derivatives and methods of use thereof for the treatment of viral diseases
WO2014059901A1 (en) 2012-10-17 2014-04-24 Merck Sharp & Dohme Corp. 2'-cyano substituted nucleoside derivatives and methods of use thereof for treatment of viral diseases
WO2014062596A1 (en) 2012-10-17 2014-04-24 Merck Sharp & Dohme Corp. 2'-methyl substituted nucleoside derivatives and methods of use thereof for the treatment of viral diseases
WO2014078463A1 (en) 2012-11-19 2014-05-22 Merck Sharp & Dohme Corp. 2 -alkynyl substituted nucleoside derivatives for treating viral diseases
WO2014206529A1 (en) * 2013-06-25 2014-12-31 Daimler Ag Defroster
WO2015121372A1 (en) * 2014-02-12 2015-08-20 Jaguar Land Rover Limited Windowpane system and vehicle incorporating same
GB2523310A (en) * 2014-02-12 2015-08-26 Jaguar Land Rover Ltd Windowpane system and vehicle incorporating same
GB2543880B (en) * 2014-02-12 2018-05-16 Jaguar Land Rover Ltd Windowpane system and vehicle incorporating same
GB2543880A (en) * 2014-02-12 2017-05-03 Jaguar Land Rover Ltd Windowpane system and vehicle incorporating same
GB2523310B (en) * 2014-02-12 2017-05-03 Jaguar Land Rover Ltd Windowpane system and vehicle incorporating same
WO2015148746A1 (en) 2014-03-28 2015-10-01 Merck Sharp & Dohme Corp. 4'-substituted nucleoside-derivatives as hiv reverse transcriptase inhibitors
DE102014006532A1 (en) * 2014-05-05 2015-11-05 Robert Csaky Device for defrosting a transparent pane
KR20170090445A (en) * 2014-11-25 2017-08-07 사빅 글로벌 테크놀러지스 비.브이. Method and device for heating a surface
KR20210064420A (en) * 2014-11-25 2021-06-02 사빅 글로벌 테크놀러지스 비.브이. Method and device for heating a surface
KR102451711B1 (en) 2014-11-25 2022-10-06 사빅 글로벌 테크놀러지스 비.브이. Method and device for heating a surface
KR102258797B1 (en) 2014-11-25 2021-05-31 사빅 글로벌 테크놀러지스 비.브이. Method and device for heating a surface
US9913318B2 (en) 2014-11-25 2018-03-06 Sabic Global Technologies B.V. Method and device for heating a surface
WO2016084008A1 (en) * 2014-11-25 2016-06-02 Sabic Global Technologies B.V. Method and device for heating a surface
US10107948B2 (en) 2014-11-25 2018-10-23 Sabic Global Technologies B.V. Method and article for emitting radiation from a surface
GB2536237A (en) * 2015-03-09 2016-09-14 Jaguar Land Rover Ltd Windshield monitoring system
GB2536237B (en) * 2015-03-09 2018-08-15 Jaguar Land Rover Ltd Windshield monitoring system
WO2017137111A1 (en) * 2016-02-11 2017-08-17 Jaguar Land Rover Limited A system comprising a transparent or translucent member
WO2017223012A1 (en) 2016-06-20 2017-12-28 Merck Sharp & Dohme Corp. Cyclic phosphate substituted nucleoside compounds and methods of use thereof for the treatment of viral diseases
WO2018091542A1 (en) 2016-11-21 2018-05-24 Idenix Pharmaceuticals Llc Cyclic phosphate substituted nucleoside derivatives for the treatment of liver diseases
US11730748B2 (en) 2016-11-21 2023-08-22 Msd International Gmbh Cyclic phosphate substituted nucleoside derivatives for the treatment of liver diseases
CN111801985B (en) * 2018-02-28 2022-09-27 Sabic环球技术有限责任公司 Method and apparatus for emitting radiation or heat from a surface
CN111801985A (en) * 2018-02-28 2020-10-20 Sabic环球技术有限责任公司 Method and apparatus for emitting radiation or heat from a surface
WO2019169077A1 (en) * 2018-02-28 2019-09-06 Sabic Global Technologies B.V. Method and device for emitting radiation or heat from a surface
JP2019192645A (en) * 2019-06-14 2019-10-31 大日本印刷株式会社 Sheet with conductor used for heating plate
WO2022013408A2 (en) 2020-07-16 2022-01-20 Merck Sharp & Dohme Corp. Cyclic cyanoenone derivatives as modulators of keap1
DE102021113571A1 (en) 2021-05-26 2022-12-01 Bayerische Motoren Werke Aktiengesellschaft Reflective display system for motor vehicle with defrost function
CN113597032A (en) * 2021-08-10 2021-11-02 北京航空航天大学 Compatible stealth anti-icing material and preparation method and application thereof

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