WO2003060384A2 - Dispositif et procede permettant d'eliminer les gaz dissous d'un milieu liquide d'echange de chaleur contenu dans un systeme d'echange de chaleur, et systeme d'echange de chaleur - Google Patents

Dispositif et procede permettant d'eliminer les gaz dissous d'un milieu liquide d'echange de chaleur contenu dans un systeme d'echange de chaleur, et systeme d'echange de chaleur Download PDF

Info

Publication number
WO2003060384A2
WO2003060384A2 PCT/IE2003/000006 IE0300006W WO03060384A2 WO 2003060384 A2 WO2003060384 A2 WO 2003060384A2 IE 0300006 W IE0300006 W IE 0300006W WO 03060384 A2 WO03060384 A2 WO 03060384A2
Authority
WO
WIPO (PCT)
Prior art keywords
heat exchange
exchange medium
inlet port
side wall
chamber
Prior art date
Application number
PCT/IE2003/000006
Other languages
English (en)
Other versions
WO2003060384A3 (fr
Inventor
Humphrey O'leary
Marianne Keane
Declan John Keane
Paul John Murphy
Thomas Mann
Gerard O'brien
Carl Christian Steinborn
Michael Gerard Tangney
Michael Kevin Winkle
Sean Kavenagh
Original Assignee
Bodenhill Properties Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bodenhill Properties Limited filed Critical Bodenhill Properties Limited
Priority to AU2003202123A priority Critical patent/AU2003202123A1/en
Priority to EP03700981A priority patent/EP1525423A2/fr
Publication of WO2003060384A2 publication Critical patent/WO2003060384A2/fr
Publication of WO2003060384A3 publication Critical patent/WO2003060384A3/fr

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D19/00Details
    • F24D19/08Arrangements for drainage, venting or aerating
    • F24D19/082Arrangements for drainage, venting or aerating for water heating systems
    • F24D19/083Venting arrangements

Definitions

  • a device and a method for removing dissolved gases from a liquid heat exchange medium in a heat exchange system, and a heat exchange system
  • the present invention relates to a device for removing dissolved gases from a liquid heat exchange medium of a heat exchange system, whereby the heat exchange system is of the type comprising a heat source and a heat exchanger, and the liquid heat exchange medium is circulated between the heat source and the heat exchanger for transferring heat from the heat source to the heat exchanger.
  • the invention also relates to a heat exchange system comprising the device for removing dissolved gases from the liquid heat exchange medium in the heat exchange system, and to a method for removing dissolved gases from a liquid heat exchange medium of a heat exchange system.
  • Such heat exchange systems typically comprise a heat source, for example, a boiler and a plurality of heat exchangers, such as radiators connected through a circulating circuit to the boiler.
  • Liquid heat exchange medium typically water
  • a pump in one of the pipes of the circulating circuit circulates the liquid heat exchange medium through the circulating circuit and in turn through the boiler and the radiators for transferring heat from the boiler to the radiators.
  • the radiators typically are supported on walls of rooms for space heating.
  • Such heat exchange systems may also include a separate circuit for heating an indirect hot water tank for providing domestic hot water.
  • such heat exchange systems may include more than one heat source, for example, a gas or oil fired boiler, and a back boiler located in a fireplace.
  • Such heat exchange systems may also include a number of separate heat exchange circuits, each including a plurality of radiators for heating different zones in a building or the like, as well as a circuit for heating an indirect tank of a domestic hot water system.
  • Such heat exchange systems may also include a circuit which includes a heat exchanger for heating water of a swimming pool, and may include one or more circuits comprising one or more under floor heat exchangers for circulating the liquid heat exchange medium through the under floor heat exchangers.
  • the liquid heat exchange medium such as water, includes dissolved gases, for example, air, and in particular, oxygen.
  • dissolved oxygen is typically referred to as free oxygen, and in general, is difficult to remove.
  • Dissolved gases, in particular, free oxygen in a water heat exchange medium causes many problems.
  • the dissolved gases significantly reduce the heat transfer efficiency of the heat exchange system. They lead to excessive noise, air locks, and cavitation in the circulating pump or pumps, as well as corrosion within the system which leads to an accumulation of sludge in the boiler or boilers, and in the radiators, thus further reducing the heat transfer efficiency of the system.
  • the present invention is directed towards providing such a device and a method, and the invention is also directed towards a heat exchange system comprising the device.
  • a device for removing dissolved gases in a liquid heat exchange medium of a heat exchange system of the type comprising a heat source and a heat exchanger, the liquid heat exchange medium being circulated between the heat source and the heat exchanger for transferring heat from the heat source to the heat exchanger
  • the device comprises a housing defining a pressure reduction chamber for accommodating the liquid heat exchange medium therethrough, at least one inlet port for connecting the device into the heat exchange system and for accommodating the liquid heat exchange medium into the pressure reduction chamber from the heat exchange system, at least one outlet port for connecting the device into the heat exchange system for returning the liquid heat exchange medium from the pressure reduction chamber to the heat exchange system, the pressure reduction chamber providing a sudden step change increase in the transverse cross-sectional area presented to the heat exchange medium between the inlet port and the outlet port sufficient for reducing the pressure in the liquid heat exchange medium flowing through the pressure reduction chamber for releasing dissolved gases from the heat exchange medium, and a venting means from the pressure reduction chamber for venting gases released from the heat exchange medium
  • the volume of the pressure reduction chamber is such as to facilitate the release of dissolved gases from the liquid heat exchange medium.
  • the volume of the pressure reduction chamber is such as to allow sufficient dwell time to the liquid heat exchange medium therein for at least some of the dissolved gases released from the heat exchange medium to exit through the venting means.
  • the step change in the transverse cross- sectional area presented to the liquid heat exchange medium between the inlet port and the outlet port is sufficient for inducing turbulence in the heat exchange medium for further facilitating release of dissolved gases from the heat exchange medium in the pressure reduction chamber.
  • the housing comprises a side wall.
  • a turbulence inducing means is located in the pressure reduction chamber for inducing turbulence in the liquid heat exchange medium in the pressure reduction chamber for further facilitating the release of dissolved gases from the heat exchange medium.
  • the turbulence inducing means is located spaced apart from at least one of the at least one inlet port.
  • the turbulence inducing means extends into the pressure reduction chamber from the housing, and is located spaced apart from at least one of the at least one inlet port.
  • the turbulence inducing means comprises an elongated turbulence inducing rib extending longitudinally along the side wall.
  • the turbulence inducing means extends from the side wall into the pressure reduction chamber a distance between 1mm and 5mm.
  • the turbulence inducing means is of width in the range of 2mm to 4mm.
  • one of the at least one inlet ports is located in the side wall, and the turbulence inducing means extends from the side wall spaced apart from the inlet port located in the side wall.
  • the turbulence inducing means is located relative to the inlet port so that the perpendicular distance from the turbulence inducing means to the centre of the inlet port lies in the range of one times the diameter of the inlet port to three times the diameter of the inlet port.
  • the turbulence inducing means is located relative to the inlet port so that the perpendicular distance from the turbulence inducing means to the centre of the inlet port is approximately twice the diameter of the inlet port.
  • the turbulence inducing means extends along the side wall for a distance corresponding to at least the diameter of the inlet port. In another embodiment of the invention the turbulence inducing means extends along the side wall for a distance corresponding to at least three times the diameter of the inlet port.
  • the turbulence inducing means extends from a line extending perpendicularly from the tubular inducing means to the centre of the inlet port on opposite first and second sides of the said line a distance corresponding to at least one and a half diameters of the inlet port.
  • the turbulence inducing means extends for a distance from the first side of the said line extending perpendicularly from the turbulence inducing means to the centre of the inlet port a distance greater than the distance from which the turbulence inducing means extends from the second side of the said line.
  • the turbulence inducing means extends on the first side of the line extending perpendicularly from the turbulence inducing means to the centre of the inlet port for a distance corresponding to at least two diameters of the inlet port.
  • the turbulence inducing means extends on the first side of the line extending perpendicularly from the turbulence inducing means to the centre of the inlet port for a distance corresponding to at least three diameters of the inlet port.
  • the turbulence inducing means extends on the second side of the line extending perpendicularly from the turbulence inducing means to the centre of the inlet port for a distance corresponding to at least two diameters of the inlet port.
  • a pair of inlet ports are located in the side wall, and the turbulence inducing means is located between the respective inlet ports, and preferably, the turbulence inducing means extends perpendicularly to a line joining the centres of the two inlet ports.
  • the turbulence inducing means is located equi-spaced between the two inlet ports.
  • the side wall is a cylindrical side wall, and the turbulence inducing means extends in a generally axial direction relative to the cylindrical side wall.
  • the cylindrical side wall defines a geometrical longitudinally extending central axis.
  • the device is adapted for connecting into the heat exchange system with the central axis extending substantially vertically.
  • the housing comprises a top wall and a spaced apart bottom wall, the top and bottom walls extending transversely of the side wall, and the side wall extends between the top and bottom walls.
  • each inlet port located in the side wall of the housing is located in the side wall towards the bottom wall thereof.
  • an inlet port is located in the top wall.
  • the top wall is of dome shape, and the inlet port is located substantially centrally in the top wall.
  • venting means is located in the top wall.
  • inlet port in the top wall acts as the venting means.
  • an outlet port is located in the side wall cooperating with the inlet port in the top wall for connecting the device into a heat exchange system.
  • the outlet port which co-operates with the inlet port in the top wall is located towards the bottom wall.
  • an outlet port is located in the side wall corresponding to each inlet port in the side wall for co-operating with the said corresponding inlet port for connecting the device into the central heat exchange system.
  • each outlet port in the side wall corresponding to an inlet port in the side wall is located spaced apart from and at a level above the corresponding inlet port.
  • the side wall adjacent each inlet port extends substantially transversely of the direction of flow of heat exchange medium from the inlet port into the pressure reduction chamber.
  • the side wall of the housing comprises at least one planar side wall.
  • the turbulence inducing means comprises an adjacent wall extending from the planar side wall.
  • two of the walls extending from the planar side wall form side walls of the housing.
  • each side wall is a planar side wall.
  • each side wall extending from a planar side wall extends from the planar side wall at a location spaced apart from an adjacent one of the inlet ports a sufficient distance for providing the sudden step change in the transverse cross-sectional area presented to the heat exchange medium.
  • each inlet port is spaced apart from the side wall to which it is closest a distance of at least 10mm. In another embodiment of the invention the periphery of each inlet port is spaced apart from the side wall to which it is closest a distance of at least 12.5mm.
  • each inlet port is spaced apart from the side wall to which it is closest a distance of at least 15mm.
  • each inlet port is spaced apart from the side wall to which it is closest a distance of at least 25mm.
  • each inlet port is of diameter approximately 25mm, and each inlet port is spaced apart from the side wall to which it is closest a distance, centre to side wall of at least 45mm.
  • each inlet port is of diameter approximately 25mm, and each inlet port is spaced apart from the side wall to which it is closest a distance, centre to side wall of at least 50mm.
  • each inlet port is of diameter approximately 25mm, and each inlet port is spaced apart from the side wall to which it is closest a distance, centre to side wall of at least 60mm.
  • each inlet port is of diameter approximately 25mm, and each inlet port is spaced apart from the side wall to which it is closest a distance, centre to side wall of at least 70mm.
  • the housing is a six-sided housing having six planar walls defining six inner planar wall surfaces forming the pressure reduction chamber, and in another embodiment of the invention the pressure reduction chamber is parallelepiped, while in a still further embodiment of the invention the pressure reduction chamber is cubic. In one embodiment of the invention at least one inlet port and one outlet port are provided in the same planar wall of the housing.
  • the minimum distance between peripheral edges of adjacent inlet and outlet ports in the same wall is at least 154mm.
  • the minimum distance between peripheral edges of adjacent inlet and outlet ports in the same wall is at least 164mm.
  • the minimum distance between peripheral edges of adjacent inlet and outlet ports in the same wall is at least 175mm.
  • the minimum distance between the peripheral edges of adjacent inlet ports on the same wall is at least 40mm.
  • the minimum distance between the peripheral edges of adjacent inlet ports on the same wall is at least 75mm.
  • the minimum distance between the peripheral edges of adjacent inlet ports on the same wall is at least 115mm.
  • a plurality of inlet ports are provided to the pressure reduction chamber, and a plurality of outlet ports are provided from the pressure reduction chamber for connecting a plurality of circuits of the heat exchange system, at least one of the circuits being a heat source circuit comprising a heat source for heating the liquid heat exchange medium, and at least one of the circuits being a heat exchange circuit comprising a heat exchanger for transferring heat from the liquid heat exchange medium of the heat exchange system.
  • the volume of the pressure reduction chamber is sufficient for facilitating mixing of the liquid heat exchange medium in the pressure reduction chamber from respective circuits of the heat exchange system.
  • the volume of the pressure reduction chamber is sufficient for facilitating mixing of the liquid heat exchange medium in the pressure reduction chamber from each operational heat exchange circuit with the liquid heat exchange medium from each operational heat source circuit.
  • each outlet port for returning the liquid heat exchange medium to a heat source circuit is located relative to the inlet port through which the liquid heat exchange medium is received into the pressure reduction chamber from the heat source circuit so that the direction of flow of the liquid heat exchange medium from the pressure reduction chamber is at 90° to the direction of flow of the liquid heat exchange medium into the pressure reduction chamber.
  • inlet and outlet ports for connecting the device to each heat exchange circuit are arranged so that the direction of flow of the liquid heat exchange medium from the pressure reduction chamber to the heat exchange circuit is at 180° to the direction of flow of the liquid heat exchange medium into the pressure reduction chamber from the heat exchange circuit.
  • the liquid heat exchange medium of the heat exchange system is a water heat exchange medium.
  • the device is adapted for releasing dissolved oxygen from the liquid water heat exchange medium.
  • the invention provides a heat exchange system comprising a heat source, and at least one heat exchanger, and a circulating system for circulating a liquid heat exchange medium between the heat source and the heat exchanger, and a device according to the invention for removing dissolved gases from the liquid heat exchange medium, characterised in that the device is connected into the circulating system so that the circulating heat exchange medium circulates through the pressure reduction chamber of the device for reducing the pressure of the liquid heat exchange medium in the pressure reduction chamber for releasing dissolved gases from the liquid heat exchange medium.
  • the heat exchange system comprises at least one heat source circuit, each heat source circuit comprising a heat source for heating the liquid heat exchange medium, and at least one heat exchange circuit, each heat exchange circuit comprising at least one heat exchanger for transferring heat from the liquid heat exchange medium.
  • each heat source circuit comprises a flow pipe and a return pipe, the flow pipe of each heat source circuit being connected to the inlet port in the top wall of the housing of the device for delivering heat exchange medium into the pressure reduction chamber, and the return pipe of each heat source circuit being connected to a corresponding one of the outlet ports in the side wall of the housing co-operating with the inlet port in the top wall for returning heat exchange medium to the heat source circuit.
  • each heat exchange circuit comprises a flow pipe and a return pipe, the return pipe of each heat exchange circuit being connected to a corresponding one of the inlet ports in the side wall of the housing of the device for returning heat exchange medium to the pressure reduction chamber, and the flow pipe of each heat exchange circuit being connected to a corresponding one of the outlet ports in the side wall of the housing of the device for receiving heat exchange medium from the pressure reduction chamber.
  • each heat exchanger comprises a heat exchanger for space heating.
  • At least one of the heat exchangers comprises a heat exchanger for providing under floor heating. In a further embodiment of the invention at least one of the heat exchangers comprises a heat exchanger for heating water for a swimming pool.
  • At least one of the heat exchangers is a heat exchanger for heating domestic hot water.
  • the circulating system comprises a primary circulating means in each heat source circuit for circulating the liquid heat exchange medium through the heat source circuit between the heat source and the pressure reduction chamber of the device.
  • the circulating system comprises a secondary circulating means in each heat exchange circuit for circulating the liquid heat exchange medium through the heat exchange circuit between the pressure reduction chamber and each heat exchanger in the heat exchange circuit.
  • the invention provides a method for removing dissolved gases in a liquid heat exchange medium of a heat exchange system of the type which comprises a heat source and a heat exchanger, the liquid heat exchange medium being circulated between the heat source and the heat exchanger for transferring heat from the heat source to the heat exchanger, characterised in that the method comprises the step of passing the liquid heat exchange medium into a pressure reduction chamber having an inlet port for receiving the liquid heat exchange medium from the heat exchange system and an outlet port for returning the liquid heat exchange medium to the heat exchange system, and the pressure reduction chamber provides a sudden step change increase in the transverse cross-sectional area presented to the liquid heat exchange medium between the inlet port and the outlet port for reducing the pressure of the liquid heat exchange medium flowing through the pressure reduction chamber sufficient for releasing dissolved gases from the liquid heat exchange medium, and venting the dissolved gases from the pressure reduction chamber.
  • the method comprises the further step of providing the pressure reduction chamber with a volume such as to facilitate the release of dissolved oxygen from the liquid heat exchange medium.
  • the volume of the pressure reduction chamber is such as to allow sufficient dwell time for the liquid heat exchange medium therein for venting at least some of the dissolved gases released from the liquid heat exchange medium therefrom.
  • the method further comprises the step of inducing turbulence in the liquid heat exchange medium in the pressure reduction chamber for further facilitating the release of dissolved gases from the liquid heat exchange medium.
  • a turbulence inducing means is provided in the pressure reduction chamber for inducing turbulence in the heat exchange medium.
  • the turbulence inducing means is located spaced apart from one of the inlet ports to the pressure reduction chamber.
  • the turbulence inducing means is provided by an elongated rib extending along a side wall of a housing defining the pressure reduction chamber.
  • the turbulence inducing means is formed by a side wall of the housing adjacent to the side wall in which the inlet port is located.
  • a particularly important advantage of the invention is that the device according to the invention removes or significantly reduces dissolved gases in a liquid heat exchange medium of a heat exchange system.
  • the dissolved gases are removed from the liquid heat exchange medium by virtue of the fact that the pressure reduction chamber provides a sudden step change increase in the transverse cross-sectional area presented to the heat exchange medium as it flows through each inlet port into the pressure reduction chamber.
  • the pressure reduction chamber provides a sudden step change increase in the transverse cross-sectional area presented to the liquid heat exchange medium, the heat exchange medium as it enters the pressure reduction chamber expands, thereby reducing the pressure of the liquid heat exchange medium.
  • the reduction in pressure in the liquid heat exchange medium causes dissolved gases in the heat exchange medium to be released. These released dissolved gases are then vented through the venting means from the pressure reduction chamber.
  • the device according to the invention makes use of the principle that dissolved gases in a liquid such as water, are released when the pressure of the liquid is reduced at constant temperature.
  • the amount of dissolved gases which are released by a change in pressure at constant temperature is a function of the pressure drop.
  • the device according to the invention also makes use of the principle that dissolved gases are released from a liquid such as water when the temperature of the liquid is increased at constant pressure.
  • the temperature of the liquid heat exchange medium being returned to the pressure reduction chamber from the heat exchange circuit where heat has been transferred from the liquid heat exchange medium is raised as the heat exchange medium enters the pressure reduction chamber from the heat exchange circuit, thereby further enhancing the release of dissolved gases from the heat exchange medium, due to the fact that as the heat exchange medium is being returned to the pressure reduction chamber, the pressure of the heat exchange medium drops and the temperature increases simultaneously.
  • the simultaneous drop in pressure and rise in temperature of the liquid heat exchange medium further increases the rate of release of dissolved gases from the liquid heat exchange medium.
  • a turbulence inducing means in the pressure reduction chamber induces turbulence into the liquid heat exchange medium in the pressure reduction chamber, and this, it has been found, further enhances the release of dissolved gases from the liquid heat exchange medium, and additionally, facilitates in rapid transfer of the released dissolved gases to and through the venting means from the pressure reduction chamber.
  • the housing forming the pressure reduction chamber comprises a plurality of planar side walls, the adjacent planar side walls to each planar side wall act as turbulence inducing means.
  • a relatively small turbulence inducing rib extending axially along the side wall adjacent to but spaced apart from an inlet port, in general, is sufficient for inducing the appropriate degree of turbulence to the heat exchange medium in the pressure reduction chamber. It is believed that the turbulence inducing rib projecting from the cylindrical side wall deflects the liquid heat exchange medium flowing circumferentially along the side wall away from the side wall and radially into the pressure reduction chamber, for in turn inducing the appropriate degree of turbulence in the liquid heat exchange medium within the pressure reduction chamber.
  • liquid heat transfer medium is water
  • water in general comprises dissolved air and dissolved oxygen
  • the advantages of the device according to the invention are even greater, since by releasing the dissolved gases from the water heat exchange medium, and in particular, dissolved air and dissolved oxygen, the corrosive effect of the dissolved oxygen in the water heat exchange medium is removed.
  • the presence of dissolved oxygen in a water heat exchange medium leads to internal corrosion of heat exchangers, boilers, and depending on the material of the pipework of the circulating system, may also result in internal corrosion of the pipework.
  • the efficiency of the heat exchange system is significantly increased, since cavitation in the pump or pumps of the circulating system is eliminated due to the fact that dissolved gases are removed from the heat exchange medium. It is well known that the presence of dissolved gases in a liquid heat exchange medium, and in particular, in a water heat exchange medium, leads to cavitation in a pump or pumps of a circulating system of a heat exchange system. By reducing and in most cases virtually eliminating cavitation, pumps of the circulating system operate significantly more efficiently, thereby enhancing the efficiency of the heat exchange system, and furthermore, permitting the use of smaller pumps.
  • Heat transfer efficiency from the boiler to the liquid heat exchange medium is significantly increased by the removal of dissolved gases from the liquid heat exchange medium, and furthermore, heat transfer efficiency between the liquid heat exchange medium and the heat exchangers is likewise similarly significantly increased due to the removal of dissolved gases in the liquid heat exchange medium.
  • the heat exchangers can operate at a significantly increased operating temperature, and furthermore, the operating temperature of the heat exchangers can be controlled within a relatively narrow tolerance of approximately 3°C.
  • the pump or pumps of the circulating system may be operated at a lower setting while maintaining the same heat output of the heat exchange system, thereby further enhancing the operating efficiency of the heat exchange system. It has also been found that increased throughput of water through a swimming pool filtration system can be achieved by using the device according to the invention, and such increases can be up to 23%.
  • the volume of the pressure reduction chamber should be matched to the volume and the flow rate of the heat exchange system in order to allow sufficient dwell time for the liquid heat exchange medium in the pressure reduction chamber to allow the released dissolved gases from the liquid heat exchange medium to be vented through the venting means from the pressure reduction chamber. Additionally, where mixing of cooler returning liquid heat exchange medium with hotter liquid heat exchange medium flowing into the pressure reduction chamber takes place, the volume of the pressure reduction chamber should be such as to facilitate adequate mixing of the cooler and hotter liquid heat exchange media within the pressure reduction chamber, in order to allow heating of the cooler heat exchange medium by the hotter heat exchange medium, for further enhancing the release of dissolved gases from the cooler returning heat exchange medium as the temperature of the cooler returning heat exchange medium increases and its pressure drops.
  • the device provides a simple, efficient system of removing dissolved gases from a liquid heat exchange medium, and in particular, for removing dissolved oxygen from a water heat exchange medium, which otherwise is particularly difficult to remove.
  • Fig. 1 is a circuit diagram of a heat exchange system according to the invention incorporating a device also according to the invention for removing dissolved gases from a liquid heat exchange medium of the heat exchange system,
  • Fig. 2 is a perspective view of the device of Fig. 1 for removing dissolved gases from the liquid heat exchange medium of the heat exchange system
  • Fig. 3 is a cutaway perspective view of a portion of the device of Fig. 2,
  • Fig. 4 is a front elevational view of the device of Fig. 2,
  • Fig. 5 is side elevational view of the device of Fig. 2,
  • Fig. 6 is a perspective view of a portion of the device of Fig. 2,
  • Fig. 7 is a perspective view of another portion of the device of Fig. 2,
  • Fig. 8 is a top plan view of the device of Fig. 2,
  • Fig. 9 is a transverse cross-sectional end elevational view of a portion of the device of Fig. 2 on the line IX-IX of Fig. 8,
  • Fig. 10 is a transverse cross-sectional side elevational view on the line X-X of Fig. 8 of the device of Fig. 2,
  • Fig. 1 1 is an enlarged plan view of a detail of the device of Fig. 2,
  • Fig. 12 is a circuit diagram of a heat exchange system according to another embodiment of the invention incorporating the device of Fig. 2,
  • Fig. 13 is a circuit diagram of a heat exchange system according to a further embodiment of the invention incorporating the device of Fig. 2,
  • Fig. 14 is a circuit diagram of a heat exchange system according to a further embodiment of the invention incorporating the device of Fig. 2,
  • Fig. 15 is a circuit diagram of a heat exchange system according to another embodiment of the invention incorporating a device also according to another embodiment of the invention for removing dissolved gases from a liquid heat exchange medium of the heat exchange system,
  • Fig. 16 is a top front perspective view of the device of Fig. 15,
  • Fig. 17 is a cutaway top perspective view of the device of Fig. 15,
  • Fig. 18 is a top side end perspective view of the device of Fig. 15,
  • Fig. 19 is another perspective view of the device of Fig. 15,
  • Fig. 20 is a circuit diagram of a heat exchange system according to another embodiment of the invention comprising the device of Fig. 16 for removing dissolved gases in a liquid heat exchange medium of a heat exchange system,
  • Fig. 21 is a top front perspective view of a device according to another embodiment of the invention for removing dissolved gases from a liquid heat exchange medium of a heat exchange system
  • Fig. 22 is a top front perspective view of a device according to another embodiment of the invention for removing dissolved gases from a liquid heat exchange medium of a heat exchange system
  • Fig. 23 is a circuit diagram of a heat exchange system according to a further embodiment of the invention incorporating the devices of Figs. 16 and 21.
  • a heat exchange system according to the invention, indicated generally by the reference numeral 1.
  • the heat exchange system is suitable for domestic water heating, and is also suitable for space heating a house in which the space heating is divided into two zones, for example, a first zone which may be the ground floor of the house, and a second zone which may be the first floor of the house.
  • the heat exchange system 1 comprises a heat source circuit 3 and two heat exchange circuits, namely, a first heat exchange circuit 4 for space heating the first zone, and a second heat exchange circuit 5 for space heating the second zone.
  • the heat source circuit 3 comprises a heat source, in this embodiment of the invention a boiler 6, which may be a gas fired or an oil fired boiler.
  • Each first and second heat exchange circuit 4 and 5 comprises a plurality of heat exchangers, namely, wall mounted radiators 7. Although only two radiators 7 are illustrated in the first heat exchange circuit 4 and one radiator 7 is illustrated in the second heat exchange circuit 5, it will be readily apparent to those skilled in the art that any appropriate number of radiators 7 will be provided in the first and second heat exchange circuits 4 and 5.
  • Heat is transferred between the boiler 6 and the radiators 7 by a liquid heat transfer medium, which in this embodiment of the invention is a water heat transfer medium.
  • a device also according to the invention for removing dissolved gases, and in particular, dissolved air and oxygen in the water heat exchange medium connects the first and second heat exchange circuits 4 and 5 with the heat source circuit 3.
  • the device 10 as will be described in detail below comprises a housing 11 which defines a pressure reduction chamber 12 for accommodating water heat exchange medium therethrough, and within which the dissolved gases are released from the water heat exchange medium, as will be described below.
  • the heat source circuit 3 comprises a flow pipe 14 which connects a hot water flow outlet of the boiler 6 to the pressure reduction chamber 12 of the device 10.
  • a return pipe 15 from the pressure reduction chamber 12 of the device 10 to a return water inlet of the boiler 6 returns water heat exchange medium from the pressure reduction chamber 12 to the boiler 6.
  • Each first and second heat exchange circuit 4 and 5 comprises a flow pipe 16 through which hot water heat exchange medium from the pressure reduction chamber 12 of the device 10 is delivered to the radiators 7, and a return pipe 17 from which water heat exchange medium from the radiators 7 is returned to the pressure reduction chamber 12 of the device 10.
  • a primary circulating means in this embodiment of the invention a primary circulating pump 18 is located in the return pipe 15 of the heat source circuit 3 for circulating water heat exchange medium between the heat source circuit 3 and the pressure reduction chamber 12 of the device 10.
  • Secondary circulating means namely, secondary circulating pumps 19 located in the return pipes 17 of the first and second heat exchange circuits 4 and 5 circulate water heat exchange medium between the pressure reduction chamber 12 of the device 10 and the radiators 7.
  • a heat exchanger in this embodiment of the invention an indirect hot water tank 20 for providing domestic hot water, is connected in series in the flow pipe 14 of the heat source circuit 3.
  • the indirect hot water tank 20 comprises a hot water cylinder 21 having an indirect heating coil 22 for heating domestic hot water in the hot water cylinder 21.
  • An inlet 23 to the heating coil 22 receives the water heat exchange medium from the boiler 6 through the flow pipe 14, and an outlet 24 from the heating coil 22 returns water heat exchange medium to the flow pipe 14 which in turn is delivered to the pressure reduction chamber 12 of the device 10.
  • a header tank 25 is connected into the heat exchange system 1 through a supply pipe 26 for pressurising the heat exchange system 1 and for providing top-up water for the heat exchange system 1.
  • the supply pipe 26 is teed into the flow pipe 14 at 27 between the indirect hot water tank 20 and the device 10.
  • An expansion pipe 28 is teed off from the flow pipe 14 of the heat source circuit 3 for accommodating expansion of the water heat exchange medium from the heat exchange system 1 to the header tank 25.
  • the expansion pipe 28 is teed off at 29 from the flow pipe 14 between the boiler 6 and the indirect hot water tank 20.
  • the operation of the heat exchange system 1 is as follows.
  • the primary circulating pump 18 is wired with the boiler 6 so that when the boiler 6 is operating, the primary circulating pump 18 also operates for circulating water heat exchange medium through the heat source circuit 3 between the boiler 6 and the pressure reduction chamber 12 of the device 10.
  • the circulating water heat exchange medium from the boiler 6 to the device 10 flows through the indirect heating coil 22 for heating domestic water in the hot water cylinder 21.
  • the appropriate one or both of the secondary circulating pumps 19 are activated for circulating the water heat exchange medium from the pressure reduction chamber 12 of the device 10 through the radiators 7 for heating the radiators 7 for space heating.
  • the housing 11 of the device 10 is a cylindrical housing of plastics material having a cylindrical side wall 30 closed at its lower end by a bottom wall 31 which is concave when viewed from above, and closed at its upper end by a dome shaped top wall 32 to form the pressure reduction chamber 12.
  • the housing 11 is two piece housing of injection moulded plastics material formed in two halves, namely, a lower half 34 and an upper half 35 which are sealably clamped together by a V-band 37.
  • Radially outwardly extending clamping flanges 38 and 39 extend circumferentially around the lower and upper halves 34 and 35, respectively, for engaging the V-band 37 for retaining the lower and upper halves 34 and 35 sealably clamped together.
  • the clamping flanges 38 and 39 are chamfered at 40 and 41, respectively, for cooperating with the V-band 37 so that as the V-band 37 is tightened around the clamping flanges 38 and 39, the flanges 38 and 39 are drawn tightly together for forming a sealed joint.
  • the cylindrical side wall 30 defines a central geometric longitudinally extending central axis 44. Longitudinally extending external reinforcing ribs 45 extend along the outer surface of the side wall 30 for strengthening the side wall 30.
  • Upper arcuate radially extending reinforcing ribs 47 and upper circumferentially extending reinforcing ribs 48 strengthen the top wall 32.
  • Lower arcuate radially extending reinforcing ribs 49 and lower circumferentially extending reinforcing ribs 50 strengthen the bottom wall 31 and provide a ground engaging support for the device 10.
  • the first lower outlet port 55 is connected to the return pipe 15 of the heat source circuit 3 for returning water heat exchange medium from the pressure reduction chamber 12 to the boiler 6.
  • the second lower outlet port 56 is blanked off.
  • the flow pipes of the respective heat source circuits would be teed into the upper inlet port 54 and the return pipes of the heat source circuits would be connected, one each to the first and second lower outlet ports 55 and 56. Accordingly, the upper inlet port 54 and the first and second lower outlet ports 55 and 56 co-operate for connecting the device 10 into the heat exchange system 1.
  • a pair of upper outlet ports 58 and 59 extend from the cylindrical side wall 30 in the upper half 35 of the housing 11 for delivering water heat exchange medium from the pressure reduction chamber 12 to the flow pipes 16 of the first and second heat exchange circuits 4 and 5, respectively.
  • a pair of lower inlet ports 60 and 61 extend from the side wall 30 of the lower half 34 of the housing 11 for receiving return water heat exchange medium into the pressure reduction chamber 12 from the return pipes 17 of the first and second heat exchange circuits 4 and 5, respectively.
  • the upper outlet port 58 and the lower inlet port 60 co-operate with each other for connecting the device 10 into the heat exchange system 1 through the first heat exchange circuit 4, while the upper outlet port 59 and the lower inlet port 61 cooperate with each other for connecting the device 10 into the heat exchange system 1 through the second heat exchange circuit 5.
  • a turbulence inducing means for inducing turbulence in the water heat exchange medium in the pressure reduction chamber 12 comprises an elongated turbulence inducing rib 64 extending parallel to the central axis 44 along the inner surface of the cylindrical side wall 30 in the lower half 34 of the housing 11.
  • the turbulence inducing rib 64 is located between and equi-distant from the lower inlet ports 60 and 61.
  • the turbulence inducing rib 64 is of width w of approximately 2.5mm, and extends from the side wall 30 into the pressure reduction chamber 12 a distance s of approximately 3mm, see Figs. 9, 10 and 11.
  • the length L of the turbulence inducing rib 64 is of length which lies between four and five times the diameter of one of the two lower inlet ports 60 and 61.
  • each of the lower inlet ports 60 and 61 are of diameter of 28mm, and accordingly, the turbulence inducing rib 64 extends axially for a length L of 123mm approximately.
  • the spacing centre to centre between the two lower inlet ports 60 and 61 is approximately equal to 4.5 diameters of one of the two lower inlet ports 60 and 61 , and is thus approximately 130mm.
  • the perpendicular distance from the turbulence inducing rib 64 to the centre of the respective lower inlet ports 60 and 61 is approximately 65mm.
  • the turbulence inducing rib 64 is located so that it extends axially upwardly above a line 65 joining the centres of the lower inlet ports 60 and 61 for a distance of just over two diameters of one of the lower inlet ports 60 and 61 , and extends downwardly below the line 65 for a similar distance.
  • the turbulence inducing rib 64 extends for a distance of approximately 62mm downwardly below the line 65, and extends for a distance upwardly above the line 65 for a distance of approximately 62mm.
  • the diameter of the upper outlet ports 58 and 59 is similar to the diameter of the two lower inlet ports 60 and 61 , and each upper outlet port 58 and 59 is located and spaced vertically above its corresponding lower inlet port 60 and 61 a distance of 5.8 diameters of the lower inlet ports 60 and 61 , namely, a distance of 163mm, approximately.
  • Water heat exchange medium on entering the pressure reduction chamber 12 through the upper inlet port 54 is presented with a sudden step change increase in the transverse cross-sectional area from the diameter of the upper inlet port 54 to the diameter of the pressure reduction chamber 12, which causes the water heat exchange medium to expand as it enters the pressure reduction chamber 12, thus reducing the pressure of the water heat exchange medium as it enters the pressure reduction chamber 12.
  • the reduction in pressure in the water heat exchange medium releases dissolved gases, in particular dissolved air and oxygen from the water heat exchange medium, which readily bubbles upwards in the pressure reduction chamber 12 and exits through the upper inlet port 54, which also acts as a venting means for venting the released dissolved gases from the water heat exchange medium from the pressure reduction chamber 12.
  • the portion of the flow pipe 14 connecting the upper inlet port 54 to the supply pipe 26, and the supply pipe 26 should continuously rise to the header tank 25 in order to ensure a continuously rising path for venting the released dissolved gases from the water heat exchange medium from the pressure reduction chamber 12 to the header tank 25 from which the vented dissolved gases are thus released to atmosphere.
  • an automatic vent unit is connected to the flow pipe 14 just above the upper inlet port 54 for venting the released dissolved gases from the water heat exchange medium.
  • Return water heat exchange medium from the return pipes 17 of the first and second heat exchange circuits 4 and 5 on entering the pressure reduction chamber 12 through the lower inlet ports 60 and 61 is presented with a sudden step increase in cross-sectional area, and thus the return water heat exchange medium entering the pressure reduction chamber 12 through the lower inlet ports 60 and 61 expands, thus reducing the pressure of the return water heat exchange medium as it enters the pressure reduction chamber 12.
  • the reduction in pressure of the return water heat exchange medium causes dissolved gases including air and oxygen to be released from the return water heat exchange medium into the pressure reduction chamber 12 which is vented through the upper inlet port 54.
  • the return water heat exchange medium being returned to the pressure reduction chamber 12 through the lower inlet ports 60 and 61 on entering the pressure reduction chamber 12 is heated, thereby raising the temperature of the return water heat exchange medium, which further facilitates in releasing dissolved gases from the water heat exchange medium.
  • the turbulence inducing rib 64 acts on the return water heat exchange medium being returned to the pressure reduction chamber 12 through the lower inlet ports 60 and 61 for inducing turbulence in the return water heat exchange medium in the pressure reduction chamber 12 which further facilitates and enhances the release of dissolved gases from the water heat exchange medium.
  • the induced turbulence also facilitates rapid venting of the released dissolved gases from the pressure reduction chamber 12 through the upper inlet port 54.
  • the turbulence inducing rib 64 induces turbulence in the return water heat exchange medium returning to the pressure reduction chamber 12 through the lower inlet ports 60 and 61 by virtue of the fact that some of the return water heat exchange medium on entering the pressure reduction chamber 12 commences to flow in a circumferential direction around the inner surface of the cylindrical side wall 30.
  • the turbulence inducing rib 64 directs this water heat exchange medium away from the side wall 30 radially into the pressure reduction chamber 12, which induces the turbulence in the water heat exchange medium in the pressure reduction chamber 12.
  • flow water heat exchange medium flowing into the pressure reduction chamber 12 through the upper inlet port 54 commences to flow along the inner surface of the top wall 32, however, on reaching the cylindrical side wall 30 which extends downwardly from the top wall 32 the flow water heat exchange medium is directed downwardly away from the inner surface of the top wall 32, thereby also inducing additional turbulence in the pressure reduction chamber 12.
  • the first and second lower outlet ports 55 and 56 extend from the pressure reduction chamber 12 at an angle of 90° to the direction at which the upper inlet port 54 enters the pressure reduction chamber 12. Accordingly, water heat exchange medium passing through the pressure reduction chamber 12 from the upper inlet port 54 to the first and second lower outlet ports 55 and 56 is turned through an angle of 90°.
  • the corresponding lower inlet and upper outlet ports 60 and 58, and 61 and 59 are located relative to each other so that the water heat exchange medium entering the pressure reduction chamber 12 through the lower inlet ports 60 and 61 is turned through an angle of 180° to exit through the respective upper outlet ports 58 and 59. This, thus, further increases the turbulence in the water heat exchange medium within the pressure reduction chamber 12.
  • the turbulence induced in the pressure reduction chamber 12 as well as enhancing the release of dissolved air and dissolved oxygen from the water heat exchange medium, also facilitates in mixing of the water heat exchange medium from the first and second heat exchange circuits 4 and 5 with the water heat exchange medium flowing into the pressure reduction chamber 12 from the heat source circuit 3.
  • the inner diameter of the cylindrical side wall 30 is approximately 226mm, while the average internal height of the pressure reduction chamber 12 is approximately 370mm, thus providing the pressure reduction chamber 12 with a volume of 17 litres, approximately.
  • the device 1 with the pressure reduction chamber 12 of volume 17 litres is suitable for use in a heat exchange system of heat output up to 150,000 BTU, and may be suitable for heat exchange systems of significantly higher heat output.
  • the volume of the pressure reduction chamber 12 is also selected to ensure adequate mixing of the water heat exchange medium from the first and second heat exchange circuits 4 and 5 with the water heat exchange medium from the heat source circuit 3. It has been found that the device 1 with the pressure reduction chamber 12 of volume 17 litres is adequate for providing the appropriate degree of mixing of the water heat exchange medium from the first and second heat exchange circuits 4 and 5 with that of the heat source circuit 3, in a heat exchange system of heat output up to 17 litres.
  • the operation of the device 10 is based on the principle that dissolved gases are released from a liquid, for example, water when the pressure of the water is reduced at constant temperature, the volume and dimensions of the pressure reduction chamber 12 of the device 10 are selected so that the respective inlet ports 54, 60 and 61 are located in walls, namely, the top wall 32 in the case of the upper inlet port 54 and the side wall 30 in the case of the lower inlet ports 60 and 61 so that the water heat exchange medium flowing into the pressure reduction chamber 12 through the respective inlet ports 54, 60 and 61 is presented with a sudden step change increase in transverse cross-sectional area, which is sufficient for reducing the pressure of the water heat exchange medium as it flows into the pressure 006
  • This reduction in pressure of the water heat exchange medium as it flows into the pressure reduction chamber 12 causes dissolved gases, and in particular, dissolved air and oxygen from the water heat exchange medium to be released.
  • the released gases bubble out of the water heat exchange medium and are vented through the upper inlet port 54 to the header tank 25 from which they are exhausted to atmosphere.
  • the heat exchange system 1 In use, with the boiler 6 and the primary circulating pump 18 operational, the heat exchange system 1 is ready for heating both domestic water in the indirect hot water tank 20 and the radiators in the first and second heat exchange circuits 4 and 5. Depending on the zones of the house to be heated, the appropriate secondary circulating pump 19 or pumps 19 in the first and second heat exchange circuits 4 and 5 are operated for circulating water heat exchange medium from the pressure reduction chamber 12 to the radiators 7.
  • the heated water heat exchange medium circulating between the heat source circuit 3 and the pressure reduction chamber 12 heats the domestic hot water in the indirect hot water tank 20, and in turn mixes with the water heat exchange medium from the first and second heat exchange circuits 4 and 5, the circulating pumps 19 of which are operational, and thus heated water heat exchange medium is circulated through the upper outlet ports 58 and 59 to the flow pipes 16 of the first and second heat exchange circuits 4 and 5, and cooler water heat exchange medium from the radiators 7 is returned through the lower inlet ports 60 and 61 from the return pipes 17 of the first and second heat exchange circuits 4 and 5.
  • the cooler return water heat exchange medium from the first and second heat exchange circuits 4 and 5 is thus returned from the pressure reduction chamber 12 through the return pipe 15 of the heat source circuit 3 to the boiler 6 for reheating.
  • dissolved gases in particular, dissolved air and oxygen are released from the water heat exchange medium as it enters the pressure reduction chamber 12 through the upper inlet port 54 and the lower inlet ports 60 and 61 as already described.
  • the released dissolved air and oxygen bubble through the water heat exchange medium in the pressure reduction chamber 12 and are vented through the upper inlet port 54 and in turn through the water in the header tank 25 to atmosphere.
  • top-up water from the header tank 25 should not be required, and in which case, it has been found that after the heat exchange system 1 has been operating for an appropriate number of hours, typically, fifteen to twenty-four hours, substantially all the dissolved gases and oxygen in the water heat exchange medium are removed. Thereafter, use of the heat exchange system continues with the water heat exchange medium with no dissolved gases, air or oxygen in the water heat exchange medium, or if there is any remaining dissolved gases, air or oxygen in the water heat exchange medium, this is subsequently removed by further passes of the water heat exchange medium through the pressure reduction chamber 12.
  • a heat exchange system also according to the invention indicated generally by the reference numeral 70.
  • the heat exchange system 70 is substantially similar to the heat exchange system 1 and similar components are identified by the same reference numerals.
  • the only difference between the heat exchange system 70 and the heat exchange system 1 is that the heating coil 22 of the indirect hot water tank 20 and flow pipe 14 of the heat source circuit 3 are parallel to each other, and the heat exchange system 70 comprises only one heat exchange circuit, namely, the first heat exchange circuit 4.
  • the second heat exchange circuit has been omitted. Because the second heat exchange circuit has been omitted, the upper outlet port 59 and the lower inlet port 61 are closed off by suitable blanking plugs. Otherwise, the heat exchange system 70 is similar to the heat exchange system 1 and its use and operation is likewise similar.
  • a heat exchange system 75 which is similar to the heat exchange systems 1 and 70, and similar components are identified by the same reference numerals.
  • the heating coil 22 of the indirect hot water tank 20 is in series with the flow pipe 14 of the heat source circuit 3.
  • the main difference between the heat exchange system 75 and the heat exchange systems 70 and 1 is that the pipework from the upper inlet port 54 of the device 10 does not continuously rise to the header tank 25.
  • an automatic air vent unit 76 is located in the flow pipe 14 of the heat source circuit 3 adjacent the upper inlet port 54 for venting released dissolved gases from the water heat exchange medium to atmosphere.
  • FIG. 14 there is illustrated a heat exchange system also according to the invention, indicated generally by the reference numeral 80.
  • the heat exchange system 80 is substantially similar to the heat exchange systems 1 and 70 and similar components are identified by the same reference numerals.
  • the heat exchange system 80 comprises only a first heat exchange circuit 4, however, in this embodiment of the invention the heat exchange system 80 is a pressurised closed system which is pressurised by a pressure vessel 81 of the type which will be well known to those skilled in the art.
  • an automatic venting unit 82 which is similar to the automatic air vent unit 76 of the heat exchange system 75, is provided in the flow pipe 14 of the heat source circuit 3 adjacent the upper inlet port 54 to the pressure reduction chamber 12.
  • a safety pressure relief valve 83 is also provided in the flow line 14 of the heat source circuit 3 adjacent the boiler 6.
  • FIG. 85 there is illustrated a heat exchange system according to another embodiment of the invention, indicated generally by the reference numeral 85.
  • the heat exchange system 85 is substantially similar to the heat exchange system 1 and similar components are identified by the same reference numerals.
  • the device 10 is substituted with a device 86 according to another embodiment of the invention also for removing dissolved air and oxygen from the water heat exchange medium.
  • the device 86 comprises a housing in the form of a hollow cube comprising a front end wall 87 and a spaced apart rear end wall 88, which are joined by respective spaced apart side walls 89 and 90.
  • a top wall 91 extends between the front and rear end walls 87 and 88 and between the side walls 89 and 90
  • a bottom wall 92 extends between the front and rear end walls 87 and 88 and the side walls 89 and 90, and defines with the top wall 91 , the front and rear end walls 87 and 88 and the side walls 89 and 90 a pressure reduction chamber 93.
  • the respective front and rear end walls, side walls and top and bottom walls 87 to 92 are all planar walls and are of similar square shape to form a cube, which in turn defines the pressure reduction chamber 93 as a cubic chamber.
  • An upper inlet port 94 is centrally located in the top wall 91 for connecfing to the flow pipe 14 of the heat source circuit 3 for accommodating water heat exchange medium from the heat source circuit 3 into the pressure reduction chamber 93.
  • a lower outlet port 95 in the side wall 89 for connecfing to the return pipe 15 of the heat source circuit 3 returns water heat exchange medium from the pressure reduction chamber 93 to the heat source circuit 3, and in turn to the boiler 6.
  • a venting means in this embodiment of the invention is provided by a vent port 97 which is located in the top wall 91 for venting released dissolved gases from the water heat exchange medium. The vent port 97 is connected directly to the supply pipe 26.
  • vent port 97 instead of being connected to the supply pipe 26 may be connected to the expansion pipe 28, and the supply pipe 26 would then be connected into the heat exchange system 1 at a suitable alternative location.
  • the vent port 97 is located in the top wall 91 on a diagonal extending through the centre of the top wall 91 to the corner defined by the front end wall 87 and the side wall 89.
  • the device 86 also comprises a lower inlet port 98 and an upper outlet port 99 in the front end wall 87 for connecting respectively to the return pipe 17 and flow pipe 16 of the first heat exchange circuit 4.
  • the first heat exchange circuit 4 is omitted, as is the second heat exchange circuit.
  • the inlet and outlet ports 98 and 99 are not used, and thus are closed off by appropriate blanking plugs.
  • the principle of operation of the device 86 for reducing dissolved gases in the water heat exchange medium is similar to that of the device 10.
  • the volume of the pressure reduction chamber 93 is selected and the respective inlet ports 94 and 98 are located in their respective corresponding walls 91 and 87 so that the water heat exchange medium flowing through the inlet ports 94 and 98 into the pressure reducfion chamber 93 is presented with a sudden step change increase in transverse cross-sectional area sufficient for reducing the pressure of the water heat exchange medium as it flows into the pressure reduction chamber 93.
  • This thus releases dissolved gases, and in particular, dissolved oxygen from the water heat exchange medium.
  • the released gases bubble out of the water heat exchange medium to the vent port 97 and in turn rise through the supply pipe 26 into the header tank 25.
  • the volume of the pressure reducfion chamber 93 is such as to induce turbulence in the water heat exchange medium as it is flowing into the pressure reduction chamber 93 through the inlet ports 94 and 98 for further enhancing the release of dissolved gases including oxygen in the water heat exchange medium.
  • the volume of the pressure reduction chamber 93 is also sized to provide a sufficient dwell time for the water heat exchange medium in the pressure reduction chamber 93 to ensure that at least most, if not all of the released gases exit through the vent port 97.
  • the volume of the pressure reduction chamber 93 should be sufficient for facilitating adequate mixing of the water heat exchange medium from the respective heat exchange circuits with the heat source circuit 3.
  • the internal volume of the pressure reduction chamber 93 is 22 litres, approximately, being formed by the walls 87 to 92 of inner dimensions 279mm by 279mm.
  • the centre of the upper inlet port 94 in the top wall 91 is spaced apart from each of the inner surfaces of the front end and side walls 87 to 90 a minimum distance of 139.5mm.
  • the bore diameter of the inlet ports 94 and 98 is 25mm.
  • the bore diameter of the upper outlet ports 99 is also 25mm, while the bore diameter of the lower outlet port 95 is 38mm.
  • the lower inlet port 98 in the front end wall 87 is closest to the bottom wall 92 and the centre of the lower inlet port 98 is spaced apart from the inner surface of the bottom wall 92 a distance of 50mm.
  • the location of the outlet ports 95 and 99 relative to the adjacent walls 87 to 92 is not particularly critical, however, it is desirable that they should be spaced apart at least 50mm from their closest adjacent wall, centre of port to wall.
  • the housing of the device 86 may be of any suitable material, however, since dissolved oxygen is being released from the water heat exchange medium within the pressure reduction chamber 93 it may in certain circumstances be desirable that the housing should be of a non-corrosive material, such as, for example, stainless steel. However, in general, it has been found that in the device 86 according to the invention dissolved air and oxygen is so rapidly released that a housing of mild steel is adequate. Additionally, since dissolved oxygen and gases are being released from the water heat exchange medium within the pressure reduction chamber 93, the walls 87 to 92 are subjected to fluctuations in pressure, and it is important that the housing should be of sufficient strength to withstand such pressure fluctuations. Typically, walls of 5mm thickness should be adequate.
  • water heat exchange medium heated in the boiler 6 is circulated by the primary circulating pump 18 through the flow and return pipes 14 and 15, respectively, from the boiler 6 to the heating coil 22 of the indirect hot water tank 20 for transferring heat from the boiler 6 to the indirect hot water tank 20 for heating domestic water therein.
  • the water heat exchange medium from the indirect hot water tank 20 on passing through the upper inlet port 94 into the pressure reduction chamber 93 on being presented with the sudden step change increase in transverse cross-sectional area expands, thus reducing the pressure in the water heat exchange medium, and in turn releasing dissolved gases, and in particular dissolved oxygen from the water heat exchange medium.
  • the dissolved gases and oxygen bubble through the water heat exchange medium in the pressure reduction chamber 93, and exit through the vent port 97.
  • the dissolved gases and oxygen from the vent port 97 are vented through the supply pipe 26, into the header tank 25, and thus to atmosphere. Any released dissolved gases which do not exit through the vent port 97 are redissolved into the water heat exchange medium, for subsequent release on the next pass through the pressure reducfion chamber 93.
  • a heat exchange system according to another embodiment of the invention indicated generally by the reference numeral 100.
  • the heat exchange system 100 is substanfially similar to the heat exchange system 85 and similar components are identified by the same reference numeral.
  • a first heat exchange circuit 4 is provided, which comprises a plurality of radiators 7, although only one radiator 7 is illustrated.
  • the return pipe 17 of the first heat exchange circuit 4 is connected into the lower inlet port 98 of the device 86, while the flow pipe 16 is connected to the upper outlet port 99 of the device 86.
  • Water heat exchange medium returning through the lower inlet port 98 from the return pipe 17 into the pressure reduction chamber 93 is presented with a sudden step change increase in transverse cross- sectional area, thus reducing the pressure of the returning water heat exchange medium, which results in release of dissolved gases, and in particular oxygen from the water heat exchange medium.
  • the released gases and oxygen bubble through the water heat exchange medium in the pressure reducfion chamber 93 and exit through the vent port 97 to the header tank 25.
  • the returning water heat exchange medium from the first heat exchange circuit 4 is mixed with hot water heat exchange medium from the heat source circuit 3 from the boiler 6, and is thus heated for recirculation from the device 86 into the first heat exchange circuit 4.
  • the rise in temperature of the water heat exchange medium returning from the first heat exchange circuit 4 further enhances the release of dissolved gases including dissolved oxygen from the returning water heat exchange medium.
  • water heat exchange medium flowing into the pressure reducfion chamber 93 from the heat source circuit 3 through the upper inlet port 94, and from the first heat exchange circuit 4 through the lower inlet port 98 is subjected to a reducfion in pressure, thus releasing dissolved gases including dissolved oxygen from the water heat exchange medium, which in turn exits through the vent port 97.
  • operation of the heat exchange system 100 is substantially similar to that of the heat exchange systems 1 and 85.
  • a device 110 for removing dissolved gases and in particular dissolved oxygen from water heat exchange medium in a central heat exchange system.
  • the device 110 is substanfially similar to the device 86, and similar components are identified by the same reference numerals.
  • the only difference between the device 110 and the device 86 is that two lower inlet ports 98a and 98b and two upper outlet ports 99a and 99b are provided in the front end wall 87 of the device 110.
  • the bore diameters of the inlet and outlet ports are similar to the bore diameters of the corresponding inlet and outlet ports of the device 86.
  • the spacing between the centres of the respective lower inlet ports 98a and 98b and their closest adjacent wall 87 to 92, and the spacing between the centres of the respective upper outlet ports 99a and 99b and their closest adjacent walls 88 to 92 is similar to that already described with reference to the device 86. Additionally, the spacing between the centres of the lower inlet ports 98a and 98b is approximately 140mm, and the spacing between the centres of the lower inlet ports 98a and 98b and their closest upper outlet port 99a and 99b is approximately 179mm. Otherwise the device 110 is similar to the device 86.
  • a heat source circuit will be connected to the device 110 through the upper inlet and lower outlet ports 94 and 95, and respective heat exchange circuits will be connected to the device 110 through the respective lower inlet and upper outlet ports 98a, 98b and 99a and 99b.
  • a second heat source circuit may be connected through one of the pairs of lower inlet and upper outlet ports 98a, 98b and 99a and 99b.
  • the upper outlet port 99 would become an inlet port for connecting to the flow pipe of the heat source circuit
  • the lower inlet port 98 would become an outlet port for connecfing to the return pipe of the heat source circuit.
  • a device 115 also according to the invention for removing dissolved gases including dissolved oxygen in a water heat exchange medium of a heat exchange system.
  • the device 115 is substantially similar to the devices 86 and 110, and similar components are identified by the same reference numerals.
  • the only difference between the device 115 and the devices 86 and 110 is that three pairs of lower inlet and upper outlet ports 98 and 99 are provided in the front end wall 87, which lower inlet and upper outlet ports are identified by the reference numerals 98a, 98b and 98c, and 99a, 99b and 99c, respectively.
  • a heat source circuit will be connected to the upper inlet and lower outlet ports 94 and 95 of the device 115, while respecfive heat exchange circuits will be connected to the respecfive pairs of lower inlet and upper outlet ports 98a, 98b and 98c, and 99a, 99b and 99c.
  • a second and/or third heat source circuit could be connected to the device 115 through any of the pairs of lower inlet and upper outlet ports 98a, 98b and 98c, and 99a, 99b and 99c, respectively.
  • the spacing between adjacent lower inlet ports 98, centre to centre is approximately 65mm, while the spacing between adjacent lower inlet and upper outlet ports 98 and 99 is approximately 179mm.
  • the device 115 is similar to the devices 86 and 110, and its operation is likewise similar.
  • a heat exchange system 120 according to a further embodiment of the invention, which is also substantially similar to the heat exchange system 85, and similar components are identified by the same reference numerals.
  • the heat exchange system 120 is a closed system, and the boiler 6 is an oil or gas fired boiler.
  • the heat exchange system 120 comprises two devices for removing dissolved gases from water heat exchange medium, namely, a device 86 and a device 110.
  • the device 86 connects the heat source circuit 3 to an intermediate circuit 121 which includes a flow pipe 122 and a return pipe 123.
  • the intermediate circuit 121 supplies water heat exchange medium from the device 86 to the device 110 which in turn supplies the water heat exchange medium to a heat exchange circuit 125.
  • the heat exchange circuit 125 comprises a plurality of heat exchangers, in this embodiment of the invention provided by under floor heat exchange units 126.
  • the device 86 is connected to the heat source circuit 3 in similar fashion as the device 86 is connected into the heat exchange system 85, the flow pipe 14 from the heat source circuit 3 being connected to the upper inlet port 94 in the top wall 91 of the device 86 and the return pipe 15 to the boiler 6 being connected to the lower outlet port 95 in the side wall 89.
  • the flow pipe 122 of the intermediate circuit 121 is connected to the upper outlet port 99 of the device 86, while the return pipe 123 of the intermediate circuit 121 is connected to the lower inlet port 98 of the device 86.
  • a pressure vessel 127 is connected to the vent port 97 of the device 86 for pressurising the heat exchange system 120.
  • a mixing valve 130 is located in the flow pipe 122 of the intermediate circuit 121 and is connected to the return pipe 123 by an intermediate pipe 131 for mixing return water heat exchange medium from the device 110 with flow water heat exchange medium from the device 86 for controlling the temperature of the water heat exchange medium to the device 110.
  • the operation of such mixing valves will be well known to those skilled in the art.
  • a secondary circulating pump 133 located in the flow pipe 122 of the intermediate circuit 121 circulates water heat exchange medium between the respective devices 86 and 110.
  • the heat exchange circuit 125 comprises a flow pipe 135 and a return pipe 136.
  • a secondary circulating pump 137 in the flow pipe 135 circulates water heat exchange medium through the heat exchange circuit 125 between the device 110 and the under floor heat exchange units 126.
  • the flow pipe 122 of the intermediate circuit 121 is connected to the upper outlet port 99a, which acts as an inlet port to the pressure reducfion chamber 93, while the return pipe 123 of the intermediate circuit 121 is connected to the lower inlet port 98a, which acts as an outlet port to the pressure reducfion chamber 93.
  • the flow pipe 135 of the heat exchange circuit 125 is connected to the upper outlet port 99b of the device 110, while the return pipe 136 of the heat exchange circuit 125 is connected to the lower inlet port 98b of the device 110.
  • An automafic vent valve 138 is connected to the vent port 97 of the device 110 for venting released dissolved gases from the pressure reduction chamber 93 of the device 110.
  • operation of the device 86 with respect to the heat source circuit 3 and the intermediate circuit 121 is similar to the operation of the device 86 in the heat exchange system 85.
  • Return water heat exchange medium being returned to the device 86 through the return pipe 123 of the intermediate circuit 121 is presented with a sudden step change increase in transverse cross-sectional area as it enters the pressure reduction chamber 93 of the device 86, and thus expands reducing the pressure of the water heat exchange medium.
  • Dissolved gases and dissolved oxygen in the water heat exchange medium are released from the water heat exchange medium and vented through the vent port 97, and in turn through the automatic vent valve 128.
  • Flow water heat exchange medium to the device 86 through the flow pipe 14 of the heat source circuit 3 is also presented with a sudden step change increase in the transverse cross-sectional area as it enters the pressure reduction chamber 93 through the upper inlet port 94, and thus expands also releasing dissolved gases from the water heat exchange medium, which are in turn vented through the vent port 97.
  • Return water heat exchange medium to the device 110 from the return pipe 136 of the heat exchange circuit 125 is likewise presented with a sudden step change increase in transverse cross-sectional area as it enters the pressure reduction chamber 93 through the lower inlet port 98b, and thus expands reducing the pressure in the water heat exchange medium, and thus releasing dissolved gases and oxygen therefrom, which are in turn vented through the vent port 97, and in turn the automafic vent valve 138.
  • flow water heat exchange medium in the flow pipe 122 of the intermediate circuit 121 similarly is subjected to a reducfion in pressure as it enters the pressure reducfion chamber 93 of the device 110 through the upper outlet port 99a, thus releasing dissolved gases, which are in turn vented through the vent port 97 and the automatic vent valve 138.
  • Figs. 15, 20 and 23 have been described as comprising devices 86 and 110 which are of cubic shape, the devices 86 and 110 may be replaced by the device 10. Additionally, the device 10 in the heat exchange systems of Figs. 1 , 12, 13 and 14 may be replaced with the devices 86, 110 or 115.
  • each side wall may be provided with one pair or more than one pair of lower inlet and upper outlet ports.
  • more than one lower outlet port may be provided from the devices 86 and 110 for connecfing the devices 86 and 110 with more than one heat source circuit, and indeed, the lower outlet ports may be provided on the same or different side walls, and furthermore, such lower outlet ports could be provided in the front and rear end walls also if desired, as well as in the side walls.
  • the device 10 has been described as comprising two lower inlet ports and two upper outlet ports, it will be readily apparent to those skilled in the art that the device 10 may be provided with many more pairs of lower inlet and upper outlet ports. Similarly, more than two lower outlet ports may be provided for connecting the device 10 with a corresponding number of heat source circuits.
  • devices 10, 86, 110 and 115 have been described as being of a specific volume, it will be readily apparent to those skilled in the art that the devices may be provided of different volumes, and indeed, the devices would be provided in appropriate volumes to match the capacity of the heat exchange systems into which they are to be connected.
  • the device 10 has been described as comprising only a single turbulence inducing rib, the device may be provided with a number of turbulence inducing ribs, and this would particularly be so where the device is provided with more than two lower inlet ports. In general, it is envisaged that a turbulence inducing rib will be provided between each adjacent pair of lower inlet ports.
  • any other suitable turbulence inducing means may be provided. It is also envisaged that while the adjacent side walls to the side wall in which an inlet port is provided to the devices 86, 110 and 115 are adequate for inducing an appropriate degree of turbulence into the water heat exchange medium in the pressure reducfion chamber of the devices, additional turbulence inducing means may be provided, for example, turbulence inducing ribs similar to that provided in the device 10.
  • vent port 97 between the upper inlet port 94 and the corner defined by the front end wall 87 and the side wall 89 in which the lower inlet and upper outlet ports 98 and 99, and the outlet port 95, respectively are located is that the volume beneath the vent port 97 is the volume within the pressure reduction chamber 93 in which most turbulence occurs, and thus the volume in which the maximum amount of dissolved air and oxygen is released from the water heat exchange medium.
  • the flow rate of the water heat exchange medium through the heat exchange system is increased by use of the device according to the invention, circulating pump or pumps within the heat exchange system can be set at their lowest settings while still maintaining the desired heat output from the heat exchange system. Indeed, it has been found that after a heat exchange system with the device according to the invention installed had been running for approximately 12 hours, a significant increase in the throughput of water through a swimming pool filtration system was achieved, and the increase achieved was approximately 23.6%.
  • a further advantage of the device according to the invention is that it is suitable for installation in new heat exchange systems, and is also ideally suited for retrofitting in existing heat exchange systems.
  • the devices according to the invention may be installed in heat exchange systems of other circuit layouts.
  • the heat source circuit may be provided without the indirect hot water tank located in the flow pipe of the heat source circuit.
  • the indirect hot water tank may be provided in one of the heat exchange circuits, or may be provided in a separate independent heat exchange circuit connected to the device through a pair of lower inlet and upper outlet ports.
  • one or more of the lower inlet ports and one or more of the upper outlet ports may be located in the base wall of the devices.
  • the housing of the device 10 has been described as being of plasfics material and formed in two parts, it is envisaged that the housing 10 may be of any other suitable material, for example, metal, such as stainless steel, mild steel or the like, as well as copper, brass or any other suitable metal.
  • the housing may be formed in one piece, and where the housing is formed by, for example, rotational plasfics moulding, the housing typically would be formed as a one piece housing.
  • the housing is of metal material or other such heat conductive materials
  • the housing may be encased or surrounded by a suitable heat insulating material, and indeed, even where the housing of the device is provided in a plastics material, the housing may also be surrounded or encased in a suitable heat insulating material.
  • the devices 86, 110 and 115 have been described as being of cubic shape, the devices may be of any other suitable or desired parallelepiped shape, or indeed, 006
  • the device 10 may be of other suitable shape besides that described, for example, instead of the side wall being a cylindrical side wall, it could be a multi-panel side wall, for example, a multi- panel side wall which would define a hexagonal, octagonal or the like cross-section in plan view. It will also be appreciated that while the devices have been described as comprising inlet and oufiet ports of specific diameters, the inlet and outlet ports may be of any other suitable cross-section, circular or otherwise, and may be of any other suitable or desired dimensions.
  • the size of the housings may be scaled upwardly or downwardly, and while the distances of the inlet and outlet ports from their closest walls and their positioning relafive to each other may also be scaled in certain cases, it is envisaged that the port sizes may not necessarily be correspondingly scaled.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Physical Water Treatments (AREA)
  • Degasification And Air Bubble Elimination (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

L'invention a trait à un dispositif (10) permettant d'éliminer l'air et l'oxygène dissous d'un milieu aqueux d'échange de chaleur contenu dans un système d'échange de chaleur (1). Ledit dispositif comprend un logement (11) définissant une chambre de réduction de pression (12). Un orifice d'entrée supérieur (54) et un orifice de sortie inférieur (55) relient la chambre de réduction de pression (12) à des tuyaux de conduite et de retour (14, 15) situés respectivement dans un circuit de source de chaleur (3), et des orifices d'entrée inférieurs (60, 61) et des orifices de sortie supérieurs (58, 59) relient la chambre de réduction de pression (12) à des tuyaux de conduite et de retour (16, 17) situés dans des premier et second circuits d'échange de chaleur (4, 5) du système d'échange de chaleur (1). La chambre de réduction de pression (12) est dimensionnée et les orifices d'entrée (54, 60, 61) sont placés de façon que le milieu aqueux d'échange de chaleur entrant dans la chambre de réduction de pression (12) se dilate, ce qui réduit la pression dudit milieu aqueux d'échange de chaleur et en libère des gaz dissous. Les gaz libérés sont évacués par l'orifice d'entrée supérieur (54) vers un collecteur (25), puis dans l'atmosphère.
PCT/IE2003/000006 2002-01-21 2003-01-21 Dispositif et procede permettant d'eliminer les gaz dissous d'un milieu liquide d'echange de chaleur contenu dans un systeme d'echange de chaleur, et systeme d'echange de chaleur WO2003060384A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU2003202123A AU2003202123A1 (en) 2002-01-21 2003-01-21 A device and a method for removing dissolved gases from a liquid heat exchange medium in a heat exchange system,and a heat exchange system
EP03700981A EP1525423A2 (fr) 2002-01-21 2003-01-21 Dispositif et procede permettant d'eliminer les gaz dissous d'un milieu liquide d'echange de chaleur contenu dans un systeme d'echange de chaleur, et systeme d'echange de chaleur

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
IE20020053 2002-01-21
IES020053 2002-01-21
IE20020862 2002-11-06
IES020862 2002-11-06

Publications (2)

Publication Number Publication Date
WO2003060384A2 true WO2003060384A2 (fr) 2003-07-24
WO2003060384A3 WO2003060384A3 (fr) 2004-04-15

Family

ID=26320341

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IE2003/000006 WO2003060384A2 (fr) 2002-01-21 2003-01-21 Dispositif et procede permettant d'eliminer les gaz dissous d'un milieu liquide d'echange de chaleur contenu dans un systeme d'echange de chaleur, et systeme d'echange de chaleur

Country Status (4)

Country Link
EP (1) EP1525423A2 (fr)
AU (1) AU2003202123A1 (fr)
IE (1) IES20030026A2 (fr)
WO (1) WO2003060384A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2514688A (en) * 2013-05-29 2014-12-03 Linda Brannigan Central Heating system

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1264146A1 (fr) 2000-05-11 2002-12-11 Timothy Cremin Chauffage central
WO2014191754A1 (fr) 2013-05-29 2014-12-04 Brannigan, Linda Système de chauffage central

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2652069A (en) * 1947-05-26 1953-09-15 Herman M Goheen Distributing and venting header
WO1999040373A1 (fr) * 1998-02-09 1999-08-12 Coopra Consumentenproducten B.V. Dispositif servant a stocker ou a rechauffer de l'eau chaude, son procede de fabrication et dispositif de purge d'air
DK199800367U4 (da) * 1998-10-01 2000-01-28 Tonni Olesen Vvs Teknik Udluftningsrør

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1264146A1 (fr) 2000-05-11 2002-12-11 Timothy Cremin Chauffage central
WO2014191754A1 (fr) 2013-05-29 2014-12-04 Brannigan, Linda Système de chauffage central

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1525423A2

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2514688A (en) * 2013-05-29 2014-12-03 Linda Brannigan Central Heating system
WO2014191754A1 (fr) * 2013-05-29 2014-12-04 Brannigan, Linda Système de chauffage central
GB2514688B (en) * 2013-05-29 2015-10-28 Linda Brannigan Central Heating system
US20160109140A1 (en) * 2013-05-29 2016-04-21 Linda BRANNIGAN Central heating system

Also Published As

Publication number Publication date
AU2003202123A1 (en) 2003-07-30
WO2003060384A3 (fr) 2004-04-15
EP1525423A2 (fr) 2005-04-27
IES20030026A2 (en) 2003-09-17

Similar Documents

Publication Publication Date Title
US4426037A (en) Boiler for a heating system, as an article of manufacture, a boiler-heating system combination, and a method for heating a heat-transfer medium such as water in a heating system
EP2771622B1 (fr) Échangeur de chaleur pour chaudière à condensation
KR100596161B1 (ko) 분리형 이중 열교환식 급탕 보일러
US4462463A (en) Triple pass heat exchanger
CA2857916A1 (fr) Systeme de chauffe-eau a reservoir de stockage a chauffage indirect
EP0073560B1 (fr) Installation de chauffage de fluides chauffée par combustible
US5950575A (en) Hydronic manifold
US11300301B2 (en) Manifold, a buffer tank comprising the manifold, and a method for operating a heat exchange system
JP3889001B2 (ja) 液体加熱システム
EP0957327B1 (fr) Ensemble serpentin d'un échangeur de chaleur
US6334411B1 (en) High efficiency, glass-lined, combination space and hot water heater
KR102337878B1 (ko) 내부 순환형 보일러
WO2003060384A2 (fr) Dispositif et procede permettant d'eliminer les gaz dissous d'un milieu liquide d'echange de chaleur contenu dans un systeme d'echange de chaleur, et systeme d'echange de chaleur
EP3286503B1 (fr) Système de chaudière
GB1578505A (en) Heat exchangers
US7465907B1 (en) Microwave boiler and hot water heater
US4681257A (en) Hot-water-furnace supplemental heater
KR100822173B1 (ko) 보일러의 연소실 냉각구조
US20220146146A1 (en) Diffuser for thermal storage tank
JP2019066084A (ja) 熱交換器
KR20110116704A (ko) 절전형전기온수보일러
EP1544551B1 (fr) Echangeur de chaleur pour systèmes de chauffage
JP4485253B2 (ja) 鋳鉄製セクショナル無圧開放式温水ヒータ
EP2754976B1 (fr) Echangeur de chaleur externe
KR20060087356A (ko) 열교환기 및 이를 채용한 스팀/온수 공급시스템

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2003700981

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2003700981

Country of ref document: EP

NENP Non-entry into the national phase in:

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP

WWW Wipo information: withdrawn in national office

Ref document number: 2003700981

Country of ref document: EP