WO2004039456A1

WO2004039456A1 - Method for neutralising toxic substances, pesticides and the hydrolysates thereof and agent for carrying out said method

Info

Publication number: WO2004039456A1
Application number: PCT/RU2002/000528
Authority: WO
Inventors: Viktor Stanislavovich Polyakov; Valeriy Vasilievich Ermilov; Sergey Ivanovich Malekin
Original assignee: Veckis Industries Ltd.
Priority date: 2002-11-01
Filing date: 2002-12-10
Publication date: 2004-05-13
Also published as: AU2002365173A1

Abstract

The invention relates to technology for recycling environmental toxicants, mainly chemical weapons (toxic substances), pesticides and the hydrolysis products thereof. The inventive method makes it possible to destroy the toxic substances, pesticides and the hydrolysates thereof associated with a subsequent biodegradation of thus obtained products and can be used for a large range of environmental toxicants. Said method can be also used for rehabilitation of lands and objects contaminated by toxic substances and pesticides. In the inventive variants, the inventive agent for chemical neutralisation of the toxic substances, pesticides and the hydrolysates thereof is embodied in the form of an amino-acid agent. The chemical neutralisation of the toxicity of the environmental toxicants is carried out by the use of said amino acid agent containing an amine acid or a mixture of aminoacids and peptides, or the derivatives thereof, or the mixture thereof in a water or water-organic medium. Said agent can be also embodied in the form of products of hydrolysis of protein-containing industrial wastes.

Description

"Method of disposal of hazardous substances, pesticides and their use"

ΑBLΑSΑΤ ΤΕΧΗИΚИ, Κ ΚΟΤΟΡΟИ ΟΤΗΟСИΤСЯСЯ ПЫББИИΕ

The invention is subject to the processing technology of the processors,

Essential, chemical weapons (hazardous substances), narcotics,

HYDROGEN PRODUCTS FOR COMPOUNDS AND PESTICIDES.

ON JANUARY 1993 YEARS SUPPLIERS MORE THAN 130 STATES SIGNED

FINAL ACT OF THE AGREEMENT ON CHEMICAL ARMS. in accordance with

All products, utilization, distribution and storage are all required.

species of chemical weapons and equipment and their delivery and support

destruction of existing supplies of chemical weapons in 2005. Β Ροssia

In accordance with international obligations on April 29, 2003

1% of the Russian chemical weapons should be destroyed.

400 tones of other substances.

ПΡΕДШΕСΤΒУГГДЫ УΡΟΒΕΗЬ ΤΕΧΗИΚИ

All over the world take up to seventy years of the twentieth century chemical

others destroyed the methods that are now banned: burning on

Free air, evaporation and dilution in the air,

floods in the sea and oceans, pollution in the ground. Β seventieth years of beginning

Use Disinfecting Supplies (ΟΒ) with

Chemical reagents and subsequent incineration of waste products. However, in connection with labor issues arising from the implementation of these processes,

The destruction of chemical weapons in the USA in the 90s

The city has been focusing all attention on direct burning ΟΒ on special

Equipped factories. Β The same is true for the public and

aggravated technical malfunctions on combustion products ив burns κ

Necessity to seek out new technologies for disinfection ΟΒ.

From the level of technology the method of processing the substances contaminating is known

οκ narrowing medium (υδ, patent Ν ° 6.039.882). The facility and the operation

Designed for the treatment of substances that contaminate the environment and

located in good condition, in good condition, in good soil, water. Κροome

Therefore, the methods and equipment described in the patent may be used for

Processing facilities, in which contaminated materials were consummated. Essence

The method is concluded in the reaction of the contaminating substance with the compaction, which

Includes a metal and a compound containing a sulfur, as a result of which

environmentally acceptable chemically less active foods. Sat

It is suitable for pollution of a type of galogenous carbohydrates, for

Pesticides, for chemical weapons and for consumers. Business in

A preferred version of the version is separate from the previous version.

iron and iron sulfide. Additives to the company increase

Efficiency of processing reactions, especially for contaminants,

located in the ground, and for services.

Also known is the method of processing the waste material by the hydraulic system.

(υδ, patent τ ° 5678243). The method includes the addition of a chemical reagent 3

(ΟΒ) of water so that the reaction of the hydrolysis of a chemical reagent with water

It happened in the patent of small cases. Ед preferred

EMBODIMENTS OF THE EMBODIMENTS ARE FULFILLED IN CURRENT CONDITIONS, AT THE CENTER

The processed material (aminealkylphosphates) is stored. Sat

Includes stirring of the compatible tank after adding water.

The process of chemical processing by alkaline is also known.

hydrolysis (^ Ο, patent ен ° 9718858). The method includes reacting chemically

Weapons with a nitrogen-based base, a type of dry liquid ammonia, in

An active metal is, for example, disposed of.

Disposable methods described in the above sources

information that is inconsistent with current requirements κ

environmental safety of destruction of chemical weapons (restraining

substances) and pesticides.

National Scientific and Research Committee of the United States recommended

for further development and implementation of alternative technology

Disposal by alkaline hydrolysis with the following biodegradation

The less toxic products obtained are hydrolyzed.

Biodegradation of chemical substances is a natural product.

πρірідні προ process, driving the cooling medium. Scientists also

We are trying to radiate microorganisms and fragmentation systems for direct

biodegradation ΟΒ. However, due to its high toxicity ΟΒ microbial cells

It is possible to destroy only the very cost of one’s life, which is essential Enjoys the biodegradation process ΟΒ and makes it very dangerous to

Ecological eyesight.

Separately allocated partition systems are too specific (το

There is a need for something for every type of material), and it’s nice and

Access for direct use ΟΒ.

The closest available analogue of the invention is a method.

Hazardous substance processing (alkalis) with an alkaline hydrolysis with

the following biodegradation resulting from the less hydrolysis

toxic substances (υЗ, patent Ν ° 6017750). The method involves

The processing of a mixture of 2,2'-dichloro-diethylsulfide and bis-2-2-

Good radio (ΗΤ), and this also includes

following operations:

- compound ΗΤ with a hydrolyzing agent for the formation of the mixture

type diglycol (ΤϋΟ) and bis-2- (2-hydroxyethyl) ethyl ether (s) (Τ-ΟΗ);

- neutralization of the optimized mixtures ΤϋΟ and Τ-ΟΗ to ρΗ, which ensures

the possibility of further biodegradation of the indicated mixture;

- biodegradation of the neutralized neutralized ΤϋΟ and Τ-ΟΗ mixtures to

Irradiated biomass and waste water.

The disadvantages of the nearest analogue are not received at the 1st stage

(alkaline hydrolysis) in the field of toxic products of neutralization,

which essentially complicates and makes available all the processes associated with further

iχ χρaneniem, τρansπορτiροvκοy and τ.π., and τayuκe udοροzhaeτ iχ ποsleduyuschuyu

biodegradation, since special facilities for biodegradation are required and Permanent renewal of microorganisms that perish due to high

toxicity of alkaline products.

ΡΑСΚΡЫΤИΕ ΕΟΟΡΕΤΕΗΡΕΤΕΗ

The objective of the present invention is the creation

highly effective and affordable means and reagent for the first stage

Processes of toxic substances (hazardous substances, pesticides and their

hydrolysis), in the process of the quick release of the original product is reduced

so that its further biodegradation is possible.

In addition, the task of the invention is to expand the operational

There is a possibility of availability, that is, there is an extension of the circle of excipients, which are

It is possible to process the equipment using the proposed method (all types of equipment,

liquid and gaseous аю, as well as potential pesticides containing functional

groups of galloid or гал ο гал π,,,,,,,,, уль с с с уль С ^""""" Г Г, Β

Ν0 ₂ ^" , 30 ₄ ^" , τροφhenyl and τ. π.), products of the hydrolysis of numerically

exciters). The method may also be used for land rehabilitation and

Hazardous substances and pesticides.

Β The result of the first stage of processing is the production of a product that is substantially

less toxic than in the well-known technology, including the one written in

the nearest analogue. Essentially less toxic food

Possesses yet another important new property - it provides food

value for microorganisms, in connection with which the opportunity is created significantly expand the circle of natural microorganisms (type

“Active sludge”), suitable for processing neutralization products ΟΒ,

Obtained in accordance with the proposed method.

PRODUCTS OBTAINED IN THE RESULTS OF THE FIRST STAGE OF THE PROCESSING

small toxicity, possibly lowering the usual small-sized

Outputs and neutralization to ΗΗ are required for the ends

Biodegradation of conventional biochemical waste water.

This substantially simplifies and reduces the cost of the processing process ΟΒ.

The declared method for the second option, as well as the nearest analogue,

It is a two-stage process-based destruction system а:

Chemical decontamination след and the next biological decay (with the help of

microorganisms) of products obtained at the first stage.

Β declared variants of the method; the assigned tasks are solved at the expense of

Then, in the quality of the main reagent for chemical neutralization ΟΒ and

Pesticides use a reagent containing an amino acid or a mixture

amino acids, or peptides, or derivatives of amino acids and peptides, or both

mixture in water or in the urban environment. Аче As a reagent, it may also

HYDRAULIC PRODUCTS FOR WHITE PRODUCTS ARE USED

The new offer of the reagent is that for the first time in the quality

Medications to reduce the toxicity of substances, substances or substances

The hydrolyzate is provided with an amine acid reagent, which is self-contained.

an amino acid or a mixture of two or more amino acids, or a peptide, or a mixture

amino acids and peptides in the aquatic or aquatic-urban environment. Аче Inventory to reduce the toxicity of other substances

May be used by products of the hydraulics of whites

industrial intentions.

From the well-known sources, it is known that amino acids are easy

Salts, in addition, amino acids, are simple healthy

Complexes with various metal ions. For this, information was not found.

the properties of amino acids and narcotic drugs to neutralize the toxicity of toxicants

(hazardous substances, pesticides and their use). Β προ process

studies have been identified that an amino acid reagent is processed with

By specified ecotoxicants, stable, non-toxic compounds are not

decomposed in the biodegradation process.

More detailed information on research is given in

Section “Information supporting the possibility of implementation”

the invention. "

The described method has no drawbacks of the above mentioned means.

detections б and possesses in comparison with them by their direct advantages. Β

Qualitative results obtained and used

The proposed method of processing ΟΒ and pesticides may be indicated

the following:

- Ensuring the destruction of ΟΒ, pesticides or their disposal

The following biofeedback products, that is, with

Using the product obtained as a result of the processing microorganisms that are not justifiable as better additives for

lands of wide purpose to get to agricultural land;

- a substantial expansion of the community of ecologists - all types ΟΒ and

Pesticides containing functional groups galoid or

πsevdοgalοidnοy πρiροdy, sulφοgρuππy (SG Βg ^', T, Ν0 ₂ ^_"4 ^80", and niτροφenil

τ.π.), products of the interaction of short-circuiting with an amino acid reagent

there are two effective biodegradations that are indicated on the good

wide universality of the method;

- the possibility of using the developed means of land restoration and

substances contaminated with and pesticides;

-use of a highly effective and affordable reagent for

detoxification ΟΒ and pesticides;

- Significantly lower neutralization products π

In comparison with the well-known technologies, in some cases the alkaline

hydrolysis, products of neutralization with an amino acid reagent

to utilize microorganisms in the process of their vital activity, therefore

There is a substantial expansion of microorganisms, and they are also suitable for processing

neutralized by the proposed method ΟΒ (pesticides);

- the possibility of conversion of neutralization products to be processed

at the first stage, as it is of little physical consequence, and the possibility of biodegradation

in conventional biochemistry of biological wastewater. ΡΟΕΕΟΟΟУУΕУΟΟΟΟΟΟΟ ΟΟΟΟΟΟ

Method of disinfecting hazardous substances, pesticides or their

Disposable liquids include a compound for the disposal of a substance, substance or substance

hydrolysis with an amino acid reagent.

The acidic reagent must contain at least one of

the following amino acids: alanine, arginine, aspartic acid, aspartic acid,

valine, histidine, glycine, glutamic acid, glutamine, isoleucine, leucine,

Lysine, Methionine, Pyrolyn, Serine, Tyrosine, Truein, Human Potassium, phenylalanine

cysteine, cystine, or a mixture of these amino acids at various combinations, or

peptide, or derivatives of amino acids and peptides, or a mixture of amino acids and

pepididov in the aquatic or aquatic-urban environment. Β πρ below

Examples (laboratory experiments) Amino acid reagent contained

One amino acid or a mixture of two or more amino acids under conditions that

The ρΗ level was maintained in the specified range.

Also in the quality of an amino acid reagent for industrial purposes

May be used with alkaline hydrous products

Inductive products containing a mixture of salts of amino acids and peptides.

Received as a result of the interaction of an amino acid reagent with

ΟΒ, pesticide or hydrolyzate ΟΒ or pesticide, non-toxic product

for the purposes of further biodegradation, they neutralize to ρΗ = 7 ÷ 8,

Ensuring the possibility of further biodegradation. 10

Biodegradation is in harmony with the use of

microorganisms, for example, “active sludge” for the disposal of non-discharged

biomass.

EXAMPLE 1. Detection and biodegradation of lewisness before action

Amino acid reagent and microorganisms.

The α-lewisite sample (2-vinyl vinyl dyne) was purchased

the interaction of arsenic with acetylene in the presence of arsenic

It is clean aluminum and is distinguished by a double partition. INDICATORS:

boiling temperature 75-79 12 mm ρτ. c., ά ²⁰ _η = 1.875, and ²⁰ _ο = 1.06092

Corresponds to published data.

Detection of Lewis was carried out by the following method. Β κοlbu

An erlenmeyer with a capacity of 50 ml, equipped with a magnetic stirrer, was placed

a solution of 124 mg of lewisite in 30 ml of 0.1 Μ amino acid reagent (ΗΗ 7 - 12),

they were kept on stand and stirred at room temperature for 5 hours,

We set up for the night. After a day, they finished up to 7.0 and

study of the toxicity of the stomach and the introduction of gastrointestinal

κρыχχ. S ₅₀ - industrial, detoxification products exceeded 5000 mg / kg.

This is the same result (the reactive mass after the detection of lewisite 0.1 Μ

The solution of the amino acid reagent) was studied as a substrate for

the activity of bacteria of the third state and the activated sludge. Were

used as a source of production, such as and dilutions of its concentration U ^"1

÷ 10 ^" . Β π π би би би и и мещ мещ мещ мещ мещ мещ мещ мещ π π π π π π π π π π π ^{""""""""""""""""""""""} 10 ^" eleven

bacteria with a rate of 10 ^b , then the incubators were incubated during the course of a temperature of 37 ° C.

After a couple of days, it was noted that all bacteria under investigation were detected. Цыbρazes with

the initial concentration of the reactive masses was transferred to the study

Simple toxicity and internal gastrointestinal administration.

INSTALLED THAT S) ₅₀ , external, disassembled with a third-party strain

{product and active sludge exceeds 5000 mg / kg.

When studying all levels of doses, no clinical manifestations were revealed

Intoxication. Regional research of domestic livestock organizations,

Indicated after 14 days after the introduction of detoxification products,

The complete absence of any manifestations of toxicity. He

Mutagenic and carcinogenic properties were found in detoxification products.

(Ames test with metabolic activation - salmonella / mixtures, strains

ΤΑ-98 and ΤΑ-100).

Example Ν ° 2. Detection of lewisism by the action of lysine.

Erlenmeyer flask with a capacity of 30 ml, equipped with a magnetic stirrer,

Contained 62 mg of α-lewisite, identical to lewisite, as used in Example 1, and

15 ml of 0.1% sodium lysinate solution (Η 8 - 12). The mixture was πρ and

When stirring and at room temperature for 5 hours, I left the solution

at night. After a couple of days, they finished up to 7.0 and gave up for research

Simple toxicity, and intimate gastrointestinal administration.

L _5Ο , in fact, detoxification products exceeded 5000 mg / kg. 12

Foreign research of domestic organizations, accessible through

14 days after the introduction of product detoxification, showed complete absence

What are some of the manifestations of the toxic effects. Not found at the factory

mutagenic and carcinogenic properties (Ames test with

metabolic activation - salmonella / mixtures, strains ΤΑ-98 and ΤΑ-

100).

EXAMPLE 3. Detection of lewism by the action of cystine.

Erlenmeyer flask with a capacity of 30 ml, equipped with a magnetic stirrer,

15 ml of 0.1% sodium cystine salt (ΗΗ 8 - 12). The mixture was extracted

When stirring, and at a room temperature for 5 hours, use

Set at night. After a couple of days, they reached 7.0 and turned on

study of the toxicity of the stomach and the introduction of gastrointestinal

κρыχχ. Ο ΙΤ ₅ ₅ πeρορalnο, προduκτοv deτοκsiκatsii πρevyshaeτ 5000 mg / κg.

Foreign research of domestic organizations, accessible through

mutagenic and carcinogenic properties (Ames test with

metabolic activation - salmonella / mixtures, strains ΤΑ-98 and ΤΑ-

100). thirteen

EXAMPLE 4. Detection of adiposity by the action of amino acid

reagent.

The proprietary compound (2,2'-diethyl diethyl sulphide) was prepared by

Ceyera of 2,2'-Dioxetiylsulfide and concentrated salted acid,

highlighted by a two-sided hopper. INDICATORS: TEMPERATURE OF BOILING 95-97710 mm

ρτ. st., ά ²⁰ _and = 1.275, and ²⁰ _ο = 1.528 correspond to the literature data.

Detection of the disease was carried out by the following method. Β κοlbu

A solution of 80 mg of impurity in 25 ml of ΟΟΜ amino acid reagent and

When stirring, and at room temperature for 5 hours. Cast

Delivered at night, after a day brought to ρΗ = 7.0 and gave up for research

Simple toxicity and internal gastrointestinal administration. 12) ₅₀ ,

Immediate detoxification products exceed 5,000 mg / kg.

Foreign research of domestic organizations, accessible through

mutagenic and carcinogenic properties (Ames test with

metabolic activation - salmonella / mixtures, strains ΤΑ-98 and ΤΑ-

100).

EXAMPLE 5. Detoxification and biodegradation of a substance hydrolyzed ν _χ д

the action of an amino acid reagent and microorganisms. 14

The sample of the hydrolysis of the substance ν _{χ was} obtained as a result of the hydrolysis of 0-

I got rid of 8-2-diethylaminomethyl-methylphosphate at a ratio of 7:

100 (for volume) for 3 months, and for a room temperature. Research

Simple toxicity and internal gastrointestinal introduction to the field

It has been shown that β Ωβο, in particular, is a hydrolyzed substance of ν _{χ which} amounts to 750 mg / kg.

Private entry for entry - a convenience store for the user

τiπu.

Deτοκsiκatsiya gidροlizaτa veschesτva ν _χ προvοdilas following οbρazοm.

A flask of Erlenmeyer with a capacity of 100 ml, equipped with a magnetic stirrer,

They placed a solution of 5 ml of the hydrolysis of the substance ν _χ , 10 ml of 0.1ο amino acid

Reagent (ρΗ 8 - 12) and 35 ml of water, mixed at room temperature in

2 hours and left at night. Exploration of toxicity

in the gastrointestinal introduction to the experiments on the territory of the river showed, that --- G-> ₅₀ ,

The perfect, improved and reactive mass exceeded 5000 mg / kg.

Hydrolysis ν _χ (ΙЛ-> 5ο, natural, 750 mg / kg) was studied as

an alternative substance for the life of a number of microorganisms

(State Assembly, General Assembly, General Assembly, State Assembly).

The plants containing π 10 ml of the ν _χ hydrolyzate were seeded (π 2 ml

each culture) with all 4 strains. After a day of incubation, at 37 ° С

all seedlings died.

The effective mass obtained after the detection of the hydrolysis of the substance

ν _{χ with an} amino acid reagent, as a substrate for

the vital activity of bacteria of the host state of tegthous and active sludge. Were fifteen

both the original source and the pedigree are used as ^"1. Β π би би би,,,,

containing 10 ml of solution, 2 ml of culture of bacteria were added

on July ⁶ , the incubations and incubations during the course of the day were 37 ° С. Marked

Bacteria of all investigated samples. Original Concentration

The reactive masses were assigned to the study of the eastern and the uterine

Toxicity and internal gastrointestinal introduction to the experiment. Established

THAT ₅ ο--е,,,,,,,,,,,,,,,,,, ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ 5

The state of waste, such as sludge and active sludge, increases 5,000 mg / kg.

There is no clinical case of inclusion.

The experience of sharing the latest practices has been improved.

daily for 5 days πο 5000 mg / kg. Let's say, ΙЛ-> ₅ ο, еееρ,,,,

increases 25,000 mg / kg. Regional research of domestic organizations

live, available after 14 days after the introduction of detoxification products,

The complete absence of any manifestations of toxicity was shown to be completely absent. He

Mutagenic and carcinogenic properties were found in detoxification products.

(Ames test with metabolic activation - salmonella / mixtures, strains

ΤΑ-98 and ΤΑ-100).

On-line study of the toxicity of the amino acid reagent

(ρΗ = 7.0) in a new experience has shown that it is, in fact, exceeds 25000

mg / κg (5000 mg / kg, daily for 5 days).

EXAMPLE 6. Detection and biodegradation of a methylated product (method)

the action of lysine and microorganisms. 16

The methylated compound (0,0-dimethyl-Ο-η-nitrite-phenyl-compound) was

Using Shradera’s method with the interaction of 0,0-dimethyl chloride

with the natrium of the natrium and highlighted by the installation. Data

Sections Ya Η ¹ and ем ³¹ and a melting point of 34-36 ° C are consistent

literature data.

Methyl detoxification was carried out according to the following procedure. Β

Erlenmeyer flask with a capacity of 100 ml, equipped with a magnetic stirrer,

5 g of parastion and 57 ml of 0.1Μ sodium lysinate were placed (ρΗ 8 - 12). Mixture

they were kept at a temperature of 50 ° С for 3.5 hours,

Set at night. After a couple of days, they finished up to 7.0 and

study of the toxicity of the stomach and the introduction of gastrointestinal

κρыχχ. Ϋ ₅ ο, industrial products of metal detoxification exceeded

5000 mg / kg

Foreign research of domestic organizations, accessible through

mutagenic and carcinogenic properties (Ames test with

metabolic activation - salmonella / mixtures, strains ΤΑ-98 and ΤΑ-

100).

Decontaminated mass after detoxification of metal by lysate

was investigated as a substrate for the viability of bacteria

active sludge and water sludge. Π π π би би би и and placed 10 ml of solution

Reacted mass and added up to 2 ml of culture of bacteria with a rate of 10 ^b , then 17

The incubations and incubations during the course of the day were 37 ° С. After a day, it is noted that

Bacteria of all investigated samples. Exploration of toxicity

Samples for example and the internal introduction to experiments on the surface of the experiment, which

ΙЛ-) ₅ ο, е ρ,,, б аз ρ ρ, аз аз аз аз ц а с ο с с с с ο с ο с ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο ο

The incidence exceeds 5000 mg / kg.

Although the essence of the invention is described in detail in several respects,

SUMMARY OF THE INVENTION Please note that this is only for

illusions and inventions are not limited to the listed examples

EXISTENCE.

Thermal modes indicated in the formula of the invention and time

The implementation of the reaction is interconnected. Incomplete modes are selected

on the basis of the required speed of the reaction and the related capacities.

The outer part of the temperature range (around 95 ° C) can be used in

Hazardous conditions, in particular, in the case of disinfecting drugs, or in case of

increase in productivity (decrease in time)

The implementation of the reaction), but at the same time additional costs will be attempted

energy for heating the mixture.

Operation of neutralization of toxicity in field conditions

It is possible that the temperature is around 10 ° C. At a lower temperature

the speed of the process essentially slows down.

The minimum time for carrying out the reaction is divided in time

neutralization of toxicity of the ecotoxicant. Increase in time, not 18

depending on the temperature, and the reaction is not affected, it does not affect

The result is a neutralization of the toxicity.

Specialists in this area should be clear that in the frames

the declared method is not operational, it may be changed in some cases,

indicated in the formula of the invention. What changes can be made without

Disclaimer of the essence of the invention set forth in the formula of the invention.

Claims

19ΦΟΡΜULΑ IZBΟIA

1. The method of decontamination of ecotoxicants, as well as the export

substances, pesticides and their hydrolyses, including the connection of the toxicant

(hazardous substance, pesticide or their hydrolysis) with a neutralizing agent

The reagent is used as a reagent, as it is used as a reagent

amino acid reagent.

2. Method πο π. 1, characterized by the fact that after connecting

Substances, pesticides or their hydrolysis with an amino acid reagent

They mix and stand the mixture at a temperature of about 10 ° C.

up to 95 ° C over time, not necessary for neutralization

toxicity.

3. Method πο π. 1 or 2, which is different after the connection

Disposable substances, pesticides or their hydrolysis with amino acids

The reagent carries out the stirring and holding of the mixture and the temperature

Around 95 ° C over time, not necessary for the neutralization of toxicity,

but not less than the hour.

4. A method for any of paragraphs 1 to 3, which is different in that

the amino acid reagent contains an amino acid or a mixture of amino acids, or 20

a peptide, or a mixture of amino acids and peptides, or a mixture of amino acids and

pepididov in the aquatic or aquatic-urban environment.

5. A method for any of paragraphs 1 to 3, which is different from

amino acid reagent contains, at least, one of the listed

amino acid: alanine, arginine, aspartic acid, asparagine, valine,

histidine, glycine, glutamic acid, glutamine, isoleucine, leucine, lysine,

methionine, naphtha, serine, tyrosine, threonine, phenylalanine, cysteine,

cystine.

6. A method for any of paragraphs 1 to 3, which is different from that in quality

Amino Acid Reagent Uses Hydrolyzed Whitewash Product

product manufacturing.

7. The method of disposal of ecotoxicants, as well as the export of

substances, pesticides and their hydrolyses, including the following stages:

- compound of an excipient (hazardous substance, substance or substance)

hydrolysis) with a neutralizing reagent;

- neutralization of the product obtained to ρΗ, which ensures

the possibility of further biodegradation;

- biodegradation for the production of decontaminated biomass and wastewater,

ο τ l

In the reagent quality, an amino acid reagent is used. 21

8. Method πο π. 7, characterized by the fact that after the connection

Substances, pesticides or their hydrolysis with an amino acid reagent

They mix and stand the mixture at a temperature of about 10 ° C.

up to 95 ° C over time, not necessary for neutralization

toxicity.

9. Method πο π. 7 or 8, which is different after connection

Disposable substances, pesticides or their hydrolysis with amino acids

Around 95 ° C over time, not necessary for the neutralization of toxicity,

but not less than the hour.

10. A method for any of paragraphs 7 to 9, which is different from

the amino acid reagent contains an amino acid or a mixture of amino acids, or

pepididov in the aquatic or aquatic-urban environment.

11. A method for any of paragraphs 7 to 9, which is different from

the amino acid reagent contains less than one of the listed

amino acid: alanine, arginine, aspartic acid, asparagine, valine,

histidine, glycine, glutamic acid, glutamine, isoleucine, leucine, lysine, 22

methionine, naphtha, serine, tyrosine, threonine, phenylalanine, cysteine,

cystine.

12. A method for any of paragraphs 7 to 9, which is different from that in quality

Amino Acid Reagent Uses Hydrolyzed Whitewash Product

product manufacturing.

13. The use of amino acids as a means of neutralization

toxicity of substances, pesticide or their hydrolysis.

14. Use of the drug as a means of neutralization

toxicity of substances, pesticide or their hydrolysis.

15. Application of the product of the hydrolysis of white products

Inventory of equipment for reducing or neutralizing the toxicity

Hazardous substances, pesticide or their hydrolysis.