WO2004111336A1 - Surface sized paper - Google Patents

Surface sized paper Download PDF

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Publication number
WO2004111336A1
WO2004111336A1 PCT/FI2004/000329 FI2004000329W WO2004111336A1 WO 2004111336 A1 WO2004111336 A1 WO 2004111336A1 FI 2004000329 W FI2004000329 W FI 2004000329W WO 2004111336 A1 WO2004111336 A1 WO 2004111336A1
Authority
WO
WIPO (PCT)
Prior art keywords
paper
surface sizing
acrylic
sizing agent
copolymer
Prior art date
Application number
PCT/FI2004/000329
Other languages
French (fr)
Inventor
Kaj Koskinen
Mikko Rissanen
Original Assignee
Upm-Kymmene Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upm-Kymmene Corporation filed Critical Upm-Kymmene Corporation
Publication of WO2004111336A1 publication Critical patent/WO2004111336A1/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/06—Vegetable or imitation parchment; Glassine paper

Definitions

  • the present invention relates to a paper comprising a base paper and, on at least one side of the base paper, a surface size layer comprising inorganic pigment and polyvinyl alcohol (PVA).
  • PVA polyvinyl alcohol
  • the surface sizing of a glazing-type base paper with a surface sizing agent comprising an inorganic filler and polyvinyl alcohol is known from prior art.
  • the polyvinyl alcohol is a good film forming agent and is therefore commonly used in surface sizing agents.
  • the properties of the surface sizing agents include deficiencies which must be compensated for by, for example, strong calendering treatments, to make the surface of the base paper as free from pores as possible before its siliconization.
  • the surface sizing agents must be compatible with silicon in such a way that the silicon can adhere to and reticulate on the surface sizing agent.
  • the paper according to the invention is characterized in that the surface sizing layer comprises an acrylic alkylene copolymer and/or its derivatives.
  • the surface energy of the surface sized paper can be adjusted to such a level that the siliconizability is improved.
  • the improvement in the sili- conizability means, among other things, lower silicon consumption, better results in Shirlastain colour tests, and lower release values of the siliconized paper.
  • the addition of an acrylic alkylene copolymer to the surface sizing agent makes the surface of the surface-sized paper more hydrophobic, wherein the surface of the paper does not necessarily need to be treated to be completely poreless by calendering treatments.
  • the base paper used for the paper according to the invention can be a glazing-type paper or a kraft paper.
  • the glazing paper refers to a paper which is made of chemical pulp and whose grammage is typically from 50 to 150 g/m 2 . Good transparency is typically required of the glazing paper; for a 60 g/m 2 paper, it is typically at least 45, measured with visible light (ISO 2469:1994). Because glazing paper is used as the base paper for release paper, a poreless surface is a requirement for good siliconizability. The poreless surface can be achieved with calendering treatments and surface sizing. The paper can be either calendered first and then surface sized, or surface sized first and then calendered.
  • the calendering is performed first, wherein a calender with more than one nip is preferably used in the calendering.
  • the calender can be a multi-nip calender or a supercalender.
  • at least one nip is formed between a hard-faced roll and a soft counter surface.
  • the moisture content of the paper is preferably at least 14 wt-% before the calendering.
  • the surface sizing agent according to the invention is used, however, the calendering treatment is not as critical as before, because the hydrophobic property of the surface sizing agent can be used to compensate for the porosity left after the calendering treatment.
  • the surface sizing agent according to the invention comprises at least an inorganic pigment and an adhesive.
  • the adhesive comprises a polyvinyl alcohol and an acrylic alkylene copolymer, such as an acrylic ethylene copolymer, and/or its derivatives.
  • the acrylic alkylene copolymer and/or its derivatives mean that the acrylic alkylene copolymer is mixed, before mixing with the surface sizing agent, with an aqueous solution of a strong base, such as sodium hydroxide, and in this way a water-soluble salt is obtained from the acrylic alkylene copolymer. That is, the acrylic alkylene copolymer is first added into the solution, and by the effect of the base, it is converted at least partly to the form of a water-soluble salt.
  • the content of the acrylic alkylene copolymer is normally from 15 to 25 wt-% of the solution comprising water, a suitable base and said acrylic alkylene copolymer.
  • the pH of the solution is from 8.5 to 9.5, preferably more than 9.
  • the content of the adhesive is normally about 70 to 90 wt-% of the dry matter of the surface sizing agent.
  • the adhesive comprises a polyvinyl alcohol and an acrylic alkylene copolymer and/or its derivatives.
  • the content of the polyvinyl alcohol may be 30 to 40 wt-% of the dry matter of the surface sizing agent; the content of the acrylic alkylene copolymer may be 20 to 70 wt-%, preferably 20 to 50 wt-% of the dry matter of the surface sizing agent.
  • the surface sizing agent may contain various additives, such as thickening agents. As an additive, it is possible to use, for example, carboxyl methyl cellulose (CMC), which improves water retention.
  • CMC carboxyl methyl cellulose
  • the content of the additives is 0 to 2 wt-%, preferably not more than 1 wt-% of the dry matter of the surface sizing agent.
  • the inorganic agent may be an inorganic pigment known as such from papermaking, for example kaoline or talc. Mixtures of various inorganic pigments are also feasible.
  • the content of the inorganic pigment as dry matter in the surface sizing agent is 20 to 70 wt-%, normally 20 to 30 wt-%.
  • the surface sizing is preferably performed with a film size press, and the surface sizing agent is then dried. After the surface sizing agent has been applied onto the surface of the base paper, the surface sizing agent may need to be neutralized to make the pH of the paper surface favourable for the subsequent silicon treatment.
  • the surface sizing agent is neutralized to the level of pH 7 by using a suitable pH lowering agent.
  • the water-soluble salt of the acrylic alkylene copolymer is changed, at least partly, back to a water-insoluble form.
  • the figure shows graphically the transverse expansion / water intake of a paper which has been surface sized by the formulation according to Example 1 , and reference samples of prior art. The results in the figure show that the paper according to the invention expands less than the reference samples. Example 1.
  • a glazing-type base paper was surface sized by using, as the surface sizing agent, a composition containing 34.5 % of polyvinyl alcohol, 34.5 % of acrylic ethylene copolymer, 30 % of kaoline, and 1 % of car- boxymethyl cellulose, calculated as weight per cent of the dry matter.
  • the acrylic ethylene copolymer was present in a solution of sodium hydroxide mixed with 20wt-% of acrylic ethylene copolymer. In the sodium hydroxide solution, the acrylic ethylene copolymer is changed into a water-soluble sodium salt. The content of ethylene in the copolymer was 80 wt-%.
  • the pH value of the solution was approximately 9.
  • the surface-sized and dried paper according to the invention was analyzed for its properties, and the results were compared with a paper of prior art. The results are shown in Table 1.
  • the Cobb value which indicates the hydro- phobicity of the paper, is clearly lower for the paper according to the invention than for the paper of prior art. From the Cobb values, it can be stated that values exceeding 17 g/m 2 are common at present, and values which are not higher than g/m 2 are good.
  • the Cobb value is typically not higher than 17 g/m 2 , advanta- geously not higher than 16 g/m 2 , and preferably not higher than
  • the results show that the Shirlastain value for the surface- sized side is lower than 18 g/m 2 .
  • the Shirlastain value is not higher than 18 g/m 2 , the value is considered good.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)

Abstract

The invention relates to a paper comprising a base paper and, on at least one side of the base paper, a surface size layer comprising an inorganic pigment and a polyvinyl alcohol (PVA). The surface size layer comprises an acrylic alkylene copolymer.

Description

Surface sized paper
The present invention relates to a paper comprising a base paper and, on at least one side of the base paper, a surface size layer comprising inorganic pigment and polyvinyl alcohol (PVA).
The surface sizing of a glazing-type base paper with a surface sizing agent comprising an inorganic filler and polyvinyl alcohol, is known from prior art. The polyvinyl alcohol is a good film forming agent and is therefore commonly used in surface sizing agents. However, the properties of the surface sizing agents include deficiencies which must be compensated for by, for example, strong calendering treatments, to make the surface of the base paper as free from pores as possible before its siliconization. Furthermore, the surface sizing agents must be compatible with silicon in such a way that the silicon can adhere to and reticulate on the surface sizing agent.
The paper according to the invention is characterized in that the surface sizing layer comprises an acrylic alkylene copolymer and/or its derivatives.
When the surface sizing layer of the paper according to the invention comprises an acrylic alkylene copolymer and/or its derivatives, the surface energy of the surface sized paper can be adjusted to such a level that the siliconizability is improved. The improvement in the sili- conizability means, among other things, lower silicon consumption, better results in Shirlastain colour tests, and lower release values of the siliconized paper. The addition of an acrylic alkylene copolymer to the surface sizing agent makes the surface of the surface-sized paper more hydrophobic, wherein the surface of the paper does not necessarily need to be treated to be completely poreless by calendering treatments.
The base paper used for the paper according to the invention can be a glazing-type paper or a kraft paper. The glazing paper refers to a paper which is made of chemical pulp and whose grammage is typically from 50 to 150 g/m2. Good transparency is typically required of the glazing paper; for a 60 g/m2 paper, it is typically at least 45, measured with visible light (ISO 2469:1994). Because glazing paper is used as the base paper for release paper, a poreless surface is a requirement for good siliconizability. The poreless surface can be achieved with calendering treatments and surface sizing. The paper can be either calendered first and then surface sized, or surface sized first and then calendered. Preferably, the calendering is performed first, wherein a calender with more than one nip is preferably used in the calendering. The calender can be a multi-nip calender or a supercalender. In the calender, at least one nip is formed between a hard-faced roll and a soft counter surface. To produce glazing paper, the moisture content of the paper is preferably at least 14 wt-% before the calendering. Now that the surface sizing agent according to the invention is used, however, the calendering treatment is not as critical as before, because the hydrophobic property of the surface sizing agent can be used to compensate for the porosity left after the calendering treatment.
The surface sizing agent according to the invention comprises at least an inorganic pigment and an adhesive. The adhesive comprises a polyvinyl alcohol and an acrylic alkylene copolymer, such as an acrylic ethylene copolymer, and/or its derivatives. The acrylic alkylene copolymer and/or its derivatives mean that the acrylic alkylene copolymer is mixed, before mixing with the surface sizing agent, with an aqueous solution of a strong base, such as sodium hydroxide, and in this way a water-soluble salt is obtained from the acrylic alkylene copolymer. That is, the acrylic alkylene copolymer is first added into the solution, and by the effect of the base, it is converted at least partly to the form of a water-soluble salt. The content of the acrylic alkylene copolymer is normally from 15 to 25 wt-% of the solution comprising water, a suitable base and said acrylic alkylene copolymer. The pH of the solution is from 8.5 to 9.5, preferably more than 9. The content of the adhesive is normally about 70 to 90 wt-% of the dry matter of the surface sizing agent. The adhesive comprises a polyvinyl alcohol and an acrylic alkylene copolymer and/or its derivatives. The content of the polyvinyl alcohol may be 30 to 40 wt-% of the dry matter of the surface sizing agent; the content of the acrylic alkylene copolymer may be 20 to 70 wt-%, preferably 20 to 50 wt-% of the dry matter of the surface sizing agent. Furthermore, the surface sizing agent may contain various additives, such as thickening agents. As an additive, it is possible to use, for example, carboxyl methyl cellulose (CMC), which improves water retention. The content of the additives is 0 to 2 wt-%, preferably not more than 1 wt-% of the dry matter of the surface sizing agent.
The inorganic agent may be an inorganic pigment known as such from papermaking, for example kaoline or talc. Mixtures of various inorganic pigments are also feasible. The content of the inorganic pigment as dry matter in the surface sizing agent is 20 to 70 wt-%, normally 20 to 30 wt-%.
The surface sizing is preferably performed with a film size press, and the surface sizing agent is then dried. After the surface sizing agent has been applied onto the surface of the base paper, the surface sizing agent may need to be neutralized to make the pH of the paper surface favourable for the subsequent silicon treatment. The surface sizing agent is neutralized to the level of pH 7 by using a suitable pH lowering agent. Thus, the water-soluble salt of the acrylic alkylene copolymer is changed, at least partly, back to a water-insoluble form.
In the following, the invention will be described with reference to the examples and the figure. The figure shows graphically the transverse expansion / water intake of a paper which has been surface sized by the formulation according to Example 1 , and reference samples of prior art. The results in the figure show that the paper according to the invention expands less than the reference samples. Example 1.
A glazing-type base paper was surface sized by using, as the surface sizing agent, a composition containing 34.5 % of polyvinyl alcohol, 34.5 % of acrylic ethylene copolymer, 30 % of kaoline, and 1 % of car- boxymethyl cellulose, calculated as weight per cent of the dry matter. The acrylic ethylene copolymer was present in a solution of sodium hydroxide mixed with 20wt-% of acrylic ethylene copolymer. In the sodium hydroxide solution, the acrylic ethylene copolymer is changed into a water-soluble sodium salt. The content of ethylene in the copolymer was 80 wt-%. The pH value of the solution was approximately 9.
The surface-sized and dried paper according to the invention was analyzed for its properties, and the results were compared with a paper of prior art. The results are shown in Table 1.
Table 1. Test results of the surface-sized paper.
Figure imgf000005_0001
The values given in the table were measured according to the following standards:
Thickness SCAN-P 7:75 Bekk porosity ISO 5627
Oil absorption (Unger) SCAN-P 37:77
Shirlastain as Cobb, but with Shirlastain liquid
Cobb ISO 535 Bekk smoothness DIN 53107
Gloss TAPPI T480 OS-78
Roughness (PPS) SCAN-P 76:95
The results show that the Cobb value, which indicates the hydro- phobicity of the paper, is clearly lower for the paper according to the invention than for the paper of prior art. From the Cobb values, it can be stated that values exceeding 17 g/m2 are common at present, and values which are not higher than g/m2 are good. For the paper of the invention, the Cobb value is typically not higher than 17 g/m2, advanta- geously not higher than 16 g/m2, and preferably not higher than
15 g/m2.
Furthermore, the results show that the Shirlastain value for the surface- sized side is lower than 18 g/m2. When the Shirlastain value is not higher than 18 g/m2, the value is considered good.
The above description does not restrict the invention, but the invention may vary within the scope of the claims.

Claims

Claims:
1. A paper comprising a base paper and, on at least one side of the base paper, a surface sizing layer which contains inorganic pigment and polyvinyl alcohol (PVA), characterized in that the surface sizing layer comprises an acrylic alkylene copolymer and/or its derivatives.
2. The paper according to claim 1, characterized in that the comonomer of the acrylic alkylene copolymer is ethylene.
3. The paper according to claim 1 or 2, characterized in that the inorganic filler is kaoline, talc, or a mixture of these.
4. The paper according to any of the preceding claims, characterized in that the surface sizing layer comprises carboxymethyl cellulose
(CMC).
PCT/FI2004/000329 2003-06-17 2004-05-31 Surface sized paper WO2004111336A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20030905 2003-06-17
FI20030905A FI121187B (en) 2003-06-17 2003-06-17 Release paper base paper

Publications (1)

Publication Number Publication Date
WO2004111336A1 true WO2004111336A1 (en) 2004-12-23

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI2004/000329 WO2004111336A1 (en) 2003-06-17 2004-05-31 Surface sized paper

Country Status (2)

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FI (1) FI121187B (en)
WO (1) WO2004111336A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8110071B2 (en) 2004-03-31 2012-02-07 Kuraray Europe Gmbh Papers providing great fat and oil penetration resistance, and method for the production thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3674896A (en) * 1966-07-28 1972-07-04 Union Carbide Corp Bonding with ammonium polymer salts
US5807781A (en) * 1994-07-21 1998-09-15 Kammerer Gmbh Release base paper having silicate-containing primer coats
WO2001017774A1 (en) * 1999-09-07 2001-03-15 Tetra Laval Holdings & Finance S A A method of producing a laminated packaging material, and packaging containers produced from the packaging material
WO2001055507A1 (en) * 2000-01-26 2001-08-02 Upm-Kymmene Corporation Base paper, method to produce it and release paper
US6426120B1 (en) * 1999-07-12 2002-07-30 Morgan Adhesives Company Treatment of cellulose substrates
EP1279768A2 (en) * 2001-07-23 2003-01-29 Ricoh Company, Ltd. Composite sheet, method of preparing same, and thermosensitive recording adhesive label sheet having same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3674896A (en) * 1966-07-28 1972-07-04 Union Carbide Corp Bonding with ammonium polymer salts
US5807781A (en) * 1994-07-21 1998-09-15 Kammerer Gmbh Release base paper having silicate-containing primer coats
US6426120B1 (en) * 1999-07-12 2002-07-30 Morgan Adhesives Company Treatment of cellulose substrates
WO2001017774A1 (en) * 1999-09-07 2001-03-15 Tetra Laval Holdings & Finance S A A method of producing a laminated packaging material, and packaging containers produced from the packaging material
WO2001055507A1 (en) * 2000-01-26 2001-08-02 Upm-Kymmene Corporation Base paper, method to produce it and release paper
EP1279768A2 (en) * 2001-07-23 2003-01-29 Ricoh Company, Ltd. Composite sheet, method of preparing same, and thermosensitive recording adhesive label sheet having same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8110071B2 (en) 2004-03-31 2012-02-07 Kuraray Europe Gmbh Papers providing great fat and oil penetration resistance, and method for the production thereof

Also Published As

Publication number Publication date
FI20030905A0 (en) 2003-06-17
FI20030905A (en) 2004-12-18
FI121187B (en) 2010-08-13

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