WO2004098871A1 - Nonwoven-fabric laminate, process for producing nonwoven-fabric laminate, and bag comprising nonwoven-fabric laminate - Google Patents

Nonwoven-fabric laminate, process for producing nonwoven-fabric laminate, and bag comprising nonwoven-fabric laminate Download PDF

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Publication number
WO2004098871A1
WO2004098871A1 PCT/JP2003/005693 JP0305693W WO2004098871A1 WO 2004098871 A1 WO2004098871 A1 WO 2004098871A1 JP 0305693 W JP0305693 W JP 0305693W WO 2004098871 A1 WO2004098871 A1 WO 2004098871A1
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WO
WIPO (PCT)
Prior art keywords
nonwoven fabric
fabric laminate
layer
film
nonwoven
Prior art date
Application number
PCT/JP2003/005693
Other languages
French (fr)
Japanese (ja)
Inventor
Akihiko Kurahashi
Takayuki Nakahara
Original Assignee
Idemitsu Unitech Co., Ltd.
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Filing date
Publication date
Application filed by Idemitsu Unitech Co., Ltd. filed Critical Idemitsu Unitech Co., Ltd.
Priority to PCT/JP2003/005693 priority Critical patent/WO2004098871A1/en
Publication of WO2004098871A1 publication Critical patent/WO2004098871A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/12Layered products comprising a layer of natural or synthetic rubber comprising natural rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary

Definitions

  • the present invention relates to a nonwoven fabric laminate, a method for producing the nonwoven fabric laminate, and a bag using the nonwoven fabric laminate.
  • nonwoven fabrics have been directly subjected to printing, aluminum deposition, or the like to impart design.
  • the embossed nonwoven fabric has a problem that it is difficult to perform delicate printing, aluminum deposition, and other processing because the fibers are randomly arranged and the surface has irregularities.
  • printing processing, aluminum vapor deposition processing, and the like are directly performed on the nonwoven fabric, there is a problem that the wear fastness is poor.
  • the wear fastness was particularly poor.
  • the design film must be laminated on the nonwoven fabric after embossing the design film, which has a problem that the manufacturing process is complicated.
  • the decorative film and the nonwoven fabric are laminated, the decorative film and the nonwoven fabric are sandwiched and adhered by a mirror plate. Therefore, after attaching a protective film on the design film and bonding the design film and the nonwoven fabric so that the embossed pattern of the design film will not be crushed, it is necessary to remove the protection film and perform other work. There is a problem that it takes time to manufacture the body.
  • An object of the present invention is to provide a nonwoven fabric laminate that is easy to produce, has good design properties, is embossed, and has excellent wear fastness, a method for producing this nonwoven fabric laminate, and a nonwoven fabric laminate.
  • the purpose is to provide used bags. Disclosure of the invention
  • the nonwoven fabric laminate of the present invention has at least a first layer made of a nonwoven fabric made of a thermoplastic resin, and a second layer made of a design film made of a thermoplastic resin that has been subjected to design processing. It is characterized by being heat-embossed laminated.
  • the nonwoven fabric of the first layer is preferably 1 to 30 denier, particularly preferably 2 to 20 denier. If it is less than 1 denier, the surface is apt to fuzz. On the other hand, if it exceeds 30 denier, it becomes inferior in denseness.
  • the basis weight of the nonwoven fabric is preferably from 5 to 200 g / m 2 , and particularly preferably T lOO g / m 2 . If it is less than 5 g Zm 2 , the strength is inferior, and if it exceeds 200 g Zm 2 , it becomes heavy, thick and hard, the handleability decreases, and the raw material cost also increases.
  • the design film of the second layer may be a film generally used as a soft packaging material, and a polyolefin film suitable for heat lamination with a nonwoven fabric is particularly preferable. Furthermore, co-extruded films are particularly preferable in consideration of the heat laminating property with the nonwoven fabric.
  • the thickness of the design film is preferably from 5 to 400 m, more preferably from 10 to 200 m. Further, it is preferably 15 to 100 m. If it is less than 5 m, the strength will be insufficient and handling will be poor. On the other hand, when the thickness is more than 400 m, the material is too thick and inferior in handleability, and because it is too rigid, it is not suitable for use as a bag or the like, and the cost of raw materials increases. In the present invention having this configuration, since a film made of a thermoplastic resin is subjected to design processing instead of printing or aluminum deposition directly on the nonwoven fabric, it is possible to apply a delicate pattern or the like. It can be excellent.
  • the wear resistance can be improved as compared with the case where printing is performed directly on the first nonwoven fabric.
  • the first and second layers can be hot-embossed and laminated at one time, which is different from a conventional case where only a design film is embossed and then laminated on a nonwoven fabric.
  • a nonwoven fabric laminate that is easily embossed can be obtained without any trouble in production.
  • the nonwoven fabric laminate preferably has a third layer made of a thermoplastic resin film or nonwoven fabric.
  • thermoplastic resin film or nonwoven fabric of the third layer may be any one that is generally used as a soft packaging material.
  • the film may be a plain film, or may be printed for further improving the design.
  • the third layer may be a nonwoven fabric in order to give an impression of the cloth to the nonwoven fabric laminate.
  • the thickness is preferably 50 g Zm 2 or less so that the decorative film can be seen.
  • the design film since the third layer is provided on the design film, the design film is protected, and the wear fastness of the nonwoven fabric laminate can be further improved.
  • the design film is formed by printing or depositing aluminum on a thermoplastic resin film.
  • Printing on the film and vapor deposition of aluminum can be easily performed, so that no labor is required for manufacturing the nonwoven fabric laminate.
  • the first layer nonwoven fabric is preferably a spunbonded nonwoven fabric.
  • Non-woven fabric is thin, high density and high abrasion resistance ⁇ Non-woven fabric can be used. Also, as compared with other non-woven fabric manufacturing methods, for example, the melt blow method, the non-woven fabric manufactured by the spun pond method has an advantage that it is made of continuous filaments and hardly generates burrs.
  • thermoplastic resin used for each of the layers is preferably a polyolefin-based resin.
  • the polyolefin resin has excellent heat laminating properties, and can be easily heat laminated by forming each layer of the polyolefin resin, and is suitable for bag making utilizing heat sealability.
  • the method for producing a nonwoven fabric laminate of the present invention comprises a nonwoven fabric laminate having at least a first layer made of a thermoplastic resin nonwoven fabric and a second layer made of a design-processed thermoplastic resin design film. The method according to claim 1, wherein at least the two layers are simultaneously hot-embossed and laminated.
  • the hot emboss laminate has at least a pair of heating rolls, and one of the heating ports can be performed using a general hot embossing device embossed by engraving, etching or the like.
  • emboss patterns can be adopted, for example, a pattern in which concaves and convexes of irregularities are formed discontinuously in a dot shape, a lattice shape, and the like.
  • the nonwoven fabric laminate has a third layer made of a thermoplastic resin film or nonwoven fabric, and the three layers are simultaneously hot-embossed and laminated.
  • the production of the non-woven fabric laminate is not troublesome because the three layers are simultaneously hot-embossed.
  • the hot embossed laminate is used when manufacturing the first layer nonwoven fabric. It is preferable that the second layer or the second layer and the third layer are laminated on each other, and the in-line processing of embossing is performed.
  • in-line processing refers to laminating a second layer, or a second layer and a third layer on a web in which the resin of the first layer of nonwoven fabric has been opened, and using this as an embossing roll, hot enbossing
  • This is a method in which the first layer of resin is thermally bonded while performing the following.
  • the bag of the present invention is characterized by being obtained by molding the above nonwoven fabric laminate.
  • FIG. 1 is a cross-sectional view showing a nonwoven fabric laminate according to an embodiment of the present invention.
  • FIG. 2 is a schematic diagram showing an apparatus for producing the nonwoven fabric laminate.
  • FIG. 3 is a schematic view showing a main part of the manufacturing apparatus. BEST MODE FOR CARRYING OUT THE INVENTION
  • FIG. 1 shows a nonwoven fabric laminate 1 of the present embodiment.
  • This nonwoven fabric laminate 1 is composed of a first layer made of a thermoplastic resin nonwoven fabric 11, a second layer made of a thermoplastic resin design film 12, and a thermoplastic resin nonwoven fabric 13. It has a third tier. Each of these layers is hot embossed laminated.
  • the first layer of nonwoven fabric 11 is made of a polyolefin resin and has a denier of 2 to 20 deniers.
  • the basis weight is 7 to 100 g Zm 2 .
  • the design film 12 of the second layer is obtained by, for example, printing or aluminum deposition on a co-extruded film made of a polyolefin resin such as polypropylene or polyethylene and subjecting it to design processing.
  • the thickness of the design film 12 is 5 to 400 m.
  • the nonwoven fabric 13 of the third layer is made of a polyolefin resin and has a basis weight of 50 g Zm 2 or less.
  • Such a nonwoven fabric laminate 1 is manufactured using a manufacturing apparatus 2 as shown in FIG.
  • the manufacturing apparatus 2 includes a hopper 21, an extruder 22, a spun-pound die 23, a spinning traction device 24, a conveyor 25, and two feeders 26 A and 26 B.
  • a heat embossing device 27 and a winding device 28 are provided.
  • the extruder 22 plasticizes and extrudes the raw material supplied via the hopper 21.
  • the extruder 22 is a single-screw extruder.
  • the spun-pound die 23 converts the raw material extruded from the extruder 22 into a continuous fiber bundle.
  • the spun pond die 23 has a spinneret 231, which turns the supplied raw material into a plurality of threads.
  • the spinneret 231 has a large number of holes, and the holes are used as a spinning nozzle to spin out a molten raw material therefrom to form a fiber bundle of continuous fibers.
  • a known die for performing the spun-pound method can be used as the spun-pound die 23.
  • the spinning pulling device 24 pulls the fiber bundle from the spun-pound die 23.
  • the spinning traction device 24 includes a cooling tower 240 for cooling the fiber bundle from the spun-pound die 23, and a tubular portion 2411 for stretching and opening the fiber bundle from the cooling tower 240. And.
  • a constriction is formed at the center of the cylindrical portion 241, and the constricted portion serves as a filament index portion 242.
  • the filament pulling section 242 has a function of indexing and spinning the spun raw material at a high speed, that is, drawing.
  • the part is a fiber opening part 243, and the yarn is uniformly spread by the turbulent flow of the cooling air in the fiber opening part 243.
  • the conveyor 25 includes a mouth 25 1, 25 2, a suction device 25 3, and a belt 25 4.
  • the conveyor 25 is a web formed by depositing fiber bundles on the belt 25.
  • the rolls 25 1 and 25 2 are made of metal, rubber, or the like. Although not shown, at least one of the rolls 25 1 and 25 2 is provided with a driving means such as a motor.
  • the suction device 2553 sucks the fiber bundle discharged from the spinneret 231 of the spun pond die 23, and passes through the cooling tower 240 and the cylindrical portion 241, to the belt 2554. It leads.
  • the belt 254 wound around the mouth 251, 252 is made of metal, rubber, plastic or the like.
  • the two payout machines 26A and 26B pay out the design film 12 of the second layer and the nonwoven fabric 13 of the third layer, respectively.
  • the heat embossing device 27 includes an emboss roll 271, and a flat roll 272.
  • an oil temperature controller is incorporated inside the embossing roll 271, so that the temperature can be controlled.
  • the flat roll 272 has a smooth surface and, like the emboss roll 271, has an oil temperature controller (not shown) incorporated therein.
  • a polyolefin resin which is a raw material of the nonwoven fabric 11, is put into an extruder 22 through a hopper 21.
  • the polyolefin resin plasticized by the extruder 22 is passed through a spunbond die 23 to form a fiber bundle, which is introduced into a spinning pulling device 24.
  • the fiber bundle drawn and spread by the spinning pulling device 24 is collected on a conveyor 25 to form a web. I do.
  • design film 12 of the second layer and the nonwoven fabric 13 of the third layer are fed from the two feeders 26 A and 26 B and laminated.
  • the non-woven fabric 11 is formed by the hot embossing device 27, and the non-woven fabric 11, the decorative film 12 and the non-woven fabric 13 are hot-embossed and laminated to obtain a non-woven fabric laminate 1.
  • the nonwoven fabric laminate 1 thus obtained can be used as a bag by sewing and heat sealing. Therefore, according to the present embodiment, the following effects can be obtained.
  • the nonwoven fabric laminate 1 is made by processing a thermoplastic resin film instead of directly printing or depositing aluminum on the nonwoven fabric, it is possible to apply delicate patterns, etc. It can be excellent.
  • the design-processed film 12 since the design-processed film 12 is used, it should have excellent wear fastness compared to the case of printing directly on the first nonwoven fabric 11. Can be.
  • the design film 12 is protected, and the wear fastness of the nonwoven fabric laminate 1 can be further improved.
  • the decorative film 12 is a co-extruded film made of a polyolefin resin, and can be easily printed and aluminum-deposited, is easily laminated by heat, and requires time and effort to manufacture the nonwoven fabric laminate 1. do not do.
  • the thickness of the design film 12 is set to 5 to 400, the strength It has a high degree of handling and does not require much effort in handling.
  • the non-woven fabric 11 is a spun-pound non-woven fabric
  • the non-woven fabric can be thin, high in density and high in abrasion resistance. Further, as compared with the melt blow method or the like, the nonwoven fabric produced by the spunbond method has an advantage that it is made of continuous filaments and is less likely to generate fluff.
  • the nonwoven fabric 11 has a denier of 2 to 20 and is less likely to generate fuzz on the surface, and can be excellent in denseness. Furthermore, since the basis weight of the nonwoven fabric 11 is 7 to 100 g Zm 2, it has the strength necessary for handling and has an appropriate weight, so that it has excellent handling properties and manufacture the nonwoven fabric laminate 1. It does not take much effort. Since the third layer is made of the nonwoven fabric 13, the nonwoven fabric laminate 1 can be given the feel of a cloth. In addition, since the basis weight of the nonwoven fabric 13 of the third layer is 50 g Zm 2 or less, the design film 12 can be seen through, and the nonwoven fabric laminate 1 having excellent design properties can be obtained. Furthermore, since the nonwoven fabric 11, the decorative film 12 and the nonwoven fabric 13 are made of a polyolefin resin having excellent heat lamination properties, they can be easily thermally laminated.
  • the nonwoven fabric laminate 1 was manufactured by in-line processing, the production of the first nonwoven fabric 11 and the hot emboss lamination can be performed simultaneously, so that the number of manufacturing steps can be reduced and the nonwoven fabric laminate can be reduced. 1. The manufacturing cost can be reduced.
  • the bag obtained by sewing the nonwoven fabric laminate 1 has excellent design, high abrasion resistance, and can be easily manufactured. It should be noted that the present invention is not limited to the above-described embodiment, but includes modifications and improvements as long as the object of the present invention can be achieved.
  • in-line processing is performed.
  • the present invention is not limited to this, and after each layer is formed, hot emboss lamination may be separately performed.
  • the first layer nonwoven fabric 11 is a spun-pound nonwoven fabric.
  • the present invention is not limited thereto, and a nonwoven fabric manufactured by another method, for example, a nonwoven fabric manufactured by a hot air card method may be used.
  • spun-pound nonwovens are thin, dense, and abrasion resistant. It has the advantage of being expensive.
  • design film 12 is printed and aluminum-deposited on a thermoplastic resin, but may be subjected to design processing by another method.
  • nonwoven fabric 11, the decorative film 12 and the nonwoven fabric 13 are made of polyolefin resin, but are not limited to polyolefin resin, and may be made of thermoplastic resin. Those generally used as soft packaging materials are preferred.
  • the third layer of the nonwoven fabric laminate 1 is the nonwoven fabric 13, but may be a transparent film.
  • a film generally used as a soft packaging material is preferable.
  • the third layer may be a film that has been subjected to design processing such as printing.
  • the printed surface is preferably a laminated surface in consideration of the fastness to friction.
  • the nonwoven fabric laminate 1 has a three-layer structure
  • the present invention is not limited to this, and the nonwoven fabric laminate 1 may have a four-layer or more structure.
  • the first-layer nonwoven fabric 11 and the second-layer design film 1 2 It may have a two-layer structure consisting only of the above.
  • the heat embossing device 27 is a single-stage type, but is not limited thereto, and may be a multi-stage type.
  • the immobilization of the nonwoven fabric 11 and the heat lamination can be performed separately, so that the laminating strength can be stabilized and the processing speed can be improved. The following experiment was performed to confirm the effects of the present invention.
  • the nonwoven fabric laminate produced in Example 1 is as follows.
  • Second layer Co-extruded unstretched polypropylene printed on the entire surface
  • Lumm (Idemitsu Unitech's “Unilux” grade RS595C, 30 zm)
  • Third layer non-woven fabric: Polypropylene spun-pound nonwoven fabric (Idemitsu Unitech's “Stratec” grade RN202, 20 g / m 2 )
  • a nonwoven fabric laminate was manufactured using the manufacturing apparatus 2 of the embodiment.
  • a polypropylene resin which is a raw material of the first layer nonwoven fabric, is put into the hopper 2 1, and 2
  • the web was deposited on a belt 254 of 5.
  • the fiber system was 3 denier.
  • the embossing roll 27 1 has an emboss area of 13% and has a lattice shape.
  • the temperature of the embossed opening 27 1 was 140 ° (:, the temperature of the flat opening 27 2 was 150 ° C.
  • the nonwoven fabric laminate produced in Example 2 is as follows.
  • Second layer Co-extruded linear low-density poly deposited with aluminum Ethylene film (Hitachi Pax 30 m, Hitachi AIC)
  • 3rd layer Co-extruded linear low-density polyethylene film partially printed with character patterns Grade LS
  • a nonwoven fabric laminate was manufactured using the manufacturing apparatus 2 in the same manner as in Example 1.
  • the linear low density polyethylene resin as a raw material for the nonwoven fabric of the first layer in the hopper one 2 1 was charged, in 2 0 0 ° C, 3 0 g / m 2 and so as to extrusion by extruder 2 2, conveyor
  • the web was deposited on 25 belts 25 4.
  • the fiber system was 4 denier.
  • the co-extruded linear low-density polyethylene film with aluminum vapor deposition and the co-extruded linear low-density polyethylene film partially printed with a character are fed out on the web by the feeding machines 26A and 26B.
  • the partially printed co-extruded linear low-density polyethylene film had a partially printed surface as a laminated surface.
  • the embossing roll 271 is the same as that of the first embodiment.
  • the temperature of the embossrol 2711 and the flat roll 2772 was 120 ° C.
  • the present invention relates to a nonwoven fabric laminate and a method for producing the same, and a bag using the nonwoven fabric laminate, and can be used as a bag for packaging or transportation, a packing material, or the like.

Abstract

A nonwoven-fabric laminate (1) which comprises a first layer comprising a nonwoven fabric (11) made of a thermoplastic resin, a second layer comprising a film with an attractive appearance (12) made of a thermoplastic resin, and a third layer comprising a nonwoven fabric (13) made of a thermoplastic resin. These layers have been laminated together by heat embossing. The film with an attractive appearance (12) as the second layer is one obtained, for example, by imparting the attractive appearance by subjecting a coextruded film made of a polyolefin, e.g., polypropylene or polyethylene, to printing or aluminum vapor deposition.

Description

明 細 書 不織布積層体、 不織布積層体の製造方法及び不織布積層体を用いた袋 技術分野  Description Nonwoven fabric laminate, method for producing nonwoven fabric laminate, and bag using nonwoven fabric laminate
本発明は、 不織布積層体、 不織布積層体の製造方法及び不織布積層体を用いた 袋に関する。 背景技術  The present invention relates to a nonwoven fabric laminate, a method for producing the nonwoven fabric laminate, and a bag using the nonwoven fabric laminate. Background art
従来、 袋には織物、 紙、 フィルム等が用いられてきたが、 熱可塑性樹脂からな る不織布を用いた袋は、 価格、 強度、 製袋性に優れているため、 近年、 普及して いる。  Textiles, paper, films, etc. have been used for bags in the past, but bags using nonwoven fabrics made of thermoplastic resin have become popular in recent years because of their excellent price, strength, and bag-making properties. .
このような不織布を用いた袋は、 その意匠性の向上が望まれており、 従来は、 不織布に、 印刷加工、 アルミ蒸着加工等を直接施して意匠性を付与していた。 し かし、 エンボス加工された不織布は、 繊維がランダムに配列し、 かつ表面に凹凸 が形成されているため、 繊細な印刷や、 アルミ蒸着等の加工が行いにくいという 問題があった。 また、 不織布上に印刷加工、 アルミ蒸着加工等を直接施した場合 には、 摩耗堅牢度が劣るという問題があった。 なかでもポリオレフイン系樹脂か らなる不織布に直接、印刷加工等をした場合には、特に摩耗堅牢度が劣っていた。 そこで、 印刷、 アルミ蒸着等により意匠加工された意匠性フィルムを不織布に ドライラミネートや押し出しラミネートする方法が提案されたが、 この方法で得 られる積層体は、 その表面にエンボス加工が施されておらず、 硬く仕上がつてし まうという問題があった。  It is desired to improve the design of bags made of such nonwoven fabrics. Conventionally, nonwoven fabrics have been directly subjected to printing, aluminum deposition, or the like to impart design. However, the embossed nonwoven fabric has a problem that it is difficult to perform delicate printing, aluminum deposition, and other processing because the fibers are randomly arranged and the surface has irregularities. Further, when printing processing, aluminum vapor deposition processing, and the like are directly performed on the nonwoven fabric, there is a problem that the wear fastness is poor. Above all, when a nonwoven fabric made of a polyolefin resin was directly subjected to printing or the like, the wear fastness was particularly poor. Therefore, a method of dry laminating or extrusion laminating a design film, which has been designed and processed by printing, aluminum vapor deposition, etc., to a nonwoven fabric has been proposed, but the laminate obtained by this method has an embossed surface. However, there was a problem that the finish was hard.
このような問題を解決するために、 印刷、 アルミ蒸着等により意匠加工された 意匠性フィルムにエンボス加工を施し、 これを不織布上に積層する方法が提案さ れている (特開平 5 — 1 3 8 8 4 6号公報等参照) 。  In order to solve such a problem, there has been proposed a method of embossing a design film which has been designed by printing, aluminum deposition, or the like, and laminating the embossed film on a nonwoven fabric (Japanese Patent Laid-Open No. 5-13). No. 8 846, etc.).
しかし、 このような方法では、 意匠性フィルムにエンボス加工を施した後に、 不織布上に積層しなければならず、 製造工程が複雑化するという問題がある。 ま た、 この方法では、 意匠性フィルムと不織布とを積層させる際に、 意匠性フィル ムと不織布とを鏡面板により挟み接着させている。 そのため、 意匠性フィルムの エンボス模様が潰れてしまわないように意匠性フィルム上に保護フィルムを取り 付け、 意匠性フィルムと不織布を接着した後 -. この保護フィルムを取り外す等の 作業が必要となり、 積層体の製造に手間がかかるという問題がある。 However, in such a method, the design film must be laminated on the nonwoven fabric after embossing the design film, which has a problem that the manufacturing process is complicated. Ma Further, in this method, when the decorative film and the nonwoven fabric are laminated, the decorative film and the nonwoven fabric are sandwiched and adhered by a mirror plate. Therefore, after attaching a protective film on the design film and bonding the design film and the nonwoven fabric so that the embossed pattern of the design film will not be crushed, it is necessary to remove the protection film and perform other work. There is a problem that it takes time to manufacture the body.
本発明の目的は、 製造が容易で、 意匠性が良好であり、 エンボス加工が施され、 摩耗堅牢度が優れた不織布積層体及びこの不織布積層体の製造方法、 さらには、 この不織布積層体を用いた袋を提供することである。 発明の開示  An object of the present invention is to provide a nonwoven fabric laminate that is easy to produce, has good design properties, is embossed, and has excellent wear fastness, a method for producing this nonwoven fabric laminate, and a nonwoven fabric laminate. The purpose is to provide used bags. Disclosure of the invention
本発明の不織布積層体は、 少なくとも熱可塑性樹脂製の不織布よりなる第一層 と、 意匠加工が施された熱可塑性樹脂製の意匠性フィルムよりなる第二層とを有 し、 これらの各層は熱エンボスラミネートされていることを特徴とする。  The nonwoven fabric laminate of the present invention has at least a first layer made of a nonwoven fabric made of a thermoplastic resin, and a second layer made of a design film made of a thermoplastic resin that has been subjected to design processing. It is characterized by being heat-embossed laminated.
第一層の不織布は、 1〜 3 0デニールが好ましく、 特に 2〜 2 0デニールが好 ましい。 1デニ一ル未満の場合には、 表面にけばが発生しやすい。 また、 3 0デ ニールを超えると、 緻密性に劣るものとなる。  The nonwoven fabric of the first layer is preferably 1 to 30 denier, particularly preferably 2 to 20 denier. If it is less than 1 denier, the surface is apt to fuzz. On the other hand, if it exceeds 30 denier, it becomes inferior in denseness.
また、 不織布の目付は 5〜2 0 0 g /m2が好ましく、 特に T l O O g /m2 が好ましい。 5 g Zm2未満の場合には、 強度が劣り、 2 0 0 g Zm2を超えると、 重く、 厚く、 硬くなり、 ハンドリング性が低下し、 さらに原料コストも高くなる。 第二層の意匠性フィルムは、 一般的に軟包材として用いされているものであれ ばよく、 特に不織布との熱ラミネートに適したポリオレフィン系フィルムが好適 である。 さらに、 不織布との熱ラミネート性を考慮すると、 共押し出しフィルム が特に好適である。 Further, the basis weight of the nonwoven fabric is preferably from 5 to 200 g / m 2 , and particularly preferably T lOO g / m 2 . If it is less than 5 g Zm 2 , the strength is inferior, and if it exceeds 200 g Zm 2 , it becomes heavy, thick and hard, the handleability decreases, and the raw material cost also increases. The design film of the second layer may be a film generally used as a soft packaging material, and a polyolefin film suitable for heat lamination with a nonwoven fabric is particularly preferable. Furthermore, co-extruded films are particularly preferable in consideration of the heat laminating property with the nonwoven fabric.
意匠性フィルムの厚みは 5〜4 0 0 mが好ましく、 1 0〜2 0 0 mがより 好ましい。 さらに、 好ましくは 1 5〜1 0 0 mである。 5 m未満の場合には、 強度が不足してハンドリング性に劣るものとなる。 また、 4 0 0 mより厚い場 合には、 厚すぎてハンドリング性に劣り、 また、 堅いため袋等として使用するに は不適当であり、 原料コストもかかることとなる。 この構成の本発明では、 不織布上に直接、 印刷、 アルミ蒸着を行うのではなく、 熱可塑性樹脂製のフィルムを意匠加工しているため、 繊細な模様等を施すことが 可能となり、 意匠性に優れたものとすることができる。 The thickness of the design film is preferably from 5 to 400 m, more preferably from 10 to 200 m. Further, it is preferably 15 to 100 m. If it is less than 5 m, the strength will be insufficient and handling will be poor. On the other hand, when the thickness is more than 400 m, the material is too thick and inferior in handleability, and because it is too rigid, it is not suitable for use as a bag or the like, and the cost of raw materials increases. In the present invention having this configuration, since a film made of a thermoplastic resin is subjected to design processing instead of printing or aluminum deposition directly on the nonwoven fabric, it is possible to apply a delicate pattern or the like. It can be excellent.
また、 意匠加工が施された意匠性フィルムを使用しているため、 第一層の不織 布上に直接、 印刷加工等する場合に比べ、 摩耗堅牢度に優れたものとすることが できる。  Further, since a design-processed film is used, the wear resistance can be improved as compared with the case where printing is performed directly on the first nonwoven fabric.
さらに、 本発明では、 第一層及第二層を一度に熱エンボスラミネートすること ができるので、 従来のように、 意匠性フィルムのみをエンボス加工した後、 これ を不織布上に積層する場合に比べ、 製造に手間がかからず、 容易にエンボス加工 された不織布積層体を得ることができる。 本発明において、 不織布積層体は、 熱可塑性樹脂製のフィルムまたは不織布よ りなる第三層を有することが好ましい。  Furthermore, in the present invention, the first and second layers can be hot-embossed and laminated at one time, which is different from a conventional case where only a design film is embossed and then laminated on a nonwoven fabric. A nonwoven fabric laminate that is easily embossed can be obtained without any trouble in production. In the present invention, the nonwoven fabric laminate preferably has a third layer made of a thermoplastic resin film or nonwoven fabric.
第三層の熱可塑性樹脂製のフィルムまたは不織布は、 一般的に軟包材として用 いられているものであればよい。 クリアー感を出すため、 無地のフィルムであつ てもよく、 さらなる意匠性向上のための印刷等が施されていてもよい。  The thermoplastic resin film or nonwoven fabric of the third layer may be any one that is generally used as a soft packaging material. In order to give a clear feeling, the film may be a plain film, or may be printed for further improving the design.
また、不織布積層体に布の印象を与えるために、第三層を不織布としてもよい。 第三層を不織布とする場合には、 意匠性フィルムが見えるようにするために、 5 0 g Zm2以下が好適である。 Further, the third layer may be a nonwoven fabric in order to give an impression of the cloth to the nonwoven fabric laminate. When the third layer is made of a nonwoven fabric, the thickness is preferably 50 g Zm 2 or less so that the decorative film can be seen.
本発明では、 意匠性フィルム上に第三層を設けたため、 意匠性フィルムが保護 され、 不織布積層体の摩耗堅牢度をより向上させることができる。  In the present invention, since the third layer is provided on the design film, the design film is protected, and the wear fastness of the nonwoven fabric laminate can be further improved.
本発明において、 前記意匠性フィルムは、 熱可塑性樹脂製のフィルム上に印刷 もしくはアルミ蒸着を行ったものであることが好ましい。  In the present invention, it is preferable that the design film is formed by printing or depositing aluminum on a thermoplastic resin film.
フィルム上への印刷、 アルミ蒸着は容易に行うことができるため、 不織布積層 体の製造に手間を要しない。  Printing on the film and vapor deposition of aluminum can be easily performed, so that no labor is required for manufacturing the nonwoven fabric laminate.
本発明において、 前記第一層の不織布はスパンボンド不織布であることが好ま しい。  In the present invention, the first layer nonwoven fabric is preferably a spunbonded nonwoven fabric.
不織布をスパンポンド不織布とすることで、 薄く、 密度が高く、 耐摩耗性が高 ぃ不織布とすることができる。また、他の不織布の製造方法、例えばメルトブロー 法と比較して、スパンポンド法により製造された不織布は、連続長繊維からなり、 ゲバが発生しにくいという利点がある。 Spun-punched non-woven fabric is thin, high density and high abrasion resistance ぃ Non-woven fabric can be used. Also, as compared with other non-woven fabric manufacturing methods, for example, the melt blow method, the non-woven fabric manufactured by the spun pond method has an advantage that it is made of continuous filaments and hardly generates burrs.
本発明において、 前記各層に用いられる前記熱可塑性樹脂は、 ポリオレフイン 系樹脂であることが好ましい。  In the present invention, the thermoplastic resin used for each of the layers is preferably a polyolefin-based resin.
ポリオレフイン系樹脂は、 熱ラミネート性に優れており、 各層をポリオレフィ ン系樹脂で形成することで、 容易に熱ラミネートすることができ、 ヒ一トシ一ル 性を利用した製袋に好適である。 本発明の不織布積層体の製造方法は、 少なくとも熱可塑性樹脂製の不織布より なる第一層と、 意匠加工が施された熱可塑性樹脂製の意匠性フィルムよりなる第 二層とを有する不織布積層体の製造方法であって、 少なくとも前記二層を同時に 熱エンボスラミネートすることを特徴とする。  The polyolefin resin has excellent heat laminating properties, and can be easily heat laminated by forming each layer of the polyolefin resin, and is suitable for bag making utilizing heat sealability. The method for producing a nonwoven fabric laminate of the present invention comprises a nonwoven fabric laminate having at least a first layer made of a thermoplastic resin nonwoven fabric and a second layer made of a design-processed thermoplastic resin design film. The method according to claim 1, wherein at least the two layers are simultaneously hot-embossed and laminated.
熱エンボスラミネートは、 少なくとも一対の加熱ロールを有しており、 一方の 加熱口一ルは、 彫刻、 エッチング等でエンボス加工されている一般的な熱ェンポ ス装置を使用して行うことができる。  The hot emboss laminate has at least a pair of heating rolls, and one of the heating ports can be performed using a general hot embossing device embossed by engraving, etching or the like.
エンボスパターンは様々なものが採用でき、 例えば、 凹凸の凹と凸がドット状 に不連続に形成されたもの、 格子状のもの等がある。  A variety of emboss patterns can be adopted, for example, a pattern in which concaves and convexes of irregularities are formed discontinuously in a dot shape, a lattice shape, and the like.
このような構成の本発明では、 二層を同時に熱エンボスラミネートしているた め、 各層毎にエンボス加工を施した後、 ラミネートする場合にくらべ、 製造工程 の簡便化を図ることができる。 本発明において、 前記不織布積層体は、 熱可塑性樹脂製のフィルムまたは不織 布よりなる第三層を備え、 前記三層を同時に熱エンボスラミネートすることが好 ましい。  In the present invention having such a configuration, since the two layers are simultaneously subjected to the hot emboss lamination, the manufacturing process can be simplified as compared with the case of laminating after embossing each layer. In the present invention, it is preferable that the nonwoven fabric laminate has a third layer made of a thermoplastic resin film or nonwoven fabric, and the three layers are simultaneously hot-embossed and laminated.
不織布積層体が第三層を有するものとしても、 三層を同時に熱エンボスラミ ネートしているので、 不織布積層体の製造に手間を要しない。  Even if the non-woven fabric laminate has a third layer, the production of the non-woven fabric laminate is not troublesome because the three layers are simultaneously hot-embossed.
本発明において、 前記熱エンボスラミネートは、 前記第一層の不織布の製造時 に第二層または、 第二層及び第三層を積層して、 エンボス加工を施すインライン 加工により行われることが好ましい。 In the present invention, the hot embossed laminate is used when manufacturing the first layer nonwoven fabric. It is preferable that the second layer or the second layer and the third layer are laminated on each other, and the in-line processing of embossing is performed.
ここで、 インライン加工とは、 第一層の不織布の樹脂が開繊されたウェブに第 二層、 または第二層及び第三層を積層し、 これをエンボスロールに り、 熱ェン ボス加工を施しつつ、 第一層の樹脂を熱接着する方法である。  Here, in-line processing refers to laminating a second layer, or a second layer and a third layer on a web in which the resin of the first layer of nonwoven fabric has been opened, and using this as an embossing roll, hot enbossing This is a method in which the first layer of resin is thermally bonded while performing the following.
このようにすれば、 第一層の不織布の製造と、 熱エンボスラミネートとを同時 に行うことができるため、 製造工程を減らすことができ、 不織布積層体の製造コ ストを削減できる。 本発明の袋は、 以上のような不織布積層体を成形して得られることを特徴とす る。  In this way, the production of the first layer nonwoven fabric and the hot emboss lamination can be performed simultaneously, so that the number of production steps can be reduced and the production cost of the nonwoven fabric laminate can be reduced. The bag of the present invention is characterized by being obtained by molding the above nonwoven fabric laminate.
前述した不織布積層体における作用 ·効果と同様の作用 ·効果を奏することが できる。 つまり、 意匠性に優れ、 摩耗堅牢度が高く、 製造が容易な袋とすること ができる。 図面の簡単な説明  The same functions and effects as those of the nonwoven fabric laminate described above can be obtained. In other words, it is possible to obtain a bag that has excellent design properties, high wear fastness, and is easy to manufacture. BRIEF DESCRIPTION OF THE FIGURES
図 1は本発明の実施形態にかかる不織布積層体を示す断面図である, 図 2は前記不織布積層体の製造装置を示す模式図である。  FIG. 1 is a cross-sectional view showing a nonwoven fabric laminate according to an embodiment of the present invention. FIG. 2 is a schematic diagram showing an apparatus for producing the nonwoven fabric laminate.
図 3は前記製造装置の要部を示す模式図である。 発明を実施するための最良の形態  FIG. 3 is a schematic view showing a main part of the manufacturing apparatus. BEST MODE FOR CARRYING OUT THE INVENTION
以下、 本発明の実施形態を図面に基づいて説明する。  Hereinafter, embodiments of the present invention will be described with reference to the drawings.
図 1には、 本実施形態の不織布積層体 1が示されている。 この不織布積層体 1 は、熱可塑性樹脂製の不織布 1 1よりなる第一層と、熱可塑性樹脂製の意匠性フィ ルム 1 2よりなる第二層と、 熱可塑性樹脂製の不織布 1 3よりなる第三層とを備 えている。 これらの各層は熱エンボスラミネートされている。  FIG. 1 shows a nonwoven fabric laminate 1 of the present embodiment. This nonwoven fabric laminate 1 is composed of a first layer made of a thermoplastic resin nonwoven fabric 11, a second layer made of a thermoplastic resin design film 12, and a thermoplastic resin nonwoven fabric 13. It has a third tier. Each of these layers is hot embossed laminated.
第一層の不織布 1 1は、 ポリオレフイン系樹脂製であり、 2〜2 0デニールで ある。 また、 その目付は、 7〜 1 0 0 g Zm2である。 第二層の意匠性フィルム 1 2は、 例えば、 ポリプロピレン、 ポリエチレン等の ポリオレフイン系樹脂製の共押し出しフィルムに印刷もしくはアルミ蒸着を施 し、 意匠加工を施したものである。 意匠性フィルム 1 2の厚みは 5〜4 0 0 m である。 The first layer of nonwoven fabric 11 is made of a polyolefin resin and has a denier of 2 to 20 deniers. The basis weight is 7 to 100 g Zm 2 . The design film 12 of the second layer is obtained by, for example, printing or aluminum deposition on a co-extruded film made of a polyolefin resin such as polypropylene or polyethylene and subjecting it to design processing. The thickness of the design film 12 is 5 to 400 m.
第三層の不織布 1 3は、 ポリオレフイン系樹脂製であり、 その目付は 5 0 g Z m2以下である。 The nonwoven fabric 13 of the third layer is made of a polyolefin resin and has a basis weight of 50 g Zm 2 or less.
このような不織布積層体 1は、 図 2に示すような製造装置 2を用いて製造され る。  Such a nonwoven fabric laminate 1 is manufactured using a manufacturing apparatus 2 as shown in FIG.
この製造装置 2は、 ホッパー 2 1と、 押し出し機 2 2と、 スパンポンド用ダイ 2 3と、 紡糸牽引装置 2 4と、 コンベア 2 5と、 二台の繰り出し機 2 6 A, 2 6 Bと、 熱エンボス装置 2 7と、 巻き取り装置 2 8とを備える。  The manufacturing apparatus 2 includes a hopper 21, an extruder 22, a spun-pound die 23, a spinning traction device 24, a conveyor 25, and two feeders 26 A and 26 B. A heat embossing device 27 and a winding device 28 are provided.
押し出し機 2 2は、 ホッパー 2 1を介して供給された原料を可塑化して押し出 すものである。本実施形態において押し出し機 2 2は、単軸の押し出し機である。 図 3に示すように、 スパンポンド用ダイ 2 3は、 押し出し機 2 2から押し出さ れた原料を連続状繊維の繊維束とするものである。 このスパンポンド用ダイ 2 3 は、 供給された原料を複数の糸状にする紡糸口金 2 3 1を有している。 紡糸口金 2 3 1は、 図示しないが、 多数の孔を有し、 これらの孔を紡糸ノズルとしてここ から溶融原料を紡出し、 連続状繊維の繊維束を形成する構成となっている。 本実 施形態において、 スパンポンド用ダイ 2 3はスパンポンド法を行うための公知の ダイを用いることができる。  The extruder 22 plasticizes and extrudes the raw material supplied via the hopper 21. In the present embodiment, the extruder 22 is a single-screw extruder. As shown in FIG. 3, the spun-pound die 23 converts the raw material extruded from the extruder 22 into a continuous fiber bundle. The spun pond die 23 has a spinneret 231, which turns the supplied raw material into a plurality of threads. Although not shown, the spinneret 231 has a large number of holes, and the holes are used as a spinning nozzle to spin out a molten raw material therefrom to form a fiber bundle of continuous fibers. In the present embodiment, a known die for performing the spun-pound method can be used as the spun-pound die 23.
紡糸牽引装置 2 4は、 スパンポンド用ダイ 2 3からの繊維束を牽引するもので ある。 この紡糸牽引装置 2 4は、 スパンポンド用ダイ 2 3からの繊維束を冷却す る冷却塔 2 4 0と、 冷却塔 2 4 0からの繊維束を延伸し、 開繊する筒部 2 4 1と を有する。  The spinning pulling device 24 pulls the fiber bundle from the spun-pound die 23. The spinning traction device 24 includes a cooling tower 240 for cooling the fiber bundle from the spun-pound die 23, and a tubular portion 2411 for stretching and opening the fiber bundle from the cooling tower 240. And.
筒部 2 4 1の中央にはくびれが形成されており、 このくびれの部分がフィラメ ント索引部 2 4 2となっている。 このフィラメント牽引部 2 4 2は、 紡糸した原 料を高速で索引して細化、 つまり、 延伸する機能を持つ。  A constriction is formed at the center of the cylindrical portion 241, and the constricted portion serves as a filament index portion 242. The filament pulling section 242 has a function of indexing and spinning the spun raw material at a high speed, that is, drawing.
さらに、 フィラメント牽引部 2 4 2の下部で、 筒部 2 4 1のくびれが広がつた 部分は開繊部 2 4 3となっており、 この開繊部 2 4 3で冷却空気による乱流で糸 条を均一に開繊させている。 In addition, the constriction of the tubular part 2 41 widened below the filament pulling part 2 42 The part is a fiber opening part 243, and the yarn is uniformly spread by the turbulent flow of the cooling air in the fiber opening part 243.
図 2に戻って、 コンベア 2 5について説明する。 コンベア 2 5は、 口一ル 2 5 1 , 2 5 2と、 吸引機 2 5 3と、 ベルト 2 5 4とを備えている。 コンベア 2 5は.. ベルト 2 5 4上に繊維束を堆積させてウェブを形成するものである。 ロール 2 5 1 , 2 5 2は、 金属、 ゴム等で構成されおり、 図示しないがロール 2 5 1, 2 5 2の少なくとも何れか一方には、 モー夕等の駆動手段が設けられている。  Returning to FIG. 2, the conveyor 25 will be described. The conveyor 25 includes a mouth 25 1, 25 2, a suction device 25 3, and a belt 25 4. The conveyor 25 is a web formed by depositing fiber bundles on the belt 25. The rolls 25 1 and 25 2 are made of metal, rubber, or the like. Although not shown, at least one of the rolls 25 1 and 25 2 is provided with a driving means such as a motor.
吸引機 2 5 3は、 スパンポンド用ダイ 2 3の紡糸口金 2 3 1から排出される繊 維束を吸引し、 冷却塔 2 4 0及び筒部 2 4 1を介して、 ベルト 2 5 4まで導くも のである。  The suction device 2553 sucks the fiber bundle discharged from the spinneret 231 of the spun pond die 23, and passes through the cooling tower 240 and the cylindrical portion 241, to the belt 2554. It leads.
口一ル 2 5 1, 2 5 2に巻装されたベルト 2 5 4は、 金属、 ゴム、 プラスチッ ク等で構成されている。  The belt 254 wound around the mouth 251, 252 is made of metal, rubber, plastic or the like.
二台の繰り出し機 2 6 A, 2 6 Bは、 それぞれ、 第二層の意匠性フィルム 1 2 及び第三層の不織布 1 3とを繰り出すものである。  The two payout machines 26A and 26B pay out the design film 12 of the second layer and the nonwoven fabric 13 of the third layer, respectively.
熱エンボス装置 2 7は、 エンボスロール 2 7 1と、 フラットロール 2 7 2とを 備えている。 エンボスロール 2 7 1は金属製であり、 ロール表面に所定のェンポ スパターンが形成されている。 また、 エンボスロール 2 7 1の内部には、 図示し ないがオイル温調機が組み込まれており、 温度コントロール可能となっている。 フラットロール 2 7 2は、 その表面が平滑となっており、 エンボスロール 2 7 1と同様に内部にオイル温調機 (図示略) が組み込まれている。 次に、 このような製造装置 2を用い 不織布積層体 1を製造する手順を説明す る。  The heat embossing device 27 includes an emboss roll 271, and a flat roll 272. The embossing roll 271, made of metal, has a predetermined emboss pattern formed on the roll surface. Although not shown, an oil temperature controller is incorporated inside the embossing roll 271, so that the temperature can be controlled. The flat roll 272 has a smooth surface and, like the emboss roll 271, has an oil temperature controller (not shown) incorporated therein. Next, a procedure for manufacturing the nonwoven fabric laminate 1 using the manufacturing apparatus 2 will be described.
まず、 ホッパー 2 1を介して、 不織布 1 1の原料であるポリオレフイン系樹脂 を押し出し機 2 2に投入する。  First, a polyolefin resin, which is a raw material of the nonwoven fabric 11, is put into an extruder 22 through a hopper 21.
この押し出し機 2 2により可塑化されたポリオレフィン系樹脂を、 スパンボン ド用ダイ 2 3を通して、 繊維束とし、 紡糸牽引装置 2 4へ導入する。 この紡糸牽 引装置 2 4で延伸、 開繊した繊維束を、 コンベア 2 5上に捕集し、 ウェブを形成 する。 The polyolefin resin plasticized by the extruder 22 is passed through a spunbond die 23 to form a fiber bundle, which is introduced into a spinning pulling device 24. The fiber bundle drawn and spread by the spinning pulling device 24 is collected on a conveyor 25 to form a web. I do.
さらに、 このウェブに二台の繰り出し機 2 6 A, 2 6 Bから、 第二層の意匠性 フィルム 1 2及び第三層の不織布 1 3を繰り出し、 積層する。  Furthermore, the design film 12 of the second layer and the nonwoven fabric 13 of the third layer are fed from the two feeders 26 A and 26 B and laminated.
次いで、これらを熱エンボス装置 2 7のエンボス口一ル 2 7 1と、フラットロー ル 2 7 2との間に供給する。 この熱エンボス装置 2 7により、 不織布 1 1を形成 すると共に、不織布 1 1、意匠性フィルム 1 2、不織布 1 3を熱エンボスラミネー トし、 不織布積層体 1を得る。  Next, these are supplied between the emboss opening 27 1 of the hot embossing device 27 and the flat roll 27 2. The non-woven fabric 11 is formed by the hot embossing device 27, and the non-woven fabric 11, the decorative film 12 and the non-woven fabric 13 are hot-embossed and laminated to obtain a non-woven fabric laminate 1.
このようにして得られた不織布積層体 1は、 図示しないが、 縫製ゃヒ一トシ一 ルすることで、 袋として使用することができる。 従って、 本実施形態によれば、 以下の効果を奏することができる。  Although not shown, the nonwoven fabric laminate 1 thus obtained can be used as a bag by sewing and heat sealing. Therefore, according to the present embodiment, the following effects can be obtained.
不織布積層体 1は、 不織布上に直接、 印刷、 アルミ蒸着を行うのではなく、 熱 可塑性樹脂製のフィルムを意匠加工しているため、 繊細な模様等を施すことが可 能となり、 意匠性に優れたものとすることができる。  Since the nonwoven fabric laminate 1 is made by processing a thermoplastic resin film instead of directly printing or depositing aluminum on the nonwoven fabric, it is possible to apply delicate patterns, etc. It can be excellent.
また、 意匠加工が施された意匠性フィルム 1 2を使用しているため、 第一層の 不織布 1 1上に直接、 印刷加工等する場合に比べ、 摩耗堅牢度に優れたものとす ることができる。  In addition, since the design-processed film 12 is used, it should have excellent wear fastness compared to the case of printing directly on the first nonwoven fabric 11. Can be.
さらに、意匠性フィルム 1 2上に第三層の不織布 1 3を設けたため、意匠性フィ ルム 1 2が保護され、 不織布積層体 1の摩耗堅牢度をより向上させることができ る。  Further, since the third-layer nonwoven fabric 13 is provided on the design film 12, the design film 12 is protected, and the wear fastness of the nonwoven fabric laminate 1 can be further improved.
また、 第一層の不織布 1 1、 第二層の意匠性フィルム 1 2、 第三層の不織布 1 3を一度に熱エンボスラミネートしているため、 従来のように、 意匠性フィルム のみをエンボス加工した後、 これを不織布上に積層する場合に比べ、 製造に手間 がかからず、 容易にエンボス加工された不織布積層体 1を得ることができる。 さらに、 意匠性フィルム 1 2は、 ポリオレフイン系樹脂製の共押し出しフィル ムであり、 印刷、 アルミ蒸着は容易に行うことができ、 熱ラミネートし易く、 不 織布積層体 1の製造に手間を要しない。  Also, since the first layer nonwoven fabric 11, the second layer design film 12 and the third layer nonwoven fabric 13 are hot-embossed and laminated at the same time, only the design film is embossed as in the past. After that, as compared with the case where this is laminated on a nonwoven fabric, the production takes less trouble and the nonwoven fabric laminate 1 which has been embossed can be easily obtained. Furthermore, the decorative film 12 is a co-extruded film made of a polyolefin resin, and can be easily printed and aluminum-deposited, is easily laminated by heat, and requires time and effort to manufacture the nonwoven fabric laminate 1. do not do.
また、 意匠性フィルム 1 2の厚さ寸法を 5〜4 0 0 としたため、 適当な強 度を有し、 ハンドリングにも手間を要しない。 In addition, since the thickness of the design film 12 is set to 5 to 400, the strength It has a high degree of handling and does not require much effort in handling.
不織布 1 1をスパンポンド不織布としたため、 薄く、 密度が高く、 耐摩耗性が 高い不織布とすることができる。 また、 メルトブロー法等と比較して、 スパンポ ンド法により製造された不織布は、 連続長繊維からなり、 ケバが発生しにくいと いう利点がある。  Since the non-woven fabric 11 is a spun-pound non-woven fabric, the non-woven fabric can be thin, high in density and high in abrasion resistance. Further, as compared with the melt blow method or the like, the nonwoven fabric produced by the spunbond method has an advantage that it is made of continuous filaments and is less likely to generate fluff.
また、 不織布 1 1は、 2〜2 0デニールであり、 表面にけばが発生しにくく、 緻密性に優れたものとすることができる。 さらに、 不織布 1 1の目付は、 7〜 1 0 0 g Zm2であるため、 ハンドリングに必要な強度を有し、 かつ、 重量も適当で あるため、 ハンドリング性に優れ、 不織布積層体 1の製造に手間を要しない。 第三層を不織布 1 3としたため、 不織布積層体 1に布の感触を与えることがで きる。また、第三層の不織布 1 3の目付は 5 0 g Zm2以下であるため、意匠性フィ ルム 1 2が透けて見え、 意匠性の優れた不織布積層体 1とすることができる。 さらに、 不織布 1 1、 意匠性フィルム 1 2、 不織布 1 3は、 熱ラミネート性に 優れるポリオレフィン系樹脂製であるため、 容易に熱ラミネートすることができ る。 In addition, the nonwoven fabric 11 has a denier of 2 to 20 and is less likely to generate fuzz on the surface, and can be excellent in denseness. Furthermore, since the basis weight of the nonwoven fabric 11 is 7 to 100 g Zm 2, it has the strength necessary for handling and has an appropriate weight, so that it has excellent handling properties and manufacture the nonwoven fabric laminate 1. It does not take much effort. Since the third layer is made of the nonwoven fabric 13, the nonwoven fabric laminate 1 can be given the feel of a cloth. In addition, since the basis weight of the nonwoven fabric 13 of the third layer is 50 g Zm 2 or less, the design film 12 can be seen through, and the nonwoven fabric laminate 1 having excellent design properties can be obtained. Furthermore, since the nonwoven fabric 11, the decorative film 12 and the nonwoven fabric 13 are made of a polyolefin resin having excellent heat lamination properties, they can be easily thermally laminated.
また、 インライン加工により、 不織布積層体 1を製造したため、 第一層の不織 布 1 1の製造と、 熱エンボスラミネートとを同時に行うことができるため、 製造 工程を減らすことができ、 不織布積層体 1の製造コストを削減できる。  In addition, since the nonwoven fabric laminate 1 was manufactured by in-line processing, the production of the first nonwoven fabric 11 and the hot emboss lamination can be performed simultaneously, so that the number of manufacturing steps can be reduced and the nonwoven fabric laminate can be reduced. 1. The manufacturing cost can be reduced.
さらに、 不織布積層体 1を縫製して得られた袋は、 意匠性に優れ、 耐摩耗性が 高く、 製造が容易なものとすることができる。 なお、 本発明は前述の実施の形態に限定されるものではなく、 本発明の目的を 達成できる範囲での変形、 改良等は本発明に含まれるものである。  Furthermore, the bag obtained by sewing the nonwoven fabric laminate 1 has excellent design, high abrasion resistance, and can be easily manufactured. It should be noted that the present invention is not limited to the above-described embodiment, but includes modifications and improvements as long as the object of the present invention can be achieved.
例えば、 前記実施形態では、 インライン加工としたが、 これに限らず、 各層を 形成したのち、 別途、 熱エンボスラミネートしてもよい。  For example, in the above-described embodiment, in-line processing is performed. However, the present invention is not limited to this, and after each layer is formed, hot emboss lamination may be separately performed.
前記実施形態は、 第一層の不織布 1 1をスパンポンド不織布としたが、 これに 限らず、 他の製法による不織布、 例えば、 熱風カード法により製造された不織布 としてもよい。 ただし、 スパンポンド不織布は、 薄く、 密度が高く、 耐摩耗性が 高いという利点を有している。 In the above-described embodiment, the first layer nonwoven fabric 11 is a spun-pound nonwoven fabric. However, the present invention is not limited thereto, and a nonwoven fabric manufactured by another method, for example, a nonwoven fabric manufactured by a hot air card method may be used. However, spun-pound nonwovens are thin, dense, and abrasion resistant. It has the advantage of being expensive.
また、 意匠性フィルム 1 2は、 熱可塑性樹脂上に印刷、 アルミ蒸着したものと したが、 他の方法により、 意匠加工を施したものとしてもよい。  Further, the design film 12 is printed and aluminum-deposited on a thermoplastic resin, but may be subjected to design processing by another method.
さらに、 不織布 1 1、 意匠性フィルム 1 2、 不織布 1 3は、 ポリオレフィン系 樹脂製としたが、 ポリオレフイン系樹脂に限られず、 熱可塑性樹脂製であればよ レ^ ただし、 意匠性フィルム 1 2は、 一般的に軟包材として用いられているもの が好ましい。  Furthermore, the nonwoven fabric 11, the decorative film 12 and the nonwoven fabric 13 are made of polyolefin resin, but are not limited to polyolefin resin, and may be made of thermoplastic resin. Those generally used as soft packaging materials are preferred.
前記実施形態では、 不織布積層体 1の第三層を不織布 1 3としたが、 透明フィ ルムとしてもよい。 透明フィルムとする場合には、 一般的に軟包材として用いら れているものが好ましい。 不織布積層体 1の意匠性をさらに向上させるために、 第三層は印刷等の意匠加工が施されたフィルムであってもよい。 印刷されたフィ ルムを用いる場合には、 摩擦堅牢度を考慮すると、 印刷面をラミ面とすることが 好ましい。  In the above embodiment, the third layer of the nonwoven fabric laminate 1 is the nonwoven fabric 13, but may be a transparent film. In the case of forming a transparent film, a film generally used as a soft packaging material is preferable. In order to further improve the design of the nonwoven fabric laminate 1, the third layer may be a film that has been subjected to design processing such as printing. When a printed film is used, the printed surface is preferably a laminated surface in consideration of the fastness to friction.
さらに、 不織布積層体 1を三層構造のものとしたが、 これに限らず、 四層以上 の構造のものとしてもよく、 第一層の不織布 1 1と、 第二層の意匠性フィルム 1 2のみからなる二層構造としてもよい。  Furthermore, although the nonwoven fabric laminate 1 has a three-layer structure, the present invention is not limited to this, and the nonwoven fabric laminate 1 may have a four-layer or more structure. The first-layer nonwoven fabric 11 and the second-layer design film 1 2 It may have a two-layer structure consisting only of the above.
また、 前記実施形態では、 熱エンボス装置 2 7は、 一段式のものとしていたが、 これに限らず、 多段式のものとしてもよい。 熱エンボス装置 2 7が多段式である 場合には、不織布 1 1の固定化と、熱ラミネートとを個別にできるため、ラミネ一 ト強度が安定化し、 加工速度を向上させることができる。 本発明の効果を確認するために以下の実験を行った。  Further, in the above-described embodiment, the heat embossing device 27 is a single-stage type, but is not limited thereto, and may be a multi-stage type. When the heat embossing device 27 is a multi-stage type, the immobilization of the nonwoven fabric 11 and the heat lamination can be performed separately, so that the laminating strength can be stabilized and the processing speed can be improved. The following experiment was performed to confirm the effects of the present invention.
(実施例 1 )  (Example 1)
実施例 1で製造した不織布積層体は以下のようである。  The nonwoven fabric laminate produced in Example 1 is as follows.
[不織布積層体の構成] [Configuration of nonwoven fabric laminate]
第一層 (不織布) :ポリプロピレン製スパンポンド不織布 (原料:ポリプロピ レン樹脂 出光石油化学社製「Idemitsu PP」グレード Y 6 0 0 5 GM、 M I ( 2 3 0 °C) = 3 0 g Z l 0分) 第二層(意匠性フィルム) :全面印刷済み共押し出し未延伸ポリプロ First layer (non-woven fabric): Spun-pound non-woven fabric made of polypropylene (Raw material: Polypropylene resin “Idemitsu PP” grade, Idemitsu Petrochemical Co., Ltd. Y 600 GM, MI (230 ° C.) = 30 g Z l 0 Minutes) Second layer (design film): Co-extruded unstretched polypropylene printed on the entire surface
ルム (出光ュニテック社製 「ュニラックス」 グレード RS 5 9 5 C、 30 zm) 第三層 (不織布) :ポリプロピレン製スパンポンド不織布 (出光ュニテック社 製 「ストラテック」 グレード RN 2 02 0、 20 g /m2) Lumm (Idemitsu Unitech's “Unilux” grade RS595C, 30 zm) Third layer (non-woven fabric): Polypropylene spun-pound nonwoven fabric (Idemitsu Unitech's “Stratec” grade RN202, 20 g / m 2 )
[不織布積層体の製造] [Manufacture of nonwoven fabric laminate]
前記実施形態の製造装置 2を用いて不織布積層体を製造した。  A nonwoven fabric laminate was manufactured using the manufacturing apparatus 2 of the embodiment.
ホッパー 2 1に第一層の不織布の原料となるポリプロピレン樹脂を投入し、 2 A polypropylene resin, which is a raw material of the first layer nonwoven fabric, is put into the hopper 2 1, and 2
30°Cで、 40 g m2となるように押し出し機 2 2により押し出し、 コンベア 2At 30 ° C, extruded with extruder 2 2 to 40 gm 2 , conveyor 2
5のベルト 2 54上にウェブを堆積させた。 繊維系は 3デニ一ルであった。 The web was deposited on a belt 254 of 5. The fiber system was 3 denier.
次に、 繰り出し機 26A, 26 Bにより、 全面印刷済み共押し出し未延伸ポリ プロピレンフィルム、 ポリプロピレン製スパンポンド不織布を繰り出してウェブ に積層させた。  Next, the co-extruded unstretched polypropylene film and polypropylene spun-punched nonwoven fabric that had been printed on the entire surface were fed by the feeders 26A and 26B, and were laminated on the web.
これを第一層のウェブがフラットロール 2 7 2に接し、 第三層の不織布がェン ボス口一ル 2 7 1に接するように、 熱エンボス装置 2 7に投入し、 不織布積層体 を得た。  This is put into the hot embossing device 27 so that the web of the first layer is in contact with the flat roll 272 and the nonwoven fabric of the third layer is in contact with the emboss opening 271 to obtain a nonwoven fabric laminate. Was.
なお、 エンボスロール 27 1は、 エンボス面積 1 3 %であり、 格子状形状のも のである。 また、 エンボス口一ル 27 1の温度は 140° (:、 フラット口一ル 27 2の温度は 1 50°Cであった。  The embossing roll 27 1 has an emboss area of 13% and has a lattice shape. The temperature of the embossed opening 27 1 was 140 ° (:, the temperature of the flat opening 27 2 was 150 ° C.
[評価] [Evaluation]
不織布積層体の摩耗堅牢度を J I S L 0 849に従い評価したところ、 結 果は 5級であり、 色落ちは認められなかった。  When the wear fastness of the nonwoven fabric laminate was evaluated in accordance with JIS L0849, the result was class 5, and no color fading was observed.
(実施例 2 )  (Example 2)
実施例 2で製造した不織布積層体は以下のようである。  The nonwoven fabric laminate produced in Example 2 is as follows.
[不織布積層体の構成] [Configuration of nonwoven fabric laminate]
第一層 (不織布) :ポリエチレン製スパンポンド不織布 (原料:直鎖状低密度 ポリエチレン樹脂 出光石油化学社製 ridemitsu LLJ グレード 2074 G、 M I (1 90 °C) = 2 5 gZl O分)  First layer (non-woven fabric): Polyethylene spun-pound non-woven fabric (raw material: linear low-density polyethylene resin ridemitsu LLJ grade 2074 G, Idemitsu Petrochemical Co., Ltd., MI (190 ° C) = 25 gZlO content)
第二層 (意匠性フィルム) :アルミ蒸着加工済み共押し出し直鎖状低密度ポリ エチレンフィルム (日立エーアイシ一社製 「ヒ夕パックス」 3 0 m) 第三層 (フィルム) :キャラクター柄が部分印刷された共押し出し直鎖状低密 度ボリエチレンフィルム (出光ュニテック社製 「ュニラックス」 グレード L SSecond layer (design film): Co-extruded linear low-density poly deposited with aluminum Ethylene film (Hitachi Pax 30 m, Hitachi AIC) 3rd layer (film): Co-extruded linear low-density polyethylene film partially printed with character patterns Grade LS
7 4 0 C、 4 0 m) (740 C, 40 m)
[不織布積層体の製造] [Manufacture of nonwoven fabric laminate]
実施例 1と同様に製造装置 2を用いて不織布積層体の製造を行った。  A nonwoven fabric laminate was manufactured using the manufacturing apparatus 2 in the same manner as in Example 1.
ホッパ一2 1に第一層の不織布の原料となる直鎖状低密度ポリエチレン樹脂を 投入し、 2 0 0 °Cで、 3 0 g /m2となるように押し出し機 2 2により押し出し、 コンベア 2 5のベルト 2 5 4上にウェブを堆積させた。 繊維系は 4デニールで あった。 The linear low density polyethylene resin as a raw material for the nonwoven fabric of the first layer in the hopper one 2 1 was charged, in 2 0 0 ° C, 3 0 g / m 2 and so as to extrusion by extruder 2 2, conveyor The web was deposited on 25 belts 25 4. The fiber system was 4 denier.
次に、 繰り出し機 2 6 A, 2 6 Bにより、 アルミ蒸着加工済み共押し出し直鎖 状低密度ポリエチレンフィルム、 キャラクタ一柄が部分印刷された共押し出し直 鎖状低密度ポリエチレンフィルムを繰り出してウェブ上に積層させた。 この際、 部分印刷された共押し出し直鎖状低密度ポリエチレンフィルムは部分印刷された 面をラミ面とした。  Next, the co-extruded linear low-density polyethylene film with aluminum vapor deposition and the co-extruded linear low-density polyethylene film partially printed with a character are fed out on the web by the feeding machines 26A and 26B. Was laminated. At this time, the partially printed co-extruded linear low-density polyethylene film had a partially printed surface as a laminated surface.
これを第一層のウェブがフラットロール 2 7 2に接し、 第三層のフィルムがェ ンポスロール 2 7 1に接するように、 熱エンボス装置 2 7に投入し、 不織布積層 体を得た。  This was put into a hot embossing device 27 so that the first layer web was in contact with the flat roll 272 and the third layer film was in contact with the emboss roll 271 to obtain a nonwoven fabric laminate.
なお、 エンボスロール 2 7 1は、 実施例 1と同様のものである。 また、 ェンポ スロール 2 7 1及びフラットロ一ル 2 7 2の温度は 1 2 0 °Cであった。  The embossing roll 271 is the same as that of the first embodiment. The temperature of the embossrol 2711 and the flat roll 2772 was 120 ° C.
[評価] [Evaluation]
不織布積層体の摩耗堅牢度を J I S L 0 8 4 9に従い評価したところ、 結 果は 5級であり、 色落ちは認められなかった。  When the wear fastness of the nonwoven fabric laminate was evaluated in accordance with JIS L0849, the result was grade 5, and no color fading was observed.
(比較例 1 )  (Comparative Example 1)
ポリプロピレン製スパンポンド不織布 (出光ュニテック社製 「ストラテック」 ダレ一ド RW 2 0 7 0、 7 0 g /m2) にグラビア印刷にて全面印刷を施した。 The entire surface was printed by gravure printing on a polypropylene spun pond nonwoven fabric (“Stratec” Dale RW 270, 70 g / m 2 , manufactured by Idemitsu Unitech).
[評価] [Evaluation]
この不織布の摩耗堅牢度を J I S L 0 8 4 9に従い評価したところ、 結果 は 3級であり、 色落ちが認められた。 When the wear fastness of this nonwoven fabric was evaluated in accordance with JISL 0849, the result was Was grade 3 and discoloration was observed.
(比較例 2 )  (Comparative Example 2)
実施例 2のアルミ蒸着加工済み共押し出し直鎖状低密度: Aluminum Extruded Coextruded Linear Low Density of Example 2:
と、 キャラクタ一柄が部分印刷された共押し出し直鎖状低密度: And a co-extruded linear low density partly printed with one character:
ルムとをドライラミネ一夕にて積層し、 さらに、 直鎖状低密度ポリエチレンスパ ンボンド不織布 (出光ュニテック社製 「ストラテック L L」 L W 2 0 4 0 4 0 g /m2) を押し出しラミネ一ト機にてポリサンドラミネ一卜した。 Laminating the Lum at Dorairamine Isseki further, linear low density polyethylene Spa spunbonded nonwoven fabric (Idemitsu Yunitekku Co. "Stora Tech LL" LW 2 0 4 0 4 0 g / m 2) extrusion laminating one winding machine At Polysandra Mineral.
[評価] [Evaluation]
この不織布の摩耗堅牢度を J I S L 0 8 4 9に従い評価したところ、 結果 は 5級であり、 色落ちは認められなかったものの、 製造工程が複雑であった。 ま た、 不織布積層体の表面はエンボス加工されておらず、 硬く仕上がり、 好適な風 合いには仕上がらなかった。 産業上の利用可能性  When the wear fastness of this nonwoven fabric was evaluated in accordance with JIS L0849, the result was grade 5, and no discoloration was observed, but the manufacturing process was complicated. In addition, the surface of the nonwoven fabric laminate was not embossed, was finished hard, and did not have a suitable texture. Industrial applicability
本発明は、 不織布積層体およびその製造方法、 この不織布積層体を用いた袋に 関し、 包装用や運搬用の袋あるいは梱包材料などとしてとして利用できる。  INDUSTRIAL APPLICABILITY The present invention relates to a nonwoven fabric laminate and a method for producing the same, and a bag using the nonwoven fabric laminate, and can be used as a bag for packaging or transportation, a packing material, or the like.

Claims

請 求 の 範 囲 The scope of the claims
1 . 少なくとも熱可塑性樹脂製の不織布よりなる第一層と、 意匠加工が施され た熱可塑性樹脂製の意匠性フィルムよりなる第二層とを有し、 これらの各層は熱 エンボスラミネートされていることを特徴とする不織布積層体。 1. At least a first layer made of a thermoplastic resin nonwoven fabric and a second layer made of a design-processed thermoplastic resin design film, and each of these layers is hot-embossed laminated. A nonwoven fabric laminate, characterized in that:
2 . 請求項 1に記載の不織布積層体において、  2. The nonwoven fabric laminate according to claim 1,
熱可塑性樹脂製のフィルムまたは不織布よりなる第三層を有することを特徴と する不織布積層体。  A nonwoven fabric laminate having a third layer made of a thermoplastic resin film or nonwoven fabric.
3 . 請求項 1または請求項 2に記載の不織布積層体において、  3. In the nonwoven fabric laminate according to claim 1 or claim 2,
前記意匠性フィルムは、 熱可塑性樹脂製のフィルム上に印刷もしくはアルミ蒸 着を行ったものであることを特徴とする不織布積層体。  The nonwoven fabric laminate, wherein the design film is formed by printing or aluminum vapor-depositing on a film made of a thermoplastic resin.
4 . 請求項 1から請求項 3の何れかに記載の不織布積層体において、  4. The nonwoven fabric laminate according to any one of claims 1 to 3,
前記第一層の不織布はスパンポンド不織布であることを特徴とする不織布積層 体。  The nonwoven fabric laminate, wherein the nonwoven fabric of the first layer is a spun pound nonwoven fabric.
5 . 請求項 1から請求項 4の何れかに記載の不織布積層体において、 5. The nonwoven fabric laminate according to any one of claims 1 to 4,
前記各層に用いられる熱可塑性樹脂は、 ポリオレフィン系樹脂であることを特 徴とする不織布積層体。  The nonwoven fabric laminate, wherein the thermoplastic resin used for each of the layers is a polyolefin-based resin.
6 . 少なくとも熱可塑性樹脂製の不織布よりなる第一層と、 意匠加工が施され た熱可塑性樹脂製の意匠性フィルムよりなる第二層とを有する不織布積層体の製 造方法であって、  6. A method for producing a nonwoven fabric laminate having at least a first layer made of a thermoplastic resin nonwoven fabric and a second layer made of a design-processed thermoplastic resin design film,
少なくとも前記二層を同時に熱エンボスラミネ一トすることを特徴とする不織 布積層体の製造方法。  A method for producing a nonwoven laminate, wherein at least the two layers are simultaneously hot-embossed and laminated.
7 . 請求項 6に記載の不織布積層体の製造方法であって、  7. The method for producing a nonwoven fabric laminate according to claim 6, wherein
前記不織布積層体は、 熱可塑性樹脂製のフィルムまたは不織布よりなる第三層 を備え、  The nonwoven fabric laminate includes a third layer made of a thermoplastic resin film or nonwoven fabric,
前記三層を同時に熱エンボスラミネートすることを特徴とする不織布積層体の 製造方法。  A method for producing a nonwoven fabric laminate, wherein the three layers are simultaneously subjected to hot emboss lamination.
8 . 請求項 6または請求項 7に記載の不織布積層体の製造方法において、 前記熱エンボスラミネートは、 前記第一層の不織布の製造時に第二層または、 第二層及び第三層を積層して、 エンボス加工を施すィンライン加工により行われ ることを特徴とする不織布積層体の製造方法。 8. The method for producing a nonwoven fabric laminate according to claim 6 or claim 7, The non-woven fabric laminate, wherein the hot emboss lamination is performed by in-line processing in which the second layer or the second layer and the third layer are laminated during the production of the first non-woven fabric, and embossing is performed. Manufacturing method.
9 . 請求項 1から請求項 5の何れかに記載の不織布積層体を用いて形成したこ とを特徵とする袋。  9. A bag characterized by being formed using the nonwoven fabric laminate according to any one of claims 1 to 5.
PCT/JP2003/005693 2003-05-07 2003-05-07 Nonwoven-fabric laminate, process for producing nonwoven-fabric laminate, and bag comprising nonwoven-fabric laminate WO2004098871A1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0819570A (en) * 1994-07-06 1996-01-23 Kuraray Co Ltd Leakage preventing sheet and sanitary material
JPH0852843A (en) * 1994-08-12 1996-02-27 New Oji Paper Co Ltd Packaging material
JPH11302961A (en) * 1998-04-16 1999-11-02 Nippon Petrochem Co Ltd Wrapping base fabric and wrapping material using the same
JP2000167962A (en) * 1998-12-03 2000-06-20 Mitsui Chemicals Inc Bulky nonwoven fabric or nonwoven fabric laminate and thermal bonding method therefor
JP2001315342A (en) * 2000-05-11 2001-11-13 Konica Corp Ink jet head, method for bonding actuator and manifold

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0819570A (en) * 1994-07-06 1996-01-23 Kuraray Co Ltd Leakage preventing sheet and sanitary material
JPH0852843A (en) * 1994-08-12 1996-02-27 New Oji Paper Co Ltd Packaging material
JPH11302961A (en) * 1998-04-16 1999-11-02 Nippon Petrochem Co Ltd Wrapping base fabric and wrapping material using the same
JP2000167962A (en) * 1998-12-03 2000-06-20 Mitsui Chemicals Inc Bulky nonwoven fabric or nonwoven fabric laminate and thermal bonding method therefor
JP2001315342A (en) * 2000-05-11 2001-11-13 Konica Corp Ink jet head, method for bonding actuator and manifold

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