WO2004078303A3 - Process for separating metals - Google Patents

Process for separating metals Download PDF

Info

Publication number
WO2004078303A3
WO2004078303A3 PCT/GB2004/000911 GB2004000911W WO2004078303A3 WO 2004078303 A3 WO2004078303 A3 WO 2004078303A3 GB 2004000911 W GB2004000911 W GB 2004000911W WO 2004078303 A3 WO2004078303 A3 WO 2004078303A3
Authority
WO
WIPO (PCT)
Prior art keywords
cathode
control
geometric
typically
spent nuclear
Prior art date
Application number
PCT/GB2004/000911
Other languages
French (fr)
Other versions
WO2004078303A2 (en
Inventor
David John Hebditch
Zara Banfield
Original Assignee
British Nuclear Fuels Plc
David John Hebditch
Zara Banfield
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Nuclear Fuels Plc, David John Hebditch, Zara Banfield filed Critical British Nuclear Fuels Plc
Priority to EP04716662A priority Critical patent/EP1601819A2/en
Priority to JP2006505912A priority patent/JP2006520470A/en
Priority to US10/547,813 priority patent/US20060169590A1/en
Publication of WO2004078303A2 publication Critical patent/WO2004078303A2/en
Publication of WO2004078303A3 publication Critical patent/WO2004078303A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/34—Electrolytic production, recovery or refining of metals by electrolysis of melts of metals not provided for in groups C25C3/02 - C25C3/32
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/005—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells for the electrolysis of melts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention relates to an electrorefining apparatus and process, the apparatus being capable of operating in continuous mode, and including means for criticality control, preferably geometric criticality control. The means for geometric criticality control preferably comprises means for control of the dimensions of the apparatus and, typically, the invention provides electrochemical cells having a large surface area per unit volume, preferably in the form of thin, flat plates. Preferred embodiments of the invention include cells which comprise a crusting liquid cathode, a cast cathode, a fluidised cell or pulsed bed, a moving belt cathode, a consolidating cathode, or a liquid anode and a plate cathode. The process comprises a continuous process for the isolation of metals, typically uranium, from spent nuclear fuels, the process comprising electrochemically treating the spent nuclear fuels in the apparatus of the invention.
PCT/GB2004/000911 2003-03-04 2004-03-03 Process for separating metals WO2004078303A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP04716662A EP1601819A2 (en) 2003-03-04 2004-03-03 Process for separating metals
JP2006505912A JP2006520470A (en) 2003-03-04 2004-03-03 Process for separating metals
US10/547,813 US20060169590A1 (en) 2003-03-04 2004-03-03 Process for separating metals

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0304884.0 2003-03-04
GBGB0304884.0A GB0304884D0 (en) 2003-03-04 2003-03-04 Process for separating metals

Publications (2)

Publication Number Publication Date
WO2004078303A2 WO2004078303A2 (en) 2004-09-16
WO2004078303A3 true WO2004078303A3 (en) 2005-02-03

Family

ID=9954059

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2004/000911 WO2004078303A2 (en) 2003-03-04 2004-03-03 Process for separating metals

Country Status (5)

Country Link
US (1) US20060169590A1 (en)
EP (1) EP1601819A2 (en)
JP (1) JP2006520470A (en)
GB (1) GB0304884D0 (en)
WO (1) WO2004078303A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1031734C2 (en) * 2006-05-03 2007-11-06 Girasolar B V Process for purifying a semiconductor material using an oxidation-reduction reaction.
JP2009540313A (en) 2006-06-15 2009-11-19 ベルゴニュークレール・ソシエテ・アノニム Criticality prevention apparatus and method in nuclear fuel production
JP4753141B2 (en) * 2007-08-01 2011-08-24 独立行政法人 日本原子力研究開発機構 Method for dissolving and separating uranium using ionic liquid, and method for recovering uranium using the same
US20090134039A1 (en) * 2007-11-28 2009-05-28 Mehlin Dean Matthews System and method for isotope selective chemical reacations
US9475998B2 (en) 2008-10-09 2016-10-25 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
JP4843106B2 (en) * 2011-01-24 2011-12-21 独立行政法人日本原子力研究開発機構 Uranium recovery method using ionic liquid
US9631290B2 (en) * 2011-10-07 2017-04-25 The Board Of Regents Of The Nevada System Of Higher Education On Behalf Of The University Of Nevada, Las Vegas Room temperature electrodeposition of actinides from ionic solutions
US20130087464A1 (en) * 2011-10-07 2013-04-11 Nevada, Las Vegas Room temperature electrodeposition of actinides from ionic solutions
US10422048B2 (en) 2014-09-30 2019-09-24 The Board Of Regents Of The Nevada System Of Higher Education On Behalf Of The University Of Nevada, Las Vegas Processes for recovering rare earth elements
JP6615629B2 (en) * 2016-02-05 2019-12-04 株式会社東芝 Electrolytic treatment apparatus and electrolytic treatment method for metal alloy fuel
AU2017371918A1 (en) * 2016-12-08 2019-07-04 Clean Resources PTE. LTD. Recovery of gold and silver from precious metals-containing solids

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5225051A (en) * 1991-09-24 1993-07-06 The United States Of America As Represented By The United States Department Of Energy Electrowinning process with electrode compartment to avoid contamination of electrolyte
US5458745A (en) * 1995-01-23 1995-10-17 Covofinish Co., Inc. Method for removal of technetium from radio-contaminated metal
US5650053A (en) * 1995-11-24 1997-07-22 The United States Of America As Represented By The United States Department Of Energy Electrorefining cell with parallel electrode/concentric cylinder cathode
WO1999041752A1 (en) * 1998-02-11 1999-08-19 British Nuclear Fuels Plc Nuclear fuel reprocessing
US6156183A (en) * 1997-10-17 2000-12-05 Kabushiki Kaisha Toshiba Method of processing spent reactor fuel with magnesium alloy cladding
WO2001041152A2 (en) * 1999-12-03 2001-06-07 British Nuclear Fuels Plc Actinide production
WO2002066712A1 (en) * 2001-02-21 2002-08-29 British Nuclear Fuels Plc Electrorefining process for separating metals
WO2002099815A2 (en) * 2001-06-06 2002-12-12 British Nuclear Fuels Plc Actinide production

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446331A (en) * 1944-02-14 1948-08-03 William Marsh Rice Inst For Th Electrodeposition of aluminum
US2446350A (en) * 1944-02-29 1948-08-03 William Marsh Rice Inst For Th Electrodeposition of aluminum
US2446349A (en) * 1944-02-29 1948-08-03 William Marsh Rice Inst For Th Electrodeposition of aluminum
GB8811195D0 (en) * 1988-05-11 1988-06-15 Atomic Energy Authority Uk Rotary centrifugal contactor
US5411722A (en) * 1993-10-27 1995-05-02 The United States Of America As Represented By The United States Department Of Energy Compact reaction cell for homogenizing and down-blanding highly enriched uranium metal
FR2738165B1 (en) * 1995-09-06 1997-11-28 Cogema PROCESS AND DEVICE FOR DISSOLVING A MIXTURE OF URANIUM AND PLUTONIUM OXIDES
JP3868635B2 (en) * 1998-09-11 2007-01-17 株式会社東芝 Method and apparatus for treating waste from nuclear fuel cycle facility

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5225051A (en) * 1991-09-24 1993-07-06 The United States Of America As Represented By The United States Department Of Energy Electrowinning process with electrode compartment to avoid contamination of electrolyte
US5458745A (en) * 1995-01-23 1995-10-17 Covofinish Co., Inc. Method for removal of technetium from radio-contaminated metal
US5650053A (en) * 1995-11-24 1997-07-22 The United States Of America As Represented By The United States Department Of Energy Electrorefining cell with parallel electrode/concentric cylinder cathode
US6156183A (en) * 1997-10-17 2000-12-05 Kabushiki Kaisha Toshiba Method of processing spent reactor fuel with magnesium alloy cladding
WO1999041752A1 (en) * 1998-02-11 1999-08-19 British Nuclear Fuels Plc Nuclear fuel reprocessing
WO2001041152A2 (en) * 1999-12-03 2001-06-07 British Nuclear Fuels Plc Actinide production
WO2002066712A1 (en) * 2001-02-21 2002-08-29 British Nuclear Fuels Plc Electrorefining process for separating metals
WO2002099815A2 (en) * 2001-06-06 2002-12-12 British Nuclear Fuels Plc Actinide production

Also Published As

Publication number Publication date
GB0304884D0 (en) 2003-04-09
US20060169590A1 (en) 2006-08-03
WO2004078303A2 (en) 2004-09-16
EP1601819A2 (en) 2005-12-07
JP2006520470A (en) 2006-09-07

Similar Documents

Publication Publication Date Title
WO2004078303A3 (en) Process for separating metals
US6298996B1 (en) Three dimensional electrode for the electrolytic removal of contaminants from aqueous waste streams
CA2627803A1 (en) Method and apparatus for recovering valuable substance from lithium secondary battery
CN106796820A (en) Reactivity control in fusedsalt reactor
US4911804A (en) Electrochemical reactor for copper removal from barren solutions
EP1487748A4 (en) Electrochemical process for decontamination of radioactive materials
EP0475622A1 (en) Process for removing radioactive burden from spent nuclear reactor decontamination solutions using electrochemical ion exchange
AU5852601A (en) Electrochemical sensing
Bertazzoli et al. Electrolytic removal of metals using a flow-through cell with a reticulated vitreous carbon cathode
KR20130143615A (en) Modular cathode assemblies and methods of using the same for electrochemical reduction
JP2005519192A5 (en)
TW200626718A (en) Microfluidic device comprising electrolysis device for cell lysis and method for electrochemically lysing cells using the same
US6942105B2 (en) In-line filtration for a particle-based electrochemical power system
TWI348502B (en) Method for regenerating etching solutions containing iron for the use in etching or pickling copper or copper alloys and an apparatus for carrying out said method
US8097132B2 (en) Process and device to obtain metal in powder, sheet or cathode from any metal containing material
Guillaume et al. Electroleaching and electrodeposition of zinc in a single-cell process for the treatment of solid waste
Bertazzoli et al. Mass transport properties of a flow-through electrolytic reactor using a porous electrode: performance and figures of merit for Pb (II) removal
JP2006520470A5 (en)
Fischer et al. Treatment of Process Water Containing Heavy Metals with a Two‐Stage Electrolysis Procedure in a Membrane Electrolysis Cell
GB2002032A (en) Electrolytic cell and method of electrolysis using such a cell
Wang et al. Diffusion of hexavalent chromium in chromium-containing slag as affected by microbial detoxification
JP2005036245A (en) Process for electrochemical decomposition of precursors in powder form and electrolysis cell suitable therefor
KR101005262B1 (en) Vertical electrokinetic flushing equipment for a decontamination of radioactive soil
EP3257818A1 (en) A method and system for electrochemically purifying water
Sedahmed Mass transfer at vertical cylinders under forced convection induced by the counter electrode gases

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
ENP Entry into the national phase

Ref document number: 2006169590

Country of ref document: US

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 10547813

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 2006505912

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 2004716662

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2004716662

Country of ref document: EP

DPEN Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed from 20040101)
WWP Wipo information: published in national office

Ref document number: 10547813

Country of ref document: US

WWR Wipo information: refused in national office

Ref document number: 2004716662

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 2004716662

Country of ref document: EP