WO2003084365A1 - Tooth brush - Google Patents

Tooth brush Download PDF

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Publication number
WO2003084365A1
WO2003084365A1 PCT/JP2002/003634 JP0203634W WO03084365A1 WO 2003084365 A1 WO2003084365 A1 WO 2003084365A1 JP 0203634 W JP0203634 W JP 0203634W WO 03084365 A1 WO03084365 A1 WO 03084365A1
Authority
WO
WIPO (PCT)
Prior art keywords
calcium carbonate
product
calcite
shell
tooth brush
Prior art date
Application number
PCT/JP2002/003634
Other languages
French (fr)
Japanese (ja)
Inventor
Koji Sasaya
Original Assignee
Chafflose Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chafflose Corporation filed Critical Chafflose Corporation
Priority to AU2002249575A priority Critical patent/AU2002249575A1/en
Priority to GB0422309A priority patent/GB2403896B/en
Priority to CNA028287282A priority patent/CN1625357A/en
Priority to KR10-2004-7016225A priority patent/KR20040108727A/en
Priority to US10/510,534 priority patent/US20060162109A1/en
Priority to PCT/JP2002/003634 priority patent/WO2003084365A1/en
Publication of WO2003084365A1 publication Critical patent/WO2003084365A1/en
Priority to HK05102338A priority patent/HK1069964A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A46—BRUSHWARE
    • A46B—BRUSHES
    • A46B15/00—Other brushes; Brushes with additional arrangements
    • A46B15/0002—Arrangements for enhancing monitoring or controlling the brushing process
    • A—HUMAN NECESSITIES
    • A46—BRUSHWARE
    • A46D—MANUFACTURE OF BRUSHES
    • A46D1/00—Bristles; Selection of materials for bristles
    • A—HUMAN NECESSITIES
    • A46—BRUSHWARE
    • A46D—MANUFACTURE OF BRUSHES
    • A46D1/00—Bristles; Selection of materials for bristles
    • A46D1/006—Antimicrobial, disinfectant bristles, handle, bristle-carrier or packaging
    • A—HUMAN NECESSITIES
    • A46—BRUSHWARE
    • A46D—MANUFACTURE OF BRUSHES
    • A46D1/00—Bristles; Selection of materials for bristles
    • A46D1/04—Preparing bristles
    • A—HUMAN NECESSITIES
    • A46—BRUSHWARE
    • A46D—MANUFACTURE OF BRUSHES
    • A46D9/00—Machines for finishing brushes
    • A46D9/06—Impregnating
    • A—HUMAN NECESSITIES
    • A46—BRUSHWARE
    • A46B—BRUSHES
    • A46B2200/00—Brushes characterized by their functions, uses or applications
    • A46B2200/10—For human or animal care
    • A46B2200/1066—Toothbrush for cleaning the teeth or dentures

Definitions

  • the present invention relates to a tooth brush
  • the tooth brushes used in conventional tooth brushing are intended to remove the above-mentioned plaque. Although it has a certain effect, it does not mean that the activity of the above fungi is suppressed.
  • the present inventor has increased the natural strength of natural materials obtained, and in particular, the use of canoles such as shells that have been disposed of as waste. It has been noticed that the product obtained by sintering and pulverizing the natural porous material that contains the antibacterial agent is not harmful to the human body but has antibacterial properties. Accordingly, the present invention has been made in view of the above circumstances, and has ascertained that a toothbrush has the above-mentioned product, and suppresses the activity of fungi in the mouth due to the antibacterial property of the product. Section The aim is to prevent tooth decay and to maintain the cleanness of tooth brushes in the mouth. Disclosure of invention
  • the present invention has been made in view of the above problems, and is obtained by mixing a product obtained by crushing a shell provided with a crystalline structure of a calcite-type structure of carbonated calcium carbonate.
  • a synthetic resin wool or a synthetic resin handle mixed with the crushed product of a shell with a crystalline structure of calcite-type calcium carbonate is solved by providing a toothbrush characterized by having at least one of them.
  • Another invention relates to a coating material containing a product obtained by pulverizing a shell having a crystal structure of a calcite-type structure of calcium carbonate. Is coated with a coating material containing a crushed product of a wool or a shell with a calcite-type crystal structure of carbonated calcium carbonate
  • a tooth brush characterized in that it has at least one of a handle and a tooth brush, which solves the above-mentioned problem by providing the tooth brush.
  • the product is a shell powder having a crystal structure of a calcite-type structure of calcium carbonate, and the product is a carbonate powder composed of porous granules.
  • a mixture of a calcium powder and a calcium oxide powder obtained by calcining the calcium carbonate powder or a water-soluble substance of the mixture is preferred.
  • FIG. 1 is an explanatory diagram showing an example of a toothbrush according to the present invention.
  • FIG. 2 is an explanatory diagram showing a cross section of the handle of the toothbrush in the second example.
  • FIG. 3 is an explanatory diagram showing a cross section of a tooth brush hair in the second example.
  • reference numeral 1 denotes a tooth brush
  • the tooth brush 1 is attached to a tip of a handle 2 molded from a synthetic resin material.
  • a plurality of hairs 3 are implanted and laid.
  • the hair 3 implanted at the tip of the tooth brush 1 is made of a synthetic resin material selected for the tooth brush hair and calcite calcium carbonate. It uses a synthetic resin material for hair formation that mixes a product obtained by pulverizing a shell having a crystal structure with a type structure.
  • the synthetic resin material selected for the handle of the tooth brush and the shell provided with the crystal structure of the calcite-type structure of calcium carbonate. It was molded using a synthetic resin material for forming a pattern, into which a product obtained by pulverizing the mixture was mixed.
  • the shell used is a crystal structure with a type structure.
  • This shell is a scallop shell, The scallop shell is different from other shells in that most of this is the crystal structure.
  • scallop is described in its ecology as "swimming in the sea” by opening and closing shells and releasing seawater vigorously to the outside. It is characterized by the ability to move quickly and escape from captors (such as hamsters), and has a large scallop to allow this movement.
  • the shell itself is required to be relatively thin, light, and strong.
  • the calcite-type crystal structure of calcium carbonate has a leaf-like structure, the inner surface of the shell is formed, and the inner layer of the shell (the core layer in the direction of the shell thickness).
  • the calcite-type crystal structure of calcium carbonate has a plate-like structure, and the structure between the shell side and the shell inner layer is the main part of the shell (surface layer and The part (excluding the hinge part) is shaped and laid, so it is thin and lightweight, but also strong.
  • the calcite-type crystal structure of calcium carbonate becomes a leaf-like structure (the needle-like crystal is a sword-like shape).
  • the inner shell is composed of a calcite-type crystal structure of calcium carbonate and a plate-like structure (veneer). Layers of needle-like crystals arranged in the same direction, like a slab, overlap several times, and the direction of the needle-like crystals is different for each layer. Therefore, as will be described later, the granules obtained by crushing the shell of this scallop are porous with a calcite-type structure remaining. In contrast, in other shells, calcium carbonate crystals spread in a plane and overlapped. As a result, the pearly luster can be obtained, but when it is made into granules, it does not exhibit porosity.
  • scallop shells are used as a raw material to obtain the product, but after removing the scallop scallop, it is considered unnecessary. What has been treated can be used, and waste can be used effectively.
  • waste shells are collected, dried in the sun, dried and hardened.
  • the shells cured by solar drying are ground to a particle size of about 200 m.
  • the crushing method itself is not particularly limited, and an existing crushing device may be used. In this way, a canola carbonate powder can be obtained, and the granules are porous granules.
  • this product is mixed with a synthetic resin material selected for hair, and the mixture is subjected to filament firing to obtain the hair 3, and the hair 3 is obtained. Can be planted in the required position of handle 2.
  • the product is mixed with the synthetic resin material selected for the pattern, and the resulting product is molded to obtain the pattern 2.
  • the calcium carbonate powder is as described above. It consists of unique porous granules of scallop shell powder, which is a natural product.
  • the product is composed of scallop shell powder, which is a natural product, and has the antibacterial properties inherent to natural products in general. It has the effect of suppressing the reproduction of spores and power. Then, in this tooth brush, raw and synthetic substances are exposed on the surface of the handle 2 and the hair 3, so that the tooth brush 1 If you brush your teeth, the fungus activity will be suppressed by the antibacterial action of natural products in general.
  • the natural product is the opposite of the chemically synthesized product, and the cultured scallop shell is also a category of the natural product.
  • the above-mentioned calcium oxide powder is highly alkaline and has high antibacterial properties. Then, if you brush your teeth with the toothbrush of the present invention, the oxidizing power of the powder will change to calcium hydroxide due to the interaction with water in the mouth. In other words, an algal environment is formed in the mouth to kill fungi and inhibit its reproductive activity, thus having a tremendous effect on the prevention of tooth decay. In addition, there is an effect that the cleanness of the toothbrush 1 after use can be maintained.
  • the product is a shell powder having a crystal structure of a calcite-type structure of calcium carbonate, a porous granular calcium carbonate powder and a carbonate powder.
  • the calcium powder is a mixture with calcined calcium oxide powder, it may be an aqueous solution of the mixture.
  • the product may be, for example, the calcium carbonate powder alone, or may be the calcium oxide powder only, for example. They may be water-soluble substances. And the state of this water 02 03634
  • both the handle 2 and the hair 3 were formed from a material mixed with a molded product, but either one of the two was mixed with a molded product. Even if they were formed from them.
  • Figures 2 and 3 show other implementation examples.
  • a coating layer 5 is formed on the surface of the handle body 4 as shown in FIG. 2.
  • the coating layer 5 is also formed on the surface of the hair body 6 as shown in FIG. Then, the coating layer 5 mixes the above-mentioned product in the form of powder or water-soluble material into a coating material, and forms the coating.
  • the bristle material is applied to the outer surface of the handle body 4 and applied to the surface of the bristle body 6.
  • the tooth brush having the above-mentioned useful effects such as the antibacterial effect is provided. 1 is obtained.
  • the method of forming the coating layer is not particularly limited.
  • a coating material is sprayed. It is also possible to form it by dipping it in a coating material.
  • one of the handle 2 and the hair 3 may be formed with a coating layer in which the product is mixed.
  • the material of each of the handle body 4 and the hair body 6 is not certified. Industrial applicability

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  • Brushes (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

Tooth decay is prevented by suppressing activity of intraoral fungi by providing on a toothbrush a product obtained by pulverizing shells having crystalline structural body of calcite type structure of calcium carbonate. A handle (2) or bristles (3) of the toothbrush (1) are formed of synthetic resin mixed with the product obtained by pulverizing shells having crystalline structural body of calcite type structure of calcium carbonate.

Description

歯ブ ラ シ Tooth brush
技術分野 . . Technical field . .
本発明 は、 歯ブラ シに関す る も ので あ る  The present invention relates to a tooth brush
明 背景技術  Akira Background technology
従来か ら 虫歯の原 因 と して は、 歯の表面 に ミ ュ ー タ ン 書  Conventionally, the cause of tooth decay has been the mutan written on the tooth surface.
ス 菌 と 呼ばれ る 連鎖球菌が介在 して食べ物 の カ ス な どが プ ラ ー ク と し て止 め置かれ、 そ の プラ ー ク に おい て 前記 ミ ュ ー タ ンス 菌ゃ乳酸菌 、 カ ン ジダ菌 な ど に よ っ て プ ラ ー ク 中 の糖分が酸に変 え ら れ、 そ の酸に よ つ て歯の 力 ノレ シ ゥ ム分が溶け 出 る 結果 で あ る 。 こ の こ と か ら 、 虫 歯の 予防 と して歯磨 き が奨励 さ れてい る。 Streptococci, called germs, intervene as food plaques and stop at the plaques, where the mutated bacteria, lactic acid bacteria, The result is that sugar in the plaque is converted into an acid by an N. bacillus or the like, and the acid strength of the tooth is dissolved out by the acid. For this reason, brushing is encouraged to prevent tooth decay.
し カゝ し な が ら 、 従来の 歯磨 き に用 い ら れ る 歯ブ ラ シ は 上記 プ ラ ー ク の取 り 除 き を行な う こ と を 目 的 と し た も の で あ り 、 それな り の効果が あ る が 、 上記菌類の活動 を抑 え る と い う も の ではない。  However, the tooth brushes used in conventional tooth brushing are intended to remove the above-mentioned plaque. Although it has a certain effect, it does not mean that the activity of the above fungi is suppressed.
上述 し た 問題 に対 して本発 明者は 、 自 然界力、 ら 得 ら れ る 天然材、 特に不用 物 と し て処分 さ れて き た貝殻な ど の カ ノレ シ ゥ ム を 多 く 含む天然多孔質材 を焼成 し粉砕 し て得 ら れ る 生成物が 、 人体に無害で あ り な が ら 抗菌性を 有す る こ と に着 目 し た も の で あ る 。 そ こ で、 本発明 は上記事 情 に鑑みて 、 歯ブ ラ シが 前記生成物 を有 してそ の 生成物 の 抗菌性に よ り 口 内 の菌類の活動 を抑止 さ せ る こ と を課 題 と し 、 虫歯 の予防 と 口 内 に入れ る 歯ブ ラ シ の清浄 さ の 維持を 図 る こ と を 目 的 と する 。 発明 の 開示 In response to the above-mentioned problems, the present inventor has increased the natural strength of natural materials obtained, and in particular, the use of canoles such as shells that have been disposed of as waste. It has been noticed that the product obtained by sintering and pulverizing the natural porous material that contains the antibacterial agent is not harmful to the human body but has antibacterial properties. Accordingly, the present invention has been made in view of the above circumstances, and has ascertained that a toothbrush has the above-mentioned product, and suppresses the activity of fungi in the mouth due to the antibacterial property of the product. Section The aim is to prevent tooth decay and to maintain the cleanness of tooth brushes in the mouth. Disclosure of invention
本発 明 は 上記課題 を考慮 し て な さ れた も の で、 炭酸力 ルシ ゥ ム の 方解石型構造に よ る 結晶構造体 を備 え た 貝殻 を粉砕 し た 生成物 が混ぜ込 ま れて い る 合成樹脂製の 毛 、 ま た は炭酸 カ ルシ ゥ ム の方解石型構造に よ る 結晶構造体 を備 え た 貝 殻 を粉砕 した生成物 が混ぜ込 ま れて い る 合成 樹脂製 の柄の少 な く と も 一方 を備 え る こ と を 特徴 と す る 歯ブ ラ シを提供 し て , 上記課題を解消する も のであ る。  The present invention has been made in view of the above problems, and is obtained by mixing a product obtained by crushing a shell provided with a crystalline structure of a calcite-type structure of carbonated calcium carbonate. A synthetic resin wool or a synthetic resin handle mixed with the crushed product of a shell with a crystalline structure of calcite-type calcium carbonate The above-mentioned problem is solved by providing a toothbrush characterized by having at least one of them.
ま た 、 も う 一つ の発明 は 、 炭酸カ ルシ ウ ム の方解石型 構造 に よ る 結晶構造体を備 え た 貝殻 を粉碎 し た生成物 を 含む コ ーテ ィ ン グ材で被覆 さ れて い る 毛、 ま た は炭酸力 ルシ ゥ ム の 方解石型構造に よ る 結晶構造体 を備 え た 貝 殼 を粉砕 し た 生成物 を含む コ ーテ ィ ン グ材で被覆 さ れて い る 柄の 少 な く と も一方を備 え る こ と を特徴 と す る 歯ブ ラ シで あ り 、 こ の歯プ ラ シ を提供 し て 上記課題 を解消す る も の で あ る 。  Another invention relates to a coating material containing a product obtained by pulverizing a shell having a crystal structure of a calcite-type structure of calcium carbonate. Is coated with a coating material containing a crushed product of a wool or a shell with a calcite-type crystal structure of carbonated calcium carbonate A tooth brush characterized in that it has at least one of a handle and a tooth brush, which solves the above-mentioned problem by providing the tooth brush.
そ し て 上記各発 明 において 、 生成物 は、 炭酸カ ル シ ゥ ム の 方解石型構造に よ る 結晶構造体 を備 え た 貝殻粉末で あ っ て 多孔質性粒体か ら な る 炭酸カ ルシ ウ ム粉末 と 該炭 酸カ ノレ シ ゥ ム粉末 を 焼成 し て な る 酸化カ ル シ ウ ム粉末 と の混合物 ま た はそ の 混合物 の水溶物 で あ る こ と が 良好で め る 。 図面の簡単 な説明 In each of the above-mentioned inventions, the product is a shell powder having a crystal structure of a calcite-type structure of calcium carbonate, and the product is a carbonate powder composed of porous granules. A mixture of a calcium powder and a calcium oxide powder obtained by calcining the calcium carbonate powder or a water-soluble substance of the mixture is preferred. BRIEF DESCRIPTION OF THE DRAWINGS
図 1 は 、 本発 明 に係 る 歯ブ ラ シ の一例 を示す説明 図 で め る 。  FIG. 1 is an explanatory diagram showing an example of a toothbrush according to the present invention.
図 2 は 、 第二の例 にお け る 歯ブ ラ シの柄の 断面 を 示す 説明 図 であ る 。  FIG. 2 is an explanatory diagram showing a cross section of the handle of the toothbrush in the second example.
図 3 は、 第二 の例 にお け る 歯ブ ラ シの毛 の 断面 を示す 説明 図 であ る 。 発明 を実施す る た め の最良の形態  FIG. 3 is an explanatory diagram showing a cross section of a tooth brush hair in the second example. BEST MODE FOR CARRYING OUT THE INVENTION
つ ぎ に本発 明 を 実施の形態 に基づい て詳細 に説明 する 図 中 1 は歯 ブ ラ シで、 該歯ブ ラ シ 1 は 、 合成樹脂素材 か ら 成形 さ れた柄 2 の先端に 、 複数本の 毛 3 を植毛 し て レヽ る 。 そ し て 、 こ の歯ブ ラ シ 1 の先端に植毛 さ れた前記 毛 3 は、 歯ブ ラ シ の 毛用 と し て選択 さ れた合成樹脂素材 に 、 炭酸カ ル シ ウ ム の方解石型構造 に よ る 結晶構造体を 備 え た 貝殻 を 粉砕 し た生成物 を 混ぜ込んだ毛形成用 合成 樹脂材料を用 いてな る も のであ る。  Next, the present invention will be described in detail based on an embodiment. In the drawings, reference numeral 1 denotes a tooth brush, and the tooth brush 1 is attached to a tip of a handle 2 molded from a synthetic resin material. A plurality of hairs 3 are implanted and laid. The hair 3 implanted at the tip of the tooth brush 1 is made of a synthetic resin material selected for the tooth brush hair and calcite calcium carbonate. It uses a synthetic resin material for hair formation that mixes a product obtained by pulverizing a shell having a crystal structure with a type structure.
ま た 、 上記柄 2 に あ っ て も 歯ブ ラ シの柄用 と し て選択 さ れた合成樹脂素材に 、 炭酸カ ル シ ゥ ム の方解石型構造 に よ る 結晶構造体 を備 えた貝殻 を粉砕 し た 生成物 を混ぜ 込ん だ柄形成用合成樹脂材料を用 い て成形 さ れた も ので あ る 。  Also, in the case of the above-mentioned handle 2, the synthetic resin material selected for the handle of the tooth brush and the shell provided with the crystal structure of the calcite-type structure of calcium carbonate. It was molded using a synthetic resin material for forming a pattern, into which a product obtained by pulverizing the mixture was mixed.
上記歯ブ ラ シ 1 の柄 2 と 毛 3 に混ぜ込 ま れ る 生成物 を 得る に 当 た っ て は 、 ま ず、 少 な く と も 貝殼主要部分 を炭 酸カ ル シ ウ ム の方解石型構造に よ る 結晶構造体 と し て い る 貝 殻 を 用 い る 。 こ の貝殻はホ タ テ の 貝殻で あ り 、 貝殻 の 大部分 を こ の結晶構造体 と し て い る 点 でホ タ テ の 貝殻 は他の貝殻 と 異な る 。 即 ち 、 ホ タ テ はそ の生態 において 、 貝 殻 を 開 閉 し て海 水 を 勢 い よ く 外 部 に 放 出 す る こ と で 「海 中 を泳 ぐ」 と 表現 さ れ る よ う に機敏 に移動 を行 い 、 捕捉者 （ ヒ ト デな ど） か ら 逃げ る 動 作が 特長 的 で あ り 、 こ の動作が行な え る よ う に大 き な 貝 柱 を有す る と と も に 貝殻 自 体が 、 比較的薄 く 軽量で 、 かつ 、 強度 を 有す る と い う 条件 を備 え て い る 。 そ の 貝殻で は、 炭酸 カ ル シ ウ ム の方解石型構造の結晶構造体が葉状構造 を呈 し て 貝 内 面 側が形成 さ れ、 貝 内層 （貝殻厚 さ 方 向 での芯 と な る 層 ） で は 、 炭酸カ ルシ ウ ム の方解石型構造の結晶 構造体 が板 状構造 を 呈 し て い て 、 こ の 貝 內 面側 と 貝 内層 と の構造が 貝 殼の主要部 （表層 部や蝶番部 を 除いた部分） を形作つ て レヽ る た め 、 薄 く 軽量で あ り な が ら 強度の あ る も の と な つ て レヽ る 。 In order to obtain the product to be mixed with the handle 2 and the hair 3 of the toothbrush 1, at least the main part of the shell is calcite of calcium carbonate. The shell used is a crystal structure with a type structure. This shell is a scallop shell, The scallop shell is different from other shells in that most of this is the crystal structure. Immediately, scallop is described in its ecology as "swimming in the sea" by opening and closing shells and releasing seawater vigorously to the outside. It is characterized by the ability to move quickly and escape from captors (such as hamsters), and has a large scallop to allow this movement. At the same time, the shell itself is required to be relatively thin, light, and strong. In the shell, the calcite-type crystal structure of calcium carbonate has a leaf-like structure, the inner surface of the shell is formed, and the inner layer of the shell (the core layer in the direction of the shell thickness). In), the calcite-type crystal structure of calcium carbonate has a plate-like structure, and the structure between the shell side and the shell inner layer is the main part of the shell (surface layer and The part (excluding the hinge part) is shaped and laid, so it is thin and lightweight, but also strong.
そ して 、 前述 した よ う ホ タ テ の 貝殻の主要部 において 、 内面側 は 、 炭酸カ ル シ ウ ム の方解石型構造の結晶構造体 が葉状構造 と な る （針状結晶 が剣 山 状に密 に詰ま っ て敷 き 並べ ら れて レヽ る 状態） と と も に 、 貝 内層 は 、 炭酸カ ル シ ゥ ム の方解石型構造の結晶構造体が板状構造 と し て い る （ベニ ヤ板 の よ う に 、 針状結晶 が 同一方向 に並 んだ層 が幾重に も 重 な り 、 針状結晶 の 向 き が層 ご と に異 な っ て い る 状態） と して レヽ る た め 、 後述す る よ う に こ の ホ タ テ の 貝 殻 を粉砕 し て得 ら れた粒体 は方解石型構造が残 っ て 多孔質性 を備 え た も の と な る 。 こ れ に比べて他の 貝 殻で は 、 炭酸カ ル シ ウ ム の結晶 が面状 に広が っ て重な っ た構 造 と な っ て お り 、 こ れ に よ り パール状光沢 を 呈す る も の と な っ て レ、 る が 、 粒体 と し た場合 に は多孔質性 を 呈 し な レヽ も の と な っ て レヽ る。 Then, as described above, in the main part of the shell of the scallop, on the inner side, the calcite-type crystal structure of calcium carbonate becomes a leaf-like structure (the needle-like crystal is a sword-like shape). The inner shell is composed of a calcite-type crystal structure of calcium carbonate and a plate-like structure (veneer). Layers of needle-like crystals arranged in the same direction, like a slab, overlap several times, and the direction of the needle-like crystals is different for each layer. Therefore, as will be described later, the granules obtained by crushing the shell of this scallop are porous with a calcite-type structure remaining. In contrast, in other shells, calcium carbonate crystals spread in a plane and overlapped. As a result, the pearly luster can be obtained, but when it is made into granules, it does not exhibit porosity. Reply
上述 し た よ う に生成物 を得 る に 当 た っ て ホ タ テ の 貝殻 を原材料 と し て い る が 、 ホ タ テ の貝柱を 取 り 除い た 後 に お い て 不要物 と し て処理 さ れて き た も の を利用 で き 、 廃 棄物 の有用 な利用 が行な え る 。 ま ず、 不用 と な っ た 貝殻 を集 め て 天 日 乾燥 を行 な っ て乾カゝ し硬化 さ せ る 。 つ ぎ に 天 日 乾燥 に よ っ て硬化 し た 貝殻 を粒径約 2 0 0 m と な る ま で に粉砕す る 。 粉砕方法 自 体は特に 限定す る も の で は な く 、 既存の粉砕装置 を 用 いれば よ い。 こ の よ う に し て炭酸カ ノレ シ ゥ ム粉末が得 ら れ る も の も の で あ り 、 粒体 は多孔性粒体 と な っ て い る。  As mentioned above, scallop shells are used as a raw material to obtain the product, but after removing the scallop scallop, it is considered unnecessary. What has been treated can be used, and waste can be used effectively. First, waste shells are collected, dried in the sun, dried and hardened. Next, the shells cured by solar drying are ground to a particle size of about 200 m. The crushing method itself is not particularly limited, and an existing crushing device may be used. In this way, a canola carbonate powder can be obtained, and the granules are porous granules.
つ ぎ に 上述 の多孔質性粒体か ら な る 炭酸カ ル シ ウ ム粉 末の 一部 分 を用 い て こ れ を ロ ー タ リ 一キ ノレ ン に入れて約 1 0 0 0 °c の 温度で数十分か ら 数時間程度 の 時間 で加熱 し て 酸化 カ ノレ シ ゥ ム粉末 を得 る よ う にす る 。 そ し て こ の 酸化 カ ル シ ウ ム粉末 と 上記炭酸カ ル シ ウ ム 粉末 と を混合 する こ と で生成物が得 ら れ る。  Next, a portion of the above-mentioned calcium carbonate powder made of the porous granules is used and put into a rotary quinolene for about 100 ° C. Heat at the temperature of c for several tens of minutes to several hours to obtain canola resodium oxide powder. Then, a product is obtained by mixing the calcium oxide powder with the above-mentioned calcium carbonate powder.
そ し て 、 こ の生成物 を 毛用 と し て選択 さ れた合成樹脂 素材 に混ぜ込み、 こ れを フ ィ ラ メ ン ト イヒす る こ と で上記 毛 3 が得 ら れ、 こ れを柄 2 の所要位置に植毛すれば よ い。 同様 に 、 柄用 と し て選択 さ れた合成樹脂素材に前記生成 物 を 混ぜ込み、 こ れ を材料 と し て成型す る こ と で柄 2 が 得 ら ^/る 。  Then, this product is mixed with a synthetic resin material selected for hair, and the mixture is subjected to filament firing to obtain the hair 3, and the hair 3 is obtained. Can be planted in the required position of handle 2. Similarly, the product is mixed with the synthetic resin material selected for the pattern, and the resulting product is molded to obtain the pattern 2.
上記生成物 中 、 炭酸カ ル シ ウ ム粉末分 は上述 し た よ う に 天然物で あ る ホ タ テ の 貝殻粉末 の独特 な 多孔質粒体か ら な る も の で あ る 。 こ の よ う に 生成物 は天然物 で あ る ホ タ テ の 貝殻粉末か ら な る も の で あ り 、 天然物一般が 有す る 抗菌性が あ り 、 こ の抗菌性か ら も 細菌や力 ビ な ど の繁 殖 を抑 え る 作用 を有す る 。 そ し て 、 こ の歯ブ ラ シ で は柄 2 と 毛 3 の表面 に生 ·成物が表 出 す る 状態 と な っ て レ、 る こ と か ら 、 こ の歯ブ ラ シ 1 で歯磨 き を すれば、 天然物一般 が 有す る 抗菌作用 に て菌類の活動 を抑 え る 。 な お 、 こ こ で天然物 と は化学合成生産物 の 対極 と し て い う も の であ り 、 養殖 さ れたホ タ テ の貝殻 も 天然物の範疇であ る 。 In the above product, the calcium carbonate powder is as described above. It consists of unique porous granules of scallop shell powder, which is a natural product. As described above, the product is composed of scallop shell powder, which is a natural product, and has the antibacterial properties inherent to natural products in general. It has the effect of suppressing the reproduction of spores and power. Then, in this tooth brush, raw and synthetic substances are exposed on the surface of the handle 2 and the hair 3, so that the tooth brush 1 If you brush your teeth, the fungus activity will be suppressed by the antibacterial action of natural products in general. Here, the natural product is the opposite of the chemically synthesized product, and the cultured scallop shell is also a category of the natural product.
ま た、 上記酸化カ ルシ ウ ム粉末分はアル力 リ 性であ り 、 高 い抗菌性 を備 え て い る 。 そ し て 、 本発 明 の 歯ブ ラ シに て 歯磨 き をすれば、 口 内 の水分 と の 交わ り に よ っ て酸化 力 ノレ シ ゥ ム粉末分が水酸化カ ル シ ウ ム に変化 し 、 ア ル力 リ 性の環境 を 口 内 に形成 して菌類 を殺すな ど し て そ の繁 殖活動 を抑止 さ せ る 、 よ っ て 、 虫歯 の予防 に絶大 な効果 が あ る と と も に 、 使用 後 の歯ブ ラ シ 1 の清浄 さ を 維持で き る効果が あ る 。  In addition, the above-mentioned calcium oxide powder is highly alkaline and has high antibacterial properties. Then, if you brush your teeth with the toothbrush of the present invention, the oxidizing power of the powder will change to calcium hydroxide due to the interaction with water in the mouth. In other words, an algal environment is formed in the mouth to kill fungi and inhibit its reproductive activity, thus having a tremendous effect on the prevention of tooth decay. In addition, there is an effect that the cleanness of the toothbrush 1 after use can be maintained.
上記実施の例で は、 生成物 を炭酸カ ルシ ウ ム の方解石 型構造に よ る 結晶構造体 を備 え た 貝 殻粉末で多孔質性粒 体の炭酸カ ル シ ウ ム粉末 と こ の炭酸カ ルシ ウ ム 粉末 を焼 成 し た酸化カ ル シ ウ ム粉末 と の混合物 と し た が 、 こ の混 合物 の水溶物 で あ っ て も よ い。 ま た 、 前記生成物 は例 え ば、 生成物 を 前記炭酸カ ルシ ウ ム粉末の み と し た り 、 或 レ、 は前記酸化カ ルシ ウ ム粉末の み と し て も よ く 、 そ れ ら の 水溶物 で あ っ て も よ い。 そ し て 、 こ の水溶物 の状態 と 02 03634 In the above embodiment, the product is a shell powder having a crystal structure of a calcite-type structure of calcium carbonate, a porous granular calcium carbonate powder and a carbonate powder. Although the calcium powder is a mixture with calcined calcium oxide powder, it may be an aqueous solution of the mixture. Further, the product may be, for example, the calcium carbonate powder alone, or may be the calcium oxide powder only, for example. They may be water-soluble substances. And the state of this water 02 03634
7 さ れた生成物 を 上記柄用 の 合成樹脂素材 と 混ぜ合 わせ、 こ の材料か ら 柄 2 を成型すれば、 表面 に抗菌物質 を よ り 緻密 に分布 さ せた も の が成型で き る よ う に な る 。 同様 に 水溶物 の 状態 と さ れた生成物 を 毛用 の合成樹脂素材 と 混 ぜ合 わせ、 こ の材料か ら 毛 3 を成型すれば、 表面 に抗菌 物質を よ り 緻密 に分布 さ せた も のが成型で き る。  7 By mixing the obtained product with the synthetic resin material for the above pattern and forming pattern 2 from this material, it is possible to form a product in which the antibacterial substance is more densely distributed on the surface. Become so . Similarly, the water-soluble product was mixed with a synthetic resin material for hair, and wool 3 was molded from this material, whereby the antibacterial substance was more precisely distributed on the surface. The object can be molded.
な お、 柄 2 と 毛 3 と の 両者 を成形物 を 混ぜ込 んだ素材 力 ら 形成 さ れた も の と し た が 、 こ の 両者の何れか一方を 成形物 を混ぜ込 ん だ素材か ら 形成 さ れた も の と し て も よ レヽ。  It should be noted that both the handle 2 and the hair 3 were formed from a material mixed with a molded product, but either one of the two was mixed with a molded product. Even if they were formed from them.
図 2 と 図 3 は他 の 実施 の例 を示 し て い る 。 こ の例 の歯 ブ ラ シ 1 の抦 2 に お レ、 て は 、 図 2 に示 さ れて い る よ う に 柄本体 4 の表面 に コ ーテ ィ ン グ層 5 が形成 さ れて い る と と も に 、 図 3 に示 さ れて レヽ る よ う に 毛 3 に お レヽ て も 毛本 体 6 の表面 に コ ー テ ィ ン グ層 5 が形成 さ れて い る 。 そ し て 、 前記 コ ーテ ィ ン グ層 5 は、 粉末 の形態ま た は水溶物 の形態 と し た上記生成物 を コ ーテ ィ ン グ素材 に混ぜ込み、 こ の コ ーテ ィ ン グ素材 を前記柄本体 4 の外面 に塗布 し 、 ま た毛本体 6 の表面に塗布 して形成 した も のであ る 。  Figures 2 and 3 show other implementation examples. As shown in FIG. 2, a coating layer 5 is formed on the surface of the handle body 4 as shown in FIG. 2. In addition, as shown in FIG. 3, the coating layer 5 is also formed on the surface of the hair body 6 as shown in FIG. Then, the coating layer 5 mixes the above-mentioned product in the form of powder or water-soluble material into a coating material, and forms the coating. The bristle material is applied to the outer surface of the handle body 4 and applied to the surface of the bristle body 6.
こ の よ う に柄 2 、 毛 3 の表面 に 生成物 を含んだ コ ーテ ィ ン グ層 5 を設 け る こ と で、 上述 し た抗菌 な どの有用 な 効果 を有 した歯ブ ラ シ 1 が得 られる。  By providing the coating layer 5 containing the product on the surface of the handle 2 and the hair 3 in this manner, the tooth brush having the above-mentioned useful effects such as the antibacterial effect is provided. 1 is obtained.
な お 、 コ ーテ ィ ン グ層 の形成手法 は特 に 限定 さ れ る も の で はな く 、 上述 し た塗布 に よ る も の の他、 コ ーテ ィ ン グ材 を吹 き 付 け た り コ ーテ ィ ン グ材 に浸漬 し て形成す る こ と も 可能であ る 。 こ の例 に お い て 、 柄 2 と 毛 3 の何れか一方 に 生成物 を 混ぜ込んで な る コ ーテ ィ ン グ層 を形成す る よ う に し て も よ い。 そ し て 、 上記柄本体 4 や毛本体 6 そ れぞれの 素材 は検定 さ れない。 産業上の利用 可能性 The method of forming the coating layer is not particularly limited. In addition to the above-mentioned coating, a coating material is sprayed. It is also possible to form it by dipping it in a coating material. In this example, one of the handle 2 and the hair 3 may be formed with a coating layer in which the product is mixed. The material of each of the handle body 4 and the hair body 6 is not certified. Industrial applicability
以上説明 し た本発明 の歯ブ ラ シを用 いて 歯磨 き を すれ ば、 口 内 に ア ルカ リ 性環境 を簡単に形成で き て 、 そ の 口 内 の 菌類 の活動 を 抑止 さ せて 虫歯予防に効果が あ る も の と な る 。 ま た 、 歯ブ ラ シに施 さ れた生成物側か ら の 力 ノレ シ ゥ ム 分 の溶 け 出 し が歯の形成に寄与で き る よ う に な る t さ ら に歯ブ ラ シ 自 体の抗菌性が高め ら れて 清浄 さ を維持 でき る な ど、 実用性に優れた効果を奏する も のであ る 。 By brushing with the toothbrush of the present invention described above, an alkaline environment can be easily formed in the mouth, and the activity of fungi in the mouth can be suppressed to reduce tooth decay. It is effective for prevention. Also, hub La facilities have been the product side or these forces Norre Shea ©-time content of soluble only Shi out Let 's that come in, contribute to the formation of tooth Ni Do that t is found in the hub La Shea It has an excellent effect on practicality, such as maintaining its cleanliness by enhancing its own antibacterial properties.

Claims

請 求 の 範 囲 The scope of the claims
1 . 炭酸カ ル シ ウ ム の方解石型構造に よ る 結晶構造体を 備 え た 貝殻を粉砕 し た生成物 が 混ぜ込 ま れて い る 合成樹 脂製 の 毛、 ま た は炭酸カ ル シ ウ ム の方解石型構造 に よ る 結晶構造体 を備 え た 貝殻を粉枠 し た生成物 が 混ぜ込 ま れ て レ、 る 合成樹脂製の柄の少 な く と も 一方 を備 え る こ と を 特徴 と する 歯ブ ラ シ。 1. Synthetic resin wool or carbonate containing mixed products of crushed shells with a calcite-type crystal structure of calcium carbonate A shell-like product with a crystal structure of the calcite-type structure of lime is mixed with at least one of the synthetic resin handles. A tooth brush characterized by this.
2 . 炭酸カ ルシ ウ ム の方解石型構造に よ る 結晶構造体 を 備 え た 貝殻を粉砕 し た生成物 を含む コ ーテ ィ ン グ材で被 覆 さ れて い る 毛 、 ま た は炭酸カ ルシ ウ ム の 方解石型構造 に よ る 結晶構造体 を備 え た 貝 殻 を粉砕 し た 生成物 を含む コ ー テ ィ ン グ材で被覆 さ れて い る 柄の少 な く と も 一方 を 備 え る こ と を特徴 と する歯ブ ラ シ。  2. Hair covered with a coating containing a crushed product of shells with a crystalline structure of calcite-type structure of calcium carbonate, or At least a handle covered with a coating material containing a crushed product of a shell with a crystalline structure of calcite-type structure of calcium carbonate A tooth brush characterized by having one side.
3 . 上記生成物 は、 炭酸カ ル シ ウ ム の方解石型構造 に よ る 結 晶構造体 を備 え た貝殻粉末で あ っ て多孔質性粒体か ら な る 炭酸カ ル シ ウ ム粉末 と 該炭酸カ ル シ ウ ム 粉末 を焼 成 し て な る 酸化カ ル シ ウ ム 粉末 と の混合物 ま た はそ の混 合物 の水溶物 で あ る 請求項 1 ま た は 2 に記載の歯ブ ラ シ  3. The above product is a shell powder provided with a crystal structure of a calcite-type structure of calcium carbonate, and is a calcium carbonate powder composed of porous particles. The mixture according to claim 1 or 2, wherein the mixture is a mixture of a calcium oxide powder obtained by calcining the calcium carbonate powder or a water-soluble substance of the mixture. Tooth brush
PCT/JP2002/003634 2002-04-11 2002-04-11 Tooth brush WO2003084365A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
AU2002249575A AU2002249575A1 (en) 2002-04-11 2002-04-11 Tooth brush
GB0422309A GB2403896B (en) 2002-04-11 2002-04-11 Tooth brush
CNA028287282A CN1625357A (en) 2002-04-11 2002-04-11 Toothbrush
KR10-2004-7016225A KR20040108727A (en) 2002-04-11 2002-04-11 Tooth brush
US10/510,534 US20060162109A1 (en) 2002-04-11 2002-04-11 Toothbrush
PCT/JP2002/003634 WO2003084365A1 (en) 2002-04-11 2002-04-11 Tooth brush
HK05102338A HK1069964A1 (en) 2002-04-11 2005-03-17 Tooth brush

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX344589B (en) * 2005-08-26 2016-12-20 Colgate-Palmolive Company * Oral care instrument including an oral care agent.
US8092110B2 (en) 2005-08-26 2012-01-10 Colgate-Palmolive Company Oral care instrument including an oral care agent
US20090007357A1 (en) * 2007-05-07 2009-01-08 The Gillette Company Oral Hygiene Implements
KR102251526B1 (en) * 2019-09-18 2021-05-12 양승호 the bristle of toothbrush with zirconia and high antibacterial shell of lily clam, and manufacturing method thereof
CN112205746A (en) * 2020-09-28 2021-01-12 上海那博新材料科技有限公司 Nano copper toothbrush bristle and manufacturing method thereof

Citations (3)

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JPH033226U (en) * 1989-05-31 1991-01-14
JPH11216016A (en) * 1998-02-03 1999-08-10 Sinto Brator Co Ltd Abrasive-fixed brush for toothbrush
JP2001240841A (en) * 2000-02-29 2001-09-04 Chafflose Corporation Adhesive

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US5633083A (en) * 1989-03-14 1997-05-27 Sunstar Kabushiki Toothbrush
EP0575623B1 (en) * 1991-12-16 1998-07-01 Kaiho Co., Ltd. Bactericide and method of retaining freshness of food
US5849311A (en) * 1996-10-28 1998-12-15 Biopolymerix, Inc. Contact-killing non-leaching antimicrobial materials
EP0984709B1 (en) * 1997-05-12 2006-08-23 Microban Products Company Antimicrobial brush

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Publication number Priority date Publication date Assignee Title
JPH033226U (en) * 1989-05-31 1991-01-14
JPH11216016A (en) * 1998-02-03 1999-08-10 Sinto Brator Co Ltd Abrasive-fixed brush for toothbrush
JP2001240841A (en) * 2000-02-29 2001-09-04 Chafflose Corporation Adhesive

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AU2002249575A1 (en) 2003-10-20
US20060162109A1 (en) 2006-07-27
GB2403896A (en) 2005-01-19
GB2403896B (en) 2005-11-09
KR20040108727A (en) 2004-12-24
CN1625357A (en) 2005-06-08
GB0422309D0 (en) 2004-11-10
HK1069964A1 (en) 2005-06-10

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