WO2004009903A1 - Paper machine roll cover - Google Patents
Paper machine roll cover Download PDFInfo
- Publication number
- WO2004009903A1 WO2004009903A1 PCT/EP2003/007816 EP0307816W WO2004009903A1 WO 2004009903 A1 WO2004009903 A1 WO 2004009903A1 EP 0307816 W EP0307816 W EP 0307816W WO 2004009903 A1 WO2004009903 A1 WO 2004009903A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hdpe particles
- particles
- roll
- layer
- hdpe
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
- D21G1/00—Calenders; Smoothing apparatus
- D21G1/02—Rolls; Their bearings
- D21G1/0233—Soft rolls
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F3/00—Press section of machines for making continuous webs of paper
- D21F3/02—Wet presses
- D21F3/08—Pressure rolls
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49544—Roller making
- Y10T29/49547—Assembling preformed components
- Y10T29/49549—Work contacting surface element assembled to core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49544—Roller making
- Y10T29/4956—Fabricating and shaping roller work contacting surface element
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49544—Roller making
- Y10T29/4956—Fabricating and shaping roller work contacting surface element
- Y10T29/49563—Fabricating and shaping roller work contacting surface element with coating or casting about a core
Definitions
- the present invention pertains generally to industrial roll covers and, more particularly, to fillers provided in elastomeric roll covers used on paper machine rolls.
- Paper machines in paper mills use a wide variety of different types of rolls in different environments for different purposes. Rolls on paper machine can be used for merely transporting the web from one location to another, or can be used in direct contact with the web or with paper machine clothing to treat the web, such as by pressing.
- the conditions under which paper machine rolls function can be quite harsh, including high temperatures and high pressures in the presence of corrosive chemicals.
- operating speeds are high, and ever increasing, and paper machine operation is substantially continuous.
- roll covers having a top layer made of a mixture of elas- tomeric material and ultra high molecular weight polyethylene (UHMWPE).
- UHMWPE ultra high molecular weight polyethylene
- the mixture includes about 100 parts elastomeric material by weight, and between about 25 and 50 parts UHMWPE by weight.
- Such roll covers may have a hardness between 10 to 50 P&J hardness scale.
- a roll cover comprising a mixture of an elastomer and UHMWPE as disclosed above has utility in paper machines for some paper making processes, and in some positions on the paper machine, it has certain shortcomings as well.
- a paper machine roll cover directly contacting the paper web must exhibit good sheet release properties. That is, the paper web, which may still contain a substantial amount of water and have minimal sheet strength, must release from the roll surface. If the web sticks or adheres to the roll surface, a web brake will occur, with the resultant waste of manufacturing time and product. Due to the large particle size of UHMWPE commonly used in rubber compounds, exposed particles on the cover surface limit the attainable surface smoothness, and thereby the sheet release properties of the roll cover.
- Adhesion between the elastomer matrix and the UHMWPE particles can be inconsistent, resulting in surface marking on the cover that translates to defects in the web being processed.
- UHMWPE fibers and particles are expensive to obtain, thus substantially increasing the cost of the roll cover. Since paper machine roll covers commonly are re-ground with some frequency, and may require re-covering after a limited number of re-grindings, the additional cost from the use of UHMWPE fibers or particles can increase substantially the cost of operating a paper machine.
- the present invention provides an improved polyethylene particle filler for an elastomeric layer of a paper machine roll by modifying the surfaces of the polyethylene particles and by using particles of smaller particle size.
- the invention comprises, in one form thereof, a surface layer for a paper machine roll cover, having a mixture of an elastomeric material and surface modified polyethylene particles.
- the invention provides a paper machine roll with a roll shell; an adhesive layer on the roll shell; and an outer layer of a mixture of an elastomeric material and surface modified polyethylene particles.
- the invention provides a method of covering a paper machine roll having steps of providing a roll shell; applying an adhesive layer to the roll shell; providing polyethylene particles; modifying the surfaces of the polyethylene particles; mixing the surface modified polyethylene particles with an elastomeric material; and applying the mixture of surface modified polyethylene particles and elastomeric material to the roll shell.
- An advantage of the present invention is providing a paper machine roll cover that is resistant to harsh operating conditions of temperature, pressure and chemicals.
- Another advantage of the present invention is providing a paper machine roll cover that can be ground to a high degree of smoothness, exhibits good sheet release properties and is resistant to marking.
- a further advantage of the present invention is providing a paper machine roll cover that is less expensive to manufacture than comparable paper machine roll covers of other compositions.
- Fig. 1 is a perspective view of a paper machine roll having a cover according to the present invention.
- Fig. 2 is an enlarged, fragmentary cross-sectional view of the roll shown in Fig. 1, taken on line 2-2 of Fig. 1.
- Corresponding reference characters indicate corresponding parts throughout the several views.
- the exemplification set out herein illustrates one preferred embodiment of the invention, in one form, and such exemplification is not to be construed as limiting the scope of the invention in any manner.
- a paper machine roll 10 that includes a roll cover 12 in accordance with the present invention.
- Cover 12 is provided on a roll shell or core 14.
- core 14 is formed of steel or other metals and is substantially cylindrical and hollow.
- the length and width of core 12 will vary depending upon the paper machine in which the roll is to be installed, and the position in the paper machine in which the roll is to be used.
- core 14 extends the width of the paper machine, and may vary in diameter from less than a foot to six feet or more in diameter.
- core 14 will be provided with suitable stub shafts 16, through shafts, journals, bearings (not shown) and the like for mounting roll 10 in a paper machine.
- roll 10 maybe a controlled deflection roll including internal structures (not shown) for maintaining the desired straightness across the face of the roll.
- roll 10 will be provided in a paper machine in nipped relationship to another roll or rolls. It also should be understood that the present invention is described for use in a paper machine, but also may have application and use in other industrial rolls. Paper machine rolls are a particularly advantageous use of the invention.
- Cover 12 is a continuous rubber coating provided around the surface of core 14, and extends throughout the effective working face-length of roll 10. Hydrophobic and hydrophilic properties of rubber affect the performance of roll covers used in the manufacture of paper. The hydrophobic and hydrophilic properties affect the wet paper web attraction or release tendency from the roll cover surface, and consequently influence which cover of two adjacent covered rolls the paper web will follow. The tendency of the wet web to follow one roll or another can be used to guide the wet web through the paper machine. If the sheet has a tendency to follow a roll surface which it is not intended to follow, problems such as flutter, vibrations and sheet breaks can occur.
- the hydrophobic and hydrophilic properties of the cover affect the attraction of the size or coating solution to the surface of the cover, thereby influencing the thickness and the evemiess of the size or coating distribution on the surface of the cover, and hence the quality of the size or coating operation. It has been observed that the addition of High Density Polyethylene (HDPE) into rubber compounds varies the hydrophobic and hydrophilic properties of a surface coated with the rubber compound.
- HDPE High Density Polyethylene
- references to HDPE or high density polyethylene particles shall be understood to mean polyethylene having an average molecular weight of less than about nine-hundred thousand (900,000), and preferably an average molecular weight of about one-hundred thousand (100,000).
- HDPE particles having a specific gravity of about 0.935 and higher have been found to be suitable, although particles having specific gravity greater than or less than this range also can be used.
- Preferred HDPE particles have had a specific gravity range from about 0.94 to about 0.96.
- a hydrophilic rubber compound surface can be made gradually more hydrophobic by the addition of HDPE particles into the rubber compound formulation.
- a hydrophilic rubber compound having no HDPE can be made semi-hydrophobic by addition of as little as 12 phr (parts per hundred of rubber) of HDPE, and can be made mostly hydrophobic by the addition of even more HDPE.
- HDPE high density polyethylene
- rubber compounds also affects the physical properties of the rubber compounds, resulting in improved resistance to abrasion and fracture.
- the amount of HDPE should be controlled, because the tendency of the compound to recover from indentation or marking suffers with an increased concentration of HDPE in the cover. Control- ling the amount of HDPE from about 10 phr to about 50 phr results in rubber compound properties with improved abrasion and fracture resistance, with acceptable indentation and marking resistance properties for typical paper machine applications.
- the desired surface modification of the HDPE particles can be achieved by at least two methods. In a reactive gas process controlled oxidation occurs. The reactive gas process is believed to modify the HDPE particle surfaces to a significant penetration depth. As a result of the free radical mechanism, cross-linking of the surface molecules on the particles occurs in concert with the treatment. The cross-linking locks the modified areas in place, making the treatment a permanent treatment to the HDPE particle surface.
- HDPE particles In a second process, known as the plasma treatment process, plasma is used to ablate the surface of the molecules as modification occurs. The result is a shallower treated layer, and the treatment is sometimes seen as less permanent. For these reasons, the reactive gas process is preferred for treating HDPE particles in accordance with the present invention.
- Preferred HDPE particles for the present invention have a surface energy of about 55+ dynes/cm.
- the composition of the matrix component of cover 12 can be varied. Load, speed, roll cover position and chemical environment can affect the bonding of cover 12 to metal core 14.
- Three basic methods have been used. In a first method, an adhesive layer 20 is applied to core 14, followed by a hard base layer 22, usually 80 Shore D or greater in hardness. An intermediate layer 24, which is softer than base layer 22 is applied thereover, followed by a top stock layer or surface layer 26. Modified HDPE particles 28 are added to top stock layer 26.
- a hard or semi-hard material which may be the base layer 22 or inte ⁇ nediate layer 24 from the first mentioned method, is bonded directly on top of adhesive layer 20 or on core 14, followed by the top stock layer 26 having modified HDPE particles 28 therein.
- the top stock layer 26 having modified HDPE particles 28 therein is applied directly on top of core 14, perhaps with the use of adhesive layer 20 between the surface of core 14 and the top stock layer 26.
- base layer 22 and intermediate layer 24 are suitable to be used in base layer 22 and intermediate layer 24 for the three-layer construction.
- Roll cover manufacturers have preferred formulations for base layer 22 and intermediate layer 24, which may vary from one manufacturer to another.
- Core 14 is prepared by cleaning and blasting with an abrasive grit, and may be primed with a suitable adhesive 20.
- a base layer 22 thickness of about 2 mm or more is applied by extrusion onto core 14 surface. Commonly, base layer 22 is between about 2 mm and about 6 mm thick, most commonly about 4 mm thick, although thinner or thicker layers can be used.
- An intermediate layer 24 of 2 mm or more is applied directly on top of base layer 22 by extrusion.
- intermediate layer 24 is between about 2mm and 4mm thick, but can be thicker.
- the top stock layer 26 can be any of several compounds applied directly on top of intermediate layer 24, again by extrusion. The selection of elastomeric materials used in top stock layer 26 depends on the paper machine position and the operating conditions in which the roll is to be installed. Hardness and other physical properties can be varied. It should be noted that roll cover manufacturers each have their own preferred formulations for each of the layers 22, 24 and the matrix component of layer 26.
- a first (or bottom) layer at least about 2 mm thick is applied by extrusion directly on top of the previously cleaned and abrasive blasted, adhesive primed metal core 14.
- the bottom layer in the two-layer method is between about 2 mm and about 6mm thick, but can be thicker.
- Top stock layers 26 as those described above for the first method can be applied directly to the first applied layer in this method.
- any of the top stocks described above are applied by extrusion directly on top of the previously cleaned, abrasive blasted, adhesive primed metal core surface.
- extrusion is merely one of the acceptable application techniques, and other application techniques also can be used.
- Mixtures including elastomeric material of about 100 parts by weight mixed with surface modified HDPE particles of between about 10 parts by weight and about 80 parts by weight are preferred, although mixtures having the higher concentrations of particles may exhibit poorer denting resistance.
- Surface modified HDPE particles commonly are available in average sizes of between 18 microns and 500 microns. Smaller average particle sizes, of from about 14 microns to about 22 microns, are preferred in the present invention.
- Preferred HDPE particles of the present invention have molecular weights of less than about 600,00, and preferably only about 100,000, as compared with UHWMPE particles which have a molecular weight many times greater.
- HDPE particles are commonly available in significantly smaller average particle sizes than are UHWMPE particles, such as, for example, 18 microns.
- surface modified HDPE particles of 18 microns average size in the covers mentioned above results in a cover with the required surface smoothness for critical paper machine operations and sliding abrasion resistance virtually as good as that of other filled elastomers.
- HDPE particles of the preferred size are considerably less expensive than the even more course UHMWPE particles.
Landscapes
- Paper (AREA)
- Rolls And Other Rotary Bodies (AREA)
- Replacement Of Web Rolls (AREA)
- Machines For Manufacturing Corrugated Board In Mechanical Paper-Making Processes (AREA)
- Packaging Of Special Articles (AREA)
- Unwinding Webs (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE60323846T DE60323846D1 (en) | 2002-07-19 | 2003-07-18 | PAPER MACHINE ROLLER COVER AND METHOD FOR THE PRODUCTION THEREOF |
SI200331466T SI1534891T1 (en) | 2002-07-19 | 2003-07-18 | Paper machine roll cover and method of covering a paper machine roll |
EP03765040A EP1534891B1 (en) | 2002-07-19 | 2003-07-18 | Paper machine roll cover and method of covering a paper machine roll |
AU2003257477A AU2003257477A1 (en) | 2002-07-19 | 2003-07-18 | Paper machine roll cover |
CA002492928A CA2492928A1 (en) | 2002-07-19 | 2003-07-18 | Paper machine roll cover |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/198,855 US7014604B2 (en) | 2002-07-19 | 2002-07-19 | Paper machine roll cover |
US10/198,855 | 2002-07-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004009903A1 true WO2004009903A1 (en) | 2004-01-29 |
Family
ID=30443188
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/007816 WO2004009903A1 (en) | 2002-07-19 | 2003-07-18 | Paper machine roll cover |
Country Status (8)
Country | Link |
---|---|
US (1) | US7014604B2 (en) |
EP (1) | EP1534891B1 (en) |
AT (1) | ATE409775T1 (en) |
AU (1) | AU2003257477A1 (en) |
CA (1) | CA2492928A1 (en) |
DE (1) | DE60323846D1 (en) |
SI (1) | SI1534891T1 (en) |
WO (1) | WO2004009903A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10287731B2 (en) * | 2005-11-08 | 2019-05-14 | Stowe Woodward Licensco Llc | Abrasion-resistant rubber roll cover with polyurethane coating |
JP4861109B2 (en) * | 2006-09-27 | 2012-01-25 | 富士通株式会社 | Image data processing apparatus, image data processing method, image data processing program, and imaging apparatus |
FI20096355A0 (en) | 2009-12-18 | 2009-12-18 | Metso Paper Inc | COATING APPLICABLE TO PART OF FIBER MACHINE MACHINE |
DE102010011401A1 (en) * | 2010-03-15 | 2011-09-15 | Oerlikon Textile Components Gmbh | idler pulley |
WO2013107721A1 (en) * | 2012-01-20 | 2013-07-25 | Voith Patent Gmbh | Roller cover containing mineral filler material and polymer filler material |
DE202012012489U1 (en) | 2012-01-20 | 2013-02-01 | Voith Patent Gmbh | Roll cover containing a matrix and thus covalently bonded polymer filler |
BR112014022248B1 (en) | 2012-04-06 | 2022-02-01 | Stowe Woodward Licensco, Llc | INDUSTRIAL CYLINDER AND METHOD OF CONSTRUCTION OF AN INDUSTRIAL CYLINDER HAVING A HYDROPHOBIC AND/OR AMPIPHOBIC COATING |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4880879A (en) | 1988-02-18 | 1989-11-14 | Air Products And Chemicals, Inc. | Abrasion resistant composite material and process for making the same |
US6328681B1 (en) | 1999-01-21 | 2001-12-11 | Stowe Woodward Inc. | Elastomeric roll cover with ultra high molecular weight polyethylene filler |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1229892A (en) * | 1967-05-05 | 1971-04-28 | ||
US3920325A (en) * | 1974-09-09 | 1975-11-18 | Xerox Corp | Moisture stable bias transfer roll |
CA1147133A (en) | 1980-08-29 | 1983-05-31 | Denis Thibault | Method for manufacturing rollers or idlers |
US4768761A (en) * | 1984-03-21 | 1988-09-06 | The B. F. Goodrich Company | Rubber-plastic composite |
JPS6256118A (en) | 1985-09-05 | 1987-03-11 | Mitsuboshi Belting Ltd | Manufacture of ultra-high-molecular-weight polyethylene lining roll |
US4972030A (en) | 1988-08-22 | 1990-11-20 | Air Products And Chemicals, Inc. | Abrasion resistant composite coating material and process for making the same |
JP2922597B2 (en) | 1990-07-02 | 1999-07-26 | バンドー化学株式会社 | Resin composition for magnet roll gap holding roller of developing device and magnet roll gap holding roller using the same |
JP2922596B2 (en) | 1990-07-02 | 1999-07-26 | バンドー化学株式会社 | Roller holding magnet roll gap of developing device |
JPH04272839A (en) | 1991-02-27 | 1992-09-29 | Nippon Petrochem Co Ltd | Composite material roll and manufacture thereof |
TW254883B (en) | 1991-04-03 | 1995-08-21 | Mitsui Petroleum Chemicals Ind | |
JPH0516298A (en) | 1991-07-16 | 1993-01-26 | Mitsui Petrochem Ind Ltd | Ultra-high-molecular-weight polyethylene coated roll |
JP2830526B2 (en) | 1991-08-16 | 1998-12-02 | 日立電線株式会社 | Rubber roller for paper feed of OA equipment |
JPH0836281A (en) * | 1994-05-18 | 1996-02-06 | Bridgestone Corp | Paper feed roll and paper feeder |
JPH09309958A (en) | 1996-05-24 | 1997-12-02 | Hitachi Cable Ltd | Rubber roller for paper conveying |
WO1997047460A1 (en) | 1996-06-10 | 1997-12-18 | Fluoron, Inc. | Heat-shrinkable uhmv polymer film, tubing, and roll covers |
EP0916111B1 (en) * | 1996-07-31 | 2001-11-28 | Agfa-Gevaert N.V. | Sheet material processing apparatus |
JPH10250870A (en) | 1997-03-12 | 1998-09-22 | Inoac Corp | Paper feeding pinch roller |
US5887517A (en) | 1997-10-24 | 1999-03-30 | Beloit Technologies, Inc. | Multiple hardness roll cover |
JP2000153933A (en) * | 1998-11-18 | 2000-06-06 | Alps Electric Co Ltd | Pressure contact roller |
US6187867B1 (en) | 1999-03-26 | 2001-02-13 | Zeon Chemicals L.P. | Hydrogenated nitrile rubber compositions containing thermoplastic polyolefins |
-
2002
- 2002-07-19 US US10/198,855 patent/US7014604B2/en not_active Expired - Lifetime
-
2003
- 2003-07-18 AT AT03765040T patent/ATE409775T1/en active
- 2003-07-18 EP EP03765040A patent/EP1534891B1/en not_active Expired - Lifetime
- 2003-07-18 SI SI200331466T patent/SI1534891T1/en unknown
- 2003-07-18 DE DE60323846T patent/DE60323846D1/en not_active Expired - Lifetime
- 2003-07-18 AU AU2003257477A patent/AU2003257477A1/en not_active Abandoned
- 2003-07-18 WO PCT/EP2003/007816 patent/WO2004009903A1/en active IP Right Grant
- 2003-07-18 CA CA002492928A patent/CA2492928A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4880879A (en) | 1988-02-18 | 1989-11-14 | Air Products And Chemicals, Inc. | Abrasion resistant composite material and process for making the same |
US6328681B1 (en) | 1999-01-21 | 2001-12-11 | Stowe Woodward Inc. | Elastomeric roll cover with ultra high molecular weight polyethylene filler |
Also Published As
Publication number | Publication date |
---|---|
EP1534891B1 (en) | 2008-10-01 |
US20040014573A1 (en) | 2004-01-22 |
EP1534891A1 (en) | 2005-06-01 |
SI1534891T1 (en) | 2009-08-31 |
CA2492928A1 (en) | 2004-01-29 |
ATE409775T1 (en) | 2008-10-15 |
US7014604B2 (en) | 2006-03-21 |
DE60323846D1 (en) | 2008-11-13 |
AU2003257477A1 (en) | 2004-02-09 |
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