WO2004030812A3 - Oxidation process and catalysts for the oxidation of alcohols to aldehides - Google Patents

Oxidation process and catalysts for the oxidation of alcohols to aldehides Download PDF

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Publication number
WO2004030812A3
WO2004030812A3 PCT/GB2003/004278 GB0304278W WO2004030812A3 WO 2004030812 A3 WO2004030812 A3 WO 2004030812A3 GB 0304278 W GB0304278 W GB 0304278W WO 2004030812 A3 WO2004030812 A3 WO 2004030812A3
Authority
WO
WIPO (PCT)
Prior art keywords
oxidation
alcohols
aldehides
catalysts
oxidation process
Prior art date
Application number
PCT/GB2003/004278
Other languages
French (fr)
Other versions
WO2004030812A2 (en
Inventor
Paul Nicholas Davey
Ivan Vasilievich Kozhevnikov
Mehdi Musawir
Gordon James Kelly
James Ross Anderson
Original Assignee
Johnson Matthey Plc
Paul Nicholas Davey
Ivan Vasilievich Kozhevnikov
Mehdi Musawir
Gordon James Kelly
James Ross Anderson
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey Plc, Paul Nicholas Davey, Ivan Vasilievich Kozhevnikov, Mehdi Musawir, Gordon James Kelly, James Ross Anderson filed Critical Johnson Matthey Plc
Priority to AU2003299186A priority Critical patent/AU2003299186A1/en
Publication of WO2004030812A2 publication Critical patent/WO2004030812A2/en
Publication of WO2004030812A3 publication Critical patent/WO2004030812A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The invention concerns a catalyst, suitable for use in the oxidation of alcohols to aldehydes, comprising a binary oxide of ruthenium (IV) with either cobalt (III) or copper (II), optionally also including a support material.
PCT/GB2003/004278 2002-10-04 2003-10-02 Oxidation process and catalysts for the oxidation of alcohols to aldehides WO2004030812A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003299186A AU2003299186A1 (en) 2002-10-04 2003-10-02 Oxidation process and catalysts for the oxidation of alcohols to aldehides

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0223020.9 2002-10-04
GB0223020A GB0223020D0 (en) 2002-10-04 2002-10-04 Oxidation process and catalysts for use therein

Publications (2)

Publication Number Publication Date
WO2004030812A2 WO2004030812A2 (en) 2004-04-15
WO2004030812A3 true WO2004030812A3 (en) 2004-06-17

Family

ID=9945297

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2003/004278 WO2004030812A2 (en) 2002-10-04 2003-10-02 Oxidation process and catalysts for the oxidation of alcohols to aldehides

Country Status (3)

Country Link
AU (1) AU2003299186A1 (en)
GB (1) GB0223020D0 (en)
WO (1) WO2004030812A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7740827B2 (en) 2005-09-23 2010-06-22 Mecs, Inc. Ruthenium oxide catalysts for conversion of sulfur dioxide to sulfur trioxide
CN104437488B (en) * 2013-09-25 2016-08-10 中国石油化工股份有限公司 A kind of preparation method of Hexalin gas-phase dehydrogenation preparing cyclohexanone catalyst
CN110193381A (en) * 2019-06-25 2019-09-03 扬州大学 A kind of NHPI-GPTMS-CoOX/SiO2Heterogeneous catalyst and its application and recovery method
CN113332998B (en) * 2021-05-28 2023-05-26 北京化工大学 High-dispersion ruthenium nanoparticle catalyst loaded on brucite and application of catalyst in preparing acetic acid by catalyzing ethanol liquid phase oxidation

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
I. V. KOZHEVNIKOV ET AL.: "HIGHLY EFFICIENT LIQUID-PHASE OXIDATION OF PRIMARY ALCOHOLS TO ALDEHYDES WITH OXYGEN CATALYSED BY RU-CO OXIDE", CHEMICAL COMMUNICATIONS, ROYAL SOCIETY OF CHEMISTRY, 14 May 2003 (2003-05-14), pages 1414 - 1415, XP002277213 *
JI H ET AL: "Highly efficient oxidation of alcohols to carbonyl compounds in the presence of molecular oxygen using a novel heterogeneous ruthenium catalyst", TETRAHEDRON LETTERS, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL, vol. 43, no. 40, 30 September 2002 (2002-09-30), pages 7179 - 7183, XP004385614, ISSN: 0040-4039 *
K. KANEDA ET AL.: "Environmentally friendly alcohol oxidation using heterogeneous catalyst in the presence of air at room temperature", CATALYSIS COMMUNICATIONS, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL, vol. 3, 2002 - 12 October 2002 (2002-10-12), pages 511 - 517, XP002277206 *
K. KANEDA ET AL.: "Highly active trimetallic Ru/CeO2/CoO(OH) catalyst for oxidation of alcohols in the presence of molecular oxygen", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, 2004, pages 161 - 170, XP002277207 *
K. KANEDA ET AL.: "Highly efficient oxidation of alcohols and aromatic compounds catalysed by the Ru-Co-Al hydrotalcite in the presence of molecular oxygen", CHEMICAL COMMUNICATIONS, ROYAL SOCIETY OF CHEMISTRY, 1999, pages 265 - 266, XP002277205 *

Also Published As

Publication number Publication date
WO2004030812A2 (en) 2004-04-15
AU2003299186A1 (en) 2004-04-23
GB0223020D0 (en) 2002-11-13
AU2003299186A8 (en) 2004-04-23

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