WO2004003044A3 - Dynamers: polymeric materials exhibiting reversible formation and component exchange - Google Patents

Dynamers: polymeric materials exhibiting reversible formation and component exchange Download PDF

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Publication number
WO2004003044A3
WO2004003044A3 PCT/IB2003/002454 IB0302454W WO2004003044A3 WO 2004003044 A3 WO2004003044 A3 WO 2004003044A3 IB 0302454 W IB0302454 W IB 0302454W WO 2004003044 A3 WO2004003044 A3 WO 2004003044A3
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WO
WIPO (PCT)
Prior art keywords
exchange
original
polymers
monomer units
dynamers
Prior art date
Application number
PCT/IB2003/002454
Other languages
French (fr)
Other versions
WO2004003044A8 (en
WO2004003044A2 (en
Inventor
Jean-Marie Lehn
W G Skene
Original Assignee
Jean-Marie Lehn
W G Skene
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jean-Marie Lehn, W G Skene filed Critical Jean-Marie Lehn
Priority to AU2003240211A priority Critical patent/AU2003240211A1/en
Publication of WO2004003044A2 publication Critical patent/WO2004003044A2/en
Publication of WO2004003044A3 publication Critical patent/WO2004003044A3/en
Publication of WO2004003044A8 publication Critical patent/WO2004003044A8/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08G12/06—Amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08G12/06—Amines
    • C08G12/08—Amines aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Alternating co-polymers involving the polycondensation of dihydrazides or diamines with dialdehydes reversibly exchange either one or both of their fundamental repeating monomer units in the presence of different monomer units. Furthermore, upon exchange of one of the repeating monomer units, the original monomer unit displaced can be re-introduced into the polymer, or the remaining unexchanged original monomer unit may also be interchanged. The polymers subjected to monomer exchange/interchange exhibit vastly different physical properties than those of the original unexchanged polymer. These dynamic, reversible polymers are therefore able to incorporate, decorporate or reshuffle their constituting monomers, in particular, with respect to environmental physical or chemical factors (heat, light, chemical entities, etc.). They thus have combinatorial features and represent adaptive materials.
PCT/IB2003/002454 2002-06-28 2003-06-24 Dynamers: polymeric materials exhibiting reversible formation and component exchange WO2004003044A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003240211A AU2003240211A1 (en) 2002-06-28 2003-06-24 Dynamers: polymeric materials exhibiting reversible formation and component exchange

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39230802P 2002-06-28 2002-06-28
US60/392,308 2002-06-28

Publications (3)

Publication Number Publication Date
WO2004003044A2 WO2004003044A2 (en) 2004-01-08
WO2004003044A3 true WO2004003044A3 (en) 2004-05-13
WO2004003044A8 WO2004003044A8 (en) 2004-06-24

Family

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Family Applications (1)

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PCT/IB2003/002454 WO2004003044A2 (en) 2002-06-28 2003-06-24 Dynamers: polymeric materials exhibiting reversible formation and component exchange

Country Status (2)

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AU (1) AU2003240211A1 (en)
WO (1) WO2004003044A2 (en)

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WO2005073265A1 (en) 2004-02-04 2005-08-11 Universite De Montreal Conjugated thiophenes having conducting properties and synthesis of same
JP2007269819A (en) * 2004-07-01 2007-10-18 Mitsui Chemicals Inc Self-restorable material
EP1897901B1 (en) * 2005-06-30 2015-03-11 Mitsui Chemicals, Inc. Biodegradable polymer, production method thereof, molded product thereof, and use thereof
US20100041863A1 (en) * 2008-08-18 2010-02-18 Xerox Corporation Semiconducting polymers
FR2943559B1 (en) 2009-03-30 2011-04-08 Centre Nat Rech Scient AUTOSUPPORTED DYNAMIC POLYMERIC MEMBRANE, PROCESS FOR PREPARATION AND USE.
CN103242128B (en) * 2013-05-28 2015-02-18 苏州大学 Preparation method of 9,10-dihydrophenanthrene derivatives
WO2015018928A1 (en) * 2013-08-09 2015-02-12 Universiteit Gent Urazole compounds
US9453099B2 (en) * 2014-03-12 2016-09-27 The Regents Of The University Of Colorado, A Body Corporate Covalently cross-linked malleable polymers and methods of use
WO2016113761A1 (en) 2015-01-15 2016-07-21 Council Of Scientific & Industrial Research Hydrophobic polymer-supported lewis acid catalyst and process for the preparation thereof
CN106117079A (en) * 2016-06-28 2016-11-16 潍坊芝麻开门化工有限公司 A kind of adipic dihydrazide preparation method
KR20190019204A (en) 2016-07-15 2019-02-26 브레우어 사이언스 인코포레이션 Dielectric materials for laser cutting
CN106946733A (en) * 2017-04-26 2017-07-14 重庆丽澄环保科技有限公司 A kind of method for preparing adipic dihydrazide
CN107417533B (en) * 2017-08-29 2022-04-01 山东清水化工有限公司 Dimethyl isophthalate and process for producing the same
CN111100012B (en) * 2019-12-16 2021-01-22 上海交通大学 Method for preparing m-phenylenediamine
CN114195967B (en) * 2021-11-25 2023-04-07 江南大学 Bio-based thermosetting resin capable of being synthesized and recovered in water, preparation method and application
WO2024135567A1 (en) * 2022-12-21 2024-06-27 国立研究開発法人物質・材料研究機構 Polymer and method for synthesis thereof
CN116199841B (en) * 2023-02-21 2023-10-03 中国科学院宁波材料技术与工程研究所 Antibacterial agent and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354122A (en) * 1962-12-21 1967-11-21 Du Pont Polymers of polyacylhydrazones and process of preparation therefor
US3506614A (en) * 1968-01-08 1970-04-14 Celanese Corp Preparation of oxymethylene and methylene sulfide polymers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354122A (en) * 1962-12-21 1967-11-21 Du Pont Polymers of polyacylhydrazones and process of preparation therefor
US3506614A (en) * 1968-01-08 1970-04-14 Celanese Corp Preparation of oxymethylene and methylene sulfide polymers

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
D.C.R.HOCKLESS, L.F.LINDOY, G.F.SWIEGERS, S.B.WILD: "Acid-catalysed rearrangements between 3,4-dihydro-2H-1,5-benzooxazocine and benzothiazocine and their macrocyclic (16-membered, 24-membered and 32 membered) oligomers.", J.CHEM.SOC.,PERKIN TRANS. 1, 1998, pages 117 - 122, XP002270859 *
HIDEYUKI OTSUKA, KOICHIRO AOTANI, ATSUSHI TAKAHARA: "A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO-containing poly(alkoxyamine ester)s.", CHEM.COMM., 2002, pages 2838 - 2839, XP002270860 *
J.M. LEHN: "dynamic combinatorial chemistry and virtual combinatorial libraries", CHEM.EUR.J., vol. 5, no. 9, 1999, pages 2455 - 2463, XP002270857 *
S.J.ROWAN, S.J.CANTRILL, G.R.L.COUSINS, J.K.M. SANDERS, J.FRASER STODDART: "Dynamic Covalent Chemistry", ANGEW.CHEM.INT.ED., vol. 41, 2002, pages 898 - 952, XP002270858 *

Also Published As

Publication number Publication date
WO2004003044A8 (en) 2004-06-24
AU2003240211A1 (en) 2004-01-19
WO2004003044A2 (en) 2004-01-08
AU2003240211A8 (en) 2004-01-19

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