WO2004054364A1 - Oil suspension concentrate - Google Patents

Oil suspension concentrate Download PDF

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Publication number
WO2004054364A1
WO2004054364A1 PCT/EP2003/013389 EP0313389W WO2004054364A1 WO 2004054364 A1 WO2004054364 A1 WO 2004054364A1 EP 0313389 W EP0313389 W EP 0313389W WO 2004054364 A1 WO2004054364 A1 WO 2004054364A1
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WO
WIPO (PCT)
Prior art keywords
sodium
ethylhexyl
sulfosuccinate
edenor
solvesso
Prior art date
Application number
PCT/EP2003/013389
Other languages
German (de)
French (fr)
Inventor
Roland Deckwer
Detlev Haase
Hans-Peter Krause
Gerhard Schnabel
Original Assignee
Bayer Cropscience Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority claimed from DE2002158216 external-priority patent/DE10258216A1/en
Priority claimed from DE2003117779 external-priority patent/DE10317779A1/en
Priority claimed from DE2003151233 external-priority patent/DE10351233A1/en
Priority to SI200332416T priority Critical patent/SI1571908T1/en
Priority to AU2003303027A priority patent/AU2003303027B2/en
Priority to BR0317271-6A priority patent/BR0317271A/en
Priority to DK03813102.5T priority patent/DK1571908T3/en
Application filed by Bayer Cropscience Gmbh filed Critical Bayer Cropscience Gmbh
Priority to ES03813102.5T priority patent/ES2532907T3/en
Priority to MXPA05006211A priority patent/MXPA05006211A/en
Priority to EA200500915A priority patent/EA012031B1/en
Priority to YUP-2005/0447A priority patent/RS20050447A/en
Priority to JP2005502419A priority patent/JP4810228B2/en
Priority to CA002509586A priority patent/CA2509586A1/en
Priority to NZ540693A priority patent/NZ540693A/en
Priority to EP03813102.5A priority patent/EP1571908B1/en
Publication of WO2004054364A1 publication Critical patent/WO2004054364A1/en
Priority to DK04819206.6T priority patent/DK1689236T3/en
Priority to HUE04819206A priority patent/HUE039420T2/en
Priority to UAA200607191A priority patent/UA83702C2/en
Priority to CN200480035169.5A priority patent/CN1886052B/en
Priority to PCT/EP2004/013154 priority patent/WO2005051082A1/en
Priority to CA2547346A priority patent/CA2547346C/en
Priority to RU2006122781/04A priority patent/RU2399205C2/en
Priority to SI200432444T priority patent/SI1689236T1/en
Priority to BRPI0416401A priority patent/BRPI0416401B1/en
Priority to AU2004292751A priority patent/AU2004292751A1/en
Priority to PT48192066T priority patent/PT1689236T/en
Priority to TR2018/07562T priority patent/TR201807562T4/en
Priority to ES04819206.6T priority patent/ES2678414T3/en
Priority to US10/997,627 priority patent/US20050233906A1/en
Priority to ARP040104415A priority patent/AR046729A1/en
Priority to HR20050530A priority patent/HRP20050530A2/en
Priority to ZA200603584A priority patent/ZA200603584B/en
Priority to CY181100738T priority patent/CY1121057T1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof

Definitions

  • the present invention relates to the field of crop protection formulations.
  • the invention relates to liquid formulations in the form of oil suspension concentrates which contain herbicidal active compounds from the group of the sulfonamides, in particular the phenylsulfonamides and heteroarylsulfonamides.
  • Active substances for crop protection are generally not used in their pure form. Depending on the area of application and the type of application, as well as on physical, chemical and biological parameters, the active ingredient is used in a mixture with customary auxiliaries and additives as an active ingredient formulation. Combinations with other active ingredients to expand the spectrum of activity and / or to protect crop plants (e.g. through safeners, antidotes) are also known.
  • Formulations of active substances for crop protection should generally have high chemical and physical stability, good applicability and user-friendliness and a broad biological action with high selectivity.
  • One way to formulate chemically labile active ingredients is to produce solid formulations.
  • Formulations of active substances from the group of sulfonylureas, in the form of powders, granules and tablets, are known (for example in EP 764404, WO 9834482, WO 9313658).
  • the processes for the production of solid formulations for example in the form of granules and tablets, are generally complex, in particular if active ingredients which have a low melting point or Auxiliaries and additives are incorporated.
  • solid formulations are generally more difficult to apply and less user-friendly.
  • Liquid formulations of sulfonylureas are e.g. described in
  • EP 0514768, EP 0163598 and EP 0514769 are examples of EP 0514768, EP 0163598 and EP 0514769.
  • the object of the present invention was to provide an improved crop protection formulation which has high chemical stability and high biological effectiveness and crop tolerance.
  • the present invention thus relates to an oil suspension concentrate comprising a) one or more herbicidal active compounds from the group of the sulfonamides, in suspended form, b) one or more safeners, c) one or more organic solvents, and d) one or more sulfosuccinates.
  • oil suspension concentrate according to the invention may optionally also contain further components: e) one or more agrochemical active ingredients different from a) and b), and f) customary auxiliaries and additives.
  • oil suspension concentrate is understood to mean a suspension concentrate based on organic solvents.
  • One or more active ingredients are suspended in the organic solvent, further active ingredients can be dissolved in the organic solvent.
  • the sulfonamide a) is present in suspended form in the organic solvent. This means that the main part (in% by weight) of sulfonamide is undissolved in finely divided form, a smaller part of the sulfonamide can be in solution.
  • the sulfonamide is preferably suspended in the organic solvent to more than 80% by weight, particularly preferably to more than 90% by weight, in each case based on the total amount of sulfonamide in the oil suspension concentrate according to the invention.
  • Preferred sulfonamides a) are phenylsulfonamides and heteroarylsulfonamides and other sulfonamides such as amidosulfuron.
  • Examples of phenylsulfonamides a) are compounds from the group of
  • Phenylsulfonylaminocarbonyltriazolinone or the phenylsulfonylureas preferably from the group of phenylsulfonylureas in question.
  • the term phenylsulfonylureas is also taken to mean those sulfonylureas in which the phenyl group is bonded to the sulfone group (SO 2 ) via a spacer such as CH 2 , O or NH.
  • Phenylsulfonylaminocarbonyltriazolinone are Flucarbazone or Propoxycarbazone and / or their salts.
  • the sulfonamides a) are commercially available and / or can be prepared by known processes such as those e.g. are described in EP-A-7687, EP-A-30138, US 5,057,144 and US 5,534,486.
  • Suitable phenylsulfonamides are phenylsulfonamides of the general formula (I) and / or their salts,
  • Phenyl radical including substituents 1-30 C-atoms, preferably 1-20 C-
  • R ß is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and includes 1-10 C atoms including substituents, for example unsubstituted or substituted C 1 -C 6 alkyl, preferably a
  • R ⁇ is a hydrogen atom or a hydrocarbon residue which is unsubstituted or substituted and has substituents 1-10 C atoms, for example unsubstituted or substituted C 1 -C 6 -alkyl, preferably a
  • A is CH 2 , O or NH, preferably O, m is zero or 1, n is zero or 1, preferably 1, and R ⁇ is a heterocyclic radical such as a pyridyl radical, a triazinyl radical or a
  • Triazolinonerest is.
  • Preferred phenylsulfonamides are phenylsulfonylureas, for example phenylsulfonylureas of the general formula (II) and / or their salts,
  • Phenyl radical including substituents 1-30 C-atoms, preferably 1-20 C-
  • R ß is a hydrogen atom or a hydrocarbon residue which is unsubstituted or substituted and has substituents including 1-10 C atoms, for example unsubstituted or substituted Ci-C ⁇ -alkyl, preferably a
  • R ⁇ is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and has substituents including 1-10 C atoms, for example unsubstituted or substituted Ci-C ⁇ -alkyl, preferably a
  • A is CH 2 , O or NH, preferably O, m is zero or 1, and R ⁇ is a heterocyclic radical such as a pyridyl radical or a triazinyl radical.
  • Phenylsulfonylureas of the formula (III) and / or their salts are preferred,
  • R 4 is C 1 -C 4 alkoxy, preferably C 2 -C 4 alkoxy, or CO-R a , where R a is the same
  • R is halogen, preferably iodine, or (A) n -NR d R e , where n is zero or 1,
  • A is a group CR'R ", in which R 'and R" are, independently of one another, the same or different H or C 1 -C 4 alkyl, R d is H or C 1 -C 4 alkyl and R e is an acyl radical such as formyl or C ⁇ -C 4 alkyl sulfonyl, and R 5 in the event that
  • R 4 is C 1 -C 4 -alkoxy, preferably C 2 -C -alkoxy, can also be H,
  • R 6 is H or -CC 4 alkyl, m is zero or 1,
  • X and Y independently of one another are identical or different halogen or NR'R ", where R 'and R" are identical or different H or C 1 -C 6 alkyl, or C 1 -C 6 alkyl, CrCe alkoxy, CrCe alkylthio , C 3 -C 6 cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 alkenyloxy or C 3 -C 6 alkynyloxy, each of the eight latter radicals being unsubstituted or by one or more radicals from the group halogen, C ⁇ -C 4 alkoxy and C ⁇ -C 4 alkylthio is substituted, preferably C 1 -C 4 alkyl or C ⁇ -C alkoxy, and
  • Z is CH or N.
  • Phenylsulfonylureas of the general formula (III) and / or their salts are particularly preferred, in which a) R 4 is CO- (CrC 4 -alkoxy), R 5 is halogen, preferably iodine, or R 5 is CH 2 -NHR e is where R e is an acyl radical, preferably CrC 4 alkyl sulfonyl, and m is zero, b) R 4 is CO-N (-CC 4 alkyl) 2l R 5 is NHR e , wherein R e is an acyl radical, preferably formyl, and m is zero, or c) R 4 is C 2 -C 4 -alkoxy, R 5 is H and m is 1.
  • Typical phenylsulfonylureas include the compounds listed below and their salts, such as the sodium salts: bensulfuron-methyl, chlorimuron-ethyl, chlorosulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron-methyl, ethoxysulfuron and its sodium salt, metsulfuron-methyl, primisulfuron , Sulfometuron-methyl, triasulfuron, tribenuron-methyl, triflusulfuron-methyl, tritosulfuron, iodosulfuron-methyl and its sodium salt (WO 92/13845), mesosulfuron-methyl and its sodium salt (Agrow No. 347, March 3, 2000, page 22 ( PJB Publications Ltd. 2000)) and foramsulfuron and its sodium salt (Agrow No. 338, October 15, 1999, page 26 (PJB Publications Ltd. 1999)).
  • Particularly preferred phenylsulfonamides are: iodosulfuron-methyl (A1.1) and its sodium salt (A1.2), mesosulfuron-methyl (A2.1) and its sodium salt (A2.2), foramsulfuron (A3.1) and its sodium salt (A3 .2), Flucarbazone (A4.1) and its sodium salt (A4.2), Propoxycarbazone (A5.1) and its sodium salt (A5.2) and ethoxysulfuron (A6.1) and its sodium salt (A6.2), metsulfuron - methyl (A7.1) and its sodium salt ⁇ /Kl.2), tribenuron-methyl (A8.1) and its sodium salt (A8.2), chlorosulfuron (A9.1) and its sodium salt (A9.2).
  • the active ingredients listed above are e.g. known from "The Pesticide Manual", 12th edition (2000), The British Crop Protection Council or the literature references listed according to the individual active ingredients.
  • heteroarylsulfonamides a) are compounds from the group of heteroarylsulfonylaminocarbonyltriazolinones or heteroarylsulfonylureas, preferably from the group of heteroarylsulfonylureas.
  • heteroarylsulfonylureas are also understood to be those sulfonylureas in which the heteroaryl group is bonded to the sulfone group (SO 2 ) via a spacer such as CH 2 , O or NH.
  • heteroarylsulfonamides examples include sulfonamides of the general formula (IV) and / or their salts,
  • R ⁇ ' (A i ) m-SO 2 -NR ß' -CO- (NR ⁇ ') n' - R ⁇ ' (IV) wherein R ⁇ ' is a heteroaryl radical which is unsubstituted or substituted, and wherein the
  • Heteroaryl radical including substituents 1-30 C atoms, preferably 1-20 C
  • R ßl is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and including substituents has 1-10 C atoms, for example unsubstituted or substituted C 1 -C 6 -alkyl, preferably a
  • R 7 ' is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and has substituents including 1-10 C atoms, for example unsubstituted or substituted Ci-C ⁇ -alkyl, preferably a
  • a ' is CH 2 , O or NH, preferably O, m' is zero or 1, n 'is zero or 1, preferably 1, and R ⁇ ' is a heterocyclic radical such as a pyridyl radical, a triazinyl radical or a
  • Triazolinonerest is.
  • heteroarylsulfonamides are heteroarylsulfonylureas, for example sulfonylureas of the general formula (V) and / or their salts,
  • Heteroaryl radical including substituents 1-30 C atoms, preferably 1-20 C
  • R ß ' is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and including substituents has 1-10 C atoms, for example unsubstituted or substituted C 1 -C 6 -alkyl, preferably a
  • R ⁇ ⁇ is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and has, including substituents, 1-10 C atoms, for example unsubstituted or substituted Ci-C ⁇ -alkyl, preferably a
  • a ' is CH 2 , O or NH, preferably O, m' is zero or 1, and R ⁇ ⁇ is a heterocyclic radical such as a pyridyl radical or a triazinyl radical.
  • R ⁇ a substituted heteroaryl such as substituted pyridyl, thienyl,
  • R ⁇ i is a triazolinone radical , preferably
  • R 7 (-C-C ⁇ o) alkyl, which is optionally substituted with halogen (F, Cl, Br, I) or (dC 3 ) halo-alkyl,
  • R 8 (C ⁇ -C ⁇ o) alkyl, which is optionally substituted with halogen (F, Cl, Br, I) or (CC 3 ) haloalkyl,
  • X and Y are independently the same or different halogen or NR'R ", where R 'and R" are the same or different H or -CC 4 alkyl, or d-Ce alkyl, CrC 6 alkoxy, CC 6 alkylthio , C 3 -C 6 cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 alkenyloxy or C 3 -C 6 alkynyloxy, each of the eight latter radicals being unsubstituted or is substituted by one or more radicals from the group halogen, C 1 -C 4 alkoxy and C 1 -C 4 alkylthio, preferably C 1 -C 4 alkyl or C 1 -C 4 alkoxy.
  • R ⁇ is particularly preferably the same
  • R 9 (-C-C 6 ) alkyl, (CrC 6 ) alkoxy, (C 2 -C 6 ) alkenyloxy, (C 2 -C 6 ) alkynyloxy, (C ⁇ -C 6 ) alkylsulfonyl, (C ⁇ -C 6 ) Alkylcarbonyl, (CrCeJalkoxycarbonyl, (C 2 -C 6 ) alkenyloxycarbonyl, (C 2 -C 6 ) alkynyloxycarbonyl, CONR'R ", (C ⁇ -C 6 ) haloalkyl, (CC 6 ) haloalkoxy, (C 2 - C 6 ) halo-alkenyloxy, (C 2 -C 6 ) halo-alkynyloxy, (-C-C 6 ) halo-alkylsulfonyl, (-C-C 6 ) halo-alkylcarbonyl
  • R 10 H (dC 3 ) alkyl, (dC 3 ) alkoxy, (C ⁇ -C 3 ) halo-alkyl, (C ⁇ -C 3 ) halo-alkoxy or
  • R 11 (-CC 6 ) alkyl, (CC 6 ) alkoxy, (C 2 -C 6 ) alkenyloxy, (C 2 -C 6 ) alkynyloxy,
  • (-C-C 6 ) alkylsulfonyl (dC 6 ) alkylcarbonyl, (CrC 6 ) alkoxycarbonyl, (C 2 -C 6 ) alkenyloxycarbonyl, (C 2 -C 6 ) alkynyloxycarbonyl, (C ⁇ -Ce) haloalkyl, (CrC 6 ) Halo-alkoxy, (C 2 -C 6 ) halo-alkenyloxy, (C 2 -C 6 ) halo-alkynyloxy, (Ci- C 6 ) halo-alkylsulfonyl, (C ⁇ -C 6 ) halo-alkylcarbonyl, (C ⁇ - C 6 ) haloalkoxycarbonyl, (C 2 -C 6 ) haloalkenyloxycarbonyl, (C 2 -C 6 ) haloalkynyloxycarbonyl, CONR'R
  • R 12 halogen (F, Cl, Br, I), (dC 6 ) alkyl, (dC 6 ) alkoxy, (CC 6 ) alkylsulfonyl,
  • R 13 (-CC 6 ) alkoxycarbonyl, (C 2 -C 6 ) alkenyloxycarbonyl, (C 2 -
  • R 14 H halogen (F, C, Br, I), (-C-C 6 ) alkyl, (dC 6 ) halo-alkyl,
  • R 16 (-CC 6 ) alkyl, (dC 6 ) alkoxy, (C 2 -C 6 ) alkenyloxy, (C 2 -C 6 ) alkynyloxy, (d-
  • R 'and R "independently of one another are H, (dC 6 ) alkyl, (dC 6 ) haloalkyl, (C 2 -C 6 ) alkenyl, (C 2 -C 6 ) haloalkenyl, (C 2 -C 6 ) alkynyl, (C 2 -C 6 ) are haloalkynyl, or NR'R "forms a heterocyclic ring which can be saturated, unsaturated or aromatic and preferably contains 4-6 ring atoms and one or more heteroatoms from the group N, O, S, and optionally by one or more substituents, preferably from the group (Cr C 3 ) alkyl, (dC 3 ) alkoxy, (CC 3 ) halo-alkyl, (-C-C 3 ) halo-alkoxy or halogen can be substituted.
  • heteroarylsulfonylureas are, for example, nicosulfuron (A10.1) and its salts such as the sodium salt (A10.2), rimsulfuron (A11.1) and its salts such as the sodium salt (A11.2), thifensulfuron-methyl (A12.1) and its salts such as the sodium salt (A12.2), pyrazosulfuron-ethyl (A13.1) and its salts such as the sodium salt (A13.2), flupyrsulfuron-methyl (A14.1) and its salts such as the sodium salt (A14.2) , Sulfosulfuron (A15.1) and its salts such as the sodium salt (A15.2), trifloxysulfuron (A16.1) and its salts such as the sodium salt (A16.2), azimsulfuron (A17.1) and its salts such as the sodium salt ( A17.2), flazasulfuron (A18.1) and its salts
  • the active ingredients listed above are e.g. known from "The Pesticide Manual”, 12th edition (2000) (PM) and 13th edition (2003), The British Crop Protection Council or the literature references listed according to the individual active ingredients.
  • the sulfonamides a) present as a component in the oil suspension concentrates according to the invention always mean all use forms, such as acids, esters, salts and isomers, such as stereoisomers and optical isomers.
  • their salts with inorganic and / or organic counterions are also always to be understood.
  • sulfonamides can form salts in which the hydrogen of the —SO 2 —NH group is replaced by a cation suitable for agriculture.
  • These salts are, for example, metal salts, in particular Alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or also ammonium salts or salts with organic amines.
  • Salt formation can also take place by addition of an acid to basic groups, such as amino and alkylamino.
  • Suitable acids for this are strong inorganic and organic acids, for example HCl, HBr, H 2 SO or HNO 3 .
  • Preferred esters are the alkyl esters, especially the d-Cio-alkyl esters such as methyl esters.
  • acyl radical means the residue of an organic acid which is formally formed by splitting off an OH group from the organic acid, e.g. the rest of a carboxylic acid and residues derived therefrom, such as thiocarboxylic acid, optionally N-substituted iminocarboxylic acids or the residues of carbonic acid monoesters, optionally N-substituted carbamic acids, sulfonic acids, sulfinic acids, phosphonic acids, phosphinic acids.
  • An acyl radical is preferably formyl or acyl from the group CO-R z , CS-R Z , CO-OR z , CS-OR z , CS-SR Z , SOR z or SO 2 R z , where R z each has a dC 10 Hydrocarbon radical such as CrCio-alkyl or C 6 -do-aryl which is unsubstituted or substituted, for example by one or more substituents from the group halogen such as F, Cl, Br, I, alkoxy, haloalkoxy, hydroxy, amino, nitro, Cyano or alkylthio, or R z means aminocarbonyl or aminosulfonyl, the latter two radicals being unsubstituted, N-monosubstituted or N, N-disubstituted, for example by substituents from the group consisting of alkyl or aryl.
  • R z each has a dC 10 Hydro
  • Acyl means, for example, formyl, haloalkylcarbonyl, alkylcarbonyl such as (dC) alkylcarbonyl, phenylcarbonyl, where the phenyl ring can be substituted, or alkyloxycarbonyl, such as (C ⁇ -C 4 ) alkyloxycarbonyl, phenyloxycarbonyl, benzyloxycarbonyl, alkylsulfonyl, such as (dC) alkylsulfonyl, alkylsulfinyl, such as CC 4 (alkylsulfinyl), N-alkyl-1-iminoalkyl, such as N- (-C-C 4 ) -1-imino- (C ⁇ -C 4 ) alkyl and other residues of organic acids.
  • alkylcarbonyl such as (dC) alkylcarbonyl, phenylcarbonyl, where the phenyl ring can be substituted, or
  • a hydrocarbon residue means a straight-chain, branched or cyclic and saturated or unsaturated aliphatic or aromatic Hydrocarbon radical, for example alkyl, aikenyl, alkinyi, cycloalkyl, cycloalkenyl or aryl.
  • a hydrocarbon radical preferably has 1 to 40 C atoms, preferably 1 to 30 C atoms;
  • a hydrocarbon radical is particularly preferably alkyl, aikenyl or alkinyi having up to 12 carbon atoms or cycloalkyl having 3, 4, 5, 6 or 7 ring atoms or phenyl.
  • Aryl means a mono-, bi- or polycyclic aromatic system, for example phenyl, naphthyl, tetrahydronaphthyl, indenyl, indanyl, pentalenyl, fluorenyl and the like, preferably phenyl.
  • a heterocyclic radical or ring can be saturated, unsaturated or heteroaromatic and unsubstituted or substituted; it preferably contains one or more heteroatoms in the ring, preferably from the group N, O and S; it is preferably an aliphatic heterocyclyl radical with 3 to 7 ring atoms or a heteroaromatic radical with 5 or 6 ring atoms and contains 1, 2 or 3 heteroatoms.
  • the heterocyclic residue can e.g. be a heteroaromatic residue or ring (heteroaryl), e.g.
  • a mono-, bi- or polycyclic aromatic system in which at least 1 ring contains one or more heteroatoms for example pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl, triazinyl, thienyl, thiazolyl, oxazolyl, furyl, pyrrolyl, pyrazolyl and imidazolyl, or is one partially or fully hydrogenated radical such as oxiranyl, oxetanyl, pyrrolidyl, piperidyl, piperazinyl, triazolyl, dioxolanyl, morpholinyl, tetrahydrofuryl.
  • heteroatoms for example pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl, triazinyl, thienyl, thiazolyl, oxazolyl, furyl, pyrrolyl, pyrazolyl and
  • Pyrimidinyl and triazinyl are preferred.
  • Possible substituents for a substituted heterocyclic radical are the substituents mentioned below, and additionally oxo.
  • the oxo group can also be attached to the hetero ring atoms, which can exist in different oxidation states, e.g. at N and S, occur.
  • Substituted radicals such as substituted hydrocarbon radicals, for example substituted alkyl, aikenyl, alkinyi, aryl, phenyl and benzyl, or substituted heterocyclyl or heteroaryl, mean, for example, a substituted radical derived from the unsubstituted basic body, the substituents being, for example, one or more, preferably 1, 2 or 3 residues from the group halogen, alkoxy, Haloalkoxy, alkylthio, hydroxy, amino, nitro, carboxy, cyano, azido, alkoxycarbonyl, alkylcarbonyl, formyl, carbamoyl, mono- and dialkylaminocarbonyl, substituted amino such as acylamino, mono- and dialkylamino, and alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, halo
  • radicals with carbon atoms those with 1 to 4 carbon atoms, in particular 1 or 2 carbon atoms, are preferred.
  • substituents from the group halogen for example fluorine and chlorine, (dC) alkyl, preferably methyl or ethyl, (dC) haloalkyl, preferably trifluoromethyl, (C 1 -C 4 ) alkoxy, preferably methoxy or ethoxy, (C ⁇ - C 4 ) Haloalkoxy, Nitro and Cyano.
  • the substituents methyl, methoxy and chlorine are particularly preferred.
  • Optionally substituted phenyl is preferably phenyl which is unsubstituted or one or more times, preferably up to three times, by identical or different radicals, preferably from the group halogen, (-C-C) alkyl, (-C-C) alkoxy, (-C-C) Haloalkyl, (-C-C 4 ) haloalkoxy and nitro is substituted, for example o-, m- and p-tolyl, dimethylphenyl, 2-, 3- and 4-chlorophenyl, 2-, 3- and 4-trifluoro- and trichlorophenyl , 2,4-, 3,5-, 2,5- and 2,3-dichlorophenyl, o-, m- and p-methoxyphenyl.
  • Cycloalkyl means a carbocyclic, saturated ring system, preferably with 3-6 C atoms, e.g. Cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl.
  • the carbon-containing radicals such as alkyl, alkoxy, haloalkyl, haloalkoxy, alkylamino and alkylthio and the corresponding unsaturated and / or substituted radicals in the carbon skeleton are each straight-chain or branched.
  • the lower carbon skeletons for example with 1 to 6 C atoms or, in the case of unsaturated groups, with 2 to 6 C atoms, are preferred for these radicals.
  • Alkyl radicals also in the composite meanings such as alkoxy, haloalkyl, etc., mean, for example, methyl, ethyl, n- or i-propyl, n-, i-, t- or 2-butyl, pentyls, Hexyls such as n-hexyl, i-hexyl and 1,3-dimethylbutyl, heptyls such as n-heptyl, 1-methylhexyl and 1,4-dimethylpentyl;
  • Aikenyl and alkynyl radicals have the meaning of the possible unsaturated radicals corresponding to the alkyl radicals;
  • Aikenyl means, for example, allyl, 1-methylprop-2-en-1-yl, 2-methyl-prop-2-en-1-yl, but-2-en-1-yl, but-3-en-1-yl , 1-methyl-but-3-en-1-yl and 1-methyl-but-2-
  • Halogen means, for example, fluorine, chlorine, bromine or iodine.
  • Haloalkyl, -aikenyl and -alkinyi are partially or completely substituted alkyl, aikenyl or alkinyi, for example CF 3 , CHF 2 , CH 2 F, CF, by halogen, preferably by fluorine, chlorine and / or bromine, in particular by fluorine or chlorine 3 CF 2 , CH 2 FCHCI, CCI 3 , CHCI 2 , CH 2 CH 2 CI;
  • Haloalkoxy is, for example, OCF 3 , OCHF 2 , OCH 2 F, CF 3 CF 2 O, OCH 2 CF 3 and OCH 2 CH 2 CI; the same applies to haloalkenyl and other halogen-substituted radicals.
  • the herbicidal active substances a) from the series of the sulfonamides are generally present in the oil suspension concentrates according to the invention in amounts of 0.01 to 50% by weight, preferably 0.1 to 30% by weight, the reference “% by weight” being used here. here and throughout the description, unless otherwise defined, on the relative weight of the respective component based on the total weight of the formulation.
  • the oil suspension concentrates according to the invention contain safeners which are suitable for reducing or avoiding damage to the crop.
  • Suitable safeners are e.g. known from WO-A-96/14747 and the literature cited therein.
  • the safeners can be present in the organic solvent in suspended and / or in dissolved form, preferably in dissolved form.
  • dichlorophenylpyrazole carboxylic acid preferably compounds such as ethyl 1- (2,4-dichlorophenyl) -5-methyl-pyrazole-3-carboxylate (S1-2), 1- (2,4-dichlorophenyI) -5-isopropyl-pyrazole- 3-carboxylic acid ethyl ester (S1-3), 1- (2,4-dichlorophenyl) -5- (1, 1-dimethyl-ethyl) pyrazole-3-carboxylic acid ethyl ester (S1-4), 1- (2,4- Dichlorophenyl) -5-phenyl-pyrazole-3-carboxylic acid ethyl ester (S1-5) and related compounds as described in EP-A-333 131 and EP-A-269 806.
  • Active substances of the phenoxyacetic or propionic acid derivative or aromatic carboxylic acid type e.g. 2,4-dichlorophenoxyacetic acid (ester) (2,4-D), 4-chloro-2-methylphenoxy-propionester (Mecoprop), MCPA or 3,6-dichloro-2-methoxy-benzoic acid (ester) (Dicamba) ,
  • PPG-1292 N-allyl-N [(1,3-dioxolan-2-yl) methyl] dichloroacetamide from PPG Industries
  • Oxyimino compound type active ingredients known as seed dressings e.g.
  • O- (1, 3-dioxolan-2-ylmethyl) oxime which is known as a seed dressing safener against damage to metolachlor
  • Active substances of the thiazole carboxylic acid ester type which are known as seed dressings, e.g.
  • Active substances of the naphthalenedicarboxylic acid derivative type which are known as seed dressings, e.g.
  • Naphthalenedicarboxylic acid anhydride which is known as a seed dressing safener for maize against damage from thiocarbamate herbicides
  • Active substances of the chromanacetic acid derivative type e.g.
  • Preferred safeners are mefenpyr, fenchlorazole, isoxadifene, cloquintocet and their C 1 -C 8 -alkyl esters, in particular mefenpyr diethyl (S1-1), fenchlorazol-ethyl (S1-6), isoxadifen-ethyl (S1-9), cloquintocet-mexyl (S2-1), and (S3-1).
  • the safeners b) are generally present in amounts from 0.1 to 60% by weight, in particular from 2 to 40% by weight.
  • the weight ratio of component a) to component b) can vary within a wide range and is generally between 1: 100 and 100: 1, preferably between 1:10 and 10: 1.
  • Optional agrochemical active ingredients e) can contain, for example, components ag) and components different from agrochemical active ingredients such as herbicides, fungicides, insecticides, plant growth regulators and the like.
  • the agrochemical active ingredients e) can be present in the organic solvent in suspended and / or dissolved form.
  • Suitable active ingredients different from components a) and b), which may optionally be present as component e) in the oil suspension concentrates according to the invention, are preferably herbicidal active ingredients, for example: A) herbicides of the phenoxyphenoxy and
  • Phenoxyphenoxy and benzyloxyphenoxy carboxylic acid derivatives e.g. Methyl 2- (4- (2,4-dichlorophenoxy) phenoxy) propionate (diclofop-methyl), methyl 2- (4- (4-bromo-2-chlorophenoxy) phenoxy) propionate (DE-A 26 01 548), 2 - (4- (4-bromo-2-fluorophenoxy) phenoxy) propionic acid methyl ester (US Pat. No. 4,808,750), 2- (4- (2-chloro-4-trifluoromethylphenoxy) phenoxy) propionic acid methyl ester (DE-A 24 33 067),
  • N-methoxymethyl-2,6-diethyl-chloroacetanilide (alachlor), N- (3-methoxyprop-2-yl) -2-methyl-6-ethyl-chloroacetanilide (metolachlor), N- (3-methyl-1, 2 , 4-oxadiazol-5-yl-methyl) 'chloroacetic acid-2,6-dimethylanilide, N- (2,6-dimethylphenyl) -N- (1-pyrazolylmethyl) chloroacetic acid amide (metazachlor); C) thiocarbamates, for example S-ethyl-N, N-dipropylthiocarbamate (EPTC), S-ethyl-N, N-diisobutylthiocarbamate (butylates);
  • S- (N-aryl-N-alkyl-carbamoylmethyl) dithiophosphonic acid esters such as S- [N- (4-chlorophenyl) -N-isopropyl-carbamoylmethyl] -O, O-dimethyl-dithiophosphate (Anilophos).
  • Alkyl azines for example as described in WO-A 97/08156, WO-A-97/31904, DE-A-19826670, WO-A-98/15536, WO-A-8/15537, WO-A-98 / 15538, WO-A-98/15539 and also DE-A-19828519, WO-A-98/34925, WO-A-98/42684, WO-A-99/18100, WO-A-99/19309, WO-A-99/37627 and WO-A-99/65882, preferably those of the formula (G)
  • Phosphorus-containing herbicides e.g. of the glusosinate type such as glufosinate in the narrower sense, d. H. D, L-2-amino-4- [hydroxy (methyl) phosphinylj-butanoic acid, glufosinate monoammonium salt, L-glufosinate, L- or (2S) -2-amino-4- [hydroxy (methyl) phosphinyl] butanoic acid, L-glufosinate monoammonium salt or bialaphos (or bilanafos), ie L-2-amino-4- [hydroxy (methyl) phosphinyl] butanoyl-L-alanyl-L-alanine, especially its sodium salt, or of the glyphosate type such as glyphosate, i.e.
  • the herbicides of groups A to H are, for example, from the respective publications mentioned above and from "The Pesticide Manual”, 12th edition, 2000, The British Crop Protection Council, "Agricultural Chemicals Book II - Herbicides -", by W.T. Thompson, Thompson Publications, Fresno CA, USA 1990 and “Farm Chemicals Handbook '90", Meister Publishing Company, Willoughby OH, USA, 1990.
  • agrochemical active ingredients (e) which are different from components (a) and (b), the known active ingredients mentioned below, as described in, for example, Weed Research 26, 441-445 (1986), or " The Pesticide Manual ", 12th edition, The British Crop Protection Council, 2000, and the literature cited therein, for example in mixture formulations or as a tank mixing partner.
  • connections are either with the "common name" after the International Organization for Standardization (ISO) or with the chemical name, if necessary together with a usual code number and always include all forms of application such as acids, salts, esters and isomers such as stereoisomers and optical isomers: acetochlor; acifluorfen; aclonifen; AKH 7088, ie [[[1- [5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrophenyl] -2-methoxyethylidene] amino] oxy] acetic acid and methyl acetate; alachlor; alloxydim; ametryn; amitrol; AMS, ie ammonium sulfamate; anilofos; asulam; atrazine; azafenidine (DPX-R6447), aziprotryn; barban; BAS 516 H, ie 5-fluoro-2-phenyl-4H-3,1-
  • ethyldithiocarbamic acid chlomethoxyfen; chloramben; cloransulam-methyl (XDE-565), chlorazifop-butyl, chlorbromuron; chlorbufam; chlorfenac; chlorflurenol-methyl; chloridazon; chlornitrofen; chlorotoluron; chloroxuron; chlorpropham; chlorthal-dimethyl; chlorthiamid; cinidon-ethyl, cinmethylin; clethodim; clodinafop and its ester derivatives (eg clodinafop-propargyl); clomazone; clomeprop; cloproxydim; clopyralid; cumyluron (JC 940); cyanazine; cycloate; cycloxydim; cycluron; cyhalofop and its ester derivatives (eg butyl ester, DEH-112); cyperquat
  • pentyl ester S-23031); flumioxazin (S-482); flumipropyn; flupoxam (KNW-739); fluorodifen; fluoroglycofen-ethyl; flupropacil (UBIC-4243); fluridone; flurochloridone; fluroxypyr; flurtamone; fluthiacet-methyl (KIH-9201), fomesafen; fosamine; furyloxyfen; glufosinate; glyphosate; halo safen; halosulfuron and its esters (e.g.
  • Preferred components e) are bromoxynil (E1) in all its use forms, including the salts and esters, for example bromoxynil octanoate (E1.1), bromoxynil heptanoate (E1.2), bromoxynil butyrate (E1.3), bromoxynil sodium (E1.4) and bromoxynil potassium (E1.5); 2,4-D (E2) in all of its Use forms including the salts and esters, for example 2,4-D-butotyl (E2.1), 2,4-D-butyl (E2.2), 2,4-D-dimethylammonium (E2.3), 2,4 -D-diethanolamine (E2.4), 2,4-D-2-ethylhexyl (E2.5), 2,4-D-isooctyl (E2.6), 2,4-D-isopropyl (E2.7) , 2,4-D-sodium (E2.8) and 2,4-D-triethanolamine (E2.9); Dicamba (E3)
  • agrochemical active ingredients e are contained in the oil suspension concentrates according to the invention, their weight fraction is 0.5 to 50% by weight, in particular 3 to 20% by weight.
  • the total active substance content (sum of component a) + b) + e)) contained in the oil suspension concentrates according to the invention is generally between 1 and 80% by weight, in particular between 3 and 60% by weight.
  • hydrocarbons which may be unsubstituted or substituted, e.g.
  • aromatic hydrocarbons e.g.
  • mono- or poly-alkyl-substituted benzenes such as toluene, xylenes, mesitylene, ethylbenzene, or
  • One or more alkyl-substituted naphthalenes such as 1-methylnaphthalene, 2-methylnaphthalene or dimethylnaphthalene, or
  • linear or branched aliphatics for example of the general formula C n H 2n + 2, such as pentane, hexane, octane, 2-methylbutane or 2,2,4-trimethylpentane, or
  • Cyclic optionally alkyl-substituted aliphatics, such as cyclohexane or methylcyclopentane, or
  • halogenated hydrocarbons such as halogenated aromatic and aliphatic hydrocarbons, such as chlorobenzene or methylene chloride, or
  • aprotic, polar solvents such as ethers, esters of Ci-Cg-alkanoic acids, which can be mono-, di- or polyfunctional, such as their mono-, di- or triesters, for example with C 1 -C 8 -alkyl alcohols, ketones with less Tautomerietendenz, phosphoric ester, amides, nitriles or sulfones, for example diisobutyl adipate, Rhodiasolv RPDE ® (Rhodia), cyclohexanone, Jeffsol ® PC (Huntsman), ⁇ - butyrolactone, N-methylpyrrolidone, dimethyl sulfoxide, acetonitrile, or Tributylphosphatam Hostarex ® PO series (Clariant ), or
  • fatty acid esters for example of natural origin, for example natural oils such as animal oils or vegetable oils, or synthetic origin, for example Edenor ® series, for example Edenor ® MEPa or Edenor ® MESU or Agnique ® ME series or Agnique ® AE series (Cognis), Salim ® ME series (Salim), Radia ® series e.g. Radia ® 30167 (ICI), Prilube ® series e.g. Prilube ® 1530 (Petrofina), Stepan ® C series (Stepan) or Witconol ® 23 series (Witco).
  • the fatty acid esters are preferably esters of C 10 -C 22 , preferably C 2 -C 20 fatty acids.
  • the C ⁇ o-C 22 fatty acid esters are, for example, esters of unsaturated or saturated C 10 -C 22 fatty acids, especially with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and especially C 8 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
  • fatty acid esters such as C ⁇ o-C 22 fatty acid esters are glycerol and glycol esters of fatty acids such as C ⁇ o-C 22 fatty acids or their transesterification products, for example alkyl fatty acid esters such as dC 2 o-alkyl-C ⁇ o-C 22 fatty acid esters, as can be obtained, for example, by transesterification of the aforementioned glycerol or glycol fatty acid esters such as C 10 -C 22 fatty acid esters with C 1 -C 2 o-alcohols (for example methanol, ethanol, propanol or butanol).
  • the transesterification can be carried out according to known methods, as described, for example, in the Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
  • Preferred alkyl fatty acid esters such as C 1 -C 2 -alkyl-C 0 -C 22 fatty acid esters are methyl esters, ethyl esters, propyl esters, butyl esters, 2-ethyl hexyl esters and dodecyl esters.
  • Preferred glycol and glycerol fatty acid esters such as C ⁇ o-C 22 fatty acid esters are the uniform or mixed glycol esters and glycerol esters of C ⁇ o-C 2 fatty acids, in particular those fatty acids with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular Cis fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
  • Animal oils c) are generally known and commercially available.
  • the term animal oils in the sense of the present invention means, for example, oils of animal origin, such as walnut oil, cod liver oil, musk oil or mink oil.
  • Vegetable oils c) are generally known and commercially available.
  • vegetable oils in the sense of the present invention means, for example, oils from oil-producing plant species such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, safflower oil, walnut oil, peanut oil, olive oil or castor oil, in particular rapeseed oil their transesterification products are also understood, for example alkyl esters such as rapeseed oil methyl ester or rapeseed oil ethyl ester.
  • oils from oil-producing plant species such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, safflower oil, walnut oil, peanut oil, olive oil or castor oil, in particular rapeseed oil their transesterification products are also understood, for example alkyl esters such as rapeseed oil methyl ester or rapeseed oil ethyl ester.
  • the vegetable oils are preferably esters of C 10 -C22, preferably C12-C20 fatty acids.
  • the C ⁇ o-C 22 fatty acid esters are, for example, esters of unsaturated or saturated C ⁇ o-C2 2 fatty acids, especially with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and especially C 8 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
  • Examples of vegetable oils are -C 0 -C 22 fatty acid esters of glycerol or glycol with the C ⁇ o-C 22 fatty acids, or -C-C 2 o-alkyl-C ⁇ o-C 22 fatty acid esters, such as those obtained by transesterification of the
  • the aforementioned glycerol or glycol C 22 C 22 fatty acid esters with dC 2 o-alcohols for example methanol, ethanol, propanol or butanol
  • the transesterification can be carried out according to known methods, as described, for example, in the Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
  • the vegetable oils can in the novel adjuvants for example in the form of commercially available vegetable oils, in particular rapeseed oils, such as Rapsölmethylester such Phytorob®B (Novance, France), Edenor® MESU and Agnique®ME series (Cognis, Germany) Radia ® series (ICI) , Prilube ® series (Petrofina) or biodiesel or in the form of commercially available vegetable oil-containing formulation additives, in particular those based on rapeseed oils such as rapeseed oil methyl ester, e.g.
  • rapeseed oils such as Rapsölmethylester such Phytorob®B (Novance, France), Edenor® MESU and Agnique®ME series (Cognis, Germany) Radia ® series (ICI) , Prilube ® series (Petrofina) or biodiesel
  • rapeseed oils such as Rapsölmethylester such Phytorob®B (Novance, France),
  • Hasten® (Victorian Chemical Company, Australia, hereinafter referred to as Hasten, main component: rapeseed oil ethyl ester), Actirob®B ( Novance, France, hereinafter ActirobB , main component: rapeseed oil methyl ester), Rako-Binol® (Bayer AG, Germany, hereinafter called Rako-Binol, main component: rapeseed oil), Renol® (Stefes, Germany, hereinafter referred to as Renol, vegetable oil component: rapeseed oil methyl ester) or Stefes Mero® (Stefes, Germany, hereinafter called Mero, main ingredient: rapeseed oil methyl ester).
  • Examples of synthetic fatty acid esters are, for example, those derived from fatty acids with an odd number of carbon atoms, such as drC 2 ⁇ fatty acid esters.
  • Preferred organic solvents are aromatic hydrocarbons, aliphatic hydrocarbons and fatty acid esters such as vegetable oils such as triglycerides of fatty acids having 10 to 22 carbon atoms, which can be both saturated and unsaturated, linear or branched and optionally carry further functional groups, such as corn oil, rapeseed oil, Sunflower seed oil, cottonseed oil, linseed oil, soybean oil, coconut oil, palm oil, safflower oil or castor oil, and their transesterification products such as fatty acid alkyl esters, and mixtures thereof.
  • vegetable oils such as triglycerides of fatty acids having 10 to 22 carbon atoms, which can be both saturated and unsaturated, linear or branched and optionally carry further functional groups, such as corn oil, rapeseed oil, Sunflower seed oil, cottonseed oil, linseed oil, soybean oil, coconut oil, palm oil, safflower oil or castor oil, and their transesterification products such as fatty acid al
  • the solvents can be contained alone or in a mixture.
  • the solvent or solvent mixture used preferably has a low solvency for the phenylsulfonamides used (component a).
  • the total solvent content in the oil suspension concentrates according to the invention is generally between 5 and 95% by weight, preferably in the range between 20 and 80% by weight.
  • the proportion of polar solvents such as aprotic, polar is generally below 20% by weight, preferably in the range from 0 to 10% by weight.
  • the sulfosuccinates (component d) contained in the oil suspension concentrates according to the invention can be, for example, mono- or diesters of sulfosuccinic acid, preferably those of the general formula (III) R 1 - (X ⁇ ) nO-CO-CH 2 -CH (SO 3 M) -CO-O- (X 2 ) mR 2 (III)
  • R C ⁇ -C 30 alkyl or C 7 -C 1 is H or an unsubstituted or substituted C ⁇ -C3-o-hydrocarbon radical, such as 30 alkylaryl
  • R 2 is H or an unsubstituted or substituted C ⁇ -C30 hydrocarbon radical such as C ⁇ -C 30 denotes alkyl or C -C 3 o-alkylaryl, or is a cation, for example a
  • Metal cation such as an alkali or alkaline earth metal cation, or a
  • Ammonium cation such as NH 4 , alkyl, alkylaryl or poly (arylalkyl) phenylammonium cation, X 1 , X 2 independently of one another, identically or differently, represent a spacer unit such as a polyether unit or a polyester unit, n, m independently of one another, identically or differently, zero or 1 are, preferably are zero, and M is a cation, for example a metal cation such as an alkali metal or
  • Alkaline earth metal cation or an ammonium cation such as NH 4 , alkyl, alkylaryl or poly (arylalkyl) phenylammonium cation.
  • Sulfosuccinates contained according to the invention are, for example a1) sulfosuccinate esterified once or twice with linear, cyclic or branched aliphatic, cycloaliphatic and / or aromatic alcohols, for example with 1 to 22 carbon atoms in the alkyl radical, preferably once or twice with methanol, ethanol, (Iso) propanol, (iso) butanol, (iso) pentanol, (iso) hexanol, cyclohexanol, (iso) heptanol, (iso) octanol (especially: ethylhexanol), (iso) nonanol, (iso) decanol, (iso) undecanol, (iso) dodecanol or (iso) tridecanol esterified mono- or dialkalisulfosuccinate, in particular mono- or disodium sulfos
  • Examples of commercially available sulfosuccinates from groups a1) to a5) which are preferred in the context of the present invention are listed below: a1) sodium dialkyl sulfosuccinate, for example sodium di (C 4 -C 8 ) alkyl sulfosuccinate such as sodium diisooctyl sulfosuccinate, preferably sodium di ( 2-ethylhexyl) sulfosuccinate, commercially for example in the form of the Aerosol ® brands (Cytec), the Agrilan ® or Lankropol ® brands (Akzo Nobel), the Empimin ® brands (Albright & Wilson), the Cropol ® brands (Croda) , the Lutensit ® brands (BASF), the Triton ® brands (Union Carbide), the Geropon ® brands (Rhodia) or the Imbirol ® , Madeol ® or Polirol ® brands (Cesalpinia),
  • Sulfosuccinates are commercially available, for example, as an aerosol ® - (Cytec), Agrilan® ® - or Lankropol ® - (Akzo Nobel), Empimin ® - (Huntsman). Cropol ® - (Croda), Lutensit ® - (BASF), Triton ® GR series (UnionCarbide), lmbirol ® - / Madeol ® - / Polirol ® - (Cesalpinia); Geropon ® AR series or Geropon ® SDS (Rhodia) available.
  • Preferred sulfosuccinates are e.g. the sodium, potassium and ammonium salts of bis (alkyl) sulfosuccinates, the alkyl radicals, identically or differently, containing 4 to 16 carbon atoms, and preferably butyl, hexyl, octyl such as 2-ethylhexyl or decyl radicals, which are linear or can be branched.
  • the total proportion of the sulfosuccinate or sulfosuccinates in the oil suspension concentrates according to the invention is generally between 0.1 and 60% by weight, in particular in the range between 0.5 and 30% by weight.
  • auxiliaries and additives (component f) in the oil suspension concentrates according to the invention e.g. still included: surfactants such as emulsifiers and dispersants, thickeners and thixotropic agents, wetting agents, anti-drift agents, adhesives, penetrants, preservatives and antifreeze agents, antioxidants, solubilizers, fillers, carriers and dyes, defoamers, fertilizers, Evaporation inhibitors, as well as agents that influence pH and viscosity.
  • surfactants such as emulsifiers and dispersants, thickeners and thixotropic agents, wetting agents, anti-drift agents, adhesives, penetrants, preservatives and antifreeze agents, antioxidants, solubilizers, fillers, carriers and dyes, defoamers, fertilizers, Evaporation inhibitors, as well as agents that influence pH and viscosity.
  • Suitable emulsifiers and dispersants are e.g. nonionic emulsifiers and dispersants in question, e.g .:
  • alkyl radical which is derived from the corresponding fatty acids or from petrochemical products, and • 1 to 100, preferably 2 to 50, ethylene oxide units (EO), wherein the free hydroxyl group to be alkoxylated,
  • di- and tri-block copolymers for example of alkylene oxides, for example of ethylene and propylene oxide, with average molar masses between 200 and 10,000, preferably 1000 to 4000 g / mol, the mass fraction of the polyethoxylated block varying between 10 and 80%, such as B. Genapol ® PF series (Clariant), Pluronic ® series (BASF), or Synperonic ® PE series (Uniqema),
  • nonionic emulsifiers and dispersants are, for example, polyethoxylated alcohols, polyethoxylated triglycerides which contain hydroxy fatty acids and polyethylene oxide-polypropylene oxide block copolymers.
  • the total proportion of nonionic emulsifiers and dispersants in the oil suspension concentrates according to the invention is generally between 0 and 20% by weight.
  • nonionic emulsifiers and dispersants in addition to their emulsifying / dispersing properties, also to increase the biological effectiveness, for. B. used as a penetration or adhesive, their proportion in the oil suspension concentrates according to the invention can increase to up to 60% by weight.
  • Ionic emulsifiers and dispersants are also suitable, for example:
  • alkali metal and alkaline earth metal salts of alkylarylsulfonic acids having a linear or branched alkyl chain such as phenylsulfonate CA or phenylsulfonate CAL (Clariant), Atlox ® 3377BM (ICI), Empiphos ® TM series (Huntsman)
  • Polyelectrolytes such as lignin sulfonates, condensation products of naphthalene sulfonate and formaldehyde, polystyrene sulfonate or sulfonated unsaturated or aromatic polymers (polystyrenes, polybutadienes or polyterpenes), such as Tamol ® series (BASF), Morwet ® D425 (Witco), Kraftsperse ® series ), Borresperse ® series (Borregard).
  • lignin sulfonates condensation products of naphthalene sulfonate and formaldehyde
  • polystyrene sulfonate or sulfonated unsaturated or aromatic polymers such as Tamol ® series (BASF), Morwet ® D425 (Witco), Kraftsperse ® series ), Borresperse ® series (Borregard).
  • Preferred ionic emulsifiers / dispersants are, for example, salts of alkylarylsulfonic acids and polyelectrolytes from the polycondensation of naphthalenesulfonate and formaldehyde.
  • the total proportion of ionic emulsifiers and dispersants in the oil suspension concentrates according to the invention is generally between 0 and 20% by weight, in particular between 0 and 8% by weight.
  • thickening and thixotropic agents are e.g. in question:
  • modified natural silicates such as chemically modified bentonites, hectorites, attapulgites, montmorillonites, smectites or other silicate minerals, such as Bentone ® (Elementis), Attagel ® (Engelhard), Agsorb ® (Oil-Dri Corporation) or Hectorite ® (Akzo Nobel)
  • silicates such as silicates from the Sipernat ® , Aerosil ® or Durosil ® series (Degussa), the CAB-O-SIL ® series (Cabot) or the Van Gel series (RT Vanderbilt),
  • Thickeners based on synthetic polymers such as Thixin ® - or (Elementis).
  • Thickeners based on natural polymers and natural oils eg from the Thixin ® or Thixatrol ® series (Elementis).
  • Preferred thickeners and thixotropic agents are e.g. modified layered silicates and thickeners based on synthetic polymers.
  • the proportion of thickeners and thixotropic agents in the oil suspension concentrates according to the invention is generally between 0 and 5% by weight, in particular between 0.2 and 3% by weight.
  • Oil suspension concentrates according to the invention are preferred, comprising: a) 0.1 to 30% by weight of one or more herbicidal active compounds from the group of the sulfonamides, b) 2 to 40% by weight of one or more safeners, c) 20 to 80% by weight. % of one or more solvents, d) 0.5 to 30% by weight of one or more sulfosuccinates, e) 3 to 20% by weight of one or more agrochemical active substances different from a) and b), f) 0 to 20% by weight of one or more nonionic emulsifiers and dispersants,
  • the oil suspension concentrate a) according to the invention contains one or more herbicidal active compounds of the formula (I) or formula (IV) and / or their salts, preferably A1.1 to A19.2, b) a safener from the group S1-1 , S1 -9 and S2-1, c) an organic solvent from the group of aliphatic hydrocarbons, the mixtures of aromatic and aliphatic hydrocarbons and vegetable oils such as rapeseed oil methyl ester, and d) an alkali di (C 4 -Ci8) alkylsulfosuccinate such as sodium Di (C 4 - C 18 ) alkyl sulfosuccinate.
  • a safener from the group S1-1 , S1 -9 and S2-1
  • an organic solvent from the group of aliphatic hydrocarbons, the mixtures of aromatic and aliphatic hydrocarbons and vegetable oils such as rapeseed oil methyl ester
  • Oil suspension concentrates according to the invention which contain the components mentioned below should be mentioned as particularly preferred examples, without any intention that this should impose a restriction.
  • sulfonamides can also be combined with one another as component a).
  • component a) e.g. different phenylsulfonylureas of the formula (II) and / or their salts are combined with one another, e.g. Mesosulfuron-methyl + iodosulfuron-methyl, mesosulfuron-methyl + iodosulfuron-methyl-sodium, mesosulfuron-methyl + foramsulfuron, mesosulfuron-methyl + foramsulfuron-sodium, mesosulfuron-methyl-sodium + iodosulfuron-methyl, mesosulfuron-ethyl-sodium + iodosulfuron methyl-sodium, mesosulfuron-methyl-sodium + foramsulfuron, mesosulfuron-methyl-sodium + foramsulfuron, mesosulfuron-methyl-sodium + foramsulfuron
  • the sulfonamides a) and their mixtures e.g. the aforementioned active ingredient mixtures of phenylsulfonylureas of the formula (II) and / or their salts can be combined with one or more safeners, in particular with the safeners mefenpyr-diethyl (S1-1), fenchlorazol-ethyl (S1-6), isoxadifen-ethyl (S1-9), Cloquintocet-mexyl (S2-1) and (S3-1).
  • the safeners mefenpyr-diethyl (S1-1), fenchlorazol-ethyl (S1-6), isoxadifen-ethyl (S1-9), Cloquintocet-mexyl (S2-1) and (S3-1).
  • All of the aforementioned combinations can also contain one or more agrochemical active substances (e), in particular selected from the group (E1), (EU), (E1.2), (E1.3), (E1.4), (E1.5 ), (E2), (E2.1), (E2.2), (E2.3), (E2.4), (E2.5), (E2.6), (E2.7), (E2.8), (E2.9), (E3), (E3.1), (E3.2), (E3.3), (E4), (E4.1), (E4.2), (E5), (E5.1), (E5.2), (E6), (E6.1), (E6.2), (E6.3), (E6.4), (E6.5).
  • agrochemical active substances e
  • E agrochemical active substances
  • phenylsulfonylaminocarbonyltriazolinones contained as component a in particular those of the formula (I) such as flucarbazones or propoxycarbazones, and heteroarylsulfonylaminocarbonyltriazolinones, in particular those of the formulas (IV), (VI) and (VII), e.g. known from WO 03/026427, e.g.
  • mixtures of several sulfonamides are present as component a) in the oil suspension concentrates according to the invention, e.g. the above-mentioned mixtures of sulfonylureas of the formula (II) and / or their salts, at least one of the sulfonamides is in suspended form; all sulfonamides can also be present in suspension.
  • the oil suspension concentrates according to the invention can be prepared by known processes, for example by mixing the components.
  • a premix can be prepared, the sulfosuccinate d) being dissolved in the organic solvent c) and, if appropriate, further auxiliaries and additives f) being added to this solution.
  • any soluble agrochemical active ingredients b) and e) used are dissolved in the premix.
  • solid sulfonamide a) and any insoluble active ingredients b) and e) used are suspended in the mixture.
  • the coarse suspension is subjected to fine grinding, if necessary after pre-grinding.
  • solid sulfonamide a) and any insoluble components b), e) and f) used are suspended in a mixture of the organic solvent c) and the sulfosuccinate d) and subjected to grinding.
  • Any soluble active ingredients b) and e) used, and auxiliaries and additives from f), which do not require grinding or are not necessary for the grinding process, are added after the grinding.
  • Common mixers can be used to produce the mixtures, which can be tempered if necessary.
  • pre-grinding e.g. High pressure homogenizers or mills operating according to the rotor-stator principle are used, such as Ultraturax homogenizers, e.g. from IKA, or tooth colloid mills, e.g. from Puck.
  • ultraturax homogenizers e.g. from IKA
  • tooth colloid mills e.g. from Puck
  • fine grinding e.g. discontinuous bead mills, e.g. from Drais or continuous bead mills, e.g. Bachofen can be used.
  • the manufacturing process can be adapted and, if necessary, pre-grinding or fine grinding can be dispensed with.
  • Components a) to f) used for the preparation can contain water as a secondary component, which is found in the oil suspension concentrates according to the invention.
  • the oil suspension concentrates according to the invention can therefore contain small amounts of water, generally from 0 to 5% by weight.
  • the oil suspension concentrates according to the invention are preferably not subjected to any further drying process.
  • the oil suspension concentrates according to the invention can optionally be diluted in a customary manner, for example to form suspensions, emulsions, suspoemulsions or solutions, preferably suspensions, for example by means of water. It may be advantageous to obtain further agrochemical active ingredients obtained from spray liquors (for example tank mixing partners in the form of corresponding formulations) and / or auxiliaries and additives customary for use, for example self-emulsifying oils such as vegetable oils or paraffin oils and / or fertilizers. The present invention therefore also relates to such herbicidal compositions based on the oil suspension concentrates according to the invention.
  • the herbicidal compositions according to the invention have excellent herbicidal activity against a broad spectrum of economically important mono- and dicotyledonous harmful plants. Perennial weeds that are difficult to control and that sprout from rhizomes, rhizomes or other permanent organs are also well recorded.
  • the funds can e.g. are applied in the pre-sowing, pre-emergence or post-emergence process.
  • some representatives of the monocotyledonous and dicotyledonous weed flora may be mentioned, which can be controlled by the herbicidal compositions according to the invention, without any restriction to certain species being mentioned.
  • the spectrum of activity extends to species such as Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp. such as Galium aparine, Ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp., Polygonum spp., Sida spp., Sinapis spp., Solanum spp., Stellaria spp., Veronica spp. and Viola spp., Xanthium spp., on the annual side, and convolvulus, cirsium, rumex and artemisia in the perennial weeds.
  • Harmful plants occurring in the rice under the specific culture conditions such as, for example, Echinochloa, Sagittaria, Alisma, Eleocharis, Scirpus and Cyperus, are also superbly combated by the agents according to the invention. If the herbicidal compositions according to the invention are applied to the surface of the earth before germination, either weed seedlings are prevented completely or the weeds grow to the cotyledon stage, but then stop growing and finally die completely after three to four weeks.
  • the herbicidal compositions according to the invention are notable for a rapid onset and long-lasting herbicidal action.
  • the rain resistance of the active ingredients in the combinations according to the invention is generally favorable.
  • a particular advantage is the fact that the effective dosages of herbicidal compounds used in the herbicidal compositions can be set so low that their soil action is optimally low. This makes their use not only possible in sensitive crops, but groundwater contamination is practically avoided.
  • the combination of active substances according to the invention enables a considerable reduction in the amount of active substances required.
  • the herbicidal compositions according to the invention have excellent herbicidal activity against mono- and dicotyledon weeds, they will Cultivated plants of economically important crops, for example dicotyledonous crops such as soybean, cotton, rapeseed, sugar beet, or Gramineae crops such as wheat, barley, rye, oats, millet, rice or corn, are only insignificantly damaged or not at all.
  • dicotyledonous crops such as soybean, cotton, rapeseed, sugar beet, or Gramineae crops
  • wheat, barley, rye, oats, millet, rice or corn are only insignificantly damaged or not at all.
  • the present compounds are very suitable for the selective control of undesired plant growth in agricultural crops or in ornamental crops.
  • the herbicidal compositions according to the invention have excellent growth-regulating properties in crop plants. They intervene regulating the plant's own metabolism and can thus be used to influence plant constituents in a targeted manner and to facilitate harvesting, e.g. by triggering desiccation and stunted growth. Furthermore, they are also suitable for general control and inhibition of undesirable vegetative growth without killing the plants. Inhibiting vegetative growth plays a major role in many monocotyledonous and dicotyledonous crops, as this can reduce or completely prevent storage.
  • the herbicidal compositions according to the invention can also be used to control harmful plants in crops of known or still to be developed genetically modified plants.
  • the transgenic plants are generally distinguished by special advantageous properties, for example resistance to certain pesticides, especially certain herbicides, resistance to plant diseases or pathogens of plant diseases such as certain insects or microorganisms such as fungi, bacteria or viruses.
  • Other special properties concern e.g. B. the crop in terms of quantity, quality, shelf life, composition and special ingredients.
  • Transgenic plants with an increased starch content or altered starch quality or with a different fatty acid composition of the crop are known.
  • the agents according to the invention in economically important transgenic crops of useful and ornamental plants, for. B. from Gramineen- Cultures such as wheat, barley, rye, oats, millet, rice and corn or also crops of sugar beet, cotton, soybean, rapeseed, potato, tomato, pea and other vegetables.
  • the agents according to the invention can preferably be used as herbicides in crops which are resistant to the phytotoxic effects of the herbicides or have been made resistant to genetic engineering.
  • the herbicidal compositions according to the invention are used in transgenic crops, in addition to the effects on harmful plants which can be observed in other crops, there are often effects which are specific to the application in the respective transgenic crop, for example a changed or specially expanded weed spectrum which can be controlled, changed application rates that can be used for the application, preferably good combinability with the herbicides to which the transgenic crop is resistant, and influencing the growth and yield of the transgenic crop plants.
  • the present invention furthermore also relates to a process for controlling unwanted vegetation, preferably in crops such as cereals (for example wheat, barley, rye, oats, rice, corn, millet), sugar beet, sugar cane, rape, cotton and soybeans, particularly preferably in monocotyledon crops such as cereals, e.g. Wheat, barley, rye, oats, crosses thereof such as triticale, rice, corn and millet, one or more herbicidal compositions according to the invention being applied to the harmful plants, parts of plants, plant seeds or the area on which the plants grow, e.g. applied the acreage.
  • crops such as cereals (for example wheat, barley, rye, oats, rice, corn, millet), sugar beet, sugar cane, rape, cotton and soybeans, particularly preferably in monocotyledon crops such as cereals, e.g. Wheat, barley, rye, oats, crosses thereof such as tritica
  • the plant cultures can also be genetically modified or obtained by mutation selection and are preferably tolerant of acetolactate synthase (ALS) inhibitors.
  • ALS acetolactate synthase
  • the oil suspension concentrate of the present invention has excellent chemical stability during manufacture and storage and is suitable especially for combinations of active substances with different physico-chemical properties, e.g. B. a poorly soluble in organic solvents herbicidal phenylsulfonamide with a soluble safener and optionally other soluble agrochemical active ingredients.
  • the oil suspension concentrate has excellent physical stability, good applicability and user-friendliness, as well as high biological effectiveness and selectivity.
  • oil suspension concentrates mentioned in the examples below were prepared as follows: A premix was prepared, the sulfosuccinate d) being dissolved in the solvent c) and the further auxiliaries and additives f) being added to this solution. Then the safener b) was dissolved in the premix. After the solution process was complete, solid sulfonamide a) was suspended in the mixture. The coarse suspension was subjected to fine grinding after pre-grinding.
  • Iodosulfuron 3- (4-methoxy-6-methyl-1, 3,5-triazin-2-yl) -1- (2-methoxycarbonyl-5-iodophenylsulfonyl) urea
  • Emulsogen ® EL-400 polyethoxylated castor oil with 40 units
  • the concentration of iodosulfuron was determined by means of HPLC before and after the preparation of the oil suspension concentrate.
  • the concentration of iodosulfuron was determined by means of HPLC before and after the preparation of the oil suspension concentrate and after 8 weeks of storage at 40 ° C.
  • the concentration of thifensulfuron was determined by means of HPLC before and after the preparation of the oil suspension concentrate.
  • Example 3.2 according to the invention showed a significantly higher chemical stability than comparative example 3.1.

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Abstract

The invention relates to an oil suspension concentrate containing: a) one or more herbicidal active substances selected from the group of sulfonamides and provided in suspended form; b) one or more safeners; c) one or more organic solvents, and; d) one or more sulfosuccinates. The oil suspension concentrate is suited for use in the field of plant protection.

Description

Beschreibungdescription
ÖlsuspensionskonzentratOil suspension concentrate
Die vorliegende Erfindung betrifft das Gebiet der Pflanzenschutzmittelformulierungen. Insbesondere betrifft die Erfindung flüssige Formulierungen in Form von Ölsuspensionskonzentraten, welche herbizide Wirkstoffe aus der Gruppe der Sulfonamide, insbesondere der Phenylsulfonamide und Heteroarylsulfonamide enthalten.The present invention relates to the field of crop protection formulations. In particular, the invention relates to liquid formulations in the form of oil suspension concentrates which contain herbicidal active compounds from the group of the sulfonamides, in particular the phenylsulfonamides and heteroarylsulfonamides.
Wirkstoffe für den Pflanzenschutz werden im allgemeinen nicht in ihrer reinen Form eingesetzt. In Abhängigkeit von dem Anwendungsgebiet und der Anwendungsart, sowie von physikalischen, chemischen und biologischen Parametern wird der Wirkstoff in Mischung mit üblichen Hilfs- und Zusatzstoffen als Wirkstoffformulierung eingesetzt. Auch die Kombinationen mit weiteren Wirkstoffen zur Erweiterung des Wirkungsspektrum und/oder zum Schutz der Kulturpflanzen (z.B. durch Safener, Antidote) sind bekannt.Active substances for crop protection are generally not used in their pure form. Depending on the area of application and the type of application, as well as on physical, chemical and biological parameters, the active ingredient is used in a mixture with customary auxiliaries and additives as an active ingredient formulation. Combinations with other active ingredients to expand the spectrum of activity and / or to protect crop plants (e.g. through safeners, antidotes) are also known.
Formulierungen von Wirkstoffen für den Pflanzenschutz sollten im allgemeinen eine hohe chemische und physikalische Stabilität, eine gute Applizierbarkeit und Anwenderfreundlichkeit und eine breite biologische Wirkung mit hoher Selektivität aufweisen.Formulations of active substances for crop protection should generally have high chemical and physical stability, good applicability and user-friendliness and a broad biological action with high selectivity.
Herbizide Wirkstoffe aus der Gruppe der Sulfonamide, wie Sulfonylharnstoffe, weisen im allgemeinen ein hohes Maß an chemischer Reaktivität auf und neigen zum chemischen Abbau, z.B. durch Hydrolyse.Herbicidal agents from the group of the sulfonamides, such as sulfonylureas, generally have a high degree of chemical reactivity and tend to chemical degradation, e.g. by hydrolysis.
Eine Möglichkeit chemisch labile Wirkstoffe zu formulieren, ist die Herstellung fester Formulierungen. So sind Formulierungen von Wirkstoffen aus der Gruppe der Sulfonylharnstoffe, in Form von Pulvern, Granulaten und Tabletten bekannt (z. B. in EP 764404, WO 9834482, WO 9313658). Die Verfahren zur Herstellung von festen Formulierungen, z.B. in Form von Granulaten und Tabletten sind jedoch im allgemeinen aufwendig, insbesondere wenn niedrig schmelzende Wirkstoffe oder Hilfs- und Zusatzstoffe eingearbeitet werden. Außerdem sind feste Formulierungen im allgemeinen schwieriger zu applizieren und weniger anwenderfreundlich.One way to formulate chemically labile active ingredients is to produce solid formulations. Formulations of active substances from the group of sulfonylureas, in the form of powders, granules and tablets, are known (for example in EP 764404, WO 9834482, WO 9313658). However, the processes for the production of solid formulations, for example in the form of granules and tablets, are generally complex, in particular if active ingredients which have a low melting point or Auxiliaries and additives are incorporated. In addition, solid formulations are generally more difficult to apply and less user-friendly.
Flüssige Formulierungen von Sulfonylharnstoffen sind z.B. beschrieben inLiquid formulations of sulfonylureas are e.g. described in
US 4599412, US 4683000, US 4671817, EP 0245058, WO 01/82693, EP 0313317,US 4599412, US 4683000, US 4671817, EP 0245058, WO 01/82693, EP 0313317,
EP 0514768, EP 0163598 und EP 0514769.EP 0514768, EP 0163598 and EP 0514769.
Die Aufgabe der vorliegenden Erfindung bestand darin, eine verbesserte Pflanzenschutzmittelformulierung zur Verfügung zu stellen, welche eine hohe chemische Stabilität sowie eine hohe biologische Effektivität und Kulturpflanzenverträglichkeit aufweist.The object of the present invention was to provide an improved crop protection formulation which has high chemical stability and high biological effectiveness and crop tolerance.
Diese Aufgabe wird gelöst durch das spezielle Ölsuspensionskonzentrat der vorliegenden Erfindung.This object is achieved by the special oil suspension concentrate of the present invention.
Die vorliegende Erfindung betrifft somit ein Ölsuspensionskonzentrat, enthaltend a) ein oder mehrere herbizide Wirkstoffe aus der Gruppe der Sulfonamide, in suspendierter Form, b) ein oder mehrere Safener, c) ein oder mehrere organische Lösungsmittel, und d) ein oder mehrere Sulfosuccinate.The present invention thus relates to an oil suspension concentrate comprising a) one or more herbicidal active compounds from the group of the sulfonamides, in suspended form, b) one or more safeners, c) one or more organic solvents, and d) one or more sulfosuccinates.
Darüber hinaus kann das erfindungsgemäße Ölsuspensionskonzentrat als weitere Komponenten gegebenenfalls noch enthalten: e) einen oder mehrere von a) und b) verschiedene agrochemische Wirkstoffe, und f) übliche Hilfs- und Zusatzstoffe.In addition, the oil suspension concentrate according to the invention may optionally also contain further components: e) one or more agrochemical active ingredients different from a) and b), and f) customary auxiliaries and additives.
Unter dem Begriff Ölsuspensionskonzentrat (OD) wird ein Suspensionskonzentrat auf Basis organischer Lösungsmittel verstanden. Dabei sind ein oder mehrere Wirkstoffe in dem organischen Lösungsmittel suspendiert, weitere Wirkstoffe können in dem organischen Lösungsmittel gelöst sein. In dem erfindungsgemäßen Ölsuspensionskonzentrat liegt das Sulfonamid a) in suspendierter Form in dem organischen Lösungsmittel vor. Dies bedeutet, daß der Hauptanteil (in Gew.-%) an Sulfonamid ungelöst in fein verteilter Form vorliegt, ein geringerer Teil des Sulfonamids kann gelöst vorliegen. Vorzugsweise ist das Sulfonamid im organischen Lösungsmittel zu mehr als 80 Gew.-%, besonders bevorzugt zu mehr als 90 Gew.-% suspendiert, jeweils bezogen auf die Gesamtmenge an Sulfonamid in dem erfindungsgemäßen Ölsuspensionskonzentrat.The term oil suspension concentrate (OD) is understood to mean a suspension concentrate based on organic solvents. One or more active ingredients are suspended in the organic solvent, further active ingredients can be dissolved in the organic solvent. In the oil suspension concentrate according to the invention, the sulfonamide a) is present in suspended form in the organic solvent. This means that the main part (in% by weight) of sulfonamide is undissolved in finely divided form, a smaller part of the sulfonamide can be in solution. The sulfonamide is preferably suspended in the organic solvent to more than 80% by weight, particularly preferably to more than 90% by weight, in each case based on the total amount of sulfonamide in the oil suspension concentrate according to the invention.
Als Sulfonamide a) bevorzugt sind Phenylsulfonamide und Heteroarylsulfonamide und sonstige Sulfonamide wie Amidosulfuron. Als Phenylsulfonamide a) kommen beispielsweise Verbindungen aus der Gruppe derPreferred sulfonamides a) are phenylsulfonamides and heteroarylsulfonamides and other sulfonamides such as amidosulfuron. Examples of phenylsulfonamides a) are compounds from the group of
Phenylsulfonylaminocarbonyltriazolinone oder der Phenylsulfonylhamstoffe, bevorzugt aus der Gruppe der Phenylsulfonylhamstoffe in Frage. Unter dem Begriff Phenylsulfonylhamstoffe werden auch solche Sulfonylharnstoffe verstanden, bei denen die Phenylgruppe über einen Spacer wie CH2, O oder NH an die Sulfongruppe (SO2) gebunden ist. Beispiele fürPhenylsulfonylaminocarbonyltriazolinone or the phenylsulfonylureas, preferably from the group of phenylsulfonylureas in question. The term phenylsulfonylureas is also taken to mean those sulfonylureas in which the phenyl group is bonded to the sulfone group (SO 2 ) via a spacer such as CH 2 , O or NH. examples for
Phenylsulfonylaminocarbonyltriazolinone sind Flucarbazone oder Propoxycarbazone und/oder deren Salze. Die Sulfonamide a) sind kommerziell erhältlich und/oder nach bekannten Verfahren herstellbar wie sie z.B. beschrieben sind in EP-A-7687, EP-A- 30138, US 5,057,144 und US 5,534,486.Phenylsulfonylaminocarbonyltriazolinone are Flucarbazone or Propoxycarbazone and / or their salts. The sulfonamides a) are commercially available and / or can be prepared by known processes such as those e.g. are described in EP-A-7687, EP-A-30138, US 5,057,144 and US 5,534,486.
Als Phenylsulfonamide kommen beispielsweise Phenylsulfonamide der allgemeinen Formel (I) und/oder deren Salze in Frage,Examples of suitable phenylsulfonamides are phenylsulfonamides of the general formula (I) and / or their salts,
Rα-(A)m-SO2-NRß-CO-(NRγ)n - Rδ (I) worin Rα ein Phenylrest ist, der unsubstituiert oder substituiert ist, und wobei derR α - (A) m -SO 2 -NR ß -CO- (NR γ ) n - R δ (I) wherein R α is a phenyl radical which is unsubstituted or substituted, and wherein the
Phenylrest inklusive Substituenten 1-30 C-Atome, vorzugsweise 1-20 C-Phenyl radical including substituents 1-30 C-atoms, preferably 1-20 C-
Atome aufweist, Rß ein Wasserstoffatom oder ein Kohlenwasserstoffrest ist, der unsubstituiert oder substituiert ist und inklusive Substituenten 1-10 C-Atome aufweist, z.B. unsubstituiertes oder substituiertes Cι-C6-Alkyl, vorzugsweise einHas atoms, R ß is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and includes 1-10 C atoms including substituents, for example unsubstituted or substituted C 1 -C 6 alkyl, preferably a
Wasserstoffatom oder Methyl, Rγ ein Wasserstoffatom oder ein Kohlen wasserstoffrest ist, der unsubstituiert oder substituiert ist und inklusive Substituenten 1-10 C-Atome aufweist, z.B. unsubstituiertes oder substituiertes Cι-C6-Alkyl, vorzugsweise einHydrogen atom or methyl, R γ is a hydrogen atom or a hydrocarbon residue which is unsubstituted or substituted and has substituents 1-10 C atoms, for example unsubstituted or substituted C 1 -C 6 -alkyl, preferably a
Wasserstoffatom oder Methyl, A gleich CH2, O oder NH, vorzugsweise O, ist, m gleich Null oder 1, n gleich Null oder 1 , vorzugsweise gleich 1 , und Rδ ein heterocyclischer Rest wie ein Pyridylrest, ein Triazinylrest oder einIs hydrogen or methyl, A is CH 2 , O or NH, preferably O, m is zero or 1, n is zero or 1, preferably 1, and R δ is a heterocyclic radical such as a pyridyl radical, a triazinyl radical or a
Triazolinonrest ist.Triazolinonerest is.
Bevorzugte Phenylsulfonamide sind Phenylsulfonylhamstoffe, beispielsweise Phenylsulfonylhamstoffe der allgemeinen Formel (II) und/oder deren Salze,Preferred phenylsulfonamides are phenylsulfonylureas, for example phenylsulfonylureas of the general formula (II) and / or their salts,
Rα-(A)m-SO2-NRß-CO-NR7 - Rδ (ll) worin Rα ein Phenylrest ist, der unsubstituiert oder substituiert ist, und wobei derR α - (A) m -SO 2 -NR ß -CO-NR 7 - R δ (II) wherein R α is a phenyl radical which is unsubstituted or substituted, and wherein the
Phenylrest inklusive Substituenten 1-30 C-Atome, vorzugsweise 1-20 C-Phenyl radical including substituents 1-30 C-atoms, preferably 1-20 C-
Atome aufweist, Rß ein Wasserstoffatom oder ein Kohlen wasserstoffrest ist, der unsubstituiert oder substituiert ist und inklusive Substituenten 1-10 C-Atome aufweist, z.B. unsubstituiertes oder substituiertes Ci-Cβ-Alkyl, vorzugsweise einHas atoms, R ß is a hydrogen atom or a hydrocarbon residue which is unsubstituted or substituted and has substituents including 1-10 C atoms, for example unsubstituted or substituted Ci-Cβ-alkyl, preferably a
Wasserstoff atom oder Methyl, Rγ ein Wasserstoffatom oder ein Kohlen wasserstoffrest ist, der unsubstituiert oder substituiert ist und inklusive Substituenten 1-10 C-Atome aufweist, z.B. unsubstituiertes oder substituiertes Ci-Cβ-Alkyl, vorzugsweise einHydrogen atom or methyl, R γ is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and has substituents including 1-10 C atoms, for example unsubstituted or substituted Ci-Cβ-alkyl, preferably a
Wasserstoffatom oder Methyl, A gleich CH2, O oder NH, vorzugsweise O, ist, m gleich Null oder 1 , und Rδ ein heterocyclischer Rest wie ein Pyridylrest oder ein Triazinylrest ist. Bevorzugt sind Phenylsulfonylhamstoffe der Formel (III) und/oder deren Salze,Is hydrogen or methyl, A is CH 2 , O or NH, preferably O, m is zero or 1, and R δ is a heterocyclic radical such as a pyridyl radical or a triazinyl radical. Phenylsulfonylureas of the formula (III) and / or their salts are preferred,
Figure imgf000006_0001
worin R4 C-ι-C4-Alkoxy, vorzugsweise C2-C4-Alkoxy, oder CO-Ra ist, worin Ra gleich
Figure imgf000006_0001
wherein R 4 is C 1 -C 4 alkoxy, preferably C 2 -C 4 alkoxy, or CO-R a , where R a is the same
OH, C-ι-C4-Alkoxy oder NRbRc ist, worin Rb und Rc unabhängig voneinander gleich oder verschieden H oder Cι-C4-Alkyl sind,Is OH, C 1 -C 4 alkoxy or NR b R c , in which R b and R c are, independently of one another, the same or different H or C 1 -C 4 alkyl,
R Halogen, vorzugsweise lod, oder (A)n-NRdRe ist, worin n gleich Null oder 1 ist,R is halogen, preferably iodine, or (A) n -NR d R e , where n is zero or 1,
A eine Gruppe CR'R" ist, worin R' und R" unabhängig voneinander gleich oder verschieden H oder Cι-C4-Alkyl sind, Rd gleich H oder Cι-C -Alkyl ist und Re ein Acylrest wie Formyl oder Cι-C4-Alkyl-Sulfonyl ist, und R5 für den Fall, daßA is a group CR'R ", in which R 'and R" are, independently of one another, the same or different H or C 1 -C 4 alkyl, R d is H or C 1 -C 4 alkyl and R e is an acyl radical such as formyl or Cι -C 4 alkyl sulfonyl, and R 5 in the event that
R4 gleich Cι-C4-Alkoxy, vorzugsweise C2-C -Alkoxy, bedeutet auch H sein kann,R 4 is C 1 -C 4 -alkoxy, preferably C 2 -C -alkoxy, can also be H,
R6 H oder Cι-C4-Alkyl ist, m gleich Null oder 1 ist,R 6 is H or -CC 4 alkyl, m is zero or 1,
X und Y unabhängig voneinander gleich oder verschieden Halogen oder NR'R", worin R' und R" gleich oder verschieden H oder Cι-C -Alkyl sind, oder C-ι-C6- Alkyl, CrCe-Alkoxy, CrCe-Alkylthio, C3-C6-Cycloalkyl, C2-C6-Alkenyl, C2-C6- Alkynyl, C3-C6-Alkenyloxy oder C3-C6-Alkynyloxy sind, wobei jeder der acht letztgenannten Reste unsubstituiert oder durch einen oder mehrere Reste aus der Gruppe Halogen, Cι-C4-Alkoxy und Cι-C4-Alkylthio substituiert ist, vorzugsweise C1-C4-Alkyl oder Cι-C -Alkoxy, undX and Y independently of one another are identical or different halogen or NR'R ", where R 'and R" are identical or different H or C 1 -C 6 alkyl, or C 1 -C 6 alkyl, CrCe alkoxy, CrCe alkylthio , C 3 -C 6 cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 alkenyloxy or C 3 -C 6 alkynyloxy, each of the eight latter radicals being unsubstituted or by one or more radicals from the group halogen, Cι-C 4 alkoxy and Cι-C 4 alkylthio is substituted, preferably C 1 -C 4 alkyl or Cι-C alkoxy, and
Z gleich CH oder N ist.Z is CH or N.
Besonders bevorzugt sind Phenylsulfonylhamstoffe der allgemeinen Formel (III) und/oder deren Salze, worin a) R4 gleich CO-(CrC4-Alkoxy) ist, R5 gleich Halogen, vorzugsweise Jod ist, oder R5 gleich CH2-NHRe ist, worin Re ein Acylrest, vorzugsweise CrC4-Alkyl-Sulfonyl ist, und m gleich Null ist, b) R4 gleich CO-N(Cι-C4-Alkyl)2l R5 gleich NHRe ist, worin Re ein Acylrest, vorzugsweise Formyl ist, und m gleich Null ist, oder c) R4 gleich C2-C4-Alkoxy, R5 gleich H und m gleich 1 ist.Phenylsulfonylureas of the general formula (III) and / or their salts are particularly preferred, in which a) R 4 is CO- (CrC 4 -alkoxy), R 5 is halogen, preferably iodine, or R 5 is CH 2 -NHR e is where R e is an acyl radical, preferably CrC 4 alkyl sulfonyl, and m is zero, b) R 4 is CO-N (-CC 4 alkyl) 2l R 5 is NHR e , wherein R e is an acyl radical, preferably formyl, and m is zero, or c) R 4 is C 2 -C 4 -alkoxy, R 5 is H and m is 1.
Typische Phenylsulfonylhamstoffe sind unter anderem die nachfolgend aufgeführten Verbindungen und deren Salze wie die Natriumsalze: Bensulfuron-methyl, Chlorimuron-Ethyl, Chlorsulfuron, Cinosulfuron, Cyclosulfamuron, Ethametsulfuron- methyl, Ethoxysulfuron und dessen Natriumsalz, Metsulfuron-methyl, Oxasulfuron, Primisulfuron-methyl, Prosulfuron, Sulfometuron-methyl, Triasulfuron, Tribenuron- methyl, Triflusulfuron-methyl, Tritosulfuron, lodosulfuron-methyl und dessen Natriumsalz (WO 92/13845), Mesosulfuron-methyl und dessen Natriumsalz (Agrow Nr. 347, 3. März 2000, Seite 22 (PJB Publications Ltd. 2000)) und Foramsulfuron und dessen Natriumsalz (Agrow Nr. 338, 15. Oktober 1999, Seite 26 (PJB Publications Ltd. 1999)).Typical phenylsulfonylureas include the compounds listed below and their salts, such as the sodium salts: bensulfuron-methyl, chlorimuron-ethyl, chlorosulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron-methyl, ethoxysulfuron and its sodium salt, metsulfuron-methyl, primisulfuron , Sulfometuron-methyl, triasulfuron, tribenuron-methyl, triflusulfuron-methyl, tritosulfuron, iodosulfuron-methyl and its sodium salt (WO 92/13845), mesosulfuron-methyl and its sodium salt (Agrow No. 347, March 3, 2000, page 22 ( PJB Publications Ltd. 2000)) and foramsulfuron and its sodium salt (Agrow No. 338, October 15, 1999, page 26 (PJB Publications Ltd. 1999)).
Besonders bevorzugte Phenylsulfonamide sind: lodosulfuron-methyl (A1.1) und dessen Natriumsalz (A1.2), Mesosulfuron-methyl (A2.1) und dessen Natriumsalz (A2.2), Foramsulfuron (A3.1) und dessen Natriumsalz (A3.2), Flucarbazone (A4.1) und dessen Natriumsalz (A4.2), Propoxycarbazone (A5.1) und dessen Natriumsalz (A5.2) und Ethoxysulfuron (A6.1) und dessen Natriumsalz (A6.2), Metsulfuron- methyl (A7.1) und dessen Natriumsalz {/Kl.2), Tribenuron-methyl (A8.1) und dessen Natriumsalz (A8.2), Chlorsulfuron (A9.1) und dessen Natriumsalz (A9.2).Particularly preferred phenylsulfonamides are: iodosulfuron-methyl (A1.1) and its sodium salt (A1.2), mesosulfuron-methyl (A2.1) and its sodium salt (A2.2), foramsulfuron (A3.1) and its sodium salt (A3 .2), Flucarbazone (A4.1) and its sodium salt (A4.2), Propoxycarbazone (A5.1) and its sodium salt (A5.2) and ethoxysulfuron (A6.1) and its sodium salt (A6.2), metsulfuron - methyl (A7.1) and its sodium salt {/Kl.2), tribenuron-methyl (A8.1) and its sodium salt (A8.2), chlorosulfuron (A9.1) and its sodium salt (A9.2).
Die vorstehend aufgeführten Wirkstoffe sind z.B. bekannt aus „The Pesticide Manual", 12. Auflage (2000), The British Crop Protection Council oder den nach den einzelnen Wirkstoffen aufgeführten Literaturstellen.The active ingredients listed above are e.g. known from "The Pesticide Manual", 12th edition (2000), The British Crop Protection Council or the literature references listed according to the individual active ingredients.
Als Heteroarylsulfonamide a) kommen beispielsweise Verbindungen aus der Gruppe der Heteroarylsulfonylaminocarbonyltriazolinone oder der Heteroarylsulfonylharnstoffe, bevorzugt aus der Gruppe der Heteroarylsulfonylharnstoffe in Frage. Unter dem Begriff Heteroarylsulfonylharnstoffe werden auch solche Sulfonylharnstoffe verstanden, bei denen die Heteroarylgruppe über einen Spacer wie CH2, O oder NH an die Sulfongruppe (SO2) gebunden ist.Examples of suitable heteroarylsulfonamides a) are compounds from the group of heteroarylsulfonylaminocarbonyltriazolinones or heteroarylsulfonylureas, preferably from the group of heteroarylsulfonylureas. Under the term heteroarylsulfonylureas are also understood to be those sulfonylureas in which the heteroaryl group is bonded to the sulfone group (SO 2 ) via a spacer such as CH 2 , O or NH.
Als Heteroarylsulfonamide kommen beispielsweise Sulfonamide der allgemeinen Formel (IV) und/oder deren Salze in Frage,Examples of suitable heteroarylsulfonamides are sulfonamides of the general formula (IV) and / or their salts,
Rα'-(Ai)m-SO2-NRß'-CO-(NRγ')n' - Rδ' (IV) worin Rα' ein Heteroarylrest ist, der unsubstituiert oder substituiert ist, und wobei derR α ' - (A i ) m-SO 2 -NR ß' -CO- (NR γ ') n' - R δ ' (IV) wherein R α ' is a heteroaryl radical which is unsubstituted or substituted, and wherein the
Heteroarylrest inklusive Substituenten 1-30 C-Atome, vorzugsweise 1-20 C-Heteroaryl radical including substituents 1-30 C atoms, preferably 1-20 C
Atome aufweist, Rßl ein Wasserstoffatom oder ein Kohlenwasserstoffrest ist, der unsubstituiert oder substituiert ist und inklusive Substituenten 1-10 C-Atome aufweist, z.B. unsubstituiertes oder substituiertes Cι-C6-Alkyl, vorzugsweise ein Has atoms, R ßl is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and including substituents has 1-10 C atoms, for example unsubstituted or substituted C 1 -C 6 -alkyl, preferably a
Wasserstoffatom oder Methyl, R7' ein Wasserstoffatom oder ein Kohlenwasserstoffrest ist, der unsubstituiert oder substituiert ist und inklusive Substituenten 1-10 C-Atome aufweist, z.B. unsubstituiertes oder substituiertes Ci-Cβ-Alkyl, vorzugsweise einIs hydrogen atom or methyl, R 7 'is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and has substituents including 1-10 C atoms, for example unsubstituted or substituted Ci-Cβ-alkyl, preferably a
Wasserstoffatom oder Methyl, A' gleich CH2, O oder NH, vorzugsweise O, ist, m' gleich Null oder 1 , n' gleich Null oder 1 , vorzugsweise gleich 1 , und Rδ' ein heterocyclischer Rest wie ein Pyridylrest, ein Triazinylrest oder einIs hydrogen or methyl, A 'is CH 2 , O or NH, preferably O, m' is zero or 1, n 'is zero or 1, preferably 1, and R δ ' is a heterocyclic radical such as a pyridyl radical, a triazinyl radical or a
Triazolinonrest ist.Triazolinonerest is.
Bevorzugte Heteroarylsulfonamide sind Heteroarylsulfonylharnstoffe, beispielsweise Sulfonylharnstoffe der allgemeinen Formel (V) und/oder deren Salze,Preferred heteroarylsulfonamides are heteroarylsulfonylureas, for example sulfonylureas of the general formula (V) and / or their salts,
Rα'-(A')m'-SO2-N Rß'-CO-N Rv' - Rδ' (V) worin R°" ein Heteroarylrest ist, der unsubstituiert oder substituiert ist, und wobei derR α ' - (A') m ' -SO 2 -NR ß' -CO-N R v ' - R δ' (V) wherein R ° "is a heteroaryl radical which is unsubstituted or substituted, and wherein the
Heteroarylrest inklusive Substituenten 1-30 C-Atome, vorzugsweise 1-20 C-Heteroaryl radical including substituents 1-30 C atoms, preferably 1-20 C
Atome aufweist, Rß' ein Wasserstoffatom oder ein Kohlenwasserstoffrest ist, der unsubstituiert oder substituiert ist und inklusive Substituenten 1-10 C-Atome aufweist, z.B. unsubstituiertes oder substituiertes C-ι-C6-Alkyl, vorzugsweise einHas atoms, R ß 'is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and including substituents has 1-10 C atoms, for example unsubstituted or substituted C 1 -C 6 -alkyl, preferably a
Wasserstoffatom oder Methyl, Rγ< ein Wasserstoffatom oder ein Kohlenwasserstoffrest ist, der unsubstituiert oder substituiert ist und inklusive Substituenten 1-10 C-Atome aufweist, z.B. unsubstituiertes oder substituiertes Ci-Cβ-Alkyl, vorzugsweise einIs hydrogen atom or methyl, R γ <is a hydrogen atom or a hydrocarbon radical which is unsubstituted or substituted and has, including substituents, 1-10 C atoms, for example unsubstituted or substituted Ci-Cβ-alkyl, preferably a
Wasserstoffatom oder Methyl, A' gleich CH2, O oder NH, vorzugsweise O, ist, m' gleich Null oder 1 , und Rδ< ein heterocyclischer Rest wie ein Pyridylrest oder ein Triazinylrest ist.Is hydrogen or methyl, A 'is CH 2 , O or NH, preferably O, m' is zero or 1, and R δ <is a heterocyclic radical such as a pyridyl radical or a triazinyl radical.
Besonders bevorzugt sind Heteroarylsulfonamide der nachfolgend genannten Formel (VI),Heteroarylsulfonamides of the formula (VI) mentioned below are particularly preferred,
R— Sθ - NH-CO— (NR")rf— Rδ' (VI)R - Sθ - NH-CO— (NR ") rf - R δ '(VI)
,worin,wherein
Rαι ein substituierter Heteroarylrest, wie substituiertes Pyridyl, Thienyl,R αι a substituted heteroaryl such as substituted pyridyl, thienyl,
Pyrazolyl oder Imidazolyl, Rγ' H, (C C3)Alkyl, optional substituiert mit Halogen (F, C, Br, I) oderPyrazolyl or imidazolyl, R γ 'H, (CC 3 ) alkyl, optionally substituted with halogen (F, C, Br, I) or
(Halo)Alkoxy (Cι-C3), bevorzugt H oder Methyl, für n' gleich 1 , Rδ' ein Pyridylrest oder ein Triazinylrest ist, vorzugsweise(Halo) alkoxy (-C-C 3 ), preferably H or methyl, for n 'is 1, R δ ' is a pyridyl radical or a triazinyl radical, preferably
Figure imgf000009_0001
und für n' gleich Null, Rδi ein Triazolinonrest ist, vorzugsweise
Figure imgf000010_0001
Figure imgf000009_0001
and for n 'is zero, R δi is a triazolinone radical , preferably
Figure imgf000010_0001
R7 (Cι-Cιo)Alkyl, welches optional substituiert ist mit Halogen (F, Cl, Br, I) oder (d-C3)Halo-Alkyl,R 7 (-C-Cιo) alkyl, which is optionally substituted with halogen (F, Cl, Br, I) or (dC 3 ) halo-alkyl,
R8 (Cι-Cιo)Alkyl, welches optional substituiert ist mit Halogen (F, Cl, Br, I) oder (C C3)Halo-Alkyl,R 8 (Cι-Cιo) alkyl, which is optionally substituted with halogen (F, Cl, Br, I) or (CC 3 ) haloalkyl,
X und Y unabhängig voneinander gleich oder verschieden Halogen oder NR'R", worin R' und R" gleich oder verschieden H oder Cι-C4-Alkyl sind, oder d- Ce-Alkyl, CrC6-Alkoxy, C C6-Alkylthio, C3-C6-Cycloalkyl, C2-C6-Alkenyl, C2-C6-Alkynyl, C3-C6-Alkenyloxy oder C3-C6-Alkynyloxy sind, wobei jeder der acht letztgenannten Reste unsubstituiert oder durch einen oder mehrere Reste aus der Gruppe Halogen, Cι-C4-Alkoxy und Cι-C - Alkylthio substituiert ist, vorzugsweise Cι-C4-Alkyl oder Cι-C4-Alkoxy.X and Y are independently the same or different halogen or NR'R ", where R 'and R" are the same or different H or -CC 4 alkyl, or d-Ce alkyl, CrC 6 alkoxy, CC 6 alkylthio , C 3 -C 6 cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 alkenyloxy or C 3 -C 6 alkynyloxy, each of the eight latter radicals being unsubstituted or is substituted by one or more radicals from the group halogen, C 1 -C 4 alkoxy and C 1 -C 4 alkylthio, preferably C 1 -C 4 alkyl or C 1 -C 4 alkoxy.
Besonders bevorzugt ist Rαι gleichR αι is particularly preferably the same
Figure imgf000010_0002
Figure imgf000010_0002
Figure imgf000010_0003
Figure imgf000010_0003
, worin R9 (Cι-C6)Alkyl, (CrC6)Alkoxy, (C2-C6)Alkenyloxy, (C2-C6)Alkinyloxy, (Cι-C6)Alkylsulfonyl, (Cι-C6)Alkylcarbonyl, (CrCeJAlkoxycarbonyl, (C2-C6)Alkenyloxycarbonyl, (C2-C6)Alkinyloxycarbonyl, CONR'R", (Cι-C6)Halo-Alkyl, (C C6)Halo-Alkoxy, (C2-C6)Halo-Alkenyloxy, (C2-C6)Halo-Alkinyloxy, (Cι-C6)Halo-Alkylsulfonyl, (Cι-C6)Halo-Alkylcarbonyl, (Cι-C6)Halo-Alkoxycarbonyl, (C2-C6)Halo-Alkenyloxycarbonyl, (C2-C6)Halo-Alkinyloxycarbonyl,, wherein R 9 (-C-C 6 ) alkyl, (CrC 6 ) alkoxy, (C 2 -C 6 ) alkenyloxy, (C 2 -C 6 ) alkynyloxy, (Cι-C 6 ) alkylsulfonyl, (Cι-C 6 ) Alkylcarbonyl, (CrCeJalkoxycarbonyl, (C 2 -C 6 ) alkenyloxycarbonyl, (C 2 -C 6 ) alkynyloxycarbonyl, CONR'R ", (Cι-C 6 ) haloalkyl, (CC 6 ) haloalkoxy, (C 2 - C 6 ) halo-alkenyloxy, (C 2 -C 6 ) halo-alkynyloxy, (-C-C 6 ) halo-alkylsulfonyl, (-C-C 6 ) halo-alkylcarbonyl, (Cι-C 6 ) halo-alkoxycarbonyl, (C 2 -C 6 ) halo-alkenyloxycarbonyl, (C 2 -C 6 ) halo-alkynyloxycarbonyl,
R10 H, (d-C3)Alkyl, (d-C3)Alkoxy, (Cι-C3)Halo-Alkyl, (Cι-C3)Halo-Alkoxy oderR 10 H, (dC 3 ) alkyl, (dC 3 ) alkoxy, (Cι-C 3 ) halo-alkyl, (Cι-C 3 ) halo-alkoxy or
Halogen (F, Cl, Br, I),Halogen (F, Cl, Br, I),
I Null oder 1 ,I zero or 1,
R11 (Cι-C6)Alkyl, (C C6)Alkoxy, (C2-C6)Alkenyloxy, (C2-C6)Alkinyloxy,R 11 (-CC 6 ) alkyl, (CC 6 ) alkoxy, (C 2 -C 6 ) alkenyloxy, (C 2 -C 6 ) alkynyloxy,
(Cι-C6)Alkylsulfonyl, (d-C6)Alkylcarbonyl, (CrC6)Alkoxycarbonyl, (C2-C6)Alkenyloxycarbonyl, (C2-C6)Alkinyloxycarbonyl, (Cι-Ce)Halo-Alkyl, (CrC6)Halo-Alkoxy, (C2-C6)Halo-Alkenyloxy, (C2-C6)Halo-Alkinyloxy, (Ci- C6)Halo-Alkylsulfonyl, (Cι-C6)Halo-Alkylcarbonyl, (Cι-C6)Halo- Alkoxycarbonyl, (C2-C6)Halo-Alkenyloxycarbonyl, (C2-C6)Halo- Alkinyloxycarbonyl, CONR'R",(-C-C 6 ) alkylsulfonyl, (dC 6 ) alkylcarbonyl, (CrC 6 ) alkoxycarbonyl, (C 2 -C 6 ) alkenyloxycarbonyl, (C 2 -C 6 ) alkynyloxycarbonyl, (Cι-Ce) haloalkyl, (CrC 6 ) Halo-alkoxy, (C 2 -C 6 ) halo-alkenyloxy, (C 2 -C 6 ) halo-alkynyloxy, (Ci- C 6 ) halo-alkylsulfonyl, (Cι-C 6 ) halo-alkylcarbonyl, (Cι- C 6 ) haloalkoxycarbonyl, (C 2 -C 6 ) haloalkenyloxycarbonyl, (C 2 -C 6 ) haloalkynyloxycarbonyl, CONR'R ",
R12 Halogen (F, Cl, Br, I), (d-C6)Alkyl, (d-C6)Alkoxy, (C C6)Alkylsulfonyl,R 12 halogen (F, Cl, Br, I), (dC 6 ) alkyl, (dC 6 ) alkoxy, (CC 6 ) alkylsulfonyl,
(Cι-C6)Alkoxycarbonyl, (C2-C6)Alkenyloxycarbonyl, (C2- C6)Alkinyloxycarbonyl, (C C6)Halo-AIkyl, (d-C6)Halo-Alkoxy, (d- C6)Halo-Alkylsulfonyl, (d-C6)Halo-Alkoxycarbonyl, (C2-C6)Halo- Alkenyloxycarbonyl, (C2-C6)HaIo-Alkinyloxycarbonyl,(Cι-C 6 ) alkoxycarbonyl, (C 2 -C 6 ) alkenyloxycarbonyl, (C 2 - C 6 ) alkynyloxycarbonyl, (CC 6 ) haloalkyl, (dC 6 ) haloalkoxy, (d- C 6 ) halo- Alkylsulfonyl, (dC 6 ) haloalkoxycarbonyl, (C 2 -C 6 ) haloalkenyloxycarbonyl, (C 2 -C 6 ) haloalkynyloxycarbonyl,
R13 (Cι-C6)Alkoxycarbonyl, (C2-C6)Alkenyloxycarbonyl, (C2-R 13 (-CC 6 ) alkoxycarbonyl, (C 2 -C 6 ) alkenyloxycarbonyl, (C 2 -
C6)Alkinyloxycarbonyl, (C C6)Alkyl, (CrC6)Alkoxy, (C1-C6)Alkylsulfonyl, (Cι-C6)Halo-Alkoxycarbonyl, (C2-C6)Halo-Alkenyioxycarbonyl, (C2- C6)Halo-Alkinyloxycarbonyl, (Cι-C6)Halo-Alkyl, (C1-C6)Halo-Alkoxy, (d- C6)Halo-Alkylsulfonyl, Halogen (F, Cl, Br, I), CONR'R", oder R13 ist ein heterocylischer Ring der gesättigt, ungesättigt oder aromatisch sein kann und vorzugsweise 4-6-Ringatome und eines oder mehrere Heteroatome aus der Gruppe N, O, S enthält, und optional durch einen oder mehrere Substituenten, vorzugsweise aus der Gruppe (d-C3)Alkyl, (Cι-C3)Alkoxy, (d-C3)Halo-Alkyl, (d-C3)Halo-Alkoxy oder Halogen substituiert sein kann, besonders bevorzugtC 6 ) alkynyloxycarbonyl, (CC 6 ) alkyl, (C r C 6 ) alkoxy, (C 1 -C 6 ) alkylsulfonyl, (Cι-C 6 ) haloalkoxycarbonyl, (C 2 -C 6 ) halo-alkenyioxycarbonyl, ( C 2 - C 6 ) halo-alkynyloxycarbonyl, (-C-C 6 ) halo-alkyl, (C 1 -C 6 ) halo-alkoxy, (d- C 6 ) halo-alkylsulfonyl, halogen (F, Cl, Br, I ), CONR'R ", or R 13 is a heterocyclic ring which can be saturated, unsaturated or aromatic and preferably contains 4-6 ring atoms and one or more heteroatoms from the group N, O, S, and optionally by one or more Substituents, preferably from the group (dC 3 ) alkyl, (-C-C 3 ) alkoxy, (dC 3 ) halo-alkyl, (dC 3 ) halo-alkoxy or halogen can be substituted, particularly preferred
Figure imgf000011_0001
R14 H, Halogen (F, C, Br, I), (Cι-C6)Alkyl, (d-C6)Halo-Alkyl,
Figure imgf000011_0001
R 14 H, halogen (F, C, Br, I), (-C-C 6 ) alkyl, (dC 6 ) halo-alkyl,
R15 H, (d-C6)Alkyl, (d-C6)Halo-Alkyl,R 15 H, (dC 6 ) alkyl, (dC 6 ) haloalkyl,
R16 (Cι-C6)Alkyl, (d-C6)Alkoxy, (C2-C6)Alkenyloxy, (C2-C6)Alkinyloxy, (d-R 16 (-CC 6 ) alkyl, (dC 6 ) alkoxy, (C 2 -C 6 ) alkenyloxy, (C 2 -C 6 ) alkynyloxy, (d-
C6)Alkylsulfonyl, (Cι-C6)Alkylcarbonyl, (Cι-C6)Alkoxycarbonyl, (C2- C6)Alkenyloxycarbonyl, (C2-C6)Alkinyloxycarbonyl, (Cι-C6)Halo-Alkyl, (d- C6)Halo-Alkoxy, (C2-C6)Halo-AIkenyloxy, (C2-C6)Halo-Alkinyloxy, (d- C6)Halo-Alkylsulfonyl, (d-C6)Halo-Alkylcarbonyl, (Cι-C6)Halo- Alkoxycarbonyl, (C2-C6)Halo-Alkenyloxycarbonyl, (C2-C6)Halo- Alkinyloxycarbonyl, CONR'R", insbesondere SO2Ethyl, undC 6 ) alkylsulfonyl, (Cι-C 6 ) alkylcarbonyl, (Cι-C 6 ) alkoxycarbonyl, (C 2 - C 6 ) alkenyloxycarbonyl, (C 2 -C 6 ) alkynyloxycarbonyl, (Cι-C 6 ) haloalkyl, ( d- C 6 ) haloalkoxy, (C 2 -C 6 ) haloalkenyloxy, (C 2 -C 6 ) haloalkynyloxy, (d- C 6 ) haloalkylsulfonyl, (dC 6 ) haloalkylcarbonyl, ( Cι-C 6 ) halo-alkoxycarbonyl, (C 2 -C 6 ) halo-alkenyloxycarbonyl, (C 2 -C 6 ) halo-alkynyloxycarbonyl, CONR'R ", in particular SO 2 ethyl, and
R' und R" unabhängig voneinander H, (d-C6)Alkyl, (d-C6)Haloalkyl, (C2-C6)Alkenyl, (C2-C6)Haloalkenyl, (C2-C6)Alkinyl, (C2-C6)Haloalkinyl sind, oder NR'R" bildet einen heterocylischen Ring der gesättigt, ungesättigt oder aromatisch sein kann und vorzugsweise 4-6-Ringatome und eines oder mehrere Heteroatome aus der Gruppe N, O, S enthält, und optional durch einen oder mehrere Substituenten, vorzugsweise aus der Gruppe (Cr C3)Alkyl, (d-C3)Alkoxy, (C C3)Halo-Alkyl, (Cι-C3)Halo-Alkoxy oder Halogen substituiert sein kann.R 'and R "independently of one another are H, (dC 6 ) alkyl, (dC 6 ) haloalkyl, (C 2 -C 6 ) alkenyl, (C 2 -C 6 ) haloalkenyl, (C 2 -C 6 ) alkynyl, (C 2 -C 6 ) are haloalkynyl, or NR'R "forms a heterocyclic ring which can be saturated, unsaturated or aromatic and preferably contains 4-6 ring atoms and one or more heteroatoms from the group N, O, S, and optionally by one or more substituents, preferably from the group (Cr C 3 ) alkyl, (dC 3 ) alkoxy, (CC 3 ) halo-alkyl, (-C-C 3 ) halo-alkoxy or halogen can be substituted.
Besonders bevorzugte Heteroarylsulfonylharnstoffe sind z.B. Nicosulfuron (A10.1) und dessen Salze wie das Natriumsalz (A10.2), Rimsulfuron (A11.1) und dessen Salze wie das Natriumsalz (A11.2), Thifensulfuron-Methyl (A12.1) und dessen Salze wie das Natriumsalz (A12.2), Pyrazosulfuron-Ethyl (A13.1) und dessen Salze wie das Natriumsalz (A13.2), Flupyrsulfuron-Methyl (A14.1) und dessen Salze wie das Natriumsalz (A14.2), Sulfosulfuron (A15.1) und dessen Salze wie das Natriumsalz (A15.2), Trifloxysulfuron (A16.1) und dessen Salze wie das Natriumsalz (A16.2), Azimsulfuron (A17.1) und dessen Salze wie das Natriumsaiz (A17.2), Flazasulfuron (A18.1) und dessen Salze wie das Natriumsalz (A18.2) und Flucetosulfuron (1-[3- [[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-2-pyridinyl]-2- fluoropropyl methoxyacetat, (A19.1)) und dessen Salze wie das Natriumsalz (A 19.2). Besonders bevorzugte Heteroarylsulfonylaminocarbonyltriazolinone sind die nachfolgend genannten Verbindungen der Formel (VII), die z.B. bekannt sind aus WO 03/026427.Particularly preferred heteroarylsulfonylureas are, for example, nicosulfuron (A10.1) and its salts such as the sodium salt (A10.2), rimsulfuron (A11.1) and its salts such as the sodium salt (A11.2), thifensulfuron-methyl (A12.1) and its salts such as the sodium salt (A12.2), pyrazosulfuron-ethyl (A13.1) and its salts such as the sodium salt (A13.2), flupyrsulfuron-methyl (A14.1) and its salts such as the sodium salt (A14.2) , Sulfosulfuron (A15.1) and its salts such as the sodium salt (A15.2), trifloxysulfuron (A16.1) and its salts such as the sodium salt (A16.2), azimsulfuron (A17.1) and its salts such as the sodium salt ( A17.2), flazasulfuron (A18.1) and its salts such as the sodium salt (A18.2) and flucetosulfuron (1- [3- [[[((4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino ] sulfonyl] -2-pyridinyl] -2-fluoropropyl methoxyacetate, (A19.1)) and its salts such as the sodium salt (A 19.2). Particularly preferred heteroarylsulfonylaminocarbonyltriazolinones are the compounds of the formula (VII) mentioned below which are known, for example, from WO 03/026427.
Figure imgf000013_0001
Figure imgf000013_0001
Figure imgf000013_0002
Figure imgf000013_0002
Figure imgf000014_0001
Figure imgf000014_0001
Die vorstehend aufgeführten Wirkstoffe sind z.B. bekannt aus „The Pesticide Manual", 12. Auflage (2000) (PM) und 13. Auflage (2003), The British Crop Protection Council oder den nach den einzelnen Wirkstoffen aufgeführten Literaturstellen.The active ingredients listed above are e.g. known from "The Pesticide Manual", 12th edition (2000) (PM) and 13th edition (2003), The British Crop Protection Council or the literature references listed according to the individual active ingredients.
Unter den in den erfindungsgemäßen Ölsuspensionskonzentraten als Komponente enthaltenen Sulfonamiden a) werden im Sinne der vorliegenden Erfindung sind stets sämtliche Anwendungsformen wie Säuren, Ester, Salze und Isomere wie Stereoisomere und optische Isomere verstanden. So sind neben den neutralen Verbindungen stets auch deren Salze mit anorganischen und/oder organischen Gegenionen zu verstehen. So können Sulfonamide z.B. Salze bilden, bei denen der Wasserstoff der -SO2-NH-Gruppe durch ein für die Landwirtschaft geeignetes Kation ersetzt ist. Diese Salze sind beispielsweise Metallsalze, insbesondere Alkalimetallsalze oder Erdalkalimetallsalze, insbesondere Natrium- und Kaliumsalze, oder auch Ammoniumsalze oder Salze mit organischen Aminen. Ebenso kann Salzbildung durch Anlagerung einer Säure an basischen Gruppen, wie z.B. Amino und Alkylamino, erfolgen. Geeignete Säuren hierfür sind starke anorganische und organische Säuren, beispielsweise HCI, HBr, H2SO oder HNO3. Bevorzugte Ester sind die Alkylester, insbesondere die d-Cio-Alkylester wie Methylester.For the purposes of the present invention, the sulfonamides a) present as a component in the oil suspension concentrates according to the invention always mean all use forms, such as acids, esters, salts and isomers, such as stereoisomers and optical isomers. In addition to the neutral compounds, their salts with inorganic and / or organic counterions are also always to be understood. For example, sulfonamides can form salts in which the hydrogen of the —SO 2 —NH group is replaced by a cation suitable for agriculture. These salts are, for example, metal salts, in particular Alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or also ammonium salts or salts with organic amines. Salt formation can also take place by addition of an acid to basic groups, such as amino and alkylamino. Suitable acids for this are strong inorganic and organic acids, for example HCl, HBr, H 2 SO or HNO 3 . Preferred esters are the alkyl esters, especially the d-Cio-alkyl esters such as methyl esters.
Soweit in dieser Beschreibung der Begriff Acylrest verwendet wird, bedeutet dieser den Rest einer organischen Säure, der formal durch Abspaltung einer OH-Gruppe aus der organischen Säure entsteht, z.B. der Rest einer Carbonsäure und Reste davon abgeleiteter Säuren wie der Thiocarbonsäure, gegebenenfalls N-substituierten Iminocarbonsäuren oder die Reste von Kohlensäuremonoestern, gegebenenfalls N-substituierter Carbaminsäuren, Sulfonsäuren, Sulfinsäuren, Phosphonsäuren, Phosphinsäuren.Insofar as the term acyl radical is used in this description, it means the residue of an organic acid which is formally formed by splitting off an OH group from the organic acid, e.g. the rest of a carboxylic acid and residues derived therefrom, such as thiocarboxylic acid, optionally N-substituted iminocarboxylic acids or the residues of carbonic acid monoesters, optionally N-substituted carbamic acids, sulfonic acids, sulfinic acids, phosphonic acids, phosphinic acids.
Ein Acylrest ist bevorzugt Formyl oder Acyl aus der Gruppe CO-Rz, CS-RZ, CO-ORz, CS-ORz, CS-SRZ, SORz oder SO2Rz, wobei Rz jeweils einen d-C10- Kohlenwasserstoffrest wie CrCio-Alkyl oder C6-do-Aryl bedeutet, der unsubstituiert oder substituiert ist, z.B. durch einen oder mehrere Substituenten aus der Gruppe Halogen wie F, Cl, Br, I, Alkoxy, Haloalkoxy, Hydroxy, Amino, Nitro, Cyano oder Alkylthio, oder Rz bedeutet Aminocarbonyl oder Aminosulfonyl, wobei die beiden letztgenannten Reste unsubstituiert, N-monosubstituiert oder N,N-disubstituiert sind, z.B. durch Substituenten aus der Gruppe Alkyl oder Aryl. Acyl bedeutet beispielsweise Formyl, Halogenalkylcarbonyl, Alkylcarbonyl wie (d-C )Alkylcarbonyl, Phenylcarbonyl, wobei der Phenylring substituiert sein kann, oder Alkyloxycarbonyl, wie (Cι-C4) Alkyloxycarbonyl, Phenyloxycarbonyl, Benzyloxycarbonyl, Alkylsulfonyl, wie (d-C ) Alkylsulfonyl, Alkylsulfinyl, wie C C4(Alkylsulfinyl), N-Alkyl-1-iminoalkyl, wie N-(Cι-C4)-1-imino-(Cι-C4)alkyl und andere Reste von organischen Säuren.An acyl radical is preferably formyl or acyl from the group CO-R z , CS-R Z , CO-OR z , CS-OR z , CS-SR Z , SOR z or SO 2 R z , where R z each has a dC 10 Hydrocarbon radical such as CrCio-alkyl or C 6 -do-aryl which is unsubstituted or substituted, for example by one or more substituents from the group halogen such as F, Cl, Br, I, alkoxy, haloalkoxy, hydroxy, amino, nitro, Cyano or alkylthio, or R z means aminocarbonyl or aminosulfonyl, the latter two radicals being unsubstituted, N-monosubstituted or N, N-disubstituted, for example by substituents from the group consisting of alkyl or aryl. Acyl means, for example, formyl, haloalkylcarbonyl, alkylcarbonyl such as (dC) alkylcarbonyl, phenylcarbonyl, where the phenyl ring can be substituted, or alkyloxycarbonyl, such as (Cι-C 4 ) alkyloxycarbonyl, phenyloxycarbonyl, benzyloxycarbonyl, alkylsulfonyl, such as (dC) alkylsulfonyl, alkylsulfinyl, such as CC 4 (alkylsulfinyl), N-alkyl-1-iminoalkyl, such as N- (-C-C 4 ) -1-imino- (Cι-C 4 ) alkyl and other residues of organic acids.
Ein Kohlenwasserstoffrest bedeutet ein geradkettiger, verzweigter oder cyclischer und gesättigter oder ungesättigter aliphatischer oder aromatischer Kohlenwasserstoffrest, z.B. Alkyl, Aikenyl, Alkinyi, Cycloalkyl, Cycloalkenyl oder Aryl. Ein Kohlenwasserstoffrest weist bevorzugt 1 bis 40 C-Atome, vorzugsweise 1 bis 30 C-Atome auf; besonders bevorzugt bedeutet ein Kohlenwasserstoffrest Alkyl, Aikenyl oder Alkinyi mit bis zu 12 C-Atomen oder Cycloalkyl mit 3, 4, 5, 6 oder 7 Ringatomen oder Phenyl.A hydrocarbon residue means a straight-chain, branched or cyclic and saturated or unsaturated aliphatic or aromatic Hydrocarbon radical, for example alkyl, aikenyl, alkinyi, cycloalkyl, cycloalkenyl or aryl. A hydrocarbon radical preferably has 1 to 40 C atoms, preferably 1 to 30 C atoms; A hydrocarbon radical is particularly preferably alkyl, aikenyl or alkinyi having up to 12 carbon atoms or cycloalkyl having 3, 4, 5, 6 or 7 ring atoms or phenyl.
Aryl bedeutet ein mono-, bi- oder polycyclisches aromatisches System, beispielsweise Phenyl, Naphthyl, Tetrahydronaphthyl, Indenyl, Indanyl, Pentalenyl, Fluorenyl und ähnliches, vorzugsweise Phenyl.Aryl means a mono-, bi- or polycyclic aromatic system, for example phenyl, naphthyl, tetrahydronaphthyl, indenyl, indanyl, pentalenyl, fluorenyl and the like, preferably phenyl.
Ein heterocyclischer Rest oder Ring (Heterocyclyl) kann gesättigt, ungesättigt oder heteroaromatisch und unsubstituiert oder substituiert sein; er enthält vorzugsweise ein oder mehrere Heteroatome im Ring, vorzugsweise aus der Gruppe N, O und S; vorzugsweise ist er ein aliphatischer Heterocyclylrest mit 3 bis 7 Ringatomen oder ein heteroaromatischer Rest mit 5 oder 6 Ringatomen und enthält 1 , 2 oder 3 Heteroatome. Der heterocyclische Rest kann z.B. ein heteroaromatischer Rest oder Ring (Heteroaryl) sein, wie z.B. ein mono-, bi- oder polycyclisches aromatisches System, in dem mindestens 1 Ring ein oder mehrere Heteroatome enthält, beispielsweise Pyridyl, Pyrimidinyl, Pyridazinyl, Pyrazinyl, Triazinyl, Thienyl, Thiazolyl, Oxazolyl, Furyl, Pyrrolyl, Pyrazolyl und Imidazolyl, oder ist ein partiell oder vollständig hydrierter Rest wie Oxiranyl, Oxetanyl, Pyrrolidyl, Piperidyl, Piperazinyl, Triazolyl, Dioxolanyl, Morpholinyl, Tetrahydrofuryl. Bevorzugt sind Pyrimidinyl und Triazinyl. Als Substituenten für einen substituierten heterocyclischen Rest kommen die weiter unten genannten Substituenten in Frage, zusätzlich auch Oxo. Die Oxogruppe kann auch an den Heteroringatomen, die in verschiedenen Oxidationsstufen existieren können, z.B. bei N und S, auftreten.A heterocyclic radical or ring (heterocyclyl) can be saturated, unsaturated or heteroaromatic and unsubstituted or substituted; it preferably contains one or more heteroatoms in the ring, preferably from the group N, O and S; it is preferably an aliphatic heterocyclyl radical with 3 to 7 ring atoms or a heteroaromatic radical with 5 or 6 ring atoms and contains 1, 2 or 3 heteroatoms. The heterocyclic residue can e.g. be a heteroaromatic residue or ring (heteroaryl), e.g. a mono-, bi- or polycyclic aromatic system in which at least 1 ring contains one or more heteroatoms, for example pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl, triazinyl, thienyl, thiazolyl, oxazolyl, furyl, pyrrolyl, pyrazolyl and imidazolyl, or is one partially or fully hydrogenated radical such as oxiranyl, oxetanyl, pyrrolidyl, piperidyl, piperazinyl, triazolyl, dioxolanyl, morpholinyl, tetrahydrofuryl. Pyrimidinyl and triazinyl are preferred. Possible substituents for a substituted heterocyclic radical are the substituents mentioned below, and additionally oxo. The oxo group can also be attached to the hetero ring atoms, which can exist in different oxidation states, e.g. at N and S, occur.
Substituierte Reste, wie substituierte Kohlenwasserstoffreste, z.B. substituiertes Alkyl, Aikenyl, Alkinyi, Aryl, Phenyl und Benzyl, oder substituiertes Heterocyclyl oder Heteroaryl, bedeuten beispielsweise einen vom unsubstituierten Grundkörper abgeleiteten substituierten Rest, wobei die Substituenten beispielsweise einen oder mehrere, vorzugsweise 1 , 2 oder 3 Reste aus der Gruppe Halogen, Alkoxy, Haloalkoxy, Alkylthio, Hydroxy, Amino, Nitro, Carboxy, Cyano, Azido, Alkoxycarbonyl, Alkylcarbonyl, Formyl, Carbamoyl, Mono- und Dialkylaminocarbonyl, substituiertes Amino, wie Acylamino, Mono- und Dialkylamino, und Alkylsulfinyl, Haloalkylsulfinyl, Alkylsulfonyl, Haloalkylsulfonyl und, im Falle cyclischer Reste, auch Alkyl und Haloalkyl sowie den genannten gesättigten kohlenwasserstoffhaltigen Resten entsprechende ungesättigte aliphatische Reste, wie Aikenyl, Alkinyi, Alkenyloxy, Alkinyloxy etc. bedeuten. Bei Resten mit C-Atomen sind solche mit 1 bis 4 C-Atomen, insbesondere 1 oder 2 C-Atomen, bevorzugt. Bevorzugt sind in der Regel Substituenten aus der Gruppe Halogen, z.B. Fluor und Chlor, (d-C )Alkyl, vorzugsweise Methyl oder Ethyl, (d-C )Haloalkyl, vorzugsweise Trifluormethyl, (Cι-C4)Alkoxy, vorzugsweise Methoxy oder Ethoxy, (Cι-C4)Haloalkoxy, Nitro und Cyano. Besonders bevorzugt sind dabei die Substituenten Methyl, Methoxy und Chlor.Substituted radicals, such as substituted hydrocarbon radicals, for example substituted alkyl, aikenyl, alkinyi, aryl, phenyl and benzyl, or substituted heterocyclyl or heteroaryl, mean, for example, a substituted radical derived from the unsubstituted basic body, the substituents being, for example, one or more, preferably 1, 2 or 3 residues from the group halogen, alkoxy, Haloalkoxy, alkylthio, hydroxy, amino, nitro, carboxy, cyano, azido, alkoxycarbonyl, alkylcarbonyl, formyl, carbamoyl, mono- and dialkylaminocarbonyl, substituted amino such as acylamino, mono- and dialkylamino, and alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, haloalkyl in the case of cyclic radicals, also alkyl and haloalkyl, and unsaturated aliphatic radicals, such as aikenyl, alkinyi, alkenyloxy, alkynyloxy, etc., corresponding to the saturated hydrocarbon-containing radicals mentioned. In the case of radicals with carbon atoms, those with 1 to 4 carbon atoms, in particular 1 or 2 carbon atoms, are preferred. As a rule, substituents from the group halogen, for example fluorine and chlorine, (dC) alkyl, preferably methyl or ethyl, (dC) haloalkyl, preferably trifluoromethyl, (C 1 -C 4 ) alkoxy, preferably methoxy or ethoxy, (Cι- C 4 ) Haloalkoxy, Nitro and Cyano. The substituents methyl, methoxy and chlorine are particularly preferred.
Gegebenenfalls substituiertes Phenyl ist vorzugsweise Phenyl, das unsubstituiert oder ein- oder mehrfach, vorzugsweise bis zu dreifach durch gleiche oder verschiedene Reste, vorzugsweise aus der Gruppe Halogen, (Cι-C )Alkyl, (Cι-C )Alkoxy, (Cι-C )Halogenalkyl, (Cι-C4)HalogenaIkoxy und Nitro substituiert ist, z.B. o-, m- und p-Tolyl, Dimethylphenyl, 2-, 3- und 4-Chlorphenyl, 2-, 3- und 4-Trifluor- und -Trichlorphenyl, 2,4-, 3,5-, 2,5- und 2,3-Dichlorphenyl, o-, m- und p-Methoxyphenyl.Optionally substituted phenyl is preferably phenyl which is unsubstituted or one or more times, preferably up to three times, by identical or different radicals, preferably from the group halogen, (-C-C) alkyl, (-C-C) alkoxy, (-C-C) Haloalkyl, (-C-C 4 ) haloalkoxy and nitro is substituted, for example o-, m- and p-tolyl, dimethylphenyl, 2-, 3- and 4-chlorophenyl, 2-, 3- and 4-trifluoro- and trichlorophenyl , 2,4-, 3,5-, 2,5- and 2,3-dichlorophenyl, o-, m- and p-methoxyphenyl.
Cycloalkyl bedeutet ein carbocyclisches, gesättigtes Ringsystem vorzugsweise mit 3-6 C-Atomen, z.B. Cyclopropyl, Cyclobutyl, Cyclopentyl oder Cyclohexyl.Cycloalkyl means a carbocyclic, saturated ring system, preferably with 3-6 C atoms, e.g. Cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl.
Die kohlenstoffhaltigen Reste wie Alkyl, Alkoxy, Haloalkyl, Haloalkoxy, Alkylamino und Alkylthio sowie die entsprechenden ungesättigten und/oder substituierten Reste im Kohlenstoffgerüst jeweils geradkettig oder verzweigt sein. Wenn nicht speziell angegeben, sind bei diesen Resten die niederen Kohlenstoffgerüste, z.B. mit 1 bis 6 C-Atomen bzw. bei ungesättigten Gruppen mit 2 bis 6 C-Atomen, bevorzugt. Alkylreste, auch in den zusammengesetzten Bedeutungen wie Alkoxy, Haloalkyl usw., bedeuten z.B. Methyl, Ethyl, n- oder i-Propyl, n-, i-, t- oder 2-Butyl, Pentyle, Hexyle, wie n-Hexyl, i-Hexyl und 1 ,3-Dimethylbutyl, Heptyle, wie n-Heptyl, 1-Methylhexyl und 1 ,4-Dimethylpentyl; Aikenyl- und Alkinylreste haben die Bedeutung der den Alkylresten entsprechenden möglichen ungesättigten Reste; Aikenyl bedeutet z.B. Allyl, 1-Methylprop-2-en-1-yl, 2-Methyl-prop-2-en-1-yl, But-2-en-1-yl, But-3-en-1-yl, 1-Methyl-but-3-en-1-yl und 1-Methyl-but-2-en-1-yl; Alkinyi bedeutet z.B. Propargyl, But-2-in-1-yl, But-3-in-1-yl, 1-Methyl-but-3-in-1-yl.The carbon-containing radicals such as alkyl, alkoxy, haloalkyl, haloalkoxy, alkylamino and alkylthio and the corresponding unsaturated and / or substituted radicals in the carbon skeleton are each straight-chain or branched. Unless specifically stated, the lower carbon skeletons, for example with 1 to 6 C atoms or, in the case of unsaturated groups, with 2 to 6 C atoms, are preferred for these radicals. Alkyl radicals, also in the composite meanings such as alkoxy, haloalkyl, etc., mean, for example, methyl, ethyl, n- or i-propyl, n-, i-, t- or 2-butyl, pentyls, Hexyls such as n-hexyl, i-hexyl and 1,3-dimethylbutyl, heptyls such as n-heptyl, 1-methylhexyl and 1,4-dimethylpentyl; Aikenyl and alkynyl radicals have the meaning of the possible unsaturated radicals corresponding to the alkyl radicals; Aikenyl means, for example, allyl, 1-methylprop-2-en-1-yl, 2-methyl-prop-2-en-1-yl, but-2-en-1-yl, but-3-en-1-yl , 1-methyl-but-3-en-1-yl and 1-methyl-but-2-en-1-yl; Alkinyi means, for example, propargyl, but-2-in-1-yl, but-3-in-1-yl, 1-methyl-but-3-in-1-yl.
Halogen bedeutet beispielsweise Fluor, Chlor, Brom oder lod. Haloalkyl, -aikenyl und -alkinyi bedeuten durch Halogen, vorzugsweise durch Fluor, Chlor und/oder Brom, insbesondere durch Fluor oder Chlor, teilweise oder vollständig substituiertes Alkyl, Aikenyl bzw. Alkinyi, z.B. CF3, CHF2, CH2F, CF3CF2, CH2FCHCI, CCI3, CHCI2, CH2CH2CI; Haloalkoxy ist z.B. OCF3, OCHF2, OCH2F, CF3CF2O, OCH2CF3 und OCH2CH2CI; entsprechendes gilt für Haloalkenyl und andere durch Halogen substituierte Reste.Halogen means, for example, fluorine, chlorine, bromine or iodine. Haloalkyl, -aikenyl and -alkinyi are partially or completely substituted alkyl, aikenyl or alkinyi, for example CF 3 , CHF 2 , CH 2 F, CF, by halogen, preferably by fluorine, chlorine and / or bromine, in particular by fluorine or chlorine 3 CF 2 , CH 2 FCHCI, CCI 3 , CHCI 2 , CH 2 CH 2 CI; Haloalkoxy is, for example, OCF 3 , OCHF 2 , OCH 2 F, CF 3 CF 2 O, OCH 2 CF 3 and OCH 2 CH 2 CI; the same applies to haloalkenyl and other halogen-substituted radicals.
Die herbiziden Wirkstoffe a) aus der Reihe der Sulfonamide sind in den erfindungsgemäßen Olsuspensionskonzentraten im allgemeinen in Mengen von 0,01 bis 50 Gew.%, bevorzugt 0,1 bis 30 Gew.% enthalten, dabei bezieht sich die Angabe „Gew.%" hier und in der gesamten Beschreibung, wenn nicht anders definiert, auf das relative Gewicht der jeweiligen Komponente bezogen auf das Gesamtgewicht der Formulierung.The herbicidal active substances a) from the series of the sulfonamides are generally present in the oil suspension concentrates according to the invention in amounts of 0.01 to 50% by weight, preferably 0.1 to 30% by weight, the reference “% by weight” being used here. here and throughout the description, unless otherwise defined, on the relative weight of the respective component based on the total weight of the formulation.
Als Komponente b) sind in den erfindungsgemäßen Olsuspensionskonzentraten Safener enthalten, die geeignet sind, Schäden an der Kulturpflanze zu reduzieren oder zu vermeiden. Geeignete Safener sind z.B. aus WO-A-96/14747 und der dort zitierten Literatur bekannt. Die Safener können in dem organischen Lösungsmittel in suspendierter und/oder in gelöster Form, vorzugsweise in gelöster Form vorliegen.As component b), the oil suspension concentrates according to the invention contain safeners which are suitable for reducing or avoiding damage to the crop. Suitable safeners are e.g. known from WO-A-96/14747 and the literature cited therein. The safeners can be present in the organic solvent in suspended and / or in dissolved form, preferably in dissolved form.
Folgende Gruppen von Verbindungen sind beispielsweise als Safener geeignet: 1) Verbindungen vom Typ der Dichlorphenylpyrazolin-3-carbonsäure (S1), vorzugsweise Verbindungen wieThe following groups of compounds are suitable, for example, as safeners: 1) Compounds of the dichlorophenylpyrazoline-3-carboxylic acid (S1) type, preferably compounds such as
1-(2,4-Dichlorphenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazolin-3- carbonsäureethylester (S1-1, Mefenpyr-diethyl, PM S. 781 - 782), und verwandte Verbindungen, wie sie in der WO 91/07874 beschrieben sind,1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3- carboxylic acid ethyl ester (S1-1, mefenpyr-diethyl, PM pp. 781-782), and related compounds, as described in WO 91/07874,
2) Derivate der Dichlorphenylpyrazolcarbonsäure, vorzugsweise Verbindungen wie 1-(2,4-DichIorphenyl)-5-methyl-pyrazol-3-carbonsäureethylester (S1-2), 1-(2,4-DichIorphenyI)-5-isopropyl-pyrazol-3-carbonsäureethylester (S1-3), 1-(2,4-Dichlorphenyl)-5-(1 ,1-dimethyl-ethyl)pyrazol-3-carbonsäureethyl-ester (S1-4), 1-(2,4-Dichlorphenyl)-5-phenyl-pyrazol-3-carbonsäureethylester (S1-5) und verwandte Verbindungen, wie sie in EP-A-333 131 und EP-A-269 806 beschrieben sind.2) Derivatives of dichlorophenylpyrazole carboxylic acid, preferably compounds such as ethyl 1- (2,4-dichlorophenyl) -5-methyl-pyrazole-3-carboxylate (S1-2), 1- (2,4-dichlorophenyI) -5-isopropyl-pyrazole- 3-carboxylic acid ethyl ester (S1-3), 1- (2,4-dichlorophenyl) -5- (1, 1-dimethyl-ethyl) pyrazole-3-carboxylic acid ethyl ester (S1-4), 1- (2,4- Dichlorophenyl) -5-phenyl-pyrazole-3-carboxylic acid ethyl ester (S1-5) and related compounds as described in EP-A-333 131 and EP-A-269 806.
3) Verbindungen vom Typ der Triazolcarbonsäuren (S1), vorzugsweise Verbindungen wie Fenchlorazol, d.h. 1-(2,4-Dichlorphenyl)-5-trichlormethyl-(1 H)-1 ,2,4-triazol-3- carbonsäureethylester (S1-6, Fenchlorazol-ethyl, PM S. 385-386), und verwandte Verbindungen (siehe EP-A-174 562 und EP-A-346 620);3) Compounds of the triazole carboxylic acid (S1) type, preferably compounds such as fenchlorazole, i.e. 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1 H) -1, 2,4-triazole-3-carboxylic acid ethyl ester (S1-6, fenchlorazole-ethyl, PM pp. 385-386), and related compounds (see EP-A-174 562 and EP-A-346 620);
4) Verbindungen vom Typ der 5-Benzyl- oder 5-Phenyl-2-isoxazolin-3- carbonsäure, oder der 5,5-Diphenyl-2-isoxazolin-3-carbonsäure vorzugsweise Verbindungen wie 5-(2,4-Dichlorbenzyl)-2-isoxazolin-3-carbonsäureethylester (S1-7) oder 5-Phenyi-2-isoxazolin-3-carbonsäureethylester (S1-8) und verwandte Verbindungen, wie sie in WO 91/08202 beschrieben sind, bzw. der 5,5-Diphenyl-2-isoxazoIin-carbonsäureethylester (S1-9, Isoxadifen-ethyl) oder -n-propylester (S1-10) oder der 5-(4-Fluorphenyl)-5-phenyl-2-isoxazolin-3- carbonsäureethylester (S1-11), wie sie in der Patentanmeldung (WO-A-95/07897) beschrieben sind.4) Compounds of the 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid type, or the 5,5-diphenyl-2-isoxazoline-3-carboxylic acid, preferably compounds such as 5- (2,4-dichlorobenzyl) Ethyl -2-isoxazoline-3-carboxylate (S1-7) or ethyl 5-phenyi-2-isoxazoline-3-carboxylate (S1-8) and related compounds, as described in WO 91/08202, or 5.5 -Diphenyl-2-isoxazoline-carboxylic acid ethyl ester (S1-9, isoxadifen-ethyl) or -n-propyl ester (S1-10) or the 5- (4-fluorophenyl) -5-phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1 -11), as described in the patent application (WO-A-95/07897).
5) Verbindungen vom Typ der 8-Chinolinoxyessigsäure (S2), vorzugsweise (5-Chlor-8-chinolinoxy)-essigsäure-(1-methyl-hex-1-yl)-ester (S2-1 Cloquintocet-mexyl, PM S. 263 - 264),5) Compounds of the 8-quinolinoxyacetic acid (S2) type, preferably (5-chloro-8-quinolinoxy) acetic acid (1-methyl-hex-1-yl) ester (S2-1 Cloquintocet-mexyl, PM S. 263 - 264),
(5-Chlor-8-chinolinoxy)-essigsäure-(1 ,3-dimethyl-but-1-yl)-ester (S2-2), (5-Chlor-8-chinolinoxy)-essigsäure-4-allyl-oxy-butylester (S2-3), (5-Chlor-8-chinolinoxy)-essigsäure-1-allyloxy-prop-2-ylester (S2-4), (5-Chlor-8-chinolinoxy)-essigsäureethylester (S2-5), (5-Chlor-8-chinolinoxy)-essigsäuremethylester (S2-6), (5-Chlor-8-chinolinoxy)-essigsäureallylester (S2-7), (5-Chlor-8-chinolinoxy)-essigsäure-2-(2-propyliden-iminoxy)-1- ethylester (S2-8),(5-chloro-8-quinolinoxy) -acetic acid- (1,3-dimethyl-but-1-yl) ester (S2-2), (5-chloro-8-quinolinoxy) -acetic acid-4-allyl-oxy -butyl ester (S2-3), (5-chloro-8-quinolinoxy) -acetic acid-1-allyloxy-prop-2-yl ester (S2-4), (5-chloro-8-quinolinoxy) ethyl acetate (S2-5 ), (5-chloro-8-quinolinoxy) -acetic acid methyl ester (S2-6), (5-chloro-8-quinolinoxy) -acetic acid allyl ester (S2-7), (5-chloro-8-quinolinoxy) acetic acid 2- (2-propylidene-iminoxy) -1-ethyl ester (S2-8),
(5-Chlor-8-chinolinoxy)-essigsäure-2-oxo-prop-1-ylester (S2-9) und verwandte Verbindungen, wie sie in EP-A-86 750, EP-A-94 349 und EP-A-191 736 oder EP-A-0 492 366 beschrieben sind.(5-Chloro-8-quinolinoxy) -acetic acid-2-oxo-prop-1-yl ester (S2-9) and related compounds as described in EP-A-86 750, EP-A-94 349 and EP-A -191 736 or EP-A-0 492 366.
6) Verbindungen vom Typ der (5-Chlor-8-chinolinoxy)-malonsäure, vorzugsweise Verbindungen wie (5-Chlor-8-chinolinoxy)-malonsäure- diethylester, (5-Chlor-8-chinolinoxy)-malonsäurediallylester, (5-Chlor-8-chinolinoxy)-malonsäure-methyl-ethylester und verwandte Verbindungen, wie sie in EP-A-0 582 198 beschrieben sind.6) Compounds of the (5-chloro-8-quinolinoxy) malonic acid type, preferably compounds such as (5-chloro-8-quinolinoxy) malonic acid diethyl ester, (5-chloro-8-quinolinoxy) malonic acid diallyl ester, (5- Chloro-8-quinolinoxy) -malonic acid methyl ethyl ester and related compounds as described in EP-A-0 582 198.
7) Wirkstoffe vom Typ der Phenoxyessig- bzw. -propionsäurederivate bzw. der aromatischen Carbonsäuren, wie z.B. 2,4-Dichlorphenoxyessigsäure(ester) (2,4-D), 4-Chlor-2-methyl-phenoxy-propionester (Mecoprop), MCPA oder 3,6-Dichlor-2-methoxy-benzoesäure(ester) (Dicamba).7) Active substances of the phenoxyacetic or propionic acid derivative or aromatic carboxylic acid type, e.g. 2,4-dichlorophenoxyacetic acid (ester) (2,4-D), 4-chloro-2-methylphenoxy-propionester (Mecoprop), MCPA or 3,6-dichloro-2-methoxy-benzoic acid (ester) (Dicamba) ,
8) Wirkstoffe vom Typ der Pyrimidine, wie „Fenclorim" (PM, S. 512-511) (= 4,6- Dichlor-2-phenylpyrimidin),8) active substances of the pyrimidines type, such as “fenclorim” (PM, pp. 512-511) (= 4,6-dichloro-2-phenylpyrimidine),
9) Wirkstoffe vom Typ der Dichloracetamide, die häufig als Vorauflaufsafener (bodenwirksame Safener) angewendet werden, wie z.B.9) Active substances of the dichloroacetamide type which are frequently used as pre-emergence safeners (soil-acting safeners), such as
„Dichlormid" (PM, S. 363-364) (= N,N-Diallyl-2,2-dichloracetamid), „R-29148" (= 3-Dichloracetyl-2,2,5-trimethyl-1 ,3-oxazolidon von der Firma Stauffer),"Dichlormid" (PM, pp. 363-364) (= N, N-diallyl-2,2-dichloroacetamide), "R-29148" (= 3-dichloroacetyl-2,2,5-trimethyl-1,3- oxazolidone from Stauffer),
„Benoxacor" (PM, s. 102-103) (= 4-Dichloracetyl-3,4-dihydro-3-methyl-2H-1 ,4- benzoxazin)."Benoxacor" (PM, see 102-103) (= 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine).
„PPG-1292" (= N-Allyl-N[(1 ,3-dioxolan-2-yl)-methyl]dichloracetamid von der Firma PPG Industries),"PPG-1292" (= N-allyl-N [(1,3-dioxolan-2-yl) methyl] dichloroacetamide from PPG Industries),
„DK-24" (= N-Allyl-N-[(allylaminocarbonyl)-methyl]-dichloracetamid von der Firma Sagro-Chem),"DK-24" (= N-allyl-N - [(allylaminocarbonyl) methyl] dichloroacetamide from Sagro-Chem),
„AD-67" oder „MON 4660" (= 3-Dichloracetyl-1-oxa-3-aza-spiro[4,5]decan von der Firma Nitrokemia bzw. Monsanto),"AD-67" or "MON 4660" (= 3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane from Nitrokemia or Monsanto),
„Dicyclonon" oder „BAS145138" oder „LAB145138" (= (= 3-Dichloracetyi- 2,5,5-trimethyl-1 ,3-diazabiclyco[4.3.0]nonan von der Firma BASF) und „Furilazol" oder „MON 13900" (siehe PM, 637-638) (= (RS)-3-Dichloracetyl-5- (2-furyl)-2,2-dimethyloxazolidon)"Dicyclonon" or "BAS145138" or "LAB145138" (= (= 3-dichloroacetyi-2,5,5-trimethyl-1,3-diazabiclyco [4.3.0] nonane from BASF) and "Furilazole" or "MON 13900" (see PM, 637-638) (= (RS) -3-dichloroacetyl-5- (2-furyl) -2,2-dimethyloxazolidone)
10) Wirkstoffe vom Typ der Dichloracetonderivate, wie z.B.10) Active substances of the dichloroacetone derivative type, e.g.
„MG 191" (CAS-Reg. Nr. 96420-72-3) (= 2-Dichlormethyl-2-methyl-1 ,3- dioxolan von der Firma Nitrokemia),"MG 191" (CAS Reg. No. 96420-72-3) (= 2-dichloromethyl-2-methyl-1,3-dioxolane from Nitrokemia),
11) Wirkstoffe vom Typ der Oxyimino-Verbindungen, die als Saatbeizmittel bekannt sind, wie z.B.11) Oxyimino compound type active ingredients known as seed dressings, e.g.
„Oxabetrinil" (PM, S. 902-903) (= (Z)-1 ,3-DioxoIan-2- ylmethoxyimino(phenyl)acetonitril), das als Saatbeiz-Safener gegen Schäden von Metolachlor bekannt ist,"Oxabetrinil" (PM, pp. 902-903) (= (Z) -1, 3-DioxoIan-2-ylmethoxyimino (phenyl) acetonitrile), which is known as a seed dressing safener against damage to metolachlor,
„Fluxofenim" (PM, S. 613-614) (= 1-(4-Chlorphenyl)-2,2,2-trifluor-1-ethanon-"Fluxofenim" (PM, pp. 613-614) (= 1- (4-chlorophenyl) -2,2,2-trifluoro-1-ethanone-
O-(1 ,3-dioxolan-2-ylmethyl)-oxim, das als Saatbeiz-Safener gegen Schäden von Metolachlor bekannt ist, undO- (1, 3-dioxolan-2-ylmethyl) oxime, which is known as a seed dressing safener against damage to metolachlor, and
„Cyometrinil" oder „CGA-43089" (PM, S. 1304) (= (Z)-Cyanomethoxyimino"Cyometrinil" or "CGA-43089" (PM, p. 1304) (= (Z) -cyanomethoxyimino
(phenyl)acetonitril), das als Saatbeiz-Safener gegen Schäden von Metolachlor bekannt ist,(phenyl) acetonitrile), which is known as a seed dressing safener against metolachlor damage,
12) Wirkstoffe vom Typ der Thiazolcarbonsäureester, die als Saatbeizmittel bekannt sind, wie z.B.12) Active substances of the thiazole carboxylic acid ester type which are known as seed dressings, e.g.
„Flurazol" (PM, S. 590-591) (= 2-Chlor-4-trifluormethyl-1 ,3-thiazol-5- carbonsäurebenzylester), das als Saatbeiz-Safener gegen Schäden von Alachlor und Metolachlor bekannt ist,"Flurazole" (PM, pp. 590-591) (= benzyl 2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate), which is known as a seed dressing safener against damage to alachlor and metolachlor,
13) Wirkstoffe vom Typ der Napthalindicarbonsäurederivate, die als Saatbeizmittel bekannt sind, wie z.B.13) Active substances of the naphthalenedicarboxylic acid derivative type, which are known as seed dressings, e.g.
„Naphthalic anhydrid" (PM, S. 1342) (= 1 ,8-"Naphthalic anhydride" (PM, p. 1342) (= 1, 8-
Naphthalindicarbonsäureanhydrid), das als Saatbeiz-Safener für Mais gegen Schäden von Thiocarbamatherbiziden bekannt ist,Naphthalenedicarboxylic acid anhydride), which is known as a seed dressing safener for maize against damage from thiocarbamate herbicides,
14) Wirkstoffe vom Typ Chromanessigsäurederivate, wie z.B.14) Active substances of the chromanacetic acid derivative type, e.g.
„CL 304415" (CAS-Reg. Nr. 31541-57-8) (= 2-84-Carboxy-chroman-4-yl)- essigsäure von der Firma American Cyanamid),"CL 304415" (CAS Reg. No. 31541-57-8) (= 2-84-carboxy-chroman-4-yl) - acetic acid from American Cyanamid),
15) Wirkstoffe, die neben einer herbiziden Wirkung gegen Schadpflanzen auch Safenerwirkung an Kulturpflanzen aufweisen, wie z.B. „Dimepiperate" oder „MY-93" (PM, S. 404-405) (= Piperidin-1- thiocarbonsäure-S-1 -methyl-1 -phenylethylester),15) Active ingredients which, in addition to a herbicidal action against harmful plants, also have a safener action on crop plants, such as, for example "Dimepiperate" or "MY-93" (PM, pp. 404-405) (= piperidine-1-thiocarboxylic acid S-1-methyl-1-phenylethyl ester),
„Daimuron" oder „SK 23" (PM, S. 330) (= 1-(1 -Methyl-1 -phenylethyl)-3-p-tolyl- harnstoff),"Daimuron" or "SK 23" (PM, p. 330) (= 1- (1-methyl-1-phenylethyl) -3-p-tolylurea),
„Cumyluron" = „JC-940" (= 3-(2-Chlorphenylmethyl)-1-(1 -methyl-1 -phenyl- ethyl)-harnstoff, siehe JP-A-60087254),"Cumyluron" = "JC-940" (= 3- (2-chlorophenylmethyl) -1- (1-methyl-1-phenylethyl) urea, see JP-A-60087254),
„Methoxyphenon" oder „NK 049" (= 3,3'-Dimethyl-4-methoxy- benzophenon),"Methoxyphenone" or "NK 049" (= 3,3'-dimethyl-4-methoxybenzophenone),
„CSB" (= 1-Brom-4-(chlormethylsulfonyl)-benzol) (CAS-Reg. Nr. 54091-06-4 von Kumiai),"COD" (= 1-bromo-4- (chloromethylsulfonyl) benzene) (CAS Reg. No. 54091-06-4 by Kumiai),
Verbindungen von Typ der Acylsulfamoylbenzoesäureamide, z.B. der nachfolgenden Formel (VIII), die z.B. bekannt sind aus WO 99/16744.Compounds of the acylsulfamoylbenzoic acid amide type, e.g. of the following formula (VIII), e.g. are known from WO 99/16744.
Figure imgf000022_0001
Figure imgf000022_0001
Figure imgf000022_0002
Figure imgf000022_0002
Bevorzugte Safener sind Mefenpyr, Fenchlorazol, Isoxadifen, Cloquintocet und deren Cι-Cι0-Alkylester, insbesondere Mefenpyr-diethyl (S1-1), Fenchlorazol-ethyl (S1-6), Isoxadifen-ethyl (S1-9), Cloquintocet-mexyl (S2-1), und (S3-1). In den erfindungsgemäßen Olsuspensionskonzentraten sind die Safener b) im allgemeinen in Mengen von 0,1 bis 60 Gew.%, insbesondere von 2 bis 40 Gew.% enthalten.Preferred safeners are mefenpyr, fenchlorazole, isoxadifene, cloquintocet and their C 1 -C 8 -alkyl esters, in particular mefenpyr diethyl (S1-1), fenchlorazol-ethyl (S1-6), isoxadifen-ethyl (S1-9), cloquintocet-mexyl (S2-1), and (S3-1). In the oil suspension concentrates according to the invention, the safeners b) are generally present in amounts from 0.1 to 60% by weight, in particular from 2 to 40% by weight.
Das Gewichtsverhältnis der Komponente a) zu der Komponente b) kann in einem weiten Bereich variieren, und liegt im allgemeinen zwischen 1 :100 und 100:1 , bevorzugt zwischen 1 :10 und 10:1.The weight ratio of component a) to component b) can vary within a wide range and is generally between 1: 100 and 100: 1, preferably between 1:10 and 10: 1.
Als optionale agrochemische Wirkstoffe e) können beispielsweise von den Komponenten a) und b) verschiedene agrochemische Wirkstoffe wie Herbizide, Fungizide, Insektizide, Pflanzenwachstumsregulatoren und dergleichen enthalten sein. Die agrochemischen Wirkstoffe e) können in dem organischen Lösungsmittel in suspendierter und/oder gelöster Form vorliegen.Optional agrochemical active ingredients e) can contain, for example, components ag) and components different from agrochemical active ingredients such as herbicides, fungicides, insecticides, plant growth regulators and the like. The agrochemical active ingredients e) can be present in the organic solvent in suspended and / or dissolved form.
Geeignete von den Komponenten a) und b) verschiedene Wirkstoffe, die in den erfindungsgemäßen Olsuspensionskonzentraten als Komponente e) optional enthalten sein können, sind vorzugsweise herbizide Wirkstoffe, beispielsweise: A) Herbizide vom Typ der Phenoxyphenoxy- undSuitable active ingredients different from components a) and b), which may optionally be present as component e) in the oil suspension concentrates according to the invention, are preferably herbicidal active ingredients, for example: A) herbicides of the phenoxyphenoxy and
Heteroaryloxyphenoxycarbonsäure-Derivate, wieHeteroaryloxyphenoxycarboxylic acid derivatives, such as
A1) Phenoxyphenoxy- und Benzyloxyphenoxy-carbonsäure-Derivate, z.B. 2-(4- (2,4-Dichlorphenoxy)-phenoxy)-propionsäuremethylester (Diclofop-methyl), 2-(4-(4-Brom-2-chlorphenoxy)phenoxy)propionsäuremethylester (DE-A 26 01 548), 2-(4-(4-Brom-2-fluorphenoxy)phenoxy)propionsäuremethylester (US-A 4,808,750), 2-(4-(2-Chlor-4-trifluormethylphenoxy)phenoxy)propionsäuremethylester (DE-A 24 33 067),A1) Phenoxyphenoxy and benzyloxyphenoxy carboxylic acid derivatives, e.g. Methyl 2- (4- (2,4-dichlorophenoxy) phenoxy) propionate (diclofop-methyl), methyl 2- (4- (4-bromo-2-chlorophenoxy) phenoxy) propionate (DE-A 26 01 548), 2 - (4- (4-bromo-2-fluorophenoxy) phenoxy) propionic acid methyl ester (US Pat. No. 4,808,750), 2- (4- (2-chloro-4-trifluoromethylphenoxy) phenoxy) propionic acid methyl ester (DE-A 24 33 067),
2-(4-(2-Fluor-4-trifluormethylphenoxy)phenoxy)propionsäuremethylester (US-A 4,808,750),Methyl 2- (4- (2-fluoro-4-trifluoromethylphenoxy) phenoxy) propionate (US Pat. No. 4,808,750),
2-(4-(2,4-Dichlorbenzyl)phenoxy)propionsäuremethylester (DE-A 24 17487), 4-(4-(4-Trifluormethylphenoxy)phenoxy)pent-2-en-säureethylester, 2-(4-(4-Trifluormethylphenoxy)phenoxy)propionsäuremethylester (DE-A 24 33 067); A2) "Einkernige" Heteroaryloxyphenoxy-alkancarbonsäure-Derivate, z.B. 2-(4-(3,5-Dichlorpyridyl-2-oxy)phenoxy)propionsäureethylester (EP-A 0 002 925), 2-(4-(3,5-Dichlorpyridyl-2-oxy)phenoxy)propionsäurepropargylester (EP-A 0 003 114),Methyl 2- (4- (2,4-dichlorobenzyl) phenoxy) propionate (DE-A 24 17487), ethyl 4- (4- (4-trifluoromethylphenoxy) phenoxy) pent-2-ene, 2- (4- (4 -Trifluoromethylphenoxy) phenoxy) propionic acid methyl ester (DE-A 24 33 067); A2) "Mononuclear" heteroaryloxyphenoxy-alkane carboxylic acid derivatives, for example ethyl 2- (4- (3,5-dichloropyridyl-2-oxy) phenoxy) propionate (EP-A 0 002 925), 2- (4- (3,5- Dichloropyridyl-2-oxy) phenoxy) propionic acid propargylester (EP-A 0 003 114),
2-(4-(3-Chlor-5-trifluormethyl-2-pyridyloxy)phenoxy)propionsäure-methylester (EP-A 0 003 890),Methyl 2- (4- (3-chloro-5-trifluoromethyl-2-pyridyloxy) phenoxy) propionate (EP-A 0 003 890),
2-(4-(3-Chlor-5-trifluormethyl-2-pyridyloxy)phenoxy)propionsäureethylester (EP-A 0 003 890),Ethyl 2- (4- (3-chloro-5-trifluoromethyl-2-pyridyloxy) phenoxy) propionate (EP-A 0 003 890),
2-(4-(5-Chlor-3-fluor-2-pyridyloxy)phenoxy)propionsäurepropargylester (EP-A 0 191 736),Propargic acid 2- (4- (5-chloro-3-fluoro-2-pyridyloxy) phenoxy) propionate (EP-A 0 191 736),
2-(4-(5-Trifluormethyl-2-pyridyloxy)phenoxy)propionsäurebutylester (Fluazifop-butyl);2- (4- (5-trifluoromethyl-2-pyridyloxy) phenoxy) propionic acid butyl ester (fluazifop-butyl);
A3) "Zweikernige" Heteroaryloxyphenoxy-alkancarbonsäure-Derivate, z.B. 2-(4-(6-Chlor-2-chinoxalyloxy)phenoxy)propionsäuremethylester und -ethylester (Quizalofop ethyl und Quizalofopethyl),A3) "dinuclear" heteroaryloxyphenoxy alkane carboxylic acid derivatives, e.g. 2- (4- (6-chloro-2-quinoxalyloxy) phenoxy) propionic acid methyl ester and ethyl ester (quizalofop ethyl and quizalofopethyl),
2-(4-(6-Fluor-2-chinoxalyloxy)phenoxy)propionsäuremethylester (s. J. Pest. Sei. Vol. 10, 61 (1985)),Methyl 2- (4- (6-fluoro-2-quinoxalyloxy) phenoxy) propionate (see J. Pest. Sci. Vol. 10, 61 (1985)),
2-(4-(6-Chlor-2-chinoxalyloxy)phenoxy)propionsäure-2-isopropylidenaminooxy- ethylester (Propaquizafop),2- (4- (6-chloro-2-quinoxalyloxy) phenoxy) propionic acid 2-isopropylideneaminooxy ethyl ester (propaquizafop),
2-(4-(6-Chlorbenzoxazol-2-yl-oxy)phenoxy)propionsäureethylester (Fenoxaprop- ethyl) und dessen D(+) Isomer (Fenoxaprop-P-ethyl, EX) und 2-(4-(6- Chlorbenzthiazol-2-yloxy)phenoxy)propionsäureethylester (DE-A 26 40 730), 2-(4-(6-Chlorchinoxalyloxy)phenoxy)propionsäure-tetrahydro-2-furylmethylester (EP- A 0 323 727);2- (4- (6-chlorobenzoxazol-2-yl-oxy) phenoxy) propionic acid ethyl ester (fenoxaprop-ethyl) and its D (+) isomer (fenoxaprop-P-ethyl, EX) and 2- (4- (6-chlorobenzothiazole Ethyl -2-yloxy) phenoxy) propionate (DE-A 26 40 730), tetrahydro-2-furylmethyl 2- (4- (6-chloroquinoxalyloxy) phenoxy) propionate (EP-A 0 323 727);
B) Chloracetanilide, z.B.B) chloroacetanilides, e.g.
N-Methoxymethyl-2,6-diethyl-chloracetanilid (Alachlor), N-(3-Methoxyprop-2-yl)-2-methyl-6-ethyl-chloracetanilid (Metolachlor), N-(3-Methyl-1 ,2,4-oxadiazol-5-yl-methyl)'Chloressigsäure-2,6-dimethylanilid, N-(2,6-Dimethylphenyl)-N-(1-pyrazolylmethyl)-chloressigsäureamid (Metazachlor); C) Thiocarbamate, z.B. S-Ethyl-N,N-dipropylthiocarbamat (EPTC), S-Ethyl-N,N-diisobutylthiocarbamat (Butylate);N-methoxymethyl-2,6-diethyl-chloroacetanilide (alachlor), N- (3-methoxyprop-2-yl) -2-methyl-6-ethyl-chloroacetanilide (metolachlor), N- (3-methyl-1, 2 , 4-oxadiazol-5-yl-methyl) 'chloroacetic acid-2,6-dimethylanilide, N- (2,6-dimethylphenyl) -N- (1-pyrazolylmethyl) chloroacetic acid amide (metazachlor); C) thiocarbamates, for example S-ethyl-N, N-dipropylthiocarbamate (EPTC), S-ethyl-N, N-diisobutylthiocarbamate (butylates);
D) Cyclohexandionoxime, z.B.D) cyclohexanedione oximes, e.g.
3-(1-Allyloxyiminobutyl)-4-hydroxy-6,6-dimethyl-2-oxocyclohex-3-encarbon- säuremethylester, (Alloxydim),3- (1-allyloxyiminobutyl) -4-hydroxy-6,6-dimethyl-2-oxocyclohex-3-encarboxylic acid methyl ester, (alloxydim),
2-(1-Ethoxyiminobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-cyclohex-2-en-1-on (Sethoxydim),2- (1-ethoxyiminobutyl) -5- (2-ethylthiopropyl) -3-hydroxy-cyclohex-2-en-1-one (sethoxydim),
2-(1-Ethoxyiminobutyl)-5-(2-phenylthiopropyl)-3-hydroxy-cyclohex-2-en-1-on (Cloproxydim),2- (1-ethoxyiminobutyl) -5- (2-phenylthiopropyl) -3-hydroxy-cyclohex-2-en-1-one (cloproxydim),
2-(1-(3-ChloraIlyloxy)iminobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-cyclohex-2-en-1-on, 2-(1-(3-Chlorallyloxy)iminopropyl)-5-(2-ethylthiopropyl)-3-hydroxy-cyclohex-2-en-1- on (Clethodim),2- (1- (3-ChloroIlyloxy) iminobutyl) -5- (2-ethylthiopropyl) -3-hydroxy-cyclohex-2-en-1-one, 2- (1- (3-chloroallyloxy) iminopropyl) -5- (2-ethylthiopropyl) -3-hydroxy-cyclohex-2-en-1-one (clethodim),
2-(1-Ethoxyiminobutyl)-3-hydroxy-5-(thian-3-yl)-cyclohex-2-enon (Cycloxydim), 2-(1-Ethoxyiminopropyl)-5-(2,4,6-trimethylphenyl)-3-hydroxy-cyclohex-2-en-1-on (Tralkoxydim);2- (1-ethoxyiminobutyl) -3-hydroxy-5- (thian-3-yl) cyclohex-2-enone (cycloxydim), 2- (1-ethoxyiminopropyl) -5- (2,4,6-trimethylphenyl) -3-hydroxy-cyclohex-2-en-1-one (tralkoxydim);
E) Benzoylcyclohexandione, z.B. 2-(2-Chlor-4-methylsulfonylbenzoyl)-cyclohexan-1 ,3-dion (SC-0051 , EP-AE) benzoylcyclohexanediones, e.g. 2- (2-chloro-4-methylsulfonylbenzoyl) cyclohexane-1,3-dione (SC-0051, EP-A
0 137 963), 2-(2-Nitrobenzoyl)-4,4-dimethyl-cyclohexan-1 ,3-dion (EP-A 0 274 634), 2-(2-Nitro-4-methylsulfonylbenzoyl)-4,4-dimethylcyclohexan-1 ,3-dion (WO 91/13548, Mesotrione);0 137 963), 2- (2-nitrobenzoyl) -4,4-dimethyl-cyclohexane-1,3-dione (EP-A 0 274 634), 2- (2-nitro-4-methylsulfonylbenzoyl) -4.4 dimethylcyclohexane-1,3-dione (WO 91/13548, mesotrione);
F) S-(N-Aryl-N-alkyl-carbamoylmethyl)-dithiophosphonsäureester, wie S-[N-(4- Chlorphenyl)-N-isopropyl-carbamoylmethyl]-O,O-dimethyl-dithiophosphat (Anilophos).F) S- (N-aryl-N-alkyl-carbamoylmethyl) dithiophosphonic acid esters, such as S- [N- (4-chlorophenyl) -N-isopropyl-carbamoylmethyl] -O, O-dimethyl-dithiophosphate (Anilophos).
G) Alkylazine, z.B. wie beschrieben in WO-A 97/08156, WO-A-97/31904, DE-A- 19826670, WO-A-98/15536, WO-A-8/15537, WO-A-98/15538, WO-A-98/15539 sowie auch DE-A-19828519, WO-A-98/34925, WO-A-98/42684, WO-A-99/18100, WO-A-99/19309, WO-A-99/37627 und WO-A-99/65882, vorzugsweise solche der Formel (G)G) Alkyl azines, for example as described in WO-A 97/08156, WO-A-97/31904, DE-A-19826670, WO-A-98/15536, WO-A-8/15537, WO-A-98 / 15538, WO-A-98/15539 and also DE-A-19828519, WO-A-98/34925, WO-A-98/42684, WO-A-99/18100, WO-A-99/19309, WO-A-99/37627 and WO-A-99/65882, preferably those of the formula (G)
Figure imgf000026_0001
worin
Figure imgf000026_0001
wherein
R (d-C4)-Alkyl oder (d-C4)-Haloalkyl; Rγ (C1-C4)-Alkyl, (C3-C6)-CycIoalkyl oder (C3-C6)-Cycloalkyl-(CrC4)-Alkyl und A -CH2-, -CH2-CH2-, -CH2-CH2-CH2-, -O-, -CH2-CH2-O-, -CH2-CH2-CH2-O- bedeuten, besonders bevorzugt solche der Formel G1-G7R (dC 4 ) alkyl or (dC 4 ) haloalkyl; R γ (C 1 -C 4 ) alkyl, (C 3 -C 6 ) cycloalkyl or (C 3 -C 6 ) cycloalkyl (CrC 4 ) alkyl and A -CH 2 -, -CH 2 -CH 2 -, -CH2-CH2-CH2-, -O-, -CH2-CH 2 -O-, -CH 2 -CH 2 -CH 2 -O-, particularly preferably those of the formula G1-G7
Figure imgf000027_0001
Figure imgf000027_0001
Figure imgf000027_0002
Figure imgf000028_0001
Figure imgf000027_0002
Figure imgf000028_0001
H) Phosphor-haltige Herbizide, z.B. vom Glusosinate-Typ wie Glufosinate im engeren Sinne, d. h. D,L-2-Amino-4-[hydroxy(methyl)phosphinylj-butansäure, Glufosinate-monoammoniumsalz, L-Glufosinate, L- oder (2S)-2-Amino-4- [hydroxy(methyl)phosphinyl]-butansäure, L-Glufosinate-monoammoniumsalz oder Bialaphos (oder Bilanafos), d.h. L-2-Amino-4-[hydroxy(methyl)phosphinyl]-butanoyl- L-alanyl-L-alanin, insbesondere dessen Natriumsalz, oder vom Glyphosate-Typ wie Glyphosate, d. h. N-(Phosphonomethyl)-glycin, Glyphosate-monoisopropylammoniumsalz, Glyphosate-natriumsalz, oder Sulfosate, d. h. N-(Phosphonomethyl)-glycin-trimesiumsalz = N-(Phosphonomethyl)-glycin- trimethylsulfoxoniumsalz.H) Phosphorus-containing herbicides, e.g. of the glusosinate type such as glufosinate in the narrower sense, d. H. D, L-2-amino-4- [hydroxy (methyl) phosphinylj-butanoic acid, glufosinate monoammonium salt, L-glufosinate, L- or (2S) -2-amino-4- [hydroxy (methyl) phosphinyl] butanoic acid, L-glufosinate monoammonium salt or bialaphos (or bilanafos), ie L-2-amino-4- [hydroxy (methyl) phosphinyl] butanoyl-L-alanyl-L-alanine, especially its sodium salt, or of the glyphosate type such as glyphosate, i.e. H. N- (phosphonomethyl) glycine, glyphosate monoisopropylammonium salt, glyphosate sodium salt, or sulfosate, i.e. H. N- (phosphonomethyl) glycine trimesium salt = N- (phosphonomethyl) glycine trimethylsulfoxonium salt.
Die Herbizide der Gruppen A bis H sind beispielsweise aus den oben jeweils genannten Schriften und aus "The Pesticide Manual", 12. Auflage, 2000, The British Crop Protection Council, "Agricultural Chemicals Book II - Herbicides -", by W.T. Thompson, Thompson Publications, Fresno CA, USA 1990 und "Farm Chemicals Handbook '90", Meister Publishing Company, Willoughby OH, USA,1990, bekannt.The herbicides of groups A to H are, for example, from the respective publications mentioned above and from "The Pesticide Manual", 12th edition, 2000, The British Crop Protection Council, "Agricultural Chemicals Book II - Herbicides -", by W.T. Thompson, Thompson Publications, Fresno CA, USA 1990 and "Farm Chemicals Handbook '90", Meister Publishing Company, Willoughby OH, USA, 1990.
Als optional enthaltene von den Komponenten (a) und (b) verschiedene agrochemische Wirkstoffe (e) kommen für die erfindungsgemäßen Ölsuspensionskonzentrate beispielsweise die nachfolgend genannten bekannten Wirkstoffe in Frage, wie sie in z.B. Weed Research 26, 441-445 (1986), oder "The Pesticide Manual", 12th edition, The British Crop Protection Council, 2000, und dort zitierter Literatur beschrieben sind, z.B. in Mischungsformulierungen oder als Tank- Mischpartner. Die Verbindungen sind entweder mit dem "common name" nach der International Organization for Standardization (ISO) oder mit dem chemischen Namen, ggf. zusammen mit einer üblichen Codenummer bezeichnet und umfassen stets sämtliche Anwendungsformen wie Säuren, Salze, Ester und Isomere wie Stereoisomere und optische Isomere: acetochlor; acifluorfen; aclonifen; AKH 7088, d.h. [[[1-[5-[2-Chloro-4-(trifluoromethyl)-phenoxy]-2-nitrophenyl]-2- methoxyethylidene]-amino]-oxy]-essigsäure und -essigsäuremethylester; alachlor; alloxydim; ametryn; amitrol; AMS, d.h. Ammoniumsulfamat; anilofos; asulam; atrazin; azafenidine (DPX-R6447), aziprotryn; barban; BAS 516 H, d.h. 5-Fluor-2-phenyl-4H- 3,1-benzoxazin-4-on; benazolin; benfluralin; benfuresate; bensulide; bentazone; benzofluor; benzoylprop-ethyl; benzthiazuron; bialaphos; bifenox; bispyribac-natrium (KIH-2023), bromacil; bromobutide; bromofenoxim; bromoxynil, insbesondere bromoxynil-octanoat und bromoxynil-heptanoat; butachlor; butamifos; butenachlor; buthidazole; butralin; butroxydim (ICI-0500), butylate; cafenstrole (CH-900); carbetamide; cafentrazone; CDAA, d.h. 2-Chlor-N,N-di-2-propenylacetamid; CDEC, d.h. D.ethyldithiocarbaminsäure-2-chlorallylester; chlomethoxyfen; chloramben; cloransulam-methyl (XDE-565), chlorazifop-butyl, chlorbromuron; chlorbufam; chlorfenac; chlorflurenol-methyl; chloridazon; chlornitrofen; chlorotoluron; chloroxuron; chlorpropham; chlorthal-dimethyl; chlorthiamid; cinidon-ethyl, cinmethylin; clethodim; clodinafop und dessen Esterderivate (z.B. clodinafop- propargyl); clomazone; clomeprop; cloproxydim; clopyralid; cumyluron (JC 940); cyanazine; cycloate; cycloxydim; cycluron; cyhalofop und dessen Esterderivate (z.B. Butylester, DEH-112); cyperquat; cyprazine; cyprazole; 2,4-D; 2,4-DB; dalapon; desmedipham; desmetryn; di-allate; dicamba; dichlobenil; dichlorprop; diclofop und dessen Ester wie diclofop-methyl; diclosulam (XDE-564), diethatyl; difenoxuron; difenzoquat; diflufenican; diflufenzopyr-natrium (SAN-835H), dimefuron; dimethachlor; dimethametryn; dimethenamid (SAN-582H); dimidazone, 5-(4,6- Dimethylpyrimidin-2-yl-carbamoylsulfamoyl)-1-(2-pyridyl)-pyrazol-4- carbonsäuremethylester (NC-330); triaziflam (IDH-1105), cinosulfon; dimethipin, dinitramine; dinoseb; dinoterb; diphenamid; dipropetryn; diquat; dithiopyr; diuron; DNOC; eglinazine-ethyl; EL 177, d.h. 5-Cyano-1-(1 ,1-dimethylethyl)-N-methyl-1 H- pyrazole-4-carboxamid; endothal; indanofan (MK-243), EPTC; esprocarb; ethalfluralin; ethidimuron; ethiozin; ethofumesate; F5231, d.h. N-[2-Chlor-4-fluor-5-[4- (3-fluorpropyl)-4,5-dihydro-5-oxo-1H-tetrazol-1-yl]-phenyl]-ethansulfonamid; ethoxyfen und dessen Ester (z.B. Ethylester, HN-252); etobenzanid (HW 52); 3-(4- Ethoxy-6-ethyl-1 ,3,5-triazin-2-yl)-1-(2,3-dihydro-1 ,1-dioxo-2-methylbenzo[b]thiophen- 7-sulfonyl)harnstoff (EP-A 079 683);As optional agrochemical active ingredients (e) which are different from components (a) and (b), the known active ingredients mentioned below, as described in, for example, Weed Research 26, 441-445 (1986), or " The Pesticide Manual ", 12th edition, The British Crop Protection Council, 2000, and the literature cited therein, for example in mixture formulations or as a tank mixing partner. The connections are either with the "common name" after the International Organization for Standardization (ISO) or with the chemical name, if necessary together with a usual code number and always include all forms of application such as acids, salts, esters and isomers such as stereoisomers and optical isomers: acetochlor; acifluorfen; aclonifen; AKH 7088, ie [[[1- [5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrophenyl] -2-methoxyethylidene] amino] oxy] acetic acid and methyl acetate; alachlor; alloxydim; ametryn; amitrol; AMS, ie ammonium sulfamate; anilofos; asulam; atrazine; azafenidine (DPX-R6447), aziprotryn; barban; BAS 516 H, ie 5-fluoro-2-phenyl-4H-3,1-benzoxazin-4-one; benazolin; benfluralin; benfuresate; bensulide; bentazone; benzofluor; benzoylprop-ethyl; benzthiazuron; bialaphos; bifenox; bispyribac sodium (KIH-2023), bromacil; bromobutide; bromofenoxim; bromoxynil, especially bromoxynil octanoate and bromoxynil heptanoate; butachlor; butamifos; butenachlor; buthidazole; butraline; butroxydim (ICI-0500), butylates; cafenstrole (CH-900); carbetamide; cafentrazone; CDAA, ie 2-chloro-N, N-di-2-propenylacetamide; CDEC, ie 2-chloroallyl ester of D. ethyldithiocarbamic acid; chlomethoxyfen; chloramben; cloransulam-methyl (XDE-565), chlorazifop-butyl, chlorbromuron; chlorbufam; chlorfenac; chlorflurenol-methyl; chloridazon; chlornitrofen; chlorotoluron; chloroxuron; chlorpropham; chlorthal-dimethyl; chlorthiamid; cinidon-ethyl, cinmethylin; clethodim; clodinafop and its ester derivatives (eg clodinafop-propargyl); clomazone; clomeprop; cloproxydim; clopyralid; cumyluron (JC 940); cyanazine; cycloate; cycloxydim; cycluron; cyhalofop and its ester derivatives (eg butyl ester, DEH-112); cyperquat; cyprazine; cyprazole; 2,4-D; 2,4-DB; dalapon; desmedipham; Desmetryn; di-allate; dicamba; dichlobenil; dichloroprop; diclofop and its esters such as diclofop-methyl; diclosulam (XDE-564), diethatyl; difenoxuron; difenzoquat; diflufenican; diflufenzopyr sodium (SAN-835H), dimefuron; dimethachlor; dimethametryn; dimethenamid (SAN-582H); dimidazone, 5- (4,6-dimethylpyrimidin-2-yl-carbamoylsulfamoyl) -1- (2-pyridyl) -pyrazole-4-carboxylic acid methyl ester (NC-330); triaziflam (IDH-1105), cinosulfone; dimethipin, dinitramine; dinoseb; dinoterb; diphenamid; dipropetryn; diquat; dithiopyr; diuron; DNOC; eglinazine-ethyl; EL 177, ie 5-cyano-1- (1, 1-dimethylethyl) -N-methyl-1H-pyrazole-4-carboxamide; endothal; indanofan (MK-243), EPTC; esprocarb; ethalfluralin; Ethidimuron; ethiozin; ethofumesate; F5231, ie N- [2-chloro-4-fluoro-5- [4- (3-fluoropropyl) -4,5-dihydro-5-oxo-1H-tetrazol-1-yl] phenyl] -ethanesulfonamide; ethoxyfen and its esters (eg ethyl ester, HN-252); etobenzanide (HW 52); 3- (4-Ethoxy-6-ethyl-1,3,5-triazin-2-yl) -1- (2,3-dihydro-1,1-dioxo-2-methylbenzo [b] thiophene-7-sulfonyl ) urea (EP-A 079 683);
3-(4-Ethyl-6-methoxy-1,3,5-triazin-2-yl)-1-(2,3-dihydro-1 ,1-dioxo-2- methylbenzo[b]thiophen-7-sulfonyl)harnstoff (EP-A 079 683); fenoprop; clomazone, fenoxaprop und fenoxaprop-P sowie deren Ester, z.B. fenoxaprop-P-ethyl und fenoxaprop-ethyl; butroxydimfenuron; flamprop-methyl; flufenacet (BAY-FOE-5043), fluazifop und fluazifop-P und deren Ester, z.B. fluazifop- butyl und fluazifop-P-butyl, florasulam (DE-570); fluchloralin; flumetsulam; fluometuron; flumiclorac und dessen Ester (z.B. Pentylester, S-23031); flumioxazin (S-482); flumipropyn; flupoxam (KNW-739); fluorodifen; fluoroglycofen-ethyl; flupropacil (UBIC-4243); fluridone; flurochloridone; fluroxypyr; flurtamone; fluthiacet- methyl (KIH-9201), fomesafen; fosamine; furyloxyfen; glufosinate; glyphosate; halosafen; halosulfuron und dessen Ester (z.B. Methylester, NC-319); haloxyfop und dessen Ester; haloxyfop-P (= R-haloxyfop) und dessen Ester; hexazinone; imazamethabenz-methyl; imazamox (AC-299263), imazapyr; imazaquin und Salze wie das Ammoniumsalz; imazapic; imazethapyr; imazosulfuron; ioxynil; isocarbamid; isopropalin; isoproturon; isouron; isoxaben; isoxapyrifop; karbutilate; lactofen; lenacil; linuron; MCPA; MCPB; mecoprop; mefenacet; mefluidid; metamitron; metazachlor; methabenzthiazuron; metam; methazole; methoxyphenone; methyldymron; metobenzuron, Mesosulfuron-methyl, mesosulfuron-methyl (WO 95/10507); metobromuron; metolachlor; S-metolachlor, metosulam (XRD 511); metoxuron; metribuzin; maleic hydrazide; molinate; monalide; monocarbamide dihydrogensulfate; monolinuron; monuron;3- (4-ethyl-6-methoxy-1,3,5-triazin-2-yl) -1- (2,3-dihydro-1,1-dioxo-2-methylbenzo [b] thiophene-7-sulfonyl ) urea (EP-A 079 683); fenoprop; clomazone, fenoxaprop and fenoxaprop-P and their esters, e.g. fenoxaprop-P-ethyl and fenoxaprop-ethyl; butroxydimfenuron; flamprop-methyl; flufenacet (BAY-FOE-5043), fluazifop and fluazifop-P and their esters, e.g. fluazifop-butyl and fluazifop-P-butyl, florasulam (DE-570); fluchloralin; flumetsulam; fluometuron; flumiclorac and its esters (e.g. pentyl ester, S-23031); flumioxazin (S-482); flumipropyn; flupoxam (KNW-739); fluorodifen; fluoroglycofen-ethyl; flupropacil (UBIC-4243); fluridone; flurochloridone; fluroxypyr; flurtamone; fluthiacet-methyl (KIH-9201), fomesafen; fosamine; furyloxyfen; glufosinate; glyphosate; halo safen; halosulfuron and its esters (e.g. methyl ester, NC-319); haloxyfop and its esters; haloxyfop-P (= R-haloxyfop) and its esters; hexazinone; imazamethabenz-methyl; imazamox (AC-299263), imazapyr; imazaquin and salts such as the ammonium salt; imazapic; imazethapyr; imazosulfuron; ioxynil; isocarbamid; isopropalin; isoproturon; isouron; isoxaben; isoxapyrifop; karbutilate; lactofen; lenacil; linuron; MCPA; MCPB; mecoprop; mefenacet; mefluidide; metamitron; metazachlor; methabenzthiazuron; metam; methazole; methoxyphenone; methyldymron; metobenzuron, mesosulfuron-methyl, mesosulfuron-methyl (WO 95/10507); metobromuron; metolachlor; S-metolachlor, metosulam (XRD 511); metoxuron; metribuzin; maleic hydrazide; molinate; monalide; monocarbamide dihydrogen sulfates; monolinuron; monuron;
MT 128, d.h. 6-Chlor-N-(3-chlor-2-propenyl)-5-methyl-N-phenyl-3-pyridazinamin; MT 5950, d.h. N-[3-Chlor-4-(1-methylethyl)-phenyl]-2-methylpentanamid; foramsulfuron (WO 95/01344); naproanilide; napropamide; naptalam; NC 310, d.h. 4-(2,4-dichlorbenzoyl)-1-methyl-5-benzyIoxypyrazol; neburon; nipyraclophen; nitralin; nitrofen; nitrofluorfen; norflurazon; orbencarb; oryzalin; oxadiargyl (RP-020630); oxadiazon; oxaziclomefone (MY-100), oxyfluorfen; paraquat; pebulate; pendimethalin; pentoxazone (KPP-314), perfluidone; phenisopham; phenmedipham; picloram; piperophos; pyributicarb; pirifenop-butyl; pretilachlor; procyazine; prodiamine; profluralin; proglinazine-ethyl; prometon; prometryn; propachlor; propanil; propaquizafop und dessen Ester; propazine; propham; propisochlor; propyzamide; prosulfalin; prosulfocarb; prynachlor; pyraflufen-ethyl (ET-751), chloridazon; pyrazoxyfen; pyribenzoxim, pyridate; pyriminobac-methyl (KIH-6127), pyrithiobac (KIH-2031); pyroxofop und dessen Ester (z.B. Propargylester); quinclorac; quinmerac; quizalofop, quizalofop und quizalofop-P und deren Esterderivate z.B. quizalofop-ethyl; quizalofop-P-tefuryl und -ethyl; S 275, d.h. 2-[4- Chlor-2-fluor-5-(2-propynyloxy)-phenyl]-4,5,6,7-tetrahydro-2H-indazol; secbumeton; sethoxydim; siduron; simazine; simetryn; SN 106279, d.h. 2-[[7-[2-Chlor-4-(trifluor- methyl)-phenoxy]-2-naphthalenyl]-oxy]-propansäure und -methylester; flazasulfuron (FMC-97285, F-6285); sulfazuron; glyphosate-trimesium (ICI-A0224); TCA; tebutam (GCP-5544); tebuthiuron; tepraloxydim (BAS-620H), terbacil; terbucarb; terbuchlor; terbumeton; terbuthylazine; terbutryn; TFH 450, d.h. N,N-Diethyl-3-[(2-ethyl-6- methylphenyl)-sulfonyl]-1 H-1 ,2,4-triazol-1-carboxamid; thenylchlor (NSK-850); thiazafluron; thiazopyr (Mon- 3200); thidiazi in (SN-124085); thiobencarb; tiocarbazil; tralkoxydim; tri-allate; triazofenamide; triclopyr; tridiphane; trietazine; trifluralin; trimeturon; tsitodef; vernolate; WL 110547, d.h. 5-Phenoxy-1-[3- (trifluormethyl)-phenyl]-1H-tetrazol; UBH-509; D-489; LS 82-556; KPP-300; KPP-421 , MT-146, NC-324; butenachlor (KH-218); DPX-N8189; haloxyfop-etotyl (DOWCO-535); DK-8910; flumioxazin (V-53482); PP-600; MBH-001 , amicarbazone, aminopyralid, beflubutamid, benzobicyclon, benzofenap, benzfendizone, butafenacil, chlorfenprop, cloprop, daimuron, dichlorprop-P, dimepipeate, dimethenamid-P, fentrazamide, flamprop-M, fluazolate, indanofan, isoxachlortole, isoxaflutole, MCPA-thioethyl, mecoprop-P, mesotrione, metamifop, penoxsulam, pethoxamid, picolinafen, profluazol, profoxydim, pyraclonil, pyrazolynate, pyridafol, pyriftalid, sulcotrione, thidiazuron.MT 128, ie 6-chloro-N- (3-chloro-2-propenyl) -5-methyl-N-phenyl-3-pyridazinamine; MT 5950, ie N- [3-chloro-4- (1-methylethyl) phenyl] -2-methylpentanamide; foramsulfuron (WO 95/01344); naproanilide; napropamide; naptalam; NC 310, ie 4- (2,4-dichlorobenzoyl) -1-methyl-5-benzyloxypyrazole; neburon; nipyraclophen; nitralin; nitrofen; nitrofluorfen; norflurazon; orbencarb; oryzalin; oxadiargyl (RP-020630); oxadiazon; oxaziclomefone (MY-100), oxyfluorfen; paraquat; pebulate; pendimethalin; pentoxazone (KPP-314), perfluidone; phenisopham; phenmedipham; picloram; piperophos; pyributicarb; pirifenop-butyl; pretilachlor; procyazine; prodi amines; profluralin; proglinazine-ethyl; prometon; prometryne; propachlor; propanil; propaquizafop and its esters; propazine; propham; propisochlor; Propyzamide; prosulfalin; prosulfocarb; prynachlor; pyraflufen-ethyl (ET-751), chloridazon; pyrazoxyfen; pyribenzoxime, pyridate; pyriminobac-methyl (KIH-6127), pyrithiobac (KIH-2031); pyroxofop and its esters (eg propargyl esters); quinclorac; quinmerac; quizalofop, quizalofop and quizalofop-P and their ester derivatives, for example quizalofop-ethyl; quizalofop-P-tefuryl and ethyl; S 275, ie 2- [4-chloro-2-fluoro-5- (2-propynyloxy) phenyl] -4,5,6,7-tetrahydro-2H-indazole; secbumeton; sethoxydim; siduron; simazine; simetryn; SN 106279, ie 2 - [[7- [2-chloro-4- (trifluoromethyl) phenoxy] -2-naphthalenyl] oxy] propanoic acid and methyl ester; flazasulfuron (FMC-97285, F-6285); sulfazuron; glyphosate trimesium (ICI-A0224); TCA; tebutam (GCP-5544); tebuthiuron; tepraloxydim (BAS-620H), terbacil; terbucarb; terbuchlor; terbumeton; Terbuthylazine; terbutryn; TFH 450, ie N, N-diethyl-3 - [(2-ethyl-6-methylphenyl) sulfonyl] -1 H-1, 2,4-triazole-1-carboxamide; thenylchlor (NSK-850); thiazafluron; thiazopyr (Mon-3200); thidiazi in (SN-124085); thiobencarb; tiocarbazil; tralkoxydim; tri-allate; triazofenamide; triclopyr; tridiphane; trietazine; trifluralin; trimeturon; tsitodef; vernolate; WL 110547, ie 5-phenoxy-1- [3- (trifluoromethyl) phenyl] -1H-tetrazole; UBH-509; D-489; LS 82-556; KPP-300; KPP-421, MT-146, NC-324; butenachlor (KH-218); DPX-N8189; haloxyfop-etotyl (DOWCO-535); DK-8910; flumioxazin (V-53482); PP-600; MBH-001, amicarbazone, aminopyralid, beflubutamid, benzobicyclon, benzofenap, benzfendizone, butafenacil, chlorfenprop, cloprop, daimuron, dichlorprop-P, dimepipeate, dimethenamid-P, fentrazamide, flamprop-M, fluazolate, Moxaflutanoleofanoleofanoleofanoleofanoleofanole thioethyl, mecoprop-P, mesotrione, metamifop, penoxsulam, pethoxamid, picolinafen, profluazol, profoxydim, pyraclonil, pyrazolynate, pyridafol, pyriftalid, sulcotrione, thidiazuron.
Bevorzugte Komponenten e) sind Bromoxynil (E1) in sämtlichen seinen Anwendungsformen einschließlich der Salze und Ester, z.B. Bromoxynil-octanoat (E1.1), Bromoxynil-heptanoat (E1.2), Bromoxynil-butyrat (E1.3), Bromoxynil-Natrium (E1.4) und Bromoxynil-Kalium (E1.5); 2,4-D (E2) in sämtlichen seiner Anwendungsformen einschließlich der Salze und Ester, z.B. 2,4-D-Butotyl (E2.1), 2,4-D-butyl (E2.2), 2,4-D-dimethylammonium (E2.3), 2,4-D-diethanolamin (E2.4), 2,4-D-2-ethylhexyl (E2.5), 2,4-D-isooctyl (E2.6), 2,4-D-isopropyl (E2.7), 2,4-D- Natrium (E2.8) und 2,4-D-triethanolamin (E2.9); Dicamba (E3) in sämtlichen seiner Anwendungsformen einschließlich der Salze und Ester, z.B. Dicamba-Natrium (E3.1), Dicamba-Kalium (E3.2) und Dicamba-dimethylammonium (E3.3); Fenoxaprop (E4) in sämtlichen seiner Anwendungsformen einschließlich der Ester, z.B. Fenoxaprop-ethyl (E4.1) und Fenoxaprop-P-ethyl (E4.2); Fluroxypyr (E5) in sämtlichen seiner Anwendungsformen einschließlich der Salze und Ester, z.B. Fluroxypyr-meptyl (E5.1) und Fluroxypyr-2-butoxy-1-methylethyl (E5.2); MCPA (E6) in sämtlichen seiner Anwendungsformen einschließlich der Salze und Ester, z.B. MCPA-Natrium (E6.1), MCPA-Kalium (E6.2), MCPA-2-ethylhexyl (E6.3), MCPA- butotyl (E6.4) und MCPA-dimethylammonium (E6.5).Preferred components e) are bromoxynil (E1) in all its use forms, including the salts and esters, for example bromoxynil octanoate (E1.1), bromoxynil heptanoate (E1.2), bromoxynil butyrate (E1.3), bromoxynil sodium (E1.4) and bromoxynil potassium (E1.5); 2,4-D (E2) in all of its Use forms including the salts and esters, for example 2,4-D-butotyl (E2.1), 2,4-D-butyl (E2.2), 2,4-D-dimethylammonium (E2.3), 2,4 -D-diethanolamine (E2.4), 2,4-D-2-ethylhexyl (E2.5), 2,4-D-isooctyl (E2.6), 2,4-D-isopropyl (E2.7) , 2,4-D-sodium (E2.8) and 2,4-D-triethanolamine (E2.9); Dicamba (E3) in all of its use forms including the salts and esters, for example dicamba sodium (E3.1), dicamba potassium (E3.2) and dicamba dimethylammonium (E3.3); Fenoxaprop (E4) in all its application forms including the esters, eg fenoxaprop-ethyl (E4.1) and fenoxaprop-P-ethyl (E4.2); Fluroxypyr (E5) in all its use forms including the salts and esters, for example fluroxypyr-meptyl (E5.1) and fluroxypyr-2-butoxy-1-methylethyl (E5.2); MCPA (E6) in all its application forms including the salts and esters, e.g. MCPA sodium (E6.1), MCPA potassium (E6.2), MCPA-2-ethylhexyl (E6.3), MCPA-butotyl (E6. 4) and MCPA-dimethylammonium (E6.5).
Soweit in den erfindungsgemäßen Olsuspensionskonzentraten agrochemische Wirkstoffe e) enthalten sind, beträgt deren Gewichtsanteil 0,5 bis 50 Gew.-%, insbesondere 3 bis 20 Gew.-%.If agrochemical active ingredients e) are contained in the oil suspension concentrates according to the invention, their weight fraction is 0.5 to 50% by weight, in particular 3 to 20% by weight.
Der in den erfindungsgemäßen Olsuspensionskonzentraten enthaltene Gesamtwirkstoffgehalt (Summe der Komponente a) + b) + e)) liegt im allgemeinen zwischen 1 und 80 Gew.%, insbesondere zwischen 3 und 60 Gew.%.The total active substance content (sum of component a) + b) + e)) contained in the oil suspension concentrates according to the invention is generally between 1 and 80% by weight, in particular between 3 and 60% by weight.
Als organische Lösungsmittel (Komponente c) kommen z.B. in Frage:As organic solvents (component c) come e.g. in question:
1) Kohlenwasserstoffe, die unsubstituiert oder substituiert sein können, z.B.1) hydrocarbons which may be unsubstituted or substituted, e.g.
1 a) aromatische Kohlenwasserstoffe, z.B.1 a) aromatic hydrocarbons, e.g.
• ein- oder mehrfach alkyl-substituierte Benzole wie Toluol, Xylole, Mesitylen, Ethylbenzol, oder • mono- or poly-alkyl-substituted benzenes such as toluene, xylenes, mesitylene, ethylbenzene, or
• ein- oder mehrfach alkyl-substituierte Naphthaline wie 1 -Methylnaphthalin, 2-Methylnaphthalin oder Dimethylnaphthalin, oder • One or more alkyl-substituted naphthalenes such as 1-methylnaphthalene, 2-methylnaphthalene or dimethylnaphthalene, or
■ andere vom Benzol abgeleitete aromatische Kohlenwasserstoffe, wie Indan oder Tetralin® , oder • Gemische hieraus, ■ other derived from benzene aromatic hydrocarbons, such as indane or tetralin ®, or • mixtures thereof,
1b) aliphatische Kohlenwasserstoffe, z.B.1b) aliphatic hydrocarbons, e.g.
• lineare oder verzweigte Aliphaten, z.B. der allgemeinen Formel CnH2n+2. wie Pentan, Hexan, Octan, 2-Methylbutan oder 2,2,4-Trimethylpentan, oder • linear or branched aliphatics, for example of the general formula C n H 2n + 2, such as pentane, hexane, octane, 2-methylbutane or 2,2,4-trimethylpentane, or
• cyclische, gegebenenfalls alkyl-substituierte Aliphaten, wie Cyclohexan oder Methylcyclopentan, oder • Cyclic, optionally alkyl-substituted aliphatics, such as cyclohexane or methylcyclopentane, or
• Gemische hieraus, wie Lösungsmittel der Exxsol®D-Reihe, lsopar®-Reihe oder Bayol®-Reihe z.B. Bayol®82 (ExxonMobil Chemicals) oder der lsane®IP- Reihe oder Hydroseal®G-Reihe (TotalFinaEIf), • mixtures thereof, such as solvents of the Exxsol ® D series, Isopar ® series or Bayol ® series, for example Bayol ® 82 (ExxonMobil Chemicals), or the lsane ® IP series or HydroSeal ® G series (TotalFinaEIf)
1c) Gemische von aromatischen und aliphatischen Kohlenwasserstoffen, wie Lösungsmittel der Solvesso®-Reihe z.B. Solvesso®100, Solvesso®150 oder Solvesso®200 (ExxonMobil Chemicals), der Solvarex®/Solvaro®-Reihe (TotalFinaEIf) oder der Caromax®-Reihe z.B. Caromax®28 (Petrochem Carless), oder1c) Mixtures of aromatic and aliphatic hydrocarbons, such as solvents from the Solvesso ® series, for example Solvesso ® 100, Solvesso ® 150 or Solvesso ® 200 (ExxonMobil Chemicals), the Solvarex ® / Solvaro ® series (TotalFinaEIf) or the Caromax ® series eg Caromax ® 28 (Petrochem Carless), or
1d) halogenierte Kohlenwasserstoffe wie halogenierte aromatische und aliphatische Kohlenwasserstoffe, wie Chlorbenzol oder Methylenchlorid, oder1d) halogenated hydrocarbons such as halogenated aromatic and aliphatic hydrocarbons, such as chlorobenzene or methylene chloride, or
2) aprotische, polare Lösungsmittel, wie Ether, Ester von Ci-Cg-Alkansäuren, die mono-, di- oder polyfunktional sein können, wie deren Mono-, Di- oder Triester, z.B. mit Cι-Ci8-Alkylalkoholen, Ketone mit geringer Tautomerietendenz, Phophorsäureester, Amide, Nitrile oder Sulfone, z.B. Diisobutyladipat, Rhodiasolv® RPDE (Rhodia), Cyclohexanon, Jeffsol®PC (Huntsman), γ- Butyrolacton, N-Methylpyrrolidon, Dimethylsulfoxid, Acetonitril, Tributylphosphatam oder Hostarex®PO-Reihe (Clariant), oder2) aprotic, polar solvents, such as ethers, esters of Ci-Cg-alkanoic acids, which can be mono-, di- or polyfunctional, such as their mono-, di- or triesters, for example with C 1 -C 8 -alkyl alcohols, ketones with less Tautomerietendenz, phosphoric ester, amides, nitriles or sulfones, for example diisobutyl adipate, Rhodiasolv RPDE ® (Rhodia), cyclohexanone, Jeffsol ® PC (Huntsman), γ- butyrolactone, N-methylpyrrolidone, dimethyl sulfoxide, acetonitrile, or Tributylphosphatam Hostarex ® PO series (Clariant ), or
3) Fettsäureester, z.B. natürlichen Ursprungs, z.B. natürliche Öle wie tierische Öle oder Pflanzenöle, oder synthetischen Ursprungs, z.B. Edenor®-Reihe z.B. Edenor®MEPa oder Edenor®MESU oder Agnique®ME-Reihe oder Agnique®AE- Reihe (Cognis), Salim®ME-Reihe (Salim), Radia®-Reihe z.B. Radia®30167 (ICI), Prilube®-Reihe z.B. Prilube®1530 (Petrofina), Stepan®C-Reihe (Stepan) oder Witconol®23-Reihe (Witco). Die Fettsäureester sind bevorzugt Ester von C10-C22-, vorzugsweise Cι -C2o-Fettsäuren. Die Cιo-C22-Fettsäureester sind beispielsweise Ester ungesättigter oder gesättigter C10-C22-Fettsäuren, insbesondere mit gerader Kohlenstoffatomzahl, z.B. Erucasäure, Laurinsäure, Palmitinsäure und insbesondere Cι8-Fettsäuren wie Stearinsäure, Ölsäure, Linolsäure oder Linolensäure.3) fatty acid esters, for example of natural origin, for example natural oils such as animal oils or vegetable oils, or synthetic origin, for example Edenor ® series, for example Edenor ® MEPa or Edenor ® MESU or Agnique ® ME series or Agnique ® AE series (Cognis), Salim ® ME series (Salim), Radia ® series e.g. Radia ® 30167 (ICI), Prilube ® series e.g. Prilube ® 1530 (Petrofina), Stepan ® C series (Stepan) or Witconol ® 23 series (Witco). The fatty acid esters are preferably esters of C 10 -C 22 , preferably C 2 -C 20 fatty acids. The Cιo-C 22 fatty acid esters are, for example, esters of unsaturated or saturated C 10 -C 22 fatty acids, especially with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and especially C 8 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
Beispiele für Fettsäureester wie Cιo-C22-Fettsäure-Ester sind Glycerin- und Glykolester von Fettsäuren wie Cιo-C22-Fettsäuren oder deren Umesterungsprodukte, z.B. Alkyl-Fettsäureester wie d-C2o-Alkyl-Cιo-C22- Fettsäure-Ester, wie sie z.B. durch Umesterung der vorgenannten Glycerin- oder Glykol-Fettsäureester wie C10-C22-Fettsäure-Ester mit Cι-C2o-Alkoholen (z.B. Methanol, Ethanol, Propanol oder Butanol) erhalten werden können. Die Umesterung kann nach bekannten Methoden erfolgen, wie sie z.B. beschrieben sind im Römpp Chemie Lexikon, 9. Auflage, Band 2, Seite 1343, Thieme Verlag Stuttgart.Examples of fatty acid esters such as Cιo-C 22 fatty acid esters are glycerol and glycol esters of fatty acids such as Cιo-C 22 fatty acids or their transesterification products, for example alkyl fatty acid esters such as dC 2 o-alkyl-Cιo-C 22 fatty acid esters, as can be obtained, for example, by transesterification of the aforementioned glycerol or glycol fatty acid esters such as C 10 -C 22 fatty acid esters with C 1 -C 2 o-alcohols (for example methanol, ethanol, propanol or butanol). The transesterification can be carried out according to known methods, as described, for example, in the Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
Als Alkyl-Fettsäureester wie Cι-C2o-Alkyl-Cι0-C22-Fettsäure-Ester bevorzugt sind Methylester, Ethylester, Propylester, Butylester, 2-ethyl-hexylester und Dodecylester. Als Glykol- und Glycerin-Fettsäureester wie Cιo-C22-Fettsäure- Ester bevorzugt sind die einheitlichen oder gemischten Glykolester und Glycerinester von Cιo-C 2-Fettsäuren, insbesondere solcher Fettsäuren mit gerader Anzahl an Kohlenstoffatomen, z.B. Erucasäure, Laurinsäure, Palmitinsäure und insbesondere Cis-Fettsäuren wie Stearinsäure, Ölsäure, Linolsäure oder Linolensäure.Preferred alkyl fatty acid esters such as C 1 -C 2 -alkyl-C 0 -C 22 fatty acid esters are methyl esters, ethyl esters, propyl esters, butyl esters, 2-ethyl hexyl esters and dodecyl esters. Preferred glycol and glycerol fatty acid esters such as Cιo-C 22 fatty acid esters are the uniform or mixed glycol esters and glycerol esters of Cιo-C 2 fatty acids, in particular those fatty acids with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and in particular Cis fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
Tierische Öle c) sind allgemein bekannt und kommerziell erhältlich. Unter dem Begriff tierische Öle im Sinne der vorliegenden Erfindung werden z.B. Öle tierischen Ursprungs verstanden wie Waltranöl, Lebertranöl, Moschusöl oder Nerzöl. Pflanzenöle c) sind allgemein bekannt und kommerziell erhältlich. Unter dem Begriff Pflanzenöle im Sinne der vorliegenden Erfindung werden z.B. Öle aus ölliefernden Pflanzenarten wie Sojaöl, Rapsöl, Maiskeimöl, Sonnenblumenöl, Baumwollsaatöl, Leinöl, Kokosöl, Palmöl, Distelöl, Walnussöl, Erdnussöl, Olivenöl oder Rhizinusöl, insbesondere Rapsöl verstanden, wobei unter den Pflanzenölen auch deren Umesterungsprodukte verstanden werden, z.B. Alkylester wie Rapsölmethylester oder Rapsölethylester.Animal oils c) are generally known and commercially available. The term animal oils in the sense of the present invention means, for example, oils of animal origin, such as walnut oil, cod liver oil, musk oil or mink oil. Vegetable oils c) are generally known and commercially available. The term vegetable oils in the sense of the present invention means, for example, oils from oil-producing plant species such as soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, safflower oil, walnut oil, peanut oil, olive oil or castor oil, in particular rapeseed oil their transesterification products are also understood, for example alkyl esters such as rapeseed oil methyl ester or rapeseed oil ethyl ester.
Die Pflanzenöle sind bevorzugt Ester von C10-C22-, vorzugsweise C12-C20- Fettsäuren. Die Cιo-C22-Fettsäureester sind beispielsweise Ester ungesättigter oder gesättigter Cιo-C22-Fettsäuren, insbesondere mit gerader Kohlenstoffatomzahl, z.B. Erucasäure, Laurinsäure, Palmitinsäure und insbesondere Cι8-Fettsäuren wie Stearinsäure, Ölsäure, Linolsäure oder Linolensäure.The vegetable oils are preferably esters of C 10 -C22, preferably C12-C20 fatty acids. The Cιo-C 22 fatty acid esters are, for example, esters of unsaturated or saturated Cιo-C2 2 fatty acids, especially with an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and especially C 8 fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
Beispiele für Pflanzenöle sind Cι0-C22-Fettsäure-Ester von Glycerin oder Glykol mit den Cιo-C22-Fettsäuren, oder Cι-C2o-Alkyl-Cιo-C22-Fettsäure-Ester, wie sie z.B. durch Umesterung der vorgenannten Glycerin- oder GIykol-Cιo-C22- Fettsäure-Ester mit d-C2o-Alkoholen (z.B. Methanol, Ethanol, Propanol oder Butanol) erhalten werden können. Die Umesterung kann nach bekannten Methoden erfolgen, wie sie z.B. beschrieben sind im Römpp Chemie Lexikon, 9. Auflage, Band 2, Seite 1343, Thieme Verlag Stuttgart.Examples of vegetable oils are -C 0 -C 22 fatty acid esters of glycerol or glycol with the Cιo-C 22 fatty acids, or -C-C 2 o-alkyl-Cιo-C 22 fatty acid esters, such as those obtained by transesterification of the The aforementioned glycerol or glycol C 22 C 22 fatty acid esters with dC 2 o-alcohols (for example methanol, ethanol, propanol or butanol) can be obtained. The transesterification can be carried out according to known methods, as described, for example, in the Römpp Chemie Lexikon, 9th edition, volume 2, page 1343, Thieme Verlag Stuttgart.
Die Pflanzenöle können in den erfindungsgemäßen Adjuvantien z.B. in Form kommerziell erhältlicher Pflanzenöle, insbesondere Rapsöle wie Rapsölmethylester, z.B. Phytorob®B (Novance, Frankreich), Edenor® MESU und Agnique®ME-Reihe (Cognis, Deutschland) Radia®-Reihe (ICI), Prilube®-Reihe (Petrofina) oder Biodiesel oder in Form kommerziell erhältlicher pflanzenölhaltiger Formulierungszusatzstoffe, insbesondere solcher auf Basis von Rapsölen wie Rapsölmethylester, z.B. Hasten® (Victorian Chemical Company, Australien, nachfolgend Hasten genannt, Hauptbestandteil: Rapsölethylester), Actirob®B (Novance, Frankreich, nachfolgend ActirobB genannt, Hauptbestandteil: Rapsölmethylester), Rako-Binol® (Bayer AG, Deutschland, nachfolgend Rako-Binol genannt, Hauptbestandteil: Rapsöl), Renol® (Stefes, Deutschland, nachfolgend Renol genannt, Pflanzenölbestandteil: Rapsölmethylester) oder Stefes Mero® (Stefes, Deutschland, nachfolgend Mero genannt, Hauptbestandteil: Rapsölmethylester) enthalten sein.The vegetable oils can in the novel adjuvants for example in the form of commercially available vegetable oils, in particular rapeseed oils, such as Rapsölmethylester such Phytorob®B (Novance, France), Edenor® MESU and Agnique®ME series (Cognis, Germany) Radia ® series (ICI) , Prilube ® series (Petrofina) or biodiesel or in the form of commercially available vegetable oil-containing formulation additives, in particular those based on rapeseed oils such as rapeseed oil methyl ester, e.g. Hasten® (Victorian Chemical Company, Australia, hereinafter referred to as Hasten, main component: rapeseed oil ethyl ester), Actirob®B ( Novance, France, hereinafter ActirobB , main component: rapeseed oil methyl ester), Rako-Binol® (Bayer AG, Germany, hereinafter called Rako-Binol, main component: rapeseed oil), Renol® (Stefes, Germany, hereinafter referred to as Renol, vegetable oil component: rapeseed oil methyl ester) or Stefes Mero® (Stefes, Germany, hereinafter called Mero, main ingredient: rapeseed oil methyl ester).
Beispiele für synthetische Fettsäureester sind z.B. solche die sich von Fettsäuren mit ungerader Kohlenstoffatomanzahl ableiten, wie drC2ι-Fettsäureester.Examples of synthetic fatty acid esters are, for example, those derived from fatty acids with an odd number of carbon atoms, such as drC 2 ι fatty acid esters.
Bevorzugte organische Lösungsmittel sind aromatische Kohlenwasserstoffe, aliphatische Kohlenwasserstoffe und Fettsäureester wie pflanzliche Öle wie Triglyceride von Fettsäuren mit 10 bis 22 C-Atomen, die sowohl gesättigt als auch ungesättigt, linear oder verzweigt sein können und gegebenenfalls weitere funktionelle Gruppen tragen, wie Maiskeimöl, Rapsöl, Sonnenblumenkernöl, Baumwollsaatöl, Leinöl, Sojaöl, Kokosöl, Palmöl, Distelöl oder Rizinusöl, und deren Umesterungsprodukte wie Fettsäurealkylester, sowie Mischungen hieraus.Preferred organic solvents are aromatic hydrocarbons, aliphatic hydrocarbons and fatty acid esters such as vegetable oils such as triglycerides of fatty acids having 10 to 22 carbon atoms, which can be both saturated and unsaturated, linear or branched and optionally carry further functional groups, such as corn oil, rapeseed oil, Sunflower seed oil, cottonseed oil, linseed oil, soybean oil, coconut oil, palm oil, safflower oil or castor oil, and their transesterification products such as fatty acid alkyl esters, and mixtures thereof.
Die Lösungsmittel können allein oder im Gemisch enthalten sein. Das verwendete Lösungsmittel bzw. Lösungsmittelgemisch weist bevorzugt ein geringes Lösevermögen für das verwendete bzw. die verwendeten Phenylsulfonamide (Komponente a) auf.The solvents can be contained alone or in a mixture. The solvent or solvent mixture used preferably has a low solvency for the phenylsulfonamides used (component a).
Der Gesamtlösungsmittelanteil in den erfindungsgemäßen Olsuspensionskonzentraten liegt im allgemeinen zwischen 5 und 95 Gew.%, bevorzugt im Bereich zwischen 20 und 80 Gew.%. Der Anteil an polaren Lösungsmitteln wie aprotischen, polaren liegt im allgemeinen unter 20 Gew.-%, bevorzugt im Bereich von 0 bis 10 Gew.%.The total solvent content in the oil suspension concentrates according to the invention is generally between 5 and 95% by weight, preferably in the range between 20 and 80% by weight. The proportion of polar solvents such as aprotic, polar is generally below 20% by weight, preferably in the range from 0 to 10% by weight.
Die in den erfindungsgemäßen Olsuspensionskonzentraten enthaltenen Sulfosuccinate (Komponente d) können z.B. Mono- oder Diester der Sulfobemsteinsäure sein, vorzugsweise solche der allgemeinen Formel (III) R1-(Xι)n-O-CO-CH2-CH(SO3M)-CO-O-(X2)m-R2 (III)The sulfosuccinates (component d) contained in the oil suspension concentrates according to the invention can be, for example, mono- or diesters of sulfosuccinic acid, preferably those of the general formula (III) R 1 - (Xι) nO-CO-CH 2 -CH (SO 3 M) -CO-O- (X 2 ) mR 2 (III)
, worin, in which
R1 H oder ein unsubstituierter oder substituierter Cι-C3o-Kohlenwasserstoffrest wie Cι-C30-Alkyl oder C7-C30-Alkylaryl bedeutet, R2 H oder ein unsubstituierter oder substituierter Cι-C30-Kohlenwasserstoffrest wie Cι-C30-Alkyl oder C -C3o-Alkylaryl bedeutet, oder ein Kation ist, z.B. einR Cι-C 30 alkyl or C 7 -C 1 is H or an unsubstituted or substituted Cι-C3-o-hydrocarbon radical, such as 30 alkylaryl, R 2 is H or an unsubstituted or substituted Cι-C30 hydrocarbon radical such as Cι-C 30 denotes alkyl or C -C 3 o-alkylaryl, or is a cation, for example a
Metallkation wie ein Alkali- oder Erdalkalimetallkation, oder einMetal cation such as an alkali or alkaline earth metal cation, or a
Ammoniumkation wie NH4, Alkyl-, Alkylaryl- oder Poly(arylalkyl)phenyl- ammoniumkation, X1, X2 unabhängig voneinander gleich oder verschieden eine Spacereinheit wie eine Polyethereinheit oder eine Polyestereinheit bedeuten, n,m unabhängig voneinander gleich oder verschieden Null oder 1 sind, vorzugsweise Null sind, und M ein Kation ist, z.B. ein Metallkation wie ein Alkali- oderAmmonium cation such as NH 4 , alkyl, alkylaryl or poly (arylalkyl) phenylammonium cation, X 1 , X 2 independently of one another, identically or differently, represent a spacer unit such as a polyether unit or a polyester unit, n, m independently of one another, identically or differently, zero or 1 are, preferably are zero, and M is a cation, for example a metal cation such as an alkali metal or
Erdalkalimetallkation, oder ein Ammoniumkation wie NH4, Alkyl-, Alkylaryl- oder Poly(arylalkyl)phenyl-ammoniumkation.Alkaline earth metal cation, or an ammonium cation such as NH 4 , alkyl, alkylaryl or poly (arylalkyl) phenylammonium cation.
Bevorzugt sind Sulfosuccinate der Formel (III), worin R1 und R2 unabhängig voneinander gleich oder verschieden lineare, verzweigte oder cyclische, gesättigte oder ungesättigte C1-C20- vorzugsweise C4-C18-Alkylreste sind, wie Methyl-, Ethyl-, Butyl-, Hexyl-, Cyclohexyl-, Octyl wie 2-Ethylhexyl-, Decyl-, Tridecyl- oder Octadecyl- Reste, oder R1 und R2 sind C7-C20-Aikylarylreste, wie Nonylphenyl, 2,4,6-Tri-sec- butylphenyl, 2,4,6-Tris-(1-phenylethyl)-phenyl, Alkylbenzyl oder ein Hydrozimtrest, X1 und X2 unabhängig voneinander gleich oder verschieden Polyethereinheiten sind, wie Polyethylenglykole -(C2H O)p- oder Polypropylenglykole -(C3H6θ)p- mit p=1 bis p=20, insbesondere p=1 bis p=12, oder Polyestereinheiten sind, wie Polyhydroxybuttersäure -(CH[CH3]-CH2-COO)q- oder Polymilchsäure -(CH[CH3]- COO)q- mit q=1 bis q=15, insbesondere q=1 bis q=8, n, m unabhängig voneinander gleich oder verschieden Null oder 1 sind, vorzugsweise Null sind, und M ein Kation ist, z.B. ein Metallkation, wie Alkali- oder Erdalkalimetallkation, oder ein Ammoniumkation, welches alkyl-substituiert sein kann.Preferred are sulfosuccinates of the formula (III), in which R 1 and R 2 are, independently of one another, the same or different linear, branched or cyclic, saturated or unsaturated C 1 -C 20 - preferably C 4 -C 18 -alkyl radicals, such as methyl, ethyl -, Butyl, hexyl, cyclohexyl, octyl such as 2-ethylhexyl, decyl, tridecyl or octadecyl radicals, or R 1 and R 2 are C 7 -C 20 -alkylaryl radicals, such as nonylphenyl, 2,4, 6-tri-sec-butylphenyl, 2,4,6-tris- (1-phenylethyl) -phenyl, alkylbenzyl or a hydrocinnam residue, X 1 and X 2 are independently the same or different polyether units, such as polyethylene glycols - (C 2 HO) p - or polypropylene glycols - (C 3 H 6 θ) p - with p = 1 to p = 20, in particular p = 1 to p = 12, or polyester units, such as polyhydroxybutyric acid - (CH [CH 3 ] -CH 2 -COO ) q - or polylactic acid - (CH [CH 3 ] - COO) q - with q = 1 to q = 15, in particular q = 1 to q = 8, n, m, independently of one another, are the same or different, zero or 1, preferably zero are, and M ei n is a cation, for example a metal cation such as alkali or Alkaline earth metal cation, or an ammonium cation, which can be alkyl substituted.
Erfindungsgemäß enthaltene Sulfosuccinate sind, beispielsweise a1) ein- oder zweifach mit linearen, cyclischen oder verzweigten aliphatischen, cycloaliphatischen und/oder aromatischen Alkoholen verestertes Sulfosuccinat, beispielsweise mit 1 bis 22 C-Atomen im Alkylrest, vorzugsweise ein- oder zweifach mit Methanol, Ethanol, (Iso)propanol, (Iso)butanol, (Iso)pentanol, (Iso)hexanol, Cyclohexanol, (Iso)heptanol, (Iso)octanol (insbesondere: Ethylhexanol), (Iso)nonanol, (Iso)decanol, (Iso)undecanol, (Iso)dodecanol oder (Iso)tridecanol verestertes Mono- oder Dialkalisulfosuccinat, insbesondere Mono- oder Dinatriumsulfosuccinat, a2) ein- oder zweifach mit (Poly) Alkylenoxidaddukten von Alkoholen verestertes Sulfosuccinat, beispielsweise mit 1 bis 22 C-Atomen im Alkylrest und 1 bis 200, vorzugsweise 2 bis 200 Alkylenoxideinheiten im (Poly) Alkylenoxidanteil, vorzugsweise ein- oder zweifach mit Dodecyl/Tetradecyl-Alkohol +2-5 mol Ethylenoxid oder mit i-Tridecyl+3mol Ethylenoxid verestertes Mono- oder Dialkalisulfosuccinat, insbesondere Mono- oder Dinatriumsulfosuccinat, a3) das Dialkali, vorzugsweise das Dinatriumsalz von einfach mit Aminen oder aminoterminierten (Poly) Alkylenoxidaddukten von Alkoholen, Aminen, Fettsäuren, Estern oder Amiden umgesetztem und nachfolgend sulfoniertem Maleinsäureanhydrid, beispielsweise mit 1 bis 22 C-Atomen im Alkylrest und 1 bis 200, vorzugsweise 2 bis 200 Alkylenoxy-Einheiten im (Poly) Alkylenoxidteil, vorzugsweise das Dinatriumsalz von einfach mit Kokosfettamin umgesetztem und nachfolgend sulfoniertem Maleinsäureanhydrid, a4) das Dialkali, vorzugsweise das Dinatriumsalz von einfach mit Amiden oder (Poly) Alkylenoxidaddukten von Amiden umgesetztem und nachfolgend sulfoniertem Maleinsäureanhydrid, beispielsweise mit 1 bis 22 C-Atomen im Alkylrest und 1 bis 200, vorzugsweise 2 bis 200 Alykylenoxy-Einheiten im (Poly) Alkylenoxidteil, vorzugsweise das Dinatriumsalz von einfach mit Oleylamid+2 mol Ethylenoxid umgesetztem und nachfolgend sulfoniertem Maleinsäureanhydrid und/oder a5) das Tetraalkali, vorzugsweise das Tetranatriumsalz von N-(1 ,2- dicarboxyethyl-)-N-Octadecylsulfo-succinamat.Sulfosuccinates contained according to the invention are, for example a1) sulfosuccinate esterified once or twice with linear, cyclic or branched aliphatic, cycloaliphatic and / or aromatic alcohols, for example with 1 to 22 carbon atoms in the alkyl radical, preferably once or twice with methanol, ethanol, (Iso) propanol, (iso) butanol, (iso) pentanol, (iso) hexanol, cyclohexanol, (iso) heptanol, (iso) octanol (especially: ethylhexanol), (iso) nonanol, (iso) decanol, (iso) undecanol, (iso) dodecanol or (iso) tridecanol esterified mono- or dialkalisulfosuccinate, in particular mono- or disodium sulfosuccinate, a2) sulfosuccinate esterified once or twice with (poly) alkylene oxide adducts of alcohols, for example with 1 to 22 carbon atoms in the alkyl radical and 1 to 200, preferably 2 to 200 alkylene oxide units in the (poly) alkylene oxide portion, preferably mono- or di-esterified with dodecyl / tetradecyl alcohol + 2-5 mol ethylene oxide or M with i-tridecyl + 3 mol ethylene oxide ono- or dialkali sulfosuccinate, in particular mono- or disodium sulfosuccinate, a3) the dialkali, preferably the disodium salt of simply reacted with amines or amino-terminated (poly) alkylene oxide adducts of alcohols, amines, fatty acids, esters or amides and subsequently sulfonated maleic anhydride, for example with 1 to 22 C atoms in the alkyl radical and 1 to 200, preferably 2 to 200 alkyleneoxy units in the (poly) alkylene oxide part, preferably the disodium salt of maleic anhydride reacted simply with coconut fatty amine and subsequently sulfonated, a4) the dialkali, preferably the disodium salt of simply with amides or ( Poly) alkylene oxide adducts of amides reacted and subsequently sulfonated maleic anhydride, for example with 1 to 22 carbon atoms in the alkyl radical and 1 to 200, preferably 2 to 200, alkyleneoxy units in the (poly) alkylene oxide part, preferably the disodium salt, simply with Oleylamide + 2 mol of ethylene oxide reacted and subsequently sulfonated maleic anhydride and / or a5) the tetraalkali, preferably the tetrasodium salt of N- (1,2-dicarboxyethyl) - N-octadecylsulfosuccinamate.
Beispiele kommerziell erhältlicher und im Rahmen der vorliegenden Erfindung bevorzugter Sulfosuccinate der Gruppen a1) bis a5) sind nachfolgend aufgeführt: a1) Natrium-Dialkylsulfosuccinat, z.B. Natrium-Di(C4-Cι8)alkylsulfosuccinat wie Natrium-Diisooctylsulfosuccinat, vorzugsweise Natrium-Di(2- ethylhexyl)sulfosuccinat, kommerziell beispielsweise in Form der Aerosol®- Marken (Cytec), der Agrilan®- oder Lankropol®-Marken (Akzo Nobel), der Empimin®-Marken (Albright&Wilson), der Cropol®-Marken (Croda), der Lutensit®-Marken (BASF) der Triton®-Marken (Union Carbide), der Geropon®- Marken (Rhodia) oder der Imbirol®-, Madeol®- oder Polirol®-Marken (Cesalpinia) erhältlich, a2) Natrium- Alkoholpolyethylenglykolethersulfosuccinat, kommerziell beispielsweise in Form von Geropon® ACR-Marken (Rhodia) erhältlich, a3) Dinatrium-Alkoholpolyethylenglykolethersemisulfosuccinat, kommerziell beispielsweise in Form der Aerosol®-Marken (Cytec), der Marlinat®- oder Sermul®-Marken (Condea), der Empicol®-Marken (Albright&Wilson), der Secosol®-Marken (Stepan), der Geropon®-Marken (Rhodia), der Disponil®- oder Texapon®-Marken (Cognis) oder der Rolpon®-Marken (Cesalpinia) erhältlich, a4) Dinatrium-N-Alkylsulfosuccinamat, kommerziell beispielsweise in Form der Aerosol®-Marken (Cytec), der Rewopol®- oder Rewoderm®-Marken (Rewo), der Empimin®-Marken (Albright&Wilson), der Geropon®-Marken (Rhodia) oder der Polirol®-Marken (Cesalpinia) erhältlich, a5) Dinatrium-Fettsäureamidpolyethylenglykolethersemisulfosuccinat, kommerziell beispielsweise in Form der Elfanol®- oder Lankropol®-Marken (Akzo Nobel), der Rewoderm®-, Rewocid®- oder Rewopol®-Marken (Rewo), der Emcol®-Marken (Witco), der Standapol®-Marken (Cognis) oder der Rolpon®-Marken (Cesalpinia) erhältlich, und a6) Tetranatrium-N-(1 ,2-dicarboxyethyl)-N-Octadecyl-sulfosuccinamat, kommerziell beispielsweise in Form von Aerosol 22®- (Cytec) erhältlich.Examples of commercially available sulfosuccinates from groups a1) to a5) which are preferred in the context of the present invention are listed below: a1) sodium dialkyl sulfosuccinate, for example sodium di (C 4 -C 8 ) alkyl sulfosuccinate such as sodium diisooctyl sulfosuccinate, preferably sodium di ( 2-ethylhexyl) sulfosuccinate, commercially for example in the form of the Aerosol ® brands (Cytec), the Agrilan ® or Lankropol ® brands (Akzo Nobel), the Empimin ® brands (Albright & Wilson), the Cropol ® brands (Croda) , the Lutensit ® brands (BASF), the Triton ® brands (Union Carbide), the Geropon ® brands (Rhodia) or the Imbirol ® , Madeol ® or Polirol ® brands (Cesalpinia), a2) sodium Alcohol polyethylene glycol ether sulfosuccinate, commercially available for example in the form of Geropon ® ACR brands (Rhodia), a3) disodium alcohol polyethylene glycol ether semisulfosuccinate, commercially available for example in the form of the Aerosol ® brands (Cytec), the Marlinat ® - or Sermul ® brands (Condea), the Empicol ® brands (Albright & Wilson), the Secosol ® brands (Stepan), the Geropon ® brands (Rhodia), the Disponil ® or Texapon ® brands (Cognis) or the Rolpon ® brands (Cesalpinia) available, a4) disodium N-alkylsulfosuccinamate, commercially, for example in the form of the Aerosol ® brands (Cytec), the Rewopol ® or Rewoderm ® brands (Rewo), the Empimin ® brands (Albright & Wilson ), the Geropon ® brands (Rhodia) or the Polirol ® brands (Cesalpinia), a5) disodium fatty acid amide polyethylene glycol ether semisulfosuccinate, commercially for example in the form of the Elfanol ® or Lankropol ® brands (Akzo Nobel), the Rewoderm ® , Rewocid ® or Rewopol ® brands (Rewo), the Emcol ® brands (Witco), the Standapol ® brands (Cognis) or the Rolpon ® brands (Cesalpinia), and a6) Tetrasodium N- (1, 2-dicarboxyethyl) -N-octadecyl sulfosuccinamate, commercially available for example in the form of Aerosol 22® - (Cytec).
Kommerziell sind Sulfosuccinate zum Beispiel als Aerosol®- (Cytec), Agrilan®- oder Lankropol®- (Akzo Nobel), Empimin®- (Huntsman). Cropol®- (Croda), Lutensit®- (BASF), Triton®GR-Reihe (UnionCarbide), lmbirol®-/Madeol®-/Polirol®- (Cesalpinia); Geropon®AR-Reihe oder Geropon®SDS (Rhodia) erhältlich.Sulfosuccinates are commercially available, for example, as an aerosol ® - (Cytec), Agrilan® ® - or Lankropol ® - (Akzo Nobel), Empimin ® - (Huntsman). Cropol ® - (Croda), Lutensit ® - (BASF), Triton ® GR series (UnionCarbide), lmbirol ® - / Madeol ® - / Polirol ® - (Cesalpinia); Geropon ® AR series or Geropon ® SDS (Rhodia) available.
Bevorzugte Sulfosuccinate sind z.B. die Natrium-, Kalium- und Ammoniumsalze von Bis(alkyl)sulfosuccinaten, wobei die Alkylreste gleich oder verschieden 4 bis 16 Kohlenstoffatome enthalten, und bevorzugt Butyl-, Hexyl-, Octyl- wie 2-Ethylhexyl- oder Decyl-Reste sind, die linear oder verzweigt sein können.Preferred sulfosuccinates are e.g. the sodium, potassium and ammonium salts of bis (alkyl) sulfosuccinates, the alkyl radicals, identically or differently, containing 4 to 16 carbon atoms, and preferably butyl, hexyl, octyl such as 2-ethylhexyl or decyl radicals, which are linear or can be branched.
Der Gesamtanteil des Sulfosuccinats bzw. der Sulfosuccinate in den erfindungsgemäßen Olsuspensionskonzentraten liegt im allgemeinen zwischen 0,1 und 60 Gew.%, insbesondere im Bereich zwischen 0,5 und 30 Gew.%.The total proportion of the sulfosuccinate or sulfosuccinates in the oil suspension concentrates according to the invention is generally between 0.1 and 60% by weight, in particular in the range between 0.5 and 30% by weight.
Als übliche Hilfs- und Zusatzstoffe (Komponente f) können in den erfindungsgemäßen Olsuspensionskonzentraten z.B. noch enthalten sein: Tenside wie Emulgatoren und Dispergatoren, Verdickungs- und Thixotropiermittel, Netz-, Anti-Drift-, Haft-, Penetrations-, Konservierungs- und Frostschutzmittel, Antioxidantien, Lösungsvermittler, Füll-, Träger- und Farbstoffe, Entschäumer, Düngemittel, Verdunstungshemmer, sowie den pH-Wert und die Viskosität beeinflussende Mittel.As usual auxiliaries and additives (component f) in the oil suspension concentrates according to the invention e.g. still included: surfactants such as emulsifiers and dispersants, thickeners and thixotropic agents, wetting agents, anti-drift agents, adhesives, penetrants, preservatives and antifreeze agents, antioxidants, solubilizers, fillers, carriers and dyes, defoamers, fertilizers, Evaporation inhibitors, as well as agents that influence pH and viscosity.
Als Emulgatoren und Dispergatoren kommen z.B. nichtionische Emulgatoren und Dispergatoren in Frage, z.B.:Suitable emulsifiers and dispersants are e.g. nonionic emulsifiers and dispersants in question, e.g .:
1) polyalkoxylierte, vorzugsweise polyethoxylierte, gesättigte und ungesättigte aliphatische Alkohole,1) polyalkoxylated, preferably polyethoxylated, saturated and unsaturated aliphatic alcohols,
• mit 8 bis 24 C-Atomen im Alkylrest, der sich von den entsprechenden Fettsäuren oder aus petrochemischen Produkten ableitet, und • mit 1 bis 100, vorzugsweise 2 bis 50, Ethylenoxideinheiten (EO), wobei die freie Hydroxy-Gruppe gegebenenfalls alkoxyliert ist,• With 8 to 24 carbon atoms in the alkyl radical, which is derived from the corresponding fatty acids or from petrochemical products, and • 1 to 100, preferably 2 to 50, ethylene oxide units (EO), wherein the free hydroxyl group to be alkoxylated,
• die z. B. kommerziell als Genapol®X- und Genapol®O-Reihe (Clariant), Crovol®M-Reihe (Croda) oder Lutensol®Reihe (BASF) erhältlich sind, • the z. B. are commercially available as Genapol ® X and Genapol ® O series (Clariant), Crovol ® M series (Croda) or Lutensol ® series (BASF),
2) polyalkoxylierte, vorzugsweise polyethoxylierte Arylalkylphenole, wie z. B. 2,4,6- Tris-(1-phenylethyl)-phenol (Tristyrylphenol) mit einem mittleren Ethoxylierungsgrad zwischen 10 und 80, bevorzugt 16 bis 40, wie z. B. Soprophor®BSU (Rhodia) oder HOE S 3474 (Clariant),2) polyalkoxylated, preferably polyethoxylated arylalkylphenols, such as. B. 2,4,6-tris (1-phenylethyl) phenol (tristyrylphenol) with an average degree of ethoxylation between 10 and 80, preferably 16 to 40, such as. B. Soprophor ® BSU (Rhodia) or HOE S 3474 (Clariant),
3) polyalkoxylierte, vorzugsweise polyethoxylierte Alkylphenole mit einem oder mehreren Alkylresten, wie z. B. Nonylphenol oder Tri-sec-butylphenol, und einem Ethoxylierungsgrad zwischen 2 und 40, bevorzugt 4 bis 15, wie z. B. Arkopal®N- Reihe oder Sapogenat®T-Reihe (Clariant),3) polyalkoxylated, preferably polyethoxylated alkylphenols with one or more alkyl radicals, such as. B. nonylphenol or tri-sec-butylphenol, and a degree of ethoxylation between 2 and 40, preferably 4 to 15, such as. B. Arkopal ® N series or Sapogenat ® T series (Clariant),
4) polyalkoxylierte, vorzugsweise polyethoxylierte Hydroxyfettsäuren oder Hydroxyfettsäuren enthaltene Glyceride, wie z. B. Ricinin bzw. Rizinusöl, mit einem Ethoxylierungsgrad zwischen 10 und 80, bevorzugt 25 bis 40, wie z. B. Emulsogen®EL-Reihe (Clariant) oder Agnique®CSO-Reihe (Cognis),4) polyalkoxylated, preferably polyethoxylated hydroxy fatty acids or glycerides containing hydroxy fatty acids, such as. B. ricinine or castor oil, with a degree of ethoxylation between 10 and 80, preferably 25 to 40, such as. B. Emulsogen ® EL series (Clariant) or Agnique ® CSO series (Cognis),
5) polyalkoxylierte, vorzugsweise polyethoxylierte Sorbitanester, wie z. B. Atplus®309 F (Uniqema) oder Alkamuls®-Reihe (Rhodia)5) polyalkoxylated, preferably polyethoxylated sorbitan esters, such as. B. Atplus ® 309 F (Uniqema) or Alkamuls ® series (Rhodia)
6) Di- und Tri-block-copolymere, z.B. aus Alkylenoxiden, z.B. aus Ethylen- und Propylenoxid mit mittleren Molmassen zwischen 200 und 10000, vorzugsweise 1000 bis 4000 g/mol, wobei der Massenanteil des polyethoxylierte Blocks zwischen 10 und 80% variiert, wie z. B. Genapol®PF-Reihe (Clariant), Pluronic®- Reihe (BASF), oder Synperonic®PE-Reihe (Uniqema),6) di- and tri-block copolymers, for example of alkylene oxides, for example of ethylene and propylene oxide, with average molar masses between 200 and 10,000, preferably 1000 to 4000 g / mol, the mass fraction of the polyethoxylated block varying between 10 and 80%, such as B. Genapol ® PF series (Clariant), Pluronic ® series (BASF), or Synperonic ® PE series (Uniqema),
Bevorzugte nichtionische Emulgatoren und Dispergatoren sind z.B. polyethoxylierte Alkohole, polyethoxylierte Triglyceride, die Hydroxyfettsäuren enthalten und Polyethylenoxid-Polypropylenoxid-Block-Copolymere. Der Gesamtanteil an nichtionischen Emulgatoren und Dispergatoren in den erfindungsgemäßen Olsuspensionskonzentraten liegt im allgemeinen zwischen 0 und 20 Gew.%. Werden nichtionische Emulgatoren und Dispergatoren, neben ihren emulgierenden/dispergierenden Eigenschaften, auch zur Erhöhung der biologischen Effektivität, z. B. als Penetrations- oder Haftmittel, eingesetzt, kann sich ihr Anteil in den erfindungsgemäßen Olsuspensionskonzentraten auf bis zu 60 Gew.% erhöhen.Preferred nonionic emulsifiers and dispersants are, for example, polyethoxylated alcohols, polyethoxylated triglycerides which contain hydroxy fatty acids and polyethylene oxide-polypropylene oxide block copolymers. The total proportion of nonionic emulsifiers and dispersants in the oil suspension concentrates according to the invention is generally between 0 and 20% by weight. Are nonionic emulsifiers and dispersants, in addition to their emulsifying / dispersing properties, also to increase the biological effectiveness, for. B. used as a penetration or adhesive, their proportion in the oil suspension concentrates according to the invention can increase to up to 60% by weight.
Es kommen auch ionische Emulgatoren und Dispergatoren in Frage, z.B.:Ionic emulsifiers and dispersants are also suitable, for example:
1) polyalkoxylierte, vorzugsweise polyethoxylierte Emulgatoren/Dispergatoren (vgl. Komponente e), die ionisch modifiziert sind, z. B. durch Umsetzung der endständigen freien Hydroxylfunktion des Polyethylenoxidblocks zu einem Sulfatoder Phosphatester (z. B. als Alkali- und Erdalkalimetallsalze), wie z. B. Genapol®LRO oder Dispergiermittel 3618 (Clariant), Emulphor® (BASF) oder Crafol®AP (Cognis),1) polyalkoxylated, preferably polyethoxylated emulsifiers / dispersants (cf. component e), which are ionically modified, e.g. B. by reacting the terminal free hydroxyl function of the polyethylene oxide block to a sulfate or phosphate ester (z. B. as alkali and alkaline earth metal salts), such as. B. Genapol ® LRO or dispersant 3618 (Clariant), Emulphor ® (BASF) or Crafol ® AP (Cognis),
2) Alkali- und Erdalkalimetallsalze von Alkylarylsulfonsäuren mit linearer oder verzweigter Alkylkette, wie Phenylsulfonat CA oder Phenylsulfonat CAL (Clariant), Atlox® 3377BM (ICI), Empiphos®TM-Reihe (Huntsman)2) alkali metal and alkaline earth metal salts of alkylarylsulfonic acids having a linear or branched alkyl chain, such as phenylsulfonate CA or phenylsulfonate CAL (Clariant), Atlox ® 3377BM (ICI), Empiphos ® TM series (Huntsman)
3) Polyelektrolyte, wie Ligninsulfonate, Kondensationsprodukte aus Naphthalinsulfonat und Formaldehyd, Polystyrolsulfonat oder sulfonierte ungesättigte oder aromatische Polymere (Polystyrole, Polybutadiene oder Polyterpene), wie Tamol®-Reihe (BASF), Morwet®D425 (Witco), Kraftsperse®- Reihe (Westvaco), Borresperse®-Reihe (Borregard).3) Polyelectrolytes, such as lignin sulfonates, condensation products of naphthalene sulfonate and formaldehyde, polystyrene sulfonate or sulfonated unsaturated or aromatic polymers (polystyrenes, polybutadienes or polyterpenes), such as Tamol ® series (BASF), Morwet ® D425 (Witco), Kraftsperse ® series ), Borresperse ® series (Borregard).
Bevorzugte ionische Emulgatoren/Dispergatoren sind z.B. Salze von Alkylarylsulfonsäuren und Polyelektrolyte aus der Polykondensation von Naphthalinsulfonat und Formaldehyd. Der Gesamtanteil an ionischen Emulgatoren und Dispergatoren in den erfindungsgemäßen Olsuspensionskonzentraten liegt im allgemeinen zwischen 0 und 20 Gew.%, insbesondere zwischen 0 und 8 Gew.%.Preferred ionic emulsifiers / dispersants are, for example, salts of alkylarylsulfonic acids and polyelectrolytes from the polycondensation of naphthalenesulfonate and formaldehyde. The total proportion of ionic emulsifiers and dispersants in the oil suspension concentrates according to the invention is generally between 0 and 20% by weight, in particular between 0 and 8% by weight.
Als Verdickungs- und Thixotropiermittel kommen z.B. in Frage:As thickening and thixotropic agents are e.g. in question:
1) modifizierte natürliche Silikate, wie chemisch modifizierte Bentonite, Hectorite, Attapulgite, Montmorillonite, Smektite oder andere Silikatmineralien, wie Bentone® (Elementis), Attagel® (Engelhard), Agsorb® (Oil-Dri Corporation) oder Hectorite® (Akzo Nobel)1) modified natural silicates, such as chemically modified bentonites, hectorites, attapulgites, montmorillonites, smectites or other silicate minerals, such as Bentone ® (Elementis), Attagel ® (Engelhard), Agsorb ® (Oil-Dri Corporation) or Hectorite ® (Akzo Nobel)
2) synthetische Silikate, wie Silikate der Sipernat®-, Aerosil®- oder Durosil®-Reihe (Degussa), der CAB-O-SIL®-Reihe (Cabot) oder der Van Gel-Reihe (R.T. Vanderbilt),2) synthetic silicates, such as silicates from the Sipernat ® , Aerosil ® or Durosil ® series (Degussa), the CAB-O-SIL ® series (Cabot) or the Van Gel series (RT Vanderbilt),
3) Verdicker auf Basis synthetischer Polymere, wie Verdicker der Thixin®- oder
Figure imgf000043_0001
(Elementis).3) Thickeners based on synthetic polymers, such as Thixin ® - or
Figure imgf000043_0001
(Elementis).
4) Verdicker auf Basis natürlicher Polymere und natürlicher Öle, z.B. aus der Thixin®- oder Thixatrol®-Reihe (Elementis).4) Thickeners based on natural polymers and natural oils, eg from the Thixin ® or Thixatrol ® series (Elementis).
Bevorzugte Verdickungs- und Thixotropiermittel sind z.B. modifizierte Schichtsilikate und Verdicker auf Basis synthetischer Polymere.Preferred thickeners and thixotropic agents are e.g. modified layered silicates and thickeners based on synthetic polymers.
Der Anteil an Verdickungs- und Thixotropiermitteln in den erfindungsgemäßen Olsuspensionskonzentraten liegt im allgemeinen zwischen 0 und 5 Gew.%, insbesondere zwischen 0,2 und 3 Gew.%.The proportion of thickeners and thixotropic agents in the oil suspension concentrates according to the invention is generally between 0 and 5% by weight, in particular between 0.2 and 3% by weight.
Bevorzugt sind erfindungsgemäße Ölsuspensionskonzentrate, enthaltend: a) 0,1 bis 30 Gew.-% eines oder mehrere herbizider Wirkstoffe aus der Gruppe der Sulfonamide, b) 2 bis 40 Gew.-% eines oder mehrere Safener, c) 20 bis 80 Gew.-% eines oder mehrere Lösungsmittel, d) 0,5 bis 30 Gew.-% eines oder mehrere Sulfosuccinate, e) 3 bis 20 Gew.-% eines oder mehrere von a) und b) verschiedener agrochemischer Wirkstoffe, f) 0 bis 20 Gew.-% eines oder mehrere nichtionischer Emulgatoren und Dispergatoren,Oil suspension concentrates according to the invention are preferred, comprising: a) 0.1 to 30% by weight of one or more herbicidal active compounds from the group of the sulfonamides, b) 2 to 40% by weight of one or more safeners, c) 20 to 80% by weight. % of one or more solvents, d) 0.5 to 30% by weight of one or more sulfosuccinates, e) 3 to 20% by weight of one or more agrochemical active substances different from a) and b), f) 0 to 20% by weight of one or more nonionic emulsifiers and dispersants,
0 bis 8 Gew.-% eines oder mehrerer ionischer Emulgatoren und0 to 8% by weight of one or more ionic emulsifiers and
Dispergatorendispersants
0 bis 3 Gew.-% eines oder mehrerer Verdickungs- und Thixotriopiermittel.0 to 3% by weight of one or more thickening and thixotroping agents.
In einer bevorzugten Ausführungsform enthält das erfindungsgemäße Ölsuspensionskonzentrat a) ein oder mehrere herbizide Wirkstoffe der Formel (I) oder Formel (IV) und/oder deren Salze, vorzugsweise A1.1 bis A19.2, b) einen Safener aus der Gruppe S1 -1 , S1 -9 und S2-1 , c) ein organisches Lösungsmittel aus der Gruppe der aliphatischen Kohlenwasserstoffe, der Gemische von aromatischen und aliphatischen Kohlenwasserstoffe und der Pflanzenöle wie Rapsölmethylester, und d) ein Alkali Di(C4-Ci8)alkylsulfosuccinat wie Natrium Di(C4- C18)alkylsulfosuccinat.In a preferred embodiment, the oil suspension concentrate a) according to the invention contains one or more herbicidal active compounds of the formula (I) or formula (IV) and / or their salts, preferably A1.1 to A19.2, b) a safener from the group S1-1 , S1 -9 and S2-1, c) an organic solvent from the group of aliphatic hydrocarbons, the mixtures of aromatic and aliphatic hydrocarbons and vegetable oils such as rapeseed oil methyl ester, and d) an alkali di (C 4 -Ci8) alkylsulfosuccinate such as sodium Di (C 4 - C 18 ) alkyl sulfosuccinate.
Als besonders bevorzugte Beispiele seien erfindungsgemäße Ölsuspensionskonzentrate genannt, welche die nachfolgend genannten Komponenten enthalten, ohne dass dadurch eine Einschränkung erfolgen soll. Dabei bedeutet Solvesso ein Lösungsmittel aus der Solvesso®-Reihe, vorzugsweise Solvesso®200, Bayol ein Lösungsmittel aus der Bayol®-Reihe, vorzugsweise Bayol®82, Edenor = Edenor®MESU und Actirob = Actirob®B.Oil suspension concentrates according to the invention which contain the components mentioned below should be mentioned as particularly preferred examples, without any intention that this should impose a restriction. Solvesso means a solvent from the Solvesso ® series, preferably Solvesso ® 200, Bayol a solvent from the Bayol ® series, preferably Bayol ® 82, Edenor = Edenor ® MESU and Actirob = Actirob ® B.
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A1.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A1.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A1.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A1.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A2.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A3.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A3.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A4.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A4.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A4.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A4.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A5.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A5.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A5.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A5.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A6.1 + EX, Natrium- di(2-ethylhexyl)sulfosuccinat + Bayol + S1-1 + A6.1 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S1-1 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A6.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S1-1 + A6.1 , Natrium- di(2-ethy\hexy.)su.fosuccinat + Edenor + S1-1 + A6.1 , Nauium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A6.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A7.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A8.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A8.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A9.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A9.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A10.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-1 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A1 .1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A11.1 , Natrium-di(2- ethylhexyll))su Ifosuccina + Edenor + S1- + A11.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S ■1 + A11.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S ■1 + A12.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Bayol + S1-1 + A12.1 , Natrium-di(2- ethylhexyll))su Ifosuccina + Edenor + S1- + A12.1 , Natrium-di(2- ethylhexyll))su Ifosuccina + Actirob B + S -1 + A12.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S -1 + A13.1 , Natrium-di(2- ethylhexyl l)su Ifosuccina + Bayol + S1-1 + A13.1 , Natrium-di(2- ethylhexyl l)su Ifosuccina + Edenor + S1- + A13.1, Natrium-di(2- ethylhexyll))su Ifosuccina + Actirob B + S -1 + A13.1, Natrium-di(2- ethylhexyl l)su Ifosuccina + Solvesso + S -1 + A14.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Bayol + S1-1 + A14.1 , Natrium-di(2- ethylhexyl l)su Ifosuccina + Edenor + S1- + A14.1 , Natrium-di(2- ethylhexyll))su Ifosuccina + Actirob B + S -1 + A14.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S -1 + A15.1 , Natrium-di(2- ethylhexy1 l)su Ifosuccina + Bayol + S1-1 + A 5.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Edenor + S1- + A15.1, Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S -1 + A15.1 , Natrium-di(2- ethylhexyll))su Ifosuccina + Solvesso + S -1 + A16.1 , Natrium-di(2- ethylhexyl l)su Ifosuccina + Bayol + S1-1 + A16.1, Natrium-di(2- ethylhexy l)su Ifosuccina + Edenor + S1- + A16.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S 1 + A16.1 , Natrium-di(2- ethylhexyll))su Ifosuccina + Solvesso + S 1 + A17.1 , Natrium-di(2- ethylhexyll))su Ifosuccina + Bayol + S1-1 + A17.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Edenor + S1- + A17.1, Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S 1 + A17.1, Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S 1 + A18.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Bayol + S1-1 + A18.1 , Natrium-di(2- ethylhexyll))su Ifosuccina + Edenor + S1- + A18.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S -1 + A18.1, Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S -1 + A19.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Bayol + S1-1 + A19.1 , Natrium-di(2- ethylhexyll))su Ifosuccinat + Edenor + S1- + A19.1, Natrium-di(2- ethylhexyll))su Ifosuccinat + Actirob B + S -1 +A19.1, Natrium-di(2- ethylhexyll))su Ifosuccinat + Solvesso + S -1 +A20.1, Natrium-di(2- ethylhexyll))su Ifosuccinat + Bayol + S1-1 + A20.1, Natrium-di(2 ethylhexyl l)su fosuccinat + Edenor + S1- + A20.1, Natrium-di(2- ethylhexyll))su fosuccinat + Actirob B + S -1 +A20.1, Natrium-di(2- ethylhexyl l)sul fosuccinat + Solvesso + S -1+21.1, Natrium-di(2- ethylhexy l)su fosuccinat + Bayol + S1-1 + A21.1, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1- + A21.1, Natrium-di(2- ethylhexy l)su fosuccinat + Actirob B + S -1 +A21.1, Natrium-di(2- ethylhexy l)su fosuccinat + Solvesso + S -1 +A22.1, Natrium-di(2- ethylhexyl l)su fosuccinat + Bayol + S1-1 + A22.1, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1- + A22.1, Natrium-di(2- ethylhexyl l)su ifosuccinat + Actirob B + S -1 +A22.1, Natrium-di(2- ethylhexyl l)su fosuccinat + Solvesso + S -1 +A23.1, Natrium-di(2- ethylhexyl l)su fosuccinat + Bayol + S1-1 + A23.1, Natrium-di(2- ethylhexyl l)su Ifosuccinat + Edenor + S1- + A23.1, Natrium-di(2- ethylhexyl l)su Ifosuccinat + Actirob B + S 1 +A23.1, Natrium-di(2- ethylhexyl l)su Ifosuccinat + Solvesso + S 1 +A24.1, Natrium-di(2- ethylhexyl l)su fosuccinat + Bayol + S1-1 + A24.1, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1- + A24.1, Natrium-di(2- ethylhexyll))su ifosuccinat + Actirob B + S -1 +A24.1, Natrium-di(2- ethylhexy l)su fosuccinat + Solvesso + S -1 +A25.1,Natrium-di(2- ethylhexy l)su Ifosuccinat + Bayol + S1-1 + A25.1, Natrium-di(2- ethylhexyl l)su fosuccinat + Edenor + S1- + A25.1, Natrium-di(2- ethylhexy l)su fosuccinat + Actirob B + S -1 +A25.1, Natrium-di(2- ethylhexyl l)su fosuccinat + Solvesso + S -1 +A26.1, Natrium-di(2- ethylhexy l)su fosuccinat + Bayol + S1-1 + A26.1, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1- + A26.1, Natrium-di(2- ethylhexy l)su fosuccinat + Actirob B + S -1 +A26.1, Natrium-di(2- ethylhexy l)su fosuccinat + Solvesso + S -1 +A27.1, Natrium-di(2- ethylhexy l)su Ifosuccinat + Bayol + S1-1 + A27.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1- + A27.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S 1-1 + A27.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S 1-1 + A28.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A28.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1- + A28.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S -1 + A28.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S -1 + A29.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A29.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1- + A29.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S 1-1 + A29.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S -1 + A30.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A30.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1- + A30.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S -1 + A30.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S -1 + A31.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A31.1 , Natriυm-di(2- ethylhexyl)sulfosuccinat + Edenor + S1- + A31.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S -1 + A31.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S 1-1 + A32.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A32.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1- + A32.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S -1 + A32.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S 1-1 + A33.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A33.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1- + A33.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S -1 + A33.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S -1 + A34.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A34.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1- + A34.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S -1 + A34.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S -1 + A35.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-1 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-1 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A35.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A36.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-1 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A36.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A37.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A37.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-1 + A37.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A37.1.Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A2.1 , Sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A3. 1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A4 .1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A4.1, sodium di (2- ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A6.1 + EX, sodium di (2-ethylhexyl ) sulfosuccinate + Solvesso + S1-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A6.1, sodium di (2-ethy \ hexy.) su.fosuccinate + Edenor + S1-1 + A6.1, nauium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A7.1, sodium -di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + actirob B + S1-1 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A8.1, Sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A9.1, sodium di (2-ethylhexyl) sulfosucci nat + Bayol + S1-1 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A9 .1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A10.1, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S1-1 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A1 .1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A11.1, sodium di (2- ethylhexyll)) su Ifosuccina + Edenor + S1- + A11.1, sodium di (2-ethylhexyl) su Ifosuccina + Actirob B + S ■ 1 + A11.1, sodium di (2-ethylhexy l) su Ifosuccina + Solvesso + S ■ 1 + A12.1, sodium di (2-ethylhexyl) su Ifosuccina + Bayol + S1-1 + A12.1, sodium di (2-ethylhexyll)) su Ifosuccina + Edenor + S1- + A12 .1, Sodium di (2-ethylhexyll)) su Ifosuccina + Actirob B + S -1 + A12.1, sodium di (2-ethylhexyl) su Ifosuccina + Solvesso + S -1 + A13.1, sodium di (2-ethylhexyl l) su Ifosuccina + Bayol + S1-1 + A13.1, sodium di (2-ethylhexyl l) su Ifosuccina + Edenor + S1- + A13.1, sodium di (2-ethylhexyll)) see below Ifosuccina + Actirob B + S -1 + A13.1, sodium di (2-ethylhexyl l) see below Ifosuccina + Solvesso + S -1 + A14.1, sodium di (2-ethylhexy l) see below Ifosuccina + Bayol + S1-1 + A14.1, sodium di (2-ethylhexyl) see Ifosuccina + Edenor + S1- + A14.1, sodium di (2-ethylhexyll)) see Ifosuccina + Actirob B + S -1 + A14. 1, sodium di (2-ethylhexyl) su Ifosuccina + Solvesso + S -1 + A15.1 , Sodium di (2-ethylhexy 1 l) su Ifosuccina + Bayol + S1-1 + A 5.1, sodium di (2- ethylhexy l) su Ifosuccina + Edenor + S1- + A15.1, sodium di (2- ethylhexy l) su Ifosuccina + Actirob B + S -1 + A15.1, sodium di (2-ethylhexyll)) su Ifosuccina + Solvesso + S -1 + A16.1, sodium di (2-ethylhexyl l) su Ifosuccina + Bayol + S1-1 + A16.1, sodium di (2-ethylhexyl) see Ifosuccina + Edenor + S1- + A16.1, sodium di (2-ethylhexyl) see Ifosuccina + Actirob B + S 1 + A16.1, sodium di (2-ethylhexyll)) su Ifosuccina + Solvesso + S 1 + A17.1, sodium di (2-ethylhexyll)) su Ifosuccina + Bayol + S1-1 + A17.1, sodium di (2-ethylhexyl) see Ifosuccina + Edenor + S1- + A17.1, sodium di (2-ethylhexyl) see Ifosuccina + Actirob B + S 1 + A17.1, sodium di (2-ethylhexyl) see below Ifosuccina + Solvesso + S 1 + A18.1, sodium di (2-ethylhexyl) see Ifosuccina + Bayol + S1-1 + A18.1, sodium di (2-ethylhexyl)) see Ifosuccina + Edenor + S1- + A18.1, sodium di (2-ethylhexyl) su Ifosuccina + Actirob B + S -1 + A18.1, Sodium di (2-ethylhexyl) su Ifosuccina + Solvesso + S -1 + A19.1, sodium di (2-ethylhexyl l) su Ifosuccina + Bayol + S1-1 + A19.1, sodium di (2- ethylhexyll)) su ifosuccinate + Edenor + S1- + A19.1, sodium di (2-ethylhexyll)) su ifosuccinate + Actirob B + S -1 + A19.1, sodium di (2-ethylhexyll)) su ifosuccinate + Solvesso + S -1 + A20.1, sodium di (2-ethylhexyll)) su ifosuccinate + Bayol + S1-1 + A20.1, sodium di (2 ethylhexyl l) su fosuccinate + Edenor + S1- + A20. 1, sodium di (2-ethylhexyll)) su fosuccinate + Actirob B + S -1 + A20.1, sodium di (2-ethylhexyl l) sul fosuccinate + Solvesso + S -1 + 21.1, sodium di (2 - ethylhexy l) su fosuccinate + Bayol + S1-1 + A21.1, sodium di (2-ethylhexy l) su fosuccinate + Edenor + S1- + A21.1, sodium di (2-ethylhexy l) su fosuccinate + Actirob B + S -1 + A21.1, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S -1 + A22.1, sodium di (2-ethylhexyl l) su fosuccinate + bayol + S1-1 + A22.1, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- + A22.1, sodium di (2-ethylhexyl l) su ifosuccinate + Actirob B + S -1 + A22.1, sodium -di (2-ethylhexyl l) su fosuccinate + Solvesso + S -1 + A23.1, sodium di (2-ethylhe xyl l) su fosuccinate + Bayol + S1-1 + A23.1, sodium di (2-ethylhexyl l) su ifosuccinate + Edenor + S1- + A23.1, sodium di (2-ethylhexyl l) su ifosuccinate + actirob B + S 1 + A23.1, sodium di (2-ethylhexyl l) su ifosuccinate + Solvesso + S 1 + A24.1, sodium di (2-ethylhexyl l) su fosuccinate + bayol + S1-1 + A24. 1, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- + A24.1, sodium di (2-ethylhexyl)) su ifosuccinate + Actirob B + S -1 + A24.1, sodium di ( 2-ethylhexyl) su fosuccinate + Solvesso + S -1 + A25.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-1 + A25.1, sodium di (2-ethylhexyl l) su fosuccinate + Edenor + S1- + A25.1, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S -1 + A25.1, sodium di (2-ethylhexyl l) su fosuccinate + Solvesso + S - 1 + A26.1, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1-1 + A26.1, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- + A26.1, sodium -di (2-ethylhexyl) su fosuccinate + Actirob B + S -1 + A26.1, sodium di (2-ethylhexyl) su fosu ccinat + Solvesso + S -1 + A27.1, sodium di (2-ethylhexyl) su Ifosuccinate + Bayol + S1-1 + A27.1, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S1- + A27.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S 1-1 + A27.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S 1- 1 + A28.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A28.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1- + A28.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S -1 + A28.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S -1 + A29.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1- 1 + A29.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1- + A29.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S 1-1 + A29.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S -1 + A30.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A30.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1 - + A30.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S -1 + A30.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S -1 + A31.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A31.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1- + A31.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S -1 + A31. 1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S 1-1 + A32.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A32.1, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S1- + A32.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S -1 + A32.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S 1-1 + A33.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A33.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1- + A33.1, sodium di (2-ethylhexyl ) sulfosuccinate + Actirob B + S -1 + A33.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S -1 + A34.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A34.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1- + A34.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S -1 + A34.1, sodium di (2- ethylhexyl) sulfosuccinate + Solvesso + S -1 + A35.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-1 + A35.1, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S1-1 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A36.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1- 1 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A37.1.
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A1.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A2.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A3.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A4.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A5.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A6.2 + EX, Natrium- di(2-ethylhexyl)sulfosuccinat + Bayol + S1-1 + A6.2 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S1-1 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A6.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S1-1 + A6.2, Natrium- di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A6.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A6.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A7.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A8.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A8.2, Natrium-di(2-ethylhexyl)su!fosuccinat + Actirob B + S1-1 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A9.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-1 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A11.2, Nauϊum-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-1 + A15.2, Natrium-di(2- ethylhexyQsulfosuccinat + Bayol + S1-1 + A15.2, Natrium-di(2- ethylhexy1 l)su Ifosuccinat + Edenor + S1- + A15.2, Natrium-di(2- ethylhexyll))su fosuccinat + Actirob B + S -1 + A15.2, Natrium-di(2- ethylhexy l)su fosuccinat + Solvesso + S -1 + A16.2, Natrium-di(2- ethylhexyll))su fosuccinat + Bayol + S1-1 - A16.2, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1- + A16.2, Natrium-di(2- ethylhexy l)su fosuccinat + Actirob B + S -1 + A16.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Solvesso + S -1 + A17.2, Natrium-di(2- ethylhexy l)su fosuccinat + Bayol + S1-1 + A17.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Edenor + S1- + A17.2, Natrium-di(2- ethylhexy l)su fosuccinat + Actirob B + S -1 + A17.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Solvesso + S -1 + A18.2, Natrium-di(2- ethylhexy l)su fosuccinat + Bayol + S1-1 + A18.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Edenor + S1- + A18.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Actirob B + S -1 + A18.2, Natrium-di(2- ethylhexy l)su fosuccinat + Solvesso + S -1 + A19.2, Natrium-di(2- ethylhexy tysu1 [fosuccinat + Bayol + S1-1 + A19.2, Natriυm-di(2- ethylhexyl l)su fosuccinat + Edenor + S1- + A19.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Actirob B + S 1 + A19.2, Natrium-di(2- ethylhexy l)su fosuccinat + Solvesso + S 1 + A20.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Bayol + S1-1 A20.2, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1- + A20.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Actirob B + S 1 + A20.2, Natrium-di(2- ethylhexy l)su fosuccinat + Solvesso + S 1 + 21.2, Natrium-di(2- ethylhexyll))su Ifosuccinat + Bayol + S1-1 + A21.2, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1- + A21.2, Natrium-di(2- ethylhexyl l)su Ifosuccinat + Actirob B + S -1 + A21.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Solvesso + S -1 + A22.2, Natrium-di(2- ethylhexy l)su fosuccinat + Bayol + S1-1 + A22.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Edenor + S1- + A22.2, Natrium-di(2- ethylhexyl l)su Ifosuccinat + Actirob B + S 1 + A22.2, Natrium-di(2- ethylhexy l)su ifosuccinat + Solvesso + S 1 + A23.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Bayol + S1-1 + A23.2, Natrium-di(2- ethylhexy )su fosuccinat + Edenor + S1- 1 + A23.2, Natrium-di(2- ethylhexyl) su fosuccinat + Actirob B + S 1-1 + A23.2, Natrium-di(2- ethylhexyl) su fosuccinat + Solvesso + S 1-1 + A24.2, Natrium-di(2- ethylhexy )su fosuccinat + Bayol + S1-1 + A24.2, Natrium-di(2- ethylhexyl) su fosuccinat + Edenor + S1- 1 + A24.2, Natrium-di(2- ethylhexyl) su fosuccinat + Actirob B + S 1-1 + A24.2, Natrium-di(2- ethylhexy )su fosuccinat + Solvesso + S 1-1 + A25.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Bayol + S1-1 + A25.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Edenor + S1- 1 + A25.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Actirob B + S 1-1 + A25.2, Natrium-di(2- ethylhexyl )su fosuccinat + Solvesso + S 1-1 + A26.2, Natrium-di(2- ethylhexy )su fosuccinat + Bayol + S1-1 + A26.2, Natrium-di(2- ethylhexyl )su fosuccinat + Edenor + S1- 1 + A26.2, Natrium-di(2- ethylhexyl) su fosuccinat + Actirob B + S 1-1 + A26.2, Natrium-di(2- ethylhexy )su fosuccinat + Solvesso + S 1-1 + A27.2, Natrium-di(2- ethylhexy )su ifosuccinat + Bayol + S1-1 + A27.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Edenor + S1- 1 + A27.2, Natrium-di(2- ethylhexyl) SU Ifosuccinat + Actirob B + S 1-1 + A27.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Solvesso + S 1-1 + A28.2, Natrium-di(2- ethylhexy )su fosuccinat + Bayol + S1-1 + A28.2, Natrium-di(2- ethylhexy )su [fosuccinat + Edenor + S1- 1 + A28.2, Natrium-di(2- ethylhexyl) SU fosuccinat + Actirob B + S 1-1 + A28.2, Natrium-di(2- ethylhexy )su fosuccinat + Solvesso + S 1-1 + A29.2, Natrium-di(2- ethylhexy )su fosuccinat + Bayol + S1-1 + A29.2, Natrium-di(2- ethylhexy )su fosuccinat + Edenor + S1- 1 + A29.2, Natrium-di(2- ethylhexy )su fosuccinat + Actirob B + S 1-1 + A29.2, Natrium-di(2- ethylhexy )su fosuccinat + Solvesso + S 1-1 + A30.2, Natrium-di(2- ethylhexyl) SU Ifosuccinat + Bayol + S1-1 + A30.2, Natrium-di(2- ethylhexyl )su fosuccinat + Edenor + S1- 1 + A30.2, Natrium-di(2- ethylhexyl )su fosuccinat + Actirob B + S 1-1 + A30.2, Natrium-di(2- ethylhexyl) SU fosuccinat + Solvesso + S 1-1 + A31.2, Natrium-di(2- ethylhexyl )su fosuccinat + Bayol + S1-1 + A31.2, Natrium-di(2- ethylhexyl)su [fosuccinat + Edenor + S1- 1 + A31.2, Natrium-di(2- ethylhexyl)su fosuccinat + Actirob B + S 1-1 + A31.2, Natrium-di(2- ethylhexyl)su fosuccinat + Solvesso + S 1-1 + A32.2, Natrium-di(2- ethylhexyl)su fosuccinat + Bayol + S1-1 + A32.2, Natrium-di(2- ethylhexyl)su fosuccinat + Edenor + S1- 1 + A32.2, Natrium-di(2- ethylhexyl)su fosuccinat + Actirob B + S 1-1 + A32.2, Natrium-di(2- ethylhexyl)su fosuccinat + Solvesso + S 1-1 + A33.2, Natrium-di(2- ethylhexyl)su fosuccinat + Bayol + S1-1 + A33.2, Natrium-di(2- ethylhexyl)su fosuccinat + Edenor + S1- 1 + A33.2, Natrium-di(2- ethylhexyl)su fosuccinat + Actirob B + S 1-1 + A33.2, Natrium-di(2- ethylhexyl)su fosuccinat + Solvesso + S 1-1 + A34.2, Natrium-di(2- ethylhexyl)su fosuccinat + Bayol + S1-1 + A34.2, Natrium-di(2- ethylhexyl)su [fosuccinat + Edenor + S1 1 + A34.2, Natrium-di(2- ethylhexyl)su fosuccinat + Actirob B + S 1-1 + A34.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S 1-1 + A35.2, Natrium-di(2- ethylhexyl)su [fosuccinat + Bayol + S1-1 + A35.2, Natrium-di(2- ethylhexyl)su fosuccinat + Edenor + S1- 1 + A35.2, Natrium-di(2- ethylhexyl)su fosuccinat + Actirob B + S 1-1 + A35.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S 1-1 + A36.2, Natrium-di(2- ethylhexyl)su fosuccinat + Bayol + S1-1 + A36.2, Natrium-di(2- ethylhexyl)su fosuccinat + Edenor + S1- 1 + A36.2, Natrium-di(2- ethylhexyl)su fosuccinat + Actirob B + S 1-1 + A36.2, Natrium-di(2- ethylhexyl)su fosuccinat + Solvesso + S 1-1 + A37.2, Natrium-di(2- ethylhexyl)su fosuccinat + Bayol + S1-1 + A37.2, Natrium-di(2- ethylhexyl)su fosuccinat + Edenor + S1 1 + A37.2, Natrium-di(2- ethylhexyl)su fosuccinat + Actirob B + S 1-1 + A37.2.Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A2.2 , Sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A3. 2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A3.2, sodium di (2-ethylhexyl ) sulfosuccinate + Solvesso + S1-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A4 .2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S 1-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A6 .2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A6.2, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A7.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1- 1 + A8.2, sodium di (2-ethylhexyl) su! Fosuccinate + Actirob B + S1-1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A9.2, sodium -di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + actirob B + S1-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A10.2, Sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A10 .2, Sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A11.2, sodium di (2- ethylhexyl) sulfosuccinate + Bayol + S1-1 + A11.2, Nauϊum-di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A12.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Edenor + S1-1 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1- 1 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-1 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-1 + A13.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1 -1 + A14.2, sodium di (2-ethylh exyl) sulfosuccinate + Edenor + S1-1 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-1 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-1 + A15.2, sodium di (2-ethylhexyl sulfosuccinate + Bayol + S1-1 + A15.2, sodium di (2- ethylhexy 1 l) su ifosuccinate + Edenor + S1- + A15.2, sodium di (2-ethylhexyll)) su fosuccinate + Actirob B + S -1 + A15.2, sodium di (2-ethylhexy l) su fosuccinate + Solvesso + S -1 + A16.2, sodium di (2-ethylhexyll)) su fosuccinate + Bayol + S1-1 - A16.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- + A16.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S -1 + A16.2, sodium di (2-ethylhexyl l) su ifosuccinate + Solvesso + S -1 + A17.2, sodium -di (2-ethylhexyl) su fosuccinate + Bayol + S1-1 + A17.2, sodium di (2-ethylhexyl l) su fosuccinate + Edenor + S1- + A17.2, sodium di (2-ethylhexy l ) su fosuccinate + Actirob B + S -1 + A17.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S -1 + A18.2, sodium di (2-ethylhexyl) su fosuccinate + bayol + S1-1 + A18.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1- + A18.2, sodium di (2-ethylhexyl l) su ifosuccinate + actirob B + S -1 + A18 .2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S -1 + A19.2, sodium di (2- et hylhexy tysu 1 [fosuccinate + Bayol + S1-1 + A19.2, natrium di (2-ethylhexyl l) su fosuccinate + Edenor + S1- + A19.2, sodium di (2-ethylhexyl l) su fosuccinate + actirob B + S 1 + A19.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S 1 + A20.2, sodium di (2-ethylhexyl l) su fosuccinate + Bayol + S1-1 A20.2 , Sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- + A20.2, sodium di (2-ethylhexyl l) su fosuccinate + Actirob B + S 1 + A20.2, sodium di (2- ethylhexy l) su fosuccinate + Solvesso + S 1 + 21.2, sodium di (2-ethylhexyll)) su ifosuccinate + Bayol + S1-1 + A21.2, sodium di (2-ethylhexy l) su fosuccinate + Edenor + S1 - + A21.2, sodium di (2-ethylhexyl l) su ifosuccinate + Actirob B + S -1 + A21.2, sodium di (2-ethylhexyl l) su fosuccinate + Solvesso + S -1 + A22.2 , Sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1-1 + A22.2, sodium di (2-ethylhexyl l) su ifosuccinate + Edenor + S1- + A22.2, sodium di (2- ethylhexyl l) su ifosuccinate + Actirob B + S 1 + A22.2, sodium di (2-ethylhexy l) su ifosuccinate + Solvesso + S 1 + A23.2, sodium di (2-ethylhexyl l) su fosuccinate + Bayol + S1-1 + A23.2, sodium di (2- ethylhexy) su fosuccinate + Edenor + S1- 1 + A23.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A23.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S 1-1 + A24.2, sodium di (2-ethylhexy) su fosuccinate + Bayol + S1-1 + A24.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- 1 + A24. 2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A24.2, sodium di (2-ethylhexy) su fosuccinate + Solvesso + S 1-1 + A25.2, sodium di (2-ethylhexy) su ifosuccinate + Bayol + S1-1 + A25.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1- 1 + A25.2, sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S 1-1 + A25.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S 1-1 + A26.2, sodium di (2-ethylhexy) su fosuccinate + Bayol + S1-1 + A26.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- 1 + A26.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A26.2, sodium -di (2-ethylhexy) su fosuccinat + Solvesso + S 1-1 + A27.2, sodium di (2- ethylhexy) su ifosuccinate + Bayol + S1-1 + A27.2, sodium di (2-ethylhexy) su ifosuccinate + Edenor + S1- 1 + A27.2, sodium di (2-ethylhexyl) SU ifosuccinate + Actirob B + S 1-1 + A27.2, sodium di (2-ethylhexy) su ifosuccinate + Solvesso + S 1-1 + A28.2, sodium di (2-ethylhexy) su fosuccinate + Bayol + S1-1 + A28. 2, sodium di (2-ethylhexy) su [fosuccinate + Edenor + S1- 1 + A28.2, sodium di (2-ethylhexyl) SU fosuccinate + Actirob B + S 1-1 + A28.2, sodium di (2-ethylhexy) su fosuccinate + Solvesso + S 1-1 + A29.2, sodium di (2-ethylhexy) su fosuccinate + Bayol + S1-1 + A29.2, sodium di (2-ethylhexy) su fosuccinate + Edenor + S1- 1 + A29.2, sodium di (2-ethylhexy) su fosuccinate + Actirob B + S 1-1 + A29.2, sodium di (2-ethylhexy) su fosuccinate + Solvesso + S 1- 1 + A30.2, sodium di (2-ethylhexyl) SU ifosuccinate + Bayol + S1-1 + A30.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- 1 + A30.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A30.2, sodium di (2-ethyl lhexyl) SU fosuccinate + Solvesso + S 1-1 + A31.2, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1-1 + A31.2, sodium di (2- ethylhexyl) su [fosuccinate + Edenor + S1-1 + A31.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A31.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S 1-1 + A32.2, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1-1 + A32.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- 1 + A32 .2, Sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A32.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S 1-1 + A33.2, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1-1 + A33.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- 1 + A33.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A33.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S 1-1 + A34.2, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1- 1 + A34.2, sodium di (2-ethylhexyl) su [fosuccinate + Edenor + S1 1 + A34.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A34.2, Sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S 1-1 + A35.2, sodium di (2-ethylhexy l) su [fosuccinate + Bayol + S1-1 + A35.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- 1 + A35.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A35.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S 1-1 + A36.2, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1-1 + A36 .2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1- 1 + A36.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A36.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S 1-1 + A37.2, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1-1 + A37.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1 1 + A37.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S 1-1 + A37.2.
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A1.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A1.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A1.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A1.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A2.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A2.1, Natrium-di(2-ethylhexyl)suIfosuccinat + Actirob B + S1-6 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A3.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A3.1, Natrium-di(2-ethylhexy.)sulfosuccinat + Edenor + S1-6 + A3.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A4.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A4.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A4.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A4.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A5.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A5.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A5.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A5.1 , Natrium-di(2-ethylhexyl)suifosuccinat + Solvesso + S1-6 + A6.1 + EX, Natrium- di(2-ethylhexyl)sulfosuccinat + Bayol + S1-6 + A6.1 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S1-6 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A6.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S1-6 + A6.1 , Natrium- di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A6.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A6.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A7.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A7.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A8.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A8.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A9.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A9.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A10.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A11.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A11.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Edenor + S1-6 + A11.1 , Natrium-di(2- ethylhexyl )sulfosuccinat + Actirob B + S1-6 + A11.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Solvesso + S1-6 + A12.1 , Natrium-di(2- ethylhexyl )sulfosuccinat + Bayol + S1-6 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-6 + A12.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A12.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A13.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A13.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A13.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A13.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A14.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A14.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A14.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A14.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A15.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A15.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A15.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A15.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A16.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A16.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A16.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A16.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A17.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A17.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A17.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A17.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A18.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A18.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A18.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A18.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A19.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A19.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A19.1 , Natrium-di(2- ethylhexyI)sulfosuccinat + Actirob B + S1-6 + A19.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A20.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A20.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A20.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A20.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + 21.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A21.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A21.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A21.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A22.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A22.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A22.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A22.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A23.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A23.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A23.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A23.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A24.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A24.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A24.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A24.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A25.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A25.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A25.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A25.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A26.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A26.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A26.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A26.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A27.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A27.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-6 + A27.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-6 + A27.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-6 + A28.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-6 + A28.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-6 + A28.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-6 + A28.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-6 + A29.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-6 + A29.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-6 + A29.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-6 + A29.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-6 + A30.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-6 + A30.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-6 + A30.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-6 + A30.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-6 + A31.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-6 + A31.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-6 + A31.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-6 + A31.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-6 + A32.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-6 + A32.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-6 + A32.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-6 + A32.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-6 + A33.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-6 + A33.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-6 + A33.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-6 + A33.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-6 + A34.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-6 + A34.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-6 + A34.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-6 + A34.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-6 + A35.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-6 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A37.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A37.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A37.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A37.1.Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A2.1 , Sodium di (2-ethylhexyl) sulfosuccinate + bayol + S1-6 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A2.1, sodium di (2-ethylhexyl) suIfosuccinate + Actirob B + S1-6 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A3. 1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A3.1, sodium di (2-ethylhexy.) Sulfosuccinate + Edenor + S1-6 + A3.1, sodium di (2-ethylhexyl ) sulfosuccinate + Actirob B + S1-6 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A4.1, sodium di (2nd -ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A5.1, sodium di (2-ethylhexyl) suifosuccinate + Solvesso + S1-6 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A6.1 + EX, sodium di (2-ethylhexyl ) sulfosuccinate + Solvesso + S1-6 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A6 .1, Sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A7.1, sodium di (2- ethylhexyl) sulfosuccinate + Bayol + S1-6 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A8.1, sodium di (2nd -ethylhexyl) sulfosuccinate + Edenor + S1-6 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1- 6 + A9.1, sodium di (2-ethylhexyl) sulfosuccin at + Bayol + S1-6 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A9 .1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A10.1, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S1-6 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A11.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A11.1, sodium di (2- ethylhexy) sulfosuccinate + Edenor + S1-6 + A11.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A11.1, sodium di (2-ethylhexy) sulfosuccinate + Solvesso + S1-6 + A12.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-6 + A12.1, sodium di ( 2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A12.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A13.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1 -6 + A13.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A13.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A13.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A14.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A14.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A14.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A14.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A15.1, sodium -di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A15.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A15.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A15 .1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A16.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A16.1, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S1-6 + A16.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A16.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A17.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A17.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A17.1, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A17.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A18.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A18.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A18.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A18.1, sodium di ( 2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A19.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A19.1, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S1-6 + A19.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A19.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A20.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A20.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A20.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A20.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + 21.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A21.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A21.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A21.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A22.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A22.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A22.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A22.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A23.1, sodium di ( 2-ethylhexyl) s sulfosuccinate + Bayol + S1-6 + A23.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A23.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A23 .1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A24.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A24.1, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S1-6 + A24.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A24.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A25.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A25.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A25.1, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A25.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A26.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A26.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A26.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A26.1, sodium di ( 2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A27.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A27.1, sodium di (2- ethylhexyl) su ifosuccinate + Edenor + S1-6 + A27.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-6 + A27.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-6 + A28.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-6 + A28.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-6 + A28.1, Sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-6 + A28.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-6 + A29.1, sodium di (2-ethylhexyl ) su ifosuccinate + Bayol + S1-6 + A29.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-6 + A29.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1 -6 + A29.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-6 + A30.1, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S1-6 + A30.1, sodium -di (2-ethylhexyl) su ifosuccinate + Edenor + S1-6 + A30.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-6 + A30.1, sodium di (2-ethylhexyl) see below ifosuccinate + Solvesso + S1-6 + A31.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-6 + A31.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-6 + A31.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-6 + A31.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-6 + A32.1, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S1-6 + A32 .1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-6 + A32.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-6 + A32.1, sodium di ( 2-ethylhexyl) su ifosuccinate + Solvesso + S1-6 + A33.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-6 + A33.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-6 + A33.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-6 + A33.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-6 + A34. 1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-6 + A34.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-6 + A34.1, sodium di (2- ethylhexyl) su ifosuccinate + actirob B + S1-6 + A34.1, natriu m-di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-6 + A35.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-6 + A35.1, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S1-6 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A36.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1- 6 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A37.1.
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A1.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A2.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A3.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A4.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A5.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A6.2 + EX, Natrium- di(2-ethylhexyl)sulfosuccinat + Bayol + S1-6 + A6.2 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S1-6 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A6.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S1-6 + A6.2, Natrium- di(2-ethylhexyi)sulfosuccinat + Edenor + S1-6 + A6.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A6.2, Natrium-di(2- ethy!hexyl)sulfosuccinat + Solvesso + S1-6 + A7.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A8.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A9.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-6 + A9.2, Natrium-di(2-ethyIhexyl)sulfosuccinat + Actirob B + S1-6 + A9.2, Natrium-di(2-ethylhexyl)suifosuccinat + Solvesso + S1-6 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A14.2, Natrium-di(2- ethylhexyl)su!fosuccinat + Actirob B + S1-6 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A15.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Edenor + S1-6 + A15.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Actirob B + S1-6 + A15.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Solvesso + S1-6 + A16.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Bayol + S1-6 + A16.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Edenor + S1-6 + A16.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Actirob B + S1-6 + A16.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Solvesso + S1-6 + A17.2, Natrium-di(2- ethylhexyl) su Ifosuccinat + Bayol + S1-6 + A17.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Edenor + S1-6 + A17.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Actirob B + S1-6 + A17.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Solvesso + S1-6 + A18.2, Natrium-di(2- ethylhexy !)SU Ifosuccinat + Bayol + S1-6 + A18.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Edenor + S1-6 + A18.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Actirob B + S1-6 + A18.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Solvesso + S1-6 + A19.2, Natrium-di(2- ethylhexy )su [fosuccinat + Bayol + S1-6 + A19.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Edenor + S1-6 + A19.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Actirob B + S1-6 + A19.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Solvesso + S1-6 + A20.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Bayol + S1-6 + A20.2, Natrium-di(2- ethylhexyl) SU Ifosuccinat + Edenor + S1-6 + A20.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Actirob B + S1-6 + A20.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Solvesso + S1-6 + 21.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Bayol + S1-6 + A21.2, Natrium-di(2- ethylhexy1 )su Ifosuccinat + Edenor + S1-6 + A21.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Actirob B + S1-6 + A21.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Solvesso + S1-6 + A22.2, Natrium-di(2- ethylhexyl) su Ifosuccinat + Bayol + S1-6 + A22.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Edenor + S1-6 + A22.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Actirob B + S1-6 + A22.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Solvesso + S1-6 + A23.2, Natrium-di(2- ethylhexyl) SU Ifosuccinat + Bayol + S1-6 + A23.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A23.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A23.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A24.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A24.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A24.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A24.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A25.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A25.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A25.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A25.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A26.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A26.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A26.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A26.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A27.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A27.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A27.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A27.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A28.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A28.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A28.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A28.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A29.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A29.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A29.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A29.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A30.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A30.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-6 + A30.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-6 + A30.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-6 + A31.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-6 + A31.2, Natrium-di(2- ethylhexyl )sulfosuccina + Edenor + S1 -6 + A31.2, Natrium-di(2- ethylhexyl )sulfosuccina + Actirob B + S1-6 + A312, Natrium-di(2- ethylhexyl)sulfosuccina + Solvesso + S1-6 + A32.2, Natrium-di(2- ethylhexyl)sulfosuccina + Bayol + S1-6 + A32.2, Natrium-di(2- ethylhexyl )sulfosuccina + Edenor + S1-6 + A32.2, Natrium-di(2- ethylhexy )sulfosuccina + Actirob B + S1-6 + A32.2, Natrium-di(2- ethylhexy )sulfosuccina + Solvesso + S1-6 + A33.2, Natrium-di(2- ethylhexy )sulfosuccina + Bayol + S1-6 + A33.2, Natrium-di(2- ethylhexyl )sulfosuccina + Edenor + S1-6 + A33.2, Natrium-di(2- ethylhexy )sulfosuccina + Actirob B + S1-6 + A33.2, Natrium-di(2- ethylhexy )sulfosuccina + Solvesso + S1-6 + A34.2, Natrium-di(2- ethylhexy )sulfosuccina + Bayol + S1-6 + A34.2, Natrium-di(2- ethylhexy )sulfosuccina + Edenor + S1-6 + A34.2, Natrium-di(2- ethylhexy! )sulfosuccina + Actirob B + S1-6 + A34.2, Natrium-di(2- ethylhexy )sulfosuccina + Solvesso + S1-6 + A35.2, Natrium-di(2- ethylhexy )sulfosuccina + Bayol + S1-6 + A35.2, Natrium-di(2- ethylhexyl )sulfosuccina + Edenor + S1-6 + A35.2, Natrium-di(2- ethylhexyl)sulfosuccina + Actirob B + S1-6 + A35.2, Natrium-di(2- ethylhexyl)sulfosuccina + Solvesso + S1-6 + A36.2, Natrium-di(2- ethylhexy )sulfosuccina + Bayol + S1-6 + A36.2, Natrium-di(2- ethylhexyl )sulfosuccina + Edenor + S1-6 + A36.2, Natrium-di(2- ethylhexyl)sulfosuccina + Actirob B + S1-6 + A36.2, Natrium-di(2- ethylhexy )sulfosuccina + Solvesso + S1-6 + A37.2, Natrium-di(2- ethylhexyl )sulfosuccina + Bayol + S1-6 + A37.2, Natrium-di(2- ethylhexyl)sulfosuccina + Edenor + S1 -6 + A37.2, Natrium-di(2- ethylhexy )sulfosuccina + Actirob B + S1 -6 + A37.2.Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A2.2 , Sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A3. 2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A3.2, sodium di (2-ethylhexyl ) sulfosuccinate + Solvesso + S1-6 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A4 .2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S 1-6 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A6 .2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A6.2, sodium di (2-ethylhexyi) sulfosuccinate + Edenor + S1-6 + A6.2, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A6.2, sodium di (2-ethy! hexyl) sulfosuccinate + Solvesso + S1-6 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1 -6 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A9.2, sodium -di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + actirob B + S1-6 + A9.2, sodium di (2-ethylhexyl) suifosuccinate + Solvesso + S1-6 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A10.2, Sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A10 .2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A11.2, sodium di (2- ethylhexyl) sulfosuccinate + Bayol + S1-6 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A12.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Edenor + S1-6 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1- 6 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A13.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1 -6 + A14.2, sodium di (2-ethylh exyl) sulfosuccinate + Edenor + S1-6 + A14.2, sodium di (2-ethylhexyl) su! fosuccinate + Actirob B + S1-6 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1 -6 + A15.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A15.2, sodium di (2- ethylhexyl) su ifosuccinate + Edenor + S1-6 + A15.2, sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S1-6 + A15.2, sodium di (2-ethylhexy) su ifosuccinate + Solvesso + S1-6 + A16.2, sodium di (2-ethylhexy) su ifosuccinate + Bayol + S1-6 + A16.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-6 + A16.2, Sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-6 + A16.2, sodium di (2-ethylhexy) su ifosuccinate + Solvesso + S1-6 + A17.2, sodium di (2-ethylhexyl ) See below ifosuccinate + Bayol + S1-6 + A17.2, sodium di (2-ethylhexyl) See below ifosuccinate + Edenor + S1-6 + A17.2, sodium di (2-ethylhexyl) below Ifosuccinate + Actirob B + S1 -6 + A17.2, sodium di (2-ethylhexy) su ifosuccinate + Solvesso + S1-6 + A18.2, sodium di (2-ethylhexy!) SU ifosuccinate + bayol + S1-6 + A18.2, Sodium di (2-ethylhexy) su ifosuccinate + Edenor + S1-6 + A18.2, sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S1-6 + A18.2, sodium di (2-ethylhexy ) see below ifosuccinate + Solvesso + S1-6 + A19.2, sodium di (2- e thylhexy) su [fosuccinate + Bayol + S1-6 + A19.2, sodium di (2-ethylhexy) su ifosuccinate + Edenor + S1-6 + A19.2, sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S1-6 + A19.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-6 + A20.2, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S1-6 + A20.2 , Sodium di (2-ethylhexyl) SU ifosuccinate + Edenor + S1-6 + A20.2, sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S1-6 + A20.2, sodium di (2- ethylhexy) su ifosuccinate + Solvesso + S1-6 + 21.2, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-6 + A21.2, sodium di (2-ethylhexy 1 ) su ifosuccinate + Edenor + S1- 6 + A21.2, sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S1-6 + A21.2, sodium di (2-ethylhexy) su ifosuccinate + Solvesso + S1-6 + A22.2, sodium -di (2-ethylhexyl) su ifosuccinate + Bayol + S1-6 + A22.2, sodium di (2-ethylhexy) su ifosuccinate + Edenor + S1-6 + A22.2, sodium di (2-ethylhexyl) su Ifosuccinate + actirob B + S1-6 + A22.2, sodium di (2-ethyl hexy) su ifosuccinate + Solvesso + S1-6 + A23.2, sodium di (2-ethylhexyl) SU ifosuccinate + Bayol + S1-6 + A23.2, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S1-6 + A23.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A23.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A24.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A24.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A24.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A24.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A25.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1- 6 + A25.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A25.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A25.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A26.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A26.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1 -6 + A26.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A26.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A27.2, sodium di (2-ethylhexyl) sulfosuccina t + Bayol + S1-6 + A27.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A27.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A27 .2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A28.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A28.2, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S1-6 + A28.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A28.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A29.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A29.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A29.2, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A29.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A30.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A30.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-6 + A30.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-6 + A30.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Solvesso + S1-6 + A31. 2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-6 + A31.2, sodium di (2- ethylhexyl) sulfosuccina + Edenor + S1 -6 + A31.2, sodium di (2-ethylhexyl) sulfosuccina + Actirob B + S1-6 + A312, sodium di (2-ethylhexyl) sulfosuccina + Solvesso + S1-6 + A32 .2, sodium di (2-ethylhexyl) sulfosuccina + Bayol + S1-6 + A32.2, sodium di (2-ethylhexyl) sulfosuccina + Edenor + S1-6 + A32.2, sodium di (2-ethylhexy ) sulfosuccina + Actirob B + S1-6 + A32.2, sodium di (2-ethylhexy) sulfosuccina + Solvesso + S1-6 + A33.2, sodium di (2-ethylhexy) sulfosuccina + Bayol + S1-6 + A33.2, sodium di (2-ethylhexyl) sulfosuccina + Edenor + S1-6 + A33.2, sodium di (2-ethylhexy) sulfosuccina + Actirob B + S1-6 + A33.2, sodium di (2 - ethylhexy) sulfosuccina + Solvesso + S1-6 + A34.2, sodium di (2-ethylhexy) sulfosuccina + Bayol + S1-6 + A34.2, sodium di (2-ethylhexy) sulfosuccina + Edenor + S1-6 + A34.2, sodium di (2-ethylhexy!) Sulfosuccina + Actirob B + S1-6 + A34.2, sodium di (2-ethylhexy) sulfosuccina + Solvesso + S1-6 + A35.2, sodium di (2-ethylhexy) sulfosuccina + Bayol + S1-6 + A35.2, sodium di (2-ethylhexyl) sulfosuccina + Edenor + S1-6 + A35.2, sodium di (2-ethylhexyl) sulfosuccina + Actirob B + S1-6 + A35.2, sodium -di (2-ethylhexyl) sulfosuccina + Solvesso + S1-6 + A36.2, sodium di (2-ethylhexy) sulfosuccina + Bayol + S1-6 + A36.2, sodium di (2-ethylhexyl) sulfosuccina + Edenor + S1-6 + A36.2, sodium di (2-ethylhexyl) sulfosuccina + Actirob B + S1-6 + A36.2, sodium di (2-ethylhexy) sulfosuccina + Solvesso + S1-6 + A37.2, Sodium di (2-ethylhexyl) sulfosuccina + Bayol + S1-6 + A37.2, sodium di (2-ethylhexyl) sulfosuccina + Edenor + S1 -6 + A37.2, sodium di (2-ethylhexy) sulfosuccina + Actirob B + S1 -6 + A37.2.
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A1.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A1.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + AU , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + AU , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A2.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A2.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A3.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A3.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A4.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A4.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A4.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A4.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A5.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A5.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A5.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A5.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A6.1 + EX, Natrium- di(2-ethylhexyl)sulfosuccinat + Bayol + S1-9 + A6.1 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S1-9 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A6.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S1-9 + A6.1 , Natrium- di(2-ethylhexyl)sulfosuccinat + Edenor + S1 -9 + A6.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A6.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A7.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A8.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A8.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A8.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A9.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A9.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A11.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A11.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-9 + A11.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-9 + A111 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-9 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-9 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-9 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-9 + A13.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A13.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-9 + A13.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-9 + A13.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-9 + A14.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-9 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-9 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-9 + A15.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A 5.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-9 + A15.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-9 + A15.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-9 + A16.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A16.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-9 + A16.1 , Natrium-di(2- ethylhexyl)su lfosuccinat + Actirob B + S1-9 + A16.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-9 + A17.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A17.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S1-9 + A17.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-9 + A17.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-9 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A18.1 , Natrium-di(2- ethyl hexyl)su Ifosuccinat + Edenor + S1-9 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S1-9 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S1-9 + A19.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A19.1 , Natrium-di(2- ethylhexy Ifosuccinat + Edenor + S1-9 + A19.1 , Natrium-di(2- ethylhexyl Ifosuccinat + Actirob B + S1-9 + A19.1 , Natrium-di(2- ethylhexy Ifosuccinat + Solvesso + S1-9 + A20.1 , Natrium-di(2- ethylhexy Ifosuccinat + Bayol + S1-9 + A20.1 , Natrium-di(2- ethylhexy Ifosuccinat + Edenor + S1-9 + A20.1 , Natrium-di(2- ethylhexy Ifosuccinat + Actirob B + S1-9 + A20.1 , Natrium-di(2- ethylhexy Ifosuccinat + Solvesso + S1-9 + 21.1 , Natrium-di(2- ethylhexyl Ifosuccinat + Bayol + S1-9 + A21.1 , Natrium-di(2- ethylhexy Ifosuccinat + Edenor + S1-9 + A21.1 , Natrium-di(2- ethylhexy1 Ifosuccinat + Actirob B + S1-9 + A21.1 , Natrium-di(2- ethylhexy Ifosuccinat + Solvesso + S1-9 + A22.1 , Natrium-di(2- ethylhexyl ilfosuccinat + Bayol + S1-9 + A22.1 , Natrium-di(2- ethylhexy Ifosuccinat + Edenor + S1-9 + A22.1 , Natrium-di(2- ethylhexyl ilfosuccinat + Actirob B + S1-9 + A22.1 , Natrium-di(2- ethylhexyl ilfosuccinat + Solvesso + S1-9 + A23.1, Natrium-di(2- ethylhexy ilfosuccinat + Bayol + S1-9 + A23.1 , Natήum-d-(2- ethylhexy ilfosuccinat + Edenor + S1-9 + A23.1, Natrium-di(2- ethylhexy ilfosuccinat + Actirob B + S1-9 + A23.1 , Natrium-di(2- ethylhexy ilfosuccinat + Solvesso + S1-9 + A24.1 , Natrium-di(2- ethylhexy ilfosuccinat + Bayol + S1-9 + A24.1 , Natrium-di(2- ethylhexy ilfosuccinat + Edenor + S1-9 + A24.1 , Natrium-di(2- ethylhexyl ilfosuccinat + Actirob B + S1-9 + A24.1 , Natrium-di(2- ethylhexyl ilfosuccinat + Solvesso + S1-9 + A25.1 , Natrium-di(2- ethylhexy ilfosuccinat + Bayol + S1-9 + A25.1 , Natrium-di(2- ethylhexyl ilfosuccinat + Edenor + S1-9 + A25.1, Natrium-di(2- ethylhexyl ilfosuccinat + Actirob B + S1-9 + A25.1 , Natrium-di(2- ethylhexy ilfosuccinat + Solvesso + S1-9 + A26.1 , Natrium-di(2- ethylhexyl ilfosuccinat + Bayol + S1-9 + A26.1 , Natrium-di(2- ethylhexyl) ilfosuccinat + Edenor + S1-9 + A26.1, Natrium-di(2- ethylhexyl) ilfosuccinat + Actirob B + S1-9 + A26.1, Natrium-di(2- ethylh. ilfosuccinat + Solvesso + S1-9 + A27.1 , Natrium-di(2- eth lhexyi )sulfosuccinat + Bayol + S1-9 + A27.1, Natrium-di(2- ethylhexyl l)su Ifosuccinat + Edenor + S1-9 + A27.1 , Natrium-di(2- ethylhexyll))su Ifosuccinat + Actirob B + S1-9 + A27.1 , Natrium-di ethylhexyl l)su Ifosuccinat + Solvesso + S1-9 + A28.1 , Natrium-di 2- ethylhexy l)su [fosuccinat + Bayol + S1-9 + A28.1 , Natrium-di(2- ethylhexy l)su Ifosuccinat + Edenor + S1-9 + A28.1 , Natrium-di(2 ethylhexyl l)su Ifosuccinat + Actirob B + S1-9 + A28.1 , Natrium-di ethylhexy l)su Ifosuccinat + Solvesso + S1-9 + A29.1 , Natrium-di ethylhexyl l)su Ifosuccinat + Bayol + S1-9 + A29.1 , Natrium-di(2- ethylhexyl l)su Ifosuccinat + Edenor + S1-9 + A29.1 , Natrium-di(2 ethylhexy l)su Ifosuccinat + Actirob B + S1-9 + A29.1, Natrium-di ethylhexy l)su Ifosuccinat + Solvesso + S1-9 + A30.1, Natrium-di ethylhexyl l)su Ifosuccinat + Bayol + S1-9 + A30.1 , Natrium-di(2- ethylhexyl l)su Ifosuccinat + Edenor + S1-9 + A30.1, Natrium-di(2 ethylhexyl l)su Ifosuccinat + Actirob B + S1-9 + A30.1, Natrium-di ethylhexyl l)su Ifosuccinat + Solvesso + S1-9 + A31.1, Natrium-di ethylhexy l)su Ifosuccinat + Bayol + S1-9 + A31.1 , Natriυm-di(2- ethylhexyl l)su Ifosuccinat + Edenor + S1-9 + A31.1, Natrium-di(2 ethylhexyl l)su [fosuccinat + Actirob B + S1-9 + A31.1, Natrium-di ethylhexyl l)su Ifosuccinat + Solvesso + S1-9 + A32.1 , Natrium-di ethylhexy l)su Ifosuccinat + Bayol + S1-9 + A32.1 , Natrium-di(2- ethylhexy l)su Ifosuccinat + Edenor + S1-9 + A32.1 , Natrium-di(2 ethylhexy l)su Ifosuccinat + Actirob B + S1-9 + A32.1 , Natrium-di ethylhexy l)su Ifosuccinat + Solvesso + S1-9 + A33.1 , Natrium-di ethylhexy l)su Ifosuccinat + Bayol + S1-9 + A33.1 , Natrium-di(2- ethylhexyll))su Ifosuccinat + Edenor + S1-9 + A33.1 , Natrium-di(2 ethylhexy l)su Ifosuccinat + Actirob B + S1-9 + A33.1, Natrium-di ethylhexyl l)su Ifosuccinat + Solvesso + S1-9 + A34.1 , Natrium-di ethylhexy l)su Ifosuccinat + Bayol + S1-9 + A34.1 , Natrium-di(2- ethylhexy l)su Ifosuccinat + Edenor + S1-9 + A34.1 , Natrium-di(2 ethylhexyl l)su Ifosuccinat + Actirob B + S1-9 + A34.1 , Natrium-di ethylhexyll))su Ifosuccinat + Solvesso + S1-9 + A35.1 , Natrium-di ethylhexy l)su Ifosuccinat + Bayol + S1-9 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A35.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A37.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A37.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A37.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A37.1Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A1.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + AU, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + AU, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A3. 1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A4 .1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A4.1, sodium di (2- ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A6.1 + EX, sodium -di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A6.1 + EX, sodium di (2- ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1 -9 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A7.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Bayol + S1-9 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1- 9 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A8.1, sodium di ( 2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1 -9 + A9.1, sodium di (2-ethylhexyl) sulfosu ccinat + Bayol + S1-9 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A9 .1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A10.1, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S1-9 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A11.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A11.1, sodium di (2- ethylhexyl) su ifosuccinate + Edenor + S1-9 + A11.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A111, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1- 9 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-9 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-9 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A13.1, sodium di (2-ethylhexyl) su Ifosuccinate + Bayol + S1-9 + A13.1, sodium di (2-ethylhexyl) su Ifosuccinate + Edenor + S1-9 + A13.1, sodium di (2-ethylhexyl) su Ifosuccinate + Actirob B + S1-9 + A13.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A14.1, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S1-9 + A14.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-9 + A14.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A14.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A15.1, sodium d i (2-ethylhexyl) su ifosuccinate + Bayol + S1-9 + A 5.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-9 + A15.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A15.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A16.1, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S1-9 + A16 .1, Sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-9 + A16.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A16.1, sodium di ( 2-ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-9 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-9 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A18. 1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-9 + A18.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-9 + A18.1, sodium di (2 - ethylhexyl) su ifosuccinate + actirob B + S1-9 + A18.1, natriu m-di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A19.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-9 + A19.1, sodium di (2- ethylhexy ifosuccinate + Edenor + S1-9 + A19.1, sodium di (2-ethylhexyl ifosuccinate + Actirob B + S1-9 + A19.1, sodium di (2-ethylhexy ifosuccinate + Solvesso + S1-9 + A20. 1, sodium di (2-ethylhexy ifosuccinate + Bayol + S1-9 + A20.1, sodium di (2-ethylhexy ifosuccinate + Edenor + S1-9 + A20.1, sodium di (2-ethylhexy ifosuccinate + actirob B + S1-9 + A20.1, sodium di (2-ethylhexy ifosuccinate + Solvesso + S1-9 + 21.1, sodium di (2-ethylhexyl ifosuccinate + Bayol + S1-9 + A21.1, sodium di ( 2-ethylhexy ifosuccinate + Edenor + S1-9 + A21.1, sodium di (2-ethylhexy 1 ifosuccinate + Actirob B + S1-9 + A21.1, sodium di (2-ethylhexy ifosuccinate + Solvesso + S1-9 + A22.1, sodium di (2-ethylhexyl ilfosuccinate + Bayol + S1-9 + A22.1, sodium di (2-ethylhexy ifosuccinate + Edenor + S1-9 + A22.1, sodium di (2-ethylhexyl ilfosuccinate + Actirob B + S1-9 + A22.1, sodium di (2-ethylhexyl ilfosuccinate + Solvesso + S1-9 + A23.1, sodium di (2-ethylhexyl ilfosuccinate + Bayol + S1-9 + A23.1 , Natήum-d- (2-ethylhexyl ilfosuccinate + Edenor + S1-9 + A23.1, sodium di (2-ethylhexyl ilfosuccinate + Actirob B + S1-9 + A23.1, sodium di (2-ethylhexyl ilfosuccinate + Solvesso + S1-9 + A24.1, sodium di (2-ethylhexyl ilfosuccinate + Bayol + S1-9 + A24.1, sodium di (2-ethylhexyl ilfosuccinate + Edenor + S1-9 + A24.1, sodium di (2-ethylhexyl ilfosuccinate + Actirob B + S1-9 + A24.1, sodium di (2-ethylhexyl ilfosuccinate + Solvesso + S1-9 + A25.1, sodium di (2-ethylhexyl ilfosuccinate + Bayol + S1- 9 + A25.1, sodium di (2-ethylhexyl ilfosuccinate + Edenor + S1-9 + A25.1, sodium di (2-ethylhexyl ilfosuccinate + Actirob B + S1-9 + A25.1, sodium di (2nd - ethylhexyl ilfosuccinate + Solvesso + S1-9 + A26.1, sodium di (2-ethylhexyl ilfosuccinate + Bayol + S1-9 + A26.1, sodium di (2-ethylhexyl) ilfosuccinate + Edenor + S1-9 + A26 .1, sodium di (2-ethylhexyl) ilfosuccinate + Actirob B + S1-9 + A26.1, sodium di (2-ethylh. ilfosuccinate + Solvesso + S1-9 + A27.1, sodium di (2- eth lhexyi) sulfosuccinate + Bayol + S1-9 + A27.1, sodium di (2- ethylhexyl l) su ifosuccinate + Edenor + S1-9 + A27.1, sodium di (2-ethylhexyll)) su ifosuccinate + Actirob B + S1-9 + A27.1, sodium di ethylhexyl l) su ifosuccinate + Solvesso + S1-9 + A28.1, sodium di (2-ethylhexyl) su [fosuccinate + Bayol + S1-9 + A28.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-9 + A28. 1, sodium di (2 ethylhexyl l) su ifosuccinate + Actirob B + S1-9 + A28.1, sodium di ethylhexy l) su ifosuccinate + Solvesso + S1-9 + A29.1, sodium di ethylhexyl l) su Ifosuccinate + bayol + S1-9 + A29.1, sodium di (2-ethylhexyl l) see ifosuccinate + Edenor + S1-9 + A29.1, sodium di (2 ethylhexy l) see ifosuccinate + Actirob B + S1- 9 + A29.1, sodium di ethylhexyl l) su ifosuccinate + Solvesso + S1-9 + A30.1, sodium di ethylhexyl l) su ifosuccinate + bayol + S1-9 + A30.1, sodium di (2- ethylhexyl l) su ifosuccinate + Edenor + S1-9 + A30.1, sodium di (2 ethylhexyl l) su ifosuccinate + Actirob B + S1-9 + A30.1, sodium di ethylhexyl l) su ifosuccinate + Solvesso + S1 -9 + A31.1, sodium di ethylhexy l) su ifosuccinate + Bayol + S1-9 + A31.1, natrium di (2-ethylhexyl l) su ifosuccinate + Edenor + S1-9 + A31.1, sodium di (2 ethylhexyl l) su [fosuccinate + Actirob B + S1-9 + A31.1, sodium di ethylhexyl l) see ifosuccinate + Solvesso + S1-9 + A32.1, sodium di ethylhexy l) see ifosuccinate + Bayol + S1-9 + A32.1, Sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-9 + A32.1, sodium di (2 ethylhexyl l) su ifosuccinate + Actirob B + S1-9 + A32.1, sodium di ethylhexyl l) see below ifosuccinate + Solvesso + S1-9 + A33.1, sodium di ethylhexyl) see below ifosuccinate + bayol + S1-9 + A33.1, sodium di (2-ethylhexyll)) see below ifosuccinate + Edenor + S1-9 + A33.1, sodium di (2 ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A33.1, sodium di ethylhexyl l) su ifosuccinate + Solvesso + S1-9 + A34.1, sodium di ethylhexyl l ) see below ifosuccinate + Bayol + S1-9 + A34.1, sodium di (2-ethylhexyl) see below ifosuccinate + Edenor + S1-9 + A34.1, sodium di (2 ethylhexyl 1) below ifosuccinate + Actirob B + S1-9 + A34.1, sodium di ethylhexyll)) su ifosuccinate + Solvesso + S1-9 + A35.1, sodium di ethylhexyl l) su ifosuccinate + Bayol + S1-9 + A35.1, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S1-9 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A36.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1- 9 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A37.1
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A1.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A2.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A3.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A4.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A5.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A6.2 + EX, Natrium- di(2-ethylhexyl)sulfosuccinat + Bayol + S1-9 + A6.2 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S1-9 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A6.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S1-9 + A6.2, Natrium- di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A6.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A6.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A7.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A8.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A9.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S1-9 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A10.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Actirob B + S1-9 + A10.2, Natrium-di ethylhexyl )su Ifosuccinat + Solvesso + S1-9 + A11.2, Natrium-di ethylhexy )su Ifosuccinat + Bayol + S1-9 + A11.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Edenor + S1-9 + A11.2, Natrium-di(2 ethylhexyl )su Ifosuccinat + Actirob B + S1-9 + A11.2, Natrium-di 2- ethylhexy )su Ifosuccinat + Solvesso + S1-9 + A12.2, Natrium-di 2- ethylhexyl )su Ifosuccinat + Bayol + S1-9 + A12.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Edenor + S1-9 + A12.2, Natrium-di(2 ethylhexy' )su Ifosuccinat + Actirob B + S1-9 + A12.2, Natrium-di 2- ethylhexy )su Ifosuccinat + Solvesso + S1-9 + A13.2, Natrium-di 2- ethylhexyl )su Ifosuccinat + Bayol + S1-9 + A13.2, Natrium-di(2- ethylhexy] )su Ifosuccinat + Edenor + S1-9 + A13.2, Natrium-di(2 ethylhexy )su Ifosuccinat + Actirob B + S1-9 + A13.2, Natrium-di 2- ethylhexyl )su Ifosuccinat + Solvesso + S1-9 + A14.2, Natrium-di 2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A14.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Edenor + S1-9 + A14.2, Natrium-di(2 ethylhexyl) su Ifosuccinat + Actirob B + S1-9 + A14.2, Natrium-di ethylhexy )su Ifosuccinat + Solvesso + S1-9 + A15.2, Natrium-di ethylhexyl) SU Ifosuccinat + Bayol + S1-9 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + 21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S1-9 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S1-9 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S1-9 + A23.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S1-9 + A23.2, Natrium-di(2- ethylhexyll))su fosuccinat + Edenor + S1-9 + A23.2, Natrium-di(2- ethylhexy l)su [fosuccinat + Actirob B + S1-9 + A23.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Solvesso + S1-9 + A24.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Bayol + S1-9 + A24.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Edenor + S1-9 + A24.2, Natrium-di(2- ethylhexy l)su [fosuccinat + Actirob B + S1-9 + A24.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Solvesso + S1-9 + A25.2, Natrium-di(2- ethylhexy l)su fosuccinat + Bayol + S1-9 + A25.2, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1-9 + A25.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Actirob B + S1-9 + A25.2, Natrium-di(2- ethylhexy l)su fosuccinat + Solvesso + S1-9 + A26.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Bayol + S1-9 + A26.2, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1-9 + A26.2, Natrium-di(2- ethylhexy l)su [fosuccinat + Actirob B + S1-9 + A26.2, Natrium-di(2- ethylhexy l)su fosuccinat + Solvesso + S1-9 + A27.2, Natrium-di(2- ethylhexy1 l)su fosuccinat + Bayol + S1-9 + A27.2, Natrium-di(2- ethylhexy I)su Ifosuccinat + Edenor + S1-9 + A27.2, Natrium-di(2- ethylhexy l)su fosuccinat + Actirob B + S1-9 + A27.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Solvesso + S1-9 + A28.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Bayol + S1-9 + A28.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Edenor + S1-9 + A28.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Actirob B + S1-9 + A28.2, Natrium-di(2- ethylhexy l)su [fosuccinat + Solvesso + S1-9 + A29.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Bayol + S1-9 + A29.2, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1-9 + A29.2, Natrium-di(2- ethylhexy l)su fosuccinat + Actirob B + S1-9 + A29.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Solvesso + S1-9 + A30.2, Natrium-di(2- ethylhexy l)su Ifosuccinat + Bayol + S1-9 + A30.2, Natrium-di(2- ethylhexy l)su fosuccinat + Edenor + S1-9 + A30.2, Natrium-di(2- ethylhexy l)su fosuccinat + Actirob B + S1-9 + A30.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Solvesso + S1-9 + A31.2, Natrium-di(2- ethylhexyl l)su fosuccinat + Bayol + S1-9 + A31.2, Natrium-di(2- ethylhexy )su fosuccinat + Edenor + S1-9 + A312, Natrium-di(2- ethylhexyl )su fosuccinat + Actirob B + S1-9 + A31.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Solvesso + S1-9 + A32.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S1-9 + A32.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Edenor + S1-9 + A32.2, Natrium-di(2- ethylhexyl) su fosuccinat + Actirob B + S1-9 + A32.2, Natrium-di(2- ethylhexy )sul fosuccinat + Solvesso + S1-9 + A33.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Bayol + S1-9 + A33.2, Natrium-di(2- ethylhexyl) SU fosuccinat + Edenor + S1-9 + A33.2, Natrium-di(2- ethylhexyl )su fosuccinat + Actirob B + S1-9 + A33.2, Natrium-di(2- ethylhexyl )su fosuccinat + Solvesso + S1-9 + A34.2, Natrium-di(2- ethylhexy )su fosuccinat + Bayol + S1-9 + A34.2, Natrium-di(2- ethylhexyl )su fosuccinat + Edenor + S1-9 + A34.2, Natrium-di(2- ethylhexyl )su fosuccinat + Actirob B + S1-9 + A34.2, Natrium-di(2- ethylhexyl) SU fosuccinat + Solvesso + S1-9 + A35.2, Natrium-di(2- ethylhexy )su fosuccinat + Bayol + S1-9 + A35.2, Natrium-di(2- ethylhexy )su fosuccinat + Edenor + S1-9 + A35.2, Natrium-di(2- ethylhexyl )su fosuccinat + Actirob B + S1-9 + A35.2, Natrium-di(2- ethylhexy )su fosuccinat + Solvesso + S1-9 + A36.2, Natrium-di(2- ethylhexyl) su Ifosuccinat + Bayol + S1-9 + A36.2, Natrium-di(2- ethylhexyl )su fosuccinat + Edenor + S1-9 + A36.2, Natrium-di(2- ethylhexyl) SU fosuccinat + Actirob B + S1-9 + A36.2, Natrium-di(2- ethylhexyl )su fosuccinat + Solvesso + S1-9 + A37.2, Natrium-di(2- ethylhexy )su fosuccinat + Bayol + S1-9 + A37.2, Natrium-di(2- ethylhexy] )su fosuccinat + Edenor + S1-9 + A37.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Actirob B + S1-9 + A37.2.Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A2.2 , Sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A3. 2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A3.2, sodium di (2-ethylhexyl ) sulfosuccinate + Solvesso + S1-9 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A4 .2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S 1-9 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A6 .2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A6.2, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A7.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1- 9 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A10 .2, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A10.2, sodium di ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A11.2, sodium di ethylhexy) su ifosuccinate + Bayol + S1-9 + A11.2, sodium di (2-ethylhexy) su ifosuccinate + Edenor + S1-9 + A11.2, sodium di (2 ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A11 .2, sodium di 2-ethylhexy) su ifosuccinate + Solvesso + S1-9 + A12.2, sodium di 2-ethylhexyl) su ifosuccinate + bayol + S1-9 + A12.2, sodium di (2-ethylhexyl ) see below ifosuccinate + Edenor + S1-9 + A12.2, sodium di (2 ethylhexy ') see below ifosuccinate + Actirob B + S1-9 + A12.2, sodium di 2-ethylhexy) see below ifosuccinate + Solvesso + S1- 9 + A13.2, sodium di 2-ethylhexyl) see ifosuccinate + Bayol + S1-9 + A13.2, sodium di (2-ethylhexy]) see ifosuccinate + Edenor + S1-9 + A13.2, sodium di (2 ethylhexy) su ifosuccinate + Actirob B + S1-9 + A13.2, sodium di 2-ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A14.2, sodium di 2-ethylhexyl) su ifosuccinate + Bayol + S1-9 + A14.2, natri um-di (2-ethylhexy) su ifosuccinate + Edenor + S1-9 + A14.2, sodium di (2 ethylhexyl) su ifosuccinate + Actirob B + S1-9 + A14.2, sodium di ethylhexy) su ifosuccinate + Solvesso + S1-9 + A15.2, sodium di ethylhexyl) SU ifosuccinate + Bayol + S1-9 + A15.2, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S1-9 + A15.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A15.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A16.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A16.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A16.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A16.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1- 9 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1 -9 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A19.2, sodium di (2-ethylhexyl) sulfosuccina t + Bayol + S1-9 + A19.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A19.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A19 .2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A20.2, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S1-9 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + 21.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A21.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A21.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A21.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A22.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A22 .2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S1-9 + A22.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S1-9 + A22.2, sodium di (2- ethylhexyl) sulfosuccinate + Solvesso + S1-9 + A23.2 , Sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S1-9 + A23.2, sodium di (2- ethylhexyll)) su fosuccinate + Edenor + S1-9 + A23.2, sodium di (2-ethylhexyl) su [fosuccinate + Actirob B + S1-9 + A23.2, sodium di (2-ethylhexyl l) su fosuccinate + Solvesso + S1-9 + A24.2, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1-9 + A24.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1- 9 + A24.2, sodium di (2-ethylhexyl) su [fosuccinate + Actirob B + S1-9 + A24.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S1-9 + A25. 2, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S1-9 + A25.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1-9 + A25.2, sodium di ( 2-ethylhexyl l) su fosuccinate + Actirob B + S1-9 + A25.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S1-9 + A26.2, sodium di (2-ethylhexyl l) su fosuccinate + Bayol + S1-9 + A26.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1-9 + A26.2, sodium di (2-ethylhexyl) su [fosuccinate + Actirob B + S1-9 + A26.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S1-9 + A27.2, sodium di (2nd - ethylhexy 1 l) su fosuccinate + Bayol + S1-9 + A27.2, sodium di (2-ethylhexy I) su ifosuccinate + Edenor + S1-9 + A27.2, sodium di (2-ethylhexy l) su fosuccinate + Actirob B + S1-9 + A27.2, sodium di (2-ethylhexyl l) su fosuccinate + Solvesso + S1-9 + A28.2, sodium di (2-ethylhexyl l) su fosuccinate + Bayol + S1 -9 + A28.2, sodium di (2-ethylhexyl l) su fosuccinate + Edenor + S1-9 + A28.2, sodium di (2-ethylhexyl l) su ifosuccinate + Actirob B + S1-9 + A28. 2, sodium di (2-ethylhexyl) su [fosuccinate + Solvesso + S1-9 + A29.2, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S1-9 + A29.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1-9 + A29.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S1-9 + A29.2, sodium di (2-ethylhexyl l ) su fosuccinate + Solvesso + S1-9 + A30.2, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-9 + A30.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1-9 + A30.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S1-9 + A30.2, sodium di (2nd - ethylhexyl l) su fosuccinate + Solvesso + S1-9 + A31.2, sodium di (2- ethylhexyl l) su fosuccinate + Bayol + S1-9 + A31.2, sodium di (2- ethylhexy) su fosuccinat + Edenor + S1-9 + A312, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S1-9 + A31.2, sodium di (2-ethylhexy) su ifosuccinate + Solvesso + S1- 9 + A32.2, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S1-9 + A32.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S1-9 + A32.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S1-9 + A32.2, sodium di (2-ethylhexy) sul fosuccinate + Solvesso + S1-9 + A33.2, sodium di (2-ethylhexy) su Ifosuccinate + Bayol + S1-9 + A33.2, sodium di (2-ethylhexyl) SU fosuccinate + Edenor + S1-9 + A33.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S1-9 + A33.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S1-9 + A34.2, sodium di (2-ethylhexy) su fosuccinate + Bayol + S1-9 + A34.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S1-9 + A34.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S1-9 + A34.2, sodium di (2-ethylhexyl) SU fosuccinate + Solvesso + S1-9 + A35.2, sodium di (2-ethylhexy ) su fosuccinate + Bayol + S1-9 + A35.2, sodium di (2-ethylhexy) su fosuccinate + Edenor + S1-9 + A35.2, sodium di (2-ethylhexyl) su fosuccinate + Actirob B + S1 -9 + A35.2, sodium di (2-ethylhexy) su fosuccinate + Solvesso + S1-9 + A36.2, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S1-9 + A36.2, sodium -di (2-ethylhexyl) su fosuccinate + Edenor + S1-9 + A36.2, sodium di (2-ethylhexyl) SU fosuccinate + Actirob B + S1-9 + A36.2, sodium di (2-ethylhexyl) su fosuccinat + Solvesso + S1-9 + A37.2, sodium di (2-ethylhexy) su fosuccinate + Bayol + S1-9 + A37.2, sodium di (2-ethylhexy]) su fosuccinate + Edenor + S1- 9 + A37.2, sodium di (2-ethylhexyl) su ifosuccinate + actirob B + S1-9 + A37.2.
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + AU , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + AU , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + AU, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + AU, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A2.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A2.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A3.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A4.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A4.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A4.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A4.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A5.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A5.1 , Natrium-di(2-ethylhexyl)suIfosuccinat + Edenor + S2-1 + A5.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A5.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A6.1 + EX, Natrium- di(2-ethylhexyl)sulfosuccinat + Bayol + S2-1 + A6.1 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S2-1 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A6.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S2-1 + A6.1 , Natrium- di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A6.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A6.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A7.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A8.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A8.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A9.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A9.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A10.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A10.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A11.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A11.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A11.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A11.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A12.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A13.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A13.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A13.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A13.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A14.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A15.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A15.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A15.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A15.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A16.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A16.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A16.1 , Natrium-di(2- ethylhexyl)su lfosuccinat + Actirob B + S2-1 + A16.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A17.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A17.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A17.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A17.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A19.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A19.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A19.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A19.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A20.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A20.1 , Natrium-di(2- ethylhexyl)suIfosuccinat + Edenor + S2-1 + A20.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A20.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + 21.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A21.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A21.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A21.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A22.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A22.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A22.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A22.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A23.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A23.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A23.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A23.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A24.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A24.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A24.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A24.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A25.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A25.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A25.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A25.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A26.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A26.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A26.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A26.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A27.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A27.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A27.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A27.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A28.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A28.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A28.1 , Natrium-di(2- ethyl hexyl)su Ifosuccinat + Actirob B + S2-1 + A28.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A29.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A29.1 , Natrium-di(2- ethyl hexyl)su Ifosuccinat + Edenor + S2-1 + A29.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A29.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A30.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A30.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A30.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A30.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A31.1 , Natrium-di(2- ethylhexyl)su lfosuccinat + Bayol + S2-1 + A31.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A31.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A31.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A32.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A32.1 , Natrium-di(2- ethyl hexyl)su Ifosuccinat + Edenor + S2-1 + A32.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A32.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A33.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A33.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A33.1 , Natrium-di(2- ethyl hexyl)su Ifosuccinat + Actirob B + S2-1 + A33.1, Natrium-di(2- ethyl hexyl)su Ifosuccinat + Solvesso + S2-1 + A34.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A34.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A34.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A34.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A35.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A37.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A37.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A37.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A37.1Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + AU, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + AU, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2- 1 + AU, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + AU, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A2.1, sodium di (2-ethylhexyl ) sulfosuccinate + Bayol + S2-1 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A3. 1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A4 .1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A4.1, sodium di (2- ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A5.1, sodium di (2-ethylhexyl) suIfosuccinate + Edenor + S2-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A6.1 + EX, Natr ium-di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A6.1 + EX, sodium di (2 -ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A7.1, sodium di ( 2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2 -1 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A9.1, sodium di (2-ethylhexyl) sulfos uccinate + Bayol + S2-1 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A9 .1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A10.1, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S2-1 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A11.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A11.1, sodium di (2- ethylhexyl) su ifosuccinate + Edenor + S2-1 + A11.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A11.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A12.1, Sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A13.1, sodium di (2-ethylhexyl ) su ifosuccinate + Bayol + S2-1 + A13.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A13.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2 -1 + A13.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A14.1, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S2-1 + A14.1, sodium -di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A14.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A14.1, sodium di (2-ethylhexyl) see ifosuccinate + Solvesso + S2-1 + A15.1, sodium di (2nd - ethylhexyl) su ifosuccinate + Bayol + S2-1 + A15.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A15.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A15.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A16.1, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S2-1 + A16.1 , Sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A16.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A16.1, sodium di (2- ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2 -1 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A18.1, Sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A18.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A18.1, sodium di (2-ethylhexyl) see ifosuccinate + Actirob B + S2-1 + A18.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A19.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A19.1, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S2-1 + A19.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A19.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A20.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A20.1, sodium di (2-ethylhexyl) suIfosuccinate + Edenor + S2-1 + A20.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A20.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + 21.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A21.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A21.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A21.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A22.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A22.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A22.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A22.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A23.1, sodium di ( 2-ethylhexyl) sulf osuccinate + Bayol + S2-1 + A23.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A23.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A23 .1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A24.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A24.1, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S2-1 + A24.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A24.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A25.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A25.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A25.1, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A25.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A26.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A26.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A26.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A26.1, sodium di ( 2-ethylhexyl) sulfosuccinate + Solv esso + S2-1 + A27.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A27.1, sodium di (2- ethylhexyl) su ifosuccinate + Edenor + S2-1 + A27.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A27.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A28.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A28.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A28.1, Sodium di (2-ethyl hexyl) su ifosuccinate + Actirob B + S2-1 + A28.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A29.1, sodium di (2- ethylhexyl) su ifosuccinate + Bayol + S2-1 + A29.1, sodium di (2-ethyl hexyl) su ifosuccinate + Edenor + S2-1 + A29.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A29.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A30.1, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S2-1 + A30.1 , Sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A30.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A30.1, sodium di (2- ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A31.1, natriu m-di (2-ethylhexyl) su lfosuccinate + bayol + S2-1 + A31.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A31.1, sodium di (2-ethylhexyl) see below ifosuccinate + Actirob B + S2-1 + A31.1, sodium di (2-ethylhexyl) see below ifosuccinate + Solvesso + S2-1 + A32.1, sodium di (2-ethylhexyl) below ifosuccinate + Bayol + S2- 1 + A32.1, sodium di (2-ethyl hexyl) su ifosuccinate + Edenor + S2-1 + A32.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A32.1, Sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A33.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A33.1, sodium di (2-ethylhexyl) see below ifosuccinate + Edenor + S2-1 + A33.1, sodium di (2-ethyl hexyl) see below ifosuccinate + Actirob B + S2-1 + A33.1, sodium di (2-ethyl hexyl) below ifosuccinate + Solvesso + S2-1 + A34.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A34.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A34.1, Sodium di (2-ethylhexyl) su ifosuccinate + actirob B + S2-1 + A34.1, Na trium-di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A35.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A35.1, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S2-1 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A36.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2- 1 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A37.1
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A1.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A2.2, Natrium-di(2- ethy!hexyl)sulfosuccinat + Bayol + S2-1 + A2.2, Natr'-um-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A3.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A4.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A5.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A6.2 + EX, Natrium- di(2-ethylhexyl)sulfosuccinat + Bayol + S2-1 + A6.2 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S2-1 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A6.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S2-1 + A6.2, Natrium- di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A6.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A6.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A7.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A8.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A9.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S2-1 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A15.2, Natrium~di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + AM.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + AM.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + 21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A23.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A23.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A23.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A23.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A24.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A24.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A24.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A24.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A25.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A25.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A25.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A25.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A26.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A26.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A26.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A26.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A27.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A27.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A27.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A27.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A28.2, Natrium-di(2- ethyl hexyl)su Ifosuccinat + Bayol + S2-1 + A28.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A28.2, Natrium-di(2- ethylhexyl)su lfosuccinat + Actirob B + S2-1 + A28.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A29.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A29.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A29.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A29.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A30.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A30.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S2-1 + A30.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S2-1 + A30.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S2-1 + A31.2, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S2-1 + A31.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A31.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A31.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A32.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A32.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A32.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A32.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A33.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A33.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A33.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A33.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A34.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A34.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A34.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A34.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A35.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A35.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A35.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A35.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A36.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A36.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A36.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A36.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S2-1 + A37.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S2-1 + A37.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S2-1 + A37.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S2-1 + A37.2.Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A2.2 , Sodium di (2-ethy! Hexyl) sulfosuccinate + Bayol + S2-1 + A2.2, Natr ' -um-di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A2.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2 -1 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A5.2, sodium -di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A6.2, sodium -di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A6.2, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A7.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2- 1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A10 .2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A11.2, sodium di (2- ethylhexyl) sulfosuccinate + Bayol + S2-1 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A12.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Edenor + S2-1 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2- 1 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A13.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2 -1 + A14.2, sodium di (2-ethylh exyl) sulfosuccinate + Edenor + S2-1 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A15.2, sodium ~ di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A15.2, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S2-1 + A15.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A15.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A16.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A16.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A16.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A16.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + AM.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2- 1 + AM.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2 -1 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A19.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A19.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A19.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A19. 2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + 21.2 , Sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A21.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A21.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A21.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A22.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A22. 2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A22.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A22.2, sodium di (2-ethylhexyl ) sulfosuccinate + Solvesso + S2-1 + A23.2, Sodium di (2-ethylhexyl) sulfosuccinate + bayol + S2-1 + A23.2, sodium di (2- ethylhexyl) su ifosuccinate + Edenor + S2-1 + A23.2, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A23.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A24.2, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A24.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A24.2, Sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A24.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A25.2, sodium di (2-ethylhexyl ) su ifosuccinate + Bayol + S2-1 + A25.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A25.2, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2 -1 + A25.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A26.2, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S2-1 + A26.2, sodium -di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A26.2, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A26.2, sodium di (2-ethylhexyl) see ifosuccinate + Solvesso + S2-1 + A27.2, sodium di (2-ethylhex yl) su ifosuccinate + Bayol + S2-1 + A27.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A27.2, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A27.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A28.2, sodium di (2-ethyl hexyl) su ifosuccinate + bayol + S2-1 + A28.2 , Sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A28.2, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A28.2, sodium di (2- ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A29.2, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A29.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2 -1 + A29.2, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S2-1 + A29.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S2-1 + A30.2, Sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A30.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S2-1 + A30.2, sodium di (2-ethylhexyl) see ifosuccinate + actirob B + S2-1 + A30.2, sodium di (2-ethylhexyl) see ifos uccinat + Solvesso + S2-1 + A31.2, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S2-1 + A31.2, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S2-1 + A31.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A31.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A32.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A32.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A32.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A32.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A33.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2- 1 + A33.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A33.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A33.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A34.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A34.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2 -1 + A34.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A34.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A35.2, sodium di (2-ethylhexyl) sulfosuccina t + Bayol + S2-1 + A35.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A35.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A35 .2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A36.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A36.2, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S2-1 + A36.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A36.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S2-1 + A37.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S2-1 + A37.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S2-1 + A37.2, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S2-1 + A37.2.
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + AU , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + AU, Natrium-di(2-ethylhexyi)sulfosuccinat + Edenor + S3-1 + AU , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + AU , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A2.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A2.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A3.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A3.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A3.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A4.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A4.1, Natrium-di(2-ethylhexyl)su!fosuccinat + Edenor + S3-1 + A4.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A4.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A5.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A5.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A5.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A5.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A6.1 + EX, Natrium- di(2-ethylhexyl)sulfosuccinat + Bayol + S3-1 + A6.1 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S3-1 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A6.1 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A6.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S3-1 + A6.1, Natrium- di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A6.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A6.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A7.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A7.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A8.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A8.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A9.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A9.1, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A9.1 , Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A10.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A10.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A111 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A11.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S3-1 + A11.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S3-1 + A11.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S3-1 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S3-1 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S3-1 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S3-1 + A12.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S3-1 + A13.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S3-1 + A13.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S3-1 + A13.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S3-1 + A13.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S3-1 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S3-1 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S3-1 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S3-1 + A14.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S3-1 + A15.1 , Natrium-di(2- ethylhexyl)su lfosuccinat + Bayol + S3-1 + A15.1 , Natrium-di(2- ethylhexyl)su lfosuccinat + Edenor + S3-1 + A15.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S3-1 + A15.1 , Natrium-di(2- ethylhexyl)su lfosuccinat + Solvesso + S3-1 + A16.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S3-1 + A16.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S3-1 + A16.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S3-1 + A16.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S3-1 + A17.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S3-1 + A17.1 , Natrium-di(2- ethylhexyl)su lfosuccinat + Edenor + S3-1 + A17.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S3-1 + A17.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S3-1 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S3-1 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Edenor + S3-1 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S3-1 + A18.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S3-1 + A19.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S3-1 + A19.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Edenor + S3-1 + A19.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Actirob B + S3-1 + A19.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Solvesso + S3-1 + A20.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Bayol + S3-1 + A20.1 , Natrium-di(2- ethylhexy! )sulfosuccinat + Edenor + S3-1 + A20.1, Natrium-di(2- ethylhexy! )sulfosuccinat + Actirob B + S3-1 + A20.1, Natrium-di(2- ethylhexyl )sulfosuccinat + Solvesso + S3-1 + 21.1 , Natrium-di(2- ethylhex )sulfosuccinat + Bayol + S3-1 + A21.1, Natrium-di(2- ethylhexy )sulfosuccinat + Edenor + S3-1 + A21.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Actirob B + S3-1 + A21.1, Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S3-1 + A22.1, Natrium-di(2- ethylhexy )sulfosuccinat + Bayol + S3-1 + A22.1 , Natrium-di(2- ethylhexy !)sulfosuccinat + Edenor + S3-1 + A22.1 , Natrium-di(2- ethylhexy! )sulfosuccinat + Actirob B + S3-1 + A22.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Solvesso + S3-1 + A23.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Bayol + S3-1 + A23.1 , Natrium-di(2- ethylhexyl )sulfosuccinat + Edenor + S3-1 + A23.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Actirob B + S3-1 + A23.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Solvesso + S3-1 + A24.1 , Natrium-di(2- ethylhexyl )sulfosuccinat + Bayol + S3-1 + A24.1 , Natrium-di(2- ethylhexy! )sulfosuccinat + Edenor + S3-1 + A24.1 , Natrium-di(2- ethylhexyl )sulfosuccinat + Actirob B + S3-1 + A24.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Solvesso + S3-1 + A25.1 , Natrium-di(2- ethylhexyl )sulfosuccinat + Bayol + S3-1 + A25.1, Natrium-di(2- ethylhexy )sulfosuccinat + Edenor + S3-1 + A25.1, Natrium-di(2- ethylhexy )sulfosuccinat + Actirob B + S3-1 + A25.1, Natrium-di(2- ethylhexy )sulfosuccinat + Solvesso + S3-1 + A26.1 , Natrium-di(2- ethylhexy )sulfosuccinat + Bayol + S3-1 + A26.1, Natrium-di(2- ethylhexy )sulfosuccinat + Edenor + S3-1 + A26.1 , Natrium-di(2- ethylhexyl) sulfosuccinat + Actirob B + S3-1 + A26.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Solvesso + S3-1 + A27.1 , Natrium-di(2- ethylhexyl)su Ifosuccinat + Bayol + S3-1 + A27.1 , Natrium-di(2- ethylhexyl l)su Ifosuccina + Edenor + S3-1 + A27.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S3-1 + A27.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S3-1 + A28.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Bayol + S3-1 + A28.1, Natrium-di(2- ethylhexy l)su Ifosuccina + Edenor + S3-1 + A28.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S3-1 + A28.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S3-1 + A29.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Bayol + S3-1 + A29.1 , Natrium-di(2- ethylhexyl l)su Ifosuccina + Edenor + S3-1 + A29.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S3-1 + A29.1 , Natrium-di(2- ethylhexy! l)su Ifosuccina + Solvesso + S3-1 + A30.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Bayol + S3-1 + A30.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Edenor + S3-1 + A30.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S3-1 + A30.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S3-1 + A31.1 , Natrium-di(2- ethylhexyl l)su Ifosuccina + Bayol + S3-1 + A31.1, Natrium-di(2- ethylhexy l)su Ifosuccina + Edenor + S3-1 + A31.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S3-1 + A31.1 , Natrium-di(2- ethylhexy l)su Ifosuccin + Solvesso + S3-1 + A32.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Bayol + S3-1 + A32.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Edenor + S3-1 + A32.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S3-1 + A32.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S3-1 + A33.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Bayol + S3-1 + A33.1, Natrium-di(2- ethylhexy l)su Ifosuccina + Edenor + S3-1 + A33.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Actirob B + S3-1 + A33.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S3-1 + A34.1 , Natrium-di(2- ethylhexy l)su Ifosuccina' + Bayol + S3-1 + A34.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Edenor + S3-1 + A34.1 , Natrium-di(2- ethylhexyl l)su Ifosuccina + Actirob B + S3-1 + A34.1 , Natrium-di(2- ethylhexy l)su Ifosuccina + Solvesso + S3-1 + A35.1 , Natrium-di(2- ethylhex l)su Ifosuccina + Bayol + S3-1 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A35.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A36.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A36.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A36.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A37.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A37.1, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A37.1 , Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A37.1Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + AU, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + AU, sodium di (2-ethylhexyi) sulfosuccinate + Edenor + S3- 1 + AU, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + AU, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A2.1, sodium di (2-ethylhexyl ) sulfosuccinate + Bayol + S3-1 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A2.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A3. 1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A3.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A4 .1, sodium di (2-ethylhexyl) su! Fosuccinate + Edenor + S3-1 + A4.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A4.1, sodium di ( 2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3- 1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A5.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A6.1 + EX, sodium - di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A6.1 + EX, sodium -di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A6.1 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A6.1 + EX, sodium di (2- ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A6.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A7.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Bayol + S3-1 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3- 1 + A7.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A8.1, sodium di ( 2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A8.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3 -1 + A9.1, sodium di (2-ethylhexyl) sulfosu ccinat + Bayol + S3-1 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A9.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A9 .1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A10.1, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S3-1 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A10.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A111, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A11.1, sodium di (2- ethylhexyl) su ifosuccinate + Edenor + S3-1 + A11.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3-1 + A11.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S3-1 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S3-1 + A12.1, Sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3-1 + A12.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A13.1, sodium di (2-ethylhexyl ) su ifosuccinate + Bayol + S3-1 + A13.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S3-1 + A13.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3 -1 + A13.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A14.1, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S3-1 + A14.1, sodium -di (2-ethylhexyl) su ifosuccinate + Edenor + S3-1 + A14.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3-1 + A14.1, sodium di (2-ethylhexyl) see ifosuccinate + Solvesso + S3-1 + A15.1, sodium di (2-ethylhexyl) su lfosuccinate + Bayol + S3-1 + A15.1, sodium di (2-ethylhexyl) su lfosuccinate + Edenor + S3-1 + A15.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3-1 + A15.1, sodium di (2-ethylhexyl) su lfosuccinate + Solvesso + S3-1 + A16.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S3-1 + A16.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S3-1 + A16.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3-1 + A16.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S3-1 + A17.1, sodium di (2-ethylhexyl) su lfosuccinate + Edenor + S3-1 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3-1 + A17.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A18 .1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S3-1 + A18.1, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S3-1 + A18.1, sodium di (2 - ethylhexyl) su ifosuccinate + actirob B + S3-1 + A18.1, natriu m-di (2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A19.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S3-1 + A19.1, sodium di (2- ethylhexy) sulfosuccinate + Edenor + S3-1 + A19.1, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3-1 + A19.1, sodium di (2-ethylhexy) sulfosuccinate + Solvesso + S3- 1 + A20.1, sodium di (2-ethylhexy) sulfosuccinate + Bayol + S3-1 + A20.1, sodium di (2-ethylhexy!) Sulfosuccinate + Edenor + S3-1 + A20.1, sodium di (2-ethylhexy!) Sulfosuccinate + Actirob B + S3-1 + A20.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + 21.1, sodium di (2-ethylhex) sulfosuccinate + Bayol + S3 -1 + A21.1, sodium di (2-ethylhexy) sulfosuccinate + Edenor + S3-1 + A21.1, sodium di (2-ethylhexy) sulfosuccinate + Actirob B + S3-1 + A21.1, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A22.1, sodium di (2-ethylhexy) sulfosuccinate + Bayol + S3-1 + A22.1, sodium di (2-ethylhexy!) sulfosuccinate + Edenor + S3-1 + A22.1, sodium di (2-ethylhexy!) Sulfosuccinate + Actirob B + S3-1 + A22.1, sodium di (2-ethylhexy) sulfosuccinate + Solvesso + S3-1 + A23. 1, sodium di (2-ethylhex y) sulfosuccinate + Bayol + S3-1 + A23.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A23.1, sodium di (2-ethylhexy) sulfosuccinate + Actirob B + S3-1 + A23.1, sodium di (2-ethylhexy) sulfosuccinate + Solvesso + S3-1 + A24.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A24.1, sodium di (2nd - ethylhexy! ) sulfosuccinate + Edenor + S3-1 + A24.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A24.1, sodium di (2-ethylhexy) sulfosuccinate + Solvesso + S3-1 + A25.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A25.1, sodium di (2-ethylhexy) sulfosuccinate + Edenor + S3-1 + A25.1, sodium di (2- ethylhexy) sulfosuccinate + Actirob B + S3-1 + A25.1, sodium di (2-ethylhexy) sulfosuccinate + Solvesso + S3-1 + A26.1, sodium di (2-ethylhexy) sulfosuccinate + Bayol + S3-1 + A26.1, sodium di (2-ethylhexy) sulfosuccinate + Edenor + S3-1 + A26.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A26.1, sodium di ( 2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A27.1, sodium di (2-ethylhexyl) su ifosuccinate + Bayol + S3-1 + A27.1, sodium di (2- ethylhexyl l) su Ifosuccina + Edenor + S3-1 + A27.1, sodium di (2-ethylhexyl) su Ifosuccina + Actirob B + S3-1 + A27.1, sodium di (2-ethylhexyl l) su Ifosuccina + Solvesso + S3-1 + A28.1, sodium di (2-ethylhexyl) see Ifosuccina + Bayol + S3-1 + A28.1, sodium di (2-ethylhexyl) see Ifosuccina + Edenor + S3-1 + A28.1, sodium di (2-ethylhexyl) see Ifosuccina + Actirob B + S3-1 + A28.1, sodium di (2-ethylhexyl) see Ifosuccina + Solvesso + S3-1 + A29.1, Sodium di (2-ethylhexyl) su Ifosuccina + Bayol + S3-1 + A29.1, sodium di (2-ethylhexyl l) su Ifosuccina + Edenor + S3-1 + A29.1, sodium di (2- ethylhexy l) su Ifosuccina + Actirob B + S3-1 + A29.1, sodium di (2-ethylhexy! l) su Ifosuccina + Solvesso + S3-1 + A30.1, sodium di (2-ethylhexy l) su Ifosuccina + Bayol + S3-1 + A30.1, sodium di (2-ethylhexyl) su Ifosuccina + Edenor + S3-1 + A30.1, sodium di (2-ethylhexyl l) su Ifosuccina + Actirob B + S3 -1 + A30.1, sodium di (2-ethylhexyl) su Ifosuccina + Solvesso + S3-1 + A31.1, natri um-di (2-ethylhexyl l) su Ifosuccina + Bayol + S3-1 + A31.1, sodium di (2-ethylhexyl l) su Ifosuccina + Edenor + S3-1 + A31.1, sodium di (2- ethylhexy l) su Ifosuccina + Actirob B + S3-1 + A31.1, sodium di (2-ethylhexy l) su Ifosuccin + Solvesso + S3-1 + A32.1, sodium di (2-ethylhexy l) su Ifosuccina + Bayol + S3-1 + A32.1, sodium di (2-ethylhexyl) see Ifosuccina + Edenor + S3-1 + A32.1, sodium di (2-ethylhexyl) see Ifosuccina + Actirob B + S3- 1 + A32.1, sodium di (2-ethylhexyl) su Ifosuccina + Solvesso + S3-1 + A33.1, sodium di (2-ethylhexyl l) su Ifosuccina + Bayol + S3-1 + A33.1, Sodium di (2-ethylhexyl) su Ifosuccina + Edenor + S3-1 + A33.1, sodium di (2-ethylhexyl l) su Ifosuccina + Actirob B + S3-1 + A33.1, sodium di (2nd - ethylhexy l) su Ifosuccina + Solvesso + S3-1 + A34.1, sodium di (2-ethylhexy l) su Ifosuccina '+ Bayol + S3-1 + A34.1, sodium di (2-ethylhexy l) su Ifosuccina + Edenor + S3-1 + A34.1, sodium di (2-ethylhexyl l) su Ifosuccina + Actirob B + S3-1 + A34.1, N atrium-di (2-ethylhexy l) su Ifosuccina + Solvesso + S3-1 + A35.1, sodium di (2-ethylhex l) su Ifosuccina + Bayol + S3-1 + A35.1, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S3-1 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A35.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A36.1, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A36.1, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3- 1 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A37.1, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A37.1
Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A1.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A1.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A2.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A2.2, Natrium-di(2-ethylhexyi)sulfosuccinat + Edenor + S3-1 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A2.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A3.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A3.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A4.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A4.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A5.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A5.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A6.2 + EX, Natrium- di(2~ethylhexyl)sulfosuccinat + Bayol + S3-1 + A6.2 + EX, Natrium-di(2-ethylhexyl) sulfosuccinat + Edenor + S3-1 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A6.2 + EX, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A6.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Bayol + S3-1 + A6.2, Natrium- di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A6.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A6.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A7.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A7.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A8.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A8.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A9.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Edenor + S3-1 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A9.2, Natrium-di(2-ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A10.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A11.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A12.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A13.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A14.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A15.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A16.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A17.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A18.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A19.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A20.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + 21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A21.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A22.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A23.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A23.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A23.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A23.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A24.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A24.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A24.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A24.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A25.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A25.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A25.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A25.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A26.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A26.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A26.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A26.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A27.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A27.2, Natπum-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A27.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A27.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A28.2, Natrium-di(2- ethylhexyl)su!fosuccinat + Bayol + S3-1 + A28.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A28.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A28.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A29.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A29.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A29.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A29.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A30.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A30.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Edenor + S3-1 + A30.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Actirob B + S3-1 + A30.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Solvesso + S3-1 + A31.2, Natrium-di(2- ethylhexyl)sulfosuccinat + Bayol + S3-1 + A31.2, Natrium-di(2- ethylhexyl )su fosuccinat + Edenor + S3-1 + A31.2, Natrium-di(2- ethylhexy )su ifosuccinat + Actirob B + S3-1 + A31.2, Natrium-di(2- ethylhexyl) su Ifosuccinat + Solvesso + S3-1 + A32.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Bayol + S3-1 + A32.2, Natrium-di(2- ethylhexyl )su fosuccinat + Edenor + S3-1 + A32.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Actirob B + S3-1 + A32.2, Natrium-di(2- ethylhexy )su fosuccinat + Solvesso + S3-1 + A33.2, Natrium-di(2- ethylhexyl )su fosuccinat + Bayol + S3-1 + A33.2, Natrium-di(2- ethylhexyl )su fosuccinat + Edenor + S3-1 + A33.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Actirob B + S3-1 + A33.2, Natrium-di(2- ethylhexy )su fosuccinat + Solvesso + S3-1 + A34.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Bayol + S3-1 + A34.2, Natrium-di(2- ethylhexyl)su fosuccinat + Edenor + S3-1 + A34.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Actirob B + S3-1 + A34.2, Natrium-di(2- ethylhexyl) su fosuccinat + Solvesso + S3-1 + A35.2, Natrium-di(2- ethylhexy )su fosuccinat + Bayol + S3-1 + A35.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Edenor + S3-1 + A35.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Actirob B + S3-1 + A35.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Solvesso + S3-1 + A36.2, Natrium-di(2- ethylhexyl )su Ifosuccinat + Bayol + S3-1 + A36.2, Natrium-di(2- ethylhexy )su Ifosuccinat + Edenor + S3-1 + A36.2, Natrium-di(2- ethylhexy )su ifosuccinat + Actirob B + S3-1 + A36.2, Natrium-di(2- ethylhexyl )su fosuccinat + Solvesso + S3-1 + A37.2, Natrium-di(2- ethylhexyl )su fosuccinat + Bayol + S3-1 + A37.2, Natrium-di(2- ethylhexy )su fosuccinat + Edenor + S3-1 + A37.2, Natrium-di(2- ethylhexy )su fosuccinat + Actirob B + S3-1 + A37.2.Sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A1.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A2.2 , Sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A2.2, sodium di (2-ethylhexyi) sulfosuccinate + Edenor + S3-1 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A2.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A3. 2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A3.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A3.2, sodium di (2-ethylhexyl ) sulfosuccinate + Solvesso + S3-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A4 .2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S 3-1 + A4.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A5.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A6.2 + EX, sodium di (2 ~ ethylhexyl) sulfosuccinate + Bayol + S3-1 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A6 .2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A6.2 + EX, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A6.2, sodium di (2- ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A6.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A7.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A7.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3- 1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A8.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A9.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A10 .2, Sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A10.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A11.2, sodium di (2- ethylhexyl) sulfosuccinate + Bayol + S3-1 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A11.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A12.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Edenor + S3-1 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A12.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3- 1 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A13.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A13.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3 -1 + A14.2, sodium di (2-ethylh exyl) sulfosuccinate + Edenor + S3-1 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A14.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A15.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A15.2, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S3-1 + A15.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A15.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A16.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A16.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A16.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A16.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3- 1 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A17.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3 -1 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A18.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A19.2, sodium di (2-ethylhexyl) sulfosuccina t + Bayol + S3-1 + A19.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A19.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A19 .2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A20.2, sodium di (2-ethylhexyl ) sulfosuccinate + Edenor + S3-1 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A20.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + 21.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A21.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A21.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A21.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A22.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A22 .2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A22.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A22.2, sodium di (2- ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A23.2 , Sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A23.2, sodium di (2- ethylhexyl) sulfosuccinate + Edenor + S3-1 + A23.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A23.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A24.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A24.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A24.2, sodium di (2nd - ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A24.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A25.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3- 1 + A25.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A25.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A25.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A26.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A26.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3 -1 + A26.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A26.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A27.2, sodium di (2-ethylhexyl) sulfosuccina t + Bayol + S3-1 + A27.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A27.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A27 .2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A28.2, sodium di (2-ethylhexyl) su! Fosuccinate + Bayol + S3-1 + A28.2, sodium di (2 - ethylhexyl) sulfosuccinate + Edenor + S3-1 + A28.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A28.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3- 1 + A29.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3-1 + A29.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A29.2, sodium di ( 2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A29.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A30.2, sodium di (2-ethylhexyl) sulfosuccinate + Bayol + S3 -1 + A30.2, sodium di (2-ethylhexyl) sulfosuccinate + Edenor + S3-1 + A30.2, sodium di (2-ethylhexyl) sulfosuccinate + Actirob B + S3-1 + A30.2, sodium di (2-ethylhexyl) sulfosuccinate + Solvesso + S3-1 + A31. 2, sodium di (2-ethylhexyl) sulfosuccinate + bayol + S3-1 + A31.2, sodium di (2- ethylhexyl) su fosuccinate + Edenor + S3-1 + A31.2, sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S3-1 + A31.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A32.2, sodium di (2-ethylhexy) su ifosuccinate + Bayol + S3-1 + A32.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S3-1 + A32.2, Sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S3-1 + A32.2, sodium di (2-ethylhexy) su fosuccinate + Solvesso + S3-1 + A33.2, sodium di (2-ethylhexyl ) su fosuccinate + Bayol + S3-1 + A33.2, sodium di (2-ethylhexyl) su fosuccinate + Edenor + S3-1 + A33.2, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3 -1 + A33.2, sodium di (2-ethylhexy) su fosuccinate + Solvesso + S3-1 + A34.2, sodium di (2-ethylhexy) su ifosuccinate + bayol + S3-1 + A34.2, sodium -di (2-ethylhexyl) su fosuccinate + Edenor + S3-1 + A34.2, sodium di (2-ethylhexyl) su ifosuccinate + Actirob B + S3-1 + A34.2, sodium di (2-ethylhexyl) su fosuccinate + Solvesso + S3-1 + A35.2, sodium di (2-ethylhex y) su fosuccinate + Bayol + S3-1 + A35.2, sodium di (2-ethylhexyl) su ifosuccinate + Edenor + S3-1 + A35.2, sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S3-1 + A35.2, sodium di (2-ethylhexyl) su ifosuccinate + Solvesso + S3-1 + A36.2, sodium di (2-ethylhexyl) su ifosuccinate + bayol + S3-1 + A36.2, Sodium di (2-ethylhexy) su ifosuccinate + Edenor + S3-1 + A36.2, sodium di (2-ethylhexy) su ifosuccinate + Actirob B + S3-1 + A36.2, sodium di (2-ethylhexyl ) su fosuccinate + Solvesso + S3-1 + A37.2, sodium di (2-ethylhexyl) su fosuccinate + Bayol + S3-1 + A37.2, sodium di (2-ethylhexy) su fosuccinate + Edenor + S3- 1 + A37.2, sodium di (2-ethylhexy) su fosuccinate + Actirob B + S3-1 + A37.2.
In den vorgenannten Kombinationen können auch mehrere Sulfonamide als Komponente a) miteinander kombiniert werden.In the aforementioned combinations, several sulfonamides can also be combined with one another as component a).
Beispiele solcher Kombinationen sind (AU) + (A1.2), (AU) + (A2.1), (AU) + (A2.2), (AU) + (A3.1), (AU) + (A3.2), (AU) + (A4.1), (AU) + (A4.2), (AU) + (A5.1), (AU) + (A5.2), (AU) + (A6.1), (AU) + (A6.2), (AU) + (A7.1), (AU) + (A7.2), (AU) + (A8.1), (AU) + (A8.2), (AU) + (A9.1), (AU) + (A9.2), (AU) + (A10.1), (AU) + (A10.2), (AU) + (A11.1), (AU) + (A11.2), (AU) + (A12.1), (AU) + (A12.2), (AU) + (A13.1), (AU) + (A13.2), (AU) + (A14.1), (AU) + (A14.2), (AU) + (A15.1), (AU) + (A15.2), (AU) + (A16.1), (AU) + (A16.2), (AU) + (A17.1), (AU) + (A17.2), (AU) + (A18.1), (AU) + (A18.2), (AU) + (A19.1),Examples of such combinations are (AU) + (A1.2), (AU) + (A2.1), (AU) + (A2.2), (AU) + (A3.1), (AU) + (A3 .2), (AU) + (A4.1), (AU) + (A4.2), (AU) + (A5.1), (AU) + (A5.2), (AU) + (A6.1), (AU) + (A6.2), (AU) + (A7.1), (AU) + (A7.2), (AU) + (A8.1), (AU) + (A8.2), (AU) + (A9.1), (AU) + (A9.2), (AU) + (A10.1), (AU) + (A10.2), (AU) + (A11.1), (AU) + (A11.2), (AU) + (A12.1), (AU) + (A12.2), (AU) + (A13.1), (AU) + (A13.2), (AU) + (A14.1), (AU) + (A14.2), (AU) + (A15.1), (AU) + (A15.2), (AU) + (A16.1), (AU) + (A16.2), (AU) + (A17.1), (AU) + (A17.2), (AU) + (A18.1), (AU) + (A18.2), (AU) + (A19.1),
(AU + (A19.2),(AU + (A19.2),
(A1.2 + (A2.1), (A1.2) + (A2.2), (A1.2) + (A3.1), (A1.2) + (A3.2), (A1.2) + (A4.1),(A1.2 + (A2.1), (A1.2) + (A2.2), (A1.2) + (A3.1), (A1.2) + (A3.2), (A1. 2) + (A4.1),
(A1.2 + (A4.2), (A1.2) + (A5.1), (A1.2) + (A5.2), (A1.2) + (A6.1), (A1.2) + (A6.2),(A1.2 + (A4.2), (A1.2) + (A5.1), (A1.2) + (A5.2), (A1.2) + (A6.1), (A1. 2) + (A6.2),
(A1.2 + (A7.1), (A1.2) + (A7.2), (A1.2) + (A8.1), (A1.2) + (A8.2), (A1.2) + (A9.1),(A1.2 + (A7.1), (A1.2) + (A7.2), (A1.2) + (A8.1), (A1.2) + (A8.2), (A1. 2) + (A9.1),
(A1.2 + (A9.2), (A1.2) + (A10.1), (A1.2) + (A10.2), (A1.2) + (A11.2), (A1.2) +(A1.2 + (A9.2), (A1.2) + (A10.1), (A1.2) + (A10.2), (A1.2) + (A11.2), (A1. 2) +
(A11 2), (A1.2) + (A12.1), (A1.2) + (A12.2), (A1.2) + (A13.1), (A1.2) + (A13.2),(A11 2), (A1.2) + (A12.1), (A1.2) + (A12.2), (A1.2) + (A13.1), (A1.2) + (A13. 2)
(A1.2 + (A14.1), (A1.2) + (A14.2), (A1.2) + (A15.1), (A1.2) + (A15.2), (A1.2) +(A1.2 + (A14.1), (A1.2) + (A14.2), (A1.2) + (A15.1), (A1.2) + (A15.2), (A1. 2) +
(A16. ), (A1.2) + (A16.2), (A1.2) + (A17.1), (A12) + (A17.2), (A12) + (A18.1),(A16.), (A1.2) + (A16.2), (A1.2) + (A17.1), (A12) + (A17.2), (A12) + (A18.1),
(A1.2 + (A18.2), (A1.2) + (A19.1), (A1.2) + (A19.2),(A1.2 + (A18.2), (A1.2) + (A19.1), (A1.2) + (A19.2),
(A2.1 + (A2.2), (A2.1) + (A3.1), (A2.1) + (A3.2), (A2.1) + (A4.1), (A2.1) + (A4.2),(A2.1 + (A2.2), (A2.1) + (A3.1), (A2.1) + (A3.2), (A2.1) + (A4.1), (A2. 1) + (A4.2),
(A2.1 + (A5.1), (A2.1) + (A5.2), (A2.1) + (A6.1), (A2.1) + (A6.2), (A2.1) + (A7.1),(A2.1 + (A5.1), (A2.1) + (A5.2), (A2.1) + (A6.1), (A2.1) + (A6.2), (A2. 1) + (A7.1),
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(A10.1) + (A10.2), (A10.1) + (A11.1), (A10.1) + (A11.2), (A10.1) + (A12.1), (A10.1) + (A12.2), (A10.1) + (A13.1), (A10.1) + (A13.2), (A10.1) + (A14.1), (A10.1) + (A14.2), (A10.1) + (A15.1), (A10.1) + (A15.2), (A10.1) + (A16.1), (A10.1) + (A16.2), (A10.1) + (A17.1), (A10.1) + (A17.2), (A10.1) + (A18.1), (A10.1) + (A18.2), (A10.1) + (A19.1), (A10.1) + (A19.2),(A10.1) + (A10.2), (A10.1) + (A11.1), (A10.1) + (A11.2), (A10.1) + (A12.1), (A10 .1) + (A12.2), (A10.1) + (A13.1), (A10.1) + (A13.2), (A10.1) + (A14.1), (A10.1 ) + (A14.2), (A10.1) + (A15.1), (A10.1) + (A15.2), (A10.1) + (A16.1), (A10.1) + (A16.2), (A10.1) + (A17.1), (A10.1) + (A17.2), (A10.1) + (A18.1), (A10.1) + (A18 .2), (A10.1) + (A19.1), (A10.1) + (A19.2),
(A10.2) + (A11.1), (A10.2) + (A11.2), (A10.2) + (A12.1), (A10.2) + (A12.2), (A10.2) + (A13.1), (A10.2) + (A13.2), (A10.2) + (A14.1), (A10.2) + (A14.2), (A10.2) + (A15.1), (A10.2) + (A15.2), (A10.2) + (A16.1), (A10.2) + (A16.2), (A10.2) + (A17.1), (A10.2) + (A17.2), (A10.2) + (A18.1), (A10.2) + (A18.2), (A10.2) + (A19.1), (A10.2) + (A19.2), (A11.1) + (A11.2), (A11.1) + (A12.1), (A11.1) + (A12.2), (A11.1) + (A13.1), (A11.1) + (A13.2), (A11.1) + (A14.1), (A11.1) + (A14.2), (A11.1) + (A15.1), (A11.1) + (A15.2), (A11.1) + (A16.1), (A11.1) + (A16.2), (A11.1) + (A17.1), (A11.1) + (A17.2), (A11.1) + (A18.1' ), (A11.1) + (A18.2), (A11.1) + (A19.1), (A11.1) + (A19.2),(A10.2) + (A11.1), (A10.2) + (A11.2), (A10.2) + (A12.1), (A10.2) + (A12.2), (A10 .2) + (A13.1), (A10.2) + (A13.2), (A10.2) + (A14.1), (A10.2) + (A14.2), (A10.2 ) + (A15.1), (A10.2) + (A15.2), (A10.2) + (A16.1), (A10.2) + (A16.2), (A10.2) + (A17.1), (A10.2) + (A17.2), (A10.2) + (A18.1), (A10.2) + (A18.2), (A10.2) + (A19 .1), (A10.2) + (A19.2), (A11.1) + (A11.2), (A11.1) + (A12.1), (A11.1) + (A12.2 ), (A11.1) + (A13.1), (A11.1) + (A13.2), (A11.1) + (A14.1), (A11.1) + (A14.2), (A11.1) + (A15.1), (A11.1) + (A15.2), (A11.1) + (A16.1), (A11.1) + (A16.2), (A11 .1) + (A17.1), (A11.1) + (A17.2), (A11.1) + (A18.1 '), (A11.1) + (A18.2), (A11.1) + (A19.1), (A11.1) + (A19.2),
(A11.2) + (A12.1), (A11.2) + (A12.2), (A11.2) + (A13.1), (A11.2) + (A13.2), (A11.2) +(A11.2) + (A12.1), (A11.2) + (A12.2), (A11.2) + (A13.1), (A11.2) + (A13.2), (A11 .2) +
(A14.1) (A11.2) + (A14.2), (A11.2) + (A15.1), (A11.2) + (A15.2), (A11.2) + (A16.1),(A14.1) (A11.2) + (A14.2), (A11.2) + (A15.1), (A11.2) + (A15.2), (A11.2) + (A16. 1),
(A11.2) + (A16.2), (A11.2) + (A17.1), (A11.2) + (A17.2), (A11.2) + (A18.1), (A11.2) +(A11.2) + (A16.2), (A11.2) + (A17.1), (A11.2) + (A17.2), (A11.2) + (A18.1), (A11 .2) +
(A18.2) , (A11.2) + (A19.1), (A11.2) + (A19.2),(A18.2), (A11.2) + (A19.1), (A11.2) + (A19.2),
(A12.1) + (A12.2), (A12.1) + (A13.1), (A12.1) + (A13.2), (A12.1) + (A14.1), (A12.1) +(A12.1) + (A12.2), (A12.1) + (A13.1), (A12.1) + (A13.2), (A12.1) + (A14.1), (A12 .1) +
(A14.2) , (A12.1) + (A15.1), (A12.1) + (A15.2), (A12.1) + (A16.1), (A12.1) + (A16.2),(A14.2), (A12.1) + (A15.1), (A12.1) + (A15.2), (A12.1) + (A16.1), (A12.1) + (A16 .2)
(A12.1) + (A17.1), (A12.1) + (A17.2), (A12.1) + (A18.1), (A12.1) + (A18.2), (A12.1) +(A12.1) + (A17.1), (A12.1) + (A17.2), (A12.1) + (A18.1), (A12.1) + (A18.2), (A12 .1) +
(A19.1) , (A12.1) + (A19.2),(A19.1), (A12.1) + (A19.2),
(A12.2) + (A13.1), (A12.2) + (A13.2), (A12.2) + (A14.1), (A12.2) + (A14.2), (A12.2) +(A12.2) + (A13.1), (A12.2) + (A13.2), (A12.2) + (A14.1), (A12.2) + (A14.2), (A12 .2) +
(A15.1) , (A12.2) + (A15.2), (A12.2) + (A16.1), (A12.2) + (A16.2), (A12.2) + (A17.1),(A15.1), (A12.2) + (A15.2), (A12.2) + (A16.1), (A12.2) + (A16.2), (A12.2) + (A17 .1),
(A12.2) + (A17.2), (A12.2) + (A18.1), (A12.2) + (A18.2), (A12.2) + (A19.1), (A12.2) +(A12.2) + (A17.2), (A12.2) + (A18.1), (A12.2) + (A18.2), (A12.2) + (A19.1), (A12 .2) +
(A19.2)(A19.2)
(A13.1) + (A13.2), (A13.1) + (A14.1), (A13.1) + (A14.2), (A13.1) + (A15.1), (A13.1) +(A13.1) + (A13.2), (A13.1) + (A14.1), (A13.1) + (A14.2), (A13.1) + (A15.1), (A13 .1) +
(A15.2) , (A13.1) + (A16.1), (A13.1) + (A16.2), (A13.1) + (A17.1), (A13.1) + (A17.2),(A15.2), (A13.1) + (A16.1), (A13.1) + (A16.2), (A13.1) + (A17.1), (A13.1) + (A17 .2)
(A13.1) + (A18.1), (A13.1) + (A18.2), (A13.1) + (A19.1), (A13.1) + (A19.2),(A13.1) + (A18.1), (A13.1) + (A18.2), (A13.1) + (A19.1), (A13.1) + (A19.2),
(A13.2) + (A14.1), (A13.2) + (A14.2), (A13.2) + (A15.1), (A13.2) + (A15.2), (A13.2) +(A13.2) + (A14.1), (A13.2) + (A14.2), (A13.2) + (A15.1), (A13.2) + (A15.2), (A13 .2) +
(A16.1) , (A13.2) + (A16.2), (A13.2) + (A17.1), (A13.2) + (A17.2), (A13.2) + (A18.1),(A16.1), (A13.2) + (A16.2), (A13.2) + (A17.1), (A13.2) + (A17.2), (A13.2) + (A18 .1),
(A13.2) + (A18.2), (A13.2) + (A19.1), (A13.2) + (A19.2),(A13.2) + (A18.2), (A13.2) + (A19.1), (A13.2) + (A19.2),
(A14.1) + (A14.2), (A14.1) + (A15.1), (A14.1) + (A15.2), (A14.1) + (A16.1), (A14.1) +(A14.1) + (A14.2), (A14.1) + (A15.1), (A14.1) + (A15.2), (A14.1) + (A16.1), (A14 .1) +
(A16.2) , (A14.1) + (A17.1), (A14.1) + (A17.2), (A14.1) + (A18.1), (A14.1) + (A18.2),(A16.2), (A14.1) + (A17.1), (A14.1) + (A17.2), (A14.1) + (A18.1), (A14.1) + (A18 .2)
(A14.1) + (A19.1), (A14.1) + (A19.2),(A14.1) + (A19.1), (A14.1) + (A19.2),
(A14.2) + (A15.1), (A14.2) + (A15.2), (A14.2) + (A16.1), (A14.2) + (A16.2), (A14.2) +(A14.2) + (A15.1), (A14.2) + (A15.2), (A14.2) + (A16.1), (A14.2) + (A16.2), (A14 .2) +
(A17.1) , (A14.2) + (A17.2), (A14.2) + (A18.1), (A14.2) + (A18.2), (A14.2) + (A19.1),(A17.1), (A14.2) + (A17.2), (A14.2) + (A18.1), (A14.2) + (A18.2), (A14.2) + (A19 .1),
(A14.2) + (A19.2),(A14.2) + (A19.2),
(A15.1) + (A15.2), (A15.1) + (A16.1), (A15.1) + (A16.2), (A15.1) + (A17.1), (A15.1) +(A15.1) + (A15.2), (A15.1) + (A16.1), (A15.1) + (A16.2), (A15.1) + (A17.1), (A15 .1) +
(A17.2) , (A15.1) + (A18.1), (A15.1) + (A18.2), (A15.1) + (A19.1), (A15.1) + (A19.2),(A17.2), (A15.1) + (A18.1), (A15.1) + (A18.2), (A15.1) + (A19.1), (A15.1) + (A19 .2)
(A15.2) + (A16.1), (A15.2) + (A16.2), (A15.2) + (A17.1), (A15.2) + (A17.2), (A15.2) +(A15.2) + (A16.1), (A15.2) + (A16.2), (A15.2) + (A17.1), (A15.2) + (A17.2), (A15 .2) +
(A18.1) , (A15.2) + (A18.2), (A15.2) + (A19.1), (A15.2) + (A19.2),(A18.1), (A15.2) + (A18.2), (A15.2) + (A19.1), (A15.2) + (A19.2),
(A16.1) + (A16.2), (A16.1) + (A17.1), (A16.1) + (A17.2), (A16.1) + (A18.1), (A16.1) +(A16.1) + (A16.2), (A16.1) + (A17.1), (A16.1) + (A17.2), (A16.1) + (A18.1), (A16 .1) +
(A18.2) , (A16.1) + (A19.1), (A16.1) + (A19.2),(A18.2), (A16.1) + (A19.1), (A16.1) + (A19.2),
(A16.2) + (A17.1), (A16.2) + (A17.2), (A16.2) + (A18.1), (A16.2) + (A18.2), (A16.2) + (A19.1), (A16.2) + (A19.2),(A16.2) + (A17.1), (A16.2) + (A17.2), (A16.2) + (A18.1), (A16.2) + (A18.2), (A16 .2) + (A19.1), (A16.2) + (A19.2),
(A17.1) + (A17.2), (A17.1) + (A18.1), (A17.1) + (A18.2), (A17.1) + (A19.1), (A17.1) +(A17.1) + (A17.2), (A17.1) + (A18.1), (A17.1) + (A18.2), (A17.1) + (A19.1), (A17 .1) +
(A19.2),(A19.2),
(A17.2) + (A18.1), (A17.2) + (A18.2), (A17.2) + (A19.1), (A17.2) + (A19.2),(A17.2) + (A18.1), (A17.2) + (A18.2), (A17.2) + (A19.1), (A17.2) + (A19.2),
(A18.1) + (A18.2), (A18.1) + (A19.1), (A18.1) + (A19.2),(A18.1) + (A18.2), (A18.1) + (A19.1), (A18.1) + (A19.2),
(A18.2) + (A19.1), (A18.2) + (A19.2),(A19.1) + (A19.2).(A18.2) + (A19.1), (A18.2) + (A19.2), (A19.1) + (A19.2).
In einer bevorzugten Ausführungsform als Komponente a) z.B. verschiedene Phenylsulfonylhamstoffe der Formel (II) und/oder deren Salze miteinander kombiniert werden, z.B. Mesosulfuron-methyl + lodosulfuron-methyl, Mesosulfuron-methyl + lodosulfuron-methyl-Natrium, Mesosulfuron-methyl + Foramsulfuron, Mesosulfuron-methyl + Foramsulfuron-Natrium, Mesosulfuron-methyl-Natrium + lodosulfuron-methyl, Mesosulfuron- ethyl-Natrium + lodosulfuron-methyl-Natrium, Mesosulfuron-methyl-Natrium + Foramsulfuron, Mesosulfuron-methyl-Natrium + Foramsulfuron-Natrium, Foramsulfuron + lodosulfuron-methyl, Foramsulfuron + lodosulfuron-methyl-Natrium, Foramsulfuron-Natrium + lodosulfuron-methyl, Foramsulfuron-Natrium + lodosulfuron-methyl-Natrium.In a preferred embodiment as component a) e.g. different phenylsulfonylureas of the formula (II) and / or their salts are combined with one another, e.g. Mesosulfuron-methyl + iodosulfuron-methyl, mesosulfuron-methyl + iodosulfuron-methyl-sodium, mesosulfuron-methyl + foramsulfuron, mesosulfuron-methyl + foramsulfuron-sodium, mesosulfuron-methyl-sodium + iodosulfuron-methyl, mesosulfuron-ethyl-sodium + iodosulfuron methyl-sodium, mesosulfuron-methyl-sodium + foramsulfuron, mesosulfuron-methyl-sodium + foramsulfuron-sodium, foramsulfuron + iodosulfuron-methyl, foramsulfuron + iodosulfuron-methyl-sodium, foramsulfuron-sodium + iodosulfuron-methyl, foramsulfuron-sodium + iodosulfuron methyl-sodium.
Die Sulfonamide a) und deren Mischungen, z.B. die vorgenannten Wirkstoffmischungen von Phenylsulfonylharnstoffen der Formel (II) und/oder deren Salze, können mit einem oder mehreren Safenern kombiniert werden, insbesondere mit den Safenern Mefenpyr-diethyl (S1-1), Fenchlorazol-ethyl (S1-6), Isoxadifen- ethyl (S1-9), Cloquintocet-mexyl (S2-1) und (S3-1).The sulfonamides a) and their mixtures, e.g. the aforementioned active ingredient mixtures of phenylsulfonylureas of the formula (II) and / or their salts can be combined with one or more safeners, in particular with the safeners mefenpyr-diethyl (S1-1), fenchlorazol-ethyl (S1-6), isoxadifen-ethyl (S1-9), Cloquintocet-mexyl (S2-1) and (S3-1).
Sämtliche vorgenannten Kombinationen können auch einen oder mehrere agrochemische Wirkstoffe (e) enthalten, insbesondere ausgewählt aus der Gruppe (E1), (EU), (E1.2), (E1.3), (E1.4), (E1.5), (E2), (E2.1), (E2.2), (E2.3), (E2.4), (E2.5), (E2.6), (E2.7), (E2.8), (E2.9), (E3), (E3.1), (E3.2), (E3.3), (E4), (E4.1), (E4.2), (E5), (E5.1), (E5.2), (E6), (E6.1), (E6.2), (E6.3), (E6.4), (E6.5).All of the aforementioned combinations can also contain one or more agrochemical active substances (e), in particular selected from the group (E1), (EU), (E1.2), (E1.3), (E1.4), (E1.5 ), (E2), (E2.1), (E2.2), (E2.3), (E2.4), (E2.5), (E2.6), (E2.7), (E2.8), (E2.9), (E3), (E3.1), (E3.2), (E3.3), (E4), (E4.1), (E4.2), (E5), (E5.1), (E5.2), (E6), (E6.1), (E6.2), (E6.3), (E6.4), (E6.5).
Die als Komponente a) enthaltenen Phenylsulfonylaminocarbonyltriazolinone, insbesondere solche der Formel (I) wie Flucarbazone oder Propoxycarbazone, und Heteroarylsulfonylaminocarbonyltriazolinone, insbesondere solche der Formel (IV), (VI) und (VII) wie z.B. bekannt aus der WO 03/026427, z.B. die Verbindungen (A20.1), (A20.2), (A21.1), (A21.2), (A22.1), (A22.2), (A23.1), (A23.2), (A24.1), (A24.2), (A25.1), (A25.2), (A26.1), (A26.2), (A27.1), (A27.2), (A28.1), (A28.2), (A29.1), (A29.2), (A30.1), (A30.2), (A31.1), (A31.2), (A32.1), (A32.2), (A33.1), (A33.2), (A34.1), (A34.2), (A35.1), (A35.2), (A36.1), (A36.2), (A37.1), (A37.2), können auch ohne Zusatz von Sulfosuccinaten Ölsuspensionskonzentrate hoher chemischer und physikalischer Stabilität bilden. Solche Ölsuspensionskonzentrate sind ebenfalls Gegenstand der vorliegenden Erfindung.The phenylsulfonylaminocarbonyltriazolinones contained as component a), in particular those of the formula (I) such as flucarbazones or propoxycarbazones, and heteroarylsulfonylaminocarbonyltriazolinones, in particular those of the formulas (IV), (VI) and (VII), e.g. known from WO 03/026427, e.g. the compounds (A20.1), (A20.2), (A21.1), (A21.2), (A22.1), (A22.2), (A23.1), (A23.2), (A24.1), (A24.2), (A25.1), (A25.2), (A26.1), (A26.2), (A27.1), (A27.2), (A28 .1), (A28.2), (A29.1), (A29.2), (A30.1), (A30.2), (A31.1), (A31.2), (A32.1 ), (A32.2), (A33.1), (A33.2), (A34.1), (A34.2), (A35.1), (A35.2), (A36.1), (A36.2), (A37.1), (A37.2), can also form oil suspension concentrates with high chemical and physical stability without the addition of sulfosuccinates. Such oil suspension concentrates are also the subject of the present invention.
Sofern in den erfindungsgemäßen Olsuspensionskonzentraten als Komponente a) Mischungen mehrerer Sulfonamide enthalten sind, z.B. die vorstehend genannten Mischungen von Sulfonylharnstoffen der Formel (II) und/oder deren Salzen, liegt zumindest eines der Sulfonamide in suspendierter Form vor, es können auch alle Sulfonamide suspendiert vorliegen.If mixtures of several sulfonamides are present as component a) in the oil suspension concentrates according to the invention, e.g. the above-mentioned mixtures of sulfonylureas of the formula (II) and / or their salts, at least one of the sulfonamides is in suspended form; all sulfonamides can also be present in suspension.
Die erfindungsgemäßen Ölsuspensionskonzentrate können durch bekannte Verfahren, z.B. durch Vermischen der Komponenten hergestellt werden. So kann z.B. eine Vormischung hergestellt werden, wobei das Sulfosuccinat d) in dem organischen Lösungsmittel c) gelöst wird und dieser Lösung, gegebenenfalls weitere Hilfs- und Zusatzstoffe f) zugegeben werden. Dann werden gegebenenfalls verwendete lösliche agrochemische Wirkstoffe b) und e) in der Vormischung gelöst. Nach Abschluß des Lösungsprozesses wird festes Sulfonamid a) und gegebenenfalls verwendete unlösliche Wirkstoffe b) und e) in die Mischung suspendiert. Die grobe Suspension wird, gegebenenfalls nach einer Vorvermahlung, einer Feinvermahlung unterzogen. In einer anderen Ausführungsvariante wird festes Sulfonamid a), sowie gegebenenfalls verwendete unlösliche Komponenten b), e) und f), in eine Mischung aus dem organischen Lösungsmittel c) und dem Sulfosuccinat d) suspendiert und einer Vermahlung unterzogen. Gegebenenfalls verwendete lösliche Wirkstoffe b) und e) sowie Hilfs- und Zusatzstoffe aus f), die keiner Vermahlung bedürfen oder für den Mahlvorgang nicht notwendig sind, werden nach der Vermahlung zugesetzt.The oil suspension concentrates according to the invention can be prepared by known processes, for example by mixing the components. For example, a premix can be prepared, the sulfosuccinate d) being dissolved in the organic solvent c) and, if appropriate, further auxiliaries and additives f) being added to this solution. Then any soluble agrochemical active ingredients b) and e) used are dissolved in the premix. After the solution process is complete, solid sulfonamide a) and any insoluble active ingredients b) and e) used are suspended in the mixture. The coarse suspension is subjected to fine grinding, if necessary after pre-grinding. In another embodiment variant, solid sulfonamide a) and any insoluble components b), e) and f) used are suspended in a mixture of the organic solvent c) and the sulfosuccinate d) and subjected to grinding. Any soluble active ingredients b) and e) used, and auxiliaries and additives from f), which do not require grinding or are not necessary for the grinding process, are added after the grinding.
Zur Herstellung der Mischungen können gängige Mischapparate verwendet werden, die gegebenenfalls temperiert werden. Zur Vorvermahlung können z.B. Hochdruckhomogenisatoren oder nach dem Rotor-Stator Prinzip arbeitende Mühlen verwendet werden, wie Ultraturax-Homogenisatoren, z.B. der Fa. IKA, oder Zahnkolloidmühlen, z.B. der Fa. Puck. Für die Feinvermahlung können z.B. diskontinuierliche Perlmühlen, z.B. der Fa. Drais oder kontinuierliche Perlmühlen, der z.B. Fa. Bachofen verwendet werden. Je nach den Eigenschaften der eingesetzten Komponenten, sowie Verfahrens- und sicherheitstechnsichen Anforderungen und aus wirtschaftlichen Gründen, kann das Herstellverfahren angepaßt und gegebenenfalls auf eine Vorvermahlung oder auch auf eine Feinvermahlung verzichtet werden.Common mixers can be used to produce the mixtures, which can be tempered if necessary. For pre-grinding e.g. High pressure homogenizers or mills operating according to the rotor-stator principle are used, such as Ultraturax homogenizers, e.g. from IKA, or tooth colloid mills, e.g. from Puck. For fine grinding e.g. discontinuous bead mills, e.g. from Drais or continuous bead mills, e.g. Bachofen can be used. Depending on the properties of the components used, process and safety requirements and for economic reasons, the manufacturing process can be adapted and, if necessary, pre-grinding or fine grinding can be dispensed with.
Die zur Herstellung eingesetzten Komponenten a) bis f) können Wasser als Nebenbestandteil enthalten, welches sich in den erfindungsgemäßen Olsuspensionskonzentraten wiederfindet. Die erfindungsgemäßen Ölsuspensionskonzentrate können daher geringe Mengen von Wasser enthalten, im allgemeinen von 0 bis 5 Gew.%. Bevorzugterweise werden die erfindungsgemäßen Ölsuspensionskonzentrate keinem weiteren Trocknungsprozeß unterzogen.Components a) to f) used for the preparation can contain water as a secondary component, which is found in the oil suspension concentrates according to the invention. The oil suspension concentrates according to the invention can therefore contain small amounts of water, generally from 0 to 5% by weight. The oil suspension concentrates according to the invention are preferably not subjected to any further drying process.
Zur Anwendung können die erfindungsgemäßen Ölsuspensionskonzentrate gegebenenfalls in üblicher weise, z.B. zu Suspensionen, Emulsionen, Suspoemulsionen oder Lösungen, vorzugsweise von Suspensionen, verdünnt werden, z.B. mittels Wasser. Es kann vorteilhaft sein, erhaltenen Spritzbrühen weitere agrochemische Wirkstoffe (z.B. Tankmischpartner in Form entsprechender Formulierungen) und/oder zur Anwendung übliche Hilfs- und Zusatzstoffe, z.B. selbstemulgierende Öle wie Pflanzenöle oder Paraffinöle und/oder Düngemittel zuzugeben. Gegenstand der vorliegenden Erfindung sind daher auch solche herbiziden Mittel, auf Basis der erfindungsgemäßen Ölsuspensionskonzentrate.For use, the oil suspension concentrates according to the invention can optionally be diluted in a customary manner, for example to form suspensions, emulsions, suspoemulsions or solutions, preferably suspensions, for example by means of water. It may be advantageous to obtain further agrochemical active ingredients obtained from spray liquors (for example tank mixing partners in the form of corresponding formulations) and / or auxiliaries and additives customary for use, for example self-emulsifying oils such as vegetable oils or paraffin oils and / or fertilizers. The present invention therefore also relates to such herbicidal compositions based on the oil suspension concentrates according to the invention.
Die erfindungsgemäßen herbiziden Mittel weisen eine ausgezeichnete herbizide Wirksamkeit gegen ein breites Spektrum wirtschaftlich wichtiger mono- und dikotyler Schadpflanzen auf. Auch schwer bekämpfbare perennierende Unkräuter, die aus Rhizomen, Wurzelstöcken oder anderen Dauerorganen austreiben, werden gut erfaßt. Dabei können die Mittel z.B. im Vorsaat-, Vorauflauf- oder Nachauflaufverfahren ausgebracht werden. Im einzelnen seien beispielhaft einige Vertreter der mono- und dikotylen Unkrautflora genannt, die durch die erfindungsgemäßen herbiziden Mittel kontrolliert werden können, ohne daß durch die Nennung eine Beschränkung auf bestimmte Arten erfolgen soll.The herbicidal compositions according to the invention have excellent herbicidal activity against a broad spectrum of economically important mono- and dicotyledonous harmful plants. Perennial weeds that are difficult to control and that sprout from rhizomes, rhizomes or other permanent organs are also well recorded. The funds can e.g. are applied in the pre-sowing, pre-emergence or post-emergence process. In particular, some representatives of the monocotyledonous and dicotyledonous weed flora may be mentioned, which can be controlled by the herbicidal compositions according to the invention, without any restriction to certain species being mentioned.
Auf der Seite der monokotylen Unkrautarten werden z.B. Apera spica venti, Avena spp., Alopecurus spp., Brac iaria spp., Digitaria spp., Lolium spp., Echinochloa spp., Panicum spp., Phalaris spp., Poa spp., Setaria spp. sowie Bromus spp. wie Bromus catharticus, Bromus secalinus, Bromus erectus, Bromus tectorum und Bromus japonicus und Cyperusarten aus der annuellen Gruppe und auf selten der perennierenden Spezies Agropyron, Cynodon, Imperata sowie Sorghum und auch ausdauernde Cyperusarten gut erfaßt.On the side of the monocot weed species, e.g. Apera spica venti, Avena spp., Alopecurus spp., Brac iaria spp., Digitaria spp., Lolium spp., Echinochloa spp., Panicum spp., Phalaris spp., Poa spp., Setaria spp. and Bromus spp. such as Bromus catharticus, Bromus secalinus, Bromus erectus, Bromus tectorum and Bromus japonicus and Cyperus species from the annual group and rarely of the perennial species Agropyron, Cynodon, Imperata as well as Sorghum and also persistent Cyperus species.
Bei dikotylen Unkrautarten erstreckt sich das Wirkungsspektrum auf Arten wie z.B. Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp. wie Galium aparine, Ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp., Polygonum spp.,Sida spp., Sinapis spp., Solanum spp., Stellaria spp., Veronica spp. und Viola spp., Xanthium spp., auf der annuellen Seite sowie Convolvulus, Cirsium, Rumex und Artemisia bei den perennierenden Unkräutern.With dicotyledon weed species, the spectrum of activity extends to species such as Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp. such as Galium aparine, Ipomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp., Polygonum spp., Sida spp., Sinapis spp., Solanum spp., Stellaria spp., Veronica spp. and Viola spp., Xanthium spp., on the annual side, and convolvulus, cirsium, rumex and artemisia in the perennial weeds.
Unter den spezifischen Kulturbedingungen im Reis vorkommende Schadpflanzen wie z.B. Echinochloa, Sagittaria, Alisma, Eleocharis, Scirpus und Cyperus werden von den erfindungsgemäßen Mitteln ebenfalls hervorragend bekämpft. Werden die erfindungsgemäßen herbiziden Mittel vor dem Keimen auf die Erdoberfläche appliziert, so wird entweder das Auflaufen der Unkrautkeimlinge vollständig verhindert oder die Unkräuter wachsen bis zum Keimblattstadium heran, stellen jedoch dann ihr Wachstum ein und sterben schließlich nach Ablauf von drei bis vier Wochen vollkommen ab.Harmful plants occurring in the rice under the specific culture conditions, such as, for example, Echinochloa, Sagittaria, Alisma, Eleocharis, Scirpus and Cyperus, are also superbly combated by the agents according to the invention. If the herbicidal compositions according to the invention are applied to the surface of the earth before germination, either weed seedlings are prevented completely or the weeds grow to the cotyledon stage, but then stop growing and finally die completely after three to four weeks.
Bei Applikation der erfindungsgemäßen herbiziden Mittel auf die grünen Pflanzenteile im Nachauflaufverfahren tritt ebenfalls sehr rasch nach der Behandlung ein drastischer Wachstumsstop ein und die Unkrautpflanzen bleiben in dem zum Applikationszeitpunkt vorhandenen Wachstumsstadium stehen oder sterben nach einer gewissen Zeit ganz ab, so daß auf diese Weise eine für die Kulturpflanzen schädliche Unkrautkonkurrenz sehr früh und nachhaltig beseitigt wird.When the herbicidal compositions according to the invention are applied to the green parts of the plant in the post-emergence process, there is also a drastic growth stop very quickly after the treatment and the weed plants remain in the growth stage present at the time of application or die completely after a certain time, so that one for harmful crop competition is eliminated very early and sustainably.
Die erfindungsgemäßen herbiziden Mittel zeichnen sich durch eine schnell einsetzende und lang andauernde herbizide Wirkung aus. Die Regenfestigkeit der Wirkstoffe in den erfindungsgemäßen Kombinationen ist in der Regel günstig. Als besonderer Vorteil fällt ins Gewicht, daß die in den herbizide Mitteln verwendeten und wirksamen Dosierungen von herbiziden Verbindungen so gering eingestellt werden können, daß ihre Bodenwirkung optimal niedrig ist. Somit wird deren Einsatz nicht nur in empfindlichen Kulturen erst möglich, sondern Grundwasser- Kontaminationen werden praktisch vermieden. Durch die erfindungsgemäßen Kombination von Wirkstoffen wird eine erhebliche Reduzierung der nötigen Aufwandmenge der Wirkstoffe ermöglicht.The herbicidal compositions according to the invention are notable for a rapid onset and long-lasting herbicidal action. The rain resistance of the active ingredients in the combinations according to the invention is generally favorable. A particular advantage is the fact that the effective dosages of herbicidal compounds used in the herbicidal compositions can be set so low that their soil action is optimally low. This makes their use not only possible in sensitive crops, but groundwater contamination is practically avoided. The combination of active substances according to the invention enables a considerable reduction in the amount of active substances required.
Die genannten Eigenschaften und Vorteile sind in der praktischen Unkrautbekämpfung von Nutzen, um landwirtschaftliche Kulturen von unerwünschten Konkurrenzpflanzen freizuhalten und damit die Erträge qualitativ und quantitativ zu sichern und/oder zu erhöhen. Der technische Standard wird durch diese neuen Mittel hinsichtlich der beschriebenen Eigenschaften deutlich übertroffen.The properties and advantages mentioned are useful in practical weed control in order to keep agricultural crops free of undesired competing plants and thus to ensure and / or increase the yields qualitatively and quantitatively. These new means significantly exceed the technical standard in terms of the properties described.
Obgleich die erfindungsgemäßen herbiziden Mittel eine ausgezeichnete herbizide Aktivität gegenüber mono- und dikotylen Unkräutern aufweisen, werden Kulturpflanzen wirtschaftlich bedeutender Kulturen z.B. zweikeimblättriger Kulturen wie Soja, Baumwolle, Raps, Zuckerrüben, oder Gramineen-Kulturen wie Weizen, Gerste, Roggen, Hafer, Hirse, Reis oder Mais, nur unwesentlich oder gar nicht geschädigt. Die vorliegenden Verbindungen eignen sich aus diesen Gründen sehr gut zur selektiven Bekämpfung von unerwünschtem Pflanzenwuchs in landwirtschaftlichen Nutzpflanzungen oder in Zierpflanzungen.Although the herbicidal compositions according to the invention have excellent herbicidal activity against mono- and dicotyledon weeds, they will Cultivated plants of economically important crops, for example dicotyledonous crops such as soybean, cotton, rapeseed, sugar beet, or Gramineae crops such as wheat, barley, rye, oats, millet, rice or corn, are only insignificantly damaged or not at all. For these reasons, the present compounds are very suitable for the selective control of undesired plant growth in agricultural crops or in ornamental crops.
Darüber hinaus weisen die erfindungsgemäßen herbiziden Mittel hervorragende wachstumsregulatorische Eigenschaften bei Kulturpflanzen auf. Sie greifen regulierend in den pflanzeneigenen Stoffwechsel ein und können damit zur gezielten Beeinflussung von Pflanzeninhaltsstoffen und zur Ernteerleichterung wie z.B. durch Auslösen von Desikkation und Wuchsstauchung eingesetzt werden. Desweiteren eignen sie sich auch zur generellen Steuerung und Hemmung von unerwünschtem vegetativen Wachstum, ohne dabei die Pflanzen abzutöten. Eine Hemmung des vegetativen Wachstums spielt bei vielen mono- und dikotylen Kulturen eine große Rolle, da das Lagern hierdurch verringert oder völlig verhindert werden kann.In addition, the herbicidal compositions according to the invention have excellent growth-regulating properties in crop plants. They intervene regulating the plant's own metabolism and can thus be used to influence plant constituents in a targeted manner and to facilitate harvesting, e.g. by triggering desiccation and stunted growth. Furthermore, they are also suitable for general control and inhibition of undesirable vegetative growth without killing the plants. Inhibiting vegetative growth plays a major role in many monocotyledonous and dicotyledonous crops, as this can reduce or completely prevent storage.
Aufgrund ihrer herbiziden und pflanzenwachstumsregulatorischen Eigenschaften können die erfindungsgemäßen herbiziden Mittel auch zur Bekämpfung von Schadpflanzen in Kulturen von bekannten oder noch zu entwickelnden gentechnisch veränderten Pflanzen eingesetzt werden. Die transgenen Pflanzen zeichnen sich in der Regel durch besondere vorteilhafte Eigenschaften aus, beispielsweise durch Resistenzen gegenüber bestimmten Pestiziden, vor allem bestimmten Herbiziden, Resistenzen gegenüber Pflanzenkrankheiten oder Erregern von Pflanzenkrankheiten wie bestimmten Insekten oder Mikroorganismen wie Pilzen, Bakterien oder Viren. Andere besondere Eigenschaften betreffen z. B. das Erntegut hinsichtlich Menge, Qualität, Lagerfähigkeit, Zusammensetzung und spezieller Inhaltsstoffe. So sind transgene Pflanzen mit erhöhtem Stärkegehalt oder veränderter Qualität der Stärke oder solche mit anderer Fettsäurezusammensetzung des Ernteguts bekannt.Because of their herbicidal and plant growth regulatory properties, the herbicidal compositions according to the invention can also be used to control harmful plants in crops of known or still to be developed genetically modified plants. The transgenic plants are generally distinguished by special advantageous properties, for example resistance to certain pesticides, especially certain herbicides, resistance to plant diseases or pathogens of plant diseases such as certain insects or microorganisms such as fungi, bacteria or viruses. Other special properties concern e.g. B. the crop in terms of quantity, quality, shelf life, composition and special ingredients. Transgenic plants with an increased starch content or altered starch quality or with a different fatty acid composition of the crop are known.
Bevorzugt ist die Anwendung der erfindungsgemäßen Mittel in wirtschaftlich bedeutenden transgenen Kulturen von Nutz- und Zierpflanzen, z. B. von Gramineen- Kulturen wie Weizen, Gerste, Roggen, Hafer, Hirse, Reis und Mais oder auch Kulturen von Zuckerrübe, Baumwolle, Soja, Raps, Kartoffel, Tomate, Erbse und anderen Gemüsesorten. Vorzugsweise können die erfindungsgemäßen Mittel als Herbizide in Nutzpflanzenkulturen eingesetzt werden, welche gegenüber den phytotoxischen Wirkungen der Herbizide resistent sind bzw. gentechnisch resistent gemacht worden sind.Preferred is the use of the agents according to the invention in economically important transgenic crops of useful and ornamental plants, for. B. from Gramineen- Cultures such as wheat, barley, rye, oats, millet, rice and corn or also crops of sugar beet, cotton, soybean, rapeseed, potato, tomato, pea and other vegetables. The agents according to the invention can preferably be used as herbicides in crops which are resistant to the phytotoxic effects of the herbicides or have been made resistant to genetic engineering.
Bei der Anwendung der erfindungsgemäßen herbiziden Mittel in transgenen Kulturen treten neben den in anderen Kulturen zu beobachtenden Wirkungen gegenüber Schadpflanzen oftmals Wirkungen auf, die für die Applikation in der jeweiligen transgenen Kultur spezifisch sind, beispielsweise ein verändertes oder speziell erweitertes Unkrautspektrum, das bekämpft werden kann, veränderte Aufwandmengen, die für die Applikation eingesetzt werden können, vorzugsweise gute Kombinierbarkeit mit den Herbiziden, gegenüber denen die transgene Kultur resistent ist, sowie Beeinflussung von Wuchs und Ertrag der transgenen Kulturpflanzen.When the herbicidal compositions according to the invention are used in transgenic crops, in addition to the effects on harmful plants which can be observed in other crops, there are often effects which are specific to the application in the respective transgenic crop, for example a changed or specially expanded weed spectrum which can be controlled, changed application rates that can be used for the application, preferably good combinability with the herbicides to which the transgenic crop is resistant, and influencing the growth and yield of the transgenic crop plants.
Gegenstand der vorliegenden Erfindung ist weiterhin auch ein Verfahren zur Bekämpfung von unerwünschtem Pflanzenwuchs, vorzugsweise in Pflanzenkulturen wie Getreide (z.B. Weizen, Gerste, Roggen, Hafer, Reis, Mais, Hirse), Zuckerrübe, Zuckerrohr, Raps, Baumwolle und Soja, besonders bevorzugt in monokotylen Kulturen wie Getreide, z.B. Weizen, Gerste, Roggen, Hafer, Kreuzungen davon wie Triticale, Reis, Mais und Hirse, wobei man ein oder mehrere erfindungsgemäße herbizide Mittel auf die Schadpflanzen, Pflanzenteile, Pflanzensamen oder die Fläche auf der die Pflanzen wachsen, z.B. die Anbaufläche appliziert.The present invention furthermore also relates to a process for controlling unwanted vegetation, preferably in crops such as cereals (for example wheat, barley, rye, oats, rice, corn, millet), sugar beet, sugar cane, rape, cotton and soybeans, particularly preferably in monocotyledon crops such as cereals, e.g. Wheat, barley, rye, oats, crosses thereof such as triticale, rice, corn and millet, one or more herbicidal compositions according to the invention being applied to the harmful plants, parts of plants, plant seeds or the area on which the plants grow, e.g. applied the acreage.
Die Pflanzenkulturen können auch gentechnisch verändert oder durch Mutationsselektion erhalten sein und sind bevorzugt tolerant gegenüber Acetolactatsynthase (ALS)-Inhibitoren.The plant cultures can also be genetically modified or obtained by mutation selection and are preferably tolerant of acetolactate synthase (ALS) inhibitors.
Das Ölsuspensionskonzentrat der vorliegenden Erfindung weist eine ausgezeichnete chemische Stabilität während der Herstellung und Lagerung auf und eignet sich insbesondere auch für Kombinationen von Wirkstoffen mit unterschiedlichen physikalisch-chemischen Eigenschaften, z. B. eines in organischen Lösungsmitteln schwerlöslichen herbiziden Phenylsulfonamids mit einem löslichen Safener und gegebenenfalls weiteren löslichen agrochemischen Wirkstoffen. Außerdem weist das Ölsuspensionskonzentrat eine ausgezeichnete physikalische Stabilität, eine gute Applizierbarkeit und Anwenderfreundlichkeit, sowie eine hohe biologische Effektivität und Selektivität auf.The oil suspension concentrate of the present invention has excellent chemical stability during manufacture and storage and is suitable especially for combinations of active substances with different physico-chemical properties, e.g. B. a poorly soluble in organic solvents herbicidal phenylsulfonamide with a soluble safener and optionally other soluble agrochemical active ingredients. In addition, the oil suspension concentrate has excellent physical stability, good applicability and user-friendliness, as well as high biological effectiveness and selectivity.
Wenn nicht anders beschrieben wurden die in den nachfolgenden Beispielen genannten Ölsuspensionskonzentrate wie folgt hergestellt: Es wurde eine Vormischung hergestellt wobei, das Sulfosuccinat d) in dem Lösungsmittel c) gelöst wurde und dieser Lösung, die weiteren Hilfs- und Zusatzstoffe f) zugegeben wurden. Dann wurde der Safener b) in der Vormischung gelöst. Nach Abschluß des Lösungsprozesses wurde festes Sulfonamid a) in die Mischung suspendiert. Die grobe Suspension wurde, nach einer Vorvermahlung, einer Feinvermahlung unterzogen.Unless otherwise described, the oil suspension concentrates mentioned in the examples below were prepared as follows: A premix was prepared, the sulfosuccinate d) being dissolved in the solvent c) and the further auxiliaries and additives f) being added to this solution. Then the safener b) was dissolved in the premix. After the solution process was complete, solid sulfonamide a) was suspended in the mixture. The coarse suspension was subjected to fine grinding after pre-grinding.
Die in den nachfolgenden Beispielen verwendeten Abkürzungen haben folgende Bedeutung:The abbreviations used in the following examples have the following meaning:
lodosulfuron = 3-(4-Methoxy-6-methyl-1 ,3,5-triazin-2-yl)-1-(2- methoxycarbonyl-5-iod-phenylsulfonyl)-harnstoffIodosulfuron = 3- (4-methoxy-6-methyl-1, 3,5-triazin-2-yl) -1- (2-methoxycarbonyl-5-iodophenylsulfonyl) urea
Natriumsalz Thifensulfuron = 3-(4-Methoxy-6-methyl-1 ,3,5-triazin-2-yl-)-1-(2- methoxycarbonyl-thiophensulfonyl)-hamstoffSodium salt thifensulfuron = 3- (4-methoxy-6-methyl-1, 3,5-triazin-2-yl -) - 1- (2-methoxycarbonylthiophensulfonyl) urea
Natriumsalz Mefenpyr = 1-(2,4-Dichlorphenyl)-5-(ethoxycarbonyl)-5-methyl-2- pyrazolin-3-carbonsäureethylester Bentone® 34 = modifiziertes Schichtsilikat, ElementisSodium salt mefenpyr = 1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylate Bentone ® 34 = modified layered silicate, Elementis
Edenor® MESU = Rapsölmethylester, CognisEdenor ® MESU = rapeseed oil methyl ester, Cognis
Emulsogen® EL-400 = polyethoxyliertes Rizinusöl mit 40 EinheitenEmulsogen ® EL-400 = polyethoxylated castor oil with 40 units
Ethylenoxid, Clariant Genapol® PF10 Polyethylenoxid-Polypropylenoxid-Blockcopolymer mitEthylene oxide, Clariant Genapol ® PF10 polyethylene oxide-polypropylene oxide block copolymer with
10% Einheiten Ethylenoxid, Clariant10% units of ethylene oxide, Clariant
Genapol® V4739 polyethoxyliertes iso-Tridecanol mit 6 EinheitenGenapol ® V4739 polyethoxylated iso-tridecanol with 6 units
Ethylenoxid, methoxy-verkappt, ClariantEthylene oxide, methoxy-capped, Clariant
Jeffsol® PC Propylencarbonat, Huntsman Solvesso® 200 aromatisches Mineralöl (Siedebereich 219-281 °C),Jeffsol ® PC propylene carbonate, Huntsman Solvesso ® 200 aromatic mineral oil (boiling range 219-281 ° C),
ExxonExxon
Thixatrol® ST Thixothropiermittel auf Basis eines Riziniusölderivates Triton® GR-7M E Di(2-Ethylhexyl)sulfosuccinat Natriumsalz in aromatischem Lösungsmittel, Union CarbideThixatrol ® ST Thixothropiermittel based on a castor oil derivative Triton ® GR-7M E Di (2-ethylhexyl) sulfosuccinate sodium salt in aromatic solvent, Union Carbide
8W40°C achtwöchiger Lagerversuch bei 40°C8W40 ° C eight-week storage test at 40 ° C
Beispiel 1example 1
Herstellung eines ÖlsuspensionskonzentratsPreparation of an oil suspension concentrate
Die Konzentration an lodosulfuron wurde mittels HPLC vor und nach der Herstellung des Ölsuspensionskonzentrats bestimmt.The concentration of iodosulfuron was determined by means of HPLC before and after the preparation of the oil suspension concentrate.
Tabelle 1 : Chemische Stabilität der Komponente a) bei der Herstellung (alle Angaben in Gramm)Table 1: Chemical stability of component a) during production (all data in grams)
Figure imgf000103_0001
Beispiel 2:
Figure imgf000103_0001
Example 2:
Herstellung und Lagerung eines ÖlsuspensionskonzentratsProduction and storage of an oil suspension concentrate
Die Konzentration an lodosulfuron wurde mittels HPLC vor und nach der Herstellung des Ölsuspensionskonzentrats sowie nach 8-wöchiger Lagerung bei 40°C bestimmt.The concentration of iodosulfuron was determined by means of HPLC before and after the preparation of the oil suspension concentrate and after 8 weeks of storage at 40 ° C.
Tabelle 2: Chemische Stabilität der Komponente a), bei Herstellung und Lagerung (alle Angaben in Gew.%)Table 2: Chemical stability of component a), during manufacture and storage (all figures in% by weight)
Figure imgf000104_0001
Beispiel 3:
Figure imgf000104_0001
Example 3:
Herstellung eines ÖlsuspensionskonzentratsPreparation of an oil suspension concentrate
Die Konzentration an Thifensulfuron wurde mittels HPLC vor und nach der Herstellung des Ölsuspensionskonzentrats bestimmt.The concentration of thifensulfuron was determined by means of HPLC before and after the preparation of the oil suspension concentrate.
Figure imgf000105_0001
Figure imgf000105_0001
Das erfindungsgemäße Beispiel 3.2 zeigte eine signifikant höhere chemische Stabilität als das Vergleichsbeispiel 3.1. Example 3.2 according to the invention showed a significantly higher chemical stability than comparative example 3.1.

Claims

Patentansprüche: claims:
1. Ölsuspensionskonzentrat, enthaltend a) ein oder mehrere herbizide Wirkstoffe aus der Gruppe der Sulfonamide, in suspendierter Form, b) ein oder mehrere Safener, c) ein oder mehrere organische Lösungsmittel, und d) ein oder mehrere Sulfosuccinate.1. Oil suspension concentrate containing a) one or more herbicidal active ingredients from the group of the sulfonamides, in suspended form, b) one or more safeners, c) one or more organic solvents, and d) one or more sulfosuccinates.
2. Ölsuspensionskonzentrat gemäß Anspruch 1 , worin als Komponente a) enthalten sind, ein oder mehrere herbizide Wirkstoffe aus der Gruppe der Phenylsulfonamide, vorzugsweise der Phenylsulfonylaminocarbonyltriazolinone und Phenylsulfonylhamstoffe, oder der Heteroarylsulfonamide, vorzugsweise der Heteroarylulfonylaminocarbonyltriazolinone und Heteroarylsulfonylharnstoffe.2. Oil suspension concentrate according to claim 1, which contains as component a) one or more herbicidal active compounds from the group of the phenylsulfonamides, preferably the phenylsulfonylaminocarbonyltriazolinones and phenylsulfonylureas, or the heteroarylsulfonamides, preferably the heteroarylulfonylaminocarbonyltrarylsulfones and heteroarylons.
3. Ölsuspensionskonzentrat gemäß Anspruch 1 oder 2, worin als Komponente b) enthalten sind, ein oder mehrere Safener aus der Gruppe Dichlorphenylpyrazolin-3- carbonsäure und ihre Ester, 5,5 -Diphenyl-2-isoxazolin-3-carbonsäure ihre Ester und 8-Chinolinoxyessigsäure und ihre Ester.3. Oil suspension concentrate according to claim 1 or 2, which contains as component b), one or more safeners from the group dichlorophenylpyrazoline-3-carboxylic acid and its esters, 5,5-diphenyl-2-isoxazoline-3-carboxylic acid, its esters and 8 -Chinolinoxyacetic acid and its esters.
4. Ölsuspensionskonzentrat gemäß einem oder mehreren der Ansprüche 1 bis 3, worin als Komponente c) enthalten sind, ein oder mehrere Lösungsmittel aus der Gruppe unsubstituierter oder substituierte Kohlenwasserstoffe, aprotische polare Lösungsmittel und Fettsäureester.4. Oil suspension concentrate according to one or more of claims 1 to 3, which contains as component c), one or more solvents from the group of unsubstituted or substituted hydrocarbons, aprotic polar solvents and fatty acid esters.
5. Ölsuspensionskonzentrat gemäß einem oder mehreren der Ansprüche 1 bis 4, worin als Komponente d) enthalten sind, ein oder mehrere Sulfosuccinate aus der Gruppe der Mono- und Diester der Sulfobernsteinsäure.5. Oil suspension concentrate according to one or more of claims 1 to 4, which contains as component d), one or more sulfosuccinates from the group of the mono- and diesters of sulfosuccinic acid.
6. Ölsuspensionskonzentrat gemäß gemäß einem oder mehreren der Ansprüche 1 bis 5, zusätzlich enthaltend e) einen oder mehrere von a) und b) verschiedene agrochemische Wirkstoffe und/oder f) übliche Hilfs- und Zusatzstoffe. 6. Oil suspension concentrate according to one or more of claims 1 to 5, additionally containing e) one or more agrochemical active substances different from a) and b) and / or f) customary auxiliaries and additives.
7. Verfahren zur Herstellung eines Ölsuspensionskonzentrats gemäß einem oder mehreren der Ansprüche 1 bis 6, worin die Komponenten gemischt und gegebenenfalls vermahlt werden.7. A process for the preparation of an oil suspension concentrate according to one or more of claims 1 to 6, wherein the components are mixed and optionally ground.
8. Verfahren zur Bekämpfung von Schadpflanzen, worin eine wirksame Menge eines Ölsuspensionskonzentrats gemäß einem oder mehreren der Ansprüche 1 bis 6 auf die Schadpflanzen, Teile der Pflanzen, Pflanzensamen, die Fläche auf der Pflanzen wachsen appliziert wird.8. A method for controlling harmful plants, wherein an effective amount of an oil suspension concentrate according to one or more of claims 1 to 6 is applied to the harmful plants, parts of the plants, plant seeds, the area on which the plants grow.
9. Verwendung eines Ölsuspensionskonzentrats gemäß einem oder mehreren der Ansprüche 1 bis 6, zur Bekämpfung von Schadpflanzen.9. Use of an oil suspension concentrate according to one or more of claims 1 to 6, for controlling harmful plants.
10. Verwendung eines Ölsuspensionskonzentrats gemäß einem oder mehreren der Ansprüche 1 bis 6, zur Herstellung eines herbiziden Mittels.10. Use of an oil suspension concentrate according to one or more of claims 1 to 6, for the preparation of a herbicidal composition.
11. Verwendung gemäß Anspruch 10, worin das herbizide Mittel eine Suspension, Emulsion, Suspoemulsion oder eine Lösung ist.11. Use according to claim 10, wherein the herbicidal composition is a suspension, emulsion, suspoemulsion or a solution.
12. Herbizides Mittel, enthaltend ein Ölsuspensionskonzentrat gemäß einem oder mehreren der Ansprüche 1 bis 6.12. Herbicidal composition containing an oil suspension concentrate according to one or more of claims 1 to 6.
13. Verfahren zur Bekämpfung von Schadpflanzen, worin eine wirksame Menge eines herbiziden Mittels gemäß Anspruch 12 auf die Schadpflanzen, Teile der Pflanzen, Pflanzensamen, die Fläche auf der Pflanzen wachsen appliziert wird.13. A method for combating harmful plants, wherein an effective amount of a herbicidal composition according to claim 12 is applied to the harmful plants, parts of the plants, plant seeds, the area on which the plants grow.
14. Verwendung eines herbiziden Mittels gemäß Anspruch 12, zur Bekämpfung von Schadpflanzen. 14. Use of a herbicidal composition according to claim 12, for controlling harmful plants.
PCT/EP2003/013389 2002-12-13 2003-11-28 Oil suspension concentrate WO2004054364A1 (en)

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CA002509586A CA2509586A1 (en) 2002-12-13 2003-11-28 Oil suspension concentrate
JP2005502419A JP4810228B2 (en) 2002-12-13 2003-11-28 Oily suspension
EA200500915A EA012031B1 (en) 2002-12-13 2003-11-28 Herbicidal oil suspension concentrate,
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TR2018/07562T TR201807562T4 (en) 2003-11-28 2004-11-19 Oily suspension concentrate.
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DK04819206.6T DK1689236T3 (en) 2003-11-28 2004-11-19 OIL SUSPENSION CONCENTRATE
ES04819206.6T ES2678414T3 (en) 2003-11-28 2004-11-19 Concentrate to suspend in oils
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RU2006122781/04A RU2399205C2 (en) 2003-11-28 2004-11-19 Oil suspension concentrate
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ARP040104415A AR046729A1 (en) 2003-11-28 2004-11-26 CONCENTRATE OF TIENIL-SULFONAMIDS TO SUSPEND IN OILS
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EP1571908A1 (en) 2005-09-14
JP2006509836A (en) 2006-03-23
MXPA05006211A (en) 2005-08-19
ES2532907T3 (en) 2015-04-01
NZ540693A (en) 2007-04-27
US20050032647A1 (en) 2005-02-10
BR0317271A (en) 2005-11-08
EA012031B1 (en) 2009-06-30
CA2509586A1 (en) 2004-07-01
AR042439A1 (en) 2005-06-22
SI1571908T1 (en) 2015-04-30
PL377629A1 (en) 2006-02-06
AU2003303027A1 (en) 2004-07-09
PT1571908E (en) 2015-03-30
HRP20050530A2 (en) 2006-07-31
EA200500915A1 (en) 2005-12-29
KR20050085624A (en) 2005-08-29
JP2011153161A (en) 2011-08-11
JP4810228B2 (en) 2011-11-09
TW200418375A (en) 2004-10-01
AU2003303027B2 (en) 2010-07-29

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