WO2004055334A1 - A method for cleaning a stationary gas turbine unit during operation - Google Patents

A method for cleaning a stationary gas turbine unit during operation Download PDF

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Publication number
WO2004055334A1
WO2004055334A1 PCT/SE2003/001674 SE0301674W WO2004055334A1 WO 2004055334 A1 WO2004055334 A1 WO 2004055334A1 SE 0301674 W SE0301674 W SE 0301674W WO 2004055334 A1 WO2004055334 A1 WO 2004055334A1
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WO
WIPO (PCT)
Prior art keywords
compressor
spray
inlet
air
drops
Prior art date
Application number
PCT/SE2003/001674
Other languages
French (fr)
Inventor
Peter Asplund
Carl-Johan Hjerpe
Original Assignee
Gas Turbine Efficiency Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gas Turbine Efficiency Ab filed Critical Gas Turbine Efficiency Ab
Priority to DE60314446T priority Critical patent/DE60314446T2/en
Priority to EP03759149A priority patent/EP1570158B1/en
Priority to US10/538,672 priority patent/US7428906B2/en
Priority to AU2003275753A priority patent/AU2003275753A1/en
Publication of WO2004055334A1 publication Critical patent/WO2004055334A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/02Cleaning by the force of jets or sprays
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D25/00Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
    • F01D25/002Cleaning of turbomachines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04DNON-POSITIVE-DISPLACEMENT PUMPS
    • F04D29/00Details, component parts, or accessories
    • F04D29/70Suction grids; Strainers; Dust separation; Cleaning
    • F04D29/701Suction grids; Strainers; Dust separation; Cleaning especially adapted for elastic fluid pumps
    • F04D29/705Adding liquids

Definitions

  • the invention relates to a method for cleaning a stationary gas turbine unit during operation, of the type revealed in the preamble to claim 1.
  • the invention thus relates to washing gas turbines equipped with axial or radial compressors.
  • Gas turbines comprise a compressor for compressing air, a combustion chamber for burning fuel together with the compressed air, and a turbine to drive the compressor.
  • the compressor comprises one or a plurality of compression steps, each compression step consisting of a rotor disc having blades and a following stator disc with guide vanes.
  • One object of the invention is to provide a method for cleaning blades and vanes from deposits of foreign substances by injecting fluid drops into the air flow upstream of the compressor.
  • the fluid drops are transported with the air flow into the compressor where they collide with the surface of the rotor blades and guide vanes, whereupon the deposits are detached by the chemical and mechanical forces of the cleaning fluid.
  • the invention is performed on gas turbines during operation.
  • the gas turbine may be a part of a power plant, pump station, ship or vehicle.
  • Air contains particles in the form of aerosols which are drawn into the compressor of the gas turbine with the air flow. A majority of these particles accompany the air flow and leave the gas turbine with the exhaust gases. However, some particles tend to adhere to components in the channels of the gas turbine. These particles form a deposit on the components, thus deteriorating the aerodynamic properties.
  • the coating causes a change in the boundary layer flow along the surface. The coating, i.e. the increased roughness of the surface, results in pressure step-up losses and a reduction in the amount of air the compressor compresses. For the compressor as a whole this entails deteriorated efficiency, reduced mass flow and reduced final pressure.
  • Another cleaning method is based on wetting the compressor components with a washing fluid by spraying drops of the washing fluid into the air intake to the compressor.
  • the washing fluid may consist of water or water mixed with chemicals.
  • the gas turbine rotor is rotated with the aid of the start motor of the gas turbine.
  • This method is known as “crank washing” or “off-line washing” and is characterised in that the gas turbine does not burn fuel during cleaning.
  • the spray is produced by the cleaning fluid being pumped through nozzles which atomize the fluid.
  • the nozzles are installed on the walls of the air duct upstream of the compressor inlet, or are installed on a frame placed temporarily in the intake duct.
  • the method results in the compressor components being drenched in cleaning fluid and the dirt particles being detached by the chemical effects of the chemicals, as well as mechanical forces deriving from rotation of the rotor.
  • the method is considered both efficient and useful.
  • the rotor speed during crank washing is a fraction of that at normal operation of the gas turbine.
  • An important feature with crank washing is that the rotor rotates at low speed so that there is little risk of mechanical damage.
  • a method known from US-A-5011540 is based on the compressor components being wetted with cleaning fluid while the gas turbine is in operation, i.e. while fuel is being burned in the combustion chamber of the gas turbine unit.
  • the method is known as "on-line washing" and, in common, with crank washing, a washing fluid is injected upstream of the compressor. This method is not as efficient as crank washing. The lower efficiency is a result of poorer cleaning mechanisms prevailing at higher rotor speeds and high air speeds when the gas turbine is in operation.
  • a specific quantity of washing fluid should be injected since too much washing fluid may cause mechanical damage in the compressor and too little washing fluid results in poor soaking of the compressor components.
  • washing fluid must not only be caught by the blade surface and guide vanes of the first step, it must also be distributed to the compressor step downstream of the first step. If a large proportion of the washing fluid is caught by the blade surface of the first step, the washing fluid will be moved to the periphery of the rotor due to centrifugal forces and will therefore no longer participate in the cleaning process.
  • the object of the invention is to fully or partially eliminate said problems.
  • Figure 1 shows the compressor and the air duct upstream of the compressor inlet.
  • Figure 2 shows a section through the air duct before the compressor inlet.
  • Figure 3A shows a section through the air duct before the compressor inlet, indicating a feasible placing of the nozzle for injecting washing fluid.
  • Figure 3B shows a section through an air duct before the compressor inlet, indicating an alternative placing of the nozzle for injecting washing fluid, and exemplifies a preferred embodiment of the invention.
  • Figure 4 shows flow patterns in a compressor step by illustration of "velocity triangles”.
  • Figure 5 shows velocity triangles for a drop of washing fluid from a nozzle under low pressure.
  • Figure 6 shows velocity triangles for a drop of washing fluid from a nozzle under high pressure and exemplifies a preferred embodiment of the invention.
  • FIG. 1 shows the design of an air duct for a gas turbine. The direction of flow is indicated by arrows. The surrounding air A is assumed to have no initial velocity. After having passed weather protection 11, filter 12 and dirt trap 13 the air velocity at B is 10 m/s. The air velocity increases further at C to 40 m/s as a result of the decreasing cross sectional area of the air duct. Immediately prior to the first blade E of the compressor the air passes a duct especially designed to accelerate the air to extremely high speeds. Between its inlet C and its outlet E the acceleration duct 15 is called the "bell mouth" 15. The purpose of the bell mouth is to accelerate the air to the speed required for the compressor to perform its compression work.
  • the bell mouth 15 is connected to the duct 19 by the joint 17.
  • the bell mouth 15 is connected to the compressor 16 by the joint 18.
  • the velocity at E varies for different gas turbine designs. For large stationary gas turbines the speed at E is typically 100 m/s, while for small flight derivative turbines the speed at E may be 200 m/s.
  • D is a point lying approximately mid-way between the inlet C and the outlet E.
  • A, B and C are low-speed areas while D and E are high-speed areas. Nozzles for washing fluid may be installed either in the low-speed area C or the high-speed area D.
  • nozzles operating under a low pressure drop so-called "low pressure nozzles” can be used.
  • the spray will penetrate to the core of the air flow and transport the drops to the compressor intake.
  • a drawback with installation in area C The air and drops are accelerated in the bell mouth. The forces acting on the drops will result in different final speeds for the drops and the air when acceleration is complete at E.
  • a “slip speed” occurs at E where slip speed is defined as the difference between the drop speed and the air speed.
  • a “slip ratio” is defined as the ratio between the drop speed and the air speed, the drop speed constituting numerator and the air speed constituting denominator. This is explained in more detail in the following.
  • the nozzles may be installed in the high-velocity area D.
  • nozzles are preferred which operate under high pressure drop, so-called "high-pressure nozzles".
  • the nozzle is directed substantially parallel to the air flow.
  • the spray produced by the nozzle has high velocity and the abrasive speed between fluid and air flow that occurs during acceleration in the bell mouth can be substantially eliminated since drops and air flow have substantially the same speed. If, instead, the nozzles in area D were to operate under low pressure the spray would not achieve sufficient impetus to penetrate into the core of the air jet. Part of the fluid is caught by the boundary layer flow along the wall of the duct where it forms a film of liquid that is transported to the compressor by the thrust of the air flow.
  • the present invention relates to installing high-pressure nozzles in area D.
  • high pressure nozzles means nozzles operating with a pressure drop of more than 120 bar, preferably 140 bar and maximally 210 bar.
  • the upper limit is set by the risk of the drops acquiring such impetus that they might damage material surfaces in the turbine unit. In practice, an upper limit is 210 bar.
  • One object of the invention is to increase the impetus of the spray by the nozzle operating under high pressure.
  • Liquid sprayed into an air duct is subjected to a compressive force by the air flow in the duct.
  • the force on the spray is the result of the projected surface of the spray against the air flow, the force of inertia of the drops and the dynamic force of the air flow on the spray.
  • the projected surface of the spray is in turn the result of the outlet velocity of the fluid, drop size and density of the spray.
  • One skilled in the art can calculate that a given flow of liquid through the nozzle will increase the impulse of the spray produced if the outlet velocity of the fluid increases.
  • the increased outlet velocity is achieved by means of a high pressure.
  • Another object of the invention is to avoid a liquid film on the surface of the air duct by using a spray with a high impulse. It has been observed in actual gas turbine installations that a spray injected in an area of the air duct where high velocity prevails will not fully penetrate into the core of the air flow. Some of the liquid is caught by the boundary layer flow and forms a liquid film that is transported into the compressor, impelled by the thrust of the air flow. This liquid will contribute to cleaning the compressor blades and guide vanes and may cause mechanical damage. Formation of the liquid film can be avoided by injecting liquid through the nozzle under high pressure.
  • a third object of the invention is to reduce the abrasive speed.
  • Air drawn into the bell mouth is subjected to acceleration. If the air contains fluid drops originating from a spray, for instance, the drops will also be accelerated.
  • the velocity achieved by the drops in relation to the air speed is a result of cross-acting forces.
  • an aerodynamic flow resistance results in a retarding force that acts on the drops.
  • a force of inertia acts on the drops as a result of the acceleration.
  • the retarding force is directed oppositely to the force of inertia.
  • the compressor is designed to compress the incoming air.
  • the rotor energy In the rotor energy is converted to kinetic energy by the rotor blade.
  • the kinetic energy In the following stator guide vane the kinetic energy is converted to an increase in pressure through a decrease in speed.
  • the compressor is designed for operation about a design point.
  • the aerodynamics around the blades and the guide vanes are most favourable at the design point.
  • the actual operating point of the compressor will deviate from the design operating point.
  • Less favourable aerodynamic conditions occur in the compressor when the actual operating point deviates from the design point. Normally this only causes a deteriorated degree of efficiency in the compressor, a certain deterioration in air capacity, and a somewhat lower pressure ratio.
  • the actual operating point may deviate so much from the design operating point that the compressor ceases to operate. In short, this means that in order to achieve satisfactory compression the air velocity in the compressor inlet must be adjusted to the design and operating conditions.
  • Yet another object of the invention is for the washing fluid to penetrate into the compressor past the first step.
  • the present invention offers new methods for the user that have never previously been available to him.
  • Figure 2 shows the part of the inlet duct where the air accelerates to extremely high speeds, known as the bell mouth.
  • This part of the duct is tubular and converges towards its outlet, i.e. towards the inlet into the compressor.
  • the flow direction is indicated by arrows.
  • the purpose of the bell mouth is to accelerate the air to the speed necessary for the compressor to perform the compression work.
  • the bell mouth is symmetrical about the axis 26.
  • the outer casing 20 and the inner casing 21 form the geometry of the bell mouth.
  • Air enters the bell mouth at the cross section 22 and leaves at the cross section 25.
  • the cross section 25 is equivalent to the first guide vane or rotor blade of the compressor.
  • the velocity at the cross section 22 is 40 m/s.
  • Figures 3A and 3B show alternative installations of the nozzles on one and the same bell mouth. Identical parts are given the same designations as in Figure 2.
  • Nozzle 31 in Figure 3A is installed upstream of the inlet to the bell mouth.
  • the air speed is low here and low-pressure nozzles are to be preferred. When the liquid pressure is low the spray speed will be low.
  • the drop velocity at cross section 33 may be assumed to be substantially equivalent to the air speed. When the drops are carried towards the compressor with the air flow, they are subjected to an increase in speed.
  • the air speed at cross section 33 is 40 m/s and at the outlet 34 it is 200 m/s. Calculation of the equations for the slip speeds gives that the drop that had a speed of 40 m/s at the inlet 33 will have assumed a speed of 130 m/s at the outlet 34. The slip ratio is thus 0.65.
  • the nozzle in Figure 3B is installed at cross section 23 which is in the highspeed area.
  • a high-pressure nozzle is preferable.
  • the nozzle is directed substantially parallel to the air flow.
  • a nozzle operating at the pressure relevant in this invention has an outlet speed of 120 m/s. Calculation of the particle trajectory for the drop in accordance with the equations for the abrasive mechanism gives a speed of 190 m/s at the outlet 34. The slip ratio is thus 0.95.
  • Figure 4 shows the aerodynamics around rotor blades and stator guide vanes in an axial compressor.
  • the blades and guide vanes are shown from the periphery of the rotor towards its centre.
  • Rotor blade 41 is one of many blades constituting a rotor disc 410.
  • the rotor rotates in the direction indicated by the arrow 43.
  • the stator guide vane 42 is one of many guide vanes constituting a stator disc 420.
  • the stator guides are fixed in the compressor casing.
  • a rotor disc and following stator disc constitute a compression step.
  • Air speeds are illustrated as vectors where the length of the vector is proportional to the speed, and the direction of the vector is the direction of the air flow.
  • Figure 4 shows the air flow through a compressor step.
  • the rotor disc rotates with the tangential speed vector 45.
  • Relative vector 46 shows the movement of the air flowing into the space between the rotor blades.
  • Vector 47 shows the movement of the air leaving the rotor disc.
  • Vector 45 is the tangential speed of the rotor.
  • Relative vector 48 shows the movement of the air flowing into the space between the guide vanes.
  • Vector 49 shows the movement of the air leaving the stator disc.
  • Figure 5 illustrates the case with low-pressure nozzles installed in the low- speed area of the air intake. Identical parts have been given the same designations as in Figure 4.
  • Vector 54 shows the movement of a drop approaching the rotor disc with a slip ratio of 0.65.
  • Vector 45 is the tangential speed of the rotor.
  • Relative vector 56 shows the movement of a drop moving towards the space between the rotor blades. By extending the vector 56 as indicated by the broken line 57 it can be seen that the drop collides with the blade at point 58.
  • Figure 6 illustrates the case with the high-pressure nozzle installed in the high-speed area of the air intake. Identical parts have been given the same designations as in Figure 4.
  • Vector 64 shows the movement of a drop approaching the rotor disc with a slip ratio of 0.95.
  • Vector 45 is the tangential speed of the rotor.
  • Relative vector 66 shows the movement of a drop moving towards the space between the rotor blades. By extending the vector 66 as indicated by the broken line 67 it is evident that the drop will not collide with the blade. This drop will continue past the rotor disc where corresponding analysis will determine whether the drop will collide with a guide vane in the stator.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)
  • Control Of Turbines (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

A method for cleaning a stationary gas turbine unit during operation, said unit comprising a turbine, a compressor (16) driven by the turbine, having an inlet (E), an air inlet duct arranged upstream of the air inlet of the compressor, the inlet duct having a part (15) of the duct adjoining the inlet of the compressor and having decreasing cross section in the flow direction in order to give the air flow a final velocity at the inlet (E) to the compressor (16), a spray of cleaning fluid being introduced in the inlet duct (15). The cleaning fluid is forced through a spray nozzle (32) with a pressure drop exceeding 120 bar to form a spray the drops of which have a mean size that is less than 150 μm, the spray being directed substantially parallel to and in the same direction as the direction of the air flow. The spray is introduced at a position (23) in the duct section (16) where the air velocity is at least 40 per cent of the final velocity at the compressor inlet (E), so that the drops of the liquid spray are caused to acquire a slip ratio of at least 0.8 at the compressor inlet (E).

Description

A method for cleaning a stationary gas turbine unit during operation
The invention relates to a method for cleaning a stationary gas turbine unit during operation, of the type revealed in the preamble to claim 1.
The invention thus relates to washing gas turbines equipped with axial or radial compressors. Gas turbines comprise a compressor for compressing air, a combustion chamber for burning fuel together with the compressed air, and a turbine to drive the compressor. The compressor comprises one or a plurality of compression steps, each compression step consisting of a rotor disc having blades and a following stator disc with guide vanes.
One object of the invention is to provide a method for cleaning blades and vanes from deposits of foreign substances by injecting fluid drops into the air flow upstream of the compressor. The fluid drops are transported with the air flow into the compressor where they collide with the surface of the rotor blades and guide vanes, whereupon the deposits are detached by the chemical and mechanical forces of the cleaning fluid. The invention is performed on gas turbines during operation. The gas turbine may be a part of a power plant, pump station, ship or vehicle.
Background art
Gas turbines consume large quantities of air. Air contains particles in the form of aerosols which are drawn into the compressor of the gas turbine with the air flow. A majority of these particles accompany the air flow and leave the gas turbine with the exhaust gases. However, some particles tend to adhere to components in the channels of the gas turbine. These particles form a deposit on the components, thus deteriorating the aerodynamic properties. As with increased roughness of the surface, the coating causes a change in the boundary layer flow along the surface. The coating, i.e. the increased roughness of the surface, results in pressure step-up losses and a reduction in the amount of air the compressor compresses. For the compressor as a whole this entails deteriorated efficiency, reduced mass flow and reduced final pressure. Modern gas turbines are equipped with filters to filter the air in front of the entrance to the compressor. These filters can catch only some of the particles. To maintain economic operation of the gas turbine, therefore, it has been found necessary to regularly clean the surface of the compressor components in order to maintain good aerodynamic properties.
Various methods for cleaning gas turbine compressors are already known. Injecting crushed nut shells into the air flow to the compressor has been found practically feasible. The drawback is that the nut-shell material may find its way into the internal air system of the gas turbine and result in clogging of ducts and valves.
Another cleaning method is based on wetting the compressor components with a washing fluid by spraying drops of the washing fluid into the air intake to the compressor. The washing fluid may consist of water or water mixed with chemicals. In the known cleaning method the gas turbine rotor is rotated with the aid of the start motor of the gas turbine. This method is known as "crank washing" or "off-line washing" and is characterised in that the gas turbine does not burn fuel during cleaning. The spray is produced by the cleaning fluid being pumped through nozzles which atomize the fluid. The nozzles are installed on the walls of the air duct upstream of the compressor inlet, or are installed on a frame placed temporarily in the intake duct.
The method results in the compressor components being drenched in cleaning fluid and the dirt particles being detached by the chemical effects of the chemicals, as well as mechanical forces deriving from rotation of the rotor. The method is considered both efficient and useful. The rotor speed during crank washing is a fraction of that at normal operation of the gas turbine. An important feature with crank washing is that the rotor rotates at low speed so that there is little risk of mechanical damage.
A method known from US-A-5011540 is based on the compressor components being wetted with cleaning fluid while the gas turbine is in operation, i.e. while fuel is being burned in the combustion chamber of the gas turbine unit. The method is known as "on-line washing" and, in common, with crank washing, a washing fluid is injected upstream of the compressor. This method is not as efficient as crank washing. The lower efficiency is a result of poorer cleaning mechanisms prevailing at higher rotor speeds and high air speeds when the gas turbine is in operation. A specific quantity of washing fluid should be injected since too much washing fluid may cause mechanical damage in the compressor and too little washing fluid results in poor soaking of the compressor components. Another problem with the on-line washing method is that the washing fluid must not only be caught by the blade surface and guide vanes of the first step, it must also be distributed to the compressor step downstream of the first step. If a large proportion of the washing fluid is caught by the blade surface of the first step, the washing fluid will be moved to the periphery of the rotor due to centrifugal forces and will therefore no longer participate in the cleaning process.
The object of the invention is to fully or partially eliminate said problems.
This object is achieved with the invention. The invention is defined in claim 1 and embodiments thereof are defined in the subordinate claims. Further developments of the cleaning method in accordance with the invention are revealed in the dependent claims.
The invention will be described in the following by way of example with reference to the accompanying drawings.
Brief description of the drawings
Figure 1 shows the compressor and the air duct upstream of the compressor inlet.
Figure 2 shows a section through the air duct before the compressor inlet. Figure 3A shows a section through the air duct before the compressor inlet, indicating a feasible placing of the nozzle for injecting washing fluid.
Figure 3B shows a section through an air duct before the compressor inlet, indicating an alternative placing of the nozzle for injecting washing fluid, and exemplifies a preferred embodiment of the invention.
Figure 4 shows flow patterns in a compressor step by illustration of "velocity triangles".
Figure 5 shows velocity triangles for a drop of washing fluid from a nozzle under low pressure.
Figure 6 shows velocity triangles for a drop of washing fluid from a nozzle under high pressure and exemplifies a preferred embodiment of the invention.
Description of the invention
Air drawn into the compressor is accelerated to high speeds in the air duct prior to compression. Figure 1 shows the design of an air duct for a gas turbine. The direction of flow is indicated by arrows. The surrounding air A is assumed to have no initial velocity. After having passed weather protection 11, filter 12 and dirt trap 13 the air velocity at B is 10 m/s. The air velocity increases further at C to 40 m/s as a result of the decreasing cross sectional area of the air duct. Immediately prior to the first blade E of the compressor the air passes a duct especially designed to accelerate the air to extremely high speeds. Between its inlet C and its outlet E the acceleration duct 15 is called the "bell mouth" 15. The purpose of the bell mouth is to accelerate the air to the speed required for the compressor to perform its compression work. The bell mouth 15 is connected to the duct 19 by the joint 17. The bell mouth 15 is connected to the compressor 16 by the joint 18. The velocity at E varies for different gas turbine designs. For large stationary gas turbines the speed at E is typically 100 m/s, while for small flight derivative turbines the speed at E may be 200 m/s. D is a point lying approximately mid-way between the inlet C and the outlet E. Within the scope of this invention A, B and C are low-speed areas while D and E are high-speed areas. Nozzles for washing fluid may be installed either in the low-speed area C or the high-speed area D.
One aim of installing nozzles in area C is that nozzles operating under a low pressure drop - so-called "low pressure nozzles" can be used. The spray will penetrate to the core of the air flow and transport the drops to the compressor intake. However, there is a drawback with installation in area C. The air and drops are accelerated in the bell mouth. The forces acting on the drops will result in different final speeds for the drops and the air when acceleration is complete at E. A "slip speed" occurs at E where slip speed is defined as the difference between the drop speed and the air speed. A "slip ratio" is defined as the ratio between the drop speed and the air speed, the drop speed constituting numerator and the air speed constituting denominator. This is explained in more detail in the following.
Alternatively the nozzles may be installed in the high-velocity area D. In the high-velocity area nozzles are preferred which operate under high pressure drop, so-called "high-pressure nozzles". The nozzle is directed substantially parallel to the air flow. The spray produced by the nozzle has high velocity and the abrasive speed between fluid and air flow that occurs during acceleration in the bell mouth can be substantially eliminated since drops and air flow have substantially the same speed. If, instead, the nozzles in area D were to operate under low pressure the spray would not achieve sufficient impetus to penetrate into the core of the air jet. Part of the fluid is caught by the boundary layer flow along the wall of the duct where it forms a film of liquid that is transported to the compressor by the thrust of the air flow. The present invention relates to installing high-pressure nozzles in area D. The term "high pressure nozzles" means nozzles operating with a pressure drop of more than 120 bar, preferably 140 bar and maximally 210 bar. The upper limit is set by the risk of the drops acquiring such impetus that they might damage material surfaces in the turbine unit. In practice, an upper limit is 210 bar.
One object of the invention is to increase the impetus of the spray by the nozzle operating under high pressure. Liquid sprayed into an air duct is subjected to a compressive force by the air flow in the duct. The force on the spray is the result of the projected surface of the spray against the air flow, the force of inertia of the drops and the dynamic force of the air flow on the spray. The projected surface of the spray is in turn the result of the outlet velocity of the fluid, drop size and density of the spray. One skilled in the art can calculate that a given flow of liquid through the nozzle will increase the impulse of the spray produced if the outlet velocity of the fluid increases. In accordance with the invention, the increased outlet velocity is achieved by means of a high pressure.
Another object of the invention is to avoid a liquid film on the surface of the air duct by using a spray with a high impulse. It has been observed in actual gas turbine installations that a spray injected in an area of the air duct where high velocity prevails will not fully penetrate into the core of the air flow. Some of the liquid is caught by the boundary layer flow and forms a liquid film that is transported into the compressor, impelled by the thrust of the air flow. This liquid will contribute to cleaning the compressor blades and guide vanes and may cause mechanical damage. Formation of the liquid film can be avoided by injecting liquid through the nozzle under high pressure.
A third object of the invention is to reduce the abrasive speed. Air drawn into the bell mouth is subjected to acceleration. If the air contains fluid drops originating from a spray, for instance, the drops will also be accelerated. The velocity achieved by the drops in relation to the air speed is a result of cross-acting forces. First of all, an aerodynamic flow resistance results in a retarding force that acts on the drops. Secondly, a force of inertia acts on the drops as a result of the acceleration. The retarding force is directed oppositely to the force of inertia. When the acceleration ceases at the end of the bell mouth the drops have assumed a velocity lower than the air speed. An slip speed has thus arisen between the drops and the air flow.
The compressor is designed to compress the incoming air. In the rotor energy is converted to kinetic energy by the rotor blade. In the following stator guide vane the kinetic energy is converted to an increase in pressure through a decrease in speed.
The compressor is designed for operation about a design point. The aerodynamics around the blades and the guide vanes are most favourable at the design point. When the compressor operates under various load conditions and different air states, the actual operating point of the compressor will deviate from the design operating point. Less favourable aerodynamic conditions occur in the compressor when the actual operating point deviates from the design point. Normally this only causes a deteriorated degree of efficiency in the compressor, a certain deterioration in air capacity, and a somewhat lower pressure ratio. In the worst case the actual operating point may deviate so much from the design operating point that the compressor ceases to operate. In short, this means that in order to achieve satisfactory compression the air velocity in the compressor inlet must be adjusted to the design and operating conditions.
Yet another object of the invention is for the washing fluid to penetrate into the compressor past the first step. Referring to the above description concerning the air flow containing liquid drops it is obvious that, if the compressor operates under advantageous aerodynamic conditions and a slip speed exists between drop and air, the speed of the drop must be less advantageous as regards aerodynamics. By means of analysis it has been determined that if a slip ratio prevails between drops and air, the drops will encounter the blades and guide vanes unfavourably. Liquid will to a great extent wet the blades and vanes of the first step, whereas it would be desirable for the liquid to penetrate into the compressor past the first step.
Preferred embodiment of the invention As described above, the present invention offers new methods for the user that have never previously been available to him.
Figure 2 shows the part of the inlet duct where the air accelerates to extremely high speeds, known as the bell mouth. This part of the duct is tubular and converges towards its outlet, i.e. towards the inlet into the compressor. The flow direction is indicated by arrows. The purpose of the bell mouth is to accelerate the air to the speed necessary for the compressor to perform the compression work. The bell mouth is symmetrical about the axis 26. The outer casing 20 and the inner casing 21 form the geometry of the bell mouth. Air enters the bell mouth at the cross section 22 and leaves at the cross section 25. The cross section 25 is equivalent to the first guide vane or rotor blade of the compressor. The velocity at the cross section 22 is 40 m/s. As a result of the geometry of the bell mouth the air accelerates to 100 m/s at the cross section 23, 170 m/s at the cross section 24, and 200 m/s at the cross section 25.
Figures 3A and 3B show alternative installations of the nozzles on one and the same bell mouth. Identical parts are given the same designations as in Figure 2.
Nozzle 31 in Figure 3A is installed upstream of the inlet to the bell mouth. The air speed is low here and low-pressure nozzles are to be preferred. When the liquid pressure is low the spray speed will be low. The drop velocity at cross section 33 may be assumed to be substantially equivalent to the air speed. When the drops are carried towards the compressor with the air flow, they are subjected to an increase in speed. The air speed at cross section 33 is 40 m/s and at the outlet 34 it is 200 m/s. Calculation of the equations for the slip speeds gives that the drop that had a speed of 40 m/s at the inlet 33 will have assumed a speed of 130 m/s at the outlet 34. The slip ratio is thus 0.65. The nozzle in Figure 3B is installed at cross section 23 which is in the highspeed area. A high-pressure nozzle is preferable. The nozzle is directed substantially parallel to the air flow. A nozzle operating at the pressure relevant in this invention has an outlet speed of 120 m/s. Calculation of the particle trajectory for the drop in accordance with the equations for the abrasive mechanism gives a speed of 190 m/s at the outlet 34. The slip ratio is thus 0.95.
Figure 4 shows the aerodynamics around rotor blades and stator guide vanes in an axial compressor. The blades and guide vanes are shown from the periphery of the rotor towards its centre. Rotor blade 41 is one of many blades constituting a rotor disc 410. The rotor rotates in the direction indicated by the arrow 43. The stator guide vane 42 is one of many guide vanes constituting a stator disc 420. The stator guides are fixed in the compressor casing. A rotor disc and following stator disc constitute a compression step. Air speeds are illustrated as vectors where the length of the vector is proportional to the speed, and the direction of the vector is the direction of the air flow. Figure 4 shows the air flow through a compressor step. Air approaches the rotor disc with an axial speed ratio 44. The rotor disc rotates with the tangential speed vector 45. Relative vector 46 shows the movement of the air flowing into the space between the rotor blades. Vector 47 shows the movement of the air leaving the rotor disc. Vector 45 is the tangential speed of the rotor. Relative vector 48 shows the movement of the air flowing into the space between the guide vanes. Vector 49 shows the movement of the air leaving the stator disc.
Figure 5 illustrates the case with low-pressure nozzles installed in the low- speed area of the air intake. Identical parts have been given the same designations as in Figure 4. Vector 54 shows the movement of a drop approaching the rotor disc with a slip ratio of 0.65. Vector 45 is the tangential speed of the rotor. Relative vector 56 shows the movement of a drop moving towards the space between the rotor blades. By extending the vector 56 as indicated by the broken line 57 it can be seen that the drop collides with the blade at point 58. Figure 6 illustrates the case with the high-pressure nozzle installed in the high-speed area of the air intake. Identical parts have been given the same designations as in Figure 4. Vector 64 shows the movement of a drop approaching the rotor disc with a slip ratio of 0.95. Vector 45 is the tangential speed of the rotor. Relative vector 66 shows the movement of a drop moving towards the space between the rotor blades. By extending the vector 66 as indicated by the broken line 67 it is evident that the drop will not collide with the blade. This drop will continue past the rotor disc where corresponding analysis will determine whether the drop will collide with a guide vane in the stator.
An analysis of drop trajectories under various operating conditions in the gas turbine shows that if the nozzle operates with pressure in accordance with the invention, this will result in washing fluid being distributed to compressor steps downstream of the first step if the nozzle is installed in the area of the bell mouth where the speed is at least 40 per cent of the final speed at the compressor intake, preferably at least 50 per cent, and most preferably at least 60 per cent of the final speed at the compressor intake. Naturally a somewhat better result is achieved the closer to the compressor intake the nozzle(s) is/ are situated, but for practical reasons the nozzle cannot be placed immediately beside the compressor intake.
Although the present invention has been illustrated and described in relation to detailed embodiments thereof, one skilled in the art will realize that various modifications in shape and detail are possible without departing from the concept and scope of the invention defined in the claims.

Claims

Claims
1. A method for cleaning a stationary gas turbine unit during operation, said unit comprising a turbine, a compressor (16) driven by the turbine, having an inlet (E), an air inlet duct arranged upstream of the air inlet of the compressor, the inlet duct having a part (15) of the duct adjoining the inlet of the compressor and having decreasing cross section in the flow direction in order to give the air flow a final velocity at the inlet (E) to the compressor (16), a spray of cleaning fluid being introduced in the inlet duct (15), characterised in that the cleaning fluid is forced through a spray nozzle (32) with a pressure drop exceeding 120 bar to form a spray the drops of which have a mean size that is less than 150 μm, the spray being directed substantially parallel to and in the same direction as the direction of the air flow, and in that the spray is introduced at a position (23) in the duct section (16) where the air velocity is at least 40 per cent of the final velocity at the compressor inlet (E), so that the drops of the liquid spray acquire a slip ratio of at least 0.8 at the compressor inlet (E).
2. A method as claimed in claim 1, characterised in that the fluid spray is established so that a substantial proportion of its drops have a mean size within the interval 50-150 μm.
3. A method as claimed in claim 2, characterised in that the fluid spray drops are given a mean size of around 70 μm.
4. A method as claimed in any one of claims 1-3, characterised in that the fluid spray is established by the cleaning fluid being forced through a spray nozzle with a pressure drop less than 210 Bar.
5. A method as claimed in any one of the preceding claims, characterised in that the fluid spray is established by the cleaning fluid being forced through a nozzle with a pressure drop of around 140 Bar.
6. A method as claimed in any one of the preceding claims, characterised in that the fluid spray drops are caused to acquire a slip ratio of at least 0.9 at the compressor inlet.
PCT/SE2003/001674 2002-12-13 2003-10-29 A method for cleaning a stationary gas turbine unit during operation WO2004055334A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE60314446T DE60314446T2 (en) 2002-12-13 2003-10-29 PROCESS FOR CLEANING A STATIONARY GAS TURBINE UNIT IN OPERATION
EP03759149A EP1570158B1 (en) 2002-12-13 2003-10-29 A method for cleaning a stationary gas turbine unit during operation
US10/538,672 US7428906B2 (en) 2002-12-13 2003-10-29 Method for cleaning a stationary gas turbine unit during operation
AU2003275753A AU2003275753A1 (en) 2002-12-13 2003-10-29 A method for cleaning a stationary gas turbine unit during operation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE0203697A SE0203697L (en) 2002-12-13 2002-12-13 Procedure for cleaning a stationary gas turbine unit during operation
SE0203697-8 2002-12-13

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AU (1) AU2003275753A1 (en)
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ES (1) ES2289328T3 (en)
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006080868A1 (en) * 2005-01-25 2006-08-03 Gas Turbine Efficiency Ab Probe cleaning method and apparatus
EP1749976A2 (en) 2005-08-04 2007-02-07 General Electric Company Washing device and method for a compressor
WO2007032738A1 (en) * 2005-09-13 2007-03-22 Gas Turbine Efficiency Ab System and method for augmenting power output from a gas turbine engine
EP1908928A2 (en) * 2006-09-29 2008-04-09 Gas Turbine Efficiency AB Nozzle for online and offline washing of gas turbine compressors
EP2353739A1 (en) 2007-03-07 2011-08-10 Gas Turbine Efficiency Sweden AB Transportable integrated wash unit
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US9316115B2 (en) 2004-06-14 2016-04-19 Ecoservices, Llc Turboengine wash system
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US7712301B1 (en) * 2006-09-11 2010-05-11 Gas Turbine Efficiency Sweden Ab System and method for augmenting turbine power output
DE102006057383A1 (en) * 2006-12-04 2008-06-05 Voith Patent Gmbh Turbine arrangement for energy utilization from sea waves, has chamber that has opening at its lower and upper ends and pipe that opens at both ends to lead air flow
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US8277647B2 (en) * 2007-12-19 2012-10-02 United Technologies Corporation Effluent collection unit for engine washing
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US9080460B2 (en) * 2009-03-30 2015-07-14 Ecoservices, Llc Turbine cleaning system
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US8206478B2 (en) 2010-04-12 2012-06-26 Pratt & Whitney Line Maintenance Services, Inc. Portable and modular separator/collector device
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US20150354403A1 (en) * 2014-06-05 2015-12-10 General Electric Company Off-line wash systems and methods for a gas turbine engine
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US20170204739A1 (en) 2016-01-20 2017-07-20 General Electric Company System and Method for Cleaning a Gas Turbine Engine and Related Wash Stand
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4196020A (en) * 1978-11-15 1980-04-01 Avco Corporation Removable wash spray apparatus for gas turbine engine
US5193976A (en) * 1990-02-14 1993-03-16 Turbotect Ag Injection device for the on-line wet cleaning of compressors
US5938402A (en) * 1996-12-11 1999-08-17 Asea Brown Boveri Ag Axial turbine of a turbocharger

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5011540A (en) * 1986-12-24 1991-04-30 Mcdermott Peter Method and apparatus for cleaning a gas turbine engine
SE504323C2 (en) * 1995-06-07 1997-01-13 Gas Turbine Efficiency Ab Procedures for washing objects such as turbine compressors
GB2333805B (en) * 1998-01-30 2001-09-19 Speciality Chemical Holdings L Cleaning method and apparatus
US6553768B1 (en) * 2000-11-01 2003-04-29 General Electric Company Combined water-wash and wet-compression system for a gas turbine compressor and related method
US6932093B2 (en) * 2003-02-24 2005-08-23 General Electric Company Methods and apparatus for washing gas turbine engine combustors

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4196020A (en) * 1978-11-15 1980-04-01 Avco Corporation Removable wash spray apparatus for gas turbine engine
US5193976A (en) * 1990-02-14 1993-03-16 Turbotect Ag Injection device for the on-line wet cleaning of compressors
US5938402A (en) * 1996-12-11 1999-08-17 Asea Brown Boveri Ag Axial turbine of a turbocharger

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* Cited by examiner, † Cited by third party
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WO2006080868A1 (en) * 2005-01-25 2006-08-03 Gas Turbine Efficiency Ab Probe cleaning method and apparatus
US8066816B2 (en) 2005-01-25 2011-11-29 Pratt & Whitney Line Maintenance Services, Inc. Probe cleaning method and apparatus
US8273187B2 (en) 2005-01-25 2012-09-25 Pratt & Whitney Line Maintenance Services, Inc. Probe cleaning method and apparatus
EP1749976A2 (en) 2005-08-04 2007-02-07 General Electric Company Washing device and method for a compressor
JP2007040307A (en) * 2005-08-04 2007-02-15 General Electric Co <Ge> On-line compressor water wash system for gas turbine
EP1749976A3 (en) * 2005-08-04 2008-07-23 General Electric Company Washing device and method for a compressor
WO2007032738A1 (en) * 2005-09-13 2007-03-22 Gas Turbine Efficiency Ab System and method for augmenting power output from a gas turbine engine
US7428818B2 (en) 2005-09-13 2008-09-30 Gas Turbine Efficiency Ab System and method for augmenting power output from a gas turbine engine
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US7571735B2 (en) 2006-09-29 2009-08-11 Gas Turbine Efficiency Sweden Ab Nozzle for online and offline washing of gas turbine compressors
US8524010B2 (en) 2007-03-07 2013-09-03 Ecoservices, Llc Transportable integrated wash unit
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US9932895B2 (en) 2013-10-10 2018-04-03 Ecoservices, Llc Radial passage engine wash manifold
JP2016061245A (en) * 2014-09-19 2016-04-25 三菱重工業株式会社 Centrifugal compressor
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US10458438B2 (en) 2014-09-19 2019-10-29 Mitsubishi Heavy Industries Compressor Corporation Centrifugal compressor

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SE522132C2 (en) 2004-01-13
SE0203697D0 (en) 2002-12-13
ATE364775T1 (en) 2007-07-15
EP1570158B1 (en) 2007-06-13
DE60314446D1 (en) 2007-07-26
US20060243308A1 (en) 2006-11-02
SE0203697L (en) 2004-01-13
AU2003275753A1 (en) 2004-07-09
ES2289328T3 (en) 2008-02-01
EP1570158A1 (en) 2005-09-07
DE60314446T2 (en) 2008-02-21
US7428906B2 (en) 2008-09-30

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