WO2004046207A3 - Polyolefin production - Google Patents

Polyolefin production Download PDF

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Publication number
WO2004046207A3
WO2004046207A3 PCT/EP2003/013077 EP0313077W WO2004046207A3 WO 2004046207 A3 WO2004046207 A3 WO 2004046207A3 EP 0313077 W EP0313077 W EP 0313077W WO 2004046207 A3 WO2004046207 A3 WO 2004046207A3
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WO
WIPO (PCT)
Prior art keywords
atom
cyclopentadienyl
group
attached
groups
Prior art date
Application number
PCT/EP2003/013077
Other languages
French (fr)
Other versions
WO2004046207A2 (en
Inventor
Abbas Razavi
Original Assignee
Atofina Res Sa
Abbas Razavi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina Res Sa, Abbas Razavi filed Critical Atofina Res Sa
Priority to AU2003292067A priority Critical patent/AU2003292067A1/en
Priority to US10/535,520 priority patent/US20060148643A1/en
Priority to EP03767597A priority patent/EP1565499A2/en
Priority to JP2004552696A priority patent/JP2006506496A/en
Publication of WO2004046207A2 publication Critical patent/WO2004046207A2/en
Publication of WO2004046207A3 publication Critical patent/WO2004046207A3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Abstract

Provided is a catalyst component for producing a polyolefin, which catalyst component comprises a metallocene catalyst having a structure according to a formula (I): Cp1Cp2R”MQp wherein Cp1 and Cp2 are each independently a cyclopentadienyl derivative which may be substituted or unsubstituted and are selected from cyclopentadienyl groups, indenyl groups and fluorenyl groups, provided that at least one of the cyclopentadienyl derivatives comprises an N atom or a P atom in it cyclopentadienyl ring; R' is a structural bridge to impart stereorigidity between Cp1 and Cp2; and when only one of Cp1 and Cp2 comprises a P atom in its cyclopentadienyl ring, R' is attached to that phosphorous atom, or is attached to a carbon atom in the cylopentadienyl ring distal to that phosphorous atom; and when one of Cp1 or Cp2 comprises an indenyl group and the other of Cp1 and Cp2 comprises an indolyl group, R' is attached either directly to the N atom of the indolyl group or to a carbon atom that is vicinal to the N atom; M is a metal from Group IIIB, IVB, VB or VIB; Q is a hydrocarbyl group having from 1-20 carbon atoms, or a halogen; and p is the valence of M minus 2.
PCT/EP2003/013077 2002-11-20 2003-11-19 Polyolefin production WO2004046207A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU2003292067A AU2003292067A1 (en) 2002-11-20 2003-11-19 Polyolefin production
US10/535,520 US20060148643A1 (en) 2002-11-20 2003-11-19 Polyolefin production
EP03767597A EP1565499A2 (en) 2002-11-20 2003-11-19 Polyolefin production
JP2004552696A JP2006506496A (en) 2002-11-20 2003-11-19 Polyolefin production

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02079921.9 2002-11-20
EP02079921A EP1422249A1 (en) 2002-11-20 2002-11-20 New metallocene catalyst system

Publications (2)

Publication Number Publication Date
WO2004046207A2 WO2004046207A2 (en) 2004-06-03
WO2004046207A3 true WO2004046207A3 (en) 2004-08-26

Family

ID=32187244

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/013077 WO2004046207A2 (en) 2002-11-20 2003-11-19 Polyolefin production

Country Status (7)

Country Link
US (1) US20060148643A1 (en)
EP (2) EP1422249A1 (en)
JP (1) JP2006506496A (en)
KR (1) KR20050083899A (en)
CN (1) CN100379768C (en)
AU (1) AU2003292067A1 (en)
WO (1) WO2004046207A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7687744B2 (en) 2002-05-13 2010-03-30 S.C. Johnson & Son, Inc. Coordinated emission of fragrance, light, and sound
CN1820543B (en) 2003-02-07 2010-11-17 约翰逊父子公司 Diffuser with light emitting diode nightlight
US7416766B2 (en) 2005-08-16 2008-08-26 S.C. Johnson & Son, Inc. Bottles made from metallocene polypropylene for delivery of fragrances
KR102073252B1 (en) 2016-12-05 2020-02-04 주식회사 엘지화학 Catalyst composition for polymerizing olefin copolymer and preparation method of olefin copolymer

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0741145A1 (en) * 1995-05-02 1996-11-06 Sumitomo Chemical Company Limited Olefin polymerization catalyst and process for producing polyolefin using the same
WO1998001487A1 (en) * 1996-07-05 1998-01-15 Bayer Aktiengesellschaft Method for producing elastomers

Family Cites Families (15)

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US3642406A (en) * 1971-01-07 1972-02-15 Baker Perkins Inc Mixing, extruding, and severing apparatus
US3730663A (en) * 1971-06-25 1973-05-01 Cities Service Co Pelletizer
US4416606A (en) * 1980-10-22 1983-11-22 Mitsubishi Gas Chemical Company, Inc. Apparatus for granulating sodium percarbonate
JPS5887013A (en) * 1981-11-18 1983-05-24 Japan Steel Works Ltd:The Continuous kneading and granulating apparatus
DE3332629A1 (en) * 1983-09-09 1985-03-28 Hermann Berstorff Maschinenbau Gmbh, 3000 Hannover METHOD AND DEVICE FOR POWDERING POLYMERS
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
JP2636036B2 (en) * 1989-03-06 1997-07-30 花王株式会社 Method and apparatus for continuous granulation of high-density detergent particles
DE4010533A1 (en) * 1990-04-02 1991-10-10 Henkel Kgaa Prodn. of high-density detergent granules
US5240400A (en) * 1990-12-17 1993-08-31 Fuji Paudal Kabushiki Kaisha Screw-type extrusion granulating apparatus, especially for producing very fine granules
EP0638593A1 (en) * 1993-08-02 1995-02-15 Shell Internationale Researchmaatschappij B.V. Catalyst compositions
JPH0920802A (en) * 1995-05-02 1997-01-21 Sumitomo Chem Co Ltd Catalyst for polymerizing olefin (co)polymer and production of olefin (co)polymer
CA2204803C (en) * 1997-05-08 2005-11-15 Nova Chemicals Ltd. Process to prepare bridged phosphole-cyclopentadienyl compounds
CA2215444C (en) * 1997-09-15 2005-08-02 Stephen John Brown Catalyst having a ketimide ligand
US6499984B1 (en) * 2000-05-22 2002-12-31 Warner-Lambert Company Continuous production of pharmaceutical granulation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0741145A1 (en) * 1995-05-02 1996-11-06 Sumitomo Chemical Company Limited Olefin polymerization catalyst and process for producing polyolefin using the same
WO1998001487A1 (en) * 1996-07-05 1998-01-15 Bayer Aktiengesellschaft Method for producing elastomers

Also Published As

Publication number Publication date
EP1422249A1 (en) 2004-05-26
AU2003292067A1 (en) 2004-06-15
EP1565499A2 (en) 2005-08-24
CN1711288A (en) 2005-12-21
CN100379768C (en) 2008-04-09
KR20050083899A (en) 2005-08-26
US20060148643A1 (en) 2006-07-06
JP2006506496A (en) 2006-02-23
WO2004046207A2 (en) 2004-06-03

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