WO2003066789A2 - Composition for an aqueous detergent used for shoes - Google Patents

Composition for an aqueous detergent used for shoes Download PDF

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Publication number
WO2003066789A2
WO2003066789A2 PCT/KR2002/002094 KR0202094W WO03066789A2 WO 2003066789 A2 WO2003066789 A2 WO 2003066789A2 KR 0202094 W KR0202094 W KR 0202094W WO 03066789 A2 WO03066789 A2 WO 03066789A2
Authority
WO
WIPO (PCT)
Prior art keywords
sole
shoes
composition
aqueous detergent
aqueous
Prior art date
Application number
PCT/KR2002/002094
Other languages
French (fr)
Inventor
Hee-Dae Park
Kwang-Jin Yoon
Original Assignee
Hee-Dae Park
Kwang-Jin Yoon
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hee-Dae Park, Kwang-Jin Yoon filed Critical Hee-Dae Park
Priority to AU2002353592A priority Critical patent/AU2002353592A1/en
Publication of WO2003066789A2 publication Critical patent/WO2003066789A2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3738—Alkoxylated silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/261—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/32—Organic compounds containing nitrogen
    • C11D7/3218—Alkanolamines or alkanolimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • This invention relates to an aqueous detergent, particularly to a composition for an aqueous detergent which contains no solvents strictly regulated by the law, and is to maximize the polarity and corrosion of the polymer.
  • Polyurethane foams are commonly referred as thermosetting urethanes, which are formed by urethane group from the reaction of polyether or polyester polyol with isocyanate (R-NCO). Polyurethane foams are also formed by the reaction of isocyanate with water (H O) to give an urea and CO 2 . These polyurethane foams conventionally apply to a mid-sole for shoes.
  • thermoplastic urethanes are conventionally referred as thermoplastic urethane, which are formed from the reaction of polyethylene with urethane groups, particularly urethane group from the polyester or polyether.
  • the TPUs are used for producing the sole-attachment or the air-bag inserted into the mid- sole for shoes.
  • the air-bag is produced by injection or extrusion molding, and when attached the sole-attachments to the sole, that aim at the torsion or reinforcement.
  • the mid-sole is made from the post-processes such as the paint spraying process or adhering process etc, which require cleansing with solvents. Also, the air- bag or the sole-attachment has to be cleansed by the solvents to promote the aqueous/inflammable paint, bond primer, PU pouring adhesion processes due to its dense skin and high rigidity in view of production properties.
  • Typical solvents include trichloroethylene, methyl ethyl ketone (hereinafter, referred as “MEK”), isopropyl alcohol (hereinafter, referred as “IPA”), the mixture of MEK with IPA, and chlorinated solvent mixture, etc.
  • MEK methyl ethyl ketone
  • IPA isopropyl alcohol
  • these detergents not only may adversely affect the health of the workers and stability in the working place, but also may cause serious environmental contamination and pollution.
  • highly volatile solvents such as those containing methyl group (-CH ) are strictly regulated by domestic and foreign laws.
  • carcinogenic substances contained in the prior detergents may cause cancer, vomiting or dermatological diseases when contacting the human body, and can be fatal to the human body when used in a prolonged period of time.
  • the object of this invention is to provide a composition for an aqueous detergent used for the shoes to solve the above-mentioned problems.
  • the composition contains no solvents which are strictly regulated by domestic and foreign laws, and maximize the polarity and corrosion of the polymer.
  • the object of this invention is to provide a composition for an aqueous detergent used for the shoes, which is non-toxic to human body.
  • the object of this invention is to provide a composition for an aqueous detergent used for shoes, which may enhance adhesive strength.
  • the object of this invention is to provide a composition for an aqueous detergent used for cleansing the PU mid-sole of the shoes.
  • the object of this invention is to provide a composition for an aqueous detergent used for cleansing the TPU and plastic injections.
  • this invention provides a composition for an aqueous detergent comprising 0.1 to 2.0% of polyether siloxane copolymer, 5.0 to 30.0% of physical mixture of stabilized, neutralized metal precursor and amino functional compounds in ethylene glycol, 0.1 to 2.0% of hydroxyl aliphatic amine, and 66.0 to 94.8% of H 2 O.
  • this invention provides a composition for an aqueous detergent comprising 0.1 to 2.0% of NaOH; 0.1 to 5.0% of isocyanuric acid, 0.1 to 2.0% of sodium diisooctylsulfosuccinate, 0.1 to 2.0% of aqueous solution of a modified polymer with groups of high pigment affinity, 0.1 to 10% of aryl alkyl polyoxyethylene ether, and 88.0 to 99.5% of H 2 O.
  • Fig. 1 is a catalog of Chartwell International, Inc., which produces and sells the physical mixture of stabilized, neutralized metal precursor and amino functional compounds in ethylene glycol in the composition for an aqueous detergent according to the preferred embodiment of the invention.
  • Fig. 2 is a catalog of TEGO Chemie Service GmbH, which produces and sells the aqueous solution of a modified polymer with groups of high pigment affinity in the composition for an aqueous detergent according to the preferred embodiment of the invention.
  • composition according to the present invention will be exemplified to the mid-sole and an air-bag for shoes and its sole attachments, but it is obvious that the present invention can also be equivalently applied to the shoemaking industry using polyurethane foam or thermoplastic urethane as composition.
  • the aqueous detergent according to the present invention contains no solvents which are strictly regulated by the law, and is to maximize the polarity and corrosion of the polymer.
  • the above-mentioned aqueous detergent may be divided into 2 categories according to its components, i.e., for cleansing the mid-sole made of polyurethane foam, or for air-bag or sole attachments made of thermoplastic urethane.
  • the compositions of those detergents are as follows.
  • the aqueous detergent composition for cleansing the mid-sole for shoes includes a polyether siloxane copolymer and a physical mixture of stabilized neutralized metal precursor and amino functional compounds in ethylene glycol (ChartwellTM B- 515.71 , manufactured by Chartwell International, Inc.) and hydroxyl aliphatic amine. T Thhee ccoommpr. osition and the properties of ChartwellTM B-515.71 are shown in the catalog of Fig. 1.
  • the aqueous detergent composition for cleansing the air-bag or sole attachment for shoes comprises NaOH, isocyanuric acid, sodium diisooctylsulfosuccinate, aqueous solution of a modified polymer with groups of high pigment affinity (TEGOTM Dispers 750W, manufactured by TEGO Chemie Service GmbH) and aryl alkyl polyoxyethylene ether.
  • TEGOTM Dispers 750W manufactured by TEGO Chemie Service GmbH
  • aryl alkyl polyoxyethylene ether aryl alkyl polyoxyethylene ether
  • An aqueous detergent is produced by mixing and stirring 0.6% of polyether siloxane copolymer, 10.0% of physical mixture of stabilized, neutralized metal precursor and amino functional compounds in ethylene glycol, 0.2% of hydroxyl aliphatic amine, and 89.2% of H 2 O.
  • the aqueous detergent comprising the above- mentioned components is "Biogenic TM 700", and is mainly used for cleansing the mid- sole.
  • An aqueous detergent is produced by mixing and stirring 0.1 % of NaOH; 0.3% of isocynuric acid, 0.2% of sodium diisooctylsulfosuccinate, 0.2% of aqueous solution of a modified polymer with groups of high pigment affinity, 0.3% of aryl alkyl polyoxyethylene ether, and 98.9% of H 2 O.
  • the aqueous detergent comprising the above-mentioned components is "Biogenic TM 300SF", and is mainly used for cleansing the air-bag and sole attachments.
  • the composition for the aqueous detergent of the present invention contains no carcinogenic substances and VOC regulation substances, it is non-toxic to human body and prevents soil or air pollution, and it has synergistic effects of enhancing the adhesive strength relative to the prior solvent detergents.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

Art. 17(2)(a) : pas de traductionArt. 17 (2) (a): no translation

Description

COMPOSITION FOR AN AQUEOUS DETERGENT USED FOR SHOES
Technical Field
This invention relates to an aqueous detergent, particularly to a composition for an aqueous detergent which contains no solvents strictly regulated by the law, and is to maximize the polarity and corrosion of the polymer.
Background Art
Polyurethane foams are commonly referred as thermosetting urethanes, which are formed by urethane group from the reaction of polyether or polyester polyol with isocyanate (R-NCO). Polyurethane foams are also formed by the reaction of isocyanate with water (H O) to give an urea and CO2. These polyurethane foams conventionally apply to a mid-sole for shoes.
Thermoplastic urethanes (hereinafter, referred as "TPUs") are conventionally referred as thermoplastic urethane, which are formed from the reaction of polyethylene with urethane groups, particularly urethane group from the polyester or polyether. The TPUs are used for producing the sole-attachment or the air-bag inserted into the mid- sole for shoes. The air-bag is produced by injection or extrusion molding, and when attached the sole-attachments to the sole, that aim at the torsion or reinforcement.
The mid-sole is made from the post-processes such as the paint spraying process or adhering process etc, which require cleansing with solvents. Also, the air- bag or the sole-attachment has to be cleansed by the solvents to promote the aqueous/inflammable paint, bond primer, PU pouring adhesion processes due to its dense skin and high rigidity in view of production properties.
Typical solvents (hereinafter, referred as "detergent") include trichloroethylene, methyl ethyl ketone (hereinafter, referred as "MEK"), isopropyl alcohol (hereinafter, referred as "IPA"), the mixture of MEK with IPA, and chlorinated solvent mixture, etc. However, these detergents not only may adversely affect the health of the workers and stability in the working place, but also may cause serious environmental contamination and pollution. Specifically, highly volatile solvents such as those containing methyl group (-CH ) are strictly regulated by domestic and foreign laws. And, carcinogenic substances contained in the prior detergents may cause cancer, vomiting or dermatological diseases when contacting the human body, and can be fatal to the human body when used in a prolonged period of time.
Summary of the Invention
Thus, the object of this invention is to provide a composition for an aqueous detergent used for the shoes to solve the above-mentioned problems. The composition contains no solvents which are strictly regulated by domestic and foreign laws, and maximize the polarity and corrosion of the polymer.
The object of this invention is to provide a composition for an aqueous detergent used for the shoes, which is non-toxic to human body.
The object of this invention is to provide a composition for an aqueous detergent used for shoes, which may enhance adhesive strength.
The object of this invention is to provide a composition for an aqueous detergent used for cleansing the PU mid-sole of the shoes.
The object of this invention is to provide a composition for an aqueous detergent used for cleansing the TPU and plastic injections.
To achieve these objects, this invention provides a composition for an aqueous detergent comprising 0.1 to 2.0% of polyether siloxane copolymer, 5.0 to 30.0% of physical mixture of stabilized, neutralized metal precursor and amino functional compounds in ethylene glycol, 0.1 to 2.0% of hydroxyl aliphatic amine, and 66.0 to 94.8% of H2O. Further, this invention provides a composition for an aqueous detergent comprising 0.1 to 2.0% of NaOH; 0.1 to 5.0% of isocyanuric acid, 0.1 to 2.0% of sodium diisooctylsulfosuccinate, 0.1 to 2.0% of aqueous solution of a modified polymer with groups of high pigment affinity, 0.1 to 10% of aryl alkyl polyoxyethylene ether, and 88.0 to 99.5% of H2O.
Brief Description of the Drawing
Fig. 1 is a catalog of Chartwell International, Inc., which produces and sells the physical mixture of stabilized, neutralized metal precursor and amino functional compounds in ethylene glycol in the composition for an aqueous detergent according to the preferred embodiment of the invention.
Fig. 2 is a catalog of TEGO Chemie Service GmbH, which produces and sells the aqueous solution of a modified polymer with groups of high pigment affinity in the composition for an aqueous detergent according to the preferred embodiment of the invention.
Detailed Description of the Invention
Preferred embodiments of this invention are specifically described as follow.
Hereinafter, the composition according to the present invention will be exemplified to the mid-sole and an air-bag for shoes and its sole attachments, but it is obvious that the present invention can also be equivalently applied to the shoemaking industry using polyurethane foam or thermoplastic urethane as composition.
First, with regard to the concept of the aqueous detergent, the aqueous detergent according to the present invention contains no solvents which are strictly regulated by the law, and is to maximize the polarity and corrosion of the polymer. Hence, the above-mentioned aqueous detergent may be divided into 2 categories according to its components, i.e., for cleansing the mid-sole made of polyurethane foam, or for air-bag or sole attachments made of thermoplastic urethane. The compositions of those detergents are as follows.
The aqueous detergent composition for cleansing the mid-sole for shoes includes a polyether siloxane copolymer and a physical mixture of stabilized neutralized metal precursor and amino functional compounds in ethylene glycol (Chartwell™ B- 515.71 , manufactured by Chartwell International, Inc.) and hydroxyl aliphatic amine. T Thhee ccoommpr. osition and the properties of Chartwell™ B-515.71 are shown in the catalog of Fig. 1.
Further, the aqueous detergent composition for cleansing the air-bag or sole attachment for shoes comprises NaOH, isocyanuric acid, sodium diisooctylsulfosuccinate, aqueous solution of a modified polymer with groups of high pigment affinity (TEGO™ Dispers 750W, manufactured by TEGO Chemie Service GmbH) and aryl alkyl polyoxyethylene ether. The composition and the properties of TEGO™ Dispers 750W are shown in the catalog of Fig. 2.
The following examples are given for the purpose of illustrating the present invention and shall not be construed as being limitations on the scope or spirit of the invention
Example
Example 1
An aqueous detergent is produced by mixing and stirring 0.6% of polyether siloxane copolymer, 10.0% of physical mixture of stabilized, neutralized metal precursor and amino functional compounds in ethylene glycol, 0.2% of hydroxyl aliphatic amine, and 89.2% of H2O. The aqueous detergent comprising the above- mentioned components is "Biogenic ™ 700", and is mainly used for cleansing the mid- sole.
Example 2
An aqueous detergent is produced by mixing and stirring 0.1 % of NaOH; 0.3% of isocynuric acid, 0.2% of sodium diisooctylsulfosuccinate, 0.2% of aqueous solution of a modified polymer with groups of high pigment affinity, 0.3% of aryl alkyl polyoxyethylene ether, and 98.9% of H2O. The aqueous detergent comprising the above-mentioned components is "Biogenic ™ 300SF", and is mainly used for cleansing the air-bag and sole attachments.
As can be seen in the above, because the composition for the aqueous detergent of the present invention contains no carcinogenic substances and VOC regulation substances, it is non-toxic to human body and prevents soil or air pollution, and it has synergistic effects of enhancing the adhesive strength relative to the prior solvent detergents.

Claims

Claim:
1. A compositon for an aqueous detergent, comprising polyether siloxane copolymer; physical mixture of stabilized, neutralized metal precursor and amino functional compounds in ethylene glycol; and hydroxyl aliphatic amine.
2. The composition according to Claim 1, wherein the aqueous detergent comprises
0.1 to 2.0 % of polyether siloxane copolymer;
5.0 to 30.0% of physical mixture of stabilized, neutralized metal precursor and amino functional compounds in ethylene glycol;
0.1 to 2.0% of hydroxyl aliphatic amine; and 66.0 to 94.8% of H2O.
3. A composition for an aqueous detergent used to cleanse a sole or sole attachments for shoes, comprising
NaOH; isocyanuric acid; sodium diisooctylsulfosuccinate; aqueous solution of a modified polymer with groups of high pigment affinity; and aryl alkyl polyoxyethylene ether.
4. A composition for an aqueous detergent for shoes according to Claim 3, comprising
0.1 to 2.0% of NaOH; 0.1 to 5.0% of isocyanuric acid; 0.1 to 2.0% of sodium diisooctylsulfosuccinate;
0.1 to 2.0% of aqueous solution of a modified polymer with groups of high pigment affinity;
0.1 to 10% of aryl alkyl polyoxyethylene ether; and 88.0 to 99.5% of H2O.
5. The composition according any one of claims 1 to 4, wherein the sole for shoes is mid-sole.
6 The composition according any one of claims 1 to 4, wherein the material is air-bag inserted into the mid-sole for shoes.
PCT/KR2002/002094 2002-02-07 2002-11-09 Composition for an aqueous detergent used for shoes WO2003066789A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002353592A AU2002353592A1 (en) 2002-11-09 2002-11-09 Composition for an aqueous detergent used for shoes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR0200184 2002-02-07

Publications (1)

Publication Number Publication Date
WO2003066789A2 true WO2003066789A2 (en) 2003-08-14

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2002/002094 WO2003066789A2 (en) 2002-02-07 2002-11-09 Composition for an aqueous detergent used for shoes

Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017505828A (en) * 2013-12-03 2017-02-23 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ Aqueous polyurethane dispersion

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017505828A (en) * 2013-12-03 2017-02-23 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ Aqueous polyurethane dispersion

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