WO2004068690A1 - Actuator - Google Patents

Actuator Download PDF

Info

Publication number
WO2004068690A1
WO2004068690A1 PCT/JP2004/000999 JP2004000999W WO2004068690A1 WO 2004068690 A1 WO2004068690 A1 WO 2004068690A1 JP 2004000999 W JP2004000999 W JP 2004000999W WO 2004068690 A1 WO2004068690 A1 WO 2004068690A1
Authority
WO
WIPO (PCT)
Prior art keywords
actuator
electrolyte
operating portion
operating
conductive polymer
Prior art date
Application number
PCT/JP2004/000999
Other languages
French (fr)
Japanese (ja)
Inventor
Tetsuji Zama
Susumu Hara
Shingo Sewa
Original Assignee
Eamex Coporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eamex Coporation filed Critical Eamex Coporation
Publication of WO2004068690A1 publication Critical patent/WO2004068690A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F03MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
    • F03GSPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
    • F03G7/00Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for
    • F03G7/005Electro-chemical actuators; Actuators having a material for absorbing or desorbing gas, e.g. a metal hydride; Actuators using the difference in osmotic pressure between fluids; Actuators with elements stretchable when contacted with liquid rich in ions, with UV light, with a salt solution
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B25HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
    • B25JMANIPULATORS; CHAMBERS PROVIDED WITH MANIPULATION DEVICES
    • B25J9/00Programme-controlled manipulators
    • B25J9/10Programme-controlled manipulators characterised by positioning means for manipulator elements
    • B25J9/1075Programme-controlled manipulators characterised by positioning means for manipulator elements with muscles or tendons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B25HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
    • B25JMANIPULATORS; CHAMBERS PROVIDED WITH MANIPULATION DEVICES
    • B25J9/00Programme-controlled manipulators
    • B25J9/10Programme-controlled manipulators characterised by positioning means for manipulator elements
    • B25J9/1095Programme-controlled manipulators characterised by positioning means for manipulator elements chemically actuated
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02NELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N11/00Generators or motors not provided for elsewhere; Alleged perpetua mobilia obtained by electric or magnetic means
    • H02N11/006Motors

Definitions

  • the present invention relates to an actuator that includes a conductive polymer in an operation part.
  • conductive polymers such as polypyrrole exhibit electrolytic stretching, which is a phenomenon of stretching or deforming due to electrochemical oxidation and reduction. Electrolytic expansion and contraction of this conductive polymer is expected to be used as artificial muscles, robot arms, artificial arm actuators, and the like, and has attracted attention in recent years.
  • the actuator When the polypyrrole film and the counter electrode are immersed in the electrolyte and a voltage is applied to the counter electrode and the polypyrrole film, the actuator has a capacity of 14.6 MPa (45 g). It describes that it expands and contracts by 1% under load. In other words, this actuator can generate a force of 14 MPa in the length direction due to electrolytic expansion and contraction.
  • the conductive polymer has a resistance value.
  • the operating part is enlarged, even if voltage is applied from one end of the operating part and voltage is applied to the entire operating part, a voltage drop occurs at the other end (tip) of the operating part.
  • a voltage is applied from one end of the operating unit, it is difficult to apply a predetermined voltage to the other end (tip) of the operating unit. For this reason, in the enlarged working section, the amount of expansion and contraction near the distal end becomes small, and it becomes difficult to obtain a desired amount of expansion and contraction.
  • the conductive polymer has a resistance value. It takes time to apply voltage to.
  • an actuating element containing a conductive polymer in its operating part is used for applications such as a switch that requires a fast response even with a small expansion / contraction ratio, it is desirable that the response be faster.
  • a method of applying a voltage to one end of a working part using a conductive polymer and applying a voltage that can expand and contract sufficiently near the other end is to apply a voltage to the working part.
  • Using multiple leads connect the leads in parallel so that they are perpendicular to the length of the working part, and apply a voltage to one end of the working part, near the middle of the working part, and near Z or the tip.
  • the leads connected in parallel inhibit the expansion and contraction of the actuator element.
  • Actuator included If the conductive polymer undergoes large expansion and contraction, for example, an expansion and contraction ratio of 10% or more, a large tension is applied to the lead due to expansion and contraction, so that the lead is cut or the connection between the lead and the working part is broken. It becomes easy to generate soil. In addition, even when the operating portion vibrates greatly due to an external impact of the actuator, a large tension is applied to the lead, and the lead is likely to be cut or the connection portion between the lead and the operating portion to be broken.
  • the present invention is an actuating device including an operating unit, a counter electrode, and an electrolyte, wherein a plurality of leads for applying a voltage to the operating unit and the counter electrode via the electrolyte are connected to the operating unit, At least one of the leads is an actuator with a conductive buffer.
  • the actuating unit can be operated without disconnecting a plurality of leads connected to the operating unit. In the evening, it is possible to apply a sufficient voltage to the vicinity of the end of the working part in the evening, so that the conductive polymer can fully exhibit the expansion / contraction performance even at the end of the working part. It is. Further, in the actuating unit, the tension applied to the lead is relieved even if the operating part expands and contracts greatly, so that the lead does not break, and the expansion and contraction of the conductive polymer is not hindered. Can expand and contract.
  • FIG. 1 is a longitudinal sectional view of the first embodiment of the present invention of the first invention.
  • FIG. 2 is a vertical cross-sectional view of the second embodiment of Actuyue Ichiyu, which is the first invention.
  • FIG. 3 is a longitudinal sectional view of one embodiment of Actuyue, which is the second invention.
  • the leads 52 and 53 are connected to conductive buffers 71 and 72, respectively, and are connected to an external power supply 8 via the leads.
  • the counter electrode 3 is also connected to the power supply 8 via a lead.
  • the electrolyte 9 is filled so that a voltage can be applied through the electrolyte 9 when a voltage is applied to the working part 2 and the counter electrode 3.
  • the shape of the actuary of the first invention is not particularly limited as long as it can include an operating portion, a counter electrode, and an electrolyte inside, and it may be cylindrical, rectangular, or polygonal. Shape.
  • the material of the housing of the case is not particularly limited, and may be a hard material such as hard plastic, metal, glass, ceramics, or a flexible material such as urethane rubber or silicon rubber.
  • the side wall surface 43 is preferably flexible.
  • the constituent material is preferably a material having flexibility.
  • the material constituting the wall surface of the housing of the actuator is preferably a hard material.
  • the operating part in the first invention is not particularly limited as long as the operating part contains a conductive polymer and the operating part expands and contracts by electrolytic expansion and contraction of the conductive polymer.
  • a desired shape such as a pillar shape or a prism shape can be obtained.
  • the conductive polymer polypyrrole, polythiophene, polyaniline, polyphenylene and the like can be used.
  • a conductive polymer containing pyrrole and Z or a pyrrole derivative in a molecular chain is produced. This is preferable because it is easy to perform and is not only stable as a conductive polymer, but also has excellent electrolytic expansion and contraction performance.
  • the conductive polymer film obtained by the electrolytic polymerization method or the laminate of the conductive polymer film obtained by the electrolytic polymerization method is used. It is preferably a body.
  • the operating portion may be a conductive polymer film obtained by an electrolytic polymerization method including a conductive metal substrate inside or on the surface, or It is preferred to be a laminate of
  • the operating portion may include a conventional conductive polymer such as a conductive polymer containing sodium P-toluenesulfonate as a dopant.
  • the operating section may be configured such that the conductive polymer contained in the operating section is a conductive polymer formed by an electrolytic polymerization method.
  • the production method it is possible to use an operating part which is a conductive polymer obtained by the production method using the electrolytic solution containing an organic compound as a solvent in the electrolytic polymerization method.
  • the organic compound may be (1) a chemical bond selected from at least one of a chemical bond group consisting of an ether bond, an ester bond, a carbon-halogen bond and a carbonate bond, and / or (2) a hydroxyl group, a nitro group
  • the molecule contains at least one functional group selected from the group consisting of a functional group consisting of a group, a sulfone group and a nitrile group.
  • the electrolyte may contain a known dopant, and a trifluoromethanesulfonic acid ion and / or a fluorine atom bonded to a central atom in order to obtain a larger elongation ratio per one oxidation-reduction cycle.
  • the obtained conductive polymer has an expansion / contraction rate of 16% or more per oxidation-reduction cycle, the above-mentioned trifluoromethanesulfonate ion and the fluorine atom with respect to the central atom or the trifluoromethanesulfonic acid ion are used as the electrolytic solution.
  • the operating part is an operating part containing the conductive polymer manufactured by the manufacturing method, the expansion and contraction rate of the operating part per oxidation-reduction cycle can be easily increased to 3% or more. One night can be used for applications requiring a large expansion and contraction rate such as artificial muscles.
  • organic compound examples include 1,2-dimethoxyethane, 1,2-jetoxetane, tetrahydrofuran, 2-methyltetrahydrofuran, 1,4-dioxane (the above organic compounds containing an ether bond), ⁇ -butyrolactone, acetic acid Ethyl, ⁇ - butyl acetate, -butyl acetate, 1,2-diacetoxetane, 3-methyl-2-oxazolidinone, methyl benzoate, ethyl benzoate, butyl benzoate, getyl phthalate (including ester bond) Organic compounds), propylene glycol, ethylene carbonate, dimethyl carbonate, dimethyl carbonate, methyl ethyl carbonate (more than organic compounds containing carbonate bonds), ethylene glycol, 1-butyl alcohol, Xanol, cyclohexanol, 1-year-old kutano 1, 1-decanol, 1-dodecanol, 1-
  • the organic compound containing a hydroxyl group is not particularly limited, but is preferably a polyhydric alcohol or a monohydric alcohol having 4 or more carbon atoms because of its good elasticity.
  • the organic compound may have any two or more bonds or functional groups selected from ether bonds, ester bonds, carbonate bonds, hydroxyl groups, nitro groups, sulfone groups, and nitrile groups in the molecule.
  • Organic compounds may be included in combination.
  • the organic compound may be a mixture of two or more of the organic compounds.
  • the halogenated hydrocarbon contained as a solvent in the electrolytic solution is one in which at least one hydrogen in the hydrocarbon is replaced by a halogen atom, and is present as a liquid stably under electrolytic polymerization conditions.
  • the halogenated hydrocarbon contained as a solvent in the electrolytic solution is one in which at least one hydrogen in the hydrocarbon is replaced by a halogen atom, and is present as a liquid stably under electrolytic polymerization conditions.
  • halogenated hydrocarbon examples include dichloromethane and dichloroethane.
  • the halogenated hydrocarbon is one kind of Can be used as a solvent in the electrolytic solution, but two or more of them can be used in combination.
  • the halogenated hydrocarbon may be used as a mixture with the above organic compound, and a mixed solvent with the organic solvent may be used as a solvent in the electrolytic solution.
  • the electrolytic solution used in the electrolytic polymerization method contains an organic compound to be electrolytically polymerized (for example, pyrrole) and a trifluoromethanesulfonic acid ion and / or an anion containing a plurality of fluorine atoms with respect to a central atom.
  • an organic compound to be electrolytically polymerized for example, pyrrole
  • a trifluoromethanesulfonic acid ion and / or an anion containing a plurality of fluorine atoms with respect to a central atom By performing electrolytic polymerization using this electrolytic solution, it is possible to obtain a conductive polymer having an excellent expansion / contraction rate per one oxidation-reduction cycle and / or displacement rate per specific time in electrolytic expansion / contraction.
  • trifluoromethanesulfonic acid ions and / or anions containing a plurality of fluorine atoms with respect to the central atom are incorporated into the conductive polymer
  • the content of the anion containing a plurality of fluorine atoms with respect to the trifluoromethanesulfonic acid ion and / or the central atom is not particularly limited in the electrolytic solution, but is 0.1 to 30% by weight in the electrolytic solution. %, More preferably 1 to 15% by weight.
  • Trifluoromethanesulfonate ion is a compound represented by the chemical formula CF 3 S ⁇ 3 —.
  • An anion containing a plurality of fluorine atoms with respect to the central atom has a structure in which a plurality of fluorine atoms are bonded to a central atom such as boron, phosphorus, antimony, and arsenic.
  • the Anion containing a plurality of fluorine atoms with respect to the central atom are not particularly limited, Tetorafu Ruorohou acid ion (BF 4 -), the Kisafuruororin acid ion (PF 6 I), the hexa full O b antimonate can be exemplified ions (_ S b F 6), and to Kisafuruoro arsenate ion (a s F 6 _).
  • CF 3 S 0 3 -, BF 4 and PF 6 - When considering the safety to human body rather preferable, CF 3 S_ ⁇ 3 and BF 4 - is preferable.
  • anion containing a plurality of fluorine atoms with respect to the central atom one kind of anion may be used, a plurality of kinds of anions may be used at the same time, and further, trifluoromethanesulfonic acid ion and a plurality of kinds of central atoms may be used. In contrast, contains multiple fluorine atoms An anion may be used at the same time.
  • the electrolytic solution used in the electrolytic polymerization method includes a solution of the organic compound solvent and the trifluoromethanesulfonate ion and anion containing a plurality of fluorine atoms with respect to Z or a central atom. And further known additives such as polyethylene glycol and polyacrylamide.
  • the electrolytic polymerization method a known electrolytic polymerization method can be used as the electrolytic polymerization of the conductive polymer monomer, and any of the constant potential method, the constant current method, and the electric sweep method can be used.
  • the electrolytic polymerization the current density 0 0 l ⁇ 2 0 m A / c m2, the reaction temperature - 7 0 ⁇ 8 0 ° C, preferably current density 0:..! ⁇ 2 m A / cm 2, the reaction The reaction is preferably performed at a temperature of ⁇ 40 to 40, and more preferably at a reaction temperature of ⁇ 20 to 3O :.
  • the operating portion includes a conductive material such as a metal wire and a conductive oxide in order to lower the resistance value as the working electrode in addition to including the conductive polymer and the dopant.
  • a conductive material such as a metal wire and a conductive oxide in order to lower the resistance value as the working electrode in addition to including the conductive polymer and the dopant.
  • the shape of the counter electrode in the first embodiment of the invention is not particularly limited as long as the counter electrode is formed of a conductive material that can be used as an electrode, and may be a rod, a line, a film, or a plate. It may be in a shape.
  • the material of the counter electrode is not particularly limited, and may be a metal containing a noble metal such as gold or platinum as a type, or may be a conductive non-metal such as a conductive resin or ITO glass. .
  • the material of the counter electrode is preferably a noble metal because it is hardly corroded and easy to process, and more preferably platinum or gold.
  • the counter electrode according to the present invention has a gap between the counter electrode and the working part such that when a voltage is applied to the counter electrode and the working part, a current flows between the counter electrode and the working part through the electrolyte and a short circuit does not occur. Is preferred. This is because having the above-mentioned interval does not require a separator such as a nonwoven fabric, and the configuration of the actuator is simple.
  • the buffer of the first invention is connected to the operating part. It is provided on the lead and has conductivity.
  • the cushioning member can reduce the tension applied to the lead due to the expansion and contraction of the operating portion and the tension applied to the lead due to the vibration of the operating portion due to an external impact.
  • the structure is not particularly limited.
  • a metal mesh, conductive fiber, conductive rubber, metal panel, or carbon spring can be used as the buffer.
  • the buffer can be used in a shape suitable for the structure of the factory, such as a band, a line, and a plate.
  • the number of the buffers may be at least one attached to the lead connected to the operating part, and may be attached to each of a plurality of leads connected to the operating part.
  • the operating part When the operating part is fixed to the housing or the like at one end, it is required that the operating part is attached to all the leads except for the lead connected to the fixed part of the operating part. It is preferable because expansion and contraction are not hindered and large expansion and contraction can be obtained with a small number of buffers.
  • the buffer is preferably an elastic body because of its simple structure and easy connection with a lead.
  • the elastic body is preferably a metal spring because it can be kept elastic without being affected by swelling due to organic components contained in the electrolyte when it comes into contact with the electrolyte.
  • the buffer is preferably a coil-shaped metal panel because it can easily follow bending and expansion and contraction from all directions.
  • Metals such as Ag, Ni, Ti, Au, Pt, Ta, and W, alloys thereof, and alloys such as SUS can be used as the material of the coil-type metal panel. Among them, the material is preferably Pt or Au because of its good corrosion resistance.
  • the buffer may be a buffer that does not inhibit the expansion and contraction of the conductive polymer.
  • the lead is connected to the operating portion at the connecting portion, but the buffer may be connected to the connecting portion without the intermediary of the lead. It is preferable that the buffer is connected to the connecting portion via a lead, because the buffer does not contact the operating portion and does not damage the operating portion. Said The connection between the shock absorber and the lead can maintain conduction between the lead and the shock absorber. The tension between the lead and the shock absorber due to the expansion and contraction of the operating portion, and the tension between the lead and the shock absorber due to external vibration. As long as the lead and the buffer do not separate from each other, there is no particular limitation. As a material for a connection portion between the buffer and the lead, a solder stop or a conductive adhesive can be used as a material. Further, the connection portion may be formed by a method of forming a composite during polymerization.
  • a voltage is applied from a power supply via a connection portion formed in the operation portion.
  • three connecting portions 51, 52, and 53 are formed, and a voltage is applied to the operating portion from three places.
  • the connection portion is formed with a connection portion 61 so as to cover one end surface of the connection portion 2, and connection portions 62 and 63 are formed partially on the side surfaces of the operation portion 2, respectively.
  • the connecting portion of the first invention is not particularly limited as long as the lead or the buffer is fixed on the operating portion so that a voltage can be applied from the lead to the operating portion.
  • the shape of the connection portion is not limited as long as a voltage is applied to the operation portion and the operation portion expands and contracts electrolytically.
  • connection portion When the connecting portion is formed at one end of the operating portion, it may be formed so as to cover one surface of one end or may be formed partially. Further, when the operating portion is formed on the side surface of the operating portion, it may be formed on a part of the side surface, or may be formed so as to go around the outer periphery of the side surface.
  • the connection portion may use a conductive adhesive, a conductive tape, a metal clip, or a metal plate. In addition, the connection portion may form a composite of a conductive polymer and a lead or a buffer during polymerization.
  • the number of the connection parts is not particularly limited as long as it is plural, and may be appropriately arranged at an appropriate place according to the type of the conductive polymer contained in the operation part and the length of the operation part.
  • the distance between adjacent connecting portions is preferably 5 cm or less in the length direction, so that a large stretch can be obtained as a whole. This is preferable because it is easy.
  • the lead 54 is an electric path for applying a voltage from a power supply to each connection portion via a conductive buffer and a lead. It is preferable that the electric path is fixed or held on the inner surface of the housing so that the lead does not vibrate and be cut by an impact on the actuator.
  • the electrolyte contained in the factories of the first invention is not particularly limited, and may be a liquid or a solid electrolyte.
  • the electrolyte When the electrolyte is in a liquid state, it may be an aqueous solvent or an organic solvent, but is easy to handle due to its low toxicity and a relatively slow volatilization rate, and it has a large expansion and contraction.
  • the solvent is an aqueous solvent.
  • the electrolyte is a solid electrolyte, it may be a gel polymer electrolyte or a completely solid polymer electrolyte, but a gel polymer electrolyte is preferred because of its high ionic conductivity in the electrolyte.
  • the electrolyte may be an electrolyte containing at least one compound selected from the group consisting of trifluoromethanesulfonate ion, anion containing a plurality of fluorine atoms with respect to a central atom, and a sulfonate having 3 or less carbon atoms.
  • the actuate can cause a larger expansion and contraction per one oxidation-reduction cycle.
  • the electrolyte is
  • Actuating part is chemical formula as single punt
  • n and m are arbitrary integers.
  • the actuate is electrolytically stretched.
  • the working part of the actuator is a perfluoroalkyl having a larger ionic radius than the conventional dopant. The doping and dedoping of rusulfonylimide results in a better stretch ratio per oxidation-reduction cycle and a better per-specified time compared to the use of electrolytes containing trifluoromethanesulfonic acid ions. The displacement rate can be shown.
  • a shaft is provided at an end (tip) of the operating portion 2 opposite to the connecting portion 61.
  • the operating portion expands and contracts electrolytically, and the shaft also moves up and down.
  • the force generated by the expansion and contraction of the operating portion 2 can be transmitted to the outside of the actuator.
  • the electrolyte is an electrolytic solution, it is preferable to cap the tip of the actuator.
  • the means for transmitting the force generated by the expansion and contraction of the operating portion 2 to the outside of the operating portion is not limited to the method of forming the shaft in the operating portion.
  • the housing may be formed of a flexible material, and the entire actuator may expand and contract.
  • the flexible material forming the housing is not particularly limited, and can be appropriately selected according to the elongation rate of the actiyue. It is preferable to use a synthetic resin of 5% or more, and it is more preferable to use a synthetic resin having an elongation of 20% or more.
  • the flexible material for example, silicon-based resin, urethane-based resin, silicon-based rubber, urethane-based rubber, or the like can be used. Further, since the flexible material also has a function of preventing the electrolyte from leaking to the outside of the actuator, it is preferable that the flexible material has solvent resistance. Silicon-based resin, urethane-based resin, silicone A system rubber or a urethane rubber can be suitably used.
  • a means for transmitting a force such as a rod-like body penetrates the housing and is used for a longer time than the structure.
  • FIG. 2 is a longitudinal sectional view of a second embodiment of the actuator of the first invention.
  • a column-shaped actuator 11 includes a film-shaped operating portion 12 and a plate-shaped counter electrode 13 inside a housing 14.
  • Leads 151, 152, 153, 154, 155 are connected to working part 12 via connections 161, 162, 163 on the working part surface, respectively.
  • the leads 15 2 and 15 3 are conductive buffers 17 1 and the leads 15 4 and
  • Electric power is supplied to 16 2 and 16 3 in series from an external power supply 18 via a lead and a buffer.
  • the counter electrode 13 is also connected to the power supply 18 via a lead.
  • the electrolyte 19 is filled so that a voltage can be applied through the electrolyte 19 when a voltage is applied to the operating part 12 and the counter electrode 13.
  • the electric path is a path including the lead 51
  • the second electric path for applying a voltage to the connection section 62 is a path including the lead 52 and the buffer 71
  • the connection section 6 3 A third electric path for applying a voltage to the coil is a path including the lead 53 and the buffer 72.
  • FIG. 1 which is the first embodiment of the first invention of the present application
  • a first electric path, a second electric path, and a third electric path are arranged in parallel.
  • FIG. 2 which is the second embodiment of the first invention
  • an electric path for applying a voltage to One electric path, a second electric path, and a third electric path are connected in series. That is, in the first invention of the present application, the connection form of the electric path for applying the voltage to the operating section may be such that a plurality of electric paths connected to the operating section may be connected in parallel, or may be connected in series. Is also good.
  • the connection format a suitable format can be selected according to the purpose.
  • a plurality of electric paths connected to the operating unit be connected in series. If there is a risk of disconnection at the connection part due to large expansion or contraction of the operation part, it is preferable that a plurality of electric paths connected to the operation part be connected in parallel.
  • a shaft is provided at the end (tip portion) on the opposite side of the connection portion 15 of the operation portion 12, and the operation is performed by the up and down movement of the shaft.
  • the power generated by the expansion and contraction of part 2 can be transmitted to outside the factory.
  • the electrolyte is an electrolytic solution, it is preferable to cap the tip of the actuator.
  • FIG. 3 is a vertical cross-sectional view of an example of an embodiment of the invention of the second invention.
  • a cylindrical actuator 21 includes a film-shaped operating part 22 and a plate-shaped counter electrode 23 inside a housing 24.
  • a lead 25 1 is connected at a connecting part 26 1 on the surface of the working part, and a lead 25 2 is connected to the adjacent connecting part 26 1 and the connecting part 26 2.
  • the node 253 is connected to the adjacent connection part 262 and connection part 263.
  • the leads 251, 252, 253 are connected in series and Connected to source 28.
  • the counter electrode 23 is also connected to the power supply 28 via a lead.
  • the electrolyte 29 is filled so that a voltage can be applied through the electrolyte 29 when a voltage is applied to the operating part 22 and the counter electrode 23.
  • a plurality of leads are connected to the operating section, and the leads are connected in series to the operating section.
  • the leads 54 are attached to the inner surface of the housing to prevent the leads from being cut.
  • leads 25 2 and 2 53 does not need to be fixed or held on the inner surface of the housing, and the structure is simple.
  • the length of a lead serving as an electric path between adjacent connecting portions is applied so that the lead is not cut when the operating portion is extended to the maximum. It is preferable that the distance between the connecting parts is equal to or longer than the distance between the connecting parts when the operating part is fully extended.
  • the shape of the actuator of the second invention is not particularly limited as long as the actuator can include the operating portion, the counter electrode, and the electrolyte inside similarly to the first invention described above.
  • the material of the housing of the actuator is not particularly limited, and a hard material such as a hard plastic, metal, glass, or ceramic is used. Alternatively, a flexible material such as urethane rubber or silicon rubber may be used. It is preferable that the material forming the wall surface of the housing of the actuator is a flexible material. Further, in applications where impact resistance is required for the actuator, it is preferable that the material constituting the wall surface of the housing of the actuator is a hard material.
  • the actuator according to the second aspect of the present invention is the same as the first aspect described above, wherein the operating part includes a conductive polymer, and the operating part expands and contracts due to electrolytic expansion and contraction of the conductive polymer.
  • conductive polymer polypyrrol, polythiophene, polyaniline, polyphenylene, and the like can be used, and a conductive polymer containing a pyrrole and / or a pyrrole derivative in a molecular chain is preferable. .
  • the organic compound may include (1) a chemical bond selected from at least one of a chemical bond group consisting of a ether bond, an ester bond, a carbon-18 bond, and a carbonate bond, and / or (2) a hydroxyl group.
  • the molecule contains at least one functional group selected from the group consisting of a nitro group, a sulfone group and a nitrile group.
  • the electrolytic solution contains, as a solvent, an organic compound containing in the molecule one or more selected from the group consisting of the chemical bond species and Z or a functional group, and a trifluoromethanesulfonate ion and a fluorine atom with respect to the central atom.
  • a conductive polymer produced by a method for producing a conductive polymer using an electrolytic solution containing anion containing a plurality of dioxins for the working part can provide a large expansion and contraction rate in one oxidation-reduction cycle. preferable. Further, the obtained conductive polymer
  • Perfluoroalkylsulfonylimid ion represented by Is preferably used.
  • the operating portion includes a conductive polymer and a dopant, and also includes a metal wire, a conductive oxide, or the like in order to reduce a resistance value as an operating electrode.
  • a conductive material can be included as appropriate.
  • the operating portion has a high physical strength of the conductive polymer film, the conductive polymer film obtained by the electrolytic polymerization method or the conductive polymer film obtained by the electrolytic polymerization method is laminated. It is preferably a body. Further, it is preferable that the operating section is a conductive polymer film obtained by an electrolytic polymerization method including a conductive metal substrate inside or on a surface thereof, or a laminate thereof.
  • the counter electrode of the second embodiment of the present invention is not particularly limited in shape as long as it is formed of a conductive material that can be used as an electrode, as in the first invention.
  • the material is not particularly limited, and is preferably a noble metal, and more preferably platinum or gold, because it is hardly corroded and easy to process.
  • connection portion is formed with a connection portion 261 so as to cover one end surface of the connection portion 2, and the connection portions 262 and 263 are formed on a part of a side surface of the operation portion 22. Each is formed.
  • the shape of the connection portion is not limited as long as the voltage is applied to the operation portion and the operation portion expands and contracts electrolytically.
  • the connecting portion when the connecting portion is formed at one end of the operating portion, the connecting portion may be formed so as to cover one surface of the one end or may be formed partially.
  • the operating portion may be formed on a part of the side surface, or may be formed so as to go around the outer periphery of the side surface.
  • connection portion As in the first invention, a conductive adhesive, a conductive tape, a metal clip, a metal plate, or a method of compounding at the time of polymerization can be used for the connection portion.
  • the number of the connection parts is not particularly limited as long as it is plural, and may be appropriately arranged at an appropriate place according to the type of the conductive polymer contained in the operation part and the length of the operation part. it can.
  • the operating part is made of a conductive polymer. When polypyrrole is contained, the distance between adjacent connecting portions is preferably 5 cm or less in the longitudinal direction, because it is easy to obtain large extensibility as a whole.
  • the polymer electrolyte it is preferable to use polyacrylamide, polyethylene glycol, agar, or the like as the gel used in the above, because the gel polymer electrolyte can be easily prepared by compounding with the aqueous solution electrolyte.
  • the electrolyte may be trifluoromethanesulfonic acid ion, an electrolyte containing at least one compound selected from the group consisting of an anion containing a plurality of fluorine atoms with respect to a central atom and a sulfonate having 3 or less carbon atoms, It is preferable that the actuate is capable of producing a larger expansion and contraction per oxidation-reduction cycle.
  • a shaft is provided at the end (tip) of the operating portion 22 opposite to the connecting portion 25 1.
  • the operating part expands and contracts electrolytically, and the shaft also moves up and down. Due to the movement of the shaft, the power generated by the expansion and contraction of the operating part 22 can be transmitted to the outside of the factory.
  • the electrolyte is an electrolyte, it is preferable to cap the tip of the actuator.
  • the casing of the first actuator may be formed of a flexible material, and the entire first actuator may extend and contract.
  • the flexible material forming the housing is not particularly limited, and can be appropriately selected according to the elongation rate of the actuary. 5% rate It is preferable to use the above synthetic resin, and it is more preferable to use a synthetic resin having an elongation of 20% or more.
  • the flexible material for example, silicon-based resin, urethane-based resin, silicon-based rubber, urethane-based rubber, or the like can be used.
  • the flexible material also has a function of preventing the electrolyte from leaking to the outside, it is preferable that the flexible material has solvent resistance.
  • Silicon-based resin, urethane-based resin, silicon-based resin Rubber or urethane rubber can be suitably used.
  • Actu Yue when the operating part has a structure that is sealed by a housing, a means for transmitting a force such as a rod-like body penetrates the housing, compared to the structure. Since there is no electrolyte leakage due to long-term use, it is excellent for use as mechanical parts such as artificial muscles.
  • the lead which is an electric path between the adjacent connecting portions, is in a slack state when the operating portion is contracted, and when the slack portion is too long.
  • a short circuit is likely to occur due to contact with the counter electrode, and the leads are likely to be entangled.
  • the actuator of the second invention of the present application it is possible to use the actuator of the second invention of the present application, but using the actuator of the first invention makes contact with the counter electrode. This is preferable because a short circuit is less likely to occur and the leads are less likely to be entangled.
  • the actuators since it is easy to obtain a larger expansion ratio, the actuators can be used even if the displacement is small.
  • the actuary of the present invention can expand the use of an actuate containing a conductive polymer, which could only be used for applications with small displacements, to applications with large displacements such as artificial muscles.
  • a lead having a buffer function may be used.
  • the above-mentioned actuary can be used as a linear actuator, for example, as shown in FIG. 1 to FIG..
  • the shaft expands and contracts by 3% or more, and the expansion and contraction of 3% or more as an actuary can be obtained. It can be suitably used for applications where the displacement of artificial muscles or the like is large.
  • the actuator of the present invention is an actuator in which a conductive polymer is driven by electricity, and is silent as it is driven. Therefore, the actuator is suitable as a driving unit or a pressing unit in an indoor use device.
  • the actuator is lighter than the conventional linear actuator because it has fewer metal parts. Therefore, the positioning device, the attitude control device, the elevating device, the transport device, the moving device, the adjusting device, the adjusting device, and the guiding device are provided. It can be suitably used as a drive unit of a device and a joint device.
  • the expansion and contraction rate of the operating portion can obtain a large expansion and contraction as an actuator. It is preferably at least 3%, more preferably at least 5% per oxidation-reduction cycle.
  • the first invention and the second invention of the second invention of the present application can be suitably used for artificial muscles, robot arms and artificial hands.
  • medical equipment such as tweezers, scissors, forceps, snares, laser scalpels, spatulas, clips, and other sensors for microsurgery technology, various sensors for inspection and repair, or repair tools, health equipment, hygrometers, hygrometer control equipment
  • Equipment used in the water such as equipment, soft manipures, underwater valves, soft transport equipment, and other industrial equipment; underwater vehicles such as goldfish; or hobby equipment such as moving fishing baits and propulsion fins.
  • the actuary of the present invention can be suitably used.
  • OA equipment, antennas, equipment for placing people such as beds and chairs, medical equipment, engines, optical equipment, fixtures, side trimmers, vehicles, lifting equipment, food processing equipment, cleaning equipment , Measurement equipment, inspection equipment, control equipment, machine tools, processing machines, electronic equipment, electron microscopes, electric razors, electric toothbrushes, manipulators, masts, play equipment, amusement equipment, riding simulation equipment, vehicle occupant restraint Equipment and equipment extension equipment for aircraft.
  • the actuator is used in a valve, a brake, and a lock device used in a general machine including the above-mentioned devices such as an OA device and a measuring device, and a truck including a drive portion or an arc portion that generates a linear drive force. It can be used as a driving unit that generates a driving force for moving the mold orbit, or as a pressing unit that performs a linear operation.
  • a driving unit of a positioning device in general, in machinery and equipment, a driving unit of a positioning device, a driving unit of an attitude control device, a driving unit of a lifting device, a driving unit of a transport device, and a driving device of a moving device.
  • the actuator is, for example, a drive unit for an ink jet part in an inkjet printer such as a CAD printer, a drive unit for displacing the optical axis of the light beam of the printer, and a head of a disk drive device such as an external storage device. It can be suitably used as a driving unit and a driving unit of a paper pressing contact force adjusting unit in a paper feeding device of an image forming apparatus including a printer, a copying machine, and a facsimile.
  • the above-mentioned actuyue is a frequency sharing antenna for radio astronomy, etc.
  • the measurement unit such as moving the high-frequency power supply unit to the second focal point, the drive unit of the drive mechanism that moves and installs the power supply unit, and the lift in the mast antenna, such as a vehicle-mounted pneumatic telescopic mast (telescopic mast) It can be suitably used for a drive unit of a mechanism.
  • the actuator may be a driving unit of a massage unit of a chair-shaped massage machine, a driving unit of a nursing or medical bed, a driving unit of a posture control device of an electric reclining chair, a massage machine, a comfortable chair, or the like.
  • the present invention can be suitably used as a driving unit used for turning a chair backrest, a dressing rest or a bed for a nursing care bed, and a driving unit for controlling the posture of a standing chair.
  • the actuator may be a driving unit of an inspection device, a driving unit of a pressure measuring device such as a blood pressure used in an extracorporeal blood treatment device, a driving unit of a catheter, an endoscope device, a forceps, or the like.
  • a driving unit of a movement device such as a jaw movement device
  • a drive unit of means for relatively expanding and contracting members of a chassis of a hoist for the disabled and raising and lowering and moving a nursing bed It can be suitably used for a driving unit for controlling the posture and the like.
  • the actuator is, for example, a drive unit of a vibration isolator that attenuates vibration transmitted from a vibration generating unit such as an engine to a vibration receiving unit such as a frame, and a valve operating device for an intake and exhaust valve of an internal combustion engine. It can be suitably used as a drive unit, a drive unit of a fuel control device of an engine, and a drive unit of a fuel supply device of an engine such as a diesel engine.
  • the actuator is a driving unit of a calibration device of an imaging device having a camera shake correction function, a driving unit of a lens driving mechanism such as a home video camera lens, and a moving lens group of an optical device such as a still camera or a video camera.
  • the present invention can be suitably used for a drive unit of an optical axis aligning device and a drive unit of a camera shutter mechanism.
  • the above-mentioned actuary can be suitably used, for example, for a pressing portion of a fixing tool such as for fixing a hose fitting to a hose body by force.
  • the actuator may be a drive unit such as a winding spring of a vehicle suspension, a drive unit of a fuel filler opener for unlocking a fuel filler lid of a vehicle, and a drive unit for extending and retracting a bulldozer blade.
  • the present invention can be suitably used for a drive unit of a drive unit for automatically changing the gear ratio of a transmission for an automobile or for automatically connecting and disconnecting a clutch.
  • the actuator may be, for example, a driving unit of a lifting device of a wheelchair with a seat plate lifting device, a driving unit of a lifting device for eliminating a step, a driving unit of a lifting and lowering device, a medical bed, an electric bed, an electric table, and an electric motor.
  • a driving unit of a lifting and lowering device for eliminating a step
  • a driving unit of a lifting and lowering device for eliminating a step
  • a driving unit of a lifting and lowering device a medical bed, an electric bed, an electric table, and an electric motor.
  • Chairs, nursing beds, lifting tables, CT scanners, truck cabin tilting devices, lifting drives for lifters, etc., and various lifting machinery, as well as loading and unloading devices for heavy vehicles It can be suitably used.
  • the above-mentioned actuary can be suitably used, for example, as a driving unit of a discharge amount adjusting mechanism such as a food discharge nozzle device of a food processing device.
  • the actuator can be suitably used, for example, in a drive unit for lifting and lowering a truck or a cleaning unit of a cleaning device.
  • the actuator is a driving unit of a measuring unit of a three-dimensional measuring device that measures the shape of a surface, a driving unit of a stage device, a driving unit of a part of a sensor such as a system for detecting a tire operating characteristic, and a force sensor.
  • Drive unit of the device that gives the initial speed of the shock response evaluation device drive unit of the piston drive device of the piston cylinder of the device including the borehole permeability test device, drive unit for moving in the elevation direction of the concentrating and tracking power generator, gas Of measurement equipment including concentration measurement equipment
  • E-beam electron beam
  • FIB forced ion beam
  • the actuator can be suitably used, for example, as a driving unit for an electric razor and a driving unit for an electric toothbrush.
  • the actuator is, for example, a drive unit of an imaging device for a three-dimensional object or a device for adjusting the depth of focus of a readout optical system shared by a CD and a DVD, and the shape of a drive target surface is changed to an active curved surface by a plurality of actuators.
  • This makes it possible to linearly move a movable unit having at least one of a drive unit of a variable mirror and a magnetic head such as an optical pickup which can approximately change a focal position by forming a desired curved surface approximately.
  • Drive unit drive unit for mounting members such as magnetic head members, and light that drives and controls the focusing lens group in the optical axis direction.
  • Driving unit for disc master exposure device, driving unit for head driving means for driving optical head, driving unit for information recording / reproducing device for recording information on recording medium or reproducing information recorded on recording medium can be suitably used for a drive unit for opening and closing a circuit breaker or a circuit breaker (a power distribution circuit breaker or a circuit breaker).
  • the actuator can be suitably used, for example, as a drive unit of the following apparatus: a drive section of a rubber composition press-molding vulcanization apparatus; Parts alignment equipment to align to the posture Drive of compression molding equipment, drive of holding mechanism of welding equipment, drive of bag filling and packaging machine, machine tool such as machining center, molding machine such as injection molding machine and press machine, etc.
  • Driving unit printing unit, driving unit of fluid application device such as coating device and lacquer spraying device, driving unit of manufacturing device for manufacturing camshaft, etc., driving unit of lifting device for covering material, tuft in shuttleless loom Driving device such as ear control body, needle driving system of tufting machine, looper driving system, driving unit such as knife driving system, driving of polishing device for polishing parts such as cam grinder and ultra-precision processing parts Drive unit of the overall frame braking device in the loom, drive unit of the shedding device for forming the warp opening for weft insertion in the loom, drive unit of the protective sheet peeling device for semiconductor substrates, etc.
  • the actuator can be suitably used, for example, as a drive unit for a probe positioning device of a scanning probe microscope such as an electron microscope, and a drive unit for positioning a fine movement device for a sample for an electron microscope.
  • the actuator is used for a drive unit of a joint mechanism represented by a wrist of a robot arm in a robot or manipulator including an automatic welding pot, an industrial mouth pot, a nursing robot, and a joint other than a direct drive type.
  • Driving unit of micromanipulator for operating in arbitrary state, driving unit of prosthesis such as electric prosthesis having multiple openable fingers, driving unit of handling robot, driving unit of prosthesis, and driving of power suit It can be suitably used for parts.
  • the actuator can be suitably used, for example, as a pressing portion of a device for pressing an upper rotary blade or a lower rotary blade of a side trimmer.
  • the above-mentioned actuyue is suitably used, for example, as a drive unit for a character or the like in a game machine such as a pachinko machine, a drive unit for an amusement device such as a doll or a pet mouth pot, and a drive unit for a simulation device of a boarding simulation device. be able to.
  • the actuator can be used, for example, in a drive unit of a valve used in a general machine including the above-described equipment and the like.
  • Drive for bellows-type pressure-sensitive control valve, drive for opening device that drives the pig iron frame, drive for vacuum gate valve, and solenoid-operated control valve for hydraulic system Suitable for drive unit, valve drive unit incorporating a motion transmission device using a pivot lever, rocket movable nozzle valve drive unit, suck back valve drive unit, and pressure control valve drive unit Can be.
  • the actuator can be used, for example, as a pressing portion of a brake used in a general machine including the above-described devices, and is preferably used for, for example, an emergency, security, parking brake, etc., or an elevator brake. It can be suitably used for a pressing portion of a simple braking device, and a pressing portion of a brake structure or a brake system.
  • the actuator can be used, for example, as a pressing portion of a lock device used in a general machine including the above-described devices and the like, for example, a pressing portion of a mechanical locking device, a pressing portion of a steering lock device for a vehicle, Further, it can be suitably used for a pressing portion of a power transmission device having both a load limiting mechanism and a coupling release mechanism.
  • an actuating unit including an operating unit, a counter electrode, and an electrolyte, wherein a lead for applying a voltage to the operating unit and the counter electrode through the electrolyte is provided.
  • a plurality of the actuators are connected to each other, and at least one of the leads is an actuator having a conductive buffer.
  • the tip of the actuator can be used. Since the voltage can be sufficiently applied, the expansion and contraction is not hindered by the lead, and the expansion and contraction of the operating portion does not occur, so that a large expansion and contraction can be obtained as an actuator.
  • An actuating device is an actuating device including an operating portion, a counter electrode, and an electrolyte, and a lead for applying a voltage to the operating portion and the counter electrode via the electrolyte.
  • actuating units connected to the operating unit in a plurality, and the leads are connected in series to the operating unit. Even with the use of this actuator, it is possible to apply a sufficient voltage to the vicinity of the end of the working part. It can be used to its full potential, and can be used to get a quick stretch. Furthermore, even if the operating portion expands and contracts significantly, the tension applied to the lead is reduced, so that not only does the expansion and contraction be prevented, but also the lead does not break.
  • the actuator is an actuator in which the conductive polymer is driven by electricity, there is no sound at the time of driving. Therefore, the actuator is suitable as a driving unit or a pressing unit in an indoor use device.
  • the actuator is lighter than the conventional linear actuator because it has fewer metal parts, so the positioning device, the posture control device, the elevating device, the transport device, the moving device, the adjusting device, and the adjusting device are used. It can be suitably used as a driving unit of a guiding device and a joint device.

Abstract

An actuator comprising a working section, a counter electrode, and an electrolyte, wherein the working section is connected with a plurality of leads for applying a voltage to the working section and the counter electrode through the electrolyte and at least one lead out of the leads has a conductive shock absorber. Voltage drop can be prevented in an actuator employing a working section containing a conductive polymer such that expansion/contraction of conductive polymer is not retarded but exhibited sufficiently while preventing the plurality of leads connected with the working section from being disconnected by an external force or expansion/contraction of the working section.

Description

ァクチユエータ Actuator
背景技術 Background art
 Light
本発明は、 作動部に導電性高分子を含むァクチユエータに関する。  The present invention relates to an actuator that includes a conductive polymer in an operation part.
 Fine
ポリ ピロールなどの導電性高分子は、 電気化学的な酸化還元によって 伸縮あるいは変形する現象である電解伸縮を発現することが知られて いる。 この導電性高分子の電解伸縮は、 人工筋肉、 ロボッ トアーム、 義 手ゃァクチユエータ等の用途と して応用が期待され、 近年注目されてい る。  It is known that conductive polymers such as polypyrrole exhibit electrolytic stretching, which is a phenomenon of stretching or deforming due to electrochemical oxidation and reduction. Electrolytic expansion and contraction of this conductive polymer is expected to be used as artificial muscles, robot arms, artificial arm actuators, and the like, and has attracted attention in recent years.
導電性高分子を用いたァクチユエータについて、 セル内に電解液、 対 極及びポリ ピロールフィルムを備えたァクチユエータの構成が 1 9 9 7年に報告されている。 A. D e l i a S a n t a e t a l .、" P e r f o r m a n c e a n d w o r k c a p a c i t y o f a p o l y p y r r o l e c o n d u c t i n g o l y m e r 1 i n e a r a c t u a t o r 、 S y n t h e t i c M e t a l s、 E l s c v i e r S c i e n c e、 1 9 9 7年、 第 9 0卷、 P 9 3— 1 0 0を参照のこと。  As for an actuator using a conductive polymer, a configuration of an actuator having an electrolyte, a counter electrode, and a polypyrrole film in a cell was reported in 1999. A. Deli a S a n t a e t a l., "P e r f o r m a n c e a d d w o r k c a p a c i t y o f a p o l y p y r r o l e c o n d u c t i n g o l y m e r 1 i n e a r a c t u a t e n e e, e, n, e, n, e, n, e, n
このァクチユエータは、 ポリ ピロールフィルム及び対極が電解液に浸 漬された状態で、 対極とポリ ピロールフィルムとに電圧を印加した場合 に、 ポリ ピロールフィルムが 1 4. 6 MP a (4 5 g ) の負荷を受けな がら 1 %の伸縮をすることが記載されている。 つまり、 このァクチユエ ータは、 電解伸縮により、 長さ方向に 1 4 MP aの力を発生させること ができる。  When the polypyrrole film and the counter electrode are immersed in the electrolyte and a voltage is applied to the counter electrode and the polypyrrole film, the actuator has a capacity of 14.6 MPa (45 g). It describes that it expands and contracts by 1% under load. In other words, this actuator can generate a force of 14 MPa in the length direction due to electrolytic expansion and contraction.
上記のァクチユエータにおいては、 例えば、 伸縮率が 1 %のポリ ピロ ールフィルムを用いて 2 c mの伸縮量を得るためには、 ァクチユエータ の作動部であるポリピロ一ルフィルムを長さ方向に 2 0 0 c mと、 大型 化する必要がある。 つまり、 ポリピロールフィルムを用いたァクチユエ 一夕素子は、 大きな伸縮量を得るためには、 ァクチユエ一夕素子のサイ ズそのものを大きくする必要がある。 In the above actuator, for example, in order to obtain an expansion amount of 2 cm using a 1% stretch ratio of a polypropylene film, it is necessary to use an actuator. It is necessary to increase the size of the polypyrrole film, which is the working part, to 200 cm in the length direction. In other words, in order to obtain a large amount of expansion and contraction, the size of the actuating element using the polypyrrole film must be increased.
しかし、 ポリピロールフィルムのように、 電気化学的に伸縮する材料 である導電性高分子を用いた作動部は、 導電性高分子が抵抗値を有して いる。作動部を大型化した場合には、作動部の一端から電圧を印加して、 作動部全体への電圧印可を試みても、 作動部の他端 (先端) では電圧降 下が生じてしまう。作動部の一端から電圧の印加では、作動部の他端(先 端) に所定の電圧を与えることが難しい。 そのために、 大型化した作動 部では、 先端付近での伸縮量が小さくなり、 所望の伸縮量を得ることが 難しくなる。  However, in an operating section using a conductive polymer, which is a material that expands and contracts electrochemically, such as a polypyrrole film, the conductive polymer has a resistance value. When the operating part is enlarged, even if voltage is applied from one end of the operating part and voltage is applied to the entire operating part, a voltage drop occurs at the other end (tip) of the operating part. When a voltage is applied from one end of the operating unit, it is difficult to apply a predetermined voltage to the other end (tip) of the operating unit. For this reason, in the enlarged working section, the amount of expansion and contraction near the distal end becomes small, and it becomes difficult to obtain a desired amount of expansion and contraction.
また、 ァクチユエ一タ素子のサイズが小さい場合であっても、 導電性 高分子が抵抗値を有しているために、 作動部の一端から電圧を印加した 場合には作動部の他端 (先端) に電圧を与えるには時間がかかる。 導電 性高分子を作動部に含むァクチユエ一夕素子を、 スィッチなどの、 伸縮 率が小さくても速い応答性が要求される用途に用いる場合には、 より応 答性が速いことが望ましい。  Even when the size of the actuator element is small, when the voltage is applied from one end of the operating section, the conductive polymer has a resistance value. It takes time to apply voltage to. In the case where an actuating element containing a conductive polymer in its operating part is used for applications such as a switch that requires a fast response even with a small expansion / contraction ratio, it is desirable that the response be faster.
導電性高分子を用いた作動部の一端に電圧が印加され、 他の端部付近 においても十分な伸縮をすることができる電圧が印加される方法とし ては、 作動部に電圧を印加するためのリードを複数用い、 リードを、 作 動部の長さ方向に垂直となるように並列させて接続して、 作動部の一端 と作動部の中間付近及び Zまたは先端付近とに電圧を印加する方法が 考えられる。 - しかし、 作動部の長さ方向に垂直となるようにリードを単に並列させ て素子に接続し、 該リードを介して作動部に電圧印加した場合には、 作 動部が伸縮することによって、 並列させて接続したリ一ドのそれぞれに 大きな張力がかかって、 リードが切れやすくなる。 また並列させて接続 したリードによりァクチユエ一タ素子の伸縮が阻害される。 作動部に含 まれる導電性高分子が、 例えば 1 0 %以上の伸縮率などの大きな伸縮を 生じる場合には、 伸縮によりリードに大きな張力がかかるので、 リード の切断やリードと作動部との接続部分の破壌が生じ易くなる。 また、 ァ クチユエ一タの外部からの衝撃によつて作動部が大きく振動した場合 にも、 リードに大きな張力かかり、 リードの切断やリードと作動部との 接続部分の破壊が生じ易くなる。 A method of applying a voltage to one end of a working part using a conductive polymer and applying a voltage that can expand and contract sufficiently near the other end is to apply a voltage to the working part. Using multiple leads, connect the leads in parallel so that they are perpendicular to the length of the working part, and apply a voltage to one end of the working part, near the middle of the working part, and near Z or the tip. There is a method. -However, if the leads are simply connected in parallel to the element so as to be perpendicular to the length direction of the working part, and a voltage is applied to the working part via the lead, the working part expands and contracts, A large tension is applied to each of the leads connected in parallel, making it easier for the leads to break. In addition, the leads connected in parallel inhibit the expansion and contraction of the actuator element. Actuator included If the conductive polymer undergoes large expansion and contraction, for example, an expansion and contraction ratio of 10% or more, a large tension is applied to the lead due to expansion and contraction, so that the lead is cut or the connection between the lead and the working part is broken. It becomes easy to generate soil. In addition, even when the operating portion vibrates greatly due to an external impact of the actuator, a large tension is applied to the lead, and the lead is likely to be cut or the connection portion between the lead and the operating portion to be broken.
本発明の目的は、 導電性高分子を含む作動部を用いたァクチユエ一夕 において、 外力や作動部の伸縮によって作動部に複数接続されたリード が切断されることのなく、 導電性高分子の伸縮を阻害しないァクチユエ —夕を提供することである。 発明の開示  SUMMARY OF THE INVENTION It is an object of the present invention to provide a method for manufacturing a conductive polymer using an active part including a conductive polymer without disconnecting a plurality of leads connected to the active part by external force or expansion and contraction of the active part. Actuyue, which does not hinder stretching—is to provide an evening. Disclosure of the invention
本発明は、作動部、対極及び電解質を備えたァクチユエ一夕であって、 前記電解質を介して前記作動部と前記対極に電圧を印加するためのリ ードが前記作動部に複数接続され、 前記リードのうちの少なくとも 1つ のリードが導電性の緩衝体を備えたァクチユエ一夕である。 前記ァクチ ユエ一夕を用いることにより、 作動部に複数接続されたリードが切断さ れることなくァクチユエ一夕が作動することができる。 前記ァクチユエ —夕は、 作動部の端部付近にも十分に電圧を印加することが可能である ので、 作動部の端部においても導電性高分子の伸縮性能を十分に発揮す ることが可能である。 さらに、 前記ァクチユエ一夕は、 作動部が大きく 伸縮してもリ一ドにかかる張力が緩和されるのでリ一ドが切れること がなく、 導電性高分子の伸縮が阻害されずに、 作動部が伸縮することが できる。  The present invention is an actuating device including an operating unit, a counter electrode, and an electrolyte, wherein a plurality of leads for applying a voltage to the operating unit and the counter electrode via the electrolyte are connected to the operating unit, At least one of the leads is an actuator with a conductive buffer. By using the actuating unit, the actuating unit can be operated without disconnecting a plurality of leads connected to the operating unit. In the evening, it is possible to apply a sufficient voltage to the vicinity of the end of the working part in the evening, so that the conductive polymer can fully exhibit the expansion / contraction performance even at the end of the working part. It is. Further, in the actuating unit, the tension applied to the lead is relieved even if the operating part expands and contracts greatly, so that the lead does not break, and the expansion and contraction of the conductive polymer is not hindered. Can expand and contract.
さらに、 本発明は、 第二の発明として、 作動部、 対極及び電解質を備 えたァクチユエ一夕であって、 前記電解質を介して前記作動部と前記対 極に電圧を印加するためのリードが前記作動部に複数接続され、 前記リ 一ドが直列して作動部に接続されているァクチユエ一夕である。 前記ァ クチユエ一夕を用いることにより、 作動部に複数接続されたリードが切 断されることがない。 前記ァクチユエ一夕も、 作動部の端部付近にも十 分に電圧を印加することが可能であるので、 作動部の端部においても導 電性高分子の伸縮性能を十分に発揮することが可能であり、 さらに、 作 動部が大きく伸縮してもリードにかかる張力が緩和されるのでリード が切れることがなく、 導電性高分子の伸縮が阻害されずに、 作動部が伸 縮することができる。 図面の簡単な説明 Further, according to a second aspect of the present invention, there is provided an actuary comprising an operating portion, a counter electrode and an electrolyte, wherein the lead for applying a voltage to the operating portion and the counter electrode via the electrolyte is provided. A plurality of actuators are connected to the operating unit, and the leads are connected in series to the operating unit. By using the above-mentioned actuary, the leads connected to the operating part are disconnected. There is no refusal. Since the voltage can be sufficiently applied also to the vicinity of the end of the working part during the above-mentioned practice, it is possible to sufficiently exhibit the stretchability of the conductive polymer even at the end of the working part. It is possible, and even if the working part expands and contracts greatly, the tension applied to the lead is relieved, so that the lead does not break, the expansion and contraction of the conductive polymer is not hindered, and the operating part expands and contracts. Can be. BRIEF DESCRIPTION OF THE FIGURES
第一図は、 第一の発明であるァクチユエ一夕の第一の態様例について の縦断面図である。  FIG. 1 is a longitudinal sectional view of the first embodiment of the present invention of the first invention.
第二図は、 第一の発明であるァクチユエ一夕の第二の態様例について の縦断面図である。  FIG. 2 is a vertical cross-sectional view of the second embodiment of Actuyue Ichiyu, which is the first invention.
第三図は、 第二の発明であるァクチユエ一夕の一態様例についての縦 断面図である。 発明を実施するための最良の形態  FIG. 3 is a longitudinal sectional view of one embodiment of Actuyue, which is the second invention. BEST MODE FOR CARRYING OUT THE INVENTION
本発明について、 以下図を用いて説明するが、 本発明はこれらに限定 されるものではない。  The present invention will be described below with reference to the drawings, but the present invention is not limited thereto.
(第一の発明)  (First invention)
本発明は、作動部、対極及び電解質を備えたァクチユエ一夕であって、 前記電解質を介して前記作動部と前記対極に電圧を印加するためのリ —ドが前記作動部に複数接続され、 前記リードのうちの少なくとも 1つ のリードが導電性の緩衝体を備えたァクチユエ一夕である。 以下、 前記 の本発明を第一の発明とする。 図 1は、 第一の発明であるァクチユエ一夕の第一の態様例についての 縦断面図である。 図 1において、 円柱状のァクチユエ一タ 1は、 膜状の 作動部 2と板状の対極 3とを筐体 4の内側に備えている。 作動部 2には、 リード 5 1、 5 2、 5 3がそれぞれ作動部表面上の接続部 6 1、 6 2、 6 3を介して接続されている。 前記リード 5 2、 5 3は、 導電性の緩衝 体 7 1 、 7 2にそれぞれ繋がり、 リードを介して外部電源 8に接続され る。 対極 3もリードを介して電源 8に接続されている。 電解質 9は、 作 動部 2と対極 3に電圧を印加した際に、 電解質 9を介して電圧を印加で きるように充填されている。 The present invention relates to an actuating device including an operating part, a counter electrode and an electrolyte, wherein a plurality of leads for applying a voltage to the operating part and the counter electrode via the electrolyte are connected to the operating part, At least one of the leads is an actuator with a conductive buffer. Hereinafter, the present invention will be referred to as a first invention. FIG. 1 is a vertical cross-sectional view of the first embodiment of Actuyue Ituyu, which is the first invention. In FIG. 1, a column-shaped actuator 1 includes a film-shaped operating portion 2 and a plate-shaped counter electrode 3 inside a housing 4. Actuator 2 has leads 51, 52, 53 connected to connections 61, 62, Connected via 6 3. The leads 52 and 53 are connected to conductive buffers 71 and 72, respectively, and are connected to an external power supply 8 via the leads. The counter electrode 3 is also connected to the power supply 8 via a lead. The electrolyte 9 is filled so that a voltage can be applied through the electrolyte 9 when a voltage is applied to the working part 2 and the counter electrode 3.
第一の発明のァクチユエ一夕は、 内側に作動部、 対極及び電解質を含 むことができれば、 形状が特に限定されるものではなく、 円筒状、 四角 柱状、 多角柱状であつても良く、 所望の形状とすることができる。  The shape of the actuary of the first invention is not particularly limited as long as it can include an operating portion, a counter electrode, and an electrolyte inside, and it may be cylindrical, rectangular, or polygonal. Shape.
前記ァクチユエ一夕の筐体の材質は、 特に限定されるものではなく、 硬質プラスチック、金属、ガラス、セラミックス等の硬質材料でもよく、 ウレタンゴム、 シリコンゴム等の可撓性を有する材料でも良い。 図 1の 筐体 4の上部 4 1及び底部 4 2が作動部の伸縮に合わせて動く場合に は、 側壁面 4 3が柔軟であることが好ましいので、 前記ァクチユエ一夕 の筐体の壁面を構成する材質は、 可撓性を有する材料であることが好ま しい。 また、 ァクチユエ一夕に耐衝撃性が要求される用途には、 前記ァ クチユエ一夕の筐体の壁面を構成する材料は、 硬質材料であることが好 ましい。  The material of the housing of the case is not particularly limited, and may be a hard material such as hard plastic, metal, glass, ceramics, or a flexible material such as urethane rubber or silicon rubber. When the upper part 41 and the bottom part 42 of the housing 4 in FIG. 1 move in accordance with the expansion and contraction of the operating part, the side wall surface 43 is preferably flexible. The constituent material is preferably a material having flexibility. Further, in applications where impact resistance is required for the actuator, the material constituting the wall surface of the housing of the actuator is preferably a hard material.
第一の発明における作動部は、 導電性高分子を含み、 導電性高分子の 電解伸縮により作動部が伸縮するものであれば、 特に限定されるもので はなく、 フィルム状、 板状、 円柱状、 角柱状などの所望の形状とするこ とができる。 前記導電性高分子としては、 ポリピロール、 ポリチォフエ ン、 ポリア二リン、 ポリフエ二レンなど用いることができるが、 分子鎖 にピロール及び Zまたはピロ一ル誘導体を含む導電性高分子であるこ とが、製造が容易であり、導電性高分子として安定であるだけではなく、 電解伸縮性能に優れているために好ましい。 また、 前記作動部は、 導電 性高分子膜の物理的強度が高いことから、 電解重合法により得られた導 電性高分子膜、 または電解重合法により得られた導電性高分子膜の積層 体であることが好ましい。 また、 前記作動部は、 内部または表面に導電 性金属基体を含む電解重合法により得られた導電性高分子膜、 またはそ の積層体であることが好ましい。 The operating part in the first invention is not particularly limited as long as the operating part contains a conductive polymer and the operating part expands and contracts by electrolytic expansion and contraction of the conductive polymer. A desired shape such as a pillar shape or a prism shape can be obtained. As the conductive polymer, polypyrrole, polythiophene, polyaniline, polyphenylene and the like can be used.A conductive polymer containing pyrrole and Z or a pyrrole derivative in a molecular chain is produced. This is preferable because it is easy to perform and is not only stable as a conductive polymer, but also has excellent electrolytic expansion and contraction performance. In addition, since the physical strength of the conductive polymer film is high in the operating portion, the conductive polymer film obtained by the electrolytic polymerization method or the laminate of the conductive polymer film obtained by the electrolytic polymerization method is used. It is preferably a body. The operating portion may be a conductive polymer film obtained by an electrolytic polymerization method including a conductive metal substrate inside or on the surface, or It is preferred to be a laminate of
前記作動部は、 ドーパントとして P—トルエンスルホン酸ナトリウム を含む導電性高分子のような従来の導電性高分子を含むものであって も良い。  The operating portion may include a conventional conductive polymer such as a conductive polymer containing sodium P-toluenesulfonate as a dopant.
また、 第一の発明のァクチユエ一夕を大きな伸縮を必要とする用途に 用いる場合には、前記作動部は、前記作動部に含まれる導電性高分子が、 電解重合法による導電性高分子の製造方法であって、 前記電解重合法が 有機化合物を溶媒として含む電解液を用いる該製造方法により得られ た導電性高分子である作動部を用いることができる。 前記有機化合物は、 ( 1) エーテル結合、 エステル結合、 炭素—ハロゲン結合及びカーポネ ート結合からなる化学結合の群から少なくとも 1つ以上選ばれた化学 結合種及び/または (2) ヒドロキシル基、 ニトロ基、 スルホン基及び 二トリル基からなる官能基の群から少なくとも 1つ以上選ばれた官能 基を分子中に含むことが好ましい。 また、 前記電解液中に、 公知のドー パントを含んでいても良く、 より大きな 1酸化還元サイクル当たりの伸 縮率を得るためにトリフルォロメタンスルホン酸イオン及び/または 中心原子に結合するフッ素原子を複数含むァニオンを含むことが好ま しい。 更に、 得られた導電性高分子の 1酸化還元サイクル当たりの伸縮 率が 1 6 %以上とするために、 前記電解液として、 上記のトリフルォロ メタンスルホン酸イオン及びノまたは中心原子に対してフッ素原子を 複数含むァニオンの替りに、 化学式 ( 1)  Further, when the actuary of the first invention is used for an application that requires a large expansion and contraction, the operating section may be configured such that the conductive polymer contained in the operating section is a conductive polymer formed by an electrolytic polymerization method. In the production method, it is possible to use an operating part which is a conductive polymer obtained by the production method using the electrolytic solution containing an organic compound as a solvent in the electrolytic polymerization method. The organic compound may be (1) a chemical bond selected from at least one of a chemical bond group consisting of an ether bond, an ester bond, a carbon-halogen bond and a carbonate bond, and / or (2) a hydroxyl group, a nitro group, Preferably, the molecule contains at least one functional group selected from the group consisting of a functional group consisting of a group, a sulfone group and a nitrile group. Further, the electrolyte may contain a known dopant, and a trifluoromethanesulfonic acid ion and / or a fluorine atom bonded to a central atom in order to obtain a larger elongation ratio per one oxidation-reduction cycle. It is preferable to include an anion containing a plurality of. Further, in order to make the obtained conductive polymer have an expansion / contraction rate of 16% or more per oxidation-reduction cycle, the above-mentioned trifluoromethanesulfonate ion and the fluorine atom with respect to the central atom or the trifluoromethanesulfonic acid ion are used as the electrolytic solution. Chemical formula (1)
(CnF (2 n + 1) S 02) (CmF (2m+ 1) S 02) N- (1) (C n F (2 n + 1) S 0 2 ) (C m F (2m + 1) S 0 2 ) N- (1)
(ここで、 n及び mは任意の整数。 )  (Where n and m are arbitrary integers.)
で表されるパーフルォロアルキルスルホ二ルイミ ドイオンをァニオン として含む電解液を用いることが好ましい。 前記作動部が前記製造方法 により製造された導電性高分子を含む作動部である場合には、 前記作動 部の 1酸化還元サイクル当たりの伸縮率を容易に 3 %以上とすること ができ、 ァクチユエ一夕を人工筋肉等の大きな伸縮率が要求される用途 に用いることができる。 前記有機化合物としては、 1, 2—ジメトキシェタン、 1, 2—ジェ トキシェタン、 テトラヒドロフラン、 2—メチルテトラヒドロフラン、 1 , 4一ジォキサン (以上、 エーテル結合を含む有機化合物)、 γ—プ チロラクトン、 酢酸ェチル、 酢酸 η-プチル、 酢酸- -プチル、 1, 2—ジ ァセトキシェタン、 3—メチルー 2—ォキサゾリジノン、 安息香酸メチ ル、 安息香酸ェチル、 安息香酸プチル、 フタル酸ジェチル (以上、 エス テル結合を含む有機化合物)、 プロピレン力一ポネート、 エチレンカー ポネート、 ジメチルカーポネート、 ジェチルカーポネート、 メチルェチ ルカ一ポネート (以上、 カーボネート結合を含む有機化合物)、 ェチレ ングリコール、 1ーブ夕ノール、 1一へキサノール、 シクロへキサノー ル、 1一才クタノール、 1ーデカノール、 1 一ドデカノール、 1—ォク タデカノール (以上、 ヒドロキシル基を含む有機化合物)、 ニトロメタ ン、 ニトロベンゼン (以上、 ニトロ基を含む有機化合物)、 スルホラン、 ジメチルスルホン (以上、 スルホン基を含む有機化合物)、 及びァセ卜 二トリル、 プチロニトリル、 ベンゾニトリル (以上、 二トリル基を含む 有機化合物) を例示することができる。 なお、 ヒドロキシル基を含む有 機化合物は、 特に限定されるものではないが、 多価アルコール及び炭素 数 4以上の 1価アルコールであることが、 伸縮率が良いために好ましレ^ なお、前記有機化合物は、前記の例示以外にも、分子中にエーテル結合、 エステル結合、 カーボネート結合、 ヒドロキシル基、 ニトロ基、 スルホ ン基及び二トリル基のうち、 2つ以上の結合あるいは官能基を任意の組 合わせで含む有機化合物であってもよい。 前記有機化合物は、 前記有機 化合物を 2種以上混合して用いても良い。 It is preferable to use an electrolytic solution containing a perfluoroalkylsulfonyl imido ion represented by the following formula as an anion. When the operating part is an operating part containing the conductive polymer manufactured by the manufacturing method, the expansion and contraction rate of the operating part per oxidation-reduction cycle can be easily increased to 3% or more. One night can be used for applications requiring a large expansion and contraction rate such as artificial muscles. Examples of the organic compound include 1,2-dimethoxyethane, 1,2-jetoxetane, tetrahydrofuran, 2-methyltetrahydrofuran, 1,4-dioxane (the above organic compounds containing an ether bond), γ-butyrolactone, acetic acid Ethyl, η- butyl acetate, -butyl acetate, 1,2-diacetoxetane, 3-methyl-2-oxazolidinone, methyl benzoate, ethyl benzoate, butyl benzoate, getyl phthalate (including ester bond) Organic compounds), propylene glycol, ethylene carbonate, dimethyl carbonate, dimethyl carbonate, methyl ethyl carbonate (more than organic compounds containing carbonate bonds), ethylene glycol, 1-butyl alcohol, Xanol, cyclohexanol, 1-year-old kutano 1, 1-decanol, 1-dodecanol, 1-octadecanol (above, organic compounds containing hydroxyl groups), nitromethane, nitrobenzene (above, organic compounds containing nitro groups), sulfolane, dimethyl sulfone (above, Organic compounds containing), and acetate nitrile, ptyronitrile, and benzonitrile (the organic compounds containing a nitrile group). The organic compound containing a hydroxyl group is not particularly limited, but is preferably a polyhydric alcohol or a monohydric alcohol having 4 or more carbon atoms because of its good elasticity. In addition to the above-described examples, the organic compound may have any two or more bonds or functional groups selected from ether bonds, ester bonds, carbonate bonds, hydroxyl groups, nitro groups, sulfone groups, and nitrile groups in the molecule. Organic compounds may be included in combination. The organic compound may be a mixture of two or more of the organic compounds.
また、 前記製造方法において、 電解液に溶媒として含まれるハロゲン 化炭化水素は、 炭化水素中の水素が少なくとも 1つ以上ハロゲン原子に 置換されたもので、 電解重合条件で液体として安定に存在することがで きるものであれば、 特に限定されるものではない。  In the above-mentioned production method, the halogenated hydrocarbon contained as a solvent in the electrolytic solution is one in which at least one hydrogen in the hydrocarbon is replaced by a halogen atom, and is present as a liquid stably under electrolytic polymerization conditions. There is no particular limitation as long as it is possible.
前記ハロゲン化炭化水素としては、 例えば、 ジクロロメタン、 ジクロ ロェタンを挙げることができる。 前記ハロゲン化炭化水素は、 1種類の みを前記電解液中の溶媒として用いることもできるが、 2種以上併用す ることもできる。 また、 前記ハロゲン化炭化水素は、 上記の有機化合物 と混合して用いてもよく、 該有機溶媒との混合溶媒を前記電解液中の溶 媒として用いることもできる。 Examples of the halogenated hydrocarbon include dichloromethane and dichloroethane. The halogenated hydrocarbon is one kind of Can be used as a solvent in the electrolytic solution, but two or more of them can be used in combination. The halogenated hydrocarbon may be used as a mixture with the above organic compound, and a mixed solvent with the organic solvent may be used as a solvent in the electrolytic solution.
前記電解重合法に用いられる電解液には、 電解重合される有機化合物 (例えば、 ピロール) およびトリフルォロメ夕ンスルホン酸イオン及び /または中心原子に対してフッ素原子を複数含むァニオンを含む。 この 電解液を用いて電解重合を行うことにより、 電解伸縮において 1酸化還 元サイクル当たりの伸縮率及び/または特定時間あたりの変位率が優 れた導電性高分子を得ることができる。 上記電解重合により、 トリフル ォロメ夕ンスルホン酸イオン及び または中心原子に対してフッ素原 子を複数含むァニオンが導電性高分子に取り込まれることになる。  The electrolytic solution used in the electrolytic polymerization method contains an organic compound to be electrolytically polymerized (for example, pyrrole) and a trifluoromethanesulfonic acid ion and / or an anion containing a plurality of fluorine atoms with respect to a central atom. By performing electrolytic polymerization using this electrolytic solution, it is possible to obtain a conductive polymer having an excellent expansion / contraction rate per one oxidation-reduction cycle and / or displacement rate per specific time in electrolytic expansion / contraction. By the above-described electrolytic polymerization, trifluoromethanesulfonic acid ions and / or anions containing a plurality of fluorine atoms with respect to the central atom are incorporated into the conductive polymer.
前記トリフルォロメタンスルホン酸イオン及び/または中心原子に 対してフッ素原子を複数含むァニオンは、 電解液中の含有量が特に限定 されるものではないが、 電解液中に 0. 1〜 3 0重量%含まれるのが好 ましく、 1〜 1 5重量%含まれるのがより好ましい。  The content of the anion containing a plurality of fluorine atoms with respect to the trifluoromethanesulfonic acid ion and / or the central atom is not particularly limited in the electrolytic solution, but is 0.1 to 30% by weight in the electrolytic solution. %, More preferably 1 to 15% by weight.
トリフルォロメタンスルホン酸イオンは、 化学式 C F 3 S〇3—で表さ れる化合物である。 また、 中心原子に対してフッ素原子を複数含むァニ オンは、 ホウ素、 リン、 アンチモン及びヒ素等の中心原子に複数のフッ 素原子が結合をした構造を有している。 中心原子に対してフッ素原子を 複数含むァニオンとしては、 特に限定されるものではないが、 テトラフ ルォロホウ酸イオン(B F4―)、へキサフルォロリン酸イオン(P F 6一)、 へキサフルォロアンチモン酸イオン (S b F6_)、 及びへキサフルォロ ヒ酸イオン (A s F6_) を例示することができる。 なかでも、 C F3 S 03—、 B F4 及び P F 6—が人体等に対する安全性を考慮すると好まし く、 CF3S〇3 及び B F4—がより好ましい。 前記の中心原子に対して フッ素原子を複数含むァニオンは、 1種類のァニオンを用いても良く、 複数種のァニオンを同時に用いても良く、 さらには、 トリフルォロメタ ンスルホン酸イオンと複数種の中心原子に対しフッ素原子を複数含む ァニオンとを同時に用いても良い。 Trifluoromethanesulfonate ion is a compound represented by the chemical formula CF 3 S〇 3 —. An anion containing a plurality of fluorine atoms with respect to the central atom has a structure in which a plurality of fluorine atoms are bonded to a central atom such as boron, phosphorus, antimony, and arsenic. The Anion containing a plurality of fluorine atoms with respect to the central atom, but are not particularly limited, Tetorafu Ruorohou acid ion (BF 4 -), the Kisafuruororin acid ion (PF 6 I), the hexa full O b antimonate can be exemplified ions (_ S b F 6), and to Kisafuruoro arsenate ion (a s F 6 _). Among them, CF 3 S 0 3 -, BF 4 and PF 6 - When considering the safety to human body rather preferable, CF 3 S_〇 3 and BF 4 - is preferable. As the anion containing a plurality of fluorine atoms with respect to the central atom, one kind of anion may be used, a plurality of kinds of anions may be used at the same time, and further, trifluoromethanesulfonic acid ion and a plurality of kinds of central atoms may be used. In contrast, contains multiple fluorine atoms An anion may be used at the same time.
前記電解重合法に用いられる電解液には、 前記有機化合物溶媒と前記 トリフルォロメタンスルホン酸イオン及び Zまたは中心原子に対して フッ素原子を複数含むァニオンとの溶液中に、 導電性高分子の単量体を 含み、 さらにポリエチレングリコールやポリアクリルアミドなどの公知 のその他の添加剤を含むこともできる。  The electrolytic solution used in the electrolytic polymerization method includes a solution of the organic compound solvent and the trifluoromethanesulfonate ion and anion containing a plurality of fluorine atoms with respect to Z or a central atom. And further known additives such as polyethylene glycol and polyacrylamide.
前記電解重合法は、 導電性高分子単量体の電解重合として、 公知の電 解重合方法を用いることが可能であり、 定電位法、 定電流法及び電気掃 引法のいずれをも用いることができる。 例えば、 前記電解重合は、 電流 密度 0 . 0 l〜2 0 m A / c m2、 反応温度— 7 0〜 8 0 °C、 好ましくは 電流密度 0 . :!〜 2 m A / c m 2、 反応温度— 4 0〜 4 0 の条件下で 行うことが好ましく、 反応温度が— 2 0〜 3 O :の条件であることがよ り好ましい。 In the electrolytic polymerization method, a known electrolytic polymerization method can be used as the electrolytic polymerization of the conductive polymer monomer, and any of the constant potential method, the constant current method, and the electric sweep method can be used. Can be. For example, the electrolytic polymerization, the current density 0 0 l~2 0 m A / c m2, the reaction temperature - 7 0~ 8 0 ° C, preferably current density 0:..! ~ 2 m A / cm 2, the reaction The reaction is preferably performed at a temperature of −40 to 40, and more preferably at a reaction temperature of −20 to 3O :.
第一の発明のァクチユエ一夕において、 作動部は、 導電性高分子及び ドーパントが含まれる他に、 動作電極としての抵抗値を低下させるため に、 金属線や導電性酸化物などの導電性材料を適宜含むことができる。 第一の発明のァクチユエ一夕における対極は、 電極として用いること ができる導電性材料で形成されているものであれば、 形状が特に限定さ れるものではなく、 棒状、 線状、 膜状及び板状であっても良い。 また、 前記対極の材質は、 特に限定されるものではなく、 種類として金、 白金 等の貴金属を含む金属であっても良く、 導電性樹脂や I T Oガラス等の 導電性非金属であっても良い。 前記対極の材質は、 腐食しにくくて加工 が容易なことから貴金属であることが好ましく、 白金または金であるこ とがより好ましい。 本発明における対極は、 対極及び作動部に電圧を印 加した際に、 対極と作動部との間で電解質を介して電流が流れ、 短絡が 生じない程度に、 作動部との間隔を有することが好ましい。 前記間隔を 有することにより、 不織布等のセパレータを必要とせず、 ァクチユエ一 タの構成が簡単だからである。  In the first aspect of the invention, the operating portion includes a conductive material such as a metal wire and a conductive oxide in order to lower the resistance value as the working electrode in addition to including the conductive polymer and the dopant. Can be included as appropriate. The shape of the counter electrode in the first embodiment of the invention is not particularly limited as long as the counter electrode is formed of a conductive material that can be used as an electrode, and may be a rod, a line, a film, or a plate. It may be in a shape. The material of the counter electrode is not particularly limited, and may be a metal containing a noble metal such as gold or platinum as a type, or may be a conductive non-metal such as a conductive resin or ITO glass. . The material of the counter electrode is preferably a noble metal because it is hardly corroded and easy to process, and more preferably platinum or gold. The counter electrode according to the present invention has a gap between the counter electrode and the working part such that when a voltage is applied to the counter electrode and the working part, a current flows between the counter electrode and the working part through the electrolyte and a short circuit does not occur. Is preferred. This is because having the above-mentioned interval does not require a separator such as a nonwoven fabric, and the configuration of the actuator is simple.
第一の発明のァクチユエ一夕における緩衝体は、 作動部に接続される リードに備えられ、 導電性を有している。 前記緩衝体は、 作動部が伸縮 によりリードにかかる張力や、 外部からの衝撃による作動部等の振動に よりリードにかかる張力を緩和でき、 作動部が伸縮を阻害するものでな ければ、 材質及び構造が特に限定されるものではない。 前記緩衝体とし ては、 例えば、 金属メッシュ、 導電性繊維、 導電性ゴム、 金属パネ、 炭 素バネを用いることができる。 また前記緩衝体は、 帯状、 線状、 板状な どのァクチユエ一夕の構造に適した形状として用いることができる。 な お、 前記緩衝体の個数は、 作動部に接続するリードに少なくとも 1っ以 上取り付けられていれば良く、 作動部に接続する複数のリードのそれぞ れに取り付けられても良い。 また、 作動部が一の端部で筐体等に固定さ れる場合には、 作動部の固定された部分に接続するリードを除く全ての リードにそれぞれに取り付けられていることが、 作動部において伸縮が 阻害されることがなく、 少ない緩衝体の個数で大きな伸縮を得ることが できるので好ましい。 The buffer of the first invention is connected to the operating part. It is provided on the lead and has conductivity. The cushioning member can reduce the tension applied to the lead due to the expansion and contraction of the operating portion and the tension applied to the lead due to the vibration of the operating portion due to an external impact. And the structure is not particularly limited. For example, a metal mesh, conductive fiber, conductive rubber, metal panel, or carbon spring can be used as the buffer. In addition, the buffer can be used in a shape suitable for the structure of the factory, such as a band, a line, and a plate. The number of the buffers may be at least one attached to the lead connected to the operating part, and may be attached to each of a plurality of leads connected to the operating part. When the operating part is fixed to the housing or the like at one end, it is required that the operating part is attached to all the leads except for the lead connected to the fixed part of the operating part. It is preferable because expansion and contraction are not hindered and large expansion and contraction can be obtained with a small number of buffers.
前記緩衝体は、 構造が簡単であり、 リードとの接続が容易であること から弾性体であることが好ましい。 前記弾性体は、 電解質と接触する場 合においては電解質中に含まれる有機成分による膨潤による影響を受 けることが無く、 弾性を保つことができることから、 金属バネであるこ とが好ましい。 特に、 全方向から屈曲や伸縮に容易に追従できることか ら、 前記緩衝体がコイル型金属パネであることが好ましい。 前記コイル 型金属パネの材料は、 A g、 N i 、 T i 、 A u、 P t、 T a、 W等の金 属ゃこれらの合金、 並びに S U S等の合金を用いることができる。 中で も、 前記材質は、 耐腐食性が良いために P t 、 A uであることが好まし い。 なお、 前記緩衝体は、 導電性高分子の伸縮を阻害しない緩衝体であ ればよい。  The buffer is preferably an elastic body because of its simple structure and easy connection with a lead. The elastic body is preferably a metal spring because it can be kept elastic without being affected by swelling due to organic components contained in the electrolyte when it comes into contact with the electrolyte. In particular, the buffer is preferably a coil-shaped metal panel because it can easily follow bending and expansion and contraction from all directions. Metals such as Ag, Ni, Ti, Au, Pt, Ta, and W, alloys thereof, and alloys such as SUS can be used as the material of the coil-type metal panel. Among them, the material is preferably Pt or Au because of its good corrosion resistance. The buffer may be a buffer that does not inhibit the expansion and contraction of the conductive polymer.
第一の発明において、 図 1では、 リードが接続部において作動部に接 続されているが、 前記緩衝体がリードを介することなく接続部に接続さ れてもよい。前記緩衝体は、 リードを介して接続部に接続されることが、 作動部と接触して作動部に外傷を与えることがないので好ましい。 前記 緩衝体と前記リードとの接続部分は、 リードと緩衝体との導通を保つこ とができ、 作動部の伸縮によってリード並びに緩衝部にかかる張力と外 部振動によりリード並びに緩衝部にかかる張力とにより、 リードと緩衝 体とが分離しなければ、 特に限定されるものではない。 前記緩衝体と前 記リードとの接続部分としては、 材料として、 はんだ止め、 導電性接着 剤を用いることができる。 また、 前記接続部分は、 重合時に複合化する などの方法を用いることができる。 In the first invention, in FIG. 1, the lead is connected to the operating portion at the connecting portion, but the buffer may be connected to the connecting portion without the intermediary of the lead. It is preferable that the buffer is connected to the connecting portion via a lead, because the buffer does not contact the operating portion and does not damage the operating portion. Said The connection between the shock absorber and the lead can maintain conduction between the lead and the shock absorber. The tension between the lead and the shock absorber due to the expansion and contraction of the operating portion, and the tension between the lead and the shock absorber due to external vibration. As long as the lead and the buffer do not separate from each other, there is no particular limitation. As a material for a connection portion between the buffer and the lead, a solder stop or a conductive adhesive can be used as a material. Further, the connection portion may be formed by a method of forming a composite during polymerization.
第一の発明において、 作動部に形成されている接続部を介して電源か ら電圧が印加される。 図 1においては、 接続部 5 1、 5 2、 5 3の 3つ が形成され、作動部には、 3箇所から電圧が印加される。前記接続部は、 図 1においては、 接続部 2の一端の面を覆うように接続部 6 1が形成さ れ、 接続部 6 2、 6 3が作動部 2の側面に一部にそれぞれ形成されてい る。 第一の発明の接続部は、 リードから作動部に電圧を印加することが できるように、 作動部上にリードまたは緩衝体が固定されるものであれ ば、 特に限定されるものではない。 前記接続部の形状についても、 作動 部に電圧が印加されて作動部が電解伸縮するものであれば、 限定される ものではない。 前記接続部は、 作動部の一端に形成される場合には、 一 端の一面を覆うように形成されても良く、 一部に形成されても良い。 ま た、 前記作動部が、 作動部の側面上に形成される場合には、 側面の一部 分に形成されても良く、 側面外周上を周回するように形成されても良い。 前記接続部は、 導電性接着剤、 導電性テープ、 金属クリップまたは金 属板を用いることができる。 また、 前記接続部は、 重合時に導電性高分 子とリード若しくは緩衝体とを複合化させることもできる。 前記接続部 の個数は、 複数個であれば特に限定されるものではなく、 作動部に含ま れる導電性高分子の種類や作動部の長さに応じて、 適当な箇所に適宜配 置することができる。 また、 前記作動部が導電性高分子としてポリピロ ールを含む場合には、 隣接した接続部の間隔は、 長さ方向において 5 c m以下であることが、 ァクチユエ一夕全体として大きな伸縮性を得るこ とが容易であるために好ましい。 リード 5 4は、 導電性の緩衝体及びリードを介して、 電源より各接続 部に電圧を印加するための電気経路である。 前記電気経路は、 ァクチュ エー夕に対する衝撃等によりリ一ドが振動して切断されることがない ように、 筐体の内側面に固定若しくは保持するように設置されることが 好ましい。 In the first invention, a voltage is applied from a power supply via a connection portion formed in the operation portion. In FIG. 1, three connecting portions 51, 52, and 53 are formed, and a voltage is applied to the operating portion from three places. In FIG. 1, the connection portion is formed with a connection portion 61 so as to cover one end surface of the connection portion 2, and connection portions 62 and 63 are formed partially on the side surfaces of the operation portion 2, respectively. ing. The connecting portion of the first invention is not particularly limited as long as the lead or the buffer is fixed on the operating portion so that a voltage can be applied from the lead to the operating portion. The shape of the connection portion is not limited as long as a voltage is applied to the operation portion and the operation portion expands and contracts electrolytically. When the connecting portion is formed at one end of the operating portion, it may be formed so as to cover one surface of one end or may be formed partially. Further, when the operating portion is formed on the side surface of the operating portion, it may be formed on a part of the side surface, or may be formed so as to go around the outer periphery of the side surface. The connection portion may use a conductive adhesive, a conductive tape, a metal clip, or a metal plate. In addition, the connection portion may form a composite of a conductive polymer and a lead or a buffer during polymerization. The number of the connection parts is not particularly limited as long as it is plural, and may be appropriately arranged at an appropriate place according to the type of the conductive polymer contained in the operation part and the length of the operation part. Can be. Further, when the operating portion contains polypyrrole as a conductive polymer, the distance between adjacent connecting portions is preferably 5 cm or less in the length direction, so that a large stretch can be obtained as a whole. This is preferable because it is easy. The lead 54 is an electric path for applying a voltage from a power supply to each connection portion via a conductive buffer and a lead. It is preferable that the electric path is fixed or held on the inner surface of the housing so that the lead does not vibrate and be cut by an impact on the actuator.
第一の発明のァクチユエ一夕に含まれる電解質は、 特に限定されるも のではなく、 液状であってもよく、 固体電解質でもよい。 前記電解質が 液状である場合には、 水溶媒であっても、 有機溶媒であっても良いが、 毒性が低く揮発する速度が比較的遅いために取り扱いが容易であり、 大 きな伸縮を得ることができるため、 水溶媒であることが好ましい。 前記 電解液が固体電解質である場合には、 ゲル高分子電解質であっても完全 固体高分子電解質であってもよいが、 電解質中のイオン伝導度が大きい ためにゲル高分子電解質が好ましい。 前記ゲル高分子電解質に用いるゲ ルとしては、 ポリアクリルアミド、 ポリエチレングリコール、 寒天など を用いることが、 水溶液電解質と複合させ、 容易にゲル高分子電解質を 調製できるので好ましい。 前記電解質は、 トリフルォロメタンスルホン 酸イオン、 中心原子に対してフッ素原子を複数含むァニオン及び炭素数 3以下のスルホン酸塩からなる群より少なくとも 1以上選ばれた化合 物を含む電解質とすることが、 ァクチユエ一夕が 1酸化還元サイクル当 たりの伸縮について、 さらに大きな伸縮を生じることが可能となるので、 好ましい。 また、 前記電解質は、  The electrolyte contained in the factories of the first invention is not particularly limited, and may be a liquid or a solid electrolyte. When the electrolyte is in a liquid state, it may be an aqueous solvent or an organic solvent, but is easy to handle due to its low toxicity and a relatively slow volatilization rate, and it has a large expansion and contraction. Preferably, the solvent is an aqueous solvent. When the electrolyte is a solid electrolyte, it may be a gel polymer electrolyte or a completely solid polymer electrolyte, but a gel polymer electrolyte is preferred because of its high ionic conductivity in the electrolyte. As the gel used for the gel polymer electrolyte, it is preferable to use polyacrylamide, polyethylene glycol, agar, or the like, since the gel polymer electrolyte can be easily prepared by complexing with the aqueous solution electrolyte. The electrolyte may be an electrolyte containing at least one compound selected from the group consisting of trifluoromethanesulfonate ion, anion containing a plurality of fluorine atoms with respect to a central atom, and a sulfonate having 3 or less carbon atoms. However, it is preferable because the actuate can cause a larger expansion and contraction per one oxidation-reduction cycle. Further, the electrolyte is
(CnF (2 n + 1) S 02) (CmF (2m+ 1) S 02) N一 (C n F (2 n + 1) S 0 2 ) (C m F (2m + 1) S 0 2 ) N
(ここで、 n及び mは任意の整数。 ) を含むことができる。 作動部がド 一パントとして化学式  (Where n and m are any integers.) Actuating part is chemical formula as single punt
(CnF (2 n + 1) S 02) (CmF (2m+ 1) S〇2) N一 (C n F (2 n + 1) S 0 2 ) (C m F (2m + 1) S〇 2 ) N
(ここで、 n及び mは任意の整数。 )  (Where n and m are arbitrary integers.)
で表されるパーフルォロアルキルスルホ二ルイミ ドイオンを含む場合 には、 When containing a perfluoroalkylsulfonyl imido ion represented by
(CnF (2 n + 1) S 02) (CmF (2m+ 1) S 02) N- (ここで、 n及び mは任意の整数。) を含む電解質を用いて本発明のァクチ ユエ一夕を電解伸縮させることが好ましい。 前記ァクチユエ一夕の作動 部が、 従来のドーパントよりもイオン半径が大きいパーフルォロアルキ ルスルホニルイミ ドのドーピング及び脱ドーピングが行われるために、 トリフルォロメ夕ンスルホン酸イオンなどを含む電解質を用いた場合 に比べて、 1酸化還元サイクル当たりの優れた伸縮率及び優れた特定時 間あたりの変位率を示すことができる。 (C n F (2 n + 1) S 0 2) (C m F (2m + 1) S 0 2) N- ( wherein, n and m are arbitrary integers.) Of the present invention using the electrolyte containing It is preferred that the actuate is electrolytically stretched. The working part of the actuator is a perfluoroalkyl having a larger ionic radius than the conventional dopant. The doping and dedoping of rusulfonylimide results in a better stretch ratio per oxidation-reduction cycle and a better per-specified time compared to the use of electrolytes containing trifluoromethanesulfonic acid ions. The displacement rate can be shown.
図 1においては、 作動部 2の接続部 6 1の反対側の端部 (先端部) に シャフトが備えられている。 電解質を介して作動部 2と対極 3に電圧が 印加されることにより、 前記作動部が電解伸縮し、 前記シャフトも上下 運動する。 前記シャフトの運動により、 作動部 2の伸縮により発生する カをァクチユエ一夕外部に伝えることができるようになつている。 なお、 前記電解質が電解液である場合には、 ァクチユエ一夕の先端部分をキヤ ップすることが好ましい。  In FIG. 1, a shaft is provided at an end (tip) of the operating portion 2 opposite to the connecting portion 61. When a voltage is applied to the operating portion 2 and the counter electrode 3 via the electrolyte, the operating portion expands and contracts electrolytically, and the shaft also moves up and down. By the movement of the shaft, the force generated by the expansion and contraction of the operating portion 2 can be transmitted to the outside of the actuator. When the electrolyte is an electrolytic solution, it is preferable to cap the tip of the actuator.
第一の発明のァクチユエ一夕においては、 作動部 2の伸縮により発生 するカをァクチユエ一夕外部に伝える手段としては、 作動部にシャフト を形成する方法に限定されるものではなく、 ァクチユエ一夕の筐体が可 撓性を有する材料で形成され、 ァクチユエ一夕全体が伸縮運動するもの であってもよい。 ァクチユエ一夕全体が伸縮運動する場合には、 筐体を 形成する可撓性材料は、 特に限定されるものではなく、 ァクチユエ一夕 の伸び率に応じて、 適宜選択することができ、 伸び率 5 %以上の合成樹 脂を用いることが好ましく、 伸び率 2 0 %以上の合成樹脂を用いること がより好ましい。 前記可撓性材料としては、 例えば、 シリコン系樹脂、 ウレタン系樹脂、 シリコン系ゴム、 ウレタン系ゴム等を用いることがで きる。 また、 前記可撓性材料は、 電解質をァクチユエ一夕外部に漏洩す ることを防止する機能をも有することから、 耐溶剤性を有することが好 ましく、 シリコン系樹脂、 ウレタン系樹脂、 シリコン系ゴム又はウレタ ン系ゴムを好適に用いることができる。 なお、 前記ァクチユエ一夕は、 作動部が筐体により密閉されている構造を備えている場合は、 棒状体の ような力を伝える手段が筐体を貫通して構造に比べて、 長期の使用によ る電解質の漏洩が無いので、 人工筋肉等の機械部品として用いることに 優れている。 図 2は、 第一の発明のァクチユエータの第二の態様例についての縦断 面図である。 図 2において、 円柱状のァクチユエータ 1 1は、 膜状の作 動部 1 2と板状の対極 1 3とを筐体 1 4の内側に備えている。 作動部 1 2には、 リード 15 1、 1 5 2、 1 5 3、 1 54、 1 5 5がそれぞれ作 動部表面上の接続部 1 6 1、 1 6 2、 1 6 3を介して接続されている。 前記リード 1 5 2、 1 5 3は導電性の緩衝体 1 7 1、前記リード 1 5 4、According to the first aspect of the invention, the means for transmitting the force generated by the expansion and contraction of the operating portion 2 to the outside of the operating portion is not limited to the method of forming the shaft in the operating portion. The housing may be formed of a flexible material, and the entire actuator may expand and contract. In the case where the entirety of the actuary elongates and contracts, the flexible material forming the housing is not particularly limited, and can be appropriately selected according to the elongation rate of the actiyue. It is preferable to use a synthetic resin of 5% or more, and it is more preferable to use a synthetic resin having an elongation of 20% or more. As the flexible material, for example, silicon-based resin, urethane-based resin, silicon-based rubber, urethane-based rubber, or the like can be used. Further, since the flexible material also has a function of preventing the electrolyte from leaking to the outside of the actuator, it is preferable that the flexible material has solvent resistance. Silicon-based resin, urethane-based resin, silicone A system rubber or a urethane rubber can be suitably used. In the case of the actuary, if the operating part has a structure that is sealed by a housing, a means for transmitting a force such as a rod-like body penetrates the housing and is used for a longer time than the structure. Since there is no electrolyte leakage due to this, it is excellent for use as mechanical parts such as artificial muscles. FIG. 2 is a longitudinal sectional view of a second embodiment of the actuator of the first invention. In FIG. 2, a column-shaped actuator 11 includes a film-shaped operating portion 12 and a plate-shaped counter electrode 13 inside a housing 14. Leads 151, 152, 153, 154, 155 are connected to working part 12 via connections 161, 162, 163 on the working part surface, respectively. Have been. The leads 15 2 and 15 3 are conductive buffers 17 1 and the leads 15 4 and
1 5 5は緩衝体 1 7 2に繋がっている。 作動部表面上の接続部 1 6 1、1 5 5 is connected to the buffer 1 7 2. Connections on the working surface 1 6 1,
1 6 2、 1 6 3には、 リード及び緩衝体を介して外部電源 1 8から直列 で電力が供給される。 対極 1 3もリードを介して電源 1 8に接続されて いる。 電解質 1 9は、 作動部 1 2と対極 1 3に電圧を印加した際に、 電 解質 1 9を介して電圧を印加できるように充填されている。 Electric power is supplied to 16 2 and 16 3 in series from an external power supply 18 via a lead and a buffer. The counter electrode 13 is also connected to the power supply 18 via a lead. The electrolyte 19 is filled so that a voltage can be applied through the electrolyte 19 when a voltage is applied to the operating part 12 and the counter electrode 13.
第二の態様例である図 2のァクチユエータ 1 1は、 作動部に電圧を印 加するために、 接続部 1 6 1、 1 6 2、 1 6 3へ電圧が与えられる。 接 続部 1 6 1に電圧を供給するための第一の電気経路は、 リード 1 5 1を 含む経路である。 接続部 1 6 2に電圧を与えるための第二の電気経路は、 リード 1 5 2と緩衝体 1 7 1とリード 1 5 3とを含む経路である。 接続 部 1 6 3に電圧を与えるための第三の電気経路は、 リード 1 5 4と緩衝 体 1 7とリード 1 5 5とを含む経路である。 これに対し、 図 1において は、 作動部に電圧を印加するために接続部 6 1、 6 2、 6 3へ電圧を与 えるための電気経路は、 接続部 6 1に電圧を与える第一の電気経路がリ ード 5 1を含む経路であり、 接続部 6 2に電圧を与えるための第二の電 気経路がリード 5 2と緩衝体 7 1 とを含む経路であり、 接続部 6 3に電 圧を与えるための第三の電気経路がリード 5 3 と緩衝体 7 2とを含む 経路である。  In the actuator 11 of FIG. 2, which is the second embodiment, a voltage is applied to the connecting portions 161, 162, and 163 in order to apply a voltage to the operating portion. The first electrical path for supplying voltage to connection 16 1 is the path that includes lead 15 1. The second electric path for applying a voltage to the connection section 16 2 is a path including the lead 15 2, the buffer 17 1, and the lead 15 3. A third electric path for applying a voltage to the connection portion 163 is a path including the lead 154, the buffer 17, and the lead 155. On the other hand, in FIG. 1, the electric path for applying a voltage to the connecting portions 61, 62, and 63 to apply a voltage to the operating portion is a first path for applying a voltage to the connecting portion 61. The electric path is a path including the lead 51, the second electric path for applying a voltage to the connection section 62 is a path including the lead 52 and the buffer 71, and the connection section 6 3 A third electric path for applying a voltage to the coil is a path including the lead 53 and the buffer 72.
本願の第一の発明の第一の態様である図 1においては、 作動部に電圧 を印加するための電気経路として、 第一の電気経路と第二の電気経路と 第三の電気経路が並列に設定されている。 第一の発明の第二の態様であ る図 2においては、 作動部に電圧を印加するための電気経路として、 第 一の電気経路と第二の電気経路と第三の電気経路が直列に接続されて いる。 即ち、 本願の第一の発明において、 作動部に電圧を印加するため の電気経路の接続形式は、 作動部に接続された複数の電気経路が並列に 接続されても良く、 直列に接続されても良い。 前記接続形式は、 目的に 応じて好適な形式を選択することができる。 ァクチユエ一夕全体として のサイズを小さくし省スペース化を図る場合には、 作動部に接続された 複数の電気経路が直列に接続されることが好ましい。 作動部の大きな伸 縮等により接続部における断線が懸念される場合には、 作動部に接続さ れた複数の電気経路が並列に接続されることが好ましい。 In FIG. 1 which is the first embodiment of the first invention of the present application, as an electric path for applying a voltage to the operating portion, a first electric path, a second electric path, and a third electric path are arranged in parallel. Is set to In FIG. 2, which is the second embodiment of the first invention, an electric path for applying a voltage to One electric path, a second electric path, and a third electric path are connected in series. That is, in the first invention of the present application, the connection form of the electric path for applying the voltage to the operating section may be such that a plurality of electric paths connected to the operating section may be connected in parallel, or may be connected in series. Is also good. As the connection format, a suitable format can be selected according to the purpose. In order to reduce the overall size of the factory and save space, it is preferable that a plurality of electric paths connected to the operating unit be connected in series. If there is a risk of disconnection at the connection part due to large expansion or contraction of the operation part, it is preferable that a plurality of electric paths connected to the operation part be connected in parallel.
図 2においても、 図 1の第一の態様と同様に、 作動部 1 2の接続部 1 5の反対側の端部 (先端部) にシャフトが備えられ、 前記シャフトの上 下運動により、 作動部 2の伸縮により発生するカをァクチユエ一夕外部 に伝えることができるようになつている。 なお、 前記電解質が電解液で ある場合には、 ァクチユエ一夕の先端部分をキャップすることが好まし い。  In FIG. 2, similarly to the first embodiment of FIG. 1, a shaft is provided at the end (tip portion) on the opposite side of the connection portion 15 of the operation portion 12, and the operation is performed by the up and down movement of the shaft. The power generated by the expansion and contraction of part 2 can be transmitted to outside the factory. When the electrolyte is an electrolytic solution, it is preferable to cap the tip of the actuator.
(第二の発明)  (Second invention)
本発明は、作動部、対極及び電解質を備えたァクチユエ一夕であって、 前記電解質を介して前記作動部と前記対極に電圧を印加するためのリ ―ドが前記作動部に複数接続され、 前記リードが直列して作動部に接続 されているァクチユエ一夕である。 以下、 前記の本発明を第二の発明と する。  The present invention relates to an actuating device comprising an operating part, a counter electrode and an electrolyte, wherein a plurality of leads for applying a voltage to the operating part and the counter electrode via the electrolyte are connected to the operating part, This is a case where the leads are connected in series to the operating part. Hereinafter, the present invention is referred to as a second invention.
(第二の発明の一態様)  (One aspect of the second invention)
図 3は、 第二の発明であるァクチユエ一夕の一態様例についての縦断面 図である。 図 3において、 円柱状のァクチユエ一夕 2 1は、 膜状の作動 部 2 2と板状の対極 2 3とを筐体 2 4の内側に備えている。 作動部 2 2 には、 リード 2 5 1が作動部表面上の接続部 2 6 1において接続され、 リード 2 5 2が隣接する接続部 2 6 1及び接続部 2 6 2に接続され、 リ ード 2 5 3が隣接する接続部 2 6 2及び接続部 2 6 3に接続されてい る。 前記リード 2 5 1、 2 5 2、 2 5 3は、 直列に接続されて、 外部電 源 2 8に接続される。 対極 2 3もリードを介して電源 2 8に接続されて いる。 電解質 2 9は、 作動部 2 2と対極 2 3に電圧を印加した際に、 電 解質 2 9を介して電圧を印加できるように充填されている。 FIG. 3 is a vertical cross-sectional view of an example of an embodiment of the invention of the second invention. In FIG. 3, a cylindrical actuator 21 includes a film-shaped operating part 22 and a plate-shaped counter electrode 23 inside a housing 24. To the working part 22, a lead 25 1 is connected at a connecting part 26 1 on the surface of the working part, and a lead 25 2 is connected to the adjacent connecting part 26 1 and the connecting part 26 2. The node 253 is connected to the adjacent connection part 262 and connection part 263. The leads 251, 252, 253 are connected in series and Connected to source 28. The counter electrode 23 is also connected to the power supply 28 via a lead. The electrolyte 29 is filled so that a voltage can be applied through the electrolyte 29 when a voltage is applied to the operating part 22 and the counter electrode 23.
第二の発明のァクチユエータは、 リードが作動部に複数接続され、 前 記リードが直列して前記作動部に接続されている。 ァクチユエ一タに強 い振動が与えられる場合には、 図 1のようにリードが並列に接続してい る構造においては、 リ一ドの切断防止のためにリード 5 4が筐体の内側 面に固定または保持されている必要があるが、 図 3のようにリードが作 動部に複数接続され、 前記リードが直列して前記作動部に接続されてい る構造においては、 リード 2 5 2、 2 5 3が筐体の内側面に固定または 保持させる必要がなく、 構造が簡易である。  In the actuator of the second invention, a plurality of leads are connected to the operating section, and the leads are connected in series to the operating section. When strong vibration is applied to the actuator, in a structure where the leads are connected in parallel as shown in Fig. 1, the leads 54 are attached to the inner surface of the housing to prevent the leads from being cut. Although it is necessary to fix or hold the lead, as shown in Fig. 3, in a structure in which a plurality of leads are connected to the working part and the leads are connected in series to the working part, leads 25 2 and 2 53 does not need to be fixed or held on the inner surface of the housing, and the structure is simple.
本願の第二の発明のァクチユエータにおいて、 隣接する接続部間の電 気経路となるリ一ドの長さは、 作動部が最大に伸張した場合に前記リ一 ドが切断されないように、 適用される接続部間の距離であって、 作動部 が最大に伸張した場合の接続部間の距離以上の長さであることが好ま しい。  In the actuator according to the second aspect of the present invention, the length of a lead serving as an electric path between adjacent connecting portions is applied so that the lead is not cut when the operating portion is extended to the maximum. It is preferable that the distance between the connecting parts is equal to or longer than the distance between the connecting parts when the operating part is fully extended.
第二の発明のァクチユエータは、 上述の第一の発明と同様に、 内側に 作動部、 対極及び電解質を含むことができれば、 形状が特に限定される ものではない。  The shape of the actuator of the second invention is not particularly limited as long as the actuator can include the operating portion, the counter electrode, and the electrolyte inside similarly to the first invention described above.
第二の発明のァクチユエータは、 上述の第一の発明の同様に、 前記ァ クチユエータの筐体の材質は、 特に限定されるものではなく、 硬質ブラ スチック、 金属、 ガラス、 セラミ ックス等の硬質材料でもよく、 ウレタ ンゴム、 シリ コンゴム等の可撓性を有する材料でも良い。 前記ァクチュ エータの筐体の壁面を構成する材質は、 可撓性を有する材料であること が好ましい。 また、 ァクチユエ一タに耐衝撃性が要求される用途には、 前記ァクチユエ一夕の筐体の壁面を構成する材料は、 硬質材料であるこ とが好ましい。 · 第二の発明のァクチユエータは、 上述の第一の発明と同様に、 作動部 は、 導電性高分子を含み、 導電性高分子の電解伸縮により作動部が伸縮 するものであれば、 特に限定されるものではない。 前記導電性高分子と しては、 ポリピロ一ル、 ポリチォフェン、 ポリア二リン、 ポリフエニレ ンなど用いることができるが、 分子鎖にピロール及び またはピロ一ル 誘導体を含む導電性高分子であることが好ましい。 In the actuator according to the second invention, as in the first invention described above, the material of the housing of the actuator is not particularly limited, and a hard material such as a hard plastic, metal, glass, or ceramic is used. Alternatively, a flexible material such as urethane rubber or silicon rubber may be used. It is preferable that the material forming the wall surface of the housing of the actuator is a flexible material. Further, in applications where impact resistance is required for the actuator, it is preferable that the material constituting the wall surface of the housing of the actuator is a hard material. · The actuator according to the second aspect of the present invention is the same as the first aspect described above, wherein the operating part includes a conductive polymer, and the operating part expands and contracts due to electrolytic expansion and contraction of the conductive polymer. There is no particular limitation as long as it does. As the conductive polymer, polypyrrol, polythiophene, polyaniline, polyphenylene, and the like can be used, and a conductive polymer containing a pyrrole and / or a pyrrole derivative in a molecular chain is preferable. .
前記作動部は、 上述の第一の発明と同様に、 ドーパントとして P—ト ルエンスルホン酸ナトリウムを含む導電性高分子のような従来の導電 性高分子を含むものであっても良い。 前記作動部は、 上述の第一の発明 と同様に、 前記作動部に含まれる導電性高分子が、 電解重合法による導 電性高分子の製造方法であって、 前記電解重合法が有機化合物を溶媒と して含む電解液を用い、 前記電解液がトリフルォロメタンスルホン酸ィ オン及び/または中心原子に対してフッ素原子を複数含むァニオンを 含む導電性高分子の製造方法により得られた導電性高分子を用いるこ とができる。 前記有機化合物は、 (1) ェ一テル結合、 エステル結合、 炭素一八ロゲン結合及びカーボネート結合からなる化学結合の群から 少なくとも 1つ以上選ばれた化学結合種及び/または (2) ヒドロキシ ル基、 ニトロ基、 スルホン基及び二トリル基からなる官能基の群から少 なくとも 1つ以上選ばれた官能基を分子中に含むことが好ましい。 前記 電解液に、 前記化学結合種及び Zまたは官能基の群から選ばれた 1以上 を分子中に含む有機化合物を溶媒として含み、 トリフルォロメ夕ンスル ホン酸イオン及びノまたは中心原子に対してフッ素原子を複数含むァ 二オンを含む電解液を用いた導電性高分子の製造方法により製造され た導電性高分子が作動部に用いられることが、 1酸化還元サイクルでの 大きな伸縮率が得られるので好ましい。 更に、 得られた導電性高分子の The operating section may include a conventional conductive polymer such as a conductive polymer containing sodium P-toluenesulfonate as a dopant, as in the first aspect of the present invention. The operating part may be a method for producing a conductive polymer by an electrolytic polymerization method, wherein the conductive polymer contained in the operating part is an organic compound, as in the first aspect of the invention. And a conductive polymer obtained by the method for producing a conductive polymer containing trifluoromethanesulfonic acid ion and / or anion containing a plurality of fluorine atoms with respect to the central atom. Functional polymers can be used. The organic compound may include (1) a chemical bond selected from at least one of a chemical bond group consisting of a ether bond, an ester bond, a carbon-18 bond, and a carbonate bond, and / or (2) a hydroxyl group. Preferably, the molecule contains at least one functional group selected from the group consisting of a nitro group, a sulfone group and a nitrile group. The electrolytic solution contains, as a solvent, an organic compound containing in the molecule one or more selected from the group consisting of the chemical bond species and Z or a functional group, and a trifluoromethanesulfonate ion and a fluorine atom with respect to the central atom. The use of a conductive polymer produced by a method for producing a conductive polymer using an electrolytic solution containing anion containing a plurality of dioxins for the working part can provide a large expansion and contraction rate in one oxidation-reduction cycle. preferable. Further, the obtained conductive polymer
1酸化還元サイクル当たりの伸縮率が 16 %以上とするために、 前記電 解液として、 上記のトリフルォロメタンスルホン酸イオン及び Zまたは 中心原子に対してフッ素原子を複数含むァニオンの替りに、化学式( 1)In order to make the expansion rate per oxidation-reduction cycle 16% or more, instead of the above-mentioned trifluoromethanesulfonate ion and anion containing a plurality of fluorine atoms with respect to Z or the central atom, a chemical formula (1)
(CnF (2n + 1) S02) (CmF (2m+1) S02) N— (1) (ここで、 n及び mは任意の整数。 ) (C n F (2n + 1 ) S0 2) (C m F (2m + 1) S0 2) N- (1) ( where, n and m are arbitrary integers.)
で表されるパーフルォロアルキルスルホ二ルイミ ドイオンをァニオン として含む電解液を用いることが好ましい。 Perfluoroalkylsulfonylimid ion represented by Is preferably used.
また、 前記作動部は、 第一の発明と同様に、 導電性高分子及びドーパ ントが含まれる他に、 動作電極としての抵抗値を低下させるために、 金 属線ゃ導電性酸化物などの導電性材料を適宜含むことができる。 また、 前記作動部は、 導電性高分子膜の物理的強度が高いことから、 電解重合 法により得られた導電性高分子膜、 または電解重合法により得られた導 電性高分子膜の積層体であることが好ましい。 また、 前記作動部は、 内 部または表面に導電性金属基体を含む電解重合法により得られた導電 性高分子膜、 またはその積層体であることが好ましい。  In addition, similarly to the first invention, the operating portion includes a conductive polymer and a dopant, and also includes a metal wire, a conductive oxide, or the like in order to reduce a resistance value as an operating electrode. A conductive material can be included as appropriate. In addition, since the operating portion has a high physical strength of the conductive polymer film, the conductive polymer film obtained by the electrolytic polymerization method or the conductive polymer film obtained by the electrolytic polymerization method is laminated. It is preferably a body. Further, it is preferable that the operating section is a conductive polymer film obtained by an electrolytic polymerization method including a conductive metal substrate inside or on a surface thereof, or a laminate thereof.
第二の発明のァクチユエ一夕における対極は、 第一の発明と同様に、 電極として用いることができる導電性材料で形成されているものであ れば、 形状が特に限定されるものではなく、 材質が特に限定されるもの ではなく、 腐食しにくくて加工が容易なことから貴金属であることが好 ましく、 白金または金であることがより好ましい。  The counter electrode of the second embodiment of the present invention is not particularly limited in shape as long as it is formed of a conductive material that can be used as an electrode, as in the first invention. The material is not particularly limited, and is preferably a noble metal, and more preferably platinum or gold, because it is hardly corroded and easy to process.
第二の発明において、 作動部に形成されている接続部は、 第一の発明 と同様に、電源から電圧が印加される。前記接続部は、図 3においては、 接続部 2の一端の面を覆うように接続部 2 6 1が形成され、 接続部 2 6 2、 2 6 3が作動部 2 2の側面の一部にそれぞれ形成されている。 前記 接続部の形状についても、 作動部に電圧が印加されて作動部が電解伸縮 するものであれば、 限定されるものではない。 前記接続部は、 第一の発 明と同様に、 作動部の一端に形成される場合には、 一端の一面を覆うよ うに形成されても良く、一部に形成されても良い。また、前記作動部が、 作動部の側面上に形成される場合には、 側面の一部分に形成されても良 く、 側面外周上を周回するように形成されても良い。  In the second invention, a voltage is applied from a power source to the connection portion formed in the operating portion, as in the first invention. In FIG. 3, the connection portion is formed with a connection portion 261 so as to cover one end surface of the connection portion 2, and the connection portions 262 and 263 are formed on a part of a side surface of the operation portion 22. Each is formed. The shape of the connection portion is not limited as long as the voltage is applied to the operation portion and the operation portion expands and contracts electrolytically. As in the first aspect, when the connecting portion is formed at one end of the operating portion, the connecting portion may be formed so as to cover one surface of the one end or may be formed partially. When the operating portion is formed on the side surface of the operating portion, the operating portion may be formed on a part of the side surface, or may be formed so as to go around the outer periphery of the side surface.
前記接続部は、 第一の発明と同様に、 導電性接着剤、 導電性テープ、 金属クリップ、 金属板や重合時に複合化させる方法を用いることができ る。前記接続部の個数は、複数個であれば特に限定されるものではなく、 作動部に含まれる導電性高分子の種類や作動部の長さに応じて、 適当な 箇所に適宜配置することができる。 また、 前記作動部が導電性高分子と してポリピロールを含む場合には、 隣接した接続部の間隔は、 長さ方向 において 5 c m以下であることが、 ァクチユエ一夕全体として大きな伸 縮性を得ることが容易であるために好ましい。 As in the first invention, a conductive adhesive, a conductive tape, a metal clip, a metal plate, or a method of compounding at the time of polymerization can be used for the connection portion. The number of the connection parts is not particularly limited as long as it is plural, and may be appropriately arranged at an appropriate place according to the type of the conductive polymer contained in the operation part and the length of the operation part. it can. Further, the operating part is made of a conductive polymer. When polypyrrole is contained, the distance between adjacent connecting portions is preferably 5 cm or less in the longitudinal direction, because it is easy to obtain large extensibility as a whole.
第二の発明のァクチユエ一夕に含まれる電解質は、 第一の発明と同様 に、 特に限定されるものではなく、 液状であってもよく、 固体電解質で もよい。 前記電解質が液状である場合には、 水溶媒であっても、 有機溶 媒であっても良いが、 毒性が低く、 揮発する速度が比較的遅いために取 り扱いが容易であるので、 水溶媒であることが好ましい。 前記電解液が 固体電解質である場合には、 電解質中のイオン伝導度が大きいためにゲ ル高分子電解質が好ましい。 前記高分子電解質としては、 に用いるゲル としては、 ポリアクリルアミド、 ポリエチレングリコ一ル、 寒天などを 用いることが、 水溶液電解質と複合させ、 容易にゲル高分子電解質を調 製できるので好ましい。 前記電解質は、 トリフルォロメタンスルホン酸 イオン、 中心原子に対してフッ素原子を複数含むァニオン及び炭素数 3 以下のスルホン酸塩からなる群より少なくとも 1以上選ばれた化合物 を含む電解質とすることが、 ァクチユエ一夕が 1酸化還元サイクル当た りのさらに大きな伸縮を生じることが可能となるので、 好ましい。  The electrolyte contained in the factories of the second invention is not particularly limited, as in the first invention, and may be a liquid or a solid electrolyte. When the electrolyte is in a liquid state, it may be a water solvent or an organic solvent, but since it has low toxicity and a relatively slow volatilization rate, it is easy to handle. Preferably it is a solvent. When the electrolytic solution is a solid electrolyte, a gel polymer electrolyte is preferable because of high ionic conductivity in the electrolyte. As the polymer electrolyte, it is preferable to use polyacrylamide, polyethylene glycol, agar, or the like as the gel used in the above, because the gel polymer electrolyte can be easily prepared by compounding with the aqueous solution electrolyte. The electrolyte may be trifluoromethanesulfonic acid ion, an electrolyte containing at least one compound selected from the group consisting of an anion containing a plurality of fluorine atoms with respect to a central atom and a sulfonate having 3 or less carbon atoms, It is preferable that the actuate is capable of producing a larger expansion and contraction per oxidation-reduction cycle.
図 3においては、作動部 2 2の接続部 2 5 1の反対側の端部(先端部) にシャフトが備えられている。 電解質を介して作動部 2 2と対極 2 3に 電圧が印加されることにより、 前記作動部が電解伸縮し、 前記シャフト も上下運動する。 前記シャフトの運動により、 作動部 2 2の伸縮により 発生するカをァクチユエ一夕の外部に伝えることができるようになつ ている。 なお、 前記電解質が電解液である場合には、 ァクチユエ一夕の 先端部分をキャップすることが好ましい。  In FIG. 3, a shaft is provided at the end (tip) of the operating portion 22 opposite to the connecting portion 25 1. When a voltage is applied to the operating part 22 and the counter electrode 23 through the electrolyte, the operating part expands and contracts electrolytically, and the shaft also moves up and down. Due to the movement of the shaft, the power generated by the expansion and contraction of the operating part 22 can be transmitted to the outside of the factory. In the case where the electrolyte is an electrolyte, it is preferable to cap the tip of the actuator.
第二の発明のァクチユエ一夕は、 第一の発明と同様に、 ァクチユエ一 夕の筐体が可撓性を有する材料で形成され、 ァクチユエ一夕全体が伸縮 運動するものであってもよい。 ァクチユエ一夕全体が伸縮運動する場合 には、 筐体を形成する可撓性材料は、 特に限定されるものではなく、 ァ クチユエ一夕の伸び率に応じて、 適宜選択することができ、 伸び率 5 % 以上の合成樹脂を用いることが好ましく、 伸び率 2 0 %以上の合成樹脂 を用いることがより好ましい。 前記可撓性材料としては、 例えば、 シリ コン系樹脂、 ウレタン系樹脂、 シリコン系ゴム、 ウレタン系ゴム等を用 いることができる。 また、 前記可撓性材料は、 電解質をァクチユエ一夕 外部に漏洩することを防止する機能をも有することから、 耐溶剤性を有 することが好ましく、 シリコン系樹脂、 ウレタン系樹脂、 シリコン系ゴ ム又はウレタン系ゴムを好適に用いることができる。 なお、 前記ァクチ ユエ一夕は、 作動部分が筐体により密閉されている構造を備えている場 合には、 棒状体のような力を伝える手段が筐体を貫通して構造に比べて、 長期の使用による電解質の漏洩が無いので、 人工筋肉等の機械部品とし て用いることに優れている。 In the second aspect of the invention, as in the first aspect, the casing of the first actuator may be formed of a flexible material, and the entire first actuator may extend and contract. In the case where the entirety of the actuary expands and contracts, the flexible material forming the housing is not particularly limited, and can be appropriately selected according to the elongation rate of the actuary. 5% rate It is preferable to use the above synthetic resin, and it is more preferable to use a synthetic resin having an elongation of 20% or more. As the flexible material, for example, silicon-based resin, urethane-based resin, silicon-based rubber, urethane-based rubber, or the like can be used. In addition, since the flexible material also has a function of preventing the electrolyte from leaking to the outside, it is preferable that the flexible material has solvent resistance. Silicon-based resin, urethane-based resin, silicon-based resin Rubber or urethane rubber can be suitably used. Incidentally, in the case of Actu Yue, when the operating part has a structure that is sealed by a housing, a means for transmitting a force such as a rod-like body penetrates the housing, compared to the structure. Since there is no electrolyte leakage due to long-term use, it is excellent for use as mechanical parts such as artificial muscles.
本願の第二の発明のァクチユエ一夕において、 前記の隣接する接続部 間の電気経路であるリードは、 作動部が収縮している場合には弛んだ状 態となり、 弛みの部分が長すぎる場合には、 対極と接触して短絡を生じ 易くなり、 リード同士が絡まることも生じ易くなる。 作動部が 3 %以上 の伸縮を生じる場合には、 本願の第二の発明のァクチユエ一夕を用いる ことも可能であるが、 第一の発明のァクチユエ一夕を用いることが、 対 極と接触して短絡を生じ難く、 リード同士が絡まることも生じ難いので、 好ましい。 上記の第一の発明及び第二の発明のァクチユエ一夕は、 より大きな伸 縮率を得ることが容易であるので、 変位が小さくても用いることができ るスィツチやセンサー等の用途以外に、 変位が大きい用途である人工筋 肉としても好適に用いることがでる。 つまり、 本発明のァクチユエ一夕 は、 変位が小さい用途にしか用いることができなかった導電性高分子を 含むァクチユエ一夕を、 人工筋肉等の変位が大きな用途へと用途拡大を 図ることができる。 また、 第一の発明及び第二の発明は、 リードに緩衝 機能を有するリードを用いてもよい。 前記ァクチユエ一夕は、 リニアァ クチユエ一夕として用いることが可能であり、 例えば、 図 1〜図 3のァ クチユエ一夕の作動部の先端に取り付けられたシャフトに動力伝達対 象部材を接続させることで、 駆動装置として用いることが可能であり、 また、 前記シャフ卜を制御対象物に押圧するようにすることで押圧装置 として用いることができる。 前記ァクチユエ一夕において作動部の 1酸 化還元サイクルあたりの伸縮率が 3 %以上である場合には、 シャフトが 3 %以上伸縮して、 ァクチユエ一夕として 3 %以上の伸縮を得ることが でき、 人工筋肉等の変位が大きな用途へと用途に好適に用いることがで きる。 本発明のァクチユエ一夕は、 電気により導電性高分子が駆動する ァクチユエ一夕であるので、 駆動時に無音であるために、 室内用途装置 における駆動部または押圧部として好適である。 また、 前記ァクチユエ 一夕は、 金属部品が少ないために従来のリニアァクチユエ一夕に比べて 軽量であるので、 位置決め装置、 姿勢制御装置、 昇降装置、 搬送装置、 移動装置、 調節装置、 調整装置、 誘導装置並びに関節装置の駆動部とし て用いること好適に用いることができる。 According to the second aspect of the present invention, the lead, which is an electric path between the adjacent connecting portions, is in a slack state when the operating portion is contracted, and when the slack portion is too long. In this case, a short circuit is likely to occur due to contact with the counter electrode, and the leads are likely to be entangled. When the operating part expands and contracts by 3% or more, it is possible to use the actuator of the second invention of the present application, but using the actuator of the first invention makes contact with the counter electrode. This is preferable because a short circuit is less likely to occur and the leads are less likely to be entangled. According to the first and second aspects of the invention, since it is easy to obtain a larger expansion ratio, the actuators can be used even if the displacement is small. It can also be used suitably as artificial muscle meat, which is an application with large displacement. In other words, the actuary of the present invention can expand the use of an actuate containing a conductive polymer, which could only be used for applications with small displacements, to applications with large displacements such as artificial muscles. . In the first invention and the second invention, a lead having a buffer function may be used. The above-mentioned actuary can be used as a linear actuator, for example, as shown in FIG. 1 to FIG. By connecting the power transmission target member to a shaft attached to the tip of the operating portion of the cutlery, the shaft can be used as a drive device, and the shaft is pressed against the control target. Thus, it can be used as a pressing device. When the expansion ratio per oxidation reduction cycle of the operating part is 3% or more in the above-mentioned actuary, the shaft expands and contracts by 3% or more, and the expansion and contraction of 3% or more as an actuary can be obtained. It can be suitably used for applications where the displacement of artificial muscles or the like is large. The actuator of the present invention is an actuator in which a conductive polymer is driven by electricity, and is silent as it is driven. Therefore, the actuator is suitable as a driving unit or a pressing unit in an indoor use device. In addition, the actuator is lighter than the conventional linear actuator because it has fewer metal parts. Therefore, the positioning device, the attitude control device, the elevating device, the transport device, the moving device, the adjusting device, the adjusting device, and the guiding device are provided. It can be suitably used as a drive unit of a device and a joint device.
上記の第一の発明及び第二の発明のァクチユエ一夕は、 人工筋肉とし て用いるためには、 前記作動部の伸縮率が、 ァクチユエ一夕としての大 きな伸縮を得ることができるために、 1酸化還元サイクル当たりの 3 % 以上、 より好ましくは 5 %以上であることが好ましい。  According to the first and second aspects of the present invention, in order to use it as an artificial muscle, the expansion and contraction rate of the operating portion can obtain a large expansion and contraction as an actuator. It is preferably at least 3%, more preferably at least 5% per oxidation-reduction cycle.
(用途)  (Application)
本願の第一の発明及び第二の発明のァクチユエ一夕は、 人工筋肉、 ロボ ットアームや義手に好適に使用することができる。 また、 マイクロサ一 ジェリー技術におけるピンセット、ハサミ、鉗子、スネア、 レーザメス、 スパチュラ、 クリップなどの医療器具、 検査や補修等を行う各種センサ —若しくは補修用工具など、 健康器具、 湿度計、 湿度計コントロール装 置、 ソフトマニュピユレ一夕一、 水中バルブ、 ソフト運搬装置などのェ 業用機器、 金魚などの水中モ一ビル、 または動く釣り餌や推進ヒレなど のホビー用品などの水中で用いられる物品についても、 本発明のァクチ ユエ一夕を好適に使用することができる。 The first invention and the second invention of the second invention of the present application can be suitably used for artificial muscles, robot arms and artificial hands. In addition, medical equipment such as tweezers, scissors, forceps, snares, laser scalpels, spatulas, clips, and other sensors for microsurgery technology, various sensors for inspection and repair, or repair tools, health equipment, hygrometers, hygrometer control equipment Equipment used in the water, such as equipment, soft manipures, underwater valves, soft transport equipment, and other industrial equipment; underwater vehicles such as goldfish; or hobby equipment such as moving fishing baits and propulsion fins. Also, the actuary of the present invention can be suitably used.
また、 本願の第一の発明及び第二の発明のァクチユエ一夕は、 次の装 置および機器において直線的な駆動力を発生する駆動部若しくは円弧 部からなるトラック型の軌道を移動するための駆動力を発生する駆動 部、 または直線的な動作若しくは曲線的な動作をする押圧部として好適 に用いることができる ; O A機器、 アンテナ、 ベッドや椅子等の人を乗 せる装置、 医療機器、 エンジン、 光学機器、 固定具、 サイドトリマ、 車 両、 昇降器械、 食品加工装置、 清掃装置、 測定機器、 検査機器、 制御機 器、 工作機械、 加工機械、 電子機器、 電子顕微鏡、 電気かみそり、 電動 歯ブラシ、マニピュレータ、 マスト、遊戯装置、 アミユーズメント機器、 乗車用シミュレーション装置、 車両乗員の押さえ装置及び航空機用付属 装備展張装置。 Also, the first invention and the second invention of the present invention are described below. A driving unit that generates a linear driving force or a driving unit that generates a driving force to move a track-type orbit formed by a circular arc, or a pressing unit that performs a linear operation or a curved operation. OA equipment, antennas, equipment for placing people such as beds and chairs, medical equipment, engines, optical equipment, fixtures, side trimmers, vehicles, lifting equipment, food processing equipment, cleaning equipment , Measurement equipment, inspection equipment, control equipment, machine tools, processing machines, electronic equipment, electron microscopes, electric razors, electric toothbrushes, manipulators, masts, play equipment, amusement equipment, riding simulation equipment, vehicle occupant restraint Equipment and equipment extension equipment for aircraft.
前記ァクチユエ一夕は、 例えば、 O A機器や測定機器等の上記機器等 を含む機械全般に用いられる弁、 ブレーキ及びロック装置において、 直 線的な駆動力を発生する駆動部もしくは円弧部からなるトラック型の 軌道を移動するための駆動力を発生する駆動部、 または直線的な動作を する押圧部として用いることができる。 また、 前記の装置、 機器、 器械 等以外においても、 機械機器類全般において、 位置決め装置の駆動部、 姿勢制御装置の駆動部、 昇降装置の駆動部、 搬送装置の駆動部、 移動装 置の駆動部、量や方向等の調節装置の駆動部、軸等の調整装置の駆動部、 誘導装置の駆動部、 及び押圧装置の押圧部として好適に用いることがで きる。 また、 前記ァクチユエ一夕は、 関節装置における駆動部として、 関節中間部材等の直接駆動可能な関節部または関節に回転運動を与え る駆動部に好適に用いることができる。  For example, the actuator is used in a valve, a brake, and a lock device used in a general machine including the above-mentioned devices such as an OA device and a measuring device, and a truck including a drive portion or an arc portion that generates a linear drive force. It can be used as a driving unit that generates a driving force for moving the mold orbit, or as a pressing unit that performs a linear operation. In addition to the above-described devices, devices, instruments, and the like, in general, in machinery and equipment, a driving unit of a positioning device, a driving unit of an attitude control device, a driving unit of a lifting device, a driving unit of a transport device, and a driving device of a moving device. It can be suitably used as a drive unit of an adjustment device for adjusting a part, an amount, a direction, etc., a drive unit of an adjustment device such as a shaft, a drive unit of a guidance device, and a pressing unit of a pressing device. Further, the actuator can be suitably used as a drive unit in a joint device, such as a directly driveable joint unit such as a joint intermediate member or a drive unit that imparts rotational motion to a joint.
前記ァクチユエ一夕は、 例えば、 C A D用プリン夕一等のインクジェ ットプリンターにおけるインクジエツト部分の駆動部、 プリンターの前 記光ビームの光軸方向を変位させる駆動部、 外部記憶装置等のディスク ドライブ装置のヘッド駆動部、 並びに、 プリンタ、 複写機及びファック スを含む画像形成装置の給紙装置における紙の押圧接触力調整手段の 駆動部として好適に用いることができる。  The actuator is, for example, a drive unit for an ink jet part in an inkjet printer such as a CAD printer, a drive unit for displacing the optical axis of the light beam of the printer, and a head of a disk drive device such as an external storage device. It can be suitably used as a driving unit and a driving unit of a paper pressing contact force adjusting unit in a paper feeding device of an image forming apparatus including a printer, a copying machine, and a facsimile.
前記ァクチユエ一夕は、 例えば、 電波天文用の周波数共用アンテナ等 の高周波数給電部を第 2焦点へ移動させるなどの測定部や給電部の移 動設置させる駆動機構の駆動部、 並びに、 車両搭載圧空作動伸縮マスト (テレスコ一ビングマスト) 等のマストゃアンテナにおけるリフト機構 の駆動部に好適に用いることができる。 For example, the above-mentioned actuyue is a frequency sharing antenna for radio astronomy, etc. The measurement unit, such as moving the high-frequency power supply unit to the second focal point, the drive unit of the drive mechanism that moves and installs the power supply unit, and the lift in the mast antenna, such as a vehicle-mounted pneumatic telescopic mast (telescopic mast) It can be suitably used for a drive unit of a mechanism.
前記ァクチユエ一夕は、 例えば、 椅子状のマッサージ機のマッサ一ジ 部の駆動部、 介護用又は医療用ベットの駆動部、 電動リクライニング椅 子の姿勢制御装置の駆動部、 マッサージ機や安楽椅子等に用いられるリ クライニングチェアのバックレスト ·ォットマンの起倒動自在にする伸 縮ロッドの駆動部、 椅子や介護用べッド等における背もたれやレツダレ スト等の人を乗せる家具における可倒式の椅子の背もたれやレツダレ スト或いは介護用べッドの寝台の旋回駆動等に用いられる駆動部、 並び に、 起立椅子の姿勢制御のため駆動部に好適に用いることができる。 前記ァクチユエ一夕は、 例えば、 検査装置の駆動部、 体外血液治療装 置等に用いられている血圧等の圧力測定装置の駆動部、 カテーテル、 内 視鏡装置や鉗子等の駆動部、 超音波を用いた白内障手術装置の駆動部、 顎運動装置等の運動装置の駆動部、 病弱者用ホイストのシャーシの部材 を相対的に伸縮させる手段の駆動部、 並びに、 介護用ベッドの昇降、 移 動や姿勢制御等のための駆動部に好適に用いることができる。  For example, the actuator may be a driving unit of a massage unit of a chair-shaped massage machine, a driving unit of a nursing or medical bed, a driving unit of a posture control device of an electric reclining chair, a massage machine, a comfortable chair, or the like. The backrest of a reclining chair used for a vehicle, the drive of an extension rod that allows the Ottoman to move up and down, and the retractable type of furniture such as chairs and nursing beds that carry a person such as a backrest or a led rest. The present invention can be suitably used as a driving unit used for turning a chair backrest, a dressing rest or a bed for a nursing care bed, and a driving unit for controlling the posture of a standing chair. For example, the actuator may be a driving unit of an inspection device, a driving unit of a pressure measuring device such as a blood pressure used in an extracorporeal blood treatment device, a driving unit of a catheter, an endoscope device, a forceps, or the like. Of a cataract surgery device using a chin, a drive unit of a movement device such as a jaw movement device, a drive unit of means for relatively expanding and contracting members of a chassis of a hoist for the disabled, and raising and lowering and moving a nursing bed It can be suitably used for a driving unit for controlling the posture and the like.
前記ァクチユエ一夕は、 例えば、 エンジン等の振動発生部からフレー ム等の振動受部へ伝達される振動を減衰させる防振装置の駆動部、 内燃 機関の吸排気弁のための動弁装置の駆動部、 エンジンの燃料制御装置の 駆動部、 並びにディーゼルエンジン等のエンジンの燃料供給装置の駆動 部として好適に用いることができる。  The actuator is, for example, a drive unit of a vibration isolator that attenuates vibration transmitted from a vibration generating unit such as an engine to a vibration receiving unit such as a frame, and a valve operating device for an intake and exhaust valve of an internal combustion engine. It can be suitably used as a drive unit, a drive unit of a fuel control device of an engine, and a drive unit of a fuel supply device of an engine such as a diesel engine.
前記ァクチユエ一夕は、 例えば、 手振れ補正機能付き撮像装置の校正 装置の駆動部、 家庭用ビデオカメラレンズ等のレンズ駆動機構の駆動部、 スチルカメラやビデオ力メラ等の光学機器の移動レンズ群を駆動する 機構の駆動部、 カメラのオートフォーカス部の駆動部、 カメラ、 ビデオ カメラ等の撮像装置に用いられるレンズ鏡筒の駆動部、 光学望遠鏡の光 を取り込むォートガイダの駆動部、 立体視力メラや双眼鏡等の 2光学系 を有する光学装置のレンズ駆動機構または鏡筒の駆動部、 光通信、 光情 報処理や光計測等に用いられるフアイバ型波長可変フィルタの波長変 換のファイバに圧縮力を与える駆動部若しくは押圧部、 光軸合せ装置の 駆動部、 並びに、 カメラのシャツタ機構の駆動部に好適に用いることが できる。 For example, the actuator is a driving unit of a calibration device of an imaging device having a camera shake correction function, a driving unit of a lens driving mechanism such as a home video camera lens, and a moving lens group of an optical device such as a still camera or a video camera. Driving mechanism drive unit, camera autofocus unit drive unit, lens barrel drive unit used in imaging devices such as cameras and video cameras, auto-guider drive unit that captures light from optical telescopes, stereoscopic vision cameras and binoculars Etc. 2 optical system Lens drive mechanism or lens barrel drive unit of an optical device having a drive unit, or a drive unit or a pressing unit that applies a compressive force to the fiber for wavelength conversion of a fiber-type wavelength tunable filter used for optical communication, optical information processing, optical measurement, etc. The present invention can be suitably used for a drive unit of an optical axis aligning device and a drive unit of a camera shutter mechanism.
前記ァクチユエ一夕は、 例えば、 ホース金具をホース本体に力シメ固 定する等の固定具の押圧部に好適に用いることができる。  The above-mentioned actuary can be suitably used, for example, for a pressing portion of a fixing tool such as for fixing a hose fitting to a hose body by force.
前記ァクチユエ一夕は、 例えば、 自動車のサスペンションの巻ばね等 の駆動部、 車両のフューエルフィラーリッドを解錠するフユ一エルフィ ラーリツドオープナーの駆動部、 ブルドーザーブレードの伸張及び引つ 込みの駆動の駆動部、 自動車用変速機の変速比を自動的に切り替える為 やクラツチを自動的に断接させる為の駆動装置の駆動部に好適に用い ることができる。  For example, the actuator may be a drive unit such as a winding spring of a vehicle suspension, a drive unit of a fuel filler opener for unlocking a fuel filler lid of a vehicle, and a drive unit for extending and retracting a bulldozer blade. The present invention can be suitably used for a drive unit of a drive unit for automatically changing the gear ratio of a transmission for an automobile or for automatically connecting and disconnecting a clutch.
前記ァクチユエ一夕は、 例えば、 座板昇降装置付車椅子の昇降装置の 駆動部、 段差解消用昇降機の駆動部、 昇降移載装置の駆動部、 医療用べ ッド、 電動ベッド、 電動テーブル、 電動椅子、 介護用ベッド、 昇降テー ブル、 C Tスキャナ、 トラックのキャビンチルト装置、 リフタ一等や各 種昇降機械装置の昇降用の駆動部、 並びに重量物搬送用特殊車両の積み 卸し装置の駆動部に好適に用いることができる。  For example, the actuator may be, for example, a driving unit of a lifting device of a wheelchair with a seat plate lifting device, a driving unit of a lifting device for eliminating a step, a driving unit of a lifting and lowering device, a medical bed, an electric bed, an electric table, and an electric motor. Chairs, nursing beds, lifting tables, CT scanners, truck cabin tilting devices, lifting drives for lifters, etc., and various lifting machinery, as well as loading and unloading devices for heavy vehicles It can be suitably used.
前記ァクチユエ一夕は、 例えば、 食品加工装置の食材吐出用ノズル装 置等の吐出量調整機構の駆動部に好適に用いることができる。  The above-mentioned actuary can be suitably used, for example, as a driving unit of a discharge amount adjusting mechanism such as a food discharge nozzle device of a food processing device.
前記ァクチユエ一夕は、 例えば、 清掃装置の台車や清掃部等の昇降等 の駆動部に好適に用いることができる。  The actuator can be suitably used, for example, in a drive unit for lifting and lowering a truck or a cleaning unit of a cleaning device.
前記ァクチユエ一夕は、 例えば、 面の形状を測定する 3次元測定装置 の測定部の駆動部、 ステージ装置の駆動部、 タイヤの動作特性を検知シ ステム等のセンサ一部分の駆動部、 力センサーの衝撃応答の評価装置の 初速を与える装置の駆動部、 孔内透水試験装置を含む装置のピストンシ リンダのビストン駆動装置の駆動部、 集光追尾式発電装置における仰角 方向へ動かすための駆動部、 気体の濃度測定装置を含む測定装置のサフ アイァレーザー発振波長切替機構のチューニングミラーの振動装置の 駆動部、 プリント基板の検査装置や液晶、 P D Pなどのフラットパネル ディスプレイの検査装置においてァライメントを必要とする場合に X Υ Θ テーブルの駆動部、 電子ビーム (Eビーム) システム又はフォー力 ストイオンビーム (F I B ) システムなどの荷電粒子ビ一ムシステム等 において用いる調節可能なアパーチャ一装置の駆動部、 平面度測定器に おける測定対象の支持装置若しくは検出部の駆動部、 並びに、 微細デバ イスの組立をはじめ、 半導体露光装置や半導体検査装置、 3次元形状測 定装置などの精密位置決め装置の駆動部に好適に使用できる。 For example, the actuator is a driving unit of a measuring unit of a three-dimensional measuring device that measures the shape of a surface, a driving unit of a stage device, a driving unit of a part of a sensor such as a system for detecting a tire operating characteristic, and a force sensor. Drive unit of the device that gives the initial speed of the shock response evaluation device, drive unit of the piston drive device of the piston cylinder of the device including the borehole permeability test device, drive unit for moving in the elevation direction of the concentrating and tracking power generator, gas Of measurement equipment including concentration measurement equipment The drive unit of the oscillation device of the tuning mirror of the eye laser oscillation wavelength switching mechanism, the X Υ Θ table drive unit when alignment is required in the inspection device of the printed circuit board and the inspection device of the flat panel display such as liquid crystal and PDP. A drive unit for an adjustable aperture device used in an electron beam (E-beam) system or a charged particle beam system such as a forced ion beam (FIB) system, a support device for a measurement object in a flatness measuring instrument, or It can be suitably used as a drive unit of a detection unit and a drive unit of a precision positioning device such as a semiconductor exposure device, a semiconductor inspection device, a three-dimensional shape measuring device, as well as assembling of a fine device.
前記ァクチユエ一夕は、 例えば、 電気かみそりの駆動部、 並びに、 電 動歯ブラシの駆動部に好適に用いることができる。  The actuator can be suitably used, for example, as a driving unit for an electric razor and a driving unit for an electric toothbrush.
前記ァクチユエ一タは、 例えば、 三次元物体の撮像デバイス或いは C D、 D V D共用の読み出し光学系の焦点深度調整用デバイスの駆動部、 複数のァクチユエ一夕によって駆動対象面を能動曲面としてその形状 を変形させることによって所望の曲面を近似的に形成して焦点位置を 容易に可変できる可変ミラ一の駆動部、 光ピックアップ等の磁気へッド の少なくとも一方を有する移動ュニッ トを直線移動させることが可能 なディスク装置の駆動部、 リニアテープストレージシステム等の磁気テ —プへッドアクチユエ一夕アセンブリのへッド送り機構の駆動部、 電子 写真方式の複写機、 プリンタ、 ファクシミリなどに適用される画像形成 装置の駆動部、 磁気ヘッド部材等の搭載部材の駆動部、 集束レンズ群を 光軸方向に駆動制御する光ディスク原盤露光装置の駆動部、 光へッドを 駆動するへッド駆動手段の駆動部、 記録媒体に対する情報の記録又は記 録媒体に記録された情報の再生を行う情報記録再生装置の駆動部、 並び に、 回路しや断器 (配電用回路しや断器) の開閉操作の駆動部に好適に 用いることができる。  The actuator is, for example, a drive unit of an imaging device for a three-dimensional object or a device for adjusting the depth of focus of a readout optical system shared by a CD and a DVD, and the shape of a drive target surface is changed to an active curved surface by a plurality of actuators. This makes it possible to linearly move a movable unit having at least one of a drive unit of a variable mirror and a magnetic head such as an optical pickup which can approximately change a focal position by forming a desired curved surface approximately. Drive unit for simple disk drives, magnetic tape drive unit for linear tape storage systems, etc., drive unit for the head feed mechanism of the assembly, image forming apparatus applied to electrophotographic copying machines, printers, facsimile machines, etc. Drive unit, drive unit for mounting members such as magnetic head members, and light that drives and controls the focusing lens group in the optical axis direction. Driving unit for disc master exposure device, driving unit for head driving means for driving optical head, driving unit for information recording / reproducing device for recording information on recording medium or reproducing information recorded on recording medium In addition, it can be suitably used for a drive unit for opening and closing a circuit breaker or a circuit breaker (a power distribution circuit breaker or a circuit breaker).
前記ァクチユエ一タは、 例えば、 次の装置の駆動部として好適に用い る とができる ; ゴム組成物のプレス成形加硫装置の駆動部、 移送され る部品について単列 ·単層化や所定の姿勢への整列をさせる部品整列装 置の駆動部、 圧縮成形装置の駆動部、 溶着装置の保持機構の駆動部、 製 袋充填包装機の駆動部、 マシニングセン夕等の工作機械や射出成形機や プレス機等の成形機械等の駆動部、 印刷装置、 塗装装置やラッカ吹き付 け装置等の流体塗布装置の駆動部、 カムシャフト等を製造する製造装置 の駆動部、 覆ェ材の吊上げ装置の駆動部、 無杼織機における房耳規制体 等の駆動装置、 タフティング機の針駆動システム、 ルーパー駆動システ ム、 およびナイフ駆動システム等の駆動部、 カム研削盤や超精密加工部 品等の部品の研磨を行う研磨装置の駆動部、 織機における綜統枠の制動 装置の駆動部、 織機における緯糸挿通のための経糸の開口部を形成する 開口装置の駆動部、 半導体基板等の保護シート剥離装置の駆動部、 通糸 装置の駆動部、 C R T用電子銃の組立装置の駆動部、 衣料用縁飾り、 テ 一ブルクロスやシートカバー等に用途をもつト一ションレースを製造 するためのトーションレース機におけるシフ夕一フォーク駆動選択リ ニァ制御装置の駆動部、 ァニールウインドウ駆動装置の水平移動機構の 駆動部、 ガラス溶融窯フォアハースの支持アームの駆動部、 カラ一受像 管の蛍光面形成方法等の露光装置のラックを進退動させる駆動部、 ポー ルボンディング装置のトーチアームの駆動部、 ボンディングへッ ドの XY方向への駆動部、 チップ部品のマウントやプローブを使った測定な どにおける部品の実装工程や測定検査工程の駆動部、 基板洗浄装置の洗 浄具支持体の昇降駆動部、 ガラス基板を走査される検出ヘッドを進退さ せる駆動部、 パターンを基板上に転写する露光装置の位置決め装置の駆 動部、 精密加工などの分野においけるサブミクロンのオーダで微小位置 決め装置の駆動部、 ケミカルメカニカルポリシングツールの計測装置の 位置決め装置の駆動部、 導体回路素子や液晶表示素子等の回路デバイス をリソグラフィ工程で製造する際に用いられる露光装置及び走査露光 装置に好適なステージ装置の位置決めのための駆動部、 ワーク等の搬送 あるいは位置決め等の手段の駆動部、 レチクルステージやウェハステー ジ等の位置決めや搬送のための駆動部、 チャンバ内の精密位置決めステ —ジ装置の駆動部、 ケミカルメカニカルポリシングシステムでのワーク ピースまたは半導体ゥェ一八の位置決め装置の駆動部、 半導体のステツ パー装置の駆動部、 加工機械の導入ステーション内に正確に位置決めす る装置の駆動部、 N C機械ゃマシニングセンター等の工作機械等または I C業界のステッパーに代表される各種機器用のパッシブ除振及びァ クティブ除振の除振装置の駆動部、 半導体素子や液晶表示素子製造のリ ソグラフイエ程に使用される露光装置等において光ビーム走査装置の 基準格子板を前記光ビームの光軸方向に変位させる駆動部、 並びに、 コ ンべャの横断方向に物品処理ュニット内へ移送する移送装置。 The actuator can be suitably used, for example, as a drive unit of the following apparatus: a drive section of a rubber composition press-molding vulcanization apparatus; Parts alignment equipment to align to the posture Drive of compression molding equipment, drive of holding mechanism of welding equipment, drive of bag filling and packaging machine, machine tool such as machining center, molding machine such as injection molding machine and press machine, etc. Driving unit, printing unit, driving unit of fluid application device such as coating device and lacquer spraying device, driving unit of manufacturing device for manufacturing camshaft, etc., driving unit of lifting device for covering material, tuft in shuttleless loom Driving device such as ear control body, needle driving system of tufting machine, looper driving system, driving unit such as knife driving system, driving of polishing device for polishing parts such as cam grinder and ultra-precision processing parts Drive unit of the overall frame braking device in the loom, drive unit of the shedding device for forming the warp opening for weft insertion in the loom, drive unit of the protective sheet peeling device for semiconductor substrates, etc. Drive Drive unit for CRT electron gun assembling equipment, clothing trim, torsion lace for torsion lace machine for manufacturing table races and seat covers, etc. The drive unit of the control device, the drive unit of the horizontal moving mechanism of the anneal window drive device, the drive unit of the support arm of the glass melting furnace forehearth, the drive for moving the rack of the exposure device forward and backward, such as the method of forming the fluorescent screen of the empty picture tube Drive unit for the torch arm of the pole bonding machine, drive unit for the bonding head in the XY direction, drive unit for the component mounting process and measurement inspection process in the mounting of chip components and measurement using probes, Driving unit for lifting and lowering the cleaning tool support of the substrate cleaning device, driving unit for moving the detection head that scans the glass substrate, and transferring the pattern onto the substrate The drive of the positioning device of the exposure equipment, the drive of the fine positioning device in the sub-micron order in the field of precision machining, the drive of the positioning device of the measurement device of the chemical mechanical polishing tool, the conductive circuit element, A drive unit for positioning a stage device suitable for an exposure apparatus and a scanning exposure apparatus used in manufacturing a circuit device such as a liquid crystal display element in a lithography process, a drive unit for transporting or positioning a work or the like, a reticle. Drive for positioning and transporting stages and wafer stages, precision positioning stage in chamber Drive for chemical mechanical polishing system, work in chemical mechanical polishing system Driving unit of positioning device for piece or semiconductor wafer, driving unit of semiconductor stepper device, driving unit of device for positioning accurately in the introduction station of processing machine, machine tool such as NC machine, machining center, etc. Light beam scanning in the drive section of passive vibration isolation and active vibration isolation devices for various devices typified by steppers in the IC industry, and in exposure devices used in the lithographic process of manufacturing semiconductor devices and liquid crystal display devices. A drive unit for displacing the reference grating plate of the apparatus in the optical axis direction of the light beam, and a transfer device for transferring the reference lattice plate into the article processing unit in a direction transverse to the conveyor.
前記ァクチユエ一夕は、 例えば、 電子顕微鏡等の走査プローブ顕微鏡 のプローブの位置決め装置の駆動部、 並びに、 電子顕微鏡用試料微動装 置の位置決め等の駆動部に好適に用いることができる。  The actuator can be suitably used, for example, as a drive unit for a probe positioning device of a scanning probe microscope such as an electron microscope, and a drive unit for positioning a fine movement device for a sample for an electron microscope.
前記ァクチユエ一夕は、 例えば、 自動溶接口ポット、 産業用口ポット や介護用ロボッ トを含むロボットまたはマニピュレータにおけるロボ ットアームの手首等に代表される関節機構の駆動部、 直接駆動型以外の 関節の駆動部、 口ポットの指のそのもの、 口ポット等のハンドとして使 用されるスライド開閉式チャック装置の運動変換機構の駆動部、 細胞微 小操作や微小部品の組立作業等において微小な対象物を任意の状態に 操作するためのマイクロマニピュレータの駆動部、 開閉可能な複数のフ ィンガーを有する電動義手等の義肢の駆動部、 ハンドリング用ロポット の駆動部、 補装具の駆動部、 並びにパワースーツの駆動部に好適に用い ることができる。  For example, the actuator is used for a drive unit of a joint mechanism represented by a wrist of a robot arm in a robot or manipulator including an automatic welding pot, an industrial mouth pot, a nursing robot, and a joint other than a direct drive type. The drive unit, the finger of the mouth pot itself, the drive unit of the motion conversion mechanism of the slide opening and closing type chuck device used as a hand of the mouth pot, etc. Driving unit of micromanipulator for operating in arbitrary state, driving unit of prosthesis such as electric prosthesis having multiple openable fingers, driving unit of handling robot, driving unit of prosthesis, and driving of power suit It can be suitably used for parts.
前記ァクチユエ一夕は、 例えば、 サイドトリマの上回転刃又は下回転 刃等を押圧する装置の押圧部に好適に用いることができる。  The actuator can be suitably used, for example, as a pressing portion of a device for pressing an upper rotary blade or a lower rotary blade of a side trimmer.
前記ァクチユエ一夕は、 例えば、 パチンコ等の遊戯装置における役物 等の駆動部、 人形やペット口ポット等のアミューズメント機器の駆動部、 並びに、 乗車用シミュレーション装置のシミュレーション装置の駆動部 に好適に用いることができる。  The above-mentioned actuyue is suitably used, for example, as a drive unit for a character or the like in a game machine such as a pachinko machine, a drive unit for an amusement device such as a doll or a pet mouth pot, and a drive unit for a simulation device of a boarding simulation device. be able to.
前記ァクチユエ一夕は、 例えば、 上記機器等を含む機械全般に用いら れる弁の駆動部に用いることができ、 例えば、 蒸発ヘリウムガスの再液 化装置の弁の駆動部、 ベローズ式の感圧制御弁の駆動部、 綜銑枠を駆動 する開口装置の駆動部、 真空ゲート弁の駆動部、 液圧システム用のソレ ノィド動作型制御バルブの駆動部、 ピポッ卜レバーを用いる運動伝達装 置を組み込んだバルブの駆動部、 ロケットの可動ノズルのバルブの駆動 部、 サックバックバルブの駆動部、 並びに、 調圧弁部の駆動部に好適に 用いることができる。 The actuator can be used, for example, in a drive unit of a valve used in a general machine including the above-described equipment and the like. Drive for bellows-type pressure-sensitive control valve, drive for opening device that drives the pig iron frame, drive for vacuum gate valve, and solenoid-operated control valve for hydraulic system Suitable for drive unit, valve drive unit incorporating a motion transmission device using a pivot lever, rocket movable nozzle valve drive unit, suck back valve drive unit, and pressure control valve drive unit Can be.
前記ァクチユエ一夕は、 例えば、 上記機器等を含む機械全般に用いら れるブレーキの押圧部として用いることができ、 例えば、 非常用、 保安 用、 停留用等のブレーキやエレベータのブレーキに用いて好適な制動装 置の押圧部、 並びに、 ブレーキ構造もしくはブレーキシステムの押圧部 に好適に用いることができる。  The actuator can be used, for example, as a pressing portion of a brake used in a general machine including the above-described devices, and is preferably used for, for example, an emergency, security, parking brake, etc., or an elevator brake. It can be suitably used for a pressing portion of a simple braking device, and a pressing portion of a brake structure or a brake system.
前記ァクチユエ一夕は、 例えば、 上記機器等を含む機械全般に用いら れるロック装置の押圧部として用いることができ、 例えば、 機械的ロッ ク装置の押圧部、 車両用ステアリングロック装置の押圧部、 並びに、 負 荷制限機構及び結合解除機構を合わせ持つ動力伝達装置の押圧部に好 適に用いることができる。 産業上の利用可能性  The actuator can be used, for example, as a pressing portion of a lock device used in a general machine including the above-described devices and the like, for example, a pressing portion of a mechanical locking device, a pressing portion of a steering lock device for a vehicle, Further, it can be suitably used for a pressing portion of a power transmission device having both a load limiting mechanism and a coupling release mechanism. Industrial applicability
本願の第一の発明のァクチユエ一夕は、 作動部、 対極及び電解質を備 えたァクチユエ一夕であって、 前記電解質を介して前記作動部と前記対 極に電圧を印加するためのリードが前記作動部に複数接続され、 前記リ ードのうちの少なくとも 1つのリードが導電性の緩衝体を備えたァク チユエ一夕である。 このァクチユエ一夕を用いることで、 作動部の端部 付近にも十分に電圧を印加することが可能であるので、 作動部の端部に おいても導電性高分子の伸縮性能を十分に発揮することが可能である。 さらに、 作動部が大きく伸縮しても前記緩衝体によりリードにかかる張 力が緩和されるのでリードが切れることがない。 また、 リードが前記緩 衝体を備えることにより、 大きな伸縮量を得るために複数箇所から作動 部に電圧を印加する場合であっても、 ァクチユエ一夕の先端部において も十分に電圧を印加することができるので、 リ一ドによって伸縮が阻害 されて作動部の伸縮が生じないということがなく、 ァクチユエ一タとし て大きな伸縮を得ることができる。 According to a first aspect of the present invention, there is provided an actuating unit including an operating unit, a counter electrode, and an electrolyte, wherein a lead for applying a voltage to the operating unit and the counter electrode through the electrolyte is provided. A plurality of the actuators are connected to each other, and at least one of the leads is an actuator having a conductive buffer. By using this actuator, it is possible to apply a sufficient voltage to the vicinity of the end of the working part, so that the conductive polymer can fully exhibit the stretching performance even at the end of the working part. It is possible to do. Further, even if the operating portion expands and contracts greatly, the tension applied to the lead is reduced by the buffer, so that the lead does not break. In addition, since the lead is provided with the buffer, even when a voltage is applied to the operating portion from a plurality of locations in order to obtain a large amount of expansion and contraction, even if a voltage is applied to the operating portion from a plurality of locations, the tip of the actuator can be used. Since the voltage can be sufficiently applied, the expansion and contraction is not hindered by the lead, and the expansion and contraction of the operating portion does not occur, so that a large expansion and contraction can be obtained as an actuator.
また、 本願の第二の発明のァクチユエ一夕は、 作動部、 対極及び電解 質を備えたァクチユエ一夕であって、 前記電解質を介して前記作動部と 前記対極に電圧を印加するためのリードが前記作動部に複数接続され、 前記リ一ドが直列して作動部に接続されているァクチユエ一夕である。 このァクチユエ一夕を用いることによつても、 作動部の端部付近にも十 分に電圧を印加することが可能であるので、 作動部の端部においても導 電性高分子の伸縮性能を十分に発揮することが可能であり、 伸縮が速い ァクチユエ一夕を得ることができる。 さらに、 作動部が大きく伸縮して もリードにかかる張力が緩和されるので伸縮阻害することがないだけ でなく、 リードが切れることがない。  An actuating device according to a second aspect of the present invention is an actuating device including an operating portion, a counter electrode, and an electrolyte, and a lead for applying a voltage to the operating portion and the counter electrode via the electrolyte. Are actuating units connected to the operating unit in a plurality, and the leads are connected in series to the operating unit. Even with the use of this actuator, it is possible to apply a sufficient voltage to the vicinity of the end of the working part. It can be used to its full potential, and can be used to get a quick stretch. Furthermore, even if the operating portion expands and contracts significantly, the tension applied to the lead is reduced, so that not only does the expansion and contraction be prevented, but also the lead does not break.
上述のように本願の第一の発明及び第二の発明のァクチユエ一夕は、 伸縮が大きい場合であっても、 伸縮を阻害することがないだけでなく、 伸縮によってリードが切れることがないので、 作動部の伸縮率が大きい 場合の用途である人工筋肉に好適である。 また、前記ァクチユエ一夕は、 電気により導電性高分子が駆動するァクチユエ一夕であるので、 駆動時 に無音であるために、 室内用途装置における駆動部または押圧部として 好適である。 また、 前記ァクチユエ一夕は、 金属部品が少ないために従 来のリニアァクチユエ一夕に比べて軽量であるので、 位置決め装置、 姿 勢制御装置、 昇降装置、 搬送装置、 移動装置、 調節装置、 調整装置、 誘 導装置並びに関節装置の駆動部として用いること好適に用いることが できる。  As described above, according to the first invention and the second invention of the second invention, even if the expansion and contraction is large, not only does the expansion and contraction not be hindered, but the lead does not break due to the expansion and contraction. It is suitable for artificial muscles that are used when the elasticity of the operating portion is large. In addition, since the actuator is an actuator in which the conductive polymer is driven by electricity, there is no sound at the time of driving. Therefore, the actuator is suitable as a driving unit or a pressing unit in an indoor use device. In addition, the actuator is lighter than the conventional linear actuator because it has fewer metal parts, so the positioning device, the posture control device, the elevating device, the transport device, the moving device, the adjusting device, and the adjusting device are used. It can be suitably used as a driving unit of a guiding device and a joint device.

Claims

請求の範囲 The scope of the claims
1 . 作動部、 対極及び電解質を備えたァクチユエ一夕であって、 前記 電解質を介して前記作動部と前記対極に電圧を印加するためのリ一ド が前記作動部に複数接続され、 前記リードのうちの少なくとも 1つのリ ードが導電性の緩衝体を備えたァクチユエ一夕。 1. An actuating device including an operating portion, a counter electrode and an electrolyte, wherein a plurality of leads for applying a voltage to the operating portion and the counter electrode via the electrolyte are connected to the operating portion, and the lead At least one of the leads has a conductive buffer.
2 . 前記作動部に接続されたリードが直列するように配され、 前記リ ードのうち少なくとも一つのリードが導電性の緩衝体を備えた請求の 範囲第 1項に記載のァクチユエ一夕。 2. The actuator according to claim 1, wherein the leads connected to the operating portion are arranged in series, and at least one of the leads has a conductive buffer.
3 . 前記緩衝体が弾性体である請求の範囲第 1項に記載のァクチユエ 々 3. The method according to claim 1, wherein the buffer is an elastic body.
4 . 前記弾性体がパネである請求の範囲第 3項に記載のァクチユエ一 夕。 4. The actuary according to claim 3, wherein the elastic body is a panel.
5 . 前記作動部が導電性高分子を含む請求の範囲第 1項に記載のァクチ ユエ一夕。 5. The actuator according to claim 1, wherein the operating portion includes a conductive polymer.
6 . ァクチユエ一夕としての伸縮率が 3 %以上である請求の範囲第 1 項に記載のァクチユエ一夕。 6. The activator according to claim 1, wherein the stretch ratio as the activator is 3% or more.
7 . 請求の範囲第 1項のァクチユエ一タを用いた人工筋肉。 7. An artificial muscle using the actuator according to claim 1.
8 . 作動部、 対極及び電解質を備えたァクチユエ一夕であって、 前記 電解質を介して前記作動部と前記対極に電圧を印加するためのリ一ド が前記作動部に複数接続され、 前記リードが直列して作動部に接続され ているァクチユエ一夕。 8. An actuating device including an operating portion, a counter electrode, and an electrolyte, wherein a plurality of leads for applying a voltage to the operating portion and the counter electrode via the electrolyte are connected to the operating portion, and the lead is provided. Are connected in series to the actuator I'm having fun.
9 . 前記作動部が導電性高分子を含む請求の範囲第 8項に記載のァクチ ユエ一夕。 9. The actuator according to claim 8, wherein the operating portion includes a conductive polymer.
1 0 . ァクチユエ一夕としての伸縮率が 3 %以上である請求の範囲第 8項に記載のァクチユエ一夕。 10. The actuary according to claim 8, wherein the stretch ratio as the actuir is 3% or more.
1 1 . 請求の範囲第 8項に記載のァクチユエ一夕を用いた人工筋肉。 11. An artificial muscle using the actiyue as set forth in claim 8.
1 2 . 請求の範囲第 1項のァクチユエ一夕を駆動部に用いた位置決め 装置、 姿勢制御装置、 昇降装置、 搬送装置、 移動装置、 調節装置、 調整 装置、 誘導装置、 または関節装置。 12. A positioning device, an attitude control device, an elevating device, a transport device, a moving device, an adjusting device, an adjusting device, a guiding device, or an articulating device using the actuator of claim 1 as a driving portion.
1 3 . 請求の範囲第 1項のァクチユエ一夕を押圧部に用いた押圧装置。 13. A pressing device using the actuator of claim 1 for the pressing portion.
1 4 . 請求の範囲第 8項のァクチユエ一夕を駆動部に用いた位置決め 装置、 姿勢制御装置、 昇降装置、 搬送装置、 移動装置、 調節装置、 調整 装置、 誘導装置、 または関節装置。 14. A positioning device, an attitude control device, an elevating device, a transport device, a moving device, an adjusting device, an adjusting device, a guiding device, or a joint device using the actuator according to claim 8 as a driving unit.
1 5 . 請求の範囲第 8項のァクチユエ一夕を押圧部に用いた押圧装置。 15. A pressing device using the actuator of claim 8 for the pressing portion.
PCT/JP2004/000999 2003-01-31 2004-02-02 Actuator WO2004068690A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003025009 2003-01-31
JP2003-025009 2003-01-31

Publications (1)

Publication Number Publication Date
WO2004068690A1 true WO2004068690A1 (en) 2004-08-12

Family

ID=32820781

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2004/000999 WO2004068690A1 (en) 2003-01-31 2004-02-02 Actuator

Country Status (1)

Country Link
WO (1) WO2004068690A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7679268B2 (en) 2005-08-05 2010-03-16 Panasonic Corporation Polymer actuator having active member layer that expands or contracts upon application of electric field
CN107401489A (en) * 2017-08-18 2017-11-28 张雄志 A kind of engine that thrust is produced using laser

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000083389A (en) * 1998-06-25 2000-03-21 Matsushita Electric Works Ltd Actuator
JP2000133854A (en) * 1998-10-27 2000-05-12 Matsushita Electric Works Ltd Actuator
JP2002345267A (en) * 2002-03-26 2002-11-29 Olympus Optical Co Ltd Piezoelectric actuator device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000083389A (en) * 1998-06-25 2000-03-21 Matsushita Electric Works Ltd Actuator
JP2000133854A (en) * 1998-10-27 2000-05-12 Matsushita Electric Works Ltd Actuator
JP2002345267A (en) * 2002-03-26 2002-11-29 Olympus Optical Co Ltd Piezoelectric actuator device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7679268B2 (en) 2005-08-05 2010-03-16 Panasonic Corporation Polymer actuator having active member layer that expands or contracts upon application of electric field
CN107401489A (en) * 2017-08-18 2017-11-28 张雄志 A kind of engine that thrust is produced using laser

Similar Documents

Publication Publication Date Title
JP2004162035A (en) Method for producing conductive polymer, conductive polymer, conductive polymer molding and conductive molymer, laminate and apparatus using them
EP1550689B1 (en) Process for producing conductive polymer
JP5838448B2 (en) Conductive polymer composite structure, method for producing conductive polymer composite structure, and actuator element
JP4732678B2 (en) Actuator, manufacturing method of actuator, and electrolytic expansion / contraction method of actuator
JP4447343B2 (en) Drive mechanism and operating method thereof
WO2004041914A1 (en) Conductive polymer composite structure
JP2008086185A (en) Polymer actuator element and manufacturing method therefor
JP4897345B2 (en) Method for driving polymer actuator element, actuator and method for manufacturing the same
WO2007007616A1 (en) Direct driven polymer actuator
WO2004075388A1 (en) Drive mechanism
JP4048236B2 (en) Conductive polymer composite structure, laminate, and method for producing conductive polymer
JP5181143B2 (en) Planar devices
JP4727193B2 (en) Actuator element including conductive polymer molding
JP4405824B2 (en) Cylindrical conductive polymer molded product, manufacturing method thereof, actuator using the same, and use thereof
JP2008236950A (en) Opening and closing actuator
WO2005004321A1 (en) Actuator element
JP2005006490A (en) Actuator
JP2004254497A (en) Actuator and its use
WO2004068690A1 (en) Actuator
WO2005026230A1 (en) Method for producing electroconductive polymer
JP4619716B2 (en) Actuator element manufacturing method and actuator element
WO2004061156A1 (en) Method for electroless plating
WO2008026534A1 (en) Polymer actuator element and method of producing the same
JP5712372B2 (en) Conductive polymer composite structure, method for producing conductive polymer composite structure, and actuator element
WO2004075389A1 (en) Actuator

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP