WO2004038081A1 - Low-density nonwoven fabric and production method and installation therefor and uses - Google Patents

Low-density nonwoven fabric and production method and installation therefor and uses Download PDF

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Publication number
WO2004038081A1
WO2004038081A1 PCT/FR2003/002941 FR0302941W WO2004038081A1 WO 2004038081 A1 WO2004038081 A1 WO 2004038081A1 FR 0302941 W FR0302941 W FR 0302941W WO 2004038081 A1 WO2004038081 A1 WO 2004038081A1
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WO
WIPO (PCT)
Prior art keywords
nonwoven
per
sheet
compressed
filaments
Prior art date
Application number
PCT/FR2003/002941
Other languages
French (fr)
Inventor
Frédéric NOELLE
Cédric LAURENT
Original Assignee
Rieter Perfojet
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rieter Perfojet filed Critical Rieter Perfojet
Priority to US10/529,843 priority Critical patent/US20060014464A1/en
Priority to EP03776960A priority patent/EP1556535A1/en
Priority to AU2003286219A priority patent/AU2003286219A1/en
Publication of WO2004038081A1 publication Critical patent/WO2004038081A1/en
Priority to US11/687,010 priority patent/US20070173163A1/en

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H18/00Needling machines
    • D04H18/04Needling machines with water jets
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/098Melt spinning methods with simultaneous stretching
    • D01D5/0985Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/007Addition polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/10Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
    • D04H3/11Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by fluid jet
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/681Spun-bonded nonwoven fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/682Needled nonwoven fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/689Hydroentangled nonwoven fabric

Definitions

  • the present invention relates to nonwoven fabrics and their production processes and installations and their applications.
  • To manufacture hygiene products such as baby diapers, adult incontinence diapers, feminine periodical protections, it is desirable to manufacture them from a material having a density as small as possible and a tensile strength as isotropic as The invention provides for this by a process for the production of a nonwoven, in which filaments from a spun-bond tower are deposited in a sheet having a longitudinal direction on a conveyor, the sheet is compressed. in a compressed tablecloth perpendicular to the plane of the tablecloth, then the compressed tablecloth is subjected to a consolidation by spraying there with water jets with a diameter of 50 to 250 microns under a pressure of 50 to 500 bar.
  • the web is deposited on the conveyor using at least one spun-bond tower whose die is inclined at an angle of from 10 to 60 ° and preferably from 20 to 50 ° relative to in the longitudinal direction and preferably using at least two spun bond turns, the dies of which are inclined in opposite directions and the water jets are projected, with the interposition of the sheet, either on a metallic fabric, the wires have a diameter of between 0.10 mm and 0.35 mm and which have at most 40 wires per centimeter in the warp direction and 40 wires per centimeter in the weft direction, that is to say on a microperforated sleeve whose dimensions of the perforations are between 50 and 600 microns and preferably between 150 and 500 microns and which has a number of perforations per cm2 between 50 and 200.
  • the threads have a diameter of between 0.18 and 0.30 mm and the fabric has a number of threads per centimeter both in the warp direction and in the weft direction from 15 to 30.
  • a nonwoven fabric of filaments having a density less than 0.10 g / cm 3 and in particular between 0.09 g / cm 3 and 0.03 g / cm 3 and better still between 0.07 and 0.03 g / cm3 and a ratio of the maximum tensile strength in the machine direction to the maximum resistance to transverse traction less than 1.5 and even less than 1, 3, or even less than 1, 1.
  • a nonwoven fabric according to the invention thus combines the isotropy of the properties with a very low density which makes this nonwoven fabric incomparable for the manufacture of baby diapers, either as a covering veil in contact with the baby's skin, either as an exterior textile trim to give a textile appearance.
  • the nonwovens according to the invention can also be used as a covering veil for feminine hygiene products, as a culture covering veil for agriculture, as a filtering medium for air or gas or liquid filtration. , in coating supports and in wiping products.
  • the nonwoven fabric according to the invention has a better acquisition speed and a greater distribution speed which makes it particularly useful for baby diapers.
  • the halo for diffusing the liquid onto the nonwoven fabric according to the invention is substantially circular, which further increases the useful surface area for acquiring and absorbing the liquid.
  • a greater instantaneous retention capacity has been found to the point that a single layer of the nonwoven fabric on the invention is equivalent to filter media consisting of 4 layers according to the prior art.
  • the life of the filter is extended.
  • the titer be between 1 and 3 dtex and the grammage between 12 and 20 g / m2.
  • the titer be between 3 and 8 dtex and in particular between 3 and 7 the grammage between 30 and 50 g / m2 and 7 dtex, the distribution layer also playing the role of an acquisition layer.
  • a title of between 1 and 3 dtex and a grammage of 15 to 30 g / m2 is preferred.
  • a title of between 2 and 6 dtex and in particular between 3 and 4 dtex and a basis weight of 15 to 30 g / m2 is preferred. The same goes for forcing sails in agriculture.
  • dtex titles ranging from 1 to 8 dtex in particular, with a preference for titles between 4 and 6 dtex and a grammage between 30 g / m2 to 150 g / m2.
  • titles of between 1 and 8 dtex are found, with a preference for securities between 2 and 6 dtex.
  • the invention accommodates non-crimped filaments, which considerably simplifies the production process. But, possibly the filaments can also be crimped, although this is not preferred because it complicates the manufacture.
  • the invention is particularly preferred for nonwovens weighing between 12 and 50 g / m2.
  • the metallic fabric is steel or bronze and has a thickness of between 0.40 and 0.75 mm. It is particularly preferred that the metallic fabric has a canvas weave, a twill weave or a satin weave.
  • the first stage of the process according to the invention consists in depositing filaments in a sheet on a conveyor.
  • the filaments can in particular be made of polyolefin, polyester, polyamide, metallocene polyvinyl alcohol, polylactic acid or other suitable plastics.
  • the filaments preferably have a titer between
  • two spun-bond towers are used, the dies of which are inclined, preferably in an opposite manner, at an angle of 10 to 60 ° and preferably of 20 to 50 ° relative to the direction longitudinal of the web which is the direction in which the conveyor moves and which is also called the machine direction.
  • the angles of inclination of the two dies can be different, one of them can also be perpendicular to the longitudinal direction of the sheet.
  • the second stage of the process consists in compressing the sheet into a compressed sheet while it is on the conveyor.
  • This compression is carried out by usual mechanical means, in particular by passing the ply through the nip between two cylinders or by compressing it between the conveyor and a cylinder.
  • the third stage of the process according to the invention consists in consolidating the compressed sheet by projecting water jets with a diameter of 50 to 250 microns under a pressure of 50 to 500 bar. It is a binding of the sheet by hydraulic entanglement which is conventional, except that care is taken to project the water jets through a metallic fabric whose wires have a prescribed diameter and whose number of wires per centimeter is prescribed in the warp direction and in the weft direction or through a microperforated sleeve as described above.
  • the diameter of the jets is preferably between 80 microns and 200 microns.
  • the jets are generally arranged in a row or in several rows, the arrangement in a row being preferred.
  • the distance between two jets in the same row is generally between 0.3 mm and 1.4 mm and preferably between 0.4 mm and 0.6 mm.
  • the consolidation treatment can also be carried out on several successive drums each equipped with one or more hydraulic injectors, in particular when the production speed is very high, for example being 800 m per minute. At these speeds, the use of gutters for recovering the rebounds from the water jets fixed on the injectors is particularly useful. In general, the speeds are between 20 m / min. and 1000 m / min. one can in particular combine a fabric drum and a drum cylinder with microperforated sleeve.
  • the metallic fabric which is called exterior can be mounted directly on a rotary support drum, but it can also be mounted on a coarse metallic fabric called interior fabric made up of threads of diameter at least equal to 0.5 mm and which serves as drainage fabric.
  • the inner metallic fabric is thus interposed between the rotary drum and the outer metallic fabric, preferably being in contact with the latter.
  • the drum consists of a fixed hollow cylinder at the periphery of which are provided slots facing the injectors, slots which are intended for the evacuation of water.
  • the fixed drum has at its periphery a rotary drum consisting of a rigid and permeable support.
  • the drum has a diameter between 300 mm and 1000 mm and preferably between 500 mm and 900 mm.
  • the water extraction slots facing the injectors preferably have a width of between 5 and 50 mm and preferably between 15 and 40 mm.
  • the nonwoven fabric of filaments obtained by the process according to the invention has a great softness. But if we accept to give up this softness, the two other desired properties can be further improved, namely the small density and the ratio of the resistance in the machine direction to the resistance in the cross direction close to the unit by choosing as a drum a metal sleeve perforated with holes diameter between 50 and 600 microns and preferably between 150 and 500 microns and comprising from 20 to 200 holes per cm 2 and preferably from 70 to
  • This calendering is carried out in a usual calender at a temperature of 100 to 250 ° C. and preferably from 130 to 170 ° C. depending on the nature of the polymer constituting the filaments (for example for polypropylene sheets, it is preferably carried out between 130 and 180 e C). with a surface of the web which is melted from 5 to 40% and preferably from 10 to 30% of the total surface, the melting points possibly being circular, oval, rectangular, diamond-shaped or the like.
  • Calendering may consist of passing the web of thermoplastic filaments between heated rollers.
  • a calender consisting of a smooth roller and an engraved roller. The pressure and the temperature applied by the calender causes a spot fusion of the web of continuous filaments.
  • the engraving can consist of points of circular, oval, square, rectangular or even diamond shape.
  • the melting points on the surface of the sheet represent from 2 to 40% of the surface and preferably from 10 to 30%.
  • Calendering speeds can reach several hundred meters per minute and in particular from 100 to 800 m / min.
  • the resistance index expressed in newtons per 50 mm per gram of nonwoven per m 2 is particularly good in the case where the calendering operation is incorporated into the process according to the invention. he can reach 2.8, namely 1.5 in the running direction and 1, 3 in the transverse direction while the grammage of the nonwoven fabric is between 12 and 150 g / m a , preferably 12 to 100 g / m2 and better from 12 to 40 g / m2. It is preferably possible to reach a resistance index of at least 3.5 and better still of at least 4.5, or even at least 5.5.
  • a conventional nonwoven of 20 g / m 2 composed of 100% polypropylene 1.7 dtex which has been carded and calendered is marketed with a thickness of 0.16 mm, a tensile strength in the machine direction. of 40 N / 50 mm, a transverse tensile strength of 9 N / 50 mm, ie a resistance ratio running direction on transverse direction of 4.44. Due to their poor mechanical properties, it is not possible to reduce the mass per square meter of these carded and then calendered nonwovens. With nonwovens made up of continuous filaments and in accordance with the invention, it is possible to obtain thicker, more resistant, more isotropic and lesser mass per square meter.
  • the residual water present in the nonwoven is extracted by suction devices connected to vacuum generators, then the nonwoven is dried, for example in a through air oven or with infrared panels or with microwaves.
  • the final nonwoven obtained has a water content of less than 5% by weight.
  • a surfactant can be applied to the nonwoven.
  • the invention also relates to a nonwoven production installation comprising at least one spun-bond lathe whose die is inclined at an angle of 10 to 60 e and, preferably, from 20 to 50 ° relative to the direction longitudinal and preferably at least two spun-bond towers whose dies are inclined in an opposite manner, depositing filaments in a sheet on a conveyor, a device for compressing the sheet so as to obtain a compressed sheet perpendicular to the plane of the sheet possibly a calender calandering the compressed sheet, then a device for consolidating by water jet the compressed sheet possibly calendered, by spraying water jets with a diameter of 50 to 250 microns and under a pressure of 50 to 500 bar , the installation comprising a machine for spraying a water jet with a metallic fabric or with a perforated sleeve as indicated above. Laboratory tests to measure thickness, density, resistance in the long direction and in the cross direction, are conducted according to ERT standards of EDANA (European Disposables And Nonwovens Association), namely
  • the sample is conditioned for 24 hours and the test is carried out at 23 ⁇ C and a relative humidity of 50%.
  • the thickness of the nonwoven is measured by measuring the distance between a reference plate on which the nonwoven rests and a parallel pressure plate which applies precise pressure to the surface under test.
  • the device consists of two horizontal circular plates fixed to a frame. The top plate moves vertically. It has an area of approximately 2500 mm2.
  • the reference plate has a flat surface with a diameter at least 50 mm larger than that of the upper plate.
  • the test piece has dimensions from 180 x 80 mm to more or less 5 mm for the width and the length.
  • a device is provided for measuring the distance between the plates when the latter are close enough to apply a pressure of 0.02 kpa.
  • a sample is conditioned for 24 hours and the test is carried out at 23 ° C and a relative humidity of 50%.
  • a dynamometer is used for the test, comprising a set of fixed jaws and a set of movable jaws moving at a constant speed. The jaws of the dynamometer have a useful width of 50 mm.
  • the dynamometer is equipped with a recorder which makes it possible to trace the curve of the tensile force as a function of the elongation. 5 samples are cut of 50 mm more or less 0.5 mm in width and 250 mm in length, this in the long direction and in the cross direction of the nonwoven.
  • the samples are tested one by one, at a constant tensile speed of 100 mm per minute and with an initial distance between jaws of 200 mm.
  • the dynamometer records the curve of the tensile force in Newtons as a function of elongation, the maximum of which is determined.
  • c) mass per square meter A sample is processed for 24 hours and the test was carried out at 23 e C and a relative humidity of 50%.
  • At least 3 samples are cut with an area of at least 50,000 mm2 with a cutting device called a cutter. Each sample is weighed on a laboratory balance with an accuracy of 0.1% of the mass of the weighed samples.
  • d) density The density is calculated from the measured thickness and the mass per square meter.
  • mv g / (e.1000)
  • mv density in grams per cubic centimeter
  • g mass per square meter of the nonwoven
  • e thickness of the nonwoven tested expressed in mm
  • FIG. 1 is a partial schematic plan view of an installation according to the invention and FIG. 2 is a complete plan view of it.
  • the installation shown in Figure 1 comprises two towers 1, 2, spun-bound respectively having a die 3, 4 which deposit on the upper strand 5 of a belt 5 without end of a conveyor 6 passing on rollers 7 of return, tensioner and guide, a sheet of continuous filaments which then pass from the left to the right in FIG. 1 on compacting rollers 8 and 9 before going to a calender 10 made up of two rollers then, by the through a conveyor 11, on a machine for spraying water jets.
  • the machine comprises a fixed internal drum 12 on which is threaded either a hollow cylinder 13 made of metallic fabric whose wires have a diameter of 0.25 mm and which has 22 wires / cm in warp direction and 22 wires / cm in weft direction, microperforated sleeve whose perforation dimensions are 200 microns and which has a number of perforations per cm 2 of 100.
  • the metallic fabric has a thickness of 0.50 mm and a satin weave. The sheet passes over the metallic fabric 13 and receives water jets with a diameter of 100 microns under a pressure of 300 bar by injectors 14.
  • All of the examples 1 to 10 are produced with a spunbond nonwoven of 20 g / m 2 produced on a PERFOBOND installation marketed by the company Rieter Perfojet composed of polypropylene filaments of 1.7 dtex.
  • This nonwoven has the distinction of having a resistance ratio running direction on transverse direction of less than 1.5, which is particularly advantageous in many applications.
  • the nonwoven has a thickness of 0.15 mm, a direction resistance of 39.8 N / 50 mm and a cross resistance of 32.1 N / 50 mm. It has a density of 0.133 g / cm 3 .
  • the nonwoven is treated with water jets on a JET LACE machine sold by the company Rieter Perfojet, which is composed of a hollow cylindrical drum at the periphery of which rotate various liners or cylinders. It is on the surface of these rotating cylinders that the filaments are treated with water jets.
  • a hydraulic injector is installed at the periphery of the drum and the jets it delivers are directed towards the cylinder.
  • the hydraulic injection delivers jets of 120 microns in diameter and the jets are spaced from each other by a center distance of 0.6 mm.
  • a vacuum of -800 mbar is applied to the interior of the hollow cylindrical drum by a vacuum generator. All tests are carried out at a linear speed of
  • the drum is equipped with a cylinder C1 consisting of a perforated sheet of stainless steel covered with a bronze fabric consisting of wires of 0.63 mm in diameter in the warp direction and of wires of 0.51 mm in the weft direction. It has 9.5 threads per cm in warp and 8.5 threads per cm in weft.
  • the injector is supplied with a pressure of 100 bar.
  • the nonwoven has a gain in thickness but its surface is perforated many holes from 0.4 to 0.5 mm 2 in area. Its touch is softer than non-woven non-woven fabric, but the perforations make it unusable.
  • the drum is equipped with a cylinder C2 consisting of a perforated sheet of stainless steel covered with a metallic fabric of stainless steel consisting of wires 0.11 mm in diameter in the warp direction and wires of 0.14 mm in the weft direction. It has 39 threads per cm in warp and 36 threads per cm in weft, The resistance index I _ 39.8 +32.1 _ 3.35 while, without
  • the injector is supplied at a pressure of 170 bar.
  • the nonwoven has a gain in thickness and its feel is softer than the initial nonwoven. It is free from defects and punctures.
  • Example 2 is repeated with a pressure of 230 bar.
  • the nonwoven has a gain in thickness and its feel is softer than the initial nonwoven (that is to say from Example 1) and than that of Example 2. It is free from defects and perforations.
  • Example 3 is repeated with a pressure of 300 bar.
  • the nonwoven has a gain in thickness and its feel is softer than the initial nonwoven and that of Example 3. It is free from defects and perforations.
  • the drum is equipped with a cylinder C3 made of a perforated sheet of stainless steel covered with a bronze fabric made up of wires of 0.22 mm in diameter in the warp direction and of wires of 0.23 mm in the weft direction. It has 25 threads per cm in warp and 20 threads per cm in weft.
  • the injector is supplied at a pressure of 170 bar.
  • the nonwoven has a gain in thickness and its feel is softer than the nonwoven of Example 1 and softer than the nonwoven of Examples 2, 3 and 4. It is free from defects and perforations .
  • Example 5 is repeated with a pressure of 230 bar.
  • the nonwoven has a gain in thickness and its feel is softer than the nonwoven of Example 1 and that of Example 5. It is free from defects and perforations.
  • Example 7 (preferred) Example 6 is repeated with a pressure of 300 bar.
  • the nonwoven has a gain in thickness and its feel is softer than the nonwoven of Example 1 and that of Example 6. It is free from defects and perforations.
  • the drum is fitted with a cylinder C4 consisting of a rigid cylindrical perforated sheet covered with a 0.35 mm thick nickel sleeve perforated with holes from 250 to 350 microns in diameter and comprising 100 holes per cm 2 , the holes being distributed randomly.
  • a cylinder C4 consisting of a rigid cylindrical perforated sheet covered with a 0.35 mm thick nickel sleeve perforated with holes from 250 to 350 microns in diameter and comprising 100 holes per cm 2 , the holes being distributed randomly.
  • the injector is supplied at a pressure of 170 bar.
  • the nonwoven has a thickness gain and its feel is softer than the nonwoven
  • Example 8 is repeated with a pressure of 230 bar.
  • the nonwoven has a gain in thickness and its feel is softer than the nonwoven of Example 1 and that of Example 8. It is free from defects and of perforations.
  • Example 8 is repeated with a pressure of 300 bar.
  • the nonwoven has a gain in thickness and its feel is softer than the initial nonwoven and that of Example 9. It is free from defects and perforations. It is nevertheless less soft than the nonwoven of Example 7.
  • a nonwoven conforming to the invention of 140 g / m2 consisting of polypropylene filaments of 1.5 dtex is subjected to a filtration test of sodium chloride particles with a diameter of 0.26 microns suspended in l 'air.
  • the device is of the TSI CERTITEST 8130 type.
  • the air flow rate through the sample is 103 l / min.
  • the nonwoven fabric according to the invention has better efficiency, less pressure drop, while having a lower surface mass.
  • the nonwoven according to the invention which has been used has a resistance in the running direction of 330 N / 50 mm and a resistance in the transverse direction of 300N / 50 mm, ie a ratio between the two of 1.1. Its thickness is 1.9 mm and its density of 0.074 g / cm3,
  • Softness is tested by a panel. The best sweetness is rated +++++, the least good.

Abstract

The invention concerns an installation for nonwoven production, characterized in that it comprises a spunbonded web plant (1) whereof the die (3) is inclined at an angle of 10 to 60° and preferably of 20 to 50° relative to the displacement direction of a conveyor (5) and preferably two spunbonded web plants whereof the dies have opposite inclinations, said conveyor whereon filaments are deposited from the die(s) in the form of a web, a station for compressing the thus formed web into a web compressed perpendicular to its plane, optionally a station (10) for calendering the compressed web, followed by a station (12) to (14) for consolidating by pressurized water jet spray the compressed and optionally calendered web with a jet spraying machine comprising a metal fabric whereof the wires have a diameter between 0.10 and 0.35 mm and which has more than 40 wires per cm and preferably 10 to 30 wires per cm both in warp direction and in weft direction or with a water jet spraying machine including a sleeve with perforations of 50 to 600 microns and having 20 to 200 perforations per cm2.

Description

Tissu non-tissé de petite masse volumique et ses procédé et installation de production et ses applicationsLow density nonwoven fabric and its production process and installation and applications
La présente invention se rapporte aux tissus non-tissés et à leurs procédés et installations de production et à leurs applications. Pour fabriquer des produits d'hygiène comme les couches bébé, les couches d'incontinence adultes, les protections périodiques féminines, il est souhaitable de les fabriquer en une matière ayant une masse volumique aussi petite que possible et une résistance à la traction aussi isotrope que possible, L'invention y pourvoit par un procédé de production d'un non-tissé, dans lequel on dépose des filaments provenant d'une tour spun-bond à filière en une nappe ayant une direction longitudinale sur un convoyeur, on comprime la nappe en une nappe comprimée perpendiculairement au plan de la nappe, puis on soumet la nappe comprimée à une consolidation en y projetant des jets d'eau d'un diamètre de 50 à 250 microns sous une pression de 50 à 500 bar. Suivant l'invention, on dépose la nappe sur le convoyeur à l'aide d'au moins une tour spun-bond dont le filière est inclinée d'un angle de de 10 à 60° et de préférence de 20 à 50° par rapport à la direction longitudinale et de préférence à l'aide d'au moins deux tours spun bond dont les filières sont inclinées de manière opposée et l'on projette les jets d'eau, avec interposition de la nappe, soit sur un tissu métallique dont les fils ont un diamètre compris entre 0,10 mm et 0,35 mm et qui ont au plus 40 fils par centimètre dans le sens chaîne et 40 fils par centimètre dans le sens trame, soit sur un manchon microperforé dont les dimensions des perforations sont comprises entre 50 et 600 microns et de préférence entre 150 et 500 microns et qui a un nombre de perforations au cm2 compris entre 50 et 200.The present invention relates to nonwoven fabrics and their production processes and installations and their applications. To manufacture hygiene products such as baby diapers, adult incontinence diapers, feminine periodical protections, it is desirable to manufacture them from a material having a density as small as possible and a tensile strength as isotropic as The invention provides for this by a process for the production of a nonwoven, in which filaments from a spun-bond tower are deposited in a sheet having a longitudinal direction on a conveyor, the sheet is compressed. in a compressed tablecloth perpendicular to the plane of the tablecloth, then the compressed tablecloth is subjected to a consolidation by spraying there with water jets with a diameter of 50 to 250 microns under a pressure of 50 to 500 bar. According to the invention, the web is deposited on the conveyor using at least one spun-bond tower whose die is inclined at an angle of from 10 to 60 ° and preferably from 20 to 50 ° relative to in the longitudinal direction and preferably using at least two spun bond turns, the dies of which are inclined in opposite directions and the water jets are projected, with the interposition of the sheet, either on a metallic fabric, the wires have a diameter of between 0.10 mm and 0.35 mm and which have at most 40 wires per centimeter in the warp direction and 40 wires per centimeter in the weft direction, that is to say on a microperforated sleeve whose dimensions of the perforations are between 50 and 600 microns and preferably between 150 and 500 microns and which has a number of perforations per cm2 between 50 and 200.
De préférence, les fils ont un diamètre compris entre 0,18 et 0,30 mm et la toile a un nombre de fils par centimètre tant dans le sens chaîne qu'en sens trame de 15 à 30. Dans ces conditions, on obtient par le procédé suivant l'invention un tissu non-tissé en filaments ayant une masse volumique inférieure à 0,10 g/cm3 et notamment comprise entre 0,09 g/cm3 et 0,03 g/cm3 et mieux encore comprise entre 0,07 et 0,03 g/cm3 et un rapport de la résistance maximum à la traction dans le sens machine à la résistance maximum à la traction dans le sens travers inférieur à 1,5 et même inférieur à 1 ,3, voire inférieur à 1 ,1. Un tissu non-tissé suivant l'invention réunit ainsi l'isotropie des propriétés à une masse volumique très petite qui rend ce tissu non-tissé incomparable pour la fabrication de couches bébé, soit en voile de recouvrement en contact avec la peau du bébé, soit en garniture textile extérieure pour donner un aspect textile. Les non-tissés suivant l'invention peuvent être aussi utilisés en voile de recouvrement pour les produits d'hygiène féminine, en voile de couverture de culture pour l'agriculture, en média filtrant pour la filtration d'air ou de gaz ou de liquide, en supports d'enduction et en produits d'essuyage. Le non-tissé suivant l'invention a une meilleure vitesse d'acquisition et une plus grande vitesse de répartition qui le rend particulièrement utile pour les couches de bébés. En outre, l'auréole de diffusion du liquide sur le non-tissé suivant l'invention est sensiblement circulaire ce qui augmente encore la surface utile d'acquisition et d'absorbtion du liquide. En filtration, on a constaté une plus grande capacité de rétention instantanée au point qu'une seule couche du non-tissé sur l'invention équivaut à des média filtrants constitués de 4 couches suivant la technique antérieure. En outre, la durée de vie du filtre est prolongée. Pour le voile de recouvrement d'une couche bébé on préfère que le titre soit compris entre le 1 et 3 dtex et le grammage compris entre 12 et 20 g/m2. Pour la couche de répartition d'une couche de bébé ou d'hygiène féminine on préfère que le titre soit compris entre 3 et 8 dtex et notamment compris entre 3 et 7 le grammage compris entre 30 et 50 g/m2 et 7 dtex, la couche de répartition jouant aussi le rôle d'une couche d'acquisition. Pour les couches assurant l'étanchéité sur les bords, le long des cuisses (leg cuff), on préfère un titre compris entre 1 et 3 dtex et un grammage de 15 à 30 g/m2. Dans l'usage en agriculture comme voile de couverture de cultures, on préférera un titre compris entre 2 et 6 dtex et notamment entre 3 et 4 dtex et un grammage de 15 à 30 g/m2. Il en va de même pour les voiles de forçage en agriculture. En filtration, on peut avoir des titres dtex très différents allant de 1 à 8 dtex notamment, avec une préférence pour des titres compris entre 4 et 6 dtex et un grammage compris entre 30 g/m2 à 150 g/m2. Pour des supports d'imprégnation et d'enduction tels qu'on en utilise par exemple dans la le bâtiment et le génie civil, dans la fabrication du cuir artificiel et synthétique on trouve des titres compris entre 1 et 8 dtex, avec une préférence pour des titres compris entre 2 et 6 dtex. L'invention s'accommode de filaments non frisés, ce qui simplifie considérablement le procédé de production. Mais, éventuellement les filaments peuvent être aussi frisés, bien que cela ne soit pas préféré parce que cela complique la fabrication.Preferably, the threads have a diameter of between 0.18 and 0.30 mm and the fabric has a number of threads per centimeter both in the warp direction and in the weft direction from 15 to 30. Under these conditions, we obtain by the process according to the invention a nonwoven fabric of filaments having a density less than 0.10 g / cm 3 and in particular between 0.09 g / cm 3 and 0.03 g / cm 3 and better still between 0.07 and 0.03 g / cm3 and a ratio of the maximum tensile strength in the machine direction to the maximum resistance to transverse traction less than 1.5 and even less than 1, 3, or even less than 1, 1. A nonwoven fabric according to the invention thus combines the isotropy of the properties with a very low density which makes this nonwoven fabric incomparable for the manufacture of baby diapers, either as a covering veil in contact with the baby's skin, either as an exterior textile trim to give a textile appearance. The nonwovens according to the invention can also be used as a covering veil for feminine hygiene products, as a culture covering veil for agriculture, as a filtering medium for air or gas or liquid filtration. , in coating supports and in wiping products. The nonwoven fabric according to the invention has a better acquisition speed and a greater distribution speed which makes it particularly useful for baby diapers. In addition, the halo for diffusing the liquid onto the nonwoven fabric according to the invention is substantially circular, which further increases the useful surface area for acquiring and absorbing the liquid. In filtration, a greater instantaneous retention capacity has been found to the point that a single layer of the nonwoven fabric on the invention is equivalent to filter media consisting of 4 layers according to the prior art. In addition, the life of the filter is extended. For the covering veil of a baby diaper it is preferred that the titer be between 1 and 3 dtex and the grammage between 12 and 20 g / m2. For the distribution layer of a baby diaper or feminine hygiene it is preferred that the titer be between 3 and 8 dtex and in particular between 3 and 7 the grammage between 30 and 50 g / m2 and 7 dtex, the distribution layer also playing the role of an acquisition layer. For the layers ensuring the sealing on the edges, along the thighs (leg cuff), a title of between 1 and 3 dtex and a grammage of 15 to 30 g / m2 is preferred. In use in agriculture as a crop cover veil, a title of between 2 and 6 dtex and in particular between 3 and 4 dtex and a basis weight of 15 to 30 g / m2 is preferred. The same goes for forcing sails in agriculture. In filtration, we can have very different dtex titles ranging from 1 to 8 dtex in particular, with a preference for titles between 4 and 6 dtex and a grammage between 30 g / m2 to 150 g / m2. For impregnation and coating supports such as those used for example in building and civil engineering, in the manufacture of artificial and synthetic leather, titles of between 1 and 8 dtex are found, with a preference for securities between 2 and 6 dtex. The invention accommodates non-crimped filaments, which considerably simplifies the production process. But, possibly the filaments can also be crimped, although this is not preferred because it complicates the manufacture.
L'invention est particulièrement préférée pour des non tissés d'un grammage compris entre 12 et 50 g/m2.The invention is particularly preferred for nonwovens weighing between 12 and 50 g / m2.
Ces propriétés remarquables peuvent s'expliquer par le fait que, par l'inclinaison de la tour spun bond, on obtient une nappe dont les filaments sont mieux entrecroisés et qui ainsi est plus apte à résister sans se trouer à la pression des jets d'eau et dont les filaments s'enchevêtrent mieux par le liage hydraulique.These remarkable properties can be explained by the fact that, by the inclination of the spun bond tower, a sheet is obtained whose filaments are better intertwined and which is thus better able to withstand without being pierced by the pressure of the jets. water and whose filaments get better entangled by the hydraulic bonding.
De préférence, le tissu métallique est en acier ou en bronze et a une épaisseur comprise entre 0,40 et 0,75 mm. On préfère tout particulièrement que le tissu métallique ait une armure toile, une armure sergé ou une armure satin.Preferably, the metallic fabric is steel or bronze and has a thickness of between 0.40 and 0.75 mm. It is particularly preferred that the metallic fabric has a canvas weave, a twill weave or a satin weave.
Le premier stade du procédé suivant l'invention consiste à déposer des filaments en une nappe sur un convoyeur. Les filaments peuvent être notamment en polyoléfine, en polyester, en polyamide, en alcool polyvinylique en métallocène, en acide polylactique ou autres matières plastiques appropriées. Les filaments ont de préférence un titre compris entreThe first stage of the process according to the invention consists in depositing filaments in a sheet on a conveyor. The filaments can in particular be made of polyolefin, polyester, polyamide, metallocene polyvinyl alcohol, polylactic acid or other suitable plastics. The filaments preferably have a titer between
0,9 à 10 dtex.0.9 to 10 dtex.
Ils sont issus d'une filière au sommet de la tour spun-bond et descendent ensuite à la verticale jusqu'au convoyeur en passant par un dispositif qui les refroidit et les étire ou les atténue à la manière classique si ce n'est que, suivant l'invention, on utilise, de préférence, deux tours spun-bond dont les filières sont inclinées, de préférence de manière opposée, d'un angle de 10 à 60° et de préférence de 20 à 50° par rapport à la direction longitudinale de la nappe qui est la direction dans laquelle se déplace le convoyeur et que l'on appelle aussi le sens machine. Les angles d'inclinaison des deux filières peuvent être différents, l'une d'entre elles pouvant aussi être perpendiculaire à la direction longitudinale de la nappe.They come from a die at the top of the spun-bond tower and then descend vertically to the conveyor through a device which cools them and stretches or attenuates them in the conventional way except, according to the invention, preferably, two spun-bond towers are used, the dies of which are inclined, preferably in an opposite manner, at an angle of 10 to 60 ° and preferably of 20 to 50 ° relative to the direction longitudinal of the web which is the direction in which the conveyor moves and which is also called the machine direction. The angles of inclination of the two dies can be different, one of them can also be perpendicular to the longitudinal direction of the sheet.
Le deuxième stade du procédé consiste à comprimer la nappe en une nappe comprimée alors qu'elle se trouve sur le convoyeur. On effectue cette compression par des moyens mécaniques habituels, notamment en faisant passer la nappe dans le pincement compris entre deux cylindres ou en la comprimant entre le convoyeur et un cylindre.The second stage of the process consists in compressing the sheet into a compressed sheet while it is on the conveyor. This compression is carried out by usual mechanical means, in particular by passing the ply through the nip between two cylinders or by compressing it between the conveyor and a cylinder.
Le troisième stade du procédé suivant l'invention consiste à consolider la nappe comprimée en y projetant des jets d'eau d'un diamètre de 50 à 250 microns sous une pression de 50 à 500 bar. Il s'agit d'un liage de la nappe par enchevêtrement hydraulique qui est classique, sauf que l'on prend soin de projeter les jets d'eau à travers un tissu métallique dont les fils ont un diamètre prescrit et dont le nombre de fils au centimètre est prescrit dans le sens chaîne et dans le sens trame ou à travers un manchon microperforé tel que décrit ci-précédemment. Le diamètre des jets est de préférence compris entre 80 microns et 200 microns. Les jets sont en général disposés sur une rangée ou sur plusieurs rangées, la disposition sur une rangée étant préférée. La distance entre deux jets d'une même rangée est en général comprise entre 0,3 mm et 1 ,4 mm et de préférence entre 0,4 mm et 0,6 mm. On peut aussi réaliser le traitement de consolidation sur plusieurs tambours successifs équipés chacun d'un ou de plusieurs injecteurs hydrauliques, notamment lorsque la vitesse de production est très grande en étant par exemple de 800 m à la minute. A ces vitesses, l'utilisation de gouttières de récupération des rebonds des jets d'eau fixés sur les injecteurs est particulièrement utile. En général, les vitesses sont comprises entre 20 m/min. et 1000 m/min. on peut notamment combiner un tambour à tissu et un cylindre tambour à manchon microperforée.The third stage of the process according to the invention consists in consolidating the compressed sheet by projecting water jets with a diameter of 50 to 250 microns under a pressure of 50 to 500 bar. It is a binding of the sheet by hydraulic entanglement which is conventional, except that care is taken to project the water jets through a metallic fabric whose wires have a prescribed diameter and whose number of wires per centimeter is prescribed in the warp direction and in the weft direction or through a microperforated sleeve as described above. The diameter of the jets is preferably between 80 microns and 200 microns. The jets are generally arranged in a row or in several rows, the arrangement in a row being preferred. The distance between two jets in the same row is generally between 0.3 mm and 1.4 mm and preferably between 0.4 mm and 0.6 mm. The consolidation treatment can also be carried out on several successive drums each equipped with one or more hydraulic injectors, in particular when the production speed is very high, for example being 800 m per minute. At these speeds, the use of gutters for recovering the rebounds from the water jets fixed on the injectors is particularly useful. In general, the speeds are between 20 m / min. and 1000 m / min. one can in particular combine a fabric drum and a drum cylinder with microperforated sleeve.
Le tissu métallique que l'on dénomme extérieur peut être monté directement sur un tambour rotatif support, mais il peut être aussi monté sur un tissu métallique grossier dit tissu intérieur constitué de fils de diamètre au moins égal à 0,5 mm et qui sert de tissu de drainage. Le tissu métallique intérieur est ainsi intercalé entre le tambour rotatif et le tissu métallique extérieur en étant de préférence en contact avec ceux-ci. Le tambour est constitué d'un cylindre creux fixe à la périphérie duquel sont ménagées des fentes en regard des injecteurs, fentes qui sont destinées à l'évacuation de l'eau. Le tambour fixe comporte à sa périphérie un tambour rotatif constitué d'un support rigide et perméable. Le tambour a un diamètre compris entre 300 mm et 1000 mm et de préférence compris entre 500 mm et 900 mm. Les fentes d'extraction de l'eau en regard des injecteurs ont de préférence une largeur comprise entre 5 et 50 mm et de préférence comprise entre 15 et 40 mm. Le tissu non-tissé en filaments obtenu par le procédé suivant l'invention a une grande douceur. Mais si l'on accepte de renoncer à cette douceur, on peut encore améliorer les deux autres propriétés recherchées, à savoir la masse volumique petite et le rapport de la résistance dans le sens machine à la résistance dans le sens travers proche de l'unité en choisissant comme tambour un manchon métallique perforé de trous de diamètre compris entre 50 et 600 microns et de préférence entre 150 et 500 microns et comprenant de 20 à 200 trous par cm2 et de préférence de 70 àThe metallic fabric which is called exterior can be mounted directly on a rotary support drum, but it can also be mounted on a coarse metallic fabric called interior fabric made up of threads of diameter at least equal to 0.5 mm and which serves as drainage fabric. The inner metallic fabric is thus interposed between the rotary drum and the outer metallic fabric, preferably being in contact with the latter. The drum consists of a fixed hollow cylinder at the periphery of which are provided slots facing the injectors, slots which are intended for the evacuation of water. The fixed drum has at its periphery a rotary drum consisting of a rigid and permeable support. The drum has a diameter between 300 mm and 1000 mm and preferably between 500 mm and 900 mm. The water extraction slots facing the injectors preferably have a width of between 5 and 50 mm and preferably between 15 and 40 mm. The nonwoven fabric of filaments obtained by the process according to the invention has a great softness. But if we accept to give up this softness, the two other desired properties can be further improved, namely the small density and the ratio of the resistance in the machine direction to the resistance in the cross direction close to the unit by choosing as a drum a metal sleeve perforated with holes diameter between 50 and 600 microns and preferably between 150 and 500 microns and comprising from 20 to 200 holes per cm 2 and preferably from 70 to
150 trous/cm2.150 holes / cm 2 .
Si l'on veut de plus augmenter la résistance du tissu non-tissé obtenu, il convient de soumettre la nappe comprimée à un calandrage avant de la consolider. On effectue ce calandrage dans une calandre habituelle à une température de 100 à 250°C et de préférence de 130 à 170°C suivant la nature du polymère constituant les filaments (par exemple pour des nappes de polypropylène, il s'effectue de préférence entre 130 et 180e C). avec une surface de la nappe qui est fondue de 5 à 40 % et de préférence de 10 à 30 % de la surface totale, les points de fusion pouvant être circulaires, ovales, rectangulaires, en forme de diamant ou autres.If it is also desired to increase the resistance of the nonwoven fabric obtained, it is necessary to subject the compressed sheet to a calendering before consolidating it. This calendering is carried out in a usual calender at a temperature of 100 to 250 ° C. and preferably from 130 to 170 ° C. depending on the nature of the polymer constituting the filaments (for example for polypropylene sheets, it is preferably carried out between 130 and 180 e C). with a surface of the web which is melted from 5 to 40% and preferably from 10 to 30% of the total surface, the melting points possibly being circular, oval, rectangular, diamond-shaped or the like.
Le calandrage peut consister à faire passer la nappe de filaments thermoplastiques entre des rouleaux chauffés. Pour la réalisation de l'invention, il est prévu d'utiliser de préférence une calandre constituée d'un rouleau lisse et d'un rouleau gravé. La pression et la température appliquées par la calandre entraîne une fusion par points de la nappe de filaments continus.Calendering may consist of passing the web of thermoplastic filaments between heated rollers. For carrying out the invention, provision is preferably made for a calender consisting of a smooth roller and an engraved roller. The pressure and the temperature applied by the calender causes a spot fusion of the web of continuous filaments.
La gravure peut être constituée de points de forme circulaire, ovale, carrée, rectangulaire voire de losanges. Les points de fusion à la surface de la nappe représentent de 2 à 40 % de la surface et de préférence de 10 à 30 %.The engraving can consist of points of circular, oval, square, rectangular or even diamond shape. The melting points on the surface of the sheet represent from 2 to 40% of the surface and preferably from 10 to 30%.
Il est aussi possible d'utiliser deux rouleaux gravés du type mâle femelle qui ont une rotation synchronisée et s'imbriquent l'un dans l'autre. Il est aussi possible d'utiliser deux rouleaux lisses. Le calandrage s'effectue à des pressions comprises entre 50It is also possible to use two engraved rollers of the male female type which have a synchronized rotation and are nested one in the other. It is also possible to use two smooth rollers. Calendering is carried out at pressures between 50
N/mm et 150 N/mm.N / mm and 150 N / mm.
Les vitesses de calandrage peuvent atteindre plusieurs centaines de mètres par minute et notamment de 100 à 800 m/min.Calendering speeds can reach several hundred meters per minute and in particular from 100 to 800 m / min.
L'indice de résistance exprimé en newtons par 50 mm par gramme de non-tissé au m2 est particulièrement bon dans le cas où l'on incorpore dans le procédé suivant l'invention l'opération de calandrage. Il peut atteindre 2,8 à savoir 1 ,5 dans le sens marche et 1 ,3 , dans le sens travers alors que le grammage du tissu non-tissé est compris entre 12 et 150 g/ma, de préférence 12 à 100 g/m2 et mieux de 12 à 40 g/m2. On peut atteindre de préférence un indice de résistance d'au moins 3,5 et mieux d'au moins 4,5, voire même d'au moins 5,5.The resistance index expressed in newtons per 50 mm per gram of nonwoven per m 2 is particularly good in the case where the calendering operation is incorporated into the process according to the invention. he can reach 2.8, namely 1.5 in the running direction and 1, 3 in the transverse direction while the grammage of the nonwoven fabric is between 12 and 150 g / m a , preferably 12 to 100 g / m2 and better from 12 to 40 g / m2. It is preferably possible to reach a resistance index of at least 3.5 and better still of at least 4.5, or even at least 5.5.
A titre de comparaison, un non-tissé classique de 20 g/m2 composé de 100 % de polypropylène 1,7 dtex qui a été cardé et calandre est commercialisé avec une épaisseur de 0,16 mm, une résistance à la traction sens machine de 40 N/50 mm, une résistance à la traction sens travers de 9 N/50 mm soit un rapport de résistance sens marche sur sens travers de 4,44. De part leurs faibles propriétés mécaniques, il n'est pas possible de réduire la masse au mètre carré de ces non-tissés cardés puis calandres. Avec les non-tissés constitués de filaments continus et conformes à l'invention, il est possible d'obtenir des non-tissés plus épais, plus résistants, plus isotropes et de masse au mètre carré moindre.By way of comparison, a conventional nonwoven of 20 g / m 2 composed of 100% polypropylene 1.7 dtex which has been carded and calendered is marketed with a thickness of 0.16 mm, a tensile strength in the machine direction. of 40 N / 50 mm, a transverse tensile strength of 9 N / 50 mm, ie a resistance ratio running direction on transverse direction of 4.44. Due to their poor mechanical properties, it is not possible to reduce the mass per square meter of these carded and then calendered nonwovens. With nonwovens made up of continuous filaments and in accordance with the invention, it is possible to obtain thicker, more resistant, more isotropic and lesser mass per square meter.
Après le dispositif de consolidation par enchevêtrement au moyen de jets d'eau sous pression, on extrait l'eau résiduelle présente dans le non-tissé par des dispositifs aspirants raccordés à des générateurs de vide, puis on sèche le non-tissé par exemple dans un four à air traversant ou avec des panneaux infrarouge ou avec des micro-ondes. Le non tissé final obtenu a une teneur en eau inférieure à 5 % en poids.After the consolidation device by entanglement by means of pressurized water jets, the residual water present in the nonwoven is extracted by suction devices connected to vacuum generators, then the nonwoven is dried, for example in a through air oven or with infrared panels or with microwaves. The final nonwoven obtained has a water content of less than 5% by weight.
Après ou avant séchage, on peut appliquer un agent tensio-actif au non tissé .After or before drying, a surfactant can be applied to the nonwoven.
L'invention vise également une installation de production de non- tissé comprenant au moins un tour spun-bond dont la filière est inclinée d'un angle de 10 à 60e et, de préférence, de 20 à 50° par rapport à la direction longitudinale et de préférence au moins deux tours spun-bond dont les filières sont inclinées de manière opposée, déposant des filaments en une nappe sur un convoyeur, un dispositif de compression de la nappe de manière à obtenir une nappe comprimée perpendiculairement au plan de la nappe éventuellement une calandre calandrant la nappe comprimée, puis un dispositif de consolidation par jet d'eau de la nappe comprimée éventuellement calandrée, par projection de jets d'eau d'un diamètre de 50 à 250 microns et sous une pression de 50 à 500 bar, l'installation comprenant une machine de projection de jet d'eau à tissu métallique ou à manchon perforé telle qu'indiquée précédemment. Les tests de laboratoire de mesure d'épaisseur, de masse volumique, de résistance dans le sens long et dans le sens travers, sont conduits selon les normes ERT de l'EDANA (European Disposables And Nonwovens Association), à savoir a) faalMflurThe invention also relates to a nonwoven production installation comprising at least one spun-bond lathe whose die is inclined at an angle of 10 to 60 e and, preferably, from 20 to 50 ° relative to the direction longitudinal and preferably at least two spun-bond towers whose dies are inclined in an opposite manner, depositing filaments in a sheet on a conveyor, a device for compressing the sheet so as to obtain a compressed sheet perpendicular to the plane of the sheet possibly a calender calandering the compressed sheet, then a device for consolidating by water jet the compressed sheet possibly calendered, by spraying water jets with a diameter of 50 to 250 microns and under a pressure of 50 to 500 bar , the installation comprising a machine for spraying a water jet with a metallic fabric or with a perforated sleeve as indicated above. Laboratory tests to measure thickness, density, resistance in the long direction and in the cross direction, are conducted according to ERT standards of EDANA (European Disposables And Nonwovens Association), namely a) faalMflur
On conditionne l'échantillon pendant 24 heures et on effectue l'essai à 23βC et à une humidité relative de 50%. On mesure l'épaisseur du non-tissé en mesurant la distance entre un plateau de référence sur lequel repose le non-tissé et un plateau presseur parallèle qui applique une pression précise sur la surface soumise à l'essai. L'appareil consiste en deux plaques horizontales circulaires fixées à un bâti. La plaque supérieure se déplace verticalement. Elle a une surface d'environ 2500 mm2. La plaque de référence a une surface plane d'un diamètre plus grand d'au moins 50 mm que celui de la plaque supérieure. La pièce d'essai a des dimensions de 180 x 80 mm a plus ou moins 5 mm pour la largeur et la longueur. Il est prévu un dispositif de mesure de la distance entre les plaques lorsque celles-ci se sont rapprochées au point d'appliquer une pression de 0,02 kpa. b) Résistance et allongement dans le sens long et dans le sens travers :The sample is conditioned for 24 hours and the test is carried out at 23 β C and a relative humidity of 50%. The thickness of the nonwoven is measured by measuring the distance between a reference plate on which the nonwoven rests and a parallel pressure plate which applies precise pressure to the surface under test. The device consists of two horizontal circular plates fixed to a frame. The top plate moves vertically. It has an area of approximately 2500 mm2. The reference plate has a flat surface with a diameter at least 50 mm larger than that of the upper plate. The test piece has dimensions from 180 x 80 mm to more or less 5 mm for the width and the length. A device is provided for measuring the distance between the plates when the latter are close enough to apply a pressure of 0.02 kpa. b) Strength and elongation in the long direction and in the cross direction:
On conditionne un échantillon pendant 24 heures et on effectue l'essai à 23°C et à une humidité relative de 50%. On utilise pour le test un dynamomètre comprenant un jeu de mâchoires fixes et un jeu de mâchoires mobiles se déplaçant à une vitesse constante. Les mâchoires du dynamomètre ont une largeur utile de 50 mm. Le dynamomètre est équipé d'un enregistreur qui permet de tracer la courbe de la force de traction en fonction de l'allongement. On coupe 5 échantillons de 50 mm plus ou mois 0,5 mm de largeur et de 250 mm de longueur, ceci dans le sens long et dans le sens travers du non tissé. Les échantillons sont testés un par un , à un vitesse constante de traction de 100 mm par minute et avec une distance initiale entre mâchoires de 200 mm. Le dynamomètre enregistre la courbe de la force de traction en newtons en fonction de allongement dont on détermine le maximum. c) masse au mètre carré : On conditionne un échantillon pendant 24 heures et on effectue l'essai à 23e C et à une humidité relative de 50%.A sample is conditioned for 24 hours and the test is carried out at 23 ° C and a relative humidity of 50%. A dynamometer is used for the test, comprising a set of fixed jaws and a set of movable jaws moving at a constant speed. The jaws of the dynamometer have a useful width of 50 mm. The dynamometer is equipped with a recorder which makes it possible to trace the curve of the tensile force as a function of the elongation. 5 samples are cut of 50 mm more or less 0.5 mm in width and 250 mm in length, this in the long direction and in the cross direction of the nonwoven. The samples are tested one by one, at a constant tensile speed of 100 mm per minute and with an initial distance between jaws of 200 mm. The dynamometer records the curve of the tensile force in Newtons as a function of elongation, the maximum of which is determined. c) mass per square meter: A sample is processed for 24 hours and the test was carried out at 23 e C and a relative humidity of 50%.
On coupe au moins 3 échantillons d'une surface d'au moins 50000 mm2 avec un appareil de découpe appelé massicot. Chaque échantillon est pesé sur une balance de laboratoire ayant une précision de 0,1% de la masse des échantillons pesés. d) masse volumioue : La masse volumique est calculée à partir de l'épaisseur mesurée et de la masse au mètre carré. mv = g/(e.1000) mv = masse volumique en gramme par centimètre cube g = masse au mètre carré du non-tissé e = épaisseur du non- tissé testé exprimée en mmAt least 3 samples are cut with an area of at least 50,000 mm2 with a cutting device called a cutter. Each sample is weighed on a laboratory balance with an accuracy of 0.1% of the mass of the weighed samples. d) density: The density is calculated from the measured thickness and the mass per square meter. mv = g / (e.1000) mv = density in grams per cubic centimeter g = mass per square meter of the nonwoven e = thickness of the nonwoven tested expressed in mm
Au dessin annexé donné uniquement à titre d'exemple : la figure 1 est une vue en plan schématique partielle, d'une installation suivant l'invention et la figure 2 en est une vue en plan complète.In the accompanying drawing given solely by way of example: FIG. 1 is a partial schematic plan view of an installation according to the invention and FIG. 2 is a complete plan view of it.
L'installation représentée à la figure 1 comprend deux tours 1 , 2, spun-bound ayant respectivement une filière 3, 4 qui déposent sur le brin 5 supérieur d'un tapis 5 sans fin d'un convoyeur 6 passant sur des rouleaux 7 de renvoi, tendeur et de guidage, une nappe de filaments continus qui passent ensuite de la gauche vers la droite à la figure 1 sur des rouleaux 8 et 9 de compactage avant d'aller à une calandre 10 constituée de deux rouleaux puis, par l'intermédiaire d'un convoyeur 11, sur une machine de projection de jets d'eau. La machine comprend un tambour 12 fixe intérieur sur lequel est enfilé soit un cylindre 13 creux en tissu métallique dont les fils ont un diamètre de 0,25 mm et qui a 22 fils/cm en sens chaîne et 22 fils/cm en sens trame, manchon microperforé dont les dimensions des perforations sont de 200 microns et qui a un nombre de perforations au cm2 de 100. Le tissu métallique a une épaisseur de 0,50 mm et une armure satin. La nappe passe sur le tissu 13 métallique et reçoit des jets d'eau d'un diamètre de 100 microns sous une pression de 300 bar par des injecteurs 14.The installation shown in Figure 1 comprises two towers 1, 2, spun-bound respectively having a die 3, 4 which deposit on the upper strand 5 of a belt 5 without end of a conveyor 6 passing on rollers 7 of return, tensioner and guide, a sheet of continuous filaments which then pass from the left to the right in FIG. 1 on compacting rollers 8 and 9 before going to a calender 10 made up of two rollers then, by the through a conveyor 11, on a machine for spraying water jets. The machine comprises a fixed internal drum 12 on which is threaded either a hollow cylinder 13 made of metallic fabric whose wires have a diameter of 0.25 mm and which has 22 wires / cm in warp direction and 22 wires / cm in weft direction, microperforated sleeve whose perforation dimensions are 200 microns and which has a number of perforations per cm 2 of 100. The metallic fabric has a thickness of 0.50 mm and a satin weave. The sheet passes over the metallic fabric 13 and receives water jets with a diameter of 100 microns under a pressure of 300 bar by injectors 14.
On voit à la figure 2 que l'axe longitudinal Y, Y' de la filière 3 et l'axe longitudinal Z,Z' de la filière 4 sont inclinés respectivement d'un angle a et b par rapport à l'axe X,X' qui correspond à la direction de la marche, mais en sens inverse. A la suite de la machine de projection de jets, il est prévu, à la figure 2, un convoyeur 15 de déshumidification, un four 16 de séchage et un dispositif 17 d'enroulement.It can be seen in FIG. 2 that the longitudinal axis Y, Y 'of the die 3 and the longitudinal axis Z, Z' of the die 4 are inclined at an angle a and b respectively with respect to the axis X, X 'which corresponds to the direction of the walk, but reverse. Following the jet projection machine, there is provided, in Figure 2, a dehumidification conveyor 15, a drying oven 16 and a winding device 17.
ExemplesExamples
Tous les exemples 1 à 10 sont réalisés avec un non-tissé spun- bond de 20 g/m2 produit sur une installation PERFOBOND commercialisé par la société Rieter Perfojet composé de filaments de polypropylène de 1 ,7 dtex. Ce non-tissé a la particularité d'avoir un rapport de résistance sens marche sur sens transversal inférieur à 1 ,5, ce qui est particulièrement avantageux dans de nombreuses applications. Le non-tissé a une épaisseur de 0,15 mm, une résistance en sens marche de 39,8 N/50 mm et une résistance en sens travers de 32,1 N/50 mm. Il présente une masse volumique de 0,133 g/cm3.All of the examples 1 to 10 are produced with a spunbond nonwoven of 20 g / m 2 produced on a PERFOBOND installation marketed by the company Rieter Perfojet composed of polypropylene filaments of 1.7 dtex. This nonwoven has the distinction of having a resistance ratio running direction on transverse direction of less than 1.5, which is particularly advantageous in many applications. The nonwoven has a thickness of 0.15 mm, a direction resistance of 39.8 N / 50 mm and a cross resistance of 32.1 N / 50 mm. It has a density of 0.133 g / cm 3 .
Après calandrage à chaud, le non-tissé est traité par jets d'eau sur une machine JET LACE commercialisée par la société Rieter Perfojet, qui est composée d'un tambour cylindrique creux à la périphérie duquel tournent différentes chemises ou cylindres. C'est à la surface de ces cylindres rotatifs que les filaments sont traités par jets d'eau. Un injecteur hydraulique est installé à la périphérie du tambour et les jets qu'il délivre sont dirigés vers le cylindre.After hot calendering, the nonwoven is treated with water jets on a JET LACE machine sold by the company Rieter Perfojet, which is composed of a hollow cylindrical drum at the periphery of which rotate various liners or cylinders. It is on the surface of these rotating cylinders that the filaments are treated with water jets. A hydraulic injector is installed at the periphery of the drum and the jets it delivers are directed towards the cylinder.
L'injection hydraulique délivre des jets de 120 microns de diamètre et les jets sont espacés les uns des autres d'un entre axe de 0,6 mm. Une dépression de -800 mbar est appliquée à l'intérieur du tambour cylindrique creux par un générateur de vide. Tous les essais sont réalisés à une vitesse linéaire deThe hydraulic injection delivers jets of 120 microns in diameter and the jets are spaced from each other by a center distance of 0.6 mm. A vacuum of -800 mbar is applied to the interior of the hollow cylindrical drum by a vacuum generator. All tests are carried out at a linear speed of
200 m/min. Tous les échantillons sont préséchés sur un convoyeur muni de fentes aspirantes puis séchés dans un four à air traversant à une température de 100°C avant d'être enroulés.200 m / min. All the samples are pre-dried on a conveyor provided with suction slots and then dried in a through-air oven at a temperature of 100 ° C before being rolled up.
Exemple 1 (comparatif) :Example 1 (comparative):
Le tambour est équipé d'un cylindre C1 constitué d'une tôle perforée en acier inoxydable recouverte d'un tissu en bronze constitué de fils de 0,63 mm de diamètre en sens chaîne et de fils de 0,51 mm en sens trame. Il comporte 9,5 fils par cm en chaîne et 8,5 fils par cm en trame. L'injecteur est alimenté avec une pression de 100 bar. Le non- tissé présente un gain d'épaisseur mais sa surface est perforée de nombreux trous de 0,4 à 0,5 mm2 de surface. Son toucher est plus doux que le non-tissé sans traitement mais les perforations le rendent Inutilisable.The drum is equipped with a cylinder C1 consisting of a perforated sheet of stainless steel covered with a bronze fabric consisting of wires of 0.63 mm in diameter in the warp direction and of wires of 0.51 mm in the weft direction. It has 9.5 threads per cm in warp and 8.5 threads per cm in weft. The injector is supplied with a pressure of 100 bar. The nonwoven has a gain in thickness but its surface is perforated many holes from 0.4 to 0.5 mm 2 in area. Its touch is softer than non-woven non-woven fabric, but the perforations make it unusable.
ξ*fifflPlfi.2 : Le tambour est équipé d'un cylindre C2 constitué d'une tôle perforée en acier inoxydable recouverte d'un tissu métallique en acier inoxydable constitué de fils de 0,11 mm de diamètre en sens chaîne et de fils de 0,14 mm en sens trame. Il comporte 39 fils par cm en chaîne et 36 fils par cm en trame, L'indice de résistance I _ 39.8 +32.1 _ 3,35 alors que, sansξ * fifflPlfi.2: The drum is equipped with a cylinder C2 consisting of a perforated sheet of stainless steel covered with a metallic fabric of stainless steel consisting of wires 0.11 mm in diameter in the warp direction and wires of 0.14 mm in the weft direction. It has 39 threads per cm in warp and 36 threads per cm in weft, The resistance index I _ 39.8 +32.1 _ 3.35 while, without
20 traitement, il est de 3,59.20 treatment, it is 3.59.
L'injecteur est alimenté à une pression de 170 bar. Le non-tissé présente un gain d'épaisseur et son toucher est plus doux que le non-tissé initial. Il est exempt de défauts et de perforations.The injector is supplied at a pressure of 170 bar. The nonwoven has a gain in thickness and its feel is softer than the initial nonwoven. It is free from defects and punctures.
I ffl 3,3 Exemple 3 :I ffl 3.3 Example 3:
L'exemple 2 est répété avec une pression de 230 bar. Le non- tissé présente un gain d'épaisseur et son toucher est plus doux que le non- tissé initial (c'est-à-dire de l'exemple 1) et que celui de l'exemple 2. Il est exempt de défauts et de perforations.Example 2 is repeated with a pressure of 230 bar. The nonwoven has a gain in thickness and its feel is softer than the initial nonwoven (that is to say from Example 1) and than that of Example 2. It is free from defects and perforations.
1 = 3,16 Exemple 4 :1 = 3.16 Example 4:
L'exemple 3 est répété avec une pression de 300 bar. Le non- tissé présente un gain d'épaisseur et son toucher est plus doux que le non- tissé initial et que celui de l'exemple 3. Il est exempt de défauts et de perforations.Example 3 is repeated with a pressure of 300 bar. The nonwoven has a gain in thickness and its feel is softer than the initial nonwoven and that of Example 3. It is free from defects and perforations.
I ≈ 2,87 Exemple 5 (préféré) :I ≈ 2.87 Example 5 (preferred):
Le tambour est équipé d'un cylindre C3 constitué d'une tôle perforée en acier inoxydable recouverte d'un tissu bronze constitué de fils de 0,22 mm de diamètre en sens chaîne et de fils de 0,23 mm en sens trame. Il comporte 25 fils par cm en chaîne et 20 fils par cm en trame. L'Injecteur est alimenté à une pression de 170 bar. Le non-tissé présente un gain d'épaisseur et son toucher est plus doux que le non-tissé de l'exemple 1 et plus doux que les non-tissés des exemples 2, 3 et 4. Il est exempt de défauts et de perforations.The drum is equipped with a cylinder C3 made of a perforated sheet of stainless steel covered with a bronze fabric made up of wires of 0.22 mm in diameter in the warp direction and of wires of 0.23 mm in the weft direction. It has 25 threads per cm in warp and 20 threads per cm in weft. The injector is supplied at a pressure of 170 bar. The nonwoven has a gain in thickness and its feel is softer than the nonwoven of Example 1 and softer than the nonwoven of Examples 2, 3 and 4. It is free from defects and perforations .
I « 3,42 Exemple 6 : (préféré)I 3.42 Example 6: (preferred)
L'exemple 5 est répété avec une pression de 230 bar. Le non- tissé présente un gain d'épaisseur et son toucher est plus doux que le non- tissé de l'exemple 1 et que celui de l'exemple 5. Il est exempt de défauts et de perforations.Example 5 is repeated with a pressure of 230 bar. The nonwoven has a gain in thickness and its feel is softer than the nonwoven of Example 1 and that of Example 5. It is free from defects and perforations.
I = 3,39 Exemple 7 : (préféré) L'exemple 6 est répété avec une pression de 300 bar. Le non- tissé présente un gain d'épaisseur et son toucher est plus doux que le non- tissé de l'exemple 1 et que celui de l'exemple 6. Il est exempt de défauts et de perforations.I = 3.39 Example 7: (preferred) Example 6 is repeated with a pressure of 300 bar. The nonwoven has a gain in thickness and its feel is softer than the nonwoven of Example 1 and that of Example 6. It is free from defects and perforations.
l ≈ 3l ≈ 3
EaampJai :EaampJai:
Le tambour est équipé d'un cylindre C4 constitué d'une tôle perforée cylindrique rigide recouverte d'un manchon en nickel de 0,35 mm d'épaisseur perforé de trous de 250 à 350 microns de diamètre et comportant 100 trous par cm2, les trous étant distribués de manière aléatoire.The drum is fitted with a cylinder C4 consisting of a rigid cylindrical perforated sheet covered with a 0.35 mm thick nickel sleeve perforated with holes from 250 to 350 microns in diameter and comprising 100 holes per cm 2 , the holes being distributed randomly.
L'injecteur est alimenté à une pression de 170 bar. Le non-tissé présente un gain d'épaisseur et son toucher est plus doux que le non-tisséThe injector is supplied at a pressure of 170 bar. The nonwoven has a thickness gain and its feel is softer than the nonwoven
initial. Il est exempt de défauts et de perforations.initial. It is free from defects and punctures.
I a 3,55I a 3.55
L'exemple 8 est répété avec une pression de 230 bar. Le non- tissé présente un gain d'épaisseur et son toucher est plus doux que le non- tissé de l'exemple 1 et que celui de l'exemple 8. Il est exempt de défauts et de perforations.Example 8 is repeated with a pressure of 230 bar. The nonwoven has a gain in thickness and its feel is softer than the nonwoven of Example 1 and that of Example 8. It is free from defects and of perforations.
I • 3,81 Exemple 10 : L'exemple 8 est répété avec une pression de 300 bar. Le non- tissé présente un gain d'épaisseur et son toucher est plus doux que le non- tissé initial et que celui de l'exemple 9. Il est exempt de défauts et de perforations. Il est néanmoins moins doux que le non-tissé de l'exemple 7.I • 3.81 Example 10: Example 8 is repeated with a pressure of 300 bar. The nonwoven has a gain in thickness and its feel is softer than the initial nonwoven and that of Example 9. It is free from defects and perforations. It is nevertheless less soft than the nonwoven of Example 7.
I * 3,21I * 3.21
Les résultats des exemples 1 à 10 sont consignés dans le tableau suivant :The results of Examples 1 to 10 are recorded in the following table:
On voit à ce tableau que l'on obtient des gains en épaisseur de près de 50 % à plus de 100 % tout en ayant des masses volumiques très inférieures à celles du non tissé de l'exemple 1 et pour des rapports de résistance dans le sens marche à la résistance dans le sens travers sensiblement équivalent.
Figure imgf000014_0001
On soumet un non tissé conforme à l'Invention de 140 g/m2 constitué de filaments de polypropylène de 1 ,5 dtex à un test de filtration de particules de chlorure de sodium d'un diamètre de 0,26 microns en suspension dans de l'air. L'appareil est du type TSI CERTITEST 8130. le débit d'air au travers de l'échantillon est de 103 l/min. On obtient une efficacité de 77 % et une perte de charge de 420 10 bar Sur le même appareil et dans les mêmes conditions on teste un produit utilisé habituellement comme médium de filtration de 170 g/m2 constitué de 4 couches de non tissé, spun-bond, melt blown, fibre polypropylène et fibre calandrée polypropylène. L'efficacité est de 74 % et la perte de charge est de 540 10"5 bar. Le non tissé suivant l'Invention a une meilleure efficacité, une moindre perte de charge, tout en ayant une masse surfacique inférieure. Le non tissé suivant l'invention qui a été utilisé a une résistance dans le sens marche de 330 N/50 mm et une résistance dans le sens travers de 300N/50 mm, soit un rapport entre les deux de 1 ,1. Son épaisseur est de 1 ,9 mm et sa masse volumique de 0,074 g/cm3,
We see in this table that we obtain thickness gains from almost 50% to more than 100% while having densities much lower than those of the nonwoven of Example 1 and for strength ratios in the direction to resistance in the cross direction substantially equivalent.
Figure imgf000014_0001
A nonwoven conforming to the invention of 140 g / m2 consisting of polypropylene filaments of 1.5 dtex is subjected to a filtration test of sodium chloride particles with a diameter of 0.26 microns suspended in l 'air. The device is of the TSI CERTITEST 8130 type. The air flow rate through the sample is 103 l / min. We obtain an efficiency of 77% and a pressure drop of 420 10 bar On the same device and under the same conditions we test a product usually used as a filtration medium of 170 g / m2 consisting of 4 layers of nonwoven, spun-bond, melt blown, polypropylene fiber and calendered polypropylene fiber. The efficiency is 74% and the pressure drop is 540 10 "5 bar. The nonwoven fabric according to the invention has better efficiency, less pressure drop, while having a lower surface mass. The nonwoven according to the invention which has been used has a resistance in the running direction of 330 N / 50 mm and a resistance in the transverse direction of 300N / 50 mm, ie a ratio between the two of 1.1. Its thickness is 1.9 mm and its density of 0.074 g / cm3,
s 4,5s 4.5
Figure imgf000015_0001
Figure imgf000015_0001
La douceur est testée par un panel. La douceur la meilleure est notée +++++, la moins bonne. Softness is tested by a panel. The best sweetness is rated +++++, the least good.

Claims

REVENDICATIONS
1. Tissu non-tissé en filaments ayant un rapport de la résistance dans le sens machine à la résistance dans le sens travers inférieur à 1 ,5, de préférence inférieur à 1 ,3 et mieux encore inférieur à 1 ,1 , caractérisé par une masse volumique inférieure à 0,10 g/cm3 et de préférence comprise entre 0,09 et 0,03 g/cm3, et mieux encore comprise entre 0,07 et 0,03 g/cm3.1. Nonwoven fabric of filaments having a ratio of resistance in the machine direction to resistance in the cross direction less than 1.5, preferably less than 1, 3 and better still less than 1, 1, characterized by a density less than 0.10 g / cm 3 and preferably between 0.09 and 0.03 g / cm 3 , and better still between 0.07 and 0.03 g / cm3.
2. Tissu non-tissé suivant la revendication 1 , dont les filaments ont un titre compris entre 0,9 et 10 dtex.2. Nonwoven fabric according to claim 1, the filaments of which have a titer between 0.9 and 10 dtex.
3. Tissu non-tissé suivant la revendication 1 ou 2, caractérisé en ce qu'il a un indice de résistance à la traction dans le sens machine d'au moins 1,5 et dans le sens travers d'au moins 1,3 newton par 50 mm par gramme de non-tissé au m2 et il a un grammage compris entre 12 et 150 g/m2 et de préférence compris entre 12 et 50 g/m2 et mieux encore entre 12 et 30 g/m2.3. Nonwoven fabric according to claim 1 or 2, characterized in that it has a tensile strength index in the machine direction of at least 1.5 and in the cross direction of at least 1.3 newton per 50 mm per gram of nonwoven per m 2 and it has a basis weight between 12 and 150 g / m 2 and preferably between 12 and 50 g / m2 and better still between 12 and 30 g / m2.
4. Procédé de production d'un non-tissé, dans lequel on dépose des filaments provenant d'une tour spun-bond à filière en une nappe ayant une direction longitudinale sur un convoyeur, on comprime la nappe en une nappe comprimée perpendiculairement au plan de la nappe, puis on soumet la nappe comprimée à une consolidation en y projetant des jets d'eau d'un diamètre de 50 à 250 microns sous une pression de 50 à 500 bar, caractérisé en ce que4. Method for producing a nonwoven, in which filaments from a spun-bond spinning tower are deposited in a sheet having a longitudinal direction on a conveyor, the sheet is compressed into a compressed sheet perpendicular to the plane of the tablecloth, then the compressed tablecloth is subjected to a consolidation by spraying there with water jets with a diameter of 50 to 250 microns under a pressure of 50 to 500 bar, characterized in that
- on dépose la nappe sur le convoyeur à l'aide d'au moins une tour spun-bond dont la filière est Inclinée par rapport à la direction longitudinale, et de préférence d'au moins deux tours spunbond dont les deux filières sont inclinées, de préférence de manière opposée, par rapport à la direction longitudinale, d'un angle de 10 à 60°, et de préférence, de 20 à 50e, - ΘR projette les jets d'eau, soit avee interposition de la nappe, sur un tissu métallique dont les fils ont un diamètre compris entre 0,10 mm et 0,35 mm et de préférence entre 0,18 mm et 0,30 mm, et qui a au plus 40 fils par cm et de préférence de 15 à 30 fils par cm en sens chaîne et au plus 40 fils par cm et de préférence de 15 à 30 fils par cm en sens trame, soit, avec interposition de la nappe, sur un manchon mlcroperforé dont les dimensions des perforations sont comprises entre 50 et 600 microns et de préférence entre 150 et 500 microns et qui a un nombre de perforations au cm2 compris entre 50 et 200.the tablecloth is deposited on the conveyor using at least one spun-bond tower, the die of which is Inclined relative to the longitudinal direction, and preferably of at least two spunbond towers, the two channels of which are inclined, preferably opposite, with respect to the longitudinal direction, by an angle of 10 to 60 °, and preferably, from 20 to 50 th , - ΘR projects the water jets, either with the interposition of the tablecloth, on a metallic fabric whose wires have a diameter between 0.10 mm and 0.35 mm and preferably between 0.18 mm and 0.30 mm , and which has at most 40 threads per cm and preferably 15 to 30 threads per cm in warp direction and at most 40 threads per cm and preferably 15 to 30 threads per cm in weft direction, that is, with interposition of the tablecloth, on a mlcroperforated sleeve whose perforation dimensions are between 50 and 600 microns and preferably between 150 and 500 microns and which has a number of perforations per cm 2 between 50 and 200.
5. Procédé suivant la revendication 4, caractérisé en ce que le tissu métallique a une épaisseur comprise entre 0,40 et 0,75 mm.5. Method according to claim 4, characterized in that the metallic fabric has a thickness of between 0.40 and 0.75 mm.
β. Procédé suivant la revendication 4 ou 5, caractérisé en ce que le tissu métallique a une armure toile, sergé ou satin.β. Method according to claim 4 or 5, characterized in that the metallic fabric has a plain, twill or satin weave.
7. Installation de production de non-tissé, caractérisée en ce qu'elle comprend une tour (1 ) spun-bond dont la filière (3) est inclinée d'un angle de 10 à 60° et, de préférence, de 20 à 50° par rapport à la direction de déplacement d'un convoyeur (5) et, de préférence, deux tours spun-bond dont les filières sont inclinées, de préférence de manière opposée, convoyeur sur lequel elle(s) dépose(nt) des filaments en une nappe, un poste de compression de la nappe ainsi formée en une nappe comprimée perpendiculairement à son plan, éventuellement un poste (10) de calandrage de la nappe comprimée, puis un poste (12 à 14) de consolidation par projection de jets d'eau sous pression de la nappe comprimée et éventuellement calandrée à l'aide d'une machine de projection de jets d'eau comprenant un tissu métallique dont les fils ont une diamètre compris entre 0,10 mm et 0,35 mm et qui a plus de 40 fils par cm et de préférence de 15 à 30 fils par cm tant en sens chaîne qu'en sens trame.ou à l'aide d'une machine de projection de jets d'eau à manchon ayant des perforations de 50 à 600 microns et ayant de 20 à 200 perforations au cm2,7. Non-woven production installation, characterized in that it comprises a spun-bond tower (1), the die (3) of which is inclined at an angle of 10 to 60 ° and preferably 20 to 50 ° relative to the direction of movement of a conveyor (5) and, preferably, two spun-bond towers whose dies are inclined, preferably opposite, conveyor on which it (s) deposits (s) filaments in a sheet, a station for compressing the sheet thus formed into a compressed sheet perpendicular to its plane, optionally a station (10) for calendering the compressed sheet, then a station (12 to 14) for consolidation by spraying jets of water under pressure from the compressed and possibly calendered sheet using a water jet spraying machine comprising a metallic fabric whose wires have a diameter of between 0.10 mm and 0.35 mm and which has more than 40 threads per cm and preferably 15 to 30 threads per cm both in direction warp only in the weft direction or using a machine for spraying water jets with sleeves having perforations of 50 to 600 microns and having 20 to 200 perforations per cm 2 ,
8. Filtre, caractérisé en ce qu'il comprend un non tissé suivant l'une quelconque des revendications 1 à 3. I. Produit d'hygiène, earactériaé en ee qu'il comprend un non tissé suivant l'une quelconque des revendications 1 à 3 d'un grammage compris entre 1 et 50 g/cm2. 8. Filter, characterized in that it comprises a nonwoven according to any one of claims 1 to 3. I. Hygiene product, earactériaé ee it comprises a nonwoven according to any one of claims 1 to 3 with a basis weight between 1 and 50 g / cm 2 .
PCT/FR2003/002941 2002-10-18 2003-10-07 Low-density nonwoven fabric and production method and installation therefor and uses WO2004038081A1 (en)

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US10/529,843 US20060014464A1 (en) 2002-10-18 2003-10-07 Low-density nonwoven fabric and production method and installation therefor and uses
EP03776960A EP1556535A1 (en) 2002-10-18 2003-10-07 Low-density nonwoven fabric and production method and installation therefor and uses
AU2003286219A AU2003286219A1 (en) 2002-10-18 2003-10-07 Low-density nonwoven fabric and production method and installation therefor and uses
US11/687,010 US20070173163A1 (en) 2002-10-18 2007-03-16 Low-density nonwoven fabric and production method and installation therefor and uses

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FR0212972A FR2846013B1 (en) 2002-10-18 2002-10-18 NON-WOVEN FABRIC OF SMALL VOLUMIC MASS AND METHOD AND PRODUCTION PLANT AND APPLICATIONS THEREOF
FR02/12972 2002-10-18

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FR2846013B1 (en) 2005-05-27
US20070173163A1 (en) 2007-07-26
AU2003286219A1 (en) 2004-05-13
US20060014464A1 (en) 2006-01-19
CN1705783A (en) 2005-12-07
FR2846013A1 (en) 2004-04-23
EP1556535A1 (en) 2005-07-27
CN101343817A (en) 2009-01-14

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