WO2004074333A3 - Process for homo- or copolymerizationof conjugated olefines - Google Patents
Process for homo- or copolymerizationof conjugated olefines Download PDFInfo
- Publication number
- WO2004074333A3 WO2004074333A3 PCT/US2004/004637 US2004004637W WO2004074333A3 WO 2004074333 A3 WO2004074333 A3 WO 2004074333A3 US 2004004637 W US2004004637 W US 2004004637W WO 2004074333 A3 WO2004074333 A3 WO 2004074333A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- occurrence
- independently
- metal
- groups
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 abstract 5
- 239000002184 metal Substances 0.000 abstract 5
- 239000003446 ligand Substances 0.000 abstract 4
- 125000004429 atom Chemical group 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000002879 Lewis base Substances 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- -1 delocalized Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 150000007527 lewis bases Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229910052727 yttrium Inorganic materials 0.000 abstract 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical group [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Metal complexes suitable for use in polymerization are described which correspond to Formula (1) in which M is yttrium, a group 4 metal, a lanthanide or an actinide metal; Ml is a group 1 or group 2 metal; T independently each occurrence is nitrogen or phosphorus; RB and RC independently each occurrence is hydrogen or is selected from certain groups and two RC groups may be joined together forming a divalent ligand group; X independently each occurrence is an anionic ligand group having up to 60 atoms, provided that X is not a cyclic, delocalized, aromatic group that is π-bonded to M, and two X groups together may form a divalent ligand group; D independently each occurrence is a neutral Lewis base ligand having up to 30 nonhydrogen atoms; x is the number 1, 2 or 3; x' is the number 1 or 2; t is a number from 0 to 3; t' is a number from 0 to 3; r is the number 0 or 1 and o is the number 1 or 2. These metal complexes may be combined with one or more activator compounds to make catalyst compositions which may be used to manufacture polymers having a high percentage of the fraction of residual olefinic double bonds that are Z or cis units and a, low 1,2 polybutadiene content. The polymers are useful for modification of plastics and for the manufacture of a wide range of products including tires, golf balls, hoses, belts, gaskets, seals, and shoes.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44817703P | 2003-02-18 | 2003-02-18 | |
| US60/448,177 | 2003-02-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2004074333A2 WO2004074333A2 (en) | 2004-09-02 |
| WO2004074333A3 true WO2004074333A3 (en) | 2005-01-27 |
Family
ID=32908548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2004/004637 WO2004074333A2 (en) | 2003-02-18 | 2004-02-17 | Process for homo- or copolymerizationof conjugated olefines |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2004074333A2 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008107135A1 (en) * | 2007-03-06 | 2008-09-12 | Basell Polyolefine Gmbh | Iron complexes and their use in polymerization processes |
| CN102131837B (en) * | 2008-08-21 | 2014-10-15 | 陶氏环球技术有限责任公司 | Metal-ligand complexes and catalysts |
| FR2946048B1 (en) * | 2009-06-02 | 2012-12-28 | Michelin Soc Tech | CATALYTIC SYSTEM FOR POLYMERIZATION OF CONJUGATED DIENES, POLYMERISATION METHOD AND FUNCTIONAL POLYMER OBTAINED |
| US8202954B2 (en) | 2010-02-19 | 2012-06-19 | Dow Global Technologies Llc | Metal-ligand complexes and catalysts |
| KR101854480B1 (en) | 2010-02-19 | 2018-05-03 | 다우 글로벌 테크놀로지스 엘엘씨 | Process for polymerizing an olefin monomer and catalyst therefor |
| US9000107B2 (en) | 2011-01-31 | 2015-04-07 | Bridgestone Corporation | Process for producing polydienes |
| ITMI20111650A1 (en) | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | BIS-IMMINICO COMPLEX OF LANTHANIDES, CATALYTIC SYSTEM INCLUDING THE BIS-IMMINICO COMPLEX AND PROCEDURE FOR (CO) POLYMERIZATION OF CONJUGATED DIENES |
| ITMI20111651A1 (en) | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | BIS-IMMINO PYRHYDIN COMPLEX OF LANTHANIDES, CATALYTIC SYSTEM INCLUDING THE BIS-IMMINO PYRHYDINAL COMPLEX AND PROCEDURE FOR (CO) POLYMERIZATION OF CONJUGATED DIENES |
| EP2767542A1 (en) | 2013-02-18 | 2014-08-20 | Basell Polyolefine GmbH | Oligomerization catalyst |
| IT201600105714A1 (en) * | 2016-10-20 | 2018-04-20 | Versalis Spa | PROCEDURE FOR THE PREPARATION OF (CO) POLYMERS OF DIENES CONJUGATED IN THE PRESENCE OF A CATALYTIC SYSTEM INCLUDING A PYRIDYLUM IRON COMPLEX (III) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001068726A1 (en) * | 2000-03-16 | 2001-09-20 | Bp Chemicals Limited | Atom transfer radical polymerisation catalyst |
| WO2002090394A1 (en) * | 2001-05-04 | 2002-11-14 | Dow Global Technologies Inc. | Random or block co-or terpolymers produced by using of metal complex catalysts |
-
2004
- 2004-02-17 WO PCT/US2004/004637 patent/WO2004074333A2/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001068726A1 (en) * | 2000-03-16 | 2001-09-20 | Bp Chemicals Limited | Atom transfer radical polymerisation catalyst |
| WO2002090394A1 (en) * | 2001-05-04 | 2002-11-14 | Dow Global Technologies Inc. | Random or block co-or terpolymers produced by using of metal complex catalysts |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004074333A2 (en) | 2004-09-02 |
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