"Electronic device comprising a percolated structured film"
The present invention relates to an electronic de- vice comprising a first electrode and a second electrode in electric contact through a conductive channel, the two electrodes being designed to apply a voltage to said conductive channel, the latter comprising a percolated structure film made of a metal or semiconductor material.
Systems consisting of a chaotic distribution of dielectric and metal are known as discontinuous or percolated structures.
When in the form of thin films, said percolated structures have properties of electron transport differing from the properties that would occur for a massive structure, and in particular a type of transport that can be related to conduction by percolation.
Said percolated structure films can also be laid by means of different deposition techniques, such as thermal evaporation, electron beam, sputtering, cluster beam deposition (PMC-Pulsed Microplasma Cluster) onto substrates made of glass, silicon with <100> orientation or other dielectric, and can be made of a metal, dielectric or semiconductor material.
Percolation level is defined as the point at which, during the deposition process, the material shifts from an insulating to a conductive behavior. This occurs since during the deposition process metal clusters are built, which grow and aggregate by thermal stirring and Coulomb attraction, thus forming an irregular structure consisting of conductive nanowires. Going on with deposition, a continuous film with metal properties is obtained. Thicknesses that are concerned by percolation effect are between 2 and 10 nanometers,
depending on substrate temperature, deposition parameters and selected metal, which can be in case of metals copper, silver, gold or aluminum.
The preparation of metal films at percolation level can also occur by cluster deposition: in particular through PMCS sources ("Pulsed Microplasma Cluster Source") metal/semiconductor matrixes consisting of a regular or chaotic cluster distribution are obtained. Said technique generates clusters by condensing, within a vacuum chamber known as pre-expansion chamber, vapors of atoms previously "stripped" off through a plasma pulse from a target; said clusters are then accelerated by means of a nozzle with ultrasonic acceleration, and then deposited onto glass or quartz substrates within a deposition chamber. The simultaneous use within the deposition chamber of thermal evaporation, e-beam, sputtering or CVD techniques, enables to obtain 3D films and matrixes with inclusions of different clusters therein. Moreover, the application of convenient masks onto the substrate allows to deposit regular matrixes of clusters spaced according to the pitch of said mask.
Electron mobility and therefore electric conductance within the material differ from a normal metal conduction. Indeed, the resistance of a percolated structure depends on the behavior of the network of
• conductive nanowires, which behave like electron waveguides and form a bi-dimensional set of nanometric channels or nanoelectrodes through which electrons can stream. The structure looks like a fractal system in which local distances between said nanoelectrodes are of a few angstroms. The application of a voltage through planar electrodes onto a percolated structure film results in an electric field with local values of 106-107 V/cm, which is sufficient to induce electron
tunneling phenomena between the metal nanoelectrodes separated by dielectric islands.
In a metal the behavior of electrons is the same as in a gas in which charges can freely move within en- ergy bands. If the system is spatially limited, electrons are arranged on energy levels and charge exchange takes place in a discrete way. The time for charging a metal cluster having a capacity C and a resistance R can be obtained from the charge/discharge time RC of the system τ = CR = C/G, where G is the conductance of the system corresponding to the inverse of resistance.
The energy associated to said time is obtained from δE - h/τ, from which the quantum conductance of the cluster is obtained, i.e. G0 = e2/2h . The conductance of a percolated layer is proportional above all to quantum conductance, i.e. G0, since said film has conductive nanowires in which electron motion is limited. Said conductance is further proportional to the width of the percolated layer subtended by the electrodes, and to the ratio of a characteristic length Lc to a distance between measuring electrodes d. The characteristic length Lc is the length representing the distance between two electrodes locally concerned by the tunneling phenomenon. Said characteristic length Lc is obtained experimentally and depends on material, deposition method and substrate type.
Depending on the voltage applied to said planar electrodes, said conductance has a strong non-linearity for given values of applied voltage. See Figure 1, where VA refers to applied voltage and G to the conductance of the percolated film.
Under the influence of a particular electric field charges can shift from a nanoelectrode to another one within the percolated film. If the absolute value of the charges in the system is above a critical value, a
charge can cross the junction, i.e. the potential barrier that limits said charge. The energy difference between final and initial status determines the critical charge value . Conductance non-linearity looks interesting for use in devices performing a function of non-linear transfer; however, the small range of applied voltage in which non-linearity effect occurs makes its use difficult . The present invention aims at conceiving a solution that can easily exploit conductance non-linearity of percolated films in electronic devices.
According to the present invention said aim is achieved thanks to an electronic device having the characteristics specifically referred to in the appended claims .
As will be evident, in the preferred embodiment of the invention the electronic device comprises a first electrode and a second electrode in electric contact through a conductive channel, the two electrodes being designed to apply a voltage to the conductive channel, the latter comprising a percolated structure film made of a metal or semiconductor material, said device including a further electrode, known as gate electrode, designed to apply a field within the structure consisting of the percolated film.
The invention will now be described with reference to the accompanying drawings, given by mere way of non- limiting example, in which: - Figure 1 is a chart of physical properties of a material used in the electronic device according to the invention;
- Figure 2 is a schematic sectioned view of a first embodiment of an electronic device according to the invention;
- Figure 3 is a schematic plan view of a second embodiment of the electronic device according to the invention.
Figure 2 shows an electronic device according to the invention, which has a vertical structure.
Said electronic device, referred to with number 10, is basically a transistor and comprises a silicon substrate 11, onto which a thin silicon oxide layer 12 is laid, deposited by evaporation or oxidation of the substrate 11. Onto said silicon oxide layer 11 a percolated film 13 is laid. The percolated film 13 is laid in the area between two metal electrodes, a drain electrode 14 and a source electrode 15, thus basically carrying out the channel of the electronic device 10. A dielectric layer 16 is deposited above the percolated film 13, so as to insulate the latter and prevent a short circuit. Above the dielectric layer 16 a gate electrode 17 is laid.
A voltage VDS is applied between the drain elec- trode 14 and the source electrode 15, whereas a gate voltage VG is applied to the gate electrode 17.
The invention exploits charge transfer occurring in the percolated metal film. For energy values of the elementary charge e of e2/C, C being cluster capacity, higher than thermal energy kT, k being Boltzmann constant and T temperature, the electron can charge the cluster. Cluster charge opposed by Coulomb repulsion of electrons already in the cluster, known as Quantum Coulomb Blockade, enables charge transition through the system. Charge migration between the two electrodes VD and VS is allowed by gate voltage VG, which balances electron repulsion and "pumps" electrons through the chain into the percolated structure. Thus, conductance oscillates depending on gate voltage VG. If simplified, the structure can be described as a
chain of n clusters within the percolated film, connected to one another through tunnel junctions: the convenient variation of VG with respect to V enables cyclically an electron to be pumped and to migrate through conductive islands. Charge transfer through tunnel junctions within the percolated film depends on the cyclical variation of applied VG and is therefore a phenomenon regulated by a frequency f. Associated transferred current depends on said frequency and is I = ef.
In other words, in the electronic device according to the invention a voltage VDS builds up between drain electrode 14 and source electrode 15, which voltage results in an electron stream depending on the conduc- tance of the percolated film 13. Voltage-current characteristic has a non-linearity, i.e. an abrupt transition, due to the transition controlled by the electronic device 10 according to the invention by applying a suitable gate voltage VG. Gate voltage VG acts as switch and enables electron cascade transport from cluster to cluster within the percolated film 13. Finally, the charge status of the clusters belonging to the percolated film 13 is used as transistor leading voltage. Since the typical size of the clusters belonging to the percolated film 13, for instance gold on silicon, is of 10 to 50 nanometers, the electronic device 10 can have the drain 14 and source 15 electrode spaced only of few nanometers, so as to be electrically con- nected to one another also by means of only one cluster of the percolated film 13. The gate electrode 17 is deposited above said cluster of the percolated film 13.
Therefore, as is quite evident, it is possible to deposit onto a percolated film rows, matrixes and dis- ordered groups of transistor devices 10, each acting on
few or even only one metal or semiconductor cluster belonging to the percolated film 13.
Figure 3 shows a plan view of a second embodiment of the electronic device according to the invention, globally referred to with number 20, which basically carries out a transistor having a horizontal or planar structure.
The electronic device 20 comprises a percolated film 23 deposited within an area lying between four metal electrodes coupled two by two on two orthogonal axes: a pair of gate electrodes 27, to which gate voltage VG is applied, and a pair including a drain electrode 24 and a source electrode 25, to which drain- source voltage VDS is applied. The percolated film 23 is laid onto a dielectric substrate 21, in particular glass or quartz.
The solution described above enables to obtain great advantages with respect to known solutions.
The electronic device according to the • invention allows to efficiently exploit conductance non-linearity of percolated films, thanks to a transistor structure, by varying gate voltage, so as to balance Quantum Electron Blockade phenomenon.
Advantageously, the structure of the electronic device according to the invention can be carried out on few or even on only one cluster of the percolated film, so that said structure has almost an infinite number of nanoelectrodes, which confer a high potentiality and functionality to the electronic device according to the invention.
Obviously, though the basic idea of the invention remains the same, construction details and embodiments can widely vary with respect to what has been described and shown by mere way of example, however without leav- ing the framework of the present invention.
The percolated film can be a material consisting of metal clusters made of copper, silver, gold or aluminum. It can also comprise nanowires made of a semiconductor material, such as nanowires of SiGe on Si<100>, or semiconductor nanocrystals aggregated in an organic matrix.
The arrangement of the nanoelectrodes on the surface of the percolated film can be a complex network of disordered nanoelectrodes.